Loading...
The URL can be used to link to this page
Your browser does not support the video tag.
Home
My WebLink
About
Back-Up Documents - Environmental Report Part 2
/.2ceAnalytical® www.pacelabs.com March 08, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451857 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 05, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry. EE&G Environmental Services. LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 11 aceAnalytical www.pacelabs.com CERTIFICATIONS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451857 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 11 aceAnalytical wvnv pacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451857 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35451857001 MW-31 Water 03/04/19 15:16 03/05/19 17:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 11 aceAnalytical www.pacelabs.com SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451857 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35451857001 MW-31 EPA 6010 JWP 3 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 11 /eAnaI}icaI wwwpacelabs.com SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451857 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35451857001 MW-31 EPA 6010 Arsenic 92.0 ug/L EPA6010 Barium 16.6 ug/L REPORT OF LABORATORY ANALYSIS 10.0 03/07/19 21:06 10.0 03/07/19 21:06 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 11 ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451857 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-31 Lab ID: 35451857001 Collected: 03/04/19 15:16 Received: 03/05/19 17:45 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3010 Arsenic 92.0 ug/L 10.0 7.1 1 03/07/19 10:29 03/07/19 21:06 7440-38-2 Barium 16.6 ug/L 10.0 0.84 1 03/07/19 10:29 03/07/19 21:06 7440-39-3 Lead 4.6 U ug/L 10.0 4.6 1 03/07/19 10:29 03/07/19 21:06 7439-92-1 Date: 03/08/2019 01:07 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 11 ace Analytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451857 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521178 Analysis Method: EPA 6010 QC Batch Method: EPA3010 Analysis Description: 6010 MET Associated Lab Samples: 35451857001 METHOD BLANK: 2814528 Matrix: Water Associated Lab Samples: 35451857001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic ug/L 7.1 U 10.0 7.1 03/07/19 20:40 Barium ug/L 0.84 U 10.0 0.84 03/07/19 20:40 Lead ug/L 4.6 U 10.0 4.6 03/07/19 20:40 LABORATORY CONTROL SAMPLE: 2814529 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic ug/L 250 251 100 80-120 Barium ug/L 250 250 100 80-120 Lead ug/L 250 260 104 80-120 1ATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2814530 2814531 MS MSD 35451859001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L 7.1 U 250 250 259 252 104 101 75-125 3 20 Barium ug/L 11.5 250 250 266 260 102 99 75-125 2 20 Lead ug/L 4.6 U 250 250 260 255 104 102 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/08/2019 01:07 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 11 ceAnalytical® www.pacelabs.com QUALIFIERS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451857 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS U Compound was analyzed for but not detected. Date: 03/08/2019 01:07 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 11 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451857 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Analytical QC Batch Method QC Batch Analytical Method Batch 35451857001 MW-31 Date: 03/08/2019 01:07 PM EPA 3010 521178 EPA 6010 521271 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 11 Pace Analytica CHAIN-CW°# • 35451857 lent The Chain -of- ll I IIIIIIIIIIIIIIIIIII mpleted accurately. Section A Section B Required Client Information: Required Project Information: 35451857 Page : 1 Of i Company EEFG Environmental Services, LLC Report To In.,,.,, r{o_- 1r,c'iA Ajg..L ••••� -•- Addreas 5'i S1 Miami Lakes Dr Copy To. Le s, C�P.ai.-47 _ Company Name Hialeah, FL 33014 `) Address Regulatory Agency Email. cc Imo;ns(C-f��� i�P_. ,..,J2r�. r.c .,`Purchase Order #. Pace Ouole Phone (305)374-8300 IFAx Project Name' \Z\ iZe_,5c. (.—c Cc,�rj` Pace Project Manager chrisuna. raschkel tpacclabs corn. State / Location Rebu•st:•d Oce Date. �j.1,,,,\r's- . k ;Air Project #: 2018-3057 Fz':e P,c.,,c h FL Requested Analysts Filtered (Y,N) mArRix cone MATRIX CODE (see valid codes to left) SAMPLE TYPE (G=GRAB C=COMP) I COLLECTED 7 # OF CONTAINERS i Preservatives 2 >- Dnekinq Water DW wmcr WT w:r,i,, w:rr�., ww SAMPLE ID Sn JSoi°SL OL START END 2 o Lu Ov Unpreserved HNO3 HCI Na2S2O3 Analyses Test ,J ` .a d o co Z } 'o O D it W ~ One Character per box. "P. wry Alt AR (A-Z, 0.9 / , -) omrr or Sample Ids must be unique 'rm.., TS DATE TIME DATE TIME a w a h O ncv = 2 0 Z m L z , O 1 X X 2 3 4 5 6 7 8 9 10 11 12 ADDITIONAL COMMENTS RELINQUISHED BY 1 AFFILIATION DATE TIME FIA PTED BY 1 AFLTION DATE TIME SAMPLE CONDITIONS r ,; ; , � �c3j,� _ i� 14�� y n ; y SAMPLER NAME AND SIGNATURE TEMP in C Received on Ice (Y/N) use y Sealed Cooler (Y/NJ_ E Ti Z. PRINT Name of SAMPLER: j / SIGNATURE of SAMPLER: -T / DATE Signed: 1 0 0 ID CO tT 0_ Document Revised. May 30, 2018 ace Analytical Document Name Sample Condition Upon Receipt Form Document No.' WO#:35451857 Issuing Authority Pace Honda Quality Office Project # FM CTR P(06Cie- Cooler #1 Temp.°C � (Visual) (3, Q (Correction Factor) 3. 9 (Actual) Cooler #2 Temp.°C 1 (Visual) 0_ 0 (Correction Factor) (0, 0 (Actual) Cooler #3 Temp.'C 5 5 (Visual) 0 . 0 (Correction Factor) (Actual) Cooler #4 Temp.'C (Visual) (Correction Factor) (Actual) Cooler #5 Temp.°C (Visual) (Correction Factor) (Actual) Cooler#6 Temp.°C (Visual) (Correction Factor) (Actual) Courier: ❑ Fed Ex ❑ UPS USPS ` Client C Commerciaj, Pace Shipping Method: D First Overnight = Priority Overnight Other Billing: E Recipient D Sender Third Party D Credit Card Tracking # Custody Seal on Cooler/Box Present: ❑Yes Packing Material: ❑Bubble Wrap ubble Bags LNone Samples shorted to lab (If Yes, complete) Standard Overnight Shorted Date: Seals intact: ni Yes El Other Comments: Ground CLIENT: 36-EEG Project Manager: Client: Thermometer Used I ` S Date: 1 , / ) l Time: Due Date: 03/12/19 SCUR) Date and Initials of pe Examining contend: Label: Deliver, pH: State of • rigi 9 For WV projects, all containers verified to 56 °C Samples on ice, cooling process has begun Samples on ice, cooling process has begun /Samples on ice, cooling process has begun 9 Samples on ice, cooling process has begun Samples on ice, cooling process has begun [i Samples on ice, cooling process has begun [i Other LI International Priority _ Unknown Shorted Time: ----QN. * Chain of Custody Present E es 111 No DN/A Chain of Custody Filled Out s 0 No ON/A Relinquished Signature & Sampler Name COC eeNo C:N/A Samples Arrived within Hold Time _ Yesss ❑ No ON/A Rush TAT requested on COC DYesN/A Sufficient Volume s _ No DN/A Correct Containers Used _ es Dr No ❑N/A Containers Intact 0 No ON/A Sample Labels match COC (sample IDs & date/time of collection) es D No ❑N/A All containers needing acid/base preservation have been checked. Yes D No ❑N/A All Containers needing preservation are found to be in compliance with EPA recommendation s _• No DN/A Exceptions: VOA, Cotiform, TOC, O&G, Carbamates Preservation information: Preservative' sssttt Lot #/Trace # 'g • Date: i ir('i�/ Initials Headspace in VOA Vials? (>6mm): t=Yes = No 7 A,..„, - Trip Blank Present: -Yes = No—ipIG/A Client Notification/ Resolution: Person Contacted: Comments/ Resolution (use back for additional comments): Date/Time Project Manager Review. Date Page 11 of 11 aceAnalytical www.pacelabs.com March 08, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451845 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 05, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry. EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 13 /72eAnalytical® www.pacelabs.com CERTIFICATIONS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451845 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 13 aceAnalytical www.pacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451845 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach. FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35451845001 MW-31 Water 03/04/19 15:16 03/05/19 17:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 13 aceAnalytical www.pacelabs.com SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451845 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach. FL 33064 954-582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35451845001 MW-31 EPA 6010 JWP 2 PASI-O EPA 300.0 JDM 2 PASI-O EPA 350.1 MAJ 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 13 aceAnalytical wwwpacelabs.com SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451845 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters 35451845001 EPA 6010 EPA 350.1 Result Units Report Limit Analyzed Qualifiers MW-31 Iron 2820 ug/L Nitrogen, Ammonia 0.58 mg/L REPORT OF LABORATORY ANALYSIS 40.0 03/07/19 21:06 0.050 03/06/19 08:18 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 13 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451845 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-31 Lab ID: 35451845001 Collected: 03/04/19 15:16 Received: 03/05/19 17:45 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3010 Aluminum 30.7 U ug/L 100 30.7 1 03/07/19 10:29 03/07/19 21:06 7429-90-5 Iron 2820 ug/L 40.0 9.2 1 03/07/19 10:29 03/07/19 21:06 7439-89-6 300.0 IC Anions Analytical Method: EPA 300.0 Nitrate as N 0.025 U mg/L 0.050 0.025 1 03/06/19 07:19 14797-55-8 Nitrite as N 0.025 U mg/L 0.050 0.025 1 03/06/19 07:19 14797-65-0 350.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia 0.58 mg/L 0.050 0.035 1 03/06/19 08:18 7664-41-7 Date: 03/08/2019 12:37 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 13 www pacelabs. corn QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451845 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521178 Analysis Method: EPA 6010 QC Batch Method: EPA 3010 Analysis Description: 6010 MET Associated Lab Samples: 35451845001 METHOD BLANK: 2814528 Matrix: Water Associated Lab Samples: 35451845001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Aluminum ug/L 30.7 U 100 Iron ug/L 9.2 U 40.0 30.7 03/07/19 20:40 9.2 03/07/19 20:40 LABORATORY CONTROL SAMPLE: 2814529 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Aluminum ug/L 2500 2520 101 80-120 Iron ug/L 2500 2610 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2814530 2814531 MS MSD 35451859001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 30.7 U 2500 2500 2590 2530 103 101 75-125 2 20 Iron ug/L 369 2500 2500 2980 2910 105 102 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/08/2019 12:37 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 13 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451845 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 520750 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 35451845001 METHOD BLANK: 2812105 Matrix: Water Associated Lab Samples: 35451845001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrate as N mg/L 0.025 U 0.050 0.025 03/06/19 11:46 Nitrite as N mg/L 0.025 U 0.050 0.025 03/06/19 11:46 LABORATORY CONTROL SAMPLE: 2812106 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/L 5 5.0 100 90-110 Nitrite as N mg/L 5 4.9 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2812128 2812129 MS MSD 35451851001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrate as N mg/L 0.025 U 5 5 4.8 4.8 96 96 90-110 1 20 Nitrite as N mg/L 0.025 U 5 5 4.9 4.9 98 97 90-110 1 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/08/2019 12:37 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 13 aceAnalytical wwwpacelabs.corn QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451845 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 520730 Analysis Method: EPA 350.1 QC Batch Method: EPA 350.1 Analysis Description: 350.1 Ammonia Associated Lab Samples: 35451845001 METHOD BLANK: 2812044 Matrix: Water Associated Lab Samples: 35451845001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Ammonia mg/L 0.035 U 0.050 0.035 03/06/19 08:14 LABORATORY CONTROL SAMPLE: 2812045 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 1 1.1 105 90-110 MATRIX SPIKE SAMPLE: 2812047 35451845001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 0.58 1 1.6 103 90-110 SAMPLE DUPLICATE: 2812046 35451845001 Dup Parameter Units Result Result RPD Max RPD Qualifiers Nitrogen, Ammonia mg/L 0.58 0.58 0 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/08/2019 12:37 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 13 aceAnalytical® www.pacelabs.com QUALIFIERS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451845 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS U Compound was analyzed for but not detected. Date: 03/08/2019 12:37 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 13 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451845 Lab ID Sample ID QC Batch Method Analytical QC Batch Analytical Method Batch 35451845001 MW-31 EPA 3010 521178 EPA 6010 521271 35451845001 MW-31 EPA 300.0 520750 35451845001 MW-31 EPA 350.1 520730 Date: 03/08/2019 12:37 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. without the written consent of Pace Analytical Services, LLC. Page 11 of 13 ' f'aceAnalytical CHAIN-OF-CU'l The Chain -of -Custody 0#:35451845 accurately. Section A Section B SeInvc 1111 Required Client Information: c Required Protect Information: I 1111 111111 II ii 1II Page : 1 Of 7 Company EE&G Environmental Services, I.LC Report To: L •( kj ` Atte Address 5751 Miami Lakes Or. Copy To. �ai3 Glrrran)3e-l' Con-35451845 Hlaleah, FL 33014 Address' Regulatory Agency Email e Purchase Order it; Pace Quote rho 2n,1v Corte Phone (305)374-8300 ax Project Name: >' �p ' ML�t'225� � 'Y (.,:,IJC',t' Pace Project Manager: Christina raschke@pacelabs com, /� State / Location . Requested Due Dale. q ��� -r� � \ p}� Protect #: 2018-305/ Pace Profile #� / FL Requ .4ales0Fil ered (YIN)• -. MATRIX CODE MATRIX CODE (see valid codes to left) SAMPLE TYPE (G=GRAB C=COMP) COLLECTED SAMPLE TEMP AT COLLECTION N OF CONTAINERS Preservatives Z >- 4 c� F c) J Dankrng Water DW Water Wr Waste Water WW Prudact P SAMPLE ID sottsol,d sL OII OL START END Unpreserred IHNO3 [ Na2S203 Methanol Other Analyses Test 8260 VOC PAH by 8270 SIM TRPH FL -PRO Pesticides 8081(ovtv„ Pesticides 81416 a 1� ICJ -o a N• = t�- � R '\ m c _X o 6010 Ba, Cd, Cr, Se, Ag, 7470 Hgcrt, Ar I O.1 M �yf1• �r +r :Z Residual Chlorine (Y/N) # w0 F One Character per box. wtpn wP (A-Z, 0-9 1 , -) Oltrner ORT Sample Ids must be unique P q nxaaa Is DATE TIME DATE TIME v _ U = O Z :1 ki, -;i .1,-,` th2r5L 5Xr> x_ ,� 2 3 4 5 6 7 8 10 11 .12` , ,ADOITIONAI:•COMMF-{JTS • i Ir .,. .. .:.� .. . ' ; '., QU 1,0I I r:^o a FIG1Al1 .. M tr CATE =' ''TiME . f: t CCEPTTcD BY,I ,FFILIATlO DATE TIME .' SAMPLECONDITON3 1 3 N q .17..'7:. -' ' - )14,[6 I1--5(Qo y tit y (,J� 5c).y N Y SAMPLER NAME AND SIONATURE i.•a -ait •r , r 6y`„ ''1''r ;. t' me"? +1*- .r i,r, 4' t TEMP in C a cc V} m o UFO} e LIS? v:'c} PRINT Name of SAMPLER: A 9 I, \ 1 SIGNATURE of SAMPLER: /f -/ %) I DATE Signed: _, , / / (i .ter J I CO 0 ZT 0 i .10— // Pace Analytical ,. .. .,ccument Name Conoit:on Upon Receipt Form, Document Revises May 30, 2018 Document No . _-C-JOT rev 13 Issuing Authority Pace Florida Quality Office WO#:35451845 Project FM: CTR Project ManagerCLIENT: 36-EEG Client: Thermometer Used State of •rig! Due Date: 03/12/19 -11 (SCUR) Date and Initials of p Examining content: Label: Deliver J pH: '� (—.) Date 3)5) Time I Initials f d Cooler #1 Temp.'C (Visual) Cooler #2 Temp.'C • , (Visual) Cooler #3 Temp.'C 55 (Visual) Cooler #4 Temp.'C (Visual) Cooler#5 Temp.'C Cooler #6 Temp.'C (Visual) (Visual) For VilV projects a _.7 a-s verified to s6 `C (Correction Factor) 3. a (Actual) 0 0 (Correction Factor) ( 0 (Actual) 0.0 (Correction Factor) (Actual) (Correction Factor) (Actual) (Correction Factor) (Correction Factor) Courier: - Fed Ex UPS ❑ USPS - - Client --- - CommerciaV— Pace (Actual) (Actual) Shipping Method: - First Overnight - Priority Overnight = Other Billing: = Recipient Tracking # = Sender Custody Seal on Cooler/Box Present: i_JYes Packing Material: I2Bubble Wrap Samples shorted to lab (If Yes, complete) ubble Bags Shorted Date Standard Overnight - Ground = Third Party = Credit Card Seals intact: — Yes ENone JOther Comments: Samples on ice Samples on ice Samples on ice cooking cooling cooing process nas begun process has begun process nas begun [ Samples on ice, cooing process has begun [ Samples on ice, cooling process has begun [ Samples on ice, cooling process has begun Other = International Priority Unknown ue Dry None Shorted Time 2,ty I yr Chain of Custody Present - es = No =N/A Chain of Custody Filled Out s = No =N/A Relinquished Signature & Sampler Name COC e. e= No =N/A 7s Samples Arrived within Hold Time Yes - No N/A Rush TAT requested on COC _YesN/A Sufficient Volume s = No =N/A Correct Containers Used es = No =N/A Containers Intact s = No 2N/A Sample Labels match COC (sample IDs & date/time of - collection) es 1 = No N/A All containers needing acid/base preservation have been checked _ es = No =N/A All Containers needing preservation are found to be in compliance with EPA recommendation es = No =N/A Exceptions VOA, Conform, TOC, 0&G, Carbamates Preservation Information Preservative ppp Lot #!Trace # • Date ! i(.._ Initials Headspace in VOA Vials? (>6mm): =Yes IT No Trip Blank Present: =Yes = No Client Notification/ Resolution: Person Contacted Comments/ Resolution (use back for additional comments): Date/Time Project Manager Review Date Page 13 of 13 www.pacelabs.com March 12, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451863 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 05, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Some analyses have been subcontracted outside of the Pace Network. The subcontracted laboratory report has been attached. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry, EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 39 ceAnalytical® www.pacelabscom CERTIFICATIONS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451863 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification Ds 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 39 aceAnalytical www.pacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451863 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35451863001 MW-31 Water 03/04/19 15:16 03/05/19 17:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 39 aceAnalytical www.pacelabs.com SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451863 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35451863001 MW-31 EPA 8081 AER 22 PASI-O FL -PRO RJR 3 PASI-O EPA6010 JWP 4 PASI-O EPA 7470 AMS 1 PASI-O EPA 8270 by SIM CB1 20 PASI-O EPA 8260 BTN 69 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 39 aceAnalytical® www.pacelabs.com SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451863 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach. FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35451863001 MW-31 EPA 8081 Dieldrin 0.0023 I ug/L 0.0096 03/09/19 04:53 1 p REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 39 �JO aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451863 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-31 Lab ID: 35451863001 Collected: 03/04/19 15:16 Received: 03/05/19 17:45 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8081 GCS Pesticides Analytical Method: EPA8081 Preparation Method: EPA3510 Aldrin 0.0014 U ug/L 0.0096 0.0014 1 03/06/19 16:26 03/09/19 04:53 309-00-2 1p alpha-BHC 0.0020 U ug/L 0.0096 0.0020 1 03/06/19 16:26 03/09/19 04:53 319-84-6 1p beta-BHC 0.0077 U ug/L 0.0096 0.0077 1 03/06/19 16:26 03/09/19 04:53 319-85-7 1p delta-BHC 0.0046 U ug/L 0.0096 0.0046 1 03/06/19 16:26 03/09/19 04:53 319-86-8 1p gamma-BHC (Lindane) 0.0021 U ug/L 0.0096 0.0021 1 03/06/19 16:26 03/09/19 04:53 58-89-9 1p Chlordane (Technical) 0.17 U ug/L 0.48 0.17 1 03/06/19 16:26 03/09/19 04:53 57-74-9 1p 4,4'-DDD 0.0085 U ug/L 0.0096 0.0085 1 03/06/19 16:26 03/09/19 04:53 72-54-8 1p 4,4'-DDE 0.0048 U ug/L 0.0096 0.0048 1 03/06/19 16:26 03/09/19 04:53 72-55-9 1 p 4,4'-DDT 0.0048 U ug/L 0.0096 0.0048 1 03/06/19 16:26 03/09/19 04:53 50-29-3 1p Dieldrin 0.0023 I ug/L 0.0096 0.0019 1 03/06/19 16:26 03/09/19 04:53 60-57-1 1p Endosulfan I 0.0049 U ug/L 0.0096 0.0049 1 03/06/19 16:26 03/09/19 04:53 959-98-8 1 p Endosulfan II 0.0038 U ug/L 0.0096 0.0038 1 03/06/19 16:26 03/09/19 04:53 33213-65-9 1p Endosulfan sulfate 0.0059 U ug/L 0.096 0.0059 1 03/06/19 16:26 03/09/19 04:53 1031-07-8 1p Endrin 0.0041 U ug/L 0.0096 0.0041 1 03/06/19 16:26 03/09/19 04:53 72-20-8 1p Endrin aldehyde 0.0034 U ug/L 0.096 0.0034 1 03/06/19 16:26 03/09/19 04:53 7421-93-4 1p Endrin ketone 0.0048 U ug/L 0.0096 0.0048 1 03/06/19 16:26 03/09/19 04:53 53494-70-5 1p Heptachlor 0.0059 U ug/L 0.0096 0.0059 1 03/06/19 16:26 03/09/19 04:53 76-44-8 1p Heptachlor epoxide 0.0050 U ug/L 0.0096 0.0050 1 03/06/19 16:26 03/09/19 04:53 1024-57-3 1p Methoxychlor 0.0092 U ug/L 0.0096 0.0092 1 03/06/19 16:26 03/09/19 04:53 72-43-5 1p Toxaphene 0.24 U ug/L 0.48 0.24 1 03/06/19 16:26 03/09/19 04:53 8001-35-2 1p Surrogates Tetrachloro-m-xylene (S) 72 % 27-124 1 03/06/19 16:26 03/09/19 04:53 877-09-8 Decachlorobiphenyl (S) 57 % 10-132 1 03/06/19 16:26 03/09/19 04:53 2051-24-3 FL -PRO Water, Low Volume Analytical Method: FL -PRO Preparation Method: EPA 3510 Petroleum Range Organics 0.77 U mg/L 0.96 0.77 1 03/07/19 09:10 03/07/19 17:33 Surrogates o-Terphenyl (S) 82 % 66-139 1 03/07/19 09:10 03/07/19 17:33 84-15-1 N-Pentatriacontane (S) 84 % 42-159 1 03/07/19 09:10 03/07/19 17:33 630-07-09 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Cadmium 0.33 U ug/L 1.0 0.33 1 03/07/19 10:29 03/07/19 21:06 7440-43-9 Chromium 1.7 U ug/L 5.0 1.7 1 03/07/19 10:29 03/07/19 21:06 7440-47-3 Selenium 8.5 U ug/L 15.0 8.5 1 03/07/19 10:29 03/07/19 21:06 7782-49-2 Silver 1.0 U ug/L 5.0 1.0 1 03/07/19 10:29 03/07/19 21:06 7440-22-4 7470 Mercury Analytical Method: EPA 7470 Preparation Method: EPA 7470 Mercury 0.10 U ug/L 0.20 0.10 1 03/07/19 10:25 03/08/19 16:18 7439-97-6 8270 MSSV PAHLV by SIM Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3510 Acenaphthene 0.040 U ug/L 0.50 0.040 1 03/07/19 02:41 03/07/19 13:02 83-32-9 Acenaphthylene 0.030 U ug/L 0.50 0.030 1 03/07/19 02:41 03/07/19 13:02 208-96-8 Anthracene 0.043 U ug/L 0.50 0.043 1 03/07/19 02:41 03/07/19 13:02 120-12-7 Benzo(a)anthracene 0.055 U ug/L 0.10 0.055 1 03/07/19 02:41 03/07/19 13:02 56-55-3 Benzo(a)pyrene 0.12 U ug/L 0.20 0.12 1 03/07/19 02:41 03/07/19 13:02 50-32-8 Benzo(b)fluoranthene 0.027 U ug/L 0.10 0.027 1 03/07/19 02:41 03/07/19 13:02 205-99-2 Date: 03/12/2019 09:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 39 -aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451863 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-31 Parameters Lab ID: 35451863001 Collected: 03/04/19 15:16 Received: 03/05/19 17:45 Matrix Water Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8270 MSSV PAHLV by SIM Analytical Method: EPA8270 by SIM Preparation Method: EPA3510 Benzo(g,h,i)perylene 0.15 U ug/L 0.50 0.15 1 03/07/19 02:41 03/07/19 13:02 191-24-2 Benzo(k)fluoranthene 0.16 U ug/L 0.50 0.16 1 03/07/19 02:41 03/07/19 13:02 207-08-9 Chrysene 0.026 U ug/L 0.50 0.026 1 03/07/19 02:41 03/07/19 13:02 218-01-9 Dibenz(a,h)anthracene 0.13 U ug/L 0.15 0.13 1 03/07/19 02:41 03/07/19 13:02 53-70-3 Fluoranthene 0.018 U ug/L 0.50 0.018 1 03/07/19 02:41 03/07/19 13:02 206-44-0 Fluorene 0.088 U ug/L 0.50 0.088 1 03/07/19 02:41 03/07/19 13:02 86-73-7 Indeno(1,2,3-cd)pyrene 0.12 U ug/L 0.15 0.12 1 03/07/19 02:41 03/07/19 13:02 193-39-5 1-Methylnaphthalene 0.19 U ug/L 2.0 0.19 1 03/07/19 02:41 03/07/19 13:02 90-12-0 2-Methylnaphthalene 0.68 U ug/L 2.0 0.68 1 03/07/19 02:41 03/07/19 13:02 91-57-6 Naphthalene 0.29 U ug/L 2.0 0.29 1 03/07/19 02:41 03/07/19 13:02 91-20-3 Phenanthrene 0.16 U ug/L 0.50 0.16 1 03/07/19 02:41 03/07/19 13:02 85-01-8 Pyrene 0.032 U ug/L 0.50 0.032 1 03/07/19 02:41 03/07/19 13:02 129-00-0 Surrogates 2-Fluorobiphenyl (S) 68 % 33-82 1 03/07/19 02:41 03/07/19 13:02 321-60-8 p-Terphenyl-d14 (S) 98 % 49-104 1 03/07/19 02:41 03/07/19 13:02 1718-51-0 8260 MSV Analytical Method: EPA 8260 1,1,1,2-Tetrachloroethane 0.32 U ug/L 1.0 0.32 1 03/06/19 16:28 630-20-6 1,1-Trichloroethane 0.30 U ug/L 1.0 0.30 1 03/06/19 16:28 71-55-6 1,1,2,2-Tetrachloroethane 0.20 U ug/L 0.50 0.20 1 03/06/19 16:28 79-34-5 1,1,2-Trichloroethane 0.30 U ug/L 1.0 0.30 1 03/06/19 16:28 79-00-5 1,1-Dichloroethane 0.34 U ug/L 1.0 0.34 1 03/06/19 16:28 75-34-3 1,1-Dichloroethene 0.27 U ug/L 1.0 0.27 1 03/06/19 16:28 75-35-4 1,1-Dichloropropene 0.31 U ug/L 1.0 0.31 1 03/06/19 16:28 563-58-6 1,2,3-Trichlorobenzene 0.34 U ug/L 1.0 0.34 1 03/06/19 16:28 87-61-6 1,2,3-Trichloropropane 1.1 U ug/L 2.0 1.1 1 03/06/19 16:28 96-18-4 1,2,3-Trimethylbenzene 0.17 U ug/L 1.0 0.17 1 03/06/19 16:28 526-73-8 1,2,4-Trichlorobenzene 0.32 U ug/L 1.0 0.32 1 03/06/19 16:28 120-82-1 1,2,4-Trimethylbenzene 0.24 U ug/L 1.0 0.24 1 03/06/19 16:28 95-63-6 1,2-Dichlorobenzene 0.29 U ug/L 1.0 0.29 1 03/06/19 16:28 95-50-1 1,2-Dichloroethane 0.27 U ug/L 1.0 0.27 1 03/06/19 16:28 107-06-2 1,2-Dichloropropane 0.23 U ug/L 1.0 0.23 1 03/06/19 16:28 78-87-5 1,3,5-Trimethylbenzene 0.24 U ug/L 1.0 0.24 1 03/06/19 16:28 108-67-8 1,3-Dichlorobenzene 0.33 U ug/L 1.0 0.33 1 03/06/19 16:28 541-73-1 1,3-Dichloropropane 0.26 U ug/L 1.0 0.26 1 03/06/19 16:28 142-28-9 1,4-Dichlorobenzene 0.28 U ug/L 1.0 0.28 1 03/06/19 16:28 106-46-7 2,2-Dichloropropane 0.59 U ug/L 1.0 0.59 1 03/06/19 16:28 594-20-7 2-Butanone (MEK) 7.5 U ug/L 10.0 7.5 1 03/06/19 16:28 78-93-3 2-Chloroethylvinyl ether 1.4 U ug/L 40.0 1.4 1 03/06/19 16:28 110-75-8 c2 2-Chlorotoluene 0.28 U ug/L 1.0 0.28 1 03/06/19 16:28 95-49-8 2-Hexanone 0.85 U ug/L 10.0 0.85 1 03/06/19 16:28 591-78-6 4-Chlorotoluene 0.22 U ug/L 1.0 0.22 1 03/06/19 16:28 106-43-4 4-Methyl-2-pentanone (MIBK) 0.32 U ug/L 10.0 0.32 1 03/06/19 16:28 108-10-1 Acetone 5.3 U ug/L 20.0 5.3 1 03/06/19 16:28 67-64-1 Benzene 0.30 U ug/L 1.0 0.30 1 03/06/19 16:28 71-43-2 Bromobenzene 0.21 U ug/L 1.0 0.21 1 03/06/19 16:28 108-86-1 Date: 03/12/2019 09:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 39 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451863 Sample: MW-31 Parameters Lab ID: 35451863001 Collected: 03/04/19 15:16 Received: 03/05/19 17:45 Matrix: Water Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Dibromochloromethane Dibromomethane Dichlorodifluoromethane Ethylbenzene lodomethane Isopropylbenzene (Cumene) Methyl-tert-butyl ether Methylene Chloride Styrene Tetrachloroethene Toluene Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene m&p-Xylene n-Butylbenzene n-Propylbenzene o-Xylene p-Isopropyltoluene sec-Butylbenzene tert-Butylbenzene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 03/12/2019 09:11 PM Analytical Method: EPA 8260 0.37 U 0.19 U 2.6 U 4.0 U 0.45 U 1.1 U 0.35 U 3.7 U 0.32 U 0.97 U 0.45 U 0.68 U 0.26 U 0.30 U 9.3 U 0.30 U 0.51 U 2.0 U 0.26 U 0.38 U 0.33 U 0.36 U 0.35 U 0.19 U 0.39 U 2.1 U 0.27 U 0.17 U 2.1 U 0.20 U 0.37 U 0.27 U 0.31 U 0.17 U 0.26 U 0.23 U 0.17 U 88 108 101 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L Ok Ok Ok 1.0 0.60 3.0 5.0 10.0 3.0 1.0 10.0 1.0 1.0 2.0 2.0 1.0 1.0 10.0 1.0 2.0 5.0 1.0 1.0 1.0 1.0 1.0 10.0 1.0 5.0 1.0 0.50 4.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 0.50 70-130 70-130 70-130 0.37 0.19 2.6 4.0 0.45 1.1 0.35 3.7 0.32 0.97 0.45 0.68 0.26 0.30 9.3 0.30 0.51 2.0 0.26 0.38 0.33 0.36 0.35 0.19 0.39 2.1 0.27 0.17 2.1 0.20 0.37 0.27 0.31 0.17 0.26 0.23 0.17 REPORT OF LABORATORY ANALYSIS 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 03/06/19 16:28 74-97-5 75-27-4 75-25-2 74-83-9 v2 75-15-0 v1 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3 v2 124-48-1 74-95-3 75-71-8 100-41-4 74-88-4 v2 98-82-8 1634-04-4 75-09-2 100-42-5 127-18-4 108-88-3 79-01-6 75-69-4 108-05-4 75-01-4 1330-20-7 156-59-2 10061-01-5 179601-23-1 104-51-8 103-65-1 95-47-6 99-87-6 135-98-8 98-06-6 156-60-5 10061-02-6 03/06/19 16:28 460-00-4 03/06/19 16:28 17060-07-0 03/06/19 16:28 2037-26-5 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 39 PaceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451863 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521100 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 35451863001 METHOD BLANK: 2814165 Matrix: Water Associated Lab Samples: 35451863001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L 0.10 U 0.20 0.10 03/08/19 15:31 LABORATORY CONTROL SAMPLE: 2814166 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2 1.9 96 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2814167 2814168 MS MSD 35451633001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual !ercury ug/L 0.10 U 2 2 1.7 1.8 86 88 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/12/2019 09:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 39 PaceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451863 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521178 Analysis Method: EPA 6010 QC Batch Method: EPA 3010 Analysis Description: 6010 MET Associated Lab Samples: 35451863001 METHOD BLANK: 2814528 Matrix: Water Associated Lab Samples: 35451863001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Cadmium ug/L 0.33 U 1.0 0.33 03/07/19 20:40 Chromium ug/L 1.7 U 5.0 1.7 03/07/19 20:40 Selenium ug/L 8.5 U 15.0 8.5 03/07/19 20:40 Silver ug/L 1.0 U 5.0 1.0 03/07/19 20:40 LABORATORY CONTROL SAMPLE: 2814529 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Cadmium ug/L 25 25.7 103 80-120 Chromium ug/L 250 255 102 80-120 Selenium ug/L 250 261 104 80-120 Silver ug/L 25 24.1 96 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2814530 2814531 MS MSD 35451859001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Cadmium ug/L 0.33 U 25 25 26.0 25.4 104 101 75-125 2 20 Chromium ug/L 1.7 U 250 250 262 252 105 101 75-125 4 20 Selenium ug/L 8.5 U 250 250 266 253 106 101 75-125 5 20 Silver ug/L 1.0 U 25 25 24.5 23.7 98 95 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/12/2019 09:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 39 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451863 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 520786 Analysis Method: EPA 8260 QC Batch Method: EPA 8260 Analysis Description: 8260 MSV Associated Lab Samples: 35451863001 METHOD BLANK: 2812236 Matrix: Water Associated Lab Samples: 35451863001 Parameter Blank Reporting Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L 0.32 U 1.0 0.32 03/06/19 09:44 1,1,1-Trichloroethane ug/L 0.30 U 1.0 0.30 03/06/19 09:44 1,1,2,2-Tetrachloroethane ug/L 0.20 U 0.50 0.20 03/06/19 09:44 1,1,2-Trichloroethane ug/L 0.30 U 1.0 0.30 03/06/19 09:44 1,1-Dichloroethane ug/L 0.34 U 1.0 0.34 03/06/19 09:44 1,1-Dichloroethene ug/L 0.27 U 1.0 0.27 03/06/19 09:44 1,1-Dichloropropene ug/L 0.31 U 1.0 0.31 03/06/19 09:44 1,2,3-Trichlorobenzene ug/L 0.34 U 1.0 0.34 03/06/19 09:44 1,2,3-Trichloropropane ug/L 1.1 U 2.0 1.1 03/06/19 09:44 1,2,3-Trimethylbenzene ug/L 0.17 U 1.0 0.17 03/06/19 09:44 1,2,4-Trichlorobenzene ug/L 0.32 U 1.0 0.32 03/06/19 09:44 1,2,4-Trimethylbenzene ug/L 0.24 U 1.0 0.24 03/06/19 09:44 1,2-Dichlorobenzene ug/L 0.29 U 1.0 0.29 03/06/19 09:44 1,2-Dichloroethane ug/L 0.27 U 1.0 0.27 03/06/19 09:44 ,2-Dichloropropane ug/L 0.23 U 1.0 0.23 03/06/19 09:44 i,3,5-Trimethylbenzene ug/L 0.24 U 1.0 0.24 03/06/19 09:44 1,3-Dichlorobenzene ug/L 0.33 U 1.0 0.33 03/06/19 09:44 1,3-Dichloropropane ug/L 0.26 U 1.0 0.26 03/06/19 09:44 1,4-Dichlorobenzene ug/L 0.28 U 1.0 0.28 03/06/19 09:44 2,2-Dichloropropane ug/L 0.59 U 1.0 0.59 03/06/19 09:44 2-Butanone (MEK) ug/L 7.5 U 10.0 7.5 03/06/19 09:44 2-Chloroethylvinyl ether ug/L 1.4 U 40.0 1.4 03/06/19 09:44 2-Chlorotoluene ug/L 0.28 U 1.0 0.28 03/06/19 09:44 2-Hexanone ug/L 0.85 U 10.0 0.85 03/06/19 09:44 4-Chlorotoluene ug/L 0.22 U 1.0 0.22 03/06/19 09:44 4-Methyl-2-pentanone (MIBK) ug/L 0.32 U 10.0 0.32 03/06/19 09:44 Acetone ug/L 5.3 U 20.0 5.3 03/06/19 09:44 Benzene ug/L 0.30 U 1.0 0.30 03/06/19 09:44 Bromobenzene ug/L 0.21 U 1.0 0.21 03/06/19 09:44 Bromochloromethane ug/L 0.37 U 1.0 0.37 03/06/19 09:44 Bromodichloromethane ug/L 0.19 U 0.60 0.19 03/06/19 09:44 Bromoform ug/L 2.6 U 3.0 2.6 03/06/19 09:44 Bromomethane ug/L 4.0 U 5.0 4.0 03/06/19 09:44 Carbon disulfide ug/L 0.45 U 10.0 0.45 03/06/19 09:44 Carbon tetrachloride ug/L 1.1 U 3.0 1.1 03/06/19 09:44 Chlorobenzene ug/L 0.35 U 1.0 0.35 03/06/19 09:44 Chloroethane ug/L 3.7 U 10.0 3.7 03/06/19 09:44 Chloroform ug/L 0.32 U 1.0 0.32 03/06/19 09:44 Chloromethane ug/L 0.97 U 1.0 0.97 03/06/19 09:44 cis-1,2-Dichloroethene ug/L 0.27 U 1.0 0.27 03/06/19 09:44 cis-1,3-Dichloropropene ug/L 0.17 U 0.50 0.17 03/06/19 09:44 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 39 PaceAnalytical wvnv.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451863 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 METHOD BLANK: 2812236 Matrix: Water Associated Lab Samples: 35451863001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Dibromochloromethane ug/L 0.45 U 2.0 0.45 03/06/19 09:44 Dibromomethane ug/L 0.68 U 2.0 0.68 03/06/19 09:44 Dichlorodifluoromethane ug/L 0.26 U 1.0 0.26 03/06/19 09:44 Ethylbenzene ug/L 0.30 U 1.0 0.30 03/06/19 09:44 lodomethane ug/L 9.3 U 10.0 9.3 03/06/19 09:44 Isopropylbenzene (Cumene) ug/L 0.30 U 1.0 0.30 03/06/19 09:44 m&p-Xylene ug/L 2.1 U 4.0 2.1 03/06/19 09:44 Methyl-tert-butyl ether ug/L 0.51 U 2.0 0.51 03/06/19 09:44 Methylene Chloride ug/L 2.0 U 5.0 2.0 03/06/19 09:44 n-Butylbenzene ug/L 0.20 U 1.0 0.20 03/06/19 09:44 n-Propylbenzene ug/L 0.37 U 1.0 0.37 03/06/19 09:44 o-Xylene ug/L 0.27 U 1.0 0.27 03/06/19 09:44 p-lsopropyltoluene ug/L 0.31 U 5.0 0.31 03/06/19 09:44 sec-Butylbenzene ug/L 0.17 U 1.0 0.17 03/06/19 09:44 Styrene ug/L 0.26 U 1.0 0.26 03/06/19 09:44 tert-Butylbenzene ug/L 0.26 U 1.0 0.26 03/06/19 09:44 Tetrachloroethene ug/L 0.38 U 1.0 0.38 03/06/19 09:44 Toluene ug/L 0.33 U 1.0 0.33 03/06/19 09:44 trans-1,2-Dichloroethene ug/L 0.23 U 1.0 0.23 03/06/19 09:44 trans-1,3-Dichloropropene ug/L 0.17 U 0.50 0.17 03/06/19 09:44 Trichloroethene ug/L 0.36 U 1.0 0.36 03/06/19 09:44 Trichlorofluoromethane ug/L 0.35 U 1.0 0.35 03/06/19 09:44 Vinyl acetate ug/L 0.19 U 10.0 0.19 03/06/19 09:44 Vinyl chloride ug/L 0.39 U 1.0 0.39 03/06/19 09:44 Xylene (Total) ug/L 2.1 U 5.0 2.1 03/06/19 09:44 1,2-Dichloroethane-d4 (S) % 103 70-130 03/06/19 09:44 4-Bromofluorobenzene (S) % 94 70-130 03/06/19 09:44 Toluene-d8 (S) % 101 70-130 03/06/19 09:44 LABORATORY CONTROL SAMPLE: 2812237 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 20 20.1 101 70-130 1,1,1-Trichloroethane ug/L 20 18.8 94 70-130 1,1,2,2-Tetrachloroethane ug/L 20 21.3 107 68-125 1,1,2-Trichloroethane ug/L 20 20.1 101 70-130 1,1-Dichloroethane ug/L 20 20.2 101 70-130 1,1-Dichloroethene ug/L 20 18.9 94 66-133 1,1-Dichloropropene ug/L 20 20.3 101 70-130 1,2,3-Trichlorobenzene ug/L 20 21.4 107 64-126 1,2,3-Trichloropropane ug/L 20 21.7 108 62-127 1,2,3-Trimethylbenzene ug/L 20 23.0 115 70-130 1,2,4-Trichlorobenzene ug/L 20 19.4 97 63-124 1,2,4-Trimethylbenzene ug/L 20 20.5 102 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/12/2019 09:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 39 tGaceAnalytical wwwpacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451863 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE: 2812237 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,2-Dichlorobenzene ug/L 20 19.5 97 70-130 1,2-Dichloroethane ug/L 20 17.7 88 70-130 1,2-Dichloropropane ug/L 20 19.3 97 70-130 1,3,5-Trimethylbenzene ug/L 20 20.2 101 70-130 1,3-Dichlorobenzene ug/L 20 19.5 98 70-130 1,3-Dichloropropane ug/L 20 20.2 101 70-130 1,4-Dichlorobenzene ug/L 20 19.4 97 70-130 2,2-Dichloropropane ug/L 20 20.2 101 59-133 2-Butanone (MEK) ug/L 40 44.2 111 47-143 2-Chloroethylvinyl ether ug/L 20 20.2 I 101 41-140 2-Chlorotoluene ug/L 20 20.1 101 70-130 2-Hexanone ug/L 40 46.8 117 48-145 4-Chlorotoluene ug/L 20 20.1 101 70-130 4-Methyl-2-pentanone (MIBK) ug/L 40 48.9 122 57-132 Acetone ug/L 40 48.2 120 46-148 Benzene ug/L 20 19.7 99 70-130 Bromobenzene ug/L 20 20.1 100 70-130 Bromochloromethane ug/L 20 19.0 95 70-130 Bromodichloromethane ug/L 20 18.4 92 70-130 Bromoform ug/L 20 17.3 87 49-126 romomethane ug/L 20 9.7 48 10-165 v2 Carbon disulfide ug/L 20 26.3 131 60-141 v1 Carbon tetrachloride ug/L 20 20.8 104 63-126 Chlorobenzene ug/L 20 19.2 96 70-130 Chloroethane ug/L 20 22.2 111 71-142 Chloroform ug/L 20 19.2 96 70-130 Chloromethane ug/L 20 16.2 81 40-140 v2 cis-1,2-Dichloroethene ug/L 20 19.3 96 70-130 cis-1,3-Dichloropropene ug/L 20 16.3 82 70-130 Dibromochloromethane ug/L 20 15.4 77 62-118 Dibromomethane ug/L 20 18.3 92 70-130 Dichlorodifluoromethane ug/L 20 20.2 101 47-150 Ethylbenzene ug/L 20 20.0 100 70-130 lodomethane ug/L 40 21.7 54 10-164 v2 lsopropylbenzene (Cumene) ug/L 20 19.6 98 70-130 m&p-Xylene ug/L 40 40.4 101 70-130 Methyl-tert-butyl ether ug/L 20 22.3 112 64-124 Methylene Chloride ug/L 20 18.2 91 65-136 n-Butylbenzene ug/L 20 20.5 102 70-130 n-Propylbenzene ug/L 20 21.2 106 70-130 o-Xylene ug/L 20 19.1 96 70-130 p-Isopropyltoluene ug/L 20 17.4 87 70-130 sec-Butylbenzene ug/L 20 20.6 103 70-130 Styrene ug/L 20 18.0 90 70-130 tert-Butylbenzene ug/L 20 20.7 103 70-130 Tetrachloroethene ug/L 20 19.7 98 64-134 Toluene ug/L 20 20.4 102 70-130 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 39 www.pace/abs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451863 LABORATORY CONTROL SAMPLE: 2812237 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers trans-1,2-Dichloroethene ug/L 20 19.7 98 68-127 trans-1,3-Dichloropropene ug/L 20 16.0 80 65-121 Trichloroethene ug/L 20 19.2 96 70-130 Trichlorofluoromethane ug/L 20 22.0 110 65-135 Vinyl acetate ug/L 20 24.4 122 60-144 Vinyl chloride ug/L 20 19.1 95 68-131 Xylene (Total) ug/L 60 59.5 99 70-130 1,2-Dichloroethane-d4 (S) % 101 70-130 4-Bromofluorobenzene (S) % 95 70-130 Toluene-d8 (S) % 99 70-130 MATRIX SPIKE SAMPLE: 2812239 Parameter 35451633002 Spike MS MS % Rec Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 0.32 U 20 13.3 67 70-130 J(M1) 1,1,1-Trichloroethane ug/L 0.30 U 20 14.4 72 70-130 1,1,2,2-Tetrachloroethane ug/L 0.20 U 20 14.9 74 68-125 1,1,2-Trichloroethane ug/L 0.30 U 20 13.9 70 70-130 1,1-Dichloroethane ug/L 0.34 U 20 15.4 77 70-130 1,1-Dichloroethene ug/L 0.27 U 20 16.8 84 66-133 1,1-Dichloropropene ug/L 0.31 U 20 14.3 71 70-130 1,2,3-Trichlorobenzene ug/L 0.34 U 20 11.7 59 64-126 J(M1) 1,2,3-Trichloropropane ug/L 1.1 U 20 13.5 68 62-127 1,2,3-Trimethylbenzene ug/L 0.17 U 20 16.3 82 70-130 1,2,4-Trichlorobenzene ug/L 0.32 U 20 10.7 54 63-124 J(M1) 1,2,4-Trimethylbenzene ug/L 0.24 U 20 12.8 64 70-130 J(M1) 1,2-Dichlorobenzene ug/L 0.29 U 20 12.7 64 70-130 J(M1) 1,2-Dichloroethane ug/L 0.27 U 20 13.1 66 70-130 J(M1) 1,2-Dichloropropane ug/L 0.23 U 20 13.9 70 70-130 1,3,5-Trimethylbenzene ug/L 0.24 U 20 13.1 65 70-130 J(M1) 1,3-Dichlorobenzene ug/L 0.33 U 20 12.9 64 70-130 J(M1) 1,3-Dichloropropane ug/L 0.26 U 20 13.4 67 70-130 J(M1) 1,4-Dichlorobenzene ug/L 0.28 U 20 13.0 65 70-130 J(M1) 2,2-Dichloropropane ug/L 0.59 U 20 12.5 62 59-133 2-Butanone (MEK) ug/L 7.5 U 40 30.1 75 47-143 2-Chloroethylvinyl ether ug/L 1.4 U 20 1.4 U 0 41-140 J(M1) 2-Chlorotoluene ug/L 0.28 U 20 13.2 66 70-130 J(M1) 2-Hexanone ug/L 0.85 U 40 28.5 71 48-145 4-Chlorotoluene ug/L 0.22 U 20 13.3 66 70-130 J(M1) 4-Methyl-2-pentanone (MIBK) ug/L 0.32 U 40 0.32 U 0 57-132 J(M1) Acetone ug/L 5.3 U 40 36.7 82 46-148 Benzene ug/L 0.30 U 20 14.2 71 70-130 Bromobenzene ug/L 0.21 U 20 14.0 70 70-130 Bromochloromethane ug/L 0.37 U 20 13.8 69 70-130 J(M1) Bromodichloromethane ug/L 0.19 U 20 13.4 67 70-130 J(M1) Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 39 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451863 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 MATRIX SPIKE SAMPLE: 2812239 Parameter 35451633002 Spike MS MS % Rec Units Result Conc. Result % Rec Limits Qualifiers Bromoform ug/L 2.6 U 20 11.8 59 49-126 Bromomethane ug/L 4.0 U 20 9.1 46 10-165 v2 Carbon disulfide ug/L 0.45 U 20 22.6 113 60-141 v1 Carbon tetrachloride ug/L 1.1 U 20 15.4 77 63-126 Chlorobenzene ug/L 0.35 U 20 13.5 67 70-130 J(M1) Chloroethane ug/L 3.7 U 20 20.6 103 71-142 Chloroform ug/L 0.32 U 20 14.3 71 70-130 Chloromethane ug/L 0.97 U 20 14.1 70 40-140 v2 cis-1,2-Dichloroethene ug/L 0.27 U 20 14.1 71 70-130 cis-1,3-Dichloropropene ug/L 0.17 U 20 10.3 52 70-130 J(M1) Dibromochloromethane ug/L 0.45 U 20 10.2 51 62-118 J(M1) Dibromomethane ug/L 0.68 U 20 12.4 62 70-130 J(M1) Dichlorodifluoromethane ug/L 0.26 U 20 18.0 90 47-150 Ethylbenzene ug/L 0.30 U 20 13.5 68 70-130 J(M1) lodomethane ug/L 9.3 U 40 9.3 U 21 10-164 v2 Isopropylbenzene (Cumene) ug/L 0.30 U 20 12.2 61 70-130 J(M1) m&p-Xylene ug/L 2.1 U 40 27.0 68 70-130 J(M1) Methyl-tert-butyl ether ug/L 0.51 U 20 14.7 74 64-124 Methylene Chloride ug/L 2.0 U 20 14.4 72 65-136 i-Butylbenzene ug/L 0.20 U 20 12.4 62 70-130 J(M1) -Propylbenzene ug/L 0.37 U 20 14.2 71 70-130 o-Xylene ug/L 0.27 U 20 11.7 59 70-130 J(M1) p-Isopropyltoluene ug/L 0.31 U 20 10.7 54 70-130 J(M1) sec-Butylbenzene ug/L 0.17 U 20 13.5 68 70-130 J(M1) Styrene ug/L 0.26 U 20 11.5 57 70-130 J(M1) tert-Butylbenzene ug/L 0.26 U 20 13.6 68 70-130 J(M1) Tetrachloroethene ug/L 0.38 U 20 12.8 64 64-134 Toluene ug/L 0.33 U 20 14.3 72 70-130 trans-1,2-Dichloroethene ug/L 0.23 U 20 14.8 74 68-127 trans-1,3-Dichloropropene ug/L 0.17 U 20 10.6 53 65-121 J(M1) Trichloroethene ug/L 0.36 U 20 13.4 67 70-130 J(M1) Trichlorofluoromethane ug/L 0.35 U 20 18.5 92 65-135 Vinyl acetate ug/L 0.19 U 20 15.3 76 60-144 Vinyl chloride ug/L 0.39 U 20 16.4 82 68-131 Xylene (Total) ug/L 2.1 U 60 38.8 65 70-130 MS 1,2-Dichloroethane-d4 (S) % 104 70-130 4-Bromofluorobenzene (S) % 90 70-130 Toluene-d8 (S) % 98 70-130 SAMPLE DUPLICATE: 2812238 35451633001 Dup Parameter Units Result Result RPD Max RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L 0.32 U 0.32 U 40 1,1,1-Trichloroethane ug/L 0.30 U 0.30 U 40 1,1,2,2-Tetrachloroethane ug/L 0.20 U 0.20 U 40 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/12/2019 09:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 39 aceAnalytical f/ www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451863 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 SAMPLE DUPLICATE: 2812238 Parameter 35451633001 Dup Max Units Result Result RPD RPD Qualifiers 1,1,2-Trichloroethane ug/L 0.30 U 0.30 U 40 1,1-Dichloroethane ug/L 0.34 U 0.34 U 40 1,1-Dichloroethene ug/L 0.27 U 0.27 U 40 1,1-Dichloropropene ug/L 0.31 U 0.31 U 40 1,2,3-Trichlorobenzene ug/L 0.34 U 0.34 U 40 1,2,3-Trichloropropane ug/L 1.1 U 1.1 U 40 1,2,3-Trimethylbenzene ug/L 0.17 U 0.17 U 40 1,2,4-Trichlorobenzene ug/L 0.32 U 0.32 U 40 1,2,4-Trimethylbenzene ug/L 0.24 U 0.24 U 40 1,2-Dichlorobenzene ug/L 0.29 U 0.29 U 40 1,2-Dichloroethane ug/L 0.27 U 0.27 U 40 1,2-Dichloropropane ug/L 0.23 U 0.23 U 40 1,3,5-Trimethylbenzene ug/L 0.24 U 0.24 U 40 1,3-Dichlorobenzene ug/L 0.33 U 0.33 U 40 1,3-Dichloropropane ug/L 0.26 U 0.26 U 40 1,4-Dichlorobenzene ug/L 0.28 U 0.28 U 40 2,2-Dichloropropane ug/L 0.59 U 0.59 U 40 2-Butanone (MEK) ug/L 7.5 U 7.5 U 40 2-Chloroethylvinyl ether ug/L 1.4 U 1.4 U 40 2-Chlorotoluene ug/L 0.28 U 0.28 U 40 2-Hexanone ug/L 0.85 U 0.85 U 40 4-Chlorotoluene ug/L 0.22 U 0.22 U 40 4-Methyl-2-pentanone (MIBK) ug/L 0.32 U 0.32 U 40 Acetone ug/L 5.3 U 5.3 U 40 Benzene ug/L 0.30 U 0.30 U 40 Bromobenzene ug/L 0.21 U 0.21 U 40 Bromochloromethane ug/L 0.37 U 0.37 U 40 Bromodichloromethane ug/L 0.19 U 0.19 U 40 Bromoform ug/L 2.6 U 2.6 U 40 Bromomethane ug/L 4.0 U 4.0 U 40 v2 Carbon disulfide ug/L 0.45 U 0.45 U 40 v1 Carbon tetrachloride ug/L 1.1 U 1.1 U 40 Chlorobenzene ug/L 0.35 U 0.35 U 40 Chloroethane ug/L 3.7 U 3.7 U 40 Chloroform ug/L 0.32 U 0.32 U 40 Chloromethane ug/L 0.97 U 0.97 U 40 v2 cis-1,2-Dichloroethene ug/L 0.27 U 0.27 U 40 cis-1,3-Dichloropropene ug/L 0.17 U 0.17 U 40 Dibromochloromethane ug/L 0.45 U 0.45 U 40 Dibromomethane ug/L 0.68 U 0.68 U 40 Dichlorodifluoromethane ug/L 0.26 U 0.26 U 40 Ethylbenzene ug/L 0.30 U 0.30 U 40 lodomethane ug/L 9.3 U 9.3 U 40 v2 lsopropylbenzene (Cumene) ug/L 0.30 U 0.30 U 40 m&p-Xylene ug/L 2.1 U 2.1 U 40 Methyl-tert-butyl ether ug/L 0.51 U 0.51 U 40 Methylene Chloride ug/L 2.0 U 2.0 U 40 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/12/2019 09:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 39 aceAnalytical / wwwpacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451863 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 SAMPLE DUPLICATE: 2812238 Parameter 35451633001 Dup Max Units Result Result RPD RPD Qualifiers n-Butylbenzene ug/L 0.20 U 0.20 U 40 n-Propylbenzene ug/L 0.37 U 0.37 U 40 o-Xylene ug/L 0.27 U 0.27 U 40 p-Isopropyltoluene ug/L 0.31 U 0.31 U 40 sec-Butylbenzene ug/L 0.17 U 0.17 U 40 Styrene ug/L 0.26 U 0.26 U 40 tert-Butylbenzene ug/L 0.26 U 0.26 U 40 Tetrachloroethene ug/L 0.38 U 0.38 U 40 Toluene ug/L 0.33 U 0.33 U 40 trans-1,2-Dichloroethene ug/L 0.23 U 0.23 U 40 trans-1,3-Dichloropropene ug/L 0.17 U 0.17 U 40 Trichloroethene ug/L 0.36 U 0.36 U 40 Trichlorofluoromethane ug/L 0.35 U 0.35 U 40 Vinyl acetate ug/L 0.19 U 0.19 U 40 Vinyl chloride ug/L 0.39 U 0.39 U 40 Xylene (Total) ug/L 2.1 U 2.1 U 40 1,2-Dichloroethane-d4 (S) % 103 104 0 40 4-Bromofluorobenzene (S) % 89 91 3 40 Y Toluene-d8 (S) % 100 100 0 40 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/12/2019 09:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 39 www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451863 QC Batch: 520947 Analysis Method: EPA 8081 QC Batch Method: EPA 3510 Analysis Description: 8081 GCS Pesticides Associated Lab Samples: 35451863001 METHOD BLANK: 2813016 Matrix: Water Associated Lab Samples: 35451863001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 4,4'-DDD ug/L 0.0089 U 0.010 0.0089 03/08/19 02:42 4,4'-DDE ug/L 0.0050 U 0.010 0.0050 03/08/19 02:42 4,4'-DDT ug/L 0.0050 U 0.010 0.0050 03/08/19 02:42 Aldrin ug/L 0.0015 U 0.010 0.0015 03/08/19 02:42 alpha-BHC ug/L 0.0021 U 0.010 0.0021 03/08/19 02:42 beta-BHC ug/L 0.0080 U 0.010 0.0080 03/08/19 02:42 Chlordane (Technical) ug/L 0.18 U 0.50 0.18 03/08/19 02:42 delta-BHC ug/L 0.0048 U 0.010 0.0048 03/08/19 02:42 Dieldrin ug/L 0.0020 U 0.010 0.0020 03/08/19 02:42 Endosulfan I ug/L 0.0051 U 0.010 0.0051 03/08/19 02:42 Endosulfan II ug/L 0.0040 U 0.010 0.0040 03/08/19 02:42 Endosulfan sulfate ug/L 0.0062 U 0.10 0.0062 03/08/19 02:42 Endrin ug/L 0.0043 U 0.010 0.0043 03/08/19 02:42 Endrin aldehyde ug/L 0.0036 U 0.10 0.0036 03/08/19 02:42 Endrin ketone ug/L 0.0050 U 0.010 0.0050 03/08/19 02:42 gamma-BHC (Lindane) ug/L 0.0022 U 0.010 0.0022 03/08/19 02:42 Heptachlor ug/L 0.0062 U 0.010 0.0062 03/08/19 02:42 Heptachlor epoxide ug/L 0.0052 U 0.010 0.0052 03/08/19 02:42 Methoxychlor ug/L 0.0096 U 0.010 0.0096 03/08/19 02:42 Toxaphene ug/L 0.25 U 0.50 0.25 03/08/19 02:42 Decachlorobiphenyl (S) % 48 10-132 03/08/19 02:42 Tetrachloro-m-xylene (S) % 67 27-124 03/08/19 02:42 LABORATORY CONTROL SAMPLE & LCSD: 2813017 2813251 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers 4,4'-DDD ug/L 0.5 0.50 0.52 99 103 67-133 4 40 4,4'-DDE ug/L 0.5 0.48 0.50 96 100 59-125 3 40 4,4'-DDT ug/L 0.5 0.51 0.52 102 104 54-132 2 40 Aldrin ug/L 0.5 0.43 0.44 87 88 25-116 2 40 alpha-BHC ug/L 0.5 0.51 0.54 102 109 53-126 6 40 beta-BHC ug/L 0.5 0.51 0.53 101 107 62-130 5 40 delta-BHC ug/L 0.5 0.47 0.52 95 104 35-122 10 40 Dieldrin ug/L 0.5 0.56 0.59 112 118 66-128 5 40 Endosulfan I ug/L 0.5 0.49 0.51 97 102 67-125 4 40 Endosulfan II ug/L 0.5 0.44 0.47 89 95 67-131 7 40 Endosulfan sulfate ug/L 0.5 0.44 0.48 88 96 62-127 9 40 Endrin ug/L 0.5 0.55 0.58 110 115 66-130 5 40 Endrin aldehyde ug/L 0.5 0.45 0.51 90 102 61-124 12 40 Endrin ketone ug/L 0.5 0.46 0.49 91 98 65-132 7 40 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/12/2019 09:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 39 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451863 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE & LCSD: 2813017 2813251 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers gamma-BHC (Lindane) ug/L 0.5 0.54 0.57 108 115 58-127 6 40 Heptachlor ug/L 0.5 0.45 0.48 90 95 35-123 5 40 Heptachlor epoxide ug/L 0.5 0.51 0.53 102 106 62-125 4 40 Methoxychlor ug/L 0.5 0.48 0.50 96 101 59-135 4 40 Decachlorobiphenyl (S) % 47 46 10-132 Tetrachloro-m-xylene (S) % 74 74 27-124 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 39 PaceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451863 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521006 Analysis Method: EPA 8270 by SIM QC Batch Method: EPA 3510 Analysis Description: 8270 Water PAHLV by SIM MSSV Associated Lab Samples: 35451863001 METHOD BLANK: 2813544 Matrix: Water Associated Lab Samples: 35451863001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1-Methylnaphthalene ug/L 0.19 U 2.0 0.19 03/07/19 08:37 2-Methylnaphthalene ug/L 0.68 U 2.0 0.68 03/07/19 08:37 Acenaphthene ug/L 0.040 U 0.50 0.040 03/07/19 08:37 Acenaphthylene ug/L 0.030 U 0.50 0.030 03/07/19 08:37 Anthracene ug/L 0.043 U 0.50 0.043 03/07/19 08:37 Benzo(a)anthracene ug/L 0.055 U 0.10 0.055 03/07/19 08:37 Benzo(a)pyrene ug/L 0.12 U 0.20 0.12 03/07/19 08:37 Benzo(b)fluoranthene ug/L 0.027 U 0.10 0.027 03/07/19 08:37 Benzo(g,h,i)perylene ug/L 0.15 U 0.50 0.15 03/07/19 08:37 Benzo(k)fluoranthene ug/L 0.16 U 0.50 0.16 03/07/19 08:37 Chrysene ug/L 0.026 U 0.50 0.026 03/07/19 08:37 Dibenz(a,h)anthracene ug/L 0.13 U 0.15 0.13 03/07/19 08:37 Fluoranthene ug/L 0.018 U 0.50 0.018 03/07/19 08:37 Fluorene ug/L 0.088 U 0.50 0.088 03/07/19 08:37 Indeno(1,2,3-cd)pyrene ug/L 0.12 U 0.15 0.12 03/07/19 08:37 Naphthalene ug/L 0.29 U 2.0 0.29 03/07/19 08:37 Phenanthrene ug/L 0.16 U 0.50 0.16 03/07/19 08:37 Pyrene ug/L 0.032 U 0.50 0.032 03/07/19 08:37 2-Fluorobiphenyl (S) % 63 33-82 03/07/19 08:37 p-Terphenyl-d14 (S) % 102 49-104 03/07/19 08:37 LABORATORY CONTROL SAMPLE: 2813545 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1-Methylnaphthalene ug/L 5 3.3 66 40-96 2-Methylnaphthalene ug/L 5 3.3 65 40-94 Acenaphthene ug/L 5 3.2 65 42-96 Acenaphthylene ug/L 5 3.2 63 39-90 Anthracene ug/L 5 3.7 75 46-109 Benzo(a)anthracene ug/L 5 4.1 83 50-116 Benzo(a)pyrene ug/L 5 4.1 83 48-117 Benzo(b)fluoranthene ug/L 5 4.2 85 51-124 Benzo(g,h,i)perylene ug/L 5 4.1 83 47-121 Benzo(k)fluoranthene ug/L 5 4.4 88 50-125 Chrysene ug/L 5 4.4 87 53-122 Dibenz(a,h)anthracene ug/L 5 4.0 80 45-123 Fluoranthene ug/L 5 4.5 90 52-119 Fluorene ug/L 5 3.4 68 44-100 Indeno(1,2,3-cd)pyrene ug/L 5 4.0 79 46-121 Naphthalene ug/L 5 3.2 64 40-91 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 39 aceAnalytical wwwpacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451863 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE: 2813545 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phenanthrene ug/L 5 3.7 73 47-111 Pyrene ug/L 5 4.4 88 51-120 2-Fluorobiphenyl (S) % 71 33-82 p-Terphenyl-d14 (S) % 98 49-104 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2813901 2813902 MS MSD 35452061003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1-Methylnaphthalene ug/L 0.19 U 5 5 3.1 3.1 62 62 40-96 1 40 2-Methylnaphthalene ug/L 0.68 U 5 5 3.2 3.1 64 61 40-94 4 40 Acenaphthene ug/L 0.040 U 5 5 3.0 3.2 60 63 42-96 4 40 Acenaphthylene ug/L 0.030 U 5 5 2.9 3.0 58 61 39-90 4 40 Anthracene ug/L 0.043 U 5 5 3.7 3.9 74 78 46-109 5 40 Benzo(a)anthracene uglL 0.055 U 5 5 4.0 4.2 81 83 50-116 3 40 Benzo(a)pyrene ug/L 0.12 U 5 5 4.0 4.0 81 79 48-117 2 40 Benzo(b)fluoranthene ug/L 0.027 U 5 5 4.0 4.0 81 80 51-124 1 40 Benzo(g,h,i)perylene ug/L 0.15 U 5 5 4.0 3.8 79 77 47-121 3 40 'enzo(k)fluoranthene ug/L 0.16 U 5 5 4.2 4.1 84 82 50-125 2 40 ,;hrysene ug/L 0.026 U 5 5 4.2 4.2 84 85 53-122 1 40 Dibenz(a,h)anthracene ug/L 0.13 U 5 5 3.9 3.7 77 74 45-123 4 40 Fluoranthene ug/L 0.018 U 5 5 4.5 4.7 89 94 52-119 5 40 Fluorene ug/L 0.088 U 5 5 3.2 3.4 65 69 44-100 5 40 Indeno(1,2,3-cd)pyrene ug/L 0.12 U 5 5 3.9 3.7 77 75 46-121 3 40 Naphthalene ug/L 0.29 U 5 5 2.9 2.9 58 58 40-91 0 40 Phenanthrene ug/L 0.16 U 5 5 3.7 3.8 73 77 47-111 4 40 Pyrene ug/L 0.032 U 5 5 4.4 4.5 87 91 51-120 4 40 2-Fluorobiphenyl (S) % 68 70 33-82 p-Terphenyl-d14 (S) % 97 98 49-104 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 21 of 39 f a eAnal�/tical J' www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451863 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521011 Analysis Method: FL -PRO QC Batch Method: EPA 3510 Analysis Description: FL -PRO Water Low Volume Associated Lab Samples: 35451863001 METHOD BLANK: 2813560 Matrix: Water Associated Lab Samples: 35451863001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Petroleum Range Organics N-Pentatriacontane (S) o-Terphenyl (S) mg/L % % 0.80 U 1.0 0.80 03/07/19 12:40 86 42-159 03/07/19 12:40 79 66-139 03/07/19 12:40 LABORATORY CONTROL SAMPLE: 2813561 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Petroleum Range Organics N-Pentatriacontane (S) o-Terphenyl (S) mg/L % ok 4.4 87 66-119 99 42-159 94 66-139 MATRIX SPIKE SAMPLE: 2814271 35452019001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Petroleum Range Organics mg/L 0.73 U 4.6 3.9 80 65-123 N-Pentatriacontane (S) % 89 42-159 o-Terphenyl (S) % 90 66-139 SAMPLE DUPLICATE: 2814272 35451859001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Petroleum Range Organics N-Pentatriacontane (S) o-Terphenyl (S) mg/L % % 0.79 U 0.77 U 97 91 81 89 9 7 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/12/2019 09:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 22 of 39 aceAnalytical® www.pacelabs.com QUALIFIERS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451863 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: 520947 [M5] A matrix spike/matrix spike duplicate was not performed for this batch due to insufficient sample volume. ANALYTE QUALIFIERS The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. U Compound was analyzed for but not detected. 1 p A matrix spike/matrix spike duplicate was not performed for this batch due to insufficient sample volume. J(M1) Estimated Value. Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. MS Analyte recovery in the matrix spike was outside QC limits for one or more of the constituent analytes used in the calculated result. Y The laboratory analysis was from an improperly preserved sample. c2 Acid preservation may not be appropriate for the analysis of 2-Chloroethylvinyl ether. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. Date: 03/12/2019 09:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 39 aceAnalytical® www pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project. 2018-3057/Melreese Golf Course Pace Project No.: 35451863 Lab ID Sample ID QC Batch Method Analytical QC Batch Analytical Method Batch 35451863001 MW-31 EPA 3510 520947 EPA 8081 521160 35451863001 MW-31 EPA 3510 521011 FL -PRO 521222 35451863001 MW-31 EPA 3010 521178 EPA 6010 521271 35451863001 MW-31 EPA 7470 521100 EPA 7470 521259 35451863001 MW-31 EPA 3510 521006 EPA 8270 by SIM 521083 35451863001 MW-31 EPA 8260 520786 Date: 03/12/2019 09:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 24 of 39 , . .. nalytical Section A CHAIN-OF-1 rOD`W0# : 35451863 The Chain -of -Custody is a LEG/ -eq.... ., avoic: II I 1 1111 111111 "II III 'age Required Client Information: Requuired Project Information: Invoice Inform Company EERG Environmental Services, LLC Report To ZUMjizsartkA.(1,qt : 1 Of 35451863 Address 5751 Miami Lakes Dr. Copy To Cel.r,c. C et,14'- -13e �_ Attention Company Name Hialeah. FL 33014 Email ` Address: Regulatory Agency '.v", M�iQ-r+�y @�fLtnd4• ee*•� Purchase Order # Pace Quote Phone (305)374-8300 1ltaz eJ Project l0 Requested Due Date. V{,. - . -�-s� Name' G L1F22:i� D Y i.,.:+tif ye.' Pace Project Manager. Christina.raschke@pacelabs.com, /'� State / Location • ti.ti,,; Project #: 2018-305/ Pace Profile # J FL Requ t Aral Fil ered (Y/N) MATRIX coo MATRIX CODE (see valid codes to left) 'SAMPLE TYPE (G=GRAB C=COMP) COLLECTED [SAMPLE TEMP AT COLLECTION T OF CONTAINERS 1 Preservatives Z >- q__- — <) `) D,Inkinp Writer DW Wnlei W1 ProdteWntrr WW Product PI SAMPLE ID SodlSJifd SL Ott oL START END ' Unpreserved Methanol Other Analyses Test 8260 VOC PAH by 8270 SIM TRPH FL -PRO Pesticides 8081( ,*„a Pesticides 814'�a�,,0 J ),i /....Ul o ..;a-0 N V 0 o 2/ l L. `� N m 'x 0 O 6010 }q, Cd, Cr, Se, Ag, 7470 Hg .35o - 1.-� Residual Chlorine (Y/N) I ill ~ One Character per box. Winn wP (A-Z, 0.9 / . -) Alr AR Sample Ids must be unique �ss n thcr or TS DATE TIME v o co x o 'Uc x Z 0It ro y Z DATE TIME x 1N Il t ��� )14\ 1� l 1 I '/ /� x . �C / j/' 1� �/' ✓. 2 !! 3 4 5 6 7 8 9 10 11 12 ADDITIONAL COMMENTS RELINQUISHED BY I AFFILIATION DATE • TIME �.- bCEPTEO BY I AFFILIATION DATE-. TIME. SAMPLE CONDITIONS � ��`� U T 1';rl �c= 1, l, q ;�, `. (-� - ``f�'-�` 31 )q �-i V 3. L y t� `1 / / C -\V...„___, .15}1c) 19q5 (:,, 0 \\',, J ). 1 SAMPLER NAME AND SIGNATURE . ITEMP in C Received on Ica (YIN) Custody Sealed Cooler (Y/N) Samples Intact (YIN) to CD PRINT Name of SAMPLER: ` t N cn 0 SIGNATURE of SAMPLER: i ( / ' y� "1 DATE Signed: h / 1 f rr Document Name Sample Condition Upon Receipt Form Document No F-FL-C-007 rev 13 Document Revised May 30, 2018 Issuing Authority Pace Florida Quality Office WO#:35451863 19 Project 4pm, CTR Due Date: 03/12/ Project Manager:CLIENT: 36-EEG Client: Thermometer Used. (� � State of rigi P (52` " . 3)5) Time is Date and Initials of p Examining content: Label: Deliver pH: r� [I For WV projects,�all containers verified to 56 `C Cooler #1 Temp.°C (Visual) V (Correction Factor) 3. V (Actual) Cooler#2 Temp.°C (Visual) 0 0 (Correction Factor) (0. 0 (Actual) Cooler #3 Temp.'C 5,5 (Visual) 0 _0 (Correction Factor) 5 .5"'i (Actual) Cooler#4 Temp.°C (Visual) (Correction Factor) (Actual) Cooler #5 Temp.°C (Visual) Cooler #6 Temp.°C (Visual) (Correction Factor) (Correction Factor) (Actual) (Actual) Courier: C Fed Ex —, UPS USPS E Client Commerciay= Pace Shipping Method: ET First Overnight — Priority Overnight Standard Overnight Other Billing: Tracking # = Recipient Sender Third Party - Credit Card Ground Samples on ice, cooling process has begun Samples on ice, cooling process has begun /Samples on ice, cooling process has begun • Samples on ice, cooling process has begun • Samples on ice, cooling process has begun • Samples on ice, cdcling process has begun Other International Priority Unknown Custody Seal on CoolerlBox Present: ❑Yes Packing Material: ❑Bubble Wrap Samples shorted to lab (If Yes, complete) Seals intact: f Yes ubble Bags UNone Li Other Shorted Date. Comments: lc lue Dry None Shorted Time Chain of Custody Present es _ No ON/A Chain of Custody Filled Out s _ No ON/A Relinquished Signature & Sampler Name COC _ eEs No ON/A v Samples Arrived within Hold Time Yesms iE No DN/A Rush TAT requested on COC L Yes _ o ON/A Sufficient Volume d)2 es _ No DN/A Correct Containers Used 'es - No ON/A Containers Intact es - No ON/A Sample Labels match COC (sample IDs & date/time of / collection) �ZS'es -' No EN/A All containers needing acid/base preservation have been /// checked.es = NoN/A All nneeding preservation are found to be in / compliance with EPA recommendation r�i�y'Cles E No EN/A Exceptions: VOA, Cotiform, TOC, O&G, Ca amazes Preservation Information Preservative rrr111 ot #/Trace # (� Date t � i Initials Headspace in VOA Vials? (>6mm)• iEYes - No,/A Trip Blank Present: E,Yes - No ON/A Client Notification/ Resolution: Person Contacted Comments/ Resolution (use back for additional comments): Date/Time. Project Manager Review: Date: Page 26 of 39 Pa ce Analytical National Center for Testing & Innovation A\ALYT CAL RI -PORT March 12, 2019 Pace Analytical - Pompano Beach, FL Sample Delivery Group. L1076224 Samples Received: 03/07/2019 Project Number: 35451863 Description: 2018-3057Melreese golf course Site: 001 Report To: Christina Raschke 3610 Park Central Blvd N Pompano Beach, FL 33064 Entire Report Reviewed By: Jason Romer Project Manager Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable. sampling conducted by Pace National is performed per guidance provided in laboratory standard operating procedures: 060302, 060303, and 060304. www.pacenational.com TABLE OF CONTENTS ONE LAB. NATIONWIDE. AO Cp: Cover Page 1 Tc: Table of Contents 2 Ss: Sample Summary 3 Cn: Case Narrative 4 Sr: Sample Results 5 MW-31 L1076224-01 5 Qc: Quality Control Summary 6 Chlorinated Acid Herbicides (GC) by Method 8151 6 OP Pesticides by Method 8141 7 GI: Glossary of Terms 10 AI: Accreditations & Locations 11 Sc: Sample Chain of Custody 12 ACCOUNT: Pace Analytical - Pompano Beach. FL I cd J Ss 4 Cn Qc GI -Al Page 28 of 39 PROJECT: SDG: DATE/TIME: PAGE: 35451863 L1076224 03/12/1913:13 2 of 13 SAMPLE SUMMARY ONE LAB. NATIONWIDE. 10 MW-31 L1076224-01 GW Collected by Collected dateitinie Received date/time 03104/1915:16 03/07/19 09:00 Chlorinated Acid Herbicides (GC) by Method 8151 OP Pesticides by Method 8141 ACCOUNT: Pace Analytical - Pompano Beach, FL Batch Dilution Preparation Analysis Analyst Location date/time date/time WG1247068 1 03/08/19 08:07 03/09/19 02:02 KLM Mt. Juliet, TN WG1246727 1 03/07/19 18:03 03/11/1916:59 HMH Mt. Juliet, TN Cp 2Tc 4 Cn 5 Sr 6 Qc GI Al Sc Page 29 of 39 PROJECT: SDG: DATE/TIME: PAGE: 35451863 L1076224 03/12/1913:13 3 of 13 CASE NARRATIVE ONE LAB. NATIONWIDE. All sample aliquots were received at the correct temperature, in the proper containers, with the appropriate preservatives, and within method specified holding times, unless qualified or notated within the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data. Jason Romer Project Manager ACCOUNT: Pace Analytical - Pompano Beach, FL Ss s Sr 6 QC GI Al Sc Page 30 of 39 PROJECT: SDG: DATE/TIME: PAGE: 35451863 L1076224 03/12/1913:13 4 of 13 MW-31 SAMPLE RESULTS - 01 Collected date/time: 03/04/19 15:16 L1076224 ONE LAB. NATIONWIDE. 10 Chlorinated Acid Herbicides (GC) by Method 8151 Result Qualifier MDL RDL Dilution Analysis Batch to ug/I ug/I ug/I date/time 0.744 U 0.744 2.00 1 03/09/2019 02:02 WG1247068 Dalapon 1.04 U 1.04 2.00 1 03/09/2019 02:02 WG1247068 2,4-DB 0.775 U 0.775 4.00 1 03/09/2019 02:02 WG1247068 Dicamba 0.813 U 0.813 2.00 1 03/09/2019 02:02 WG1247068 Dichloroprop 0.778 U 0.778 2.00 1 03/09/2019 02:02 WG1247068 Dinoseb 0.795 U 0.795 2.00 1 03/09/2019 02:02 WG1247068 MCPA 13.1 J U 13.1 200 1 03/09/2019 02:02 WG1247068 MCPP 7.15 U 7.15 200 1 03/09/2019 02:02 WG1247068 2,4,5-T 0.843 U 0.843 2.00 1 03/09/2019 02:02 WG1247068 2,4,5-TP (Silvex) 0.845 U 0.845 2.00 1 03/09/2019 02:02 WG1247068 /2,4-Dichlorophenyl Acetic 63.0 14.0-158 03/09/2019 02:02 WG1247068 Acid OP Pesticides by Method 8141 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Azinphos-Methyl 0.348 U 0.348 1.00 1 03/11/201916:59 WG1246727 Bolstar (Sulprofos) 0.205 U 0.205 1.00 1 03/11/201916:59 WG1246727 Chlorpyrifos 0.245 U 0.245 1.00 1 03/11/201916:59 WG1246727 Coumaphos 0.277 U 0.277 1.00 1 03/11/201916:59 WG1246727 Demeton,-0 and -S 0.341 J U 0.341 2.00 1 03/11/201916:59 WG1246727 Diazinon 0.377 U 0.377 1.00 1 03/11/201916:59 WG1246727 Dichlorvos 0.212 U 0.212 2.00 1 03/11/201916:59 WG1246727 Dimethoate 0.105 U 0.105 1.00 1 03/11/201916:59 WG1246727 Disulfoton 0.277 U 0.277 1.00 1 03/11/2019 16:59 WG1246727 --" 0.261 J U 0.261 1.00 1 03/11/201916:59 WG1246727 yop 0.354 U 0.354 1.00 1 03/11/201916:59 WG1246727 Ethyl Parathion 0.292 J U 0.292 1.00 1 03/11/201916:59 WG1246727 Fensulfothion 0.130 U 0.130 1.00 1 03/11/201916:59 WG1246727 Fenthion 0.266 U 0.266 1.00 1 03/11/201916:59 WG1246727 Malathion 0.173 U 0.173 1.00 1 03/11/201916:59 WG1246727 Merphos 0.267 U 0.267 2.00 1 03/11/201916:59 WG1246727 Methyl parathion 0.257 J U 0.257 1.00 1 03/11/2019 16:59 WG1246727 Mevinphos 0.118 U 0.118 1.00 1 03/11/201916:59 WG1246727 Naled 0.289 J U 0.289 1.00 1 03/11/201916:59 WG1246727 Phorate 0.282 U 0.282 1.00 1 03/11/201916:59 WG1246727 Ronnel 0.252 U 0.252 1.00 1 03/11/201916:59 WG1246727 Stirophos 0.226 U 0.226 1.00 1 03/11/201916:59 WG1246727 Sulfotep 0.202 U 0.202 1.00 1 03/11/201916:59 WG1246727 TEPP 9.74 J U 9.74 20.0 1 03/11/201916:59 WG1246727 Tokuthion (Prothothiofos) 0.254 U 0.254 1.00 1 03/11/201916:59 WG1246727 Trichloronate 0.213 U 0.213 1.00 1 03/11/201916:59 WG1246727 (S) Triphenyl Phosphate 61.0 42.0-129 03/11/201916:59 WG1246727 ACCOUNT: Pace Analytical - Pompano Beach, FL Cp Tc Ss Cn s Sr QC GI Al Page 31 of 39 PROJECT: SDG: DATE/TIME: PAGE: 35451863 L1076224 03/12/1913:13 5 of 13 WG1247068 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. 10 Chlorinated Acid Herbicides (GC) by Method 8151 L1076224-01 Method Blank (MB) (MB) R3390374-1 03/09/19 01:08 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I 2,4-D 0.744 U 0.744 2.00 Dalapon 1.04 U 1.04 2.00 2,4-DB 0.775 U 0.775 4.00 Dicamba 0.813 U 0.813 2.00 Dichloroprop 0.778 U 0.778 2.00 Dinoseb 0.795 U 0.795 2.00 MCPA 13.1 U 13.1 200 MCPP 7.15 U 7.15 200 2,4,5-T 0.843 U 0.843 2.00 2,4,5-TP (Silvex) 0.845 U 0.845 2.00 (S)2,4-Dichlorophenyl Acetic 66.2 14.0-158 Acid Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3390374-2 03/09/19 01:22 • (LCSD) R3390374-3 03/09/19 01:35 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I % % % % % 2,4-0 5.00 3.28 3.31 65.6 66.2 50.0-120 0.910 20 Dalapon 5.00 2.64 2.67 52.8 53.4 32.0-120 1.13 20 2,4-DB 5.00 3.73 4.10 74.6 82.0 53.0-140 I, 9.45 20 Dicamba 5.00 3.49 3.50 69.8 70.0 51.0-120 0.286 20 Dichloroprop 5.00 3.26 3.30 65.2 66.0 55.0-127 1.22 20 Dinoseb 5.00 2.21 2.18 44.2 43.6 36.0-134 1.37 20 MCPA 50.0 232 193 464 386 10.0-160 J L P J L 18.4 40 MCPP 50.0 19.9 20.5 39.8 41.0 10.0-160 2.97 23 2,4,5-T 5.00 3.72 3.69 74.4 73.8 54.0-120 0.810 20 2,4,5-TP (Silvex) 5.00 3.69 3.68 73.8 73.6 50.0-125 0.271 20 (S) 2,4-Dichlorophenyl Acetic Acid 62.8 60.8 14.0-158 ACCOUNT: ruse Analytical - Pompano Beach, FL Cp 2Tc 3 SS 4 Cn 6 QC 'GI Al ' ge32of39 PROJECT: SDG: DATE/TIME: ,AGE: 35451863 L1076224 03/12/1913:13 6 of 13 WG12 727 QUALITY CO' ROL SUMMARY ONE LAB. "ONWIDE. OP Pestici.. , by Method 8141 1.1, .24-01 Method Blank (MB) (MB) R3390660-1 03/11/1911:42 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I Azinphos-Methyl 0.348 U 0.348 1.00 Bolstar (Sulprofos) 0.205 U 0.205 1.00 Chlorpyrifos 0.245 U 0.245 1.00 Coumaphos 0.277 U 0.277 1.00 Demeton,-0 and -S 0.341 U 0.341 2.00 Diazinon 0.377 U 0.377 1.00 Dichlorvos 0.212 U 0.212 2.00 Dimethoate 0.105 U 0.105 1.00 Disulfoton 0.277 U 0.277 1.00 EPN 0.261 U 0.261 1.00 Ethoprop 0.354 U 0.354 1.00 Ethyl Parathion 0.292 U 0.292 1.00 Fensulfothion 0.130 U 0.130 1.00 Fenthion 0.266 U 0.266 1.00 Malathion 0.173 U 0.173 1.00 Merphos 0.267 U 0.267 2.00 Methyl parathion 0.257 U 0.257 1.00 Mevinphos 0.118 U 0.118 1.00 Naled 0.289 U 0.289 1.00 Phorate 0.282 U 0.282 1.00 Ronnel 0.252 U 0.252 1.00 Stirophos 0.226 U 0.226 1.00 Sulfotep 0.202 lJ 0.202 1.00 TEPP 9.74 U 9.74 20.0 Tokuthion (Prothothiofos) 0.254 U 0.254 1.00 Trichloronate 0.213 U 0.213 1.00 (S) Tripheny/ Phosphate 56.4 42.0-129 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3390660-2 03/11/19 12:45 • (LCSD) 93390660-3 03/11/19 13:17 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I % % % % % Azinphos-Methyl 5.00 3.70 4.38 74.0 87.6 43.0-142 16.8 20 Bolstar (Sulprofos) 5.00 3.58 4.03 71.6 80.6 47.0-128 11.8 20 Chlorpyrifos 5.00 3.62 4.26 72.4 85.2 50.0-126 16.2 20 Coumaphos 5.00 3.85 4.40 77.0 88.0 37.0-137 P P 13.3 20 Demeton,-0 and -S 2.50 ND ND 0.000 0.000 22.0-150 J J 0.000 24 Diazinon 5.00 4.14 4.41 82.8 88.2 54.0-130 6.32 20 ACCOUNT: Pace Analytical - Pompano Beach, FL Cp Tc 3 SS 4 Cn Sr 6 Qc 7GI nAl Page 33 of 39 PROJECT: SDG: DATE/TIME: PAGE: 35451863 L1076224 03/12/1913:13 7 of 13 WG1246727 QUALITY CONTROL SUMMARY OP Pesticides by Method 8141 L1076224-01 ONE LAB. NATIONWIDE. ilk Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3390660-2 03/11/19 12:45 • (LCSD) R3390660-3 03/11/19 13:17 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I % % % % % Dichlorvos 5.00 3.88 4.38 77.6 87.6 43.0-135 12.1 24 Dimethoate 5.00 2.17 2.80 43.4 56.0 27.0-120 25.4 27 Disulfoton 5.00 3.59 4.10 71.8 82.0 44.0-136 13.3 21 EPN 5.00 8.45 9.01 169 180 31.0-143 J J 6.41 21 Ethoprop 5.00 3.76 4.05 75.2 81.0 52.0-130 7.43 20 Ethyl Parathion 5.00 7.36 8.02 147 160 42.0-134 J J 8.58 20 Fensulfothion 5.00 3.79 4.36 75.8 87.2 42.0-137 14.0 20 Fenthion 5.00 3.44 4.03 68.8 80.6 53.0-133 P 15.8 20 Malathion 5.00 3.29 3.56 65.8 71.2 47.0-121 7.88 20 Merphos 5.00 3.48 4.14 69.6 82.8 14.0-123 17.3 25 Methyl parathion 5.00 4.92 6.10 98.4 122 43.0-135 J 21.4 20 Mevinphos 5.00 3.57 4.33 71.4 86.6 49.0-123 19.2 23 Naled 5.00 5.47 7.24 109 145 25.0-126 J 27.9 26 Phorate 5.00 3.60 3.74 72.0 74.8 44.0-129 3.81 20 Ronnel 5.00 3.42 3.93 68.4 78.6 51.0-125 13.9 20 Stirophos 5.00 3.77 4.61 75.4 92.2 53.0-125 20.0 20 Sulfotep 5.00 3.87 4.40 77.4 88.0 40.0-140 12.8 22 TEPP 50.0 17.6 34.2 35.2 68.4 18.0-122 J 64.1 32 Tokuthion (Prothothiofos) 5.00 3.59 4.14 71.8 82.8 50.0-128 14.2 20 Trichloronate 5.00 3.74 4.26 74.8 85.2 47.0-130 13.0 21 (S) Triphenyl Phosphate 68.0 74.6 42.0-129 L1075936-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1075936-01 03/11/19 14:52 • (MS) R3390660-4 03/11/19 15:24 • (MSD) R3390660-5 03/11/19 15:55 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I ug/I % % % % % Azinphos-Methyl 5.00 0.348 3.50 3.62 70.0 72.4 1 29.0-157 3.37 20 Bolstar (Sulprofos) 5.00 0.205 3.33 3.39 66.6 67.8 1 37.0-138 1.79 20 Chlorpyrifos 5.00 0.245 3.63 3.62 72.6 72.4 1 42.0-131 0.276 20 Coumaphos 5.00 0.277 3.74 3.57 74.8 71.4 1 31.0-150 P P 4.65 20 Demeton,-0 and -S 2.50 0.341 0.341 0.341 0.000 0.000 1 30.0-152 J U J U 0.000 20 Diazinon 5.00 0.377 4.06 4.04 81.2 80.8 1 47.0-134 0.494 20 Dichlorvos 5.00 0.212 3.92 3.65 78.4 73.0 1 39.0-140 7.13 22 Dimethoate 5.00 0.105 2.54 2.39 50.8 47.8 1 17.0-129 6.09 20 Disulfoton 5.00 0.277 3.45 3.42 69.0 68.4 1 42.0-131 0.873 21 EPN 5.00 0.261 8.45 8.23 169 165 1 17.0-155 J J P 2.64 20 Ethoprop 5.00 0.354 3.68 3.13 73.6 62.6 1 46.0-133 16.2 20 Ethyl Parathion 5.00 0.292 7.11 7.22 142 144 1 30.0-138 J P J P 1.54 20 ACCOUNT: race Analytical - Pompano Beach, FL Cp Tc 3Ss 4 Cn Sr 6 Qc 7GI Al `'age 34 of 39 PROJECT: SDG: DATE/TIME: ?AGE: 35451863 L1076224 03/12/1913:13 8 of 13 WG12 727 QUALITY COP ROL SUMMARY OP Pestici. by Method 8141 L1< z4-01 ONE LAB. N ` ` 0NWIDE. at L1075936-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1075936-01 03/11/19 14:52 • (MS) R3390660-4 03/11/19 15:24 • (MSD) R3390660-5 03/11/19 15:55 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I ug/I % % % % % Fensulfothion 5.00 0.130 3.68 3.94 73.6 78.8 1 36.0-145 6.82 20 Fenthion 5.00 0.266 3.44 3.43 68.8 68.6 1 46.0-140 P P 0.291 20 Malathion 5.00 0.173 3.69 3.19 73.8 63.8 1 39.0-126 14.5 20 Merphos 5.00 0.267 2.97 2.82 59.4 56.4 1 10.0-120 5.18 27 Methyl parathion 5.00 0.257 4.89 4.98 97.8 99.6 1 28.0-142 1.82 20 Mevinphos 5.00 0.118 3.61 3.39 72.2 67.8 1 38.0-134 6.29 20 Naled 5.00 0.289 5.51 5.11 110 102 1 14.0-130 7.53 20 Phorate 5.00 0.282 3.44 3.33 68.8 66.6 1 38.0-134 3.25 20 Ronnel 5.00 0.252 3.58 3.21 71.6 64.2 1 42.0-131 10.9 20 Stirophos 5.00 0.226 3.89 3.63 77.8 72.6 1 33.0-143 6.91 20 Sulfotep 5.00 0.202 3.98 3.72 79.6 74.4 1 34.0-143 6.75 20 TEPP 50.0 9.74 30.9 38.7 61.8 77.4 1 38.0-120 22.4 25 Tokuthion (Prothothiofos) 5.00 0.254 3.58 3.48 71.6 69.6 1 35.0-140 2.83 24 Trichloronate 5.00 0.213 3.89 3.58 77.8 71.6 1 41.0-133 8.30 20 (S) Tripheny/ Phosphate 67.4 66.0 42.0-129 ACCOUNT: Pace Analytical - Pompano Beach, FL 1Cp Tc 3 SS a Cn Sr 6 Qc GI Al Page 35 of 39 PROJECT: SDG: DATE/TIME: PAGE: 35451863 L1076224 03/12/19 13:13 9 of 13 GLOSSARY OF TERMS ONE LAB. NATIONWIDE. Mk Guide to Reading and Understanding Your Laboratory Report The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and if you have additional questions please contact your project representative. Abbreviations and Definitions MDL ND RDL Rec. RPD SDG (S) Analyte Dilution Limits Original Sample Qualifier Result Uncertainty (Radiochemistry) Case Narrative (Cn) Quality Control Summary (Qc) Sample Chain of Custody (Sc) Sample Results (Sr) Sample Summary (Ss) Qualifier Method Detection Limit. Not detected at the Reporting Limit (or MDL where applicable). Reported Detection Limit. Recovery. Relative Percent Difference. Sample Delivery Group. Surrogate (Surrogate Standard) - Analyses added to every blank, sample, Laboratory Control Sample/Duplicate and Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be detected in all environmental media. The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes reported. If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor. These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or duplicated within these ranges. The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control sample. The Original Sample may not be included within the reported SDG. This column provides a letter and/or number designation that corresponds to additional information concerning the result reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable. The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL" (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte. Confidence level of 2 sigma. A brief discussion about the included sample results, including a discussion of any non -conformances to protocol observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report. This section of the report includes the results of the laboratory quality control analyses required by procedure or analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material. This is the document created in the field when your samples were initially collected. This is used to verify the time and date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the samples from the time of collection until delivery to the laboratory for analysis. This section of your report will provide the results of all testing performed on your samples. These results are provided by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for each sample will provide the name and method number for the analysis reported. This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and times of preparation and/or analysis. Description J L P U The value is outside laboratory established criteria. Off -scale high. Actual value is known to be greater than value given. RPD between the primary and confirmatory analysis exceeded 40%. Indicates the compound was analyzed for but not detected above the method detection limit. ACCOUNT: PROJECT: SDG: Pace Analytical - Pompano Beach, FL 35451863 L1076224 DATE/TIME: 03/12/1913:13 4Cn 5 Sr 6 Qc GI 3Al Page 36 of 39 PAGE: 10 of 13 ACCREDITATIONS & LOCATIONS ONE LAB. NATIONWIDE. Pace National is the only environmental laboratory accredited/certified to support your work nationwide from one location. One phone call, one point of contact, one laboratory. No other lab is as accessible or prepared to handle your needs throughout the country. our capacity and capability from our single location laboratory is comparable to the collective totals of the network laboratories in our industry. The most significant benefit to our one location design is the design of our laboratory campus. The model is conducive to accelerated productivity, decreasing turn -around time, and preventing cross contamination, thus protecting sample integrity. our focus on premium quality and prompt service allows us to be YOUR LAB OF CHOICE. * Not all certifications held by the laboratory are applicable to the results reported in the attached report. Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace National. State Accreditations Alabama 40660 Nebraska NE-0S-15-05 Alaska 17-026 Nevada TN-03-2002-34 Arizona AZ0612 New Hampshire 2975 Arkansas 88-0469 New Jersey—NELAP TN002 California 2932 New Mexico' n/a Colorado TN00003 New York 11742 Connecticut PH-0197 North Carolina Env375 Florida E87487 North Carolina' DW21704 Georgia NELAP North Carolina' 41 Georgia' 923 North Dakota R-140 Idaho TN00003 Ohio—VAP CL0069 Illinois 200008 Oklahoma 9915 Indiana C-TN-01 Oregon TN200002 Iowa 364 Pennsylvania 68-02979 Kansas E-10277 Rhode Island LA000356 Kentucky 15 90010 South Carolina 84004 Kentucky 2 16 South Dakota n/a Louisiana A130792 Tennessee 2006 Louisiana' LA180010 Texas T104704245-18-15 Maine TN0002 Texas LAB0152 Maryland 324 Utah TN00003 Massachusetts M-TN003 Vermont VT2006 Michigan 9958 Virginia 460132 Minnesota 047-999-395 Washington C847 Mississippi TN00003 West Virginia 233 Missouri 340 Wisconsin 9980939910 Montana CERT0086 Wyoming A2LA Third Party Federal Accreditations A2LA — ISO 17025 1461.01 A2LA — ISO 17025 5 1461.02 Canada 1461.01 EPA—Crypto TN00003 AIHA-LAP,LLC EMLAP 100789 DOD 1461.01 USDA P330-15-00234 Drinking Water 2 Underground Storage Tanks ' Aquatic Toxicity < Chemical/Microbiological 5 Mold ` Wastewater n/a Accreditation not applicable Our Locations Pace National has sixty-four client support centers that provide sample pickup and/or the delivery of sampling supplies. If you would like assistance from one of our support offices, please contact our main office. Pace National performs all testing at our central laboratory. ACCOUNT: Pace Analytical - Pompano Beach, FL PROJECT: 35451863 SDG: L1076224 DATE/TIME: 03/12/19 13:13 Page 37 of 39 PAGE: 11 of 13 Cp Tc 4 Cn 5 Sr 6 Qc GI CAI Sc Chain of Custody Workorder: 35451863 Workorder Name: Christina Raschke Pace Analytical South Florida 3610 Park Central Blvd N Pompano Beach, FL 33064 Phone (954)582-4300 Email christina.raschke@pacelabs.com State of Sample Origin: Item 1 Sample ID M W-31 2 3 4 5 FL Collect Datull'iitio ,. 3/4/2019 15:16 2018-3057Melreese Golf Course Results Requested By: 3/12/2019 Lab11) 35451863001 Matrix W�trr P.O. 5-1�'t�U 131I aceAnalytical e www pace/abs. com Lrc--� �Zzy LAB USE ONLY 1 Transfers Released By 1 2 Date/Time Rec ed By ? k �% /i � J' Z 3 Cooler Temperature on Receipt °C Custody Seal (. 3 4-0 • : I- if A3 Date/Time 121 or N 1 Received on Ice Y or N PAD SCREEN: <C.5 11.1 5rA BAG). ,,toT3 Samples Intact Y or Wednesday. March 06, 2019 1 57 16 PM FMT-ALL-C-002rev.00 24March2009 a,ir 1 of 38 of 39 Pace Analytical National Center Cooler Receipt Client: 1),A6 Z P61�. for Testing & Innovation Form SI)G4: ie (pZL4-1 Cooler Received/Opened On: 3 / /19 Temperature: \ ,t'\ Received By: Jeremy \Vehh Signature: (_____ V !� , Receipt Check List NP Yes No COC Seal Present / Intact? - COC Signed / Accurate? _,--- Bottles arrive intact? --__----- bottles used? ,, ,Correct Sufficient volume sent? If Applicable VOA Zero headspace? Preservation Correct / Checked? Page 39 of 39 aceAnalytical® www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 March 28, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451838 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 05, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry, EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 18 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451838 Lab ID Sample ID Matrix Date Collected Date Received 35451838001 MW-31 Water 03/04/19 15:16 03/05/19 17:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 18 Pace.AnahliCa! CHAIN -OF -(WO : 35451838 „", „rra�rr-�J-,-,,,,, 11111111111111111111111 .ea accurafery. Section A Section 8 Required Client Information: Required Project Information: 35451838 Page : 1 Of Company EE&G Environmental Services. I.LC Report To jv1.x 1„.„P r.( 4V .«,.J, `/ , Adcress 5751 Miami Lakes Dr. Copy To (_',f -,,` \ c. ,,, ^ : ., �\ Company Name I liaieah. I-L 33014 �r,, J Address Regulatory Agency Email v__n �i (y,..l, , <� ..,.-, Purchase Order # Pace Quote Phone (305)374-8300 lliax J Project Name I'Iri2.\; gl w p1t; %- 4,r5 Pace Project Manager chrtsllna raschke@lpacelabs com, State l Location • �y' Requested Due Date C*.S.,.., �,<<" - ,. 7 Project #: 2018-30/ Pace Profile 8 ' - FL Requ�c3 Aida( 's Filtered (Y/N) NW kix cone MATRIX CODE (see va',d codes to left) SAMPLE TYPE (G=GR.4e C=COMP) COLLECTED SAMPLE TEt.(P AT COLLECT!ON It OF CONTAINERS J Preservatives 5- ? ',; Ur inking W.+I,•r OW W.rlr., W I W., •..I.• W.rt,.r WW PInduct SAMPLE ID °°s°°°St Oil oL START END Unpreserved H2304 HNO3 NaOH Na2S203 Other Analyses Test 8260 VOC PAH by 8270 Sltvi TRPH FL -PRO Pesticides 8081` ..,�,-,J Pesticides 8141{ Herbicides 8151(6). l: �i o e_ x O_ 6010 Ba, Cd, Cr. Se. Ag, 7470 Hg,cg,) -4ynmar`:q 3 SC l .� n "� .! 2 Z r c- o m a # W H One Character per box. WIt We Sample Ids must be unique P 9 r�•:.n, rs DATE TIME DATE TIME "6 _ c c - 2 3 4 5 6 7 8 9 10 11 12 ADDITIONAL COMMENTS RELINQUISHED BY I AFFILIATION DATE TIME ACCEPTED BY I AFFILIATION DATE TIME SAMPLE COMMONS /L 1-,,., K7 Jly//7 iL.D. ( '7C /,%:f i ' "jI4/ �I ? c -4, 3eb \i �� 7r,� /I(- - - - wit,` 8., pi-N. L- 315110► `F-34 -(0 0 N SAMPLER NAME AND SIGNATURE TEMP in C Recelved on Ice (Y/N) Cuslody Seated Cooler (YIN) Samples Intact (YIN) PRINT Name of SAMPLER: 1 J ' i SIGNATURE of SAMPLER: ' / :. ,---.1. ( DATE Signed: co 0) 0 Pace Analytical ._ _ eceiot Form Doccnent Revised May 30 2018 Project # Project Manager: Client: Thermometer Useo State of Cooler #1 Temp.'C WP!15451838 PM: CTR CLIENT: 36-EEG issuing Authority Pace Florida Quality Office Due Date: 03/15/19 , 3 ) Time • Date and Initials of p Examining content: Label: Deliver, pH:_ Il For 7,.',/ crclects, a.. cx:are•s ;er 5eo tc s5 `C _(Visual) (Correction Factor) 3. V (Actual) Cooler#2 Temp.°C ((Visual) 0 0 (Correction Factor) 0 (Actual) Cooler #3 Temp.'C 5s 3 (Visual) (Correction Factor) 5. 5 (Actual) Cooler #4 Temp.°C (Visual) (Correction Factor) (Actual) P (on dsx Cooler #5 Temp.'C (Visual) (Correction Factor) Cooler #6 Temp.'C (Visual) (Correction Factor) Courier: Fed Ex — - UPS .) USPS — - Client L Commerciaj — Pace Shipping Method: - First Overnight _ Priority Overnight - Standard Overnight — Ground = International Priority j J Sarno es co ,ce cooling process has begun Samo:es on ice, cooling process nes becun /Sar:o:es cn ice c03! ng process nas becun L Samples cn ice cooling process has begun Samples or. ice ccoine process has becun F Ser"pies on ice. coolnc crocess .nas becun Other = Other Billing: = Recipient Tracking # Custody Seal on Cooler/Box Present: Packing Material: -'Bubble Wrap Samples shorted to lab (If Yes, complete) = Sender Third Party ubble Bags LNone Shorted Date (Actual) (Actual) = Credit Card Seals intact: _ Yes Other ' Comments: Unknown ue Dry None Shorted TimeQty: Chain of Custody Present...#7,frr E. No =N/A Chain of Custody Filled Out es _ No -N/A Relinquished Signature & Sampler Name COC s _ e�1 No =N/A Samples Arrived within Hold Time Yes = No :N/A Rush TAT requested on COC _YesN/A Sufficient Volume _Yes = No 1N/A Correct Containers Used /' C' = No 1 N/A Containers Intact _.yes = No =NA Sampie Labels match COC (sample IDs & date/time of collection s 11 No =NIA All containers needng acid/base preservation have teen ,., checked =Yes = No1Cr A All Containers needing preservation are found to be in comphance with EPA recommendatior =Yes = No /A Exceptions VGA. Conform, TOC, O&G. Carcamates Preservation Information Preservative Lot r •ace # Cate i-,t,e s Headspace in VOA Vials? (>6mm) _Yes = No .6/ Trip Blank Present: -Yes = No i7,A'" Client Notification/ Resolution: Person Contacted Comments/ Resolution (use back for additional comments): Date/Time Project Manager Review Date Page 4 of 18 /2e Analytical rnm www.pacelabs.com www.pacelabs.com Report Prepared for: Christina Raschke PASI Florida 3610 Park Central Blvd N Pompano Beach FL 33064 TL9 REPORT OF LABORATORY ANALYSIS FOR PCDD/PCDF Report Prepared Date: March 14, 2019 Report No 104661058290FCDFR Pace Analytical Services, LLC. 1700 Elm Street Minneapolis, MN 55414 Phone: 612.607.1700 Fax: 612.607.6444 Report Information: Pace Project #: 10466105 Sample Receipt Date: 03/07/2019 Client Project #: 35451838 Client Sub PO #: N/A State Cert #: E87605 Invoicing & Reporting Options: The report provided has been invoiced as a Level 2 PCDD/PCDF Report. If an upgrade of this report package is requested, an additional charge may be applied. Please review the attached invoice for accuracy and forward any questions to Kirsten Hogberg, your Pace Project Manager. This report has been reviewed by: 141e-b March 15, 2019 Kirsten Hogberg, Project Manager (612) 607-6407 (612) 607-6444 (fax) kirsten.hogberg@pacelabs.com Report of Laboratory Analysis Thisreportshouldnotbereproduced,exceptinfull, withoutthewrittenconsentofPaceAnalyticalServices,Inc. Theresultsrelateonlyt othesamplesincludedi nthisreport. Page 5 of 18 Page 1 of 14 ace Analytical Pace Analytical Services, LLC. 1700 Elm Street Minneapolis, MN 55414 Phone: 612.607.1700 Fax: 612.607.6444 DISCUSSION This report presents the results from the analysis performed on one sample submitted by a representative of Pace Analytical Services, LLC. The sample was analyzed for the presence or absence of polychlorodibenzo-p-dioxins (PCDDs) and polychlorodibenzofurans (PCDFs) using a modified version of USEPA Method 8290. The reporting limits were based on signal-to-noise measurements. Estimated Maximum Possible Concentration (EMPC) values were treated as positives in the toxic equivalence calculations. Per request, estimated detection limit (EDL) values were provided and flagged "U" where the target analytes were not detected. The recoveries of the isotopically -labeled PCDD/PCDF internal standards in the sample extract ranged from 41-74%. Except for two low values, which were flagged "R" on the results table, the labeled internal standard recoveries obtained for this project were within the 40-135% target range specified in Method 8290. Also, since the quantification of the native 2,3,7,8-substituted congeners was based on isotope dilution, the data were automatically corrected for recovery and accurate values were obtained. A laboratory method blank was prepared and analyzed with the sample batch as part of our routine quality control procedures. The results show that PCDDs and PCDFs were not detected. These results indicate that the sample preparation procedures did not significantly impact the results of the field sample determinations. Laboratory spike samples were also prepared with the sample batch using clean reference matrix that had been fortified with native standard materials. The results show that the spiked native compounds were recovered at 92-120% with relative percent differences of 0.0-10.3%. These results were within the target ranges for the method. Matrix spikes were not prepared with the sample batch. REPORT OF LABORATORYANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466105_8290FC_DFR Page 6 of 18 Page 2 of 14 Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel 612-607-1700 Fax 612-607-6444 Minnesota Laboratory Certifications Authority Certificate # Authority Certificate # A2LA 2926.01 Minnesota - Pet 1240 Alabama 40770 Mississippi MN00064 Alaska - DW MN00064 Missouri - DW 10100 Alaska - UST 17-009 Montana CERT0092 Arizona AZ0014 Nebraska NE-OS-18-06 Arkansas - DW MN00064 Nevada MN00064 Arkansas - WW 88-0680 New Hampshire 2081 CNMI Saipan MP0003 New Jersey (NE MN002 California 2929 New York 11647 Colorado MN00064 North Carolina 27700 Connecticut PH-0256 North Carolina - 27700 EPA Region 8+ via MN 027-053 North Carolina - 530 Florida (NELAP E87605 North Dakota R-036 Georgia 959 Ohio - DW 41244 Guam 17-001r Ohio - VAP CL101 Hawaii MN00064 Oklahoma 9507 Idaho MN00064 Oregon - Primar MN300001 Illinois 200011 Oregon - Secon MN200001 Indiana C-MN-01 Pennsylvania 68-00563 Iowa 368 Puerto Rico MN00064 Kansas E-10167 South Carolina 74003 Kentucky - DW 90062 South Dakota NA Kentucky - WW 90062 Tennessee TN02818 Louisiana - DE 03086 Texas T104704192 Louisiana - DW MN00064 Utah (NELAP) MN00064 Maine MN00064 Virginia 460163 Maryland 322 Washington C486 Massachusetts M-MN064 West Virginia - 382 Michigan 9909 West Virginia - 9952C Minnesota 027-053-137 Wisconsin 999407970 Minnesota - De via MN 027-053 Wyoming - UST 2926.01 REPORT OF LABORATORYANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466105_8290FC_DFR Page 7 of 18 Page 3 of 14 Appendix A Sample Management Report No 10466105_8290FC_Ie Analytical Services, Inc. Page 8 of 18 Page 4 of 14 21d0 ad06Z8 901-991706 oN pode lv m cn 0 Chain of Custody I Samples were sent directly to the Subcontracting Laboratory. Workorder: 35451838 Christina Raschke Pace Analytical South Florida 3610 Park Central Blvd N Pompano Beach, FL 33064 Phone (954)582-4300 2 3 4 Transfers 3 Workorder Name: 2018-3057Melreese Golf Course Released By Cooler Temperature on Receipt Pace Analytical Minnesota 1700 Elm Street SE Suite 200 Minneapolis, MN 55414 Phone (612)607-1700 3/4/2019 15:16 354 DatplTime Received By Custody Seal (Y )or State Of Origin: FL Cert. Needed: fl Yes No Owner Received Date: 3/5/2019 YlT..+!-'3?,/_7/fly ceAna(,icaim www.pacelabs,eo Results RPninra $cnd By 3/15/2019 WOC10466105 �IIII III III NOM III LAB USE ONLY Received on Ice Y )or N I Samples Intact Y lor **"ln order to maintain client confidentiality, location/name of the sampling site, sampler's name and signature may not be provided on this COC documen . This chain of custody is considered complete as is since this information is available in the owner laboratory. a, Tuesday, March 05, 2019 7:29:34 PM M � , FMT-ALL_ C-002rev.00 24March2009 Page 1 of 1 Thermometer: PaceAnalytrcal J Document Name: Sample Condition Upon Receipt Form Document No.: F-MN-L-213-rev.25 Document Revised: 06Feb2019 Page 1 of 1 Issuing Authority: Pace Minnesota Quality Office Sample Condition Upon Receipt Courier: Tracking Number: Client Name: Fed Ex CUPS ❑Pace ❑SpeeDee 5 f M 75'/ Custody Seal on Cooler/Box Present? Project #: orrr C . ❑LISPS ['Client ❑Commercial See Exception WO#:10466105 PM: KNH Due Date: 03/21/19 CLIENT: PASI-FL ❑No Seals Intact? I Yes ❑No Biological Tissue Frozen? ❑Yes :No N/A Packing Material: Bubble Wrap sZBubble Bags ['None ['Other: Temp Blank? ❑Yes "Wet 081ue ['None ❑Dry ['Melted ❑ G87A9155100842 ,87A9170600254 Type of Ice: Note: Each West Virginia Sample must have temp taken (no temp blanks) Temp should be above freezing to 6°C Cooler Temp Read w/temp blank: oC Correction Factor: 4 0 tI Cooler Temp Corrected w/temp blank : °C Average Corrected Temp See Excep (no temp bjnk only): °C USDA Regulated Soil: ( N/A, water sample/Other: ) Date/Initials of Person Examining Contents: 43 Did samples originate in a quarantine zone within the United States: AL, AR, CA, FL, GA, Did samples originate from a foreign source (internationally, is ID, LA. MS, NC, NM, NY, OK, OR, SC, TN, TX or VA (check maps)? [Des ❑No Hawaii and Puerto Rico)? ['Yes ❑No If Yes to either question, fill out a Regulated Soil Checklist (F-MN-Q-338) and include with SCUR/COC paperwork. n. d'%✓1 `� COMMENTS: Chain of Custody Present and Filled Out? As NO 1. Chain of Custody Relinquished? JQves ❑No 2. Sampler Name and/or Signature on COC? ccc❑Y s ❑No N/A 3. Samples Arrived within Hold Time? Yes ❑No 4. Short Hold Time Analysis (<72 hr)? Yes , o 5. ❑Fecal Coliform ❑HPC ❑Total Coliform/E cali ❑BOD/cBOD ❑Hex Chrome ❑Turbidity ❑Nitrate ❑Nitrite ❑Orthophos ❑Other Rush Turn Around Time Requested? ❑Yes No 6. Sufficient Volume? es Ohio 7. Correct Containers Used? -Pace Containers Used? es ,es ❑No ❑No 8. Containers Intact? 'es DNo 9. Field Filtered Volume Received for Dissolved Tests? ❑Yes ❑No/A 10. Is sediment visible in the dissolved container? •Yes ❑No Is sufficient information available to reconcile the samples to the COC? Matrix:rater ❑Soil ❑oil ❑Other es ❑No 11. If no, write ID/ Date/Time on Container Below: See Exception • All containers needing acid/base preservation have been checked? All containers needing preservation are found to be in compliance with EPA recommendation? (HNO3, H2SO4, <2pH, NaOH >9 Sulfide, NaOH>12 Cyanide) Exceptions: VOA, Coliform, TOC/DOC Oil and Grease, DR0/8015 (water) and Dioxin/PFAS ❑Yes ❑Yes ['Yes ❑No [iN/A ❑No 7/A ❑No ON/A 12. Sample # ❑ NaOH • HNO3 H2SO4❑EZinc Acetate Positive for Res. III Yes See Exception Chlorine? • No • Headspace in VOA Vials (greater than 6mm)? :Yes ❑No ©N/A 13. See Exception rip Blank Present? -rip Blank Custody Seals Present? ['Yes ❑Yes ❑No ❑No ©N/A ..N/A 14. Pace Trip Blank Lot 4 (if purchased): CLIENT NOTIFICATION/RESOLUTION Person Contacted: Comments/Resolution: Date/Time: Field Data Required? Dees ❑No Project Manager Review: £�/ Date: 3/8/2019 Note: Whenever there is a discrepancy of _cting or Carolina com� ante s: pies, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( i.e out of hold, incorrect preservative, out of temp, incorrect containers). Report No 10466105_8290FC_DFR Labeled by: r' , Page 10 of 18 Page 6 of 14 PaceAnalytical Document Name: SCUR Exception Form — Coolers Above 6°C Document Revised: 04feb2019 Page 1 of 1 Document No.: F-MN-C-298-Rev.01 issuing Authority: Pace Minnesota Quality Office SCUR Exceptions: During sample triage, this form is to be placed in each cooler that arrives above 6.0 degrees Celsius Workorder #: Container Out of Temp Sample IDs Type Other issues # of Containers Issue Type: Sample ID Container # of Type Containers PM Notified? ❑Yes ❑No If yes, indicate who was contacted/date/time. If no, indicate reason why. Multiple Cooler Project? Dyes ENo If you answered yes, fill out information to the left. No Temp Blank Read Temp Corrected Temp 0 t, Average Temp 12 / £ '1 Tracking Number pH Adjustment Log for Preserved Samples Sample ID Type of Preserv. pH Upon Receipt Date Adjusted Time i Adjusted Amount Added (mL) Lot # Added pH After In Compliance after addition? Initials Yes El No "Yes •No ❑Yes NI No Yes II No Report No 10466105_8290FC_DFR Page 11of18 Page 7 of 14 Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis. MN 55414 AnalyticalTM Reporting Flags A = Reporting Limit based on signal to noise B = Less than 10x higher than method blank level C = Result obtained from confirmation analysis D = Result obtained from analysis of diluted sample E = Exceeds calibration range I = Interferencepresent J = Estimated value L = Suppressive interference, analyte may be biased low Nn = Value obtained from additional analysis P = PCDEInterference R = Recovery outside target range S = Peak saturated U = Analyte not detected V = Result verified by confirmation analysis X = %D Exceeds limits Y = Calculated using average of daily RFs * = SeeDiscussion REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466105_8290FC_DFR Tel: 612-607-1700 Fax. 612-607-6444 Page 12 of 18 Page 8 of 14 Appendix B Sample Analysis Summary Report No 10466105_8290FC_e Analytical Services, Inc. Page 13 of 18 Page 9 of 14 TM Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Analytical Client's Sample ID Lab Sample ID Filename Injected By Total Amount Extracted % Moisture Dry Weight Extracted ICAL ID CCal Filename(s) Method Blank ID Native Isomers Metho d 8290 Sample Analysis Results Client - PASI Florida M W-31 35451838001 F1903136_14 SMT 1030 mL NA NA F190112 F190313A_18 & F1903136_17 BLANK-68966 Conc pg/L EMPC EDL pg/L pg/L Tel: 612-607-1700 Fax: 612- 607-6444 Matrix Water Dilution NA Collected 03/04/2019 15:16 Received 03/07/2019 09:00 Extracted 03/11/2019 12:00 Analyzed 03/14/2019 06:22 Internal Standards 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD 1.2 U 1.2 U 1.7 U 1.7 U 1.7 U 1.2 U 1.5 U 1.7 U 1.7 U 1.7 U 1.5 U 1.2 U 2.0 U 1.6 U 2.4 U 2.4 U 2.7 U 2.5 U 3.5 U 6.6 U 5.1 U 4.9 U 4.9 U 13 U 13 U 1.7 1.5 1.2 2.0 1.6 2.4 2.4 2.7 2.5 1.2 2,3,7,8-TCDF-13C 1.2 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 1.7 2,3,4,7,8-PeCDF-13C 1.7 1,2,3,7, 8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 1.7 1,2,3,6,7,8-HxCDF-13C 1.2 2,3,4,6,7,8-HxCDF-13C 1.5 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 1.7 1,2, 3,6,7, 8-HxCDD-13C 1.7 1,2,3,4,6,7,8-HpCDF-13C 1,2, 3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 ng's Percent Added Recovery 2.00 68 2.00 71 2.00 62 2.00 59 2.00 66 2.00 68 2.00 64 2.00 74 2.00 65 2.00 65 2.00 68 2.00 51 2.00 45 2.00 49 4.00 41 2.00 NA 2.00 NA 0.20 86 3.5 Total 2,3,7,8-TCDD 6.6 Equivalence: 0.00 pg/L 5.1 (Lower -bound - Using ITE Factors) 4.9 4.9 13 13 Conc = Concentration (Totals include 2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit ND = Not Detected NA = Not Applicable NC = Not Calculated REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466105_8290FC_DFR Page 14 of 18 Page 10 of 14 AnalyticalTM Lab Sample Name Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) Native Isomers 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD Method 8290 Blank Analysis Results DFBLKDC BLANK-68966 F190313B_06 945 mL F190112 F190313A 18 & F1903131317 Conc pg/L 2.1 U 2.1 U 2.3 U 2.3 U 2.0 U 1.6 U 1.8 U 1.8 U 1.8 U 2.1 U 1.9 U 1.8 U 2.1 U 2.0 U 2.1 U 2.2 U 1.8 U 2.0 U 3.0 U 6.0 U 4.5 U 4.4 U 4.4 U 9.1 U 7.3 U 2.1 1.9 1.8 2.1 2.0 2.1 2.2 1.8 2.0 EMPC EDL pg/L pg/L Matrix Dilution Extracted Analyzed Injected By Internal Standards Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis. MN 55414 Tel: 612-607-1700 Fax:612-607-6444 Water NA 03/11/2019 12:00 03/14/2019 00:29 SMT 2.1 2,3,7,8-TCDF-13C 2.1 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 2.3 2,3,4,7,8-PeCDF-13C 2.3 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 2.0 1,2,3,6,7,8-HxCDF-13C 1.6 2,3,4,6,7,8-HxCDF-13C 1.8 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 1.8 1,2,3,6,7,8-HxCDD-13C 1.8 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 ng's Percent Added Recovery 2.00 66 2.00 70 2.00 62 2.00 61 2.00 71 2.00 64 2.00 57 2.00 73 2.00 63 2.00 66 2.00 66 2.00 51 2.00 47 2.00 51 4.00 44 2.00 NA 2.00 NA 0.20 88 3.0 Total 2,3,7,8-TCDD 6.0 Equivalence: 0.00 pg/L 4.5 (Lower -bound - Using ITE Factors) 4.4 4.4 9.1 7.3 Conc. Concentration (Totals include 2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL= Estimated Detection Limit REPORT OF LABORATORYANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466105_8290FC DFR Page 15 of 18 Page 11 of 14 Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Analytical Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) Method Blank ID Native Isomers 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD TM Method Method 8290 Laboratory Control Spike Results Qs (ng) 0.20 LCS-68967 F190313B_01 923 mL F190112 F190313A_18 & F190313B_17 BLANK-68966 Qm (ng) 0.22 0.20 0.23 1.0 1.0 1.1 1.1 1.0 0.97 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.1 1.1 1.1 1.1 1.1 1.2 1.0 Rec. Matrix Dilution Extracted Analyzed Injected By Internal Standards 109 2,3,7,8-TCDF-13C 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 117 2,3,4,7,8-PeCDF-13C 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 105 1,2,3,6,7,8-HxCDF-13C 111 2,3,4,6,7,8-HxCDF-13C 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 97 1,2,3,6,7, 8-HxCDD-13C 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 113 108 105 105 111 120 103 1.0 1.1 107 1.0 1.0 102 1.0 1.0 100 2.0 2.2 108 2.0 2.2 109 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 Tel: 612-607-1700 Fax: 612-607-6444 Water NA 03/11/2019 12:00 03/13/2019 20:48 SMT ng's Percent Added Recovery 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 4.0 2.0 2.0 0.20 58 60 52 51 58 52 49 60 49 55 54 41 37 R 40 33 R NA NA 80 Qs = Quantity Spiked Qm = Quantity Measured Rec. = Recovery (Expressed as Percent) R = Recovery outside of target range Y = RF averaging used in calculations Nn = Value obtained from additional analysis NA = Not Applicable = See Discussion REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466105_8290FC_DFR Page 16 of 18 Page 12 of 14 Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Analytical Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) Method Blank ID Native Isomers 2,3,7,8-TCDF Total TCDF 2, 3, 7, 8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD TM Method 8290 Laboratory Control Spike Results LCSD-68968 F190313B_02 894 mL F190112 F190313A18 & F190313B17 BLANK-68966 Qs Qm (ng) (ng) Rec. 0.20 0.22 109 0.20 0.23 116 1.0 1.1 105 1.0 1.1 109 1.0 0.99 99 1.0 1.0 105 1.0 1.0 104 1.0 0.99 99 1.0 0.97 97 1.0 1.1 109 1.0 1.1 115 1.0 1.0 104 1.0 1.0 104 1.0 0.92 92 1.0 0.99 99 2.0 2.1 105 2.0 2.1 106 Matrix Dilution Extracted Analyzed Injected By Internal Standards 2,3,7,8-TCDF-13C 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 2,3,4,7,8-PeCDF-13C 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 1,2,3,6,7,8-HxCDF-13C 2,3,4,6,7,8-HxCDF-13C 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 1,2,3,6,7,8-HxCDD-13C 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 Tel: 612-607-1700 Fax. 612-607-6444 Water NA 03/11/2019 12:00 03/13/2019 21:33 SMT ng's Percent Added Recovery 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 4.0 2.0 2.0 0.20 70 74 61 59 66 66 63 73 63 66 65 51 47 51 42 NA NA 89 Qs = Quantity Spiked Qm = Quantity Measured Rec. = Recovery (Expressed as Percent) R = Recovery outside of target range Y = RF averaging used in calculations Nn = Value obtained from additional analysis NA = Not Applicable * = See Discussion REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466105_8290FCDFR Page 13 of 14 Page 17 of 18 TM Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Analytical Method 8290 Spike Recovery Relative Percent Difference (RPD) Results Client PASI Florida Spike 1 ID LCS-68967 Spike 2 ID LCSD-68968 Spike 1 Filename F190313B_01 Spike 2 Filename F190313B_02 Spike 1 Spike 2 Compound %REC %REC %RPD Tel: 612-607-1700 Fax: 612-607-6444 2,3,7,8-TCDF 109 109 0.0 2,3,7,8-TCDD 117 116 0.9 1,2,3,7,8-PeCDF 105 105 0.0 2,3,4,7,8-PeCDF 111 109 1.8 1,2,3,7,8-PeCDD 97 99 2.0 1,2,3,4,7,8-HxCDF 113 105 7.3 1,2,3,6,7,8-HxCDF 108 104 3.8 2,3,4,6,7,8-HxCDF 105 99 5.9 1,2,3,7,8,9-HxCDF 105 97 7.9 1,2,3,4,7,8-HxCDD 111 109 1.8 1,2,3,6,7,8-HxCDD 120 115 4.3 1,2,3,7,8,9-HxCDD 103 104 1.0 1,2,3,4,6,7,8-HpCDF 107 104 2.8 1,2,3,4,7,8,9-HpCDF 102 92 10.3 1,2,3,4,6,7,8-HpCDD 100 99 1.0 OCDF 108 105 2.8 OCDD 109 106 2.8 %REC = Percent Recovered RPD = The difference between the two values divided by the mean value REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466105_8290FC_DFR Page 14 of 14 Page 18 of 18 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 April 11, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457301 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 28, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Kelsey Cortina, EE&G Environmental Solutions, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 13 CERTIFICATIONS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457301 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alaska DEC- CS/UST/LUST Alabama Certification #: 41320 Arizona Certification# AZ0819 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 13 aceAnalytical wwwpacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457301 Lab ID Sample ID Matrix Date Collected Date Received 35457301001 MW-31 Water 03/27/19 12:51 03/28/19 17:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 13 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457301 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35457301001 MW-31 EPA 8081 TCB 22 PASI-O EPA6010 JWP 2 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 13 aceAnalytical wwwpacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457301 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35457301001 MW-31 EPA 6010 Arsenic 85.2 ug/L EPA6010 Iron 2430 ug/L REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 10.0 04/03/19 16:45 40.0 04/03/19 16:45 Page 5 of 13 ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No 35457301 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-31 Lab ID: 35457301001 Collected: 03/27/19 12:51 Received: 03/28/19 17:45 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8081 GCS Pesticides Analytical Method: EPA 8081 Preparation Method: EPA 3510 Aldrin 0.0014 U ug/L 0.0097 0.0014 1 04/03/19 17:20 04/09/19 15:44 309-00-2 1p alpha-BHC 0.0020 U ug/L 0.0097 0.0020 1 04/03/19 17:20 04/09/19 15:44 319-84-6 1p beta-BHC 0.0077 U ug/L 0.0097 0.0077 1 04/03/19 17:20 04/09/19 15:44 319-85-7 1p delta-BHC 0.0046 U ug/L 0.0097 0.0046 1 04/03/19 17:20 04/09/19 15:44 319-86-8 1p gamma-BHC (Lindane) 0.0021 U ug/L 0.0097 0.0021 1 04/03/19 17:20 04/09/19 15:44 58-89-9 1p Chlordane (Technical) 0.17 U ug/L 0.48 0.17 1 04/03/19 17:20 04/09/19 15:44 57-74-9 1p 4,4'-DDD 0.0086 U ug/L 0.0097 0.0086 1 04/03/19 17:20 04/09/19 15:44 72-54-8 1p,CU 4,4'-DDE 0.0048 U ug/L 0.0097 0.0048 1 04/03/19 17:20 04/09/19 15:44 72-55-9 1p 4,4'-DDT 0.0048 U ug/L 0.0097 0.0048 1 04/03/19 17:20 04/09/19 15:44 50-29-3 1p,CU Dieldrin 0.0019 U ug/L 0.0097 0.0019 1 04/03/19 17:20 04/09/19 15:44 60-57-1 1p Endosulfan I 0.0049 U ug/L 0.0097 0.0049 1 04/03/19 17:20 04/09/19 15:44 959-98-8 1p Endosulfan II 0.0039 U ug/L 0.0097 0.0039 1 04/03/19 17:20 04/09/19 15:44 33213-65-9 1p,CU Endosulfan sulfate 0.0060 U ug/L 0.097 0.0060 1 04/03/19 17:20 04/09/19 15:44 1031-07-8 ip,CU Endrin 0.0042 U ug/L 0.0097 0.0042 1 04/03/19 17:20 04/09/19 15:44 72-20-8 1p Endrin aldehyde 0.0035 U ug/L 0.097 0.0035 1 04/03/19 17:20 04/09/19 15:44 7421-93-4 1p,CU Endrin ketone 0.0048 U ug/L 0.0097 0.0048 1 04/03/19 17:20 04/09/19 15:44 53494-70-5 1p,CU Heptachlor 0.0060 U ug/L 0.0097 0.0060 1 04/03/19 17:20 04/09/19 15:44 76-44-8 1p Heptachlor epoxide 0.0050 U ug/L 0.0097 0.0050 1 04/03/19 17:20 04/09/19 15:44 1024-57-3 1p Methoxychlor 0.0093 U ug/L 0.0097 0.0093 1 04/03/19 17:20 04/09/19 15:44 72-43-5 1p,CU Toxaphene 0.24 U ug/L 0.48 0.24 1 04/03/19 17:20 04/09/19 15:44 8001-35-2 1p Surrogates Tetrachloro-m-xylene (S) 64 % 27-124 1 04/03/19 17:20 04/09/19 15:44 877-09-8 Decachlorobiphenyl (S) 55 % 10-132 1 04/03/19 17:20 04/09/19 15:44 2051-24-3 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3010 Arsenic 85.2 ug/L Iron 2430 ug/L Date: 04/11/2019 09:47 PM 10.0 7.1 1 04/03/19 07:51 04/03/19 16:45 7440-38-2 40.0 9.2 1 04/03/19 07:51 04/03/19 16:45 7439-89-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 13 www pacelabs. corn QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457301 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 528000 QC Batch Method: EPA 3010 Associated Lab Samples: 35457301001 Analysis Method: EPA 6010 Analysis Description: 6010 MET METHOD BLANK: 2857698 Matrix: Water Associated Lab Samples: 35457301001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic ug/L 7.1 U 10.0 Iron ug/L 9.2 U 40.0 7.1 04/03/19 15:56 9.2 04/03/1915:56 LABORATORY CONTROL SAMPLE: 2857699 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic ug/L 500 490 98 80-120 Iron ug/L 2000 2010 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2857700 2857701 MS MSD 35457297001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L 7.1 U 500 500 524 511 105 102 75-125 2 20 Iron ug/L 347 2000 2000 2320 2260 99 96 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/11/2019 09:47 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 13 ace Analytical www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457301 QC Batch: 528202 QC Batch Method: EPA 3510 Associated Lab Samples: 35457301001 Analysis Method: EPA 8081 Analysis Description: 8081 GCS Pesticides METHOD BLANK: 2858737 Matrix: Water Associated Lab Samples: 35457301001 Parameter Blank Reporting Units Result Limit MDL Analyzed Qualifiers 4,4'-DDD ug/L 0.0089 U 0.010 0.0089 04/09/19 11:33 CU 4,4'-DDE ug/L 0.0050 U 0.010 0.0050 04/09/19 11:33 4,4'-DDT ug/L 0.0050 U 0.010 0.0050 04/09/19 11:33 CU Aldrin ug/L 0.0015 U 0.010 0.0015 04/09/19 11:33 alpha-BHC ug/L 0.0021 U 0.010 0.0021 04/09/19 11:33 beta-BHC ug/L 0.0080 U 0.010 0.0080 04/09/19 11:33 Chlordane (Technical) ug/L 0.18 U 0.50 0.18 04/09/19 11:33 delta-BHC ug/L 0.0048 U 0.010 0.0048 04/09/19 11:33 Dieldrin ug/L 0.0020 U 0.010 0.0020 04/09/19 11:33 Endosulfan I ug/L 0.0051 U 0.010 0.0051 04/09/19 11:33 Endosulfan II ug/L 0.0040 U 0.010 0.0040 04/09/19 11:33 CU Endosulfan sulfate ug/L 0.0062 U 0.10 0.0062 04/09/19 11:33 CU Endrin ug/L 0.0043 U 0.010 0.0043 04/09/19 11:33 Endrin aldehyde ug/L 0.013 I 0.10 0.0036 04/09/19 11:33 CU Endrin ketone ug/L 0.0050 U 0.010 0.0050 04/09/19 11:33 CU gamma-BHC (Lindane) ug/L 0.0022 U 0.010 0.0022 04/09/19 11:33 Heptachlor ug/L 0.0062 U 0.010 0.0062 04/09/19 11:33 Heptachlor epoxide ug/L 0.0052 U 0.010 0.0052 04/09/19 11:33 Methoxychlor ug/L 0.0096 U 0.010 0.0096 04/09/19 11:33 CU Toxaphene ug/L 0.25 U 0.50 0.25 04/09/19 11:33 Decachlorobiphenyl (S) % 53 10-132 04/09/19 11:33 Tetrachloro-m-xylene (S) % 66 27-124 04/09/19 11:33 LABORATORY CONTROL SAMPLE & LCSD: 2858738 2858834 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers 4,4'-DDD ug/L 0.5 0.52 0.49 104 98 67-133 6 40 CH 4,4'-DDE ug/L 0.5 0.47 0.43 94 87 59-125 8 40 4,4'-DDT ug/L 0.5 0.57 0.52 113 104 54-132 8 40 CH Aldrin ug/L 0.5 0.31 0.30 63 60 25-116 5 40 alpha-BHC ug/L 0.5 0.50 0.46 100 92 53-126 9 40 beta-BHC ug/L 0.5 0.56 0.51 112 103 62-130 9 40 delta-BHC ug/L 0.5 0.25 0.23 50 47 35-122 6 40 Dieldrin ug/L 0.5 0.51 0.48 102 96 66-128 6 40 Endosulfan I ug/L 0.5 0.51 0.48 103 96 67-125 6 40 Endosulfan II ug/L 0.5 0.52 0.49 103 98 67-131 6 40 CH Endosulfan sulfate ug/L 0.5 0.54 0.51 108 102 62-127 6 40 CH Endrin ug/L 0.5 0.53 0.49 106 98 66-130 8 40 Endrin aldehyde ug/L 0.5 0.60 0.56 120 113 61-124 6 40 CH Endrin ketone ug/L 0.5 0.57 0.55 115 109 65-132 5 40 CH Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/11/2019 09:47 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 13 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457301 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE & LCSD: 2858738 2858834 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers gamma-BHC (Lindane) ug/L 0.5 0.53 0.48 106 96 58-127 10 40 Heptachlor ug/L 0.5 0.39 0.36 79 72 35-123 9 40 Heptachlor epoxide ug/L 0.5 0.51 0.47 102 95 62-125 7 40 Methoxychlor ug/L 0.5 0.56 0.52 111 105 59-135 6 40 CH Decachlorobiphenyl (S) % 48 56 10-132 Tetrachloro-m-xylene (S) % 77 70 27-124 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/11/2019 09:47 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 13 ace Analytical www.pacelabs.com QUALIFIERS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457301 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: 528202 [M5] A matrix spike/matrix spike duplicate was not performed for this batch due to insufficient sample volume. ANALYTE QUALIFIERS The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. U Compound was analyzed for but not detected. 1 p A matrix spike/matrix spike duplicate was not performed for this batch due to insufficient sample volume. CH The continuing calibration for this compound is outside of Pace Analytical acceptance limits. The results may be biased high. CU The continuing calibration for this analyte is above laboratory acceptance limits. Analyte was not detected above the reporting limit in any of the associated samples. Date: 04/11/2019 09:47 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 13 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach. FL 33064 954-582-4300 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457301 Lab ID Sample ID QC Batch Method Analytical QC Batch Analytical Method Batch 35457301001 MW-31 35457301001 MW-31 Date: 04/11/2019 09:47 PM EPA 3510 528202 EPA 8081 529083 EPA 3010 528000 EPA 6010 528101 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 13 )3P? e4ra'R/4i1 CH/ WW1 :35457301 The C Il w l I ■r.. . _. _ _ ocument De completed accurately. _... 004110110 IIat 11111 I IIf iif I IN IIIILI Required Client Information: Required Project Information: 35457301 Company EE&G Report To Craig Page 9 Of Address. 5751 Miami Lakes Drive, Miami Clevenger Copy To: Lakes, FL Company Name Address Regulatory Agency Emailccievrngergi,ecrn)(Ia con) Purchase Order# Pace Quote Phone (305) 374-8300 !Fax Project Name Melrese Golf Course Pace Project Manager' Stater Location Requested Due Date -T j\t''" Project #: 2018-3057 Pace Profile # FL MATRIX CODE fr a Ou COLLECTED = Preservatives Z >- Requested Analysis Filtered (YIN) Minkel Water DW Wafer WT Wa.k W WW1, W Product P SAMPLE ID sxxso11d St Oil OL ii a m Q d' (.2. START END O u j rn �, 152 '- _ ..-. Z >_ o W F One Character per box. WIPo WP Sample Ids must be unique O°"'� oT 7scue 15 o ¢ r- i L.24 N DATE TIME 5, r a co w U a w P. 0_= p' M i = co rr y 2 o m 2 en >. C a — c ti U m DATE TIME O LP 17. 2 3 4 5 6 7 8 9 10 11 12 ADDITIONAL COMMENTS RELINQUISHED BY AFFILIATION DATE TIME ACCEPTED BY I AF IUATION DATE TIME SAMPLE CONDITIONS y_ G <{J / ; 1 i`il% 6 r-- SAMPLER NAME AND SIGNATURE c PRINT Name of SAMPLER: ,;' LL ( (, c o w SIGNATURE of SAMPLER: , I 1 I , "-t-,-, , , DATE Signed: � --% 1 I ' - w i- m a C2 8 ; 8 8 z g 0 , E 8 z -e > m 0 a) co to l3 ace Analytical Document Revise_ tv'lay30 201a 007•er t3 0 : 354 73O1 Project PM: GT'R Project Manage CLIENT: 36 EEG Client. Thermometer Used 3 3'° Due Date: 04/04/19 Date T(SCUR) Issuino Authority Pace Florida Quality Office Time Date and Initials of person: Examining contents: Label: Deliver: pH: State of Or^igin n Fo• �Ar�' projects, ar containers verified to 55 `C Cooler #1 Temp.'f'• !/ (Visual) e • 0 (Correction Factor) ° (Actual) ) 117 Samples or:: e, cooling process has oecun Cooler#2 Temp.'C (Visual) (Correction Factor) (Actual) ) [ Samples or ,ce. coohna process has begun Cooler #3Temp.°C (Visual) (Correction Factor) (Actual) Cooler #4 Temp.°C (Visual) (Correction Factor) (Actual) Cooler#5 Temp.'C (Visual) (Correction Factor) (Actual) Cooler #6 Temp.'C (Visual) (Correction Factor) (Actual) Courier: LT Fed Ex 11 UPS ❑ USPS — Client C Commercial Pace Shipping Method: = First Overnight _ Priority Overnight = Standard Overnight = Ground = International Priority 17 Other Billing: = Recipient = Sender 11 Third Party = Credit Card = Unknown Tracking # ials Custody Seal on Cooler/Box Present: riYes Packing Material: _'Bubble Wrap ❑ Bubble Bags !None Samples shorted to lab (If Yes, complete) Shorted Date - Seals intact: _ Yes � No Ice: L_!Other Shorted Time. Blue Dry None Qty. Comments: Chain of Custody Present .GYes = No =N/A Chain of Custody Filled Out 'Yes I No .I -N/A Relinquished Signature & Sampler Name COC Samples Arrived within Hold Time Wes No =N/A = No _N/A Rush TAT requested on COC Sufficient Volume =Yes /No EN/A _Fes E No =N/A Correct Containers Used 2 es E No EN/A Containers Intact Sample Labels match COC (sample !Ds & date collection) As = No =N/A +me of es = No EN/A ✓ Samples on ice ccomno process has oegur • Samples on ce cooling process has begufi C Samples on ice cooling process has begun L Sa -pes or ',fie, cooling process nas t:eour Other es E No =N/A es Exceptions VOA Conform TOC, O&G, Caroamates Headspace in VOA Vials? ( >6mm) Trip Blank Present - AU containers needing acid/base preservation have ceen checked All Containers needing preservation are found to be in compliance with EPA recommendation No =N/A =Yes N AVIA Preservation Information Preservative Lot #/Trace # Date initials Time -Yes E No ;/f'i!A Client Notification/ Resolution: Person Contacted Comments/ Resolution (use back for additional comments): Dale/Time Project Manager Review Date Page 13 of 13 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 March 08, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451854 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 05, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry, EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 11 wvnv.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 CERTIFICATIONS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451854 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 11 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451854 Lab ID Sample ID Matrix Date Collected Date Received 35451854001 MW-39 Water 03/04/19 13:04 03/05/19 17:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 11 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451854 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35451854001 MW-39 EPA6010 JWP 3 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 11 /2eAnaIyticaI wwwpacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451854 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35451854001 MW-39 EPA 6010 Barium 11.5 ug/L 10.0 03/07/19 20:46 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 11 /eAnaIyt/caI www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No. 35451854 Sample: MW-39 Lab ID: 35451854001 Collected: 03/04/19 13:04 Received: 03/05/19 17:45 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Arsenic 7.1 U ug/L 10.0 7.1 1 03/07/19 10:29 03/07/19 20:46 7440-38-2 Barium 11.5 ug/L 10.0 0.84 1 03/07/19 10:29 03/07/19 20:46 7440-39-3 Lead 4.6 U ug/L 10.0 4.6 1 03/07/19 10:29 03/07/19 20:46 7439-92-1 Date: 03/08/2019 01:05 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 11 QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451854 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521178 Analysis Method: EPA 6010 QC Batch Method: EPA3010 Analysis Description: 6010 MET Associated Lab Samples: 35451854001 METHOD BLANK: 2814528 Matrix: Water Associated Lab Samples: 35451854001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic ug/L 7.1 U 10.0 7.1 03/07/19 20:40 Barium ug/L 0.84 U 10.0 0.84 03/07/19 20:40 Lead ug/L 4.6 U 10.0 4.6 03/07/19 20:40 LABORATORY CONTROL SAMPLE: 2814529 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic ug/L 250 251 100 80-120 Barium ug/L 250 250 100 80-120 Lead ug/L 250 260 104 80-120 `AATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2814530 2814531 MS MSD 35451859001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L 7.1 U 250 250 259 252 104 101 75-125 3 20 Barium ug/L 11.5 250 250 266 260 102 99 75-125 2 20 Lead ug/L 4.6 U 250 250 260 255 104 102 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/08/2019 01:05 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 11 aceAnalytical wvnv.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALIFIERS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451854 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL- Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PAST-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS U Compound was analyzed for but not detected. Date: 03/08/2019 01:05 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 11 aceAnalytical www.pace/abs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451854 Lab ID Sample ID QC Batch Method Analytical QC Batch Analytical Method Batch 35451854001 MW-39 Date: 03/08/2019 01:05 PM EPA 3010 521178 EPA 6010 521271 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 11 11-celinaMical CHAIN-CWO# : 35451854 The Chain -of. lent mpleted accurately, Section A Section B 11111 Required Client Information: Required Project Information: Ell 1111111111 III Page : 1 Of , 9 Company. EE&G Environmental Services, LLC 35451854 Report To th ,yam, bra µtC\,-,[+d \ 10--, _ Address 5751 Miami Lakes Dr. 1?-.- CopyTo. CC eti + Hialeah, FL 33014 v�� Addressy'Va'Ic Regulatory Agency ` E-mail thadt •�.. r,..„v n�� of fLlr.1q. Cc. r, Purchase Order�#� Pace Quote Phone. (305)374-8300 I""' �, � ry Project Name' N\t,.�t- e,5c, �•\Y (,-,,) je,_ Pace Project Manager, christina.raschke@pacelabs.com, State 1 Location Requested Dee Dale. S- - ah,e,,--" V' Project #: 2018-3057 Face ProiLie #. FL Requested Analysis Filtered ,YIN) MATRIX CODE MATRIX CODE (see valid codes to left) SAMPLE TYPE (G=GRAB C=COMP) COLLECTED Z # OF CONTAINERS Preservatives Z >- Drinking Wnter ow wmer wr wnraewnter WW SAMPLE ID Product 011 o t. START END O 0 U H2SO4 HNO3 HCI Na2S203 Analyses Test 6010As, Pbtt z d co o n W One Character per box. wire wP (A-Z, 0-9 1, -) Other oT Sample Ids must be unique ri„ue TS DATE TIME DATE TIME a 5 w a e) Z m m c = = O Z ° L `- L 0 2 r 3 4 5 6 7 8 9 10 11 12 ADDITIONAL COMMENTS RELINQUISHED BY l AFFILIATION . : DATE , TIME ,.ACCEPTED BY 1 AFFILIATION DATE TIME SAMPLE CONDITIONS /_---�• 1 _ —Th�- -cJ 5/ / •t i C-, iG r7.,��ll // - . >/-- /i,- % r� t CI 5G ? RJ Y _V-i-l- 3 6 "ic ri-L1-5 co jlf,r1-\1-. /5 cj rU y. SAMPLER NAME AND SIGNATURE TEMP in C o > _ m Z ', o m `m .-., °o Z n z_ PRINT Name of SAMPLER: �, �� L1i\\ �^�1 rJ 1�' � ',- SIGNATURE of SAMPLER: %) ATE Signed: l Document Name Sam Condition Upon Receipt Fur, Document Revisec May 30, 2018 Document No F-FL-C-007 rev 1'1 Issuing Authority Pace Florida Quality Office immimmrwo# Due Date: 03/12/19 ProjectPm, CTR Project ManageCLiENT: 36-EEG Client. Thermometer Used State of MINEOBI- Date and Initials of p Examining content: (' Label: Deliver ❑ For W+/ projects, all containers verified to <6 °C Cooler #1 Temp.'C (Visual) 0. 0 (Correction Factor) 3, s (Actual) Cooler#2 Temp.'C (Visual) V- 0 (Correction Factor) (0. 0 (Actual) Cooler#3 Temp.'C _5_(Visual) 0-0 (Correction Factor) 56 (Actual) (Correction Factor) (Actual) 1 r Date C 1 / 5 , Time: � IR- (06do, Cooler #4 Temp.°C (Visual) Cooler#5 Temp.°C (Visual) (Correction Factor) (Actual) Cooler#6 Temp.'C (Visual) (Correction Factor) (Actual) Courier: Fed Ex I UPS ❑ USPS Client LT Commercia-.Pace Shipping Method: 7. First Overnight = Priority Overnight r Standard Overnight _, Ground Other Billing: = Recipient Tracking # Sender Custody Seal on Cooler/Box Present: Dyes Packing Material: OBubble Wrap Samples shorted to lab (If Yes, complete) Third Party = Credit Card Seals intact: 7 Yes ubble Bags LiNone JOther Shorted Date. ! ) Shorted Time. Samples on ice, cooling process has begun Samples or ice, cooling process has beoun (—�Sarnoles or•. ice, coohnc process has beoun L Samples on ice, cooling process has begun L Samples on ice, cooling process has begun L Samples on ice, cooling process has begun D Other International Priority Unknown Comments: lue Dry None Oty: Chain of Custody Present E es =+ No EtN/A Chain of Custody Filled Out s - No ON/A Relinquished Signature & Sampler Name COC _, es 0 No SIN/A Samples Arrived within Hold Time dyesm+ No . N/A Rush TAT requested on COC _YesN/A Sufficient Volume i,Xes = No DN/A Correct Containers Used s E No i7N/A Containers Intact ,GYes No ON/A Sample Labels match COC (sample IDs & date/time of collection) • < I. ' No ON/A All containers needing acid/base preservation have been checked 1s - No ❑N/A All Containers needing preservation are found to be in compliance with EPA recommendation ^ es _ No _N/A Exceptions VOA, Conform, TOC, O&G, Cerbamates Preservation Information - Preservative Lot #/Trace # Date. i ir/ Initials Headspace in VOA Vials? ( >6mm): EYes _ No DNA/` Trip Blank Present: _Yes - No—�F AC/ Client Notification/ Resolution: Person Contacted. Comments/ Resolution (use back for additional comments): Date/Time Project Manager Review. Date. Page 11 of 11 aceAnalytical® www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 March 08, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451846 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 05, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry, EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 13 www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-562-4300 CERTIFICATIONS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451846 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 13 aceAnalytical wwwpacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451846 Lab ID Sample ID Matrix Date Collected Date Received 35451846001 MW-39 Water 03/04/19 13:04 03/05/19 17:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 13 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 SAMPLE ANALYTE COUNT Project 2018-3057/Melreese Golf Course Pace Project No.: 35451846 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35451846001 MW-39 EPA 6010 JWP 2 PASI-O EPA 300.0 JDM 2 PASI-O EPA 350.1 MAJ 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 13 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451846 Lab Sample ID Client Sample ID Method Parameters 35451846001 EPA 6010 EPA 350.1 MW-39 Iron Nitrogen, Ammonia Result Units Report Limit Analyzed Qualifiers 369 ug/L 0.67 mg/L REPORT OF LABORATORY ANALYSIS 40.0 03/07/19 20:46 0.050 03/06/19 08:23 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 13 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451846 Sample: MW-39 Lab ID: 35451846001 Collected: 03/04/19 13:04 Received: 03/05/19 17:45 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Iron 300.0 IC Anions Nitrate as N Nitrite as N 350.1 Ammonia Nitrogen, Ammonia Analytical Method: EPA 6010 Preparation Method. EPA 3010 30.7 U ug/L 369 ug/L 100 30.7 1 03/07/19 10:29 03/07/19 20:46 7429-90-5 40.0 9.2 1 03/07/19 10:29 03/07/19 20:46 7439-89-6 Analytical Method: EPA 300.0 0.025 U mg/L 0.050 0.025 1 03/06/19 07:42 14797-55-8 0.025 U mg/L 0.050 0.025 1 03/06/19 07:42 14797-65-0 Analytical Method: EPA 350.1 0.67 mg/L 0.050 0.035 1 03/06/19 08:23 7664-41-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/08/2019 12:38 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 13 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451846 QC Batch: 521178 Analysis Method: EPA 6010 QC Batch Method: EPA 3010 Analysis Description: 6010 MET Associated Lab Samples: 35451846001 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 METHOD BLANK: 2814528 Matrix: Water Associated Lab Samples: 35451846001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Aluminum ug/L 30.7 U 100 Iron ug/L 9.2 U 40.0 30.7 03/07/19 20:40 9.2 03/07/19 20:40 LABORATORY CONTROL SAMPLE: 2814529 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Aluminum ug/L 2500 2520 101 80-120 Iron ug/L 2500 2610 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2814530 2814531 MS MSD 35451859001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 30.7 U 2500 2500 2590 2530 103 101 75-125 2 20 Iron ug/L 369 2500 2500 2980 2910 105 102 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/08/2019 12:38 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 13 ceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451846 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 520750 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 35451846001 METHOD BLANK: 2812105 Matrix: Water Associated Lab Samples: 35451846001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrate as N mg/L 0.025 U 0.050 0.025 03/06/19 11:46 Nitrite as N mg/L 0.025 U 0.050 0.025 03/06/19 11:46 LABORATORY CONTROL SAMPLE: 2812106 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/L 5 5.0 100 90-110 Nitrite as N mg/L 5 4.9 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2812128 2812129 MS MSD 35451851001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrate as N mg/L 0.025 U 5 5 4.8 4.8 96 96 90-110 1 20 Nitrite as N mg/L 0.025 U 5 5 4.9 4.9 98 97 90-110 1 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/08/2019 12:38 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 13 ace Analytical wv,wpacelabs.corn QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451846 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 520730 Analysis Method: EPA 350.1 QC Batch Method: EPA 350.1 Analysis Description: 350.1 Ammonia Associated Lab Samples: 35451846001 METHOD BLANK: 2812044 Matrix: Water Associated Lab Samples: 35451846001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Ammonia mg/L 0.035 U 0.050 0.035 03/06/19 08:14 LABORATORY CONTROL SAMPLE: 2812045 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 1 1.1 105 90-110 MATRIX SPIKE SAMPLE: 2812047 35451845001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 0.58 1 1.6 103 90-110 SAMPLE DUPLICATE: 2812046 35451845001 Dup Parameter Units Result Result RPD Max RPD Qualifiers Nitrogen, Ammonia mg/L 0.58 0.58 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/08/2019 12:38 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 13 QUALIFIERS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451846 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported. represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS U Compound was analyzed for but not detected. Date: 03/08/2019 12:38 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 13 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451846 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID QC Batch Method Analytical QC Batch Analytical Method Batch 35451846001 MW-39 EPA 3010 521178 EPA 6010 521271 35451846001 MW-39 EPA 300.0 520750 35451846001 MW-39 EPA 350.1 520730 Date: 03/08/2019 12:38 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 13 �aceAna/yfrral CHAIN-of-CUS-I14p :35451846 The Chain -of -Custody is a irately. Section A Section B Section 11111 Required Client Information: Required Project Information: Invoice 1111 11111 II III III Page : 1 Of 1 Company EE&G Environmental Services, LLC Report To. ate, ILAa NA"EA 13," Attenhor 35451846 Address 5751 Miami Lakes Dr Copy To C' .eLi . GtC iele r-�t Company Name. Hialeah, FL 33014 �J Address Regulatory Agency Email e ., - Purchase Order 4.. Pace Quote rr,40 n tnc‘Q " cot.1 Phone (305)374-8300 . (ax U Project Name' eArL25e... G014, C.Durse Pace Project Manager. christina.raschke@pacelabs.com, -, State / Location' Requested Due Date. _yT Lam.,--.,-25 "� \ Project #: 2018-305 / Pace Profile it / FL Requr t d A al Filtered (Y/N) -- MATRIX CODE MATRIX CODE (see valid codes to left) 'SAMPLE TYPE (G=GRAB C=COMP) COLLECTED SAMPLE TEMP AT COLLECTION Preservatives 2 >- fiL it 3 Dunking Water DW Walt. WT Warm Water WW Product P SAMPLE ID so'Iusom START END Unpreserved HNO3 NaOH Na2S2O3 Other Analyses Test 8260 VOC PAH by 8270 SIM TRPH FL -PRO Pesticides 8081CO3,v„ Pesticides 8141(cria,r, Herbicides 8151( \ t ` = o rn c e o O 6010 Ba, Cd, Cr, Se, Ag, 7470 Hg yip As, ?ootc, .4t,�e. 0. et). -.4. Residual Chlorine (YIN) xt W ~ One Character per box. Wipe WO (A-Z, 0-9 1 , -) Au AR Other Oi Sample Ids must be unique Tissue TS DATE TIME DATE TIME w F Z p o .Q _ _ m t 1 I�( �.� -)'s ,� 3kIt'Z,.'i /,- N'.5- 2 3 4 5 6 7 8 9 10 11 12 ADDITIONAL COMMENTS RELINQUISHED BY I AFFILIATION - DAT11. TIME i•r1(1CCEPTED BY 'AFFILIATION' J DATE TIME. SAMPLE CONDITIONS p /Iru % L .;) < /G;x-' . (2--- 'ice. �i'.�. / 3�41cJ 1''. 1J 3 �/ 1 ,e, ' Ll/4/ , / f( =, 51 / 71-1- 0. ° y y / 5E y N )( SAMPLER NAME AND SIGNATURE TEMP in C Received on Ice (Y/N) usto y Sealed Cooler (Y/N)_ N c ? PRINT Name of SAMPLER: LL1 41 • ? - ` v� SIGNATURE of SAMPLE/FIX,(1 I DATE Signed: y Pi7COAnalytical rev 13 _rocurnen, i':evlsec May 30 2018 ssuinp Pace ,'.o'caQuality O"Ice Samples shorted to lab (If Yes, complete) WO#:3545,174§71.21111.111.111111.1111111111 Project # PM: CTR Project Manager: CLIENT: 36-EEC Client: Thermometer Usec Date State of ng�F\ P ( t�� cts al; containers ventaa to 56'C Cooler #1 Temp.'C (J (Visual) O. 00 (Correction Factor) 3. s (Actual) Sarnoies on ,ce cooing process ras oeoen Cooler #2 Temp.'C (Visual) 0 (Correction Factor) (� 0 (Actual) Samp:es o ce ccDu'g :Process has becun Cooler #3 Temp.'C 5. J (Visual) 0 , 0 (Correction Factor)v�5 r :n "l (Actual) Samples c- :o= cco;r. process as begun Cooler #4 Temp.'C (Visual) (Correction Factor) JJJ (Actual) �L Samaes D, :ce coc::r_ process has begun Cooler #5Temp.`C (Visual) (Correction Factor) (Actual) [ Sampescr:ce cD.. mccess has b€oun Cooler #6 Temp.'C (Visual) (Correction Factor) (Actual) [ Sa--:p,es c- : e. cc... „ceSS `las begun Due Date: 03/12/19 Date and Initials of p Examining contents: Label: Deliver.)\ pH: Initials I Courier: — Fed Ex — UPS L] USPS — Client r-- CommerclaI Pace Other Shipping Method: - First Overnight _ Pnor:ty Overnight __ Standard Overnight Ground IT International Priority _ Other Billing: _ Recipient _ Sender _ Third Party _ Credit Card = Unknown Tracking # Custody Seal on Cooler/Box Present: Yes do Seals intact: Yes Ic( Wet lue Dry None Packing Material: Bubble Wrap ubble Bags L_None ._;Other Shorted Date • Shorted Time 1_ Qty Chain of Custody Present - es _ No _N/A Chain of Custody Filled Out �"l es _ No=Nst!A. Relinquished Sionature & Sampler Name COC _ e/s �_ No _N/A Samples Arrived within Hole Time Yes No EN/A Rush TAT requested on COC _Yees to _N/A Sufficient Volume c = No N/A !!!_...)<ss Correct Containers Used No EN/A Containers Intact _ No _N/A Sample Labe:s match COC (samcie IDs & cate'time of collection) es _ No _N/A All containers needmc ac.d'oase preservation have been _.Yes _ No _N/A All Containers neecmo preservation are fount to be in compliance wan EPA recommenoat.on - es _ No _NIA Exceptions VOA. Coli orro. TOC, C&G. Caroamaies Preservation Informationchecked Preservative Lot #'Trace Dale i i Indiais ! ti Headspace in VOA Vials? (>6mm) :Yes No Trip Blank Present. _Yes /A = Client Notification/ Resolution: Person Contacted Comments/ Resolution (use back for additional comments): Date'Time Project Manager Review Date Page 13 of 13 aceAnalytical www.pacelabs.com March 12, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451859 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 05, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Some analyses have been subcontracted outside of the Pace Network. The subcontracted laboratory report has been attached. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry, EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 38 aceAnalytical® www.pacelabs.com CERTIFICATIONS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451859 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 38 aceAnalytical0 www.pacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451859 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35451859001 MW-39 Water 03/04/19 13:04 03/05/19 17:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 38 aceAnalytical www.pacelabs.com SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451859 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35451859001 MW-39 EPA 8081 AER 22 PASI-O FL -PRO BP2 3 PASI-O EPA 6010 JWP 4 PASI-O EPA 7470 AMS 1 PASI-O EPA 8270 by SIM CB1 20 PASI-O EPA 8260 BTN 69 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 38 iI l ceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451859 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-39 Parameters Lab ID: 35451859001 Collected: 03/04/19 13:04 Received: 03/05/19 17:45 Matrix: Water Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8081 GCS Pesticides Aldrin alpha-BHC beta-BHC delta-BHC gamma-BHC (Lindane) Chlordane (Technical) 4,4'-DDD 4,4'-DDE 4,4'-DDT Dieldrin Endosulfan I Endosulfan II Endosulfan sulfate Endrin Endrin aldehyde Endrin ketone Heptachlor Heptachlor epoxide ,ethoxychlor Toxaphene Surrogates Tetrachloro-m-xylene (S) Decachlorobiphenyl (S) FL -PRO Water, Low Volume Petroleum Range Organics Surrogates o-Terphenyl (S) N-Pentatriacontane (S) 6010 MET ICP Cadmium Chromium Selenium Silver 7470 Mercury Mercury 8270 MSSV PAHLV by SIM Acenaphthene Acenaphthylene Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Date: 03/12/2019 09:06 PM Analytical Method: EPA 8081 Preparation Method: EPA 3510 0.0014 0.0020 0.0077 0.0046 0.0021 0.17 0.0086 0.0048 0.0048 0.0019 0.0049 0.0039 0.0060 0.0041 0.0035 0.0048 0.0060 0.0050 0.0093 0.24 71 61 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 0.0096 0.0096 0.0096 0.0096 0.0096 0.48 0.0096 0.0096 0.0096 0.0096 0.0096 0.0096 0.096 0.0096 0.096 0.0096 0.0096 0.0096 0.0096 0.48 27-124 10-132 0.0014 0.0020 0.0077 0.0046 0.0021 0.17 0.0086 0.0048 0.0048 0.0019 0.0049 0.0039 0.0060 0.0041 0.0035 0.0048 0.0060 0.0050 0.0093 0.24 03/06/19 16:26 03/06/19 16:26 03/06/19 16:26 03/06/19 16:26 03/06/19 16:26 03/06/19 16:26 03/06/19 16:26 03/06/19 16:26 03/06/19 16:26 03/06/19 16:26 03/06/19 16:26 03/06/19 16:26 03/06/19 16:26 03/06/19 16:26 03/06/19 16:26 03/06/19 16:26 03/06/19 16:26 03/06/19 16:26 03/06/19 16:26 03/06/19 16:26 1 03/06/19 16:26 1 03/06/19 16:26 Analytical Method: FL -PRO Preparation Method: EPA 3510 0.79 U mg/L 0.99 0.79 1 03/07/19 09:10 81 97 66-139 42-159 1 03/07/19 09:10 1 03/07/19 09:10 Analytical Method: EPA 6010 Preparation Method: EPA 3010 0.33 U 1.7 U 8.5 U 1.0 U ug/L ug/L ug/L ug/L 1.0 5.0 15.0 5.0 0.33 1.7 8.5 1.0 03/07/19 10:29 03/07/19 10:29 03/07/19 10:29 03/07/19 10:29 Analytical Method: EPA 7470 Preparation Method: EPA 7470 0.10 U ug/L 0.20 0.10 1 03/07/19 10:25 Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3510 0.040 U 0.030 U 0.043 U 0.055 U 0.12 U 0.027 U ug/L ug/L ug/L ug/L ug/L ug/L 0.50 0.50 0.50 0.10 0.20 0.10 0.040 0.030 0.043 0.055 0.12 0.027 03/07/19 02:41 03/07/19 02:41 03/07/19 02:41 03/07/19 02:41 03/07/19 02:41 03/07/19 02:41 REPORT OF LABORATORY ANALYSIS 03/09/19 03:48 03/09/19 03:48 03/09/19 03:48 03/09/19 03:48 03/09/19 03:48 03/09/19 03:48 03/09/19 03:48 03/09/19 03:48 03/09/19 03:48 03/09/19 03:48 03/09/19 03:48 03/09/19 03:48 03/09/19 03:48 03/09/19 03:48 03/09/19 03:48 03/09/19 03:48 03/09/19 03:48 03/09/19 03:48 03/09/19 03:48 03/09/19 03:48 309-00-2 319-84-6 319-85-7 319-86-8 58-89-9 57-74-9 72-54-8 72-55-9 50-29-3 60-57-1 959-98-8 33213-65-9 1031-07-8 72-20-8 7421-93-4 53494-70-5 76-44-8 1024-57-3 72-43-5 8001-35-2 03/09/19 03:48 877-09-8 03/09/19 03:48 2051-24-3 03/07/19 13:11 03/07/19 13:11 84-15-1 03/07/19 13:11 630-07-09 03/07/19 20:46 03/07/19 20:46 03/07/19 20:46 03/07/19 20:46 7440-43-9 7440-47-3 7782-49-2 7440-22-4 03/08/19 16:09 7439-97-6 03/07/19 11:34 83-32-9 03/07/19 11:34 208-96-8 03/07/19 11:34 120-12-7 03/07/19 11:34 56-55-3 03/07/19 11:34 50-32-8 03/07/19 11:34 205-99-2 1p 1p 1p 1p 1p 1p 1p 1p 1p 1p 1p 1p 1p 1p 1p 1p 1p 1p 1p 1p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 38 aceAnalytical® wwwpace/abs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451859 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-39 Lab ID: 35451859001 Collected: 03/04/19 13:04 Received: 03/05/19 17:45 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8270 MSSV PAHLV by SIM Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3510 Benzo(g,h,i)perylene 0.15 U ug/L 0.50 0.15 1 03/07/19 02:41 03/07/19 11:34 191-24-2 Benzo(k)fluoranthene 0.16 U ug/L 0.50 0.16 1 03/07/19 02:41 03/07/19 11:34 207-08-9 Chrysene 0.026 U ug/L 0.50 0.026 1 03/07/19 02:41 03/07/19 11:34 218-01-9 Dibenz(a,h)anthracene 0.13 U ug/L 0.15 0.13 1 03/07/19 02:41 03/07/19 11:34 53-70-3 Fluoranthene 0.018 U ug/L 0.50 0.018 1 03/07/19 02:41 03/07/19 11:34 206-44-0 Fluorene 0.088 U ug/L 0.50 0.088 1 03/07/19 02:41 03/07/19 11:34 86-73-7 Indeno(1,2,3-cd)pyrene 0.12 U ug/L 0.15 0.12 1 03/07/19 02:41 03/07/19 11:34 193-39-5 1-Methylnaphthalene 0.19 U ug/L 2.0 0.19 1 03/07/19 02:41 03/07/19 11:34 90-12-0 2-Methylnaphthalene 0.68 U ug/L 2.0 0.68 1 03/07/19 02:41 03/07/19 11:34 91-57-6 Naphthalene 0.29 U ug/L 2.0 0.29 1 03/07/19 02:41 03/07/19 11:34 91-20-3 Phenanthrene 0.16 U ug/L 0.50 0.16 1 03/07/19 02:41 03/07/19 11:34 85-01-8 Pyrene 0.032 U ug/L 0.50 0.032 1 03/07/19 02:41 03/07/19 11:34 129-00-0 Surrogates 2-Fluorobiphenyl (S) 72 % 33-82 1 03/07/19 02:41 03/07/19 11:34 321-60-8 p-Terphenyl-d14 (S) 100 % 49-104 1 03/07/19 02:41 03/07/19 11:34 1718-51-0 8260 MSV Analytical Method: EPA 8260 1,1,1,2-Tetrachloroethane 0.32 U ug/L 1.0 0.32 1 03/06/19 14:53 630-20-6 1,1.1-Trichloroethane 0.30 U ug/L 1.0 0.30 1 03/06/19 14:53 71-55-6 1,1,2,2-Tetrachloroethane 0.20 U ug/L 0.50 0.20 1 03/06/19 14:53 79-34-5 1,1,2-Trichloroethane 0.30 U ug/L 1.0 0.30 1 03/06/19 14:53 79-00-5 1,1-Dichloroethane 0.34 U ug/L 1.0 0.34 1 03/06/19 14:53 75-34-3 1,1-Dichloroethene 0.27 U ug/L 1.0 0.27 1 03/06/19 14:53 75-35-4 1,1-Dichloropropene 0.31 U ug/L 1.0 0.31 1 03/06/19 14:53 563-58-6 1,2,3-Trichlorobenzene 0.34 U ug/L 1.0 0.34 1 03/06/19 14:53 87-61-6 1,2,3-Trichloropropane 1.1 U ug/L 2.0 1.1 1 03/06/19 14:53 96-18-4 1,2,3-Trimethylbenzene 0.17 U ug/L 1.0 0.17 1 03/06/19 14:53 526-73-8 1,2,4-Trichlorobenzene 0.32 U ug/L 1.0 0.32 1 03/06/19 14:53 120-82-1 1,2,4-Trimethylbenzene 0.24 U ug/L 1.0 0.24 1 03/06/19 14:53 95-63-6 1,2-Dichlorobenzene 0.29 U ug/L 1.0 0.29 1 03/06/19 14:53 95-50-1 1,2-Dichloroethane 0.27 U ug/L 1.0 0.27 1 03/06/19 14:53 107-06-2 1,2-Dichloropropane 0.23 U ug/L 1.0 0.23 1 03/06/19 14:53 78-87-5 1,3,5-Trimethylbenzene 0.24 U ug/L 1.0 0.24 1 03/06/19 14:53 108-67-8 1,3-Dichlorobenzene 0.33 U ug/L 1.0 0.33 1 03/06/19 14:53 541-73-1 1,3-Dichloropropane 0.26 U ug/L 1.0 0.26 1 03/06/19 14:53 142-28-9 1,4-Dichlorobenzene 0.28 U ug/L 1.0 0.28 1 03/06/19 14:53 106-46-7 2,2-Dichloropropane 0.59 U ug/L 1.0 0.59 1 03/06/19 14:53 594-20-7 2-Butanone (MEK) 7.5 U ug/L 10.0 7.5 1 03/06/19 14:53 78-93-3 2-Chloroethylvinyl ether 1.4 U ug/L 40.0 1.4 1 03/06/19 14:53 110-75-8 c2 2-Chlorotoluene 0.28 U ug/L 1.0 0.28 1 03/06/19 14:53 95-49-8 2-Hexanone 0.85 U ug/L 10.0 0.85 1 03/06/19 14:53 591-78-6 4-Chlorotoluene 0.22 U ug/L 1.0 0.22 1 03/06/19 14:53 106-43-4 4-Methyl-2-pentanone (MIBK) 0.32 U ug/L 10.0 0.32 1 03/06/19 14:53 108-10-1 Acetone 5.3 U ug/L 20.0 5.3 1 03/06/19 14:53 67-64-1 Benzene 0.30 U ug/L 1.0 0.30 1 03/06/19 14:53 71-43-2 Bromobenzene 0.21 U ug/L 1.0 0.21 1 03/06/19 14:53 108-86-1 Date: 03/12/2019 09:06 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 38 aceAnalytiCal® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451859 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-39 Parameters Lab ID: 35451859001 Collected: 03/04/19 13:04 Received: 03/05/19 17:45 Matrix: Water Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Bromochloromethane Bromod i chloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Dibromochloromethane Dibromomethane Dichlorodifluoromethane Ethylbenzene lodomethane Isopropylbenzene (Cumene) Methyl-tert-butyl ether Methylene Chloride yrene retrachloroethene Toluene Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene m&p-Xylene n-Butylbenzene n-Propylbenzene o-Xylene p-Isopropyltoluene sec-Butylbenzene tert-Butylbenzene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 03/12/2019 09:06 PM Analytical Method: EPA 8260 0.37 U ug/L 1.0 0.37 1 0.19 U ug/L 0.60 0.19 1 2.6 U ug/L 3.0 2.6 1 4.0 U ug/L 5.0 4.0 1 0.45 U ug/L 10.0 0.45 1 1.1 U ug/L 3.0 1.1 1 0.35 U ug/L 1.0 0.35 1 3.7 U ug/L 10.0 3.7 1 0.32 U ug/L 1.0 0.32 1 0.97 U ug/L 1.0 0.97 1 0.45 U ug/L 2.0 0.45 1 0.68 U ug/L 2.0 0.68 1 0.26 U ug/L 1.0 0.26 1 0.30 U ug/L 1.0 0.30 1 9.3 U ug/L 10.0 9.3 1 0.30 U ug/L 1.0 0.30 1 0.51 U ug/L 2.0 0.51 1 2.0 U ug/L 5.0 2.0 1 0.26 U ug/L 1.0 0.26 1 0.38 U ug/L 1.0 0.38 1 0.33 U ug/L 1.0 0.33 1 0.36 U ug/L 1.0 0.36 1 0.35 U ug/L 1.0 0.35 1 0.19 U ug/L 10.0 0.19 1 0.39 U ug/L 1.0 0.39 1 2.1 U ug/L 5.0 2.1 1 0.27 U ug/L 1.0 0.27 1 0.17 U ug/L 0.50 0.17 1 2.1 U ug/L 4.0 2.1 1 0.20 U ug/L 1.0 0.20 1 0.37 U ug/L 1.0 0.37 1 0.27 U ug/L 1.0 0.27 1 0.31 U ug/L 5.0 0.31 1 0.17 U ug/L 1.0 0.17 1 0.26 U ug/L 1.0 0.26 1 0.23 U ug/L 1.0 0.23 1 0.17 U ug/L 0.50 0.17 1 89 % 70-130 1 106 % 70-130 1 101 % 70-130 1 REPORT OF LABORATORY ANALYSIS 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 03/06/19 14:53 74-97-5 75-27-4 75-25-2 74-83-9 v2 75-15-0 v1 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3 v2 124-48-1 74-95-3 75-71-8 100-41-4 74-88-4 v2 98-82-8 1634-04-4 75-09-2 100-42-5 127-18-4 108-88-3 79-01-6 75-69-4 108-05-4 75-01-4 1330-20-7 156-59-2 10061-01-5 179601-23-1 104-51-8 103-65-1 95-47-6 99-87-6 135-98-8 98-06-6 156-60-5 10061-02-6 03/06/19 14:53 460-00-4 03/06/19 14:53 17060-07-0 03/06/19 14:53 2037-26-5 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 38 QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451859 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521100 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 35451859001 METHOD BLANK: 2814165 Matrix: Water Associated Lab Samples: 35451859001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L 0.10 U 0.20 0.10 03/08/1915:31 LABORATORY CONTROL SAMPLE: 2814166 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2 1.9 96 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2814167 2814168 MS MSD 35451633001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L 0.10 U 2 2 1.7 1.8 86 88 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:06 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 38 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451859 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521178 Analysis Method: EPA 6010 QC Batch Method: EPA3010 Analysis Description: 6010 MET Associated Lab Samples: 35451859001 METHOD BLANK: 2814528 Matrix: Water Associated Lab Samples: 35451859001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Cadmium ug/L 0.33 U 1.0 0.33 03/07/19 20:40 Chromium ug/L 1.7 U 5.0 1.7 03/07/19 20:40 Selenium ug/L 8.5 U 15.0 8.5 03/07/19 20:40 Silver ug/L 1.0 U 5.0 1.0 03/07/19 20:40 LABORATORY CONTROL SAMPLE: 2814529 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Cadmium ug/L 25 25.7 103 80-120 Chromium ug/L 250 255 102 80-120 Selenium ug/L 250 261 104 80-120 Silver ug/L 25 24.1 96 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2814530 2814531 MS MSD 35451859001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Cadmium ug/L 0.33 U 25 25 26.0 25.4 104 101 75-125 2 20 Chromium ug/L 1.7 U 250 250 262 252 105 101 75-125 4 20 Selenium ug/L 8.5 U 250 250 266 253 106 101 75-125 5 20 Silver ug/L 1.0 U 25 25 24.5 23.7 98 95 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:06 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 38 2ceAnalytical® www.pacelabscom QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451859 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 520786 Analysis Method: EPA 8260 QC Batch Method: EPA 8260 Analysis Description: 8260 MSV Associated Lab Samples: 35451859001 METHOD BLANK: 2812236 Matrix: Water Associated Lab Samples: 35451859001 Parameter Blank Reporting Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L 0.32 U 1.0 0.32 03/06/19 09:44 1,1,1-Trichloroethane ug/L 0.30 U 1.0 0.30 03/06/19 09:44 1,1,2,2-Tetrachloroethane ug/L 0.20 U 0.50 0.20 03/06/19 09:44 1,1,2-Trichloroethane ug/L 0.30 U 1.0 0.30 03/06/19 09:44 1,1-Dichloroethane ug/L 0.34 U 1.0 0.34 03/06/19 09:44 1,1-Dichloroethene ug/L 0.27 U 1.0 0.27 03/06/19 09:44 1,1-Dichloropropene ug/L 0.31 U 1.0 0.31 03/06/19 09:44 1,2,3-Trichlorobenzene ug/L 0.34 U 1.0 0.34 03/06/19 09:44 1,2,3-Trichloropropane ug/L 1.1 U 2.0 1.1 03/06/19 09:44 1,2,3-Trimethylbenzene ug/L 0.17 U 1.0 0.17 03/06/19 09:44 1,2,4-Trichlorobenzene ug/L 0.32 U 1.0 0.32 03/06/19 09:44 1,2,4-Trimethylbenzene ug/L 0.24 U 1.0 0.24 03/06/19 09:44 1,2-Dichlorobenzene ug/L 0.29 U 1.0 0.29 03/06/19 09:44 1,2-Dichloroethane ug/L 0.27 U 1.0 0.27 03/06/19 09:44 1,2-Dichloropropane ug/L 0.23 U 1.0 0.23 03/06/19 09:44 1,3,5-Trimethylbenzene ug/L 0.24 U 1.0 0.24 03/06/19 09:44 1,3-Dichlorobenzene ug/L 0.33 U 1.0 0.33 03/06/19 09:44 1,3-Dichloropropane ug/L 0.26 U 1.0 0.26 03/06/19 09:44 1,4-Dichlorobenzene ug/L 0.28 U 1.0 0.28 03/06/19 09:44 2,2-Dichloropropane ug/L 0.59 U 1.0 0.59 03/06/19 09:44 2-Butanone (MEK) ug/L 7.5 U 10.0 7.5 03/06/19 09:44 2-Chloroethylvinyl ether ug/L 1.4 U 40.0 1.4 03/06/19 09:44 2-Chlorotoluene ug/L 0.28 U 1.0 0.28 03/06/19 09:44 2-Hexanone ug/L 0.85 U 10.0 0.85 03/06/19 09:44 4-Chlorotoluene ug/L 0.22 U 1.0 0.22 03/06/19 09:44 4-Methyl-2-pentanone (MIBK) ug/L 0.32 U 10.0 0.32 03/06/19 09:44 Acetone ug/L 5.3 U 20.0 5.3 03/06/19 09:44 Benzene ug/L 0.30 U 1.0 0.30 03/06/19 09:44 Bromobenzene ug/L 0.21 U 1.0 0.21 03/06/19 09:44 Bromochloromethane ug/L 0.37 U 1.0 0.37 03/06/19 09:44 Bromodichloromethane ug/L 0.19 U 0.60 0.19 03/06/19 09:44 Bromoform ug/L 2.6 U 3.0 2.6 03/06/19 09:44 Bromomethane ug/L 4.0 U 5.0 4.0 03/06/19 09:44 Carbon disulfide ug/L 0.45 U 10.0 0.45 03/06/19 09:44 Carbon tetrachloride ug/L 1.1 U 3.0 1.1 03/06/19 09:44 Chlorobenzene ug/L 0.35 U 1.0 0.35 03/06/19 09:44 Chloroethane ug/L 3.7 U 10.0 3.7 03/06/19 09:44 Chloroform ug/L 0.32 U 1.0 0.32 03/06/19 09:44 Chloromethane ug/L 0.97 U 1.0 0.97 03/06/19 09:44 cis-1,2-Dichloroethene ug/L 0.27 U 1.0 0.27 03/06/19 09:44 cis-1,3-Dichloropropene ug/L 0.17 U 0.50 0.17 03/06/19 09:44 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:06 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 38 if 2ceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451859 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 METHOD BLANK: 2812236 Matrix: Water Associated Lab Samples: 35451859001 Parameter Blank Reporting Units Result Limit MDL Analyzed Qualifiers Dibromochloromethane ug/L 0.45 U 2.0 0.45 03/06/19 09:44 Dibromomethane ug/L 0.68 U 2.0 0.68 03/06/19 09:44 Dichlorodifluoromethane ug/L 0.26 U 1.0 0.26 03/06/19 09:44 Ethylbenzene ug/L 0.30 U 1.0 0.30 03/06/19 09:44 lodomethane ug/L 9.3 U 10.0 9.3 03/06/19 09:44 Isopropylbenzene (Cumene) ug/L 0.30 U 1.0 0.30 03/06/19 09:44 m&p-Xylene ug/L 2.1 U 4.0 2.1 03/06/19 09:44 Methyl-tert-butyl ether ug/L 0.51 U 2.0 0.51 03/06/19 09:44 Methylene Chloride ug/L 2.0 U 5.0 2.0 03/06/19 09:44 n-Butylbenzene ug/L 0.20 U 1.0 0.20 03/06/19 09:44 n-Propylbenzene ug/L 0.37 U 1.0 0.37 03/06/19 09:44 o-Xylene ug/L 0.27 U 1.0 0.27 03/06/19 09:44 p-Isopropyltoluene ug/L 0.31 U 5.0 0.31 03/06/19 09:44 sec-Butylbenzene ug/L 0.17 U 1.0 0.17 03/06/19 09:44 Styrene ug/L 0.26 U 1.0 0.26 03/06/19 09:44 tert-Butylbenzene ug/L 0.26 U 1.0 0.26 03/06/19 09:44 Tetrachloroethene ug/L 0.38 U 1.0 0.38 03/06/19 09:44 Toluene ug/L 0.33 U 1.0 0.33 03/06/19 09:44 -ans-1,2-Dichloroethene ug/L 0.23 U 1.0 0.23 03/06/19 09:44 sans-1,3-Dichloropropene ug/L 0.17 U 0.50 0.17 03/06/19 09:44 Trichloroethene ug/L 0.36 U 1.0 0.36 03/06/19 09:44 Trichlorofluoromethane ug/L 0.35 U 1.0 0.35 03/06/19 09:44 Vinyl acetate ug/L 0.19 U 10.0 0.19 03/06/19 09:44 Vinyl chloride ug/L 0.39 U 1.0 0.39 03/06/19 09:44 Xylene (Total) ug/L 2.1 U 5.0 2.1 03/06/19 09:44 1,2-Dichloroethane-d4 (S) % 103 70-130 03/06/19 09:44 4-Bromofluorobenzene (S) % 94 70-130 03/06/19 09:44 Toluene-d8 (S) % 101 70-130 03/06/19 09:44 LABORATORY CONTROL SAMPLE: 2812237 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 20 20.1 101 70-130 1,1,1-Trichloroethane ug/L 20 18.8 94 70-130 1,1,2,2-Tetrachloroethane ug/L 20 21.3 107 68-125 1,1,2-Trichloroethane ug/L 20 20.1 101 70-130 1,1-Dichloroethane ug/L 20 20.2 101 70-130 1,1-Dichloroethene ug/L 20 18.9 94 66-133 1,1-Dichloropropene ug/L 20 20.3 101 70-130 1,2,3-Trichlorobenzene ug/L 20 21.4 107 64-126 1,2,3-Trichloropropane ug/L 20 21.7 108 62-127 1,2,3-Trimethylbenzene ug/L 20 23.0 115 70-130 1,2,4-Trichlorobenzene ug/L 20 19.4 97 63-124 1,2,4-Trimethylbenzene ug/L 20 20.5 102 70-130 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:06 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 38 QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451859 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE: 2812237 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,2-Dichlorobenzene ug/L 20 19.5 97 70-130 1,2-Dichloroethane ug/L 20 17.7 88 70-130 1,2-Dichloropropane ug/L 20 19.3 97 70-130 1,3,5-Trimethylbenzene ug/L 20 20.2 101 70-130 1,3-Dichlorobenzene ug/L 20 19.5 98 70-130 1,3-Dichloropropane ug/L 20 20.2 101 70-130 1,4-Dichlorobenzene ug/L 20 19.4 97 70-130 2,2-Dichloropropane ug/L 20 20.2 101 59-133 2-Butanone (MEK) ug/L 40 44.2 111 47-143 2-Chloroethylvinyl ether ug/L 20 20.2 I 101 41-140 2-Chlorotoluene ug/L 20 20.1 101 70-130 2-Hexanone ug/L 40 46.8 117 48-145 4-Chlorotoluene ug/L 20 20.1 101 70-130 4-Methyl-2-pentanone (MIBK) ug/L 40 48.9 122 57-132 Acetone ug/L 40 48.2 120 46-148 Benzene ug/L 20 19.7 99 70-130 Bromobenzene ug/L 20 20.1 100 70-130 Bromochloromethane ug/L 20 19.0 95 70-130 Bromodichloromethane ug/L 20 18.4 92 70-130 Bromoform ug/L 20 17.3 87 49-126 Bromomethane ug/L 20 9.7 48 10-165 v2 Carbon disulfide ug/L 20 26.3 131 60-141 v1 Carbon tetrachloride ug/L 20 20.8 104 63-126 Chlorobenzene ug/L 20 19.2 96 70-130 Chloroethane ug/L 20 22.2 111 71-142 Chloroform ug/L 20 19.2 96 70-130 Chloromethane ug/L 20 16.2 81 40-140 v2 cis-1,2-Dichloroethene ug/L 20 19.3 96 70-130 cis-1,3-Dichloropropene ug/L 20 16.3 82 70-130 Dibromochloromethane ug/L 20 15.4 77 62-118 Dibromomethane ug/L 20 18.3 92 70-130 Dichlorodifluoromethane ug/L 20 20.2 101 47-150 Ethylbenzene ug/L 20 20.0 100 70-130 lodomethane ug/L 40 21.7 54 10-164 v2 Isopropylbenzene (Cumene) ug/L 20 19.6 98 70-130 m&p-Xylene ug/L 40 40.4 101 70-130 Methyl-tert-butyl ether ug/L 20 22.3 112 64-124 Methylene Chloride ug/L 20 18.2 91 65-136 n-Butylbenzene ug/L 20 20.5 102 70-130 n-Propylbenzene ug/L 20 21.2 106 70-130 o-Xylene ug/L 20 19.1 96 70-130 p-Isopropyltoluene ug/L 20 17.4 87 70-130 sec-Butylbenzene ug/L 20 20.6 103 70-130 Styrene ug/L 20 18.0 90 70-130 tert-Butylbenzene ug/L 20 20.7 103 70-130 Tetrachloroethene ug/L 20 19.7 98 64-134 Toluene ug/L 20 20.4 102 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/12/2019 09:06 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 38 /eAnaIyticaI wwwpacelabs.com fa QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451859 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE: 2812237 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers trans-1 ,2-Dichloroethene ug/L 20 19.7 98 68-127 trans-1,3-Dichloropropene ug/L 20 16.0 80 65-121 Trichloroethene ug/L 20 19.2 96 70-130 Trichlorofluoromethane ug/L 20 22.0 110 65-135 Vinyl acetate ug/L 20 24.4 122 60-144 Vinyl chloride ug/L 20 19.1 95 68-131 Xylene (Total) ug/L 60 59.5 99 70-130 1,2-Dichloroethane-d4 (S) % 101 70-130 4-Bromofluorobenzene (S) % 95 70-130 Toluene-d8 (S) % 99 70-130 MATRIX SPIKE SAMPLE: Parameter 2812239 35451633002 Spike MS MS % Rec Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 0.32 U 20 13.3 67 70-130 J(M1) 1,1,1-Trichloroethane ug/L 0.30 U 20 14.4 72 70-130 1,1,2,2-Tetrachloroethane ug/L 0.20 U 20 14.9 74 68-125 1,1,2-Trichloroethane ug/L 0.30 U 20 13.9 70 70-130 ',1-Dichloroethane ug/L 0.34 U 20 15.4 77 70-130 1,1-Dichloroethene ug/L 0.27 U 20 16.8 84 66-133 1,1-Dichloropropene ug/L 0.31 U 20 14.3 71 70-130 1,2,3-Trichlorobenzene ug/L 0.34 U 20 11.7 59 64-126 J(M1) 1,2,3-Trichloropropane ug/L 1.1 U 20 13.5 68 62-127 1,2,3-Trimethylbenzene ug/L 0.17 U 20 16.3 82 70-130 1,2,4-Trichlorobenzene ug/L 0.32 U 20 10.7 54 63-124 J(M1) 1,2,4-Trimethylbenzene ug/L 0.24 U 20 12.8 64 70-130 J(M1) 1,2-Dichlorobenzene ug/L 0.29 U 20 12.7 64 70-130 J(M1) 1,2-Dichloroethane ug/L 0.27 U 20 13.1 66 70-130 J(M1) 1,2-Dichloropropane ug/L 0.23 U 20 13.9 70 70-130 1,3,5-Trimethylbenzene ug/L 0.24 U 20 13.1 65 70-130 J(M1) 1,3-Dichlorobenzene ug/L 0.33 U 20 12.9 64 70-130 J(M1) 1,3-Dichloropropane ug/L 0.26 U 20 13.4 67 70-130 J(M1) 1,4-Dichlorobenzene ug/L 0.28 U 20 13.0 65 70-130 J(M1) 2,2-Dichloropropane ug/L 0.59 U 20 12.5 62 59-133 2-Butanone (MEK) ug/L 7.5 U 40 30.1 75 47-143 2-Chloroethylvinyl ether ug/L 1.4 U 20 1.4 U 0 41-140 J(M1) 2-Chlorotoluene ug/L 0.28 U 20 13.2 66 70-130 J(M1) 2-Hexanone ug/L 0.85 U 40 28.5 71 48-145 4-Chlorotoluene ug/L 0.22 U 20 13.3 66 70-130 J(M1) 4-Methyl-2-pentanone (MIBK) ug/L 0.32 U 40 0.32 U 0 57-132 J(M1) Acetone ug/L 5.3 U 40 36.7 82 46-148 Benzene ug/L 0.30 U 20 14.2 71 70-130 Bromobenzene ug/L 0.21 U 20 14.0 70 70-130 Bromochloromethane ug/L 0.37 U 20 13.8 69 70-130 J(M1) Bromodichloromethane ug/L 0.19 U 20 13.4 67 70-130 J(M1) Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:06 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 38 aceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451859 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 MATRIX SPIKE SAMPLE: 2812239 Parameter 35451633002 Spike MS MS % Rec Units Result Conc. Result % Rec Limits Qualifiers Bromoform ug/L 2.6 U 20 11.8 59 49-126 Bromomethane ug/L 4.0 U 20 9.1 46 10-165 v2 Carbon disulfide ug/L 0.45 U 20 22.6 113 60-141 v1 Carbon tetrachloride ug/L 1.1 U 20 15.4 77 63-126 Chlorobenzene ug/L 0.35 U 20 13.5 67 70-130 J(M1) Chloroethane ug/L 3.7 U 20 20.6 103 71-142 Chloroform ug/L 0.32 U 20 14.3 71 70-130 Chloromethane ug/L 0.97 U 20 14.1 70 40-140 v2 cis-1,2-Dichloroethene ug/L 0.27 U 20 14.1 71 70-130 cis-1,3-Dichloropropene ug/L 0.17 U 20 10.3 52 70-130 J(M1) Dibromochloromethane ug/L 0.45 U 20 10.2 51 62-118 J(M1) Dibromomethane ug/L 0.68 U 20 12.4 62 70-130 J(M1) Dichlorodifluoromethane ug/L 0.26 U 20 18.0 90 47-150 Ethylbenzene ug/L 0.30 U 20 13.5 68 70-130 J(M1) lodomethane ug/L 9.3 U 40 9.3 U 21 10-164 v2 Isopropylbenzene (Cumene) ug/L 0.30 U 20 12.2 61 70-130 J(M1) m&p-Xylene ug/L 2.1 U 40 27.0 68 70-130 J(M1) Methyl-tert-butyl ether ug/L 0.51 U 20 14.7 74 64-124 Methylene Chloride ug/L 2.0 U 20 14.4 72 65-136 n-Butylbenzene ug/L 0.20 U 20 12.4 62 70-130 J(M1) n-Propylbenzene ug/L 0.37 U 20 14.2 71 70-130 o-Xylene ug/L 0.27 U 20 11.7 59 70-130 J(M1) p-Isopropyltoluene ug/L 0.31 U 20 10.7 54 70-130 J(M1) sec-Butylbenzene ug/L 0.17 U 20 13.5 68 70-130 J(M1) Styrene ug/L 0.26 U 20 11.5 57 70-130 J(M1) tert-Butylbenzene ug/L 0.26 U 20 13.6 68 70-130 J(M1) Tetrachloroethene ug/L 0.38 U 20 12.8 64 64-134 Toluene ug/L 0.33 U 20 14.3 72 70-130 trans-1,2-Dichloroethene ug/L 0.23 U 20 14.8 74 68-127 trans-1,3-Dichloropropene ug/L 0.17 U 20 10.6 53 65-121 J(M1) Trichloroethene ug/L 0.36 U 20 13.4 67 70-130 J(M1) Trichlorofluoromethane ug/L 0.35 U 20 18.5 92 65-135 Vinyl acetate ug/L 0.19 U 20 15.3 76 60-144 Vinyl chloride ug/L 0.39 U 20 16.4 82 68-131 Xylene (Total) ug/L 2.1 U 60 38.8 65 70-130 MS 1,2-Dichloroethane-d4 (S) % 104 70-130 4-Bromofluorobenzene (S) % 90 70-130 Toluene-d8 (S) % 98 70-130 SAMPLE DUPLICATE: 2812238 35451633001 Dup Parameter Units Result Result RPD Max RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L 0.32 U 0.32 U 40 1,1,1-Trichloroethane ug/L 0.30 U 0.30 U 40 1,1,2,2-Tetrachloroethane ug/L 0.20 U 0.20 U 40 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/12/2019 09:06 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 38 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451859 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 SAMPLE DUPLICATE: 2812238 Parameter 35451633001 Dup Max Units Result Result RPD RPD Qualifiers 1,1,2-Trichloroethane ug/L 0.30 U 0.30 U 40 1,1-Dichloroethane ug/L 0.34 U 0.34 U 40 1,1-Dichloroethene ug/L 0.27 U 0.27 U 40 1,1-Dichloropropene ug/L 0.31 U 0.31 U 40 1,2,3-Trichlorobenzene ug/L 0.34 U 0.34 U 40 1,2,3-Trichloropropane ug/L 1.1 U 1.1 U 40 1,2,3-Trimethylbenzene ug/L 0.17 U 0.17 U 40 1,2,4-Trichlorobenzene ug/L 0.32 U 0.32 U 40 1,2,4-Trimethylbenzene ug/L 0.24 U 0.24 U 40 1,2-Dichlorobenzene ug/L 0.29 U 0.29 U 40 1,2-Dichloroethane ug/L 0.27 U 0.27 U 40 1,2-Dichloropropane ug/L 0.23 U 0.23 U 40 1,3,5-Trimethylbenzene ug/L 0.24 U 0.24 U 40 1,3-Dichlorobenzene ug/L 0.33 U 0.33 U 40 1,3-Dichloropropane ug/L 0.26 U 0.26 U 40 1,4-Dichlorobenzene ug/L 0.28 U 0.28 U 40 2,2-Dichloropropane ug/L 0.59 U 0.59 U 40 2-Butanone (MEK) ug/L 7.5 U 7.5 U 40 2-Chloroethylvinyl ether ug/L 1.4 U 1.4 U 40 2-Chlorotoluene ug/L 0.28 U 0.28 U 40 -Hexanone ug/L 0.85 U 0.85 U 40 4-Chlorotoluene ug/L 0.22 U 0.22 U 40 4-Methyl-2-pentanone (MIBK) ug/L 0.32 U 0.32 U 40 Acetone ug/L 5.3 U 5.3 U 40 Benzene ug/L 0.30 U 0.30 U 40 Bromobenzene ug/L 0.21 U 0.21 U 40 Bromochloromethane ug/L 0.37 U 0.37 U 40 Bromodichloromethane ug/L 0.19 U 0.19 U 40 Bromoform ug/L 2.6 U 2.6 U 40 Bromomethane ug/L 4.0 U 4.0 U 40 v2 Carbon disulfide ug/L 0.45 U 0.45 U 40 v1 Carbon tetrachloride ug/L 1.1 U 1.1 U 40 Chlorobenzene ug/L 0.35 U 0.35 U 40 Chloroethane ug/L 3.7 U 3.7 U 40 Chloroform ug/L 0.32 U 0.32 U 40 Chloromethane ug/L 0.97 U 0.97 U 40 v2 cis-1,2-Dichloroethene ug/L 0.27 U 0.27 U 40 cis-1,3-Dichloropropene ug/L 0.17 U 0.17 U 40 Dibromochloromethane ug/L 0.45 U 0.45 U 40 Dibromomethane ug/L 0.68 U 0.68 U 40 Dichlorodifluoromethane ug/L 0.26 U 0.26 U 40 Ethylbenzene ug/L 0.30 U 0.30 U 40 lodomethane ug/L 9.3 U 9.3 U 40 v2 Isopropylbenzene (Cumene) ug/L 0.30 U 0.30 U 40 m&p-Xylene ug/L 2.1 U 2.1 U 40 Methyl-tert-butyl ether ug/L 0.51 U 0.51 U 40 Methylene Chloride ug/L 2.0 U 2.0 U 40 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date. 03/12/2019 09:06 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 38 /72ceAnalytical® wwwpacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451859 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 SAMPLE DUPLICATE: 2812238 Parameter 35451633001 Dup Max Units Result Result RPD RPD Qualifiers n-Butylbenzene ug/L 0.20 U 0.20 U 40 n-Propylbenzene ug/L 0.37 U 0.37 U 40 o-Xylene ug/L 0.27 U 0.27 U 40 p-Isopropyltoluene ug/L 0.31 U 0.31 U 40 sec-Butylbenzene ug/L 0.17 U 0.17 U 40 Styrene ug/L 0.26 U 0.26 U 40 tert-Butylbenzene ug/L 0.26 U 0.26 U 40 Tetrachloroethene ug/L 0.38 U 0.38 U 40 Toluene ug/L 0.33 U 0.33 U 40 trans-1,2-Dichloroethene ug/L 0.23 U 0.23 U 40 trans-1,3-Dichloropropene ug/L 0.17 U 0.17 U 40 Trichloroethene ug/L 0.36 U 0.36 U 40 Trichlorofluoromethane ug/L 0.35 U 0.35 U 40 Vinyl acetate ug/L 0.19 U 0.19 U 40 Vinyl chloride ug/L 0.39 U 0.39 U 40 Xylene (Total) ug/L 2.1 U 2.1 U 40 1,2-Dichloroethane-d4 (S) % 103 104 0 40 4-Bromofluorobenzene (S) % 89 91 3 40 Y Toluene-d8 (S) % 100 100 0 40 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/12/2019 09:06 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 38 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451859 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 520947 Analysis Method: EPA 8081 QC Batch Method: EPA 3510 Analysis Description: 8081 GCS Pesticides Associated Lab Samples: 35451859001 METHOD BLANK: 2813016 Matrix: Water Associated Lab Samples: 35451859001 Parameter Blank Reporting Units Result Limit MDL Analyzed Qualifiers 4,4'-DDD ug/L 0.0089 U 0.010 0.0089 03/08/19 02:42 4,4'-DDE ug/L 0.0050 U 0.010 0.0050 03/08/19 02:42 4,4'-DDT ug/L 0.0050 U 0.010 0.0050 03/08/19 02:42 Aldrin ug/L 0.0015 U 0.010 0.0015 03/08/19 02:42 alpha-BHC ug/L 0.0021 U 0.010 0.0021 03/08/19 02:42 beta-BHC ug/L 0.0080 U 0.010 0.0080 03/08/19 02:42 Chlordane (Technical) ug/L 0.18 U 0.50 0.18 03/08/19 02:42 delta-BHC ug/L 0.0048 U 0.010 0.0048 03/08/19 02:42 Dieldrin ug/L 0.0020 U 0.010 0.0020 03/08/19 02:42 Endosulfan I ug/L 0.0051 U 0.010 0.0051 03/08/19 02:42 Endosulfan II ug/L 0.0040 U 0.010 0.0040 03/08/19 02:42 Endosulfan sulfate ug/L 0.0062 U 0.10 0.0062 03/08/19 02:42 Endrin ug/L 0.0043 U 0.010 0.0043 03/08/19 02:42 Endrin aldehyde ug/L 0.0036 U 0.10 0.0036 03/08/19 02:42 -ndrin ketone ug/L 0.0050 U 0.010 0.0050 03/08/19 02:42 jamma-BHC (Lindane) ug/L 0.0022 U 0.010 0.0022 03/08/19 02:42 Heptachlor ug/L 0.0062 U 0.010 0.0062 03/08/19 02:42 Heptachlor epoxide ug/L 0.0052 U 0.010 0.0052 03/08/19 02:42 Methoxychlor ug/L 0.0096 U 0.010 0.0096 03/08/19 02:42 Toxaphene ug/L 0.25 U 0.50 0.25 03/08/19 02:42 Decachlorobiphenyl (S) % 48 10-132 03/08/19 02:42 Tetrachloro-m-xylene (S) % 67 27-124 03/08/19 02:42 LABORATORY CONTROL SAMPLE & LCSD: 2813017 2813251 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers 4,4'-DDD ug/L 0.5 0.50 0.52 99 103 67-133 4 40 4,4'-DDE ug/L 0.5 0.48 0.50 96 100 59-125 3 40 4,4'-DDT ug/L 0.5 0.51 0.52 102 104 54-132 2 40 Aldrin ug/L 0.5 0.43 0.44 87 88 25-116 2 40 alpha-BHC ug/L 0.5 0.51 0.54 102 109 53-126 6 40 beta-BHC ug/L 0.5 0.51 0.53 101 107 62-130 5 40 delta-BHC ug/L 0.5 0.47 0.52 95 104 35-122 10 40 Dieldrin ug/L 0.5 0.56 0.59 112 118 66-128 5 40 Endosulfan I ug/L 0.5 0.49 0.51 97 102 67-125 4 40 Endosulfan II ug/L 0.5 0.44 0.47 89 95 67-131 7 40 Endosulfan sulfate ug/L 0.5 0.44 0.48 88 96 62-127 9 40 Endrin ug/L 0.5 0.55 0.58 110 115 66-130 5 40 Endrin aldehyde ug/L 0.5 0.45 0.51 90 102 61-124 12 40 Endrin ketone ug/L 0.5 0.46 0.49 91 98 65-132 7 40 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/12/2019 09:06 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 38 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451859 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE & LCSD: 2813017 2813251 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers gamma-BHC (Lindane) ug/L 0.5 0.54 0.57 108 115 58-127 6 40 Heptachlor ug/L 0.5 0.45 0.48 90 95 35-123 5 40 Heptachlor epoxide ug/L 0.5 0.51 0.53 102 106 62-125 4 40 Methoxychlor ug/L 0.5 0.48 0.50 96 101 59-135 4 40 Decachlorobiphenyl (S) % 47 46 10-132 Tetrachloro-m-xylene (S) % 74 74 27-124 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:06 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 38 (eAnaIYticaI wwwpacelabscom QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451859 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521006 Analysis Method: EPA 8270 by SIM QC Batch Method: EPA 3510 Analysis Description: 8270 Water PAHLV by SIM MSSV Associated Lab Samples: 35451859001 METHOD BLANK: 2813544 Matrix: Water Associated Lab Samples: 35451859001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1-Methylnaphthalene ug/L 0.19 U 2.0 0.19 03/07/19 08:37 2-Methylnaphthalene ug/L 0.68 U 2.0 0.68 03/07/19 08:37 Acenaphthene ug/L 0.040 U 0.50 0.040 03/07/19 08:37 Acenaphthylene ug/L 0.030 U 0.50 0.030 03/07/19 08:37 Anthracene ug/L 0.043 U 0.50 0.043 03/07/19 08:37 Benzo(a)anthracene ug/L 0.055 U 0.10 0.055 03/07/19 08:37 Benzo(a)pyrene ug/L 0.12 U 0.20 0.12 03/07/19 08:37 Benzo(b)fluoranthene ug/L 0.027 U 0.10 0.027 03/07/19 08:37 Benzo(g,h,i)perylene ug/L 0.15 U 0.50 0.15 03/07/19 08:37 Benzo(k)fluoranthene ug/L 0.16 U 0.50 0.16 03/07/19 08:37 Chrysene ug/L 0.026 U 0.50 0.026 03/07/19 08:37 Dibenz(a,h)anthracene ug/L 0.13 U 0.15 0.13 03/07/19 08:37 Fluoranthene ug/L 0.018 U 0.50 0.018 03/07/19 08:37 Fluorene ug/L 0.088 U 0.50 0.088 03/07/19 08:37 ideno(1,2,3-cd)pyrene ug/L 0.12 U 0.15 0.12 03/07/19 08:37 Japhthalene ug/L 0.29 U 2.0 0.29 03/07/19 08:37 Phenanthrene ug/L 0.16 U 0.50 0.16 03/07/19 08:37 Pyrene ug/L 0.032 U 0.50 0.032 03/07/19 08:37 2-Fluorobiphenyl (S) % 63 33-82 03/07/19 08:37 p-Terphenyl-d14 (S) % 102 49-104 03/07/19 08:37 LABORATORY CONTROL SAMPLE: 2813545 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1-Methylnaphthalene ug/L 5 3.3 66 40-96 2-Methylnaphthalene ug/L 5 3.3 65 40-94 Acenaphthene ug/L 5 3.2 65 42-96 Acenaphthylene ug/L 5 3.2 63 39-90 Anthracene ug/L 5 3.7 75 46-109 Benzo(a)anthracene ug/L 5 4.1 83 50-116 Benzo(a)pyrene ug/L 5 4.1 83 48-117 Benzo(b)fluoranthene ug/L 5 4.2 85 51-124 Benzo(g,h,i)perylene ug/L 5 4.1 83 47-121 Benzo(k)fluoranthene ug/L 5 4.4 88 50-125 Chrysene ug/L 5 4.4 87 53-122 Dibenz(a,h)anthracene ug/L 5 4.0 80 45-123 Fluoranthene ug/L 5 4.5 90 52-119 Fluorene ug/L 5 3.4 68 44-100 Indeno(1,2,3-cd)pyrene ug/L 5 4.0 79 46-121 Naphthalene ug/L 5 3.2 64 40-91 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:06 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 38 aceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451859 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE: 2813545 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phenanthrene ug/L 5 3.7 73 47-111 Pyrene ug/L 5 4.4 88 51-120 2-Fluorobiphenyl (S) % 71 33-82 p-Terphenyl-d14 (S) % 98 49-104 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2813901 2813902 MS MSD 35452061003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1-Methylnaphthalene ug/L 0.19 U 5 5 3.1 3.1 62 62 40-96 1 40 2-Methylnaphthalene ug/L 0.68 U 5 5 3.2 3.1 64 61 40-94 4 40 Acenaphthene ug/L 0.040 U 5 5 3.0 3.2 60 63 42-96 4 40 Acenaphthylene ug/L 0.030 U 5 5 2.9 3.0 58 61 39-90 4 40 Anthracene ug/L 0.043 U 5 5 3.7 3.9 74 78 46-109 5 40 Benzo(a)anthracene ug/L 0.055 U 5 5 4.0 4.2 81 83 50-116 3 40 Benzo(a)pyrene ug/L 0.12 U 5 5 4.0 4.0 81 79 48-117 2 40 Benzo(b)fluoranthene ug/L 0.027 U 5 5 4.0 4.0 81 80 51-124 1 40 Benzo(g,h,i)perylene ug/L 0.15 U 5 5 4.0 3.8 79 77 47-121 3 40 Benzo(k)fluoranthene ug/L 0.16 U 5 5 4.2 4.1 84 82 50-125 2 40 Chrysene ug/L 0.026 U 5 5 4.2 4.2 84 85 53-122 1 40 Dibenz(a,h)anthracene ug/L 0.13 U 5 5 3.9 3.7 77 74 45-123 4 40 Fluoranthene ug/L 0.018 U 5 5 4.5 4.7 89 94 52-119 5 40 Fluorene ug/L 0.088 U 5 5 3.2 3.4 65 69 44-100 5 40 Indeno(1,2,3-cd)pyrene ug/L 0.12 U 5 5 3.9 3.7 77 75 46-121 3 40 Naphthalene ug/L 0.29 U 5 5 2.9 2.9 58 58 40-91 0 40 Phenanthrene ug/L 0.16 U 5 5 3.7 3.8 73 77 47-111 4 40 Pyrene ug/L 0.032 U 5 5 4.4 4.5 87 91 51-120 4 40 2-Fluorobiphenyl (S) % 68 70 33-82 p-Terphenyl-d14 (S) % 97 98 49-104 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:06 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 38 ceAnalytical® www.paceiabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451859 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521011 Analysis Method: FL -PRO QC Batch Method: EPA 3510 Analysis Description: FL -PRO Water Low Volume Associated Lab Samples: 35451859001 METHOD BLANK: 2813560 Matrix: Water Associated Lab Samples: 35451859001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Petroleum Range Organics mg/L 0.80 U 1.0 0.80 03/07/19 12:40 N-Pentatriacontane (S) % 86 42-159 03/07/19 12:40 o-Terphenyl (S) % 79 66-139 03/07/19 12:40 LABORATORY CONTROL SAMPLE: 2813561 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Petroleum Range Organics mg/L N-Pentatriacontane (S) o-Terphenyl (S) 5 4.4 87 66-119 99 42-159 94 66-139 MATRIX SPIKE SAMPLE: 2814271 35452019001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Petroleum Range Organics mg/L 0.73 U 4.6 3.9 80 65-123 N-Pentatriacontane (S) % 89 42-159 o-Terphenyl (S) % 90 66-139 SAMPLE DUPLICATE: 2814272 35451859001 Dup Parameter Units Result Result RPD Max RPD Qualifiers Petroleum Range Organics mg/L 0.79 U 0.77 U N-Pentatriacontane (S) % 97 91 o-Terphenyl (S) % 81 89 9 7 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/12/2019 09:06 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 21 of 38 aceAnalytical® www.pacelabs.com QUALIFIERS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451859 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: 520947 [M5] A matrix spike/matrix spike duplicate was not performed for this batch due to insufficient sample volume. ANALYTE QUALIFIERS The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. U Compound was analyzed for but not detected. 1 p A matrix spike/matrix spike duplicate was not performed for this batch due to insufficient sample volume. J(M1) Estimated Value. Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. MS Analyte recovery in the matrix spike was outside QC limits for one or more of the constituent analytes used in the calculated result. Y The laboratory analysis was from an improperly preserved sample. c2 Acid preservation may not be appropriate for the analysis of 2-Chloroethylvinyl ether. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. Date: 03/12/2019 09:06 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 22 of 38 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451859 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID QC Batch Method Analytical QC Batch Analytical Method Batch 35451859001 MW-39 EPA 3510 520947 EPA 8081 521160 35451859001 MW-39 EPA 3510 521011 FL -PRO 521222 35451859001 MW-39 EPA 3010 521178 EPA 6010 521271 35451859001 MW-39 EPA 7470 521100 EPA 7470 521259 35451859001 MW-39 EPA 3510 521006 EPA 8270 by SIM 521083 35451859001 MW-39 EPA 8260 520786 Date: 03/12/2019 09:06 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 38 2eAnalytical WO#:35451669 Request Document -elevant fields must be completed accurately. Seaton A Section B 5451859 Required Client Information: Required Project Information: tf -1• Page : 1 Of Company EERG Environmental Services. LLC Report To=1111;021!trL kt Lafit ice` Address 5751 Miami Lakes Dr. Copy To 11f'Q.i G'{ve�gje_i \ Company Name Hialeah, FL 33014 - L..) Address Regulatory Agency Email mr ,grr, M n e,Pk,„_,„AI. caa^ Purchase Order #. .„t e, /' - L)C C � Pace Quote - Phone' (305)37,1-8300lax `J jam\ Project Name ` �' e„k 7e S Pace Project Manager. 1 9 chrislina.raschke(alpacelabs.com, /'. State / Location 1.f� Requested Due Date. _:,,,a.,�� ,,' , �-1 Project #: 2018-3U5/ Pace Profile # / FL Requ a`X Filtered (Y/N) W MATRIX Cone Onnk,nq Wow ow Water wr wa.ta Water ww SAMPLE ID ollSod/Solid a One Character per box. wipe WP Ad , AR O-S I -)- 0re, O le Ids must be unique rluar Ts MATRIX CODE (see valid codes to left) SAMPLE TYPE (G=GRAB C=COMP) COLLECTED SAMPLE TEMP AT COLLECTION a w Z 0 0 O >< Preservatives Z % �' S _ t) J START END LInpreserved v O N T.'. ZO _',7-4'h U _✓ HOeN Na2S2O3 Methanol Other Analyses Test 8260 VOC PAH by 8270 SIM TRPH FL -PRO l Pesticides 8081(0„v„, Pesticides 8141( y Herbicides 8151(67 l, .` cn Q CV cSam 0 6010131, Cd, Cr, Se, Ag, 7470 Hg ?vbI,fie. . G • — ",z (1(A-Zr 2 Residual Chlorine (Y/N) DATE TIME DATE TIME 1 v�� 71 3. i4'{r1`I I )`"( �U ��// 1� ,_1 I` �_/ )"' '. , ✓ 74 '/ .' 7` ,/ l� c� '- `� J" 2 3 4 5 6 7 8 9 10 11 12 ADDITIONAL COMMENTS - RELINQUISHED B/Y I AFFILIATION{ .{ . DALE TIME AGCEPTED BY l AFFILIATION / DATE TIME SA�M$I PLE CONDj�,I\TI�ONS ,�Ij /_ �/ GYl r� T'" l' C: '4 N J (? /' ! �', C _ /rye s 0'—r /I, ! % / �, 1. j �' ( it f �' ;Jti )11 i CI 174'J (C. ! I �/ ICJ, f v/ TEMP in C SAMPLER NAME AND SIGNATURE . c ro > 1,1 ml j m o-- v m m PRINT Name of SAMPLER: i A(/ , / c) `ll . -L:)‘1 tt...` SIGNATURE of SAMPLER: .f/i r) ( DATE Signed: ...7d Page 24 of 38 ace AnaJytiCa/ :. ,. Document Name Sample Condition Upon Receipt Forte- Document Revised May 30, 2018 Document No F-FL-C-007 rev 13 Issuing Authority Pace Florida Quality Office Wp :35451859 Project — PM: CTR Project ManageCLIENT: 36-EEG Clien Due Date: 03/12/19 Thermometer Used (�� Date State of rigs P� Cooler #1 Temp.°C J (Visual) (Correction Factor) 3, s (Actual) Cooler #2 Temp.°C (Visual) 0 0 (Correction Factor) w° 0 (Actual) Cooler #3 Temp.'C 5.5 (Visual) 0 _0 (Correction Factor) 5 .5 (Actual) Cooler #4 Temp.'C Samples shorted to lab (If Yes, complete) (Visual) Cooler #5 Temp.°C (Visual) Cooler #6 Temp.°C (Visual) Courier: Fed Ex (Correction Factor) (Correction Factor) (Correction Factor) (Actual) (Actual) (Actual) UPS ❑ USPS —' Client LL3 Commercial) Pace Shipping Method: = First Overnight I Priority Overnight _ Standard Overnight Other Billing: - Recipient Tracking # Sender Custody Seal on Cooler/Box Present: DV- es Third Party L Ground L Credit Card Seals intact: ri Yes D Packing Material: ❑Bubble Wrap ubble Bags L JNone [Other Shorted Date. I Shorted Time izmtamimmmimm Date and Initials of p Examining content: Label: Deliver pH: Time. 1,71 For }ASV projects, all containers verified to 58 `C Samples on ice, cooking process has begun Samples on ice, cooling process has begun �Samoles on ice, cooling process has begun E Samples on ice, cooling process has begun Samples on ice, cooling process has begun L Samples on ice, cooling process has begun Other International Priority Unknown Corments: lue Dry None -- Chain of Custody Present _ es _0 No `N/A Chain of Custody Filled Out s i.1 No uN/A Relinquished Signature & Sampler Name COC _ e�D No LN/A ms Samples Arrived within Hold Time s 0 No ❑N/A vYe Rush TAT requested on COC ❑ Yes N/A Sufficient Volume �y,:xes D No uN/A Correct Containers Used - es Di No ON/A Containers Intact yYet D No ❑N/A Sample Labels match COC (sample IDs & date/time of collection) _ 0' No ❑N/A All containers needing acid/base preservation have been checked. checked. ,,,'r = No ❑N/A All Containers needing preservation are found to be in compliance with EPA recommendation• ,ems =• No LN/A Exceptions. VOA, Coliform, TOC, O&G, Carbamates Preservation Information - Preservative Lot #/Trace # ° Date. l it Initials Headspace in VOA Vials? ( >6mm): OYes 0 No Trip Blank Present: LYes O No + Client Notification/ Resolution: Person Contacted Comments/ Resolution (use back for additional comments): Date/Time: Project Manager Review: Date Page 25 of 38 /eAnaIyticaI National Center for Testing & Innovation A\ALYTI CAL March 12, 2019 R -PORT Pace Analytical - Pompano Beach, FL Sample Delivery Group: L1076238 Samples Received: 03/07/2019 Project Number: 35451859 Description: 2018-3057Melreese golf course Site: 001 Report To: Christina Raschke 3610 Park Central Blvd N Pompano Beach, FL 33064 Entire Report Reviewed By: Jason Romer Project Manager Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable. sampling conducted by Pace National is performed per guidance provided in laboratory standard operating procedures: 060302, 060303, and 060304. 12065 Lebanon Rd Mount Juliet, TN 37122 615-758-5858 800-767-5859 www.pacenational.com TABLE OF CONTENTS ONE LAB. NATIONWIDE. Cp: Cover Page Tc: Table of Contents 2 Ss: Sample Summary 3 Cn: Case Narrative 4 Sr: Sample Results 5 MW-39 L1076238-01 5 Qc: Quality Control Summary 6 Chlorinated Acid Herbicides (GC) by Method 8151 6 OP Pesticides by Method 8141 7 GI: Glossary of Terms 10 AI: Accreditations & Locations 11 Sc: Sample Chain of Custody 12 ACCOUNT: Pace Analytical - Pompano Beach, FL Cp z Tc Ss a Cn 6 Qc GI Al Page 27 of 38 PROJECT: SDG: DATE/TIME: PAGE: 35451859 L1076238 03/12/1915:52 2 of 13 SAMPLE SUMMARY ONE LAB. NATIONWIDE.alik MW-39 L1076238-01 GW Collected by Collected date time Received date/time 3 3/04/1913:04 0307/19 09:00 Method Chlorinated Acid Herbicides (GC) by Method 8151 OP Pesticides by Method 8141 ACCOUNT: Pace Analytical - Pompano Beach, FL Batch Dilution Preparation Analysis Analyst Location date/time date/time WG1247068 1 03/08/19 08:07 03/09/19 02:43 KLM Mt. Juliet, TN WG1246727 1 03/07/19 18:03 03/11/19 20:15 HMH Mt. Juliet, TN �l Ss a Cn 6 Qc GI Al Cr Page 28 of 38 PROJECT: SDG: DATE/TIME: PAGE: 35451859 L1076238 03/12/19 15:52 3 of 13 CASE NARRATIVE ONE LAB. NATIONWIDE. 41, All sample aliquots were received at the correct temperature, in the proper containers, with the appropriate preservatives, and within method specified holding times, unless qualified or notated within the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data. Jason Romer Project Manager ACCOUNT: Pace Analytical - Pompano Beach, FL Cp Ss Cn 5 Sr 6 Qc GI Al Page 29 of 38 PROJECT: SDG: DATE/TIME: PAGE: 35451859 L1076238 03/12/1915:52 4 of 13 MW-39 Collected date/time: 03/04/19 13:04 SAMPLE RESULTS - 01 L1076238 ONE LAB. NATIONWIDE. .10 Chlorinated Acid Herbicides (GC) by Method 8151 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time 2,4-D 0.744 U 0.744 2.00 1 03/09/2019 02:43 WG1247068 Dalapon 1.04 U 1.04 2.00 1 03/09/2019 02:43 WG1247068 2,4-DB 0.775 U 0.775 4.00 1 03/09/2019 02:43 WG1247068 Dicamba 0.813 U 0.813 2.00 1 03/09/2019 02:43 WG1247068 Dichloroprop 0.778 U 0.778 2.00 1 03/09/2019 02:43 WG1247068 Dinoseb 0.795 U 0.795 2.00 1 03/09/2019 02:43 WG1247068 MCPA 13.1 J U 13.1 200 1 03/09/2019 02:43 WG1247068 MCPP 7.15 U 7.15 200 1 03/09/2019 02:43 WG1247068 2,4,5-7 0.843 U 0.843 2.00 1 03/09/2019 02:43 WG1247068 2,4,5-TP (Silvex) 0.845 U 0.845 2.00 1 03/09/2019 02:43 WG1247068 (S)2,4-Dichlorophenyl Acetic 62.8 14.0-158 03/09/2019 02:43 WG1247068 Acid OP Pesticides by Method 8141 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date/time Azinphos-Methyl 0.348 U 0.348 1.00 1 03/11/2019 20:15 WG1246727 Bolstar (Sulprofos) 0.205 U 0.205 1.00 1 03/11/2019 20:15 WG1246727 Chlorpyrifos 0.245 U 0.245 1.00 1 03/11/2019 20:15 WG1246727 Coumaphos 0.277 U 0.277 1.00 1 03/11/2019 20:15 WG1246727 Demeton,-0 and -S 0.341 J U 0.341 2.00 1 03/11/2019 20:15 WG1246727 Diazinon 0.377 U 0.377 1.00 1 03/11/2019 20:15 WG1246727 Dichlorvos 0.212 U 0.212 2.00 1 03/11/2019 20:15 WG1246727 Dimethoate 0.105 U 0.105 1.00 1 03/11/2019 20:15 WG1246727 Disulfoton 0.277 U 0.277 1.00 1 03/11/2019 20:15 WG1246727 EPN 0.261 J U 0.261 1.00 1 03/11/2019 20:15 WG1246727 Ethoprop 0.354 U 0.354 1.00 1 03/11/2019 20:15 WG1246727 Ethyl Parathion 0.292 J U 0.292 1.00 1 03/11/2019 20:15 WG1246727 Fensulfothion 0.130 U 0.130 1.00 1 03/11/2019 20:15 WG1246727 Fenthion 0.266 U 0.266 1.00 1 03/11/2019 20:15 WG1246727 Malathion 0.173 U 0.173 1.00 1 03/11/2019 20:15 WG1246727 Merphos 0.267 U 0.267 2.00 1 03/11/2019 20:15 WG1246727 Methyl parathion 0.257 J U 0.257 1.00 1 03/11/2019 20:15 WG1246727 Mevinphos 0.118 U 0.118 1.00 1 03/11/201920:15 WG1246727 Naled 0.289 J U 0.289 1.00 1 03/11/2019 20:15 WG1246727 Phorate 0.282 U 0.282 1.00 1 03/11/2019 20:15 WG1246727 Ronne) 0.252 U 0.252 1.00 1 03/11/2019 20:15 WG1246727 Stirophos 0.226 U 0.226 1.00 1 03/11/2019 20:15 WG1246727 Sulfotep 0.202 U 0.202 1.00 1 03/11/2019 20:15 WG1246727 TEPP 9.74 J U 9.74 20.0 1 03/11/2019 20:15 WG1246727 Tokuthion (Prothothiofos) 0.254 U 0.254 1.00 1 03/11/2019 20:15 WG1246727 Trichloronate 0.213 U 0.213 1.00 1 03/11/2019 20:15 WG1246727 (5)Triphenyl Phosphate 79.8 42.0-129 03/11/2019 20:15 WG1246727 ACCOUNT: Pace Analytical - Pompano Beach, FL SS 4 Cn 5 Sr Oc GI Al Page 30 of 38 PROJECT: SDG: DATE/TIME: PAGE: 35451859 L1076238 03/12/1915:52 5 of 13 WG12 168 QUALITY COS -'OL SUMMARY ONE LAB. h'"'?,NWIDE.410 Chlorinated ..id Herbicides (GC) by Method 8151 Liu ,8-01 Method Blank (MB) (MB) R3390374-1 03/09/19 01:08 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I 2,4-D 0.744 U 0.744 2.00 Dalapon 1.04 U 1.04 2.00 2,4-DB 0.775 U 0.775 4.00 Dicamba 0.813 U 0.813 2.00 Dichloroprop 0.778 U 0.778 2.00 Dinoseb 0.795 U 0.795 2.00 MCPA 13.1 U 13.1 200 MCPP 7.15 U 7.15 200 2,4,5-T 0.843 U 0.843 2.00 2,4,5-TP (Silvex) 0.845 U 0.845 2.00 (S)2,4-Dichloropheny/Acetic 66.2 14.0-158 Acid Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3390374-2 03/09/19 01:22 • (LCSD) R3390374-3 03/09/19 01:35 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I % % % % % 2,4-D 5.00 3.28 3.31 65.6 66.2 50.0-120 0.910 20 Dalapon 5.00 2.64 2.67 52.8 53.4 32.0-120 1.13 20 2,4-DB 5.00 3.73 4.10 74.6 82.0 53.0-140 P 9.45 20 Dicamba 5.00 3.49 3.50 69.8 70.0 51.0-120 0.286 20 Dichloroprop 5.00 3.26 3.30 65.2 66.0 55.0-127 1.22 20 Dinoseb 5.00 2.21 2.18 44.2 43.6 36.0-134 1.37 20 MCPA 50.0 232 193 464 386 10.0-160 J L P J L 18.4 40 MCPP 50.0 19.9 20.5 39.8 41.0 10.0-160 2.97 23 2,4,5-T 5.00 3.72 3.69 74.4 73.8 54.0-120 0.810 20 2,4,5-TP (Silvex) 5.00 3.69 3.68 73.8 73.6 50.0-125 0.271 20 (S) 2,4-Dichlorophenyl Acetic Acid ACCOUNT: Pace Analytical- Pompano Beach, FL 62.8 60.8 14.0-158 C p 3SS 4 Cn 6 Qc GI Al Page 31 of 38 PROJECT: SDG: DATE/TIME: PAGE: 35451859 L1076238 03/12/19 15:52 6 of 13 WG1246727 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. AO OP Pesticides by Method 8141 L1076238-01 Method Blank (MB) (MB) R3390660-1 03/11/19 11:42 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I Azinphos-Methyl 0.348 U 0.348 1.00 Bolstar (Sulprofos) 0.205 U 0.205 1.00 Chlorpyrifos 0.245 U 0.245 1.00 Coumaphos 0.277 U 0.277 1.00 Demeton,-0 and -S 0.341 U 0.341 2.00 Diazinon 0.377 U 0.377 1.00 Dichlorvos 0.212 U 0.212 2.00 Dimethoate 0.105 U 0.105 1.00 Disulfoton 0.277 U 0.277 1.00 EPN 0.261 U 0.261 1.00 Ethoprop 0.354 U 0.354 1.00 Ethyl Parathion 0.292 U 0.292 1.00 Fensulfothion 0.130 U 0.130 1.00 Fenthion 0.266 U 0.266 1.00 Malathion 0.173 U 0.173 1.00 Merphos 0.267 U 0.267 2.00 Methyl parathion 0.257 U 0.257 1.00 Mevinphos 0.118 U 0.118 1.00 Naled 0.289 U 0.289 1.00 Phorate 0.282 U 0.282 1.00 Ronnel 0.252 U 0.252 1.00 Stirophos 0.226 U 0.226 1.00 Sulfotep 0.202 U 0.202 1.00 TEPP 9.74 U 9.74 20.0 Tokuthion (Prothothiofos) 0.254 U 0.254 1.00 Trichloronate 0.213 U 0.213 1.00 (5) Tnphenyl Phosphate 56.4 42.0-129 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3390660-2 03/11/19 12:45 • (LCSD) R3390660-3 03/11/19 13:17 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I % % % % % Azinphos-Methyl 5.00 3.70 4.38 74.0 87.6 43.0-142 16.8 20 Bolstar (Sulprofos) 5.00 3.58 4.03 71.6 80.6 47.0-128 11.8 20 Chlorpyrifos 5.00 3.62 4.26 72.4 85.2 50.0-126 16.2 20 Coumaphos 5.00 3.85 4.40 77.0 88.0 37.0-137 P P 13.3 20 Demeton,-0 and -S 2.50 ND ND 0.000 0.000 22.0-150 J J 0.000 24 Diazinon 5.00 4.14 4.41 82.8 88.2 54.0-130 6.32 20 ACCOUNT: I-o,e Analytical - Pompano Beach, FL PROJECT: 35451859 SDG: L1076238 DATE/TIME: 03/12/1915:52 1Cp 3 SS 1 Cn 6 QC GI Al '".ge 32 of 38 AGE: 7of13 WG12 727 QUALITY COr ROL SUMMARY ONE LAB. `7)NWIDE. .40 OP Pestich. by Method 8141 L1L .38-01 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3390660-2 03/11/19 12:45 • (LCSD) R3390660-3 03/11/19 13:17 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I % % % % % Dichlorvos 5.00 3.88 4.38 77.6 87.6 43.0-135 12.1 24 Dimethoate 5.00 2.17 2.80 43.4 56.0 27.0-120 25.4 27 Disulfoton 5.00 3.59 4.10 71.8 82.0 44.0-136 13.3 21 EPN 5.00 8.45 9.01 169 180 31.0-143 J J 6.41 21 Ethoprop 5.00 3.76 4.05 75.2 81.0 52.0-130 7.43 20 Ethyl Parathion 5.00 7.36 8.02 147 160 42.0-134 J J 8.58 20 Fensulfothion 5.00 3.79 4.36 75.8 87.2 42.0-137 14.0 20 Fenthion 5.00 3.44 4.03 68.8 80.6 53.0-133 P 15.8 20 Malathion 5.00 3.29 3.56 65.8 71.2 47.0-121 7.88 20 Merphos 5.00 3.48 4.14 69.6 82.8 14.0-123 17.3 25 Methyl parathion 5.00 4.92 6.10 98.4 122 43.0-135 J 21.4 20 Mevinphos 5.00 3.57 4.33 71.4 86.6 49.0-123 19.2 23 Naled 5.00 5.47 7.24 109 145 25.0-126 J 27.9 26 Phorate 5.00 3.60 3.74 72.0 74.8 44.0-129 3.81 20 Ronnel 5.00 3.42 3.93 68.4 78.6 51.0-125 13.9 20 Stirophos 5.00 3.77 4.61 75.4 92.2 53.0-125 20.0 20 Sulfotep 5.00 3.87 4.40 77.4 88.0 40.0-140 12.8 22 TEPP 50.0 17.6 34.2 35.2 68.4 18.0-122 J 64.1 32 Tokuthion (Prothothiofos) 5.00 3.59 4.14 71.8 82.8 50.0-128 14.2 20 Trichloronate 5.00 3.74 4.26 74.8 85.2 47.0-130 13.0 21 (S) Tripheny/ Phosphate 68.0 74.6 42.0-129 L1075936-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1075936-01 03/11/19 14:52 • (MS) R3390660-4 03/11/19 15:24 • (MSD) R3390660-5 03/11/19 15:55 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I ug/I % % % % % Azinphos-Methyl 5.00 0.348 3.50 3.62 70.0 72.4 1 29.0-157 3.37 20 Bolster (Sulprofos) 5.00 0.205 3.33 3.39 66.6 67.8 1 37.0-138 1.79 20 Chlorpyrifos 5.00 0.245 3.63 3.62 72.6 72.4 1 42.0-131 0.276 20 Coumaphos 5.00 0.277 3.74 3.57 74.8 71.4 1 31.0-150 P P 4.65 20 Demeton,-0 and -S 2.50 0.341 0.341 0.341 0.000 0.000 1 30.0-152 J U J U 0.000 20 Diazinon 5.00 0.377 4.06 4.04 81.2 80.8 1 47.0-134 0.494 20 Dichlorvos 5.00 0.212 3.92 3.65 78.4 73.0 1 39.0-140 7.13 22 Dimethoate 5.00 0.105 2.54 2.39 50.8 47.8 1 17.0-129 6.09 20 Disulfoton 5.00 0.277 3.45 3.42 69.0 68.4 1 42.0-131 0.873 21 EPN 5.00 0.261 8.45 8.23 169 165 1 17.0-155 J J P 2.64 20 Ethoprop 5.00 0.354 3.68 3.13 73.6 62.6 1 46.0-133 16.2 20 Ethyl Parathion 5.00 0.292 7.11 7.22 142 144 1 30.0-138 J P J P 1.54 20 ACCOUNT: Pace Analytical - Pompano Beach, FL Cp 3SS 4 Cn Sr 6 QC GI Al Sc Page 33 of 38 PROJECT: SDG: DATE/TIME: PAGE: 35451859 L1076238 03/12/19 15:52 8 of 13 WG1246727 QUALITY CONTROL SUMMARY OP Pesticides by Method 8141 L1076238-01 ONE LAB. NATIONWIDE. 40 L1075936-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1075936-01 03/11/19 14:52 • (MS) R3390660-4 03/11/19 15:24 • (MSD) R3390660-5 03/11/19 15:55 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I ug/I % % % % % Fensulfothion 5.00 0.130 3.68 3.94 73.6 78.8 1 36.0-145 6.82 20 Fenthion 5.00 0.266 3.44 3.43 68.8 68.6 1 46.0-140 P P 0.291 20 Malathion 5.00 0.173 3.69 3.19 73.8 63.8 1 39.0-126 14.5 20 Merphos 5.00 0.267 2.97 2.82 59.4 56.4 1 10.0-120 5.18 27 Methyl parathion 5.00 0.257 4.89 4.98 97.8 99.6 1 28.0-142 1.82 20 Mevinphos 5.00 0.118 3.61 3.39 72.2 67.8 1 38.0-134 6.29 20 Naled 5.00 0.289 5.51 5.11 110 102 1 14.0-130 7.53 20 Phorate 5.00 0.282 3.44 3.33 68.8 66.6 1 38.0-134 3.25 20 Ronnel 5.00 0.252 3.58 3.21 71.6 64.2 1 42.0-131 10.9 20 Stirophos 5.00 0.226 3.89 3.63 77.8 72.6 1 33.0-143 6.91 20 Sulfotep 5.00 0.202 3.98 3.72 79.6 74.4 1 34.0-143 6.75 20 TEPP 50.0 9.74 30.9 38.7 61.8 77.4 1 38.0-120 22.4 25 Tokuthion (Prothothlofos) 5.00 0.254 3.58 3.48 71.6 69.6 1 35.0-140 2.83 24 Trichloronate 5.00 0.213 3.89 3.58 77.8 71.6 1 41.0-133 8.30 20 (S) Tripheny/ Phosphate 67.4 66.0 42.0-129 ACCOUNT: Pace Analytical - Pompano Beach, FL Cp 2 Tc 3S5 4 Cn Sr 6 Qc 7 GI Al Sc age 34 of 38 PROJECT: SDG: DATE/TIME: AGE: 35451859 L1076238 03/12/19 15:52 9 of 13 GLOSSARY OF TERMS ONE LAB. NATIONWIDE. Guide to Reading and Understanding Your Laboratory Report The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and if you have additional questions please contact your project representative. Abbreviations and Definitions MDL ND RDL Rec. RPD SDG (S) Analyte Dilution Limits Original Sample Qualifier Result Uncertainty (Radiochemistry) Case Narrative (Cn) Quality Control Summary (Qc) Sample Chain of Custody (Sc) Sample Results (Sr) Sample Summary (Ss) Qualifier Method Detection Limit. Not detected at the Reporting Limit (or MDL where applicable). Reported Detection Limit. Recovery. Relative Percent Difference. Sample Delivery Group. Surrogate (Surrogate Standard) - Analyses added to every blank, sample, Laboratory Control Sample/Duplicate and Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be detected in all environmental media. The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes reported. If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor. These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or duplicated within these ranges. The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control sample. The Original Sample may not be included within the reported SDG. This column provides a letter and/or number designation that corresponds to additional information concerning the result reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable. The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL" (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte. Confidence level of 2 sigma. A brief discussion about the included sample results, including a discussion of any non -conformances to protocol observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report. This section of the report includes the results of the laboratory quality control analyses required by procedure or analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material. This is the document created in the field when your samples were initially collected. This is used to verify the time and date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the samples from the time of collection until delivery to the laboratory for analysis. This section of your report will provide the results of all testing performed on your samples. These results are provided by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for each sample will provide the name and method number for the analysis reported. This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and times of preparation and/or analysis. Description J L P U The value is outside laboratory established criteria. Off -scale high. Actual value is known to be greater than value given. RPD between the primary and confirmatory analysis exceeded 40%. Indicates the compound was analyzed for but not detected above the method detection limit. ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Pompano Beach, FL 35451859 L1076238 03/12/1915:52 Cp SS 4 Cn 5 Sr Qr 7GI Al Page 35 of 38 PAGE: 10 of 13 ACCREDITATIONS & LOCATIONS ONE LAB. NATIONWIDE.ilk Pace National is the only environmental laboratory accredited/certified to support your work nationwide from one location. One phone call, one point of contact, one laboratory. No other lab is as accessible or prepared to handle your needs throughout the country. Our capacity and capability from our single location laboratory is comparable to the collective totals of the network laboratories in our industry. The most significant benefit to our one location design is the design of our laboratory campus. The model is conducive to accelerated productivity, decreasing turn -around time, and preventing cross contamination, thus protecting sample integrity. Our focus on premium quality and prompt service allows us to be YOUR LAB OF CHOICE. Not ail certifications held by the laboratory are applicable to the results reported in the attached report. Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace National. State Accreditations Alabama 40660 Nebraska NE-O5-15-05 Alaska 17-026 Nevada TN-03-2002-34 Arizona AZ0612 New Hampshire 2975 Arkansas 88-0469 New Jersey—NELAP TN002 California 2932 New Mexico' n/a Colorado TN00003 New York 11742 Connecticut PH-0197 North Carolina Env375 Florida E87487 North Carolina' DW21704 Georgia NELAP North Carolina' 41 Georgia' 923 North Dakota R-140 Idaho TN00003 Ohio—VAP CL0069 Illinois 200008 Oklahoma 9915 Indiana C-TN-01 Oregon TN200002 Iowa 364 Pennsylvania 68-02979 Kansas E-10277 Rhode Island LA000356 Kentucky' 6 90010 South Carolina 84004 Kentucky 2 16 South Dakota n/a Louisiana A130792 Tennessee' 6 2006 Louisiana' LA180010 Texas T104704245-18-15 Maine TN0002 Texas 5 LAB0152 Maryland 324 Utah TN00003 Massachusetts M-TN003 Vermont VT2006 Michigan 9958 Virginia 460132 Minnesota 047-999-395 Washington C847 Mississippi TN00003 West Virginia 233 Missouri 340 Wisconsin 9980939910 Montana CERT0086 Wyoming A2LA Third Party Federal Accreditations A2LA — ISO 17025 1461.01 A2LA — ISO 17025 5 1461.02 Canada 1461.01 EPA—Crypto TN00003 AIHA-LAP,LLC EMLAP 100789 DOD 1461.01 USDA P330-15-00234 Drinking Water 2 Underground Storage Tanks ' Aquatic Toxicity C Chemical/Microbiological 5 Mold 6 Wastewater n/a Accreditation not applicable Our Locations Pace National has sixty-four client support centers that provide sample pickup and/or the delivery of sampling supplies. If you would like assistance from one of our support offices, please contact our main office. Pace National performs all testing at our central laboratory. ACCOUNT: Pace Analytical - Pompano Beach, FL PROJECT: 35451859 SDG: L1076238 DATE/TIME: 03/12/1915:52 Ss 4 Cn 5 Sr 6 Qc GI Page 36 of 38 PAGE: 11ofU Al Chain Custody of Workorder: 35451859 Workorder Name: 2018-3057Melreese Golf Course Results Requested ace Analytical. By: 3/12/2019 Christina Raschke Pace Analytical South Florida /`.J P.O. f�C - 1 > 3610 Park Central Blvd N 1 Pompano Beach, FL 33064 1` Phone (954)582-4300 Email chnstina.raschke@pacelabs.com State of Sample Origin: FL .5 a v = _ � �- .3- Lt O7C{ 23.g LAB USE ONLY 1 MW-39 3/4/2019 13:04 35451859001 Water 7i X k I 2 3 4 5 Transfers Released By Date ime Rec d By Date/Time /66 1' 7/o0 /y /yJJ - 4Y4 q 2 3 Cooler Temperature on Receipt °C I Custody Seal ! Y J or N Received on Ice Y or N 1 Samples Intact Y or N 131°"'=1y42 /) 3 061 1,3C( no L RAD SCREEN: <0.5 millhr Wednesday. March 06. 2019 1:53:37 PM FMT-ALL-C-002rev.00 24March2009 Page 37 of 38 'ace A na ytica 1 ationa Center for Testing & Innovation Cooler Receipt Form Client: e Ac P11� L L 0-76z &' Cooler Received/Opened On: '3 /'l /19 Temperature: I [„I Received Ry: Jeremy Webb j Signature: � /)/ Receipt Check List NP Yes No COC Seal Present / Intact? ,— COC Signed / Accurate? lJ Bottles arrive intact? /--- Correct bottles used? f--r Sufficient volume sent? /--- If Applicable VOA Zero headspace? Preservation Correct / Checked? ,e 38 of 38 aceAnalytical www.pacelabs.com March 28, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451835 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 05, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry, EE&G Environmental Services, LLC pCCR n REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services. LLC. Page 1 of 18 aceAnalytical® www.pacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451835 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35451835001 MW-39 Water 03/04/19 13:04 03/05/19 17:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 18 "ceMalytircj CHAIN-of-CU&WO : 35451335 The Chain -of -Custody is . Section A Section B Sectior Required Client Information: Required Project Information: Invoice l 11111111111111111111 Page : 1 Of Company EERG Environmental Services, I.LC Report To , v`.cl,.ac-A 1j Atlantic), 35451835 Address 5751 Miami Lakes Dr V Copy To Crct.ic� C le,40-ng4'r Company.„ii,� Hialeah, FL 33014 ,.J C.J Address Regulatory Agency Email AtaiRgs==i0g= mQ�^ eEtistn,A4 Gores Purchase Order�#. Pace Quote. Phone (305)374-8300 ax c1 Project Name- P't �Lkr2.25� GA- (. tarye Pace Protect Manager. christinaraschke@pacelabs.com, /' • State! Location • Requested Due Date. '_ -�.- - - A"�' P Project #: 2018-3u5 / Pace Profile 5: / FL Requ (Y/N) MA1Rix ComE "" lSAMPLE TYPE (G=GRAB C=COMP) COLLECTED SAMPLE TEMP AT COLLECTION I # OF CONTAINERS Preservatives >- }� 2 (a,sFiltered o�mk,�n wmrr nw w e VV w.ur wmrr ww SAMPLE ID Product ol P Soil/Solid Si. oii oL 8 _ w 1.'‘," START END Unpreserred H2SO4 Na2S203. Methanol Analyses Test 8260 VOC PAH by 8270 SIM TRPH FL -PRO Pesticides 8081(o vni Pesticides 814 6 Herbicides 8151(ChL1 l dC t, �5.. o rn w c 0 0 6010 Ba, Cd, Cr, Se, Ag, 7470 Hg.'9t) As, 7y�0I .4k,fie. ?ivnmcr•:t .350 . t ;vy ;.Z Residual Chlorine (YIN) 1 W One Character per box. wire WP other or Sample Ids must be unique sue TS o x DA-E TIME DATE TIME M 0 _ = 0 Z .' L_ O 1 `iU,-L --3 ,� 4'41 o•9. -{ i .X X 2 3 4 5 6 7 8 9 10 11 12 ADDITIONAL COMMENTS - -. RELINQUISHED BY f AFFILIATION ` " DATE:_' . TIME -.. CEPTED 9Y f AFFILIATION :: - DATE TIME SAMPLE CONDITIONS --4 ( 'i-,-s- L'-C--' JC<f'C: 3[4/ (i i G 3C-' C'T ,,,=--.i,il-- '-?/-1/i4j. /.)-d' ',.Y..7.H:i y Y L\` ( \- k 3p)1 q R �T45 5 y (0r0 y SAMPLER NAME AND SIGNATURE • . f c � � m Z v o y m o ? m n m m ---7 PRINT Name of SAMPLER: l Cr'--wit C%,�i U � SIGNATURE of SAMPLER: L� .� i ?,� r•,_•_";,-, ii"-.5 .. DATE Signed: 3 / 4/ a w ----. Ai ., a/ iC8/ .. ,, S_ - _ _ DocJrner.t rlev:sec May 30 2918 .-.-_ " .,_ -. Issuing Authority Pace Ficnca Quality Office 35451835 Project ;pm: CTR Project ManagerCLIENT: 36-EEG Client: Thermometer Used State of Cooler #1 Temp.'C Cooler #2 Temp.'C (n l ) (Visual) Cooler #3 Temp.'C Ss 5 (Visual) (Visual) (Visual) (Visual) Cooler #4 Temp.'C Cooler #5 Temp,`C Cooler #6 Temp.'C Courier: — Fed Ex 3 F (pcida. Due Date: 03/15/19 Date 3) 5) 1(( Time Date and Initials of p Examining content: Label: Deaver{ pH j5 itials crcjects, a!,c.. _ ... _..;:cd to 58 `C (Visual) 3. D (Correction Factor) (Actual) Samoies c^ ce cooling process pas begun 0 V. (Correction Factor) (D. 0 (Actual) 5aro:es ce cooling process ^as beeun 0 .0 (Correction Factor) 5. (Actual) (1Samo es Pr.ice cco!,rc process begun (Correction Factor) JJJ (Actual) L Samo.es on ice_ cooling process nes begun (Correction Factor) (Actual) L Saro<es on ice, cooling process has begun; (Correction Factor) (Actual) L Sar-o,es or ice cooling process `.as begun — UPS Shipping Method: - First Overnight Other Billing: _ Recipient Tracking # U USPS — Client i— Commercial, Pace Priority Overnight _ Sender Custody Seal on Cooler/Box Present: Yes Packing Material: -Bubble Wrap Samples shorted to lab (If Yes, complete) Standard Overnight Third Party _ Credit Card ubble Bags ENone Shorted Date Seals intact: _ Yes Other 1 v Comments: Ground L Other _ International Priority Unknown lc lue Dry None Shorted TimeOty Chain of Custody Present _ es E No EN/A Chain of Custody Filled Out s _ No _N/A Relinquished Signature & Sampler Name COC e _ _ No _N/A Samples Arrived within Hold Time vYesms — No EN/A Rush TAT requested on COC _YesN/A Sufficient Volume es _ No -N/A Correct Containers Used 1.E No EN/A Containers Intact _ No _N/A j Sample Labels match COC (sample IDs & date+time of collection) — es E: No _N/A All containers needing acid/base preservation have been‘,;:if‘ checked _Yes _- No ;�P?IA All Containers needing preservation are founc ;co be in compliance with EPA. recommendation _Yes _ No _ /A Exceptions VOA Coldorm• TOO, C&' Carbamates Preservation Informabcn Preservative Lot #fTraoe Date : i Initials Headspace in VOA Vials' (>6mm) =Yes _ No Trip Blank Present: _Yes _ No Client Notification/ Resolution: Person Contacted Comments/ Resolution (use back for additional comments): Date/Time Project Manager Review Date Page 4 of 18 ace Analytical 'M u�uvw narrlah� � nin www.pacelabs.com Report Prepared for: Christina Raschke PASI Florida 3610 Park Central Blvd N Pompano Beach FL 33064 REPORT OF LABORATORY ANALYSIS FOR PCDD/PCDF Report Prepared Date: March 14, 2019 Report No 10466120_8290FC_DFR Pace Analytical Services, LLC. 1700 Elm Street Minneapolis, MN 55414 Phone: 612.607.1700 Fax: 612.607.6444 Report Information: Pace Project #: 10466120 Sample Receipt Date: 03/07/2019 Client Project #: 35451835 Client Sub PO #: N/A State Cert #: E87605 Invoicing & Reporting Options: The report provided has been invoiced as a Level 2 PCDD/PCDF Report. If an upgrade of this report package is requested, an additional charge may be applied. Please review the attached invoice for accuracy and forward any questions to Kirsten Hogberg, your Pace Project Manager. This report has been reviewed by: March 15, 2019 Kirsten Hogberg, Project Manager (612) 607-6407 (612) 607-6444 (fax) kirsten.hogberg@pacelabs.com Report of Laboratory Analysis Thisreportshouldnotbereproduced,except infull, withoutthewrittenconsentofPaceAnalyticalServices,Inc. Theresultsrelateonlyt othesamplesincludedinthisreport. Page 5 of 18 Page 1 of 14 ace Analytical Pace Analytical Services, LLC. 1700 Elm Street Minneapolis, MN 55414 Phone: 612.607.1700 Fax: 612.607.6444 DISCUSSION This report presents the results from the analysis performed on one sample submitted by a representative of Pace Analytical Services, LLC. The sample was analyzed for the presence or absence of polychlorodibenzo-p-dioxins (PCDDs) and polychlorodibenzofurans (PCDFs) using a modified version of USEPA Method 8290. The reporting limits were based on signal-to-noise measurements. Estimated Maximum Possible Concentration (EMPC) values were treated as positives in the toxic equivalence calculations. Per request, estimated detection limit (EDL) values were provided and flagged "U" where the target analytes were not detected. The recoveries of the isotopically -labeled PCDD/PCDF internal standards in the sample extract ranged from 42-69%. Except for two low values, which were flagged "R" on the results table, the labeled internal standard recoveries obtained for this project were within the 40-135% target range specified in Method 8290. Also, since the quantification of the native 2,3,7,8-substituted congeners was based on isotope dilution, the data were automatically corrected for recovery and accurate values were obtained. A laboratory method blank was prepared and analyzed with the sample batch as part of our routine quality control procedures. The results show that PCDDs and PCDFs were not detected. These results indicate that the sample preparation procedures did not significantly impact the results of the field sample determinations. Laboratory spike samples were also prepared with the sample batch using clean reference matrix that had been fortified with native standard materials. The results show that the spiked native compounds were recovered at 92-120% with relative percent differences of 0.0-10.3%. These results were within the target ranges for the method. Matrix spikes were not prepared with the sample batch. REPORT OF LABORATORYANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466120_8290FC_DFR Page 6 of 18 Page 2 of 14 TM Minnesota Laboratory Certifications Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612-607-6444 Authority Certificate # Authority Certificate # A2LA 2926.01 Minnesota - Pet 1240 Alabama 40770 Mississippi MN00064 Alaska - DW MN00064 Missouri - DW 10100 Alaska - UST 17-009 Montana CERT0092 Arizona AZ0014 Nebraska N E-OS-18-06 Arkansas - DW MN00064 Nevada MN00064 Arkansas - WW 88-0680 New Hampshire 2081 CNMI Saipan MP0003 New Jersey (NE MN002 California 2929 New York 11647 Colorado MN00064 North Carolina 27700 Connecticut PH-0256 North Carolina - 27700 EPA Region 8+ via MN 027-053 North Carolina - 530 Florida (NELAP E87605 North Dakota R-036 Georgia 959 Ohio - DW 41244 Guam 17-001r Ohio - VAP CL101 Hawaii MN00064 Oklahoma 9507 Idaho MN00064 Oregon - Primar MN300001 Illinois 200011 Oregon - Secon MN200001 Indiana C-MN-01 Pennsylvania 68-00563 Iowa 368 Puerto Rico MN00064 Kansas E-10167 South Carolina 74003 Kentucky - DW 90062 South Dakota NA Kentucky - WW 90062 Tennessee TN02818 Louisiana - DE 03086 Texas T104704192 Louisiana - DW MN00064 Utah (NELAP) MN00064 Maine MN00064 Virginia 460163 Maryland 322 Washington C486 Massachusetts M-MN064 West Virginia - 382 Michigan 9909 West Virginia - 9952C Minnesota 027-053-137 Wisconsin 999407970 Minnesota - De via MN 027-053 Wyoming - UST 2926.01 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Page 7 of 18 Page 3 of 14 Report No 10466120_8290FC_DFR Appendix A Sample Management Report No 10466120_8290FC_e Analytical Services, Inc. Page 8 of 18 Page 4 of 14 Report No 10466120_8290FC_DFR v (0 (D cn 0 Chain of Custody Samples were sent directly to the Subcontracting Laboratory. Workorder: 35451835 Workorder Name: 2018-3057Melreese Golf Course State Of Origin: FL Cert. Needed: I I Yes No Owner Received Date: 3/5/2019 Results Requested By: 3/15/2019 Christina Raschke Pace Analytical South Florida 3610 Park Central Blvd N Pompano Beach, FL 33064 Phone (954)582-4300 Pace Analytical Minnesota 1700 Elm Street SE Suite 200 Minneapolis, MN 55414 Phone (612)607-1700 MW-39 PS EMI 3/4/2019 13:04 35451835001 Water ceAna. v ca! www.picelat s c4rn WOp:10466120 111114III II I IIIIII II III ■©■■■■■■■■■■■ Immouniummium ■■■■■■■■■■■■■ ■■■■■•u.u..■■ ■■■■■■■■■■■■■ ua,.w. ink _ _.. Transfers Released By 1 2 3 z Da •/Time •ceived By MIL Date/Time OMMIVIIMMEMPEIIWZNMPAIMIMEC wmwmmilmisi Cooler Tem , eratu re on Recei it LAB USE ONLY ***In order to maintain client confidentiality, location/name of the sampling site, sampler's name and signature may not be provided on this COC document. This chain of custody is considered complete as is since this information is available in the owner laboratory. -o co 0 Tuesday, March 05, 2019 7:32:13 F'M w FMT-ALL-C-002rev.00 24March2009 Page 1 of 1 Document Name: Sample Condition Upon Receipt Form Document Revised: 06Feb2019 Page 1 of 1 6`, ? ' .aceAnalytical Document No.: F-M N-L-213-rev.25 Issuing Authority: Pace Minnesota Quality Office Client Name: I L)f /Ck( Fed Ex UPS Sample Condition Upon Receipt Courier: P roj e c t WO* 10466120 ❑LISPS ❑Client ❑Pace ❑SpeeDee ['Commercial See Exception Tracking Number: Custody Seal on Cooler/Box Present? ❑ es No Seals Intact? ZrYes r PM: KNH Due Date: 03/21/19 CLIENT: PAST -FL ❑No Biological Tissue Frozen? Yes ❑Noi/A Packing Material: Bubble Wrap ubble Bags ❑None Daher: Temp Blank? Eyes Thermometer: 0 G87A9155100842 G87A9170600254 Type of Ice: /Wet ❑Blue :hone Dory ❑Melted Note: Each West Virginia Sample must have temp taken (no temp blanks) Average Corrected Temp See Exce tons (no to p bl nk only): i °C ' USDA Regulated Soil: (gN/A, water sample/Other: ) Date/Initials of Person Examining Contents . .J LZZL Did samples originate in a quarantine zone within the United States: AL, AR, CA, FL, GA, Did samples originate from a foreign source (internationally, including ID, LA. MS, NC, NM, NY, OK, OR, 5C, TN, TX or VA (check maps)? Des ❑No Hawaii and Puerto Rico)? ['Yes ❑No If Yes to either question, fill out a Regulated Soli Checklist (F-MN-Q-338) and include with SCUR/COC paperwork. Temp should be above freezing to 6°C Cooler Temp Read w/temp blank: oC Correction Factor: tl1 t 1 Cooler Temp Corrected w/temp blank : oC COMMENTS: Chain of Custody Present and Filled Out?es ❑No 1. Chain of Custody Relinquished? es ❑No 2. Sampler Name and/or Signature on COC? ❑Yes ❑No ,/A 3. Samples Arrived within Hold Time? ,es DNo 4. Short Hold Time Analysis (<72 hr)? DYes ,o 5. ID Fecal Coliform DHPC ❑Total Coliform/E coil ❑80D/caoo ❑Hex Chrome ❑Turbidity ❑Nitrate ['Nitrite ❑Orthophos DOther Ruth Turn Around Time Requested? ❑Yes So b. Sufficient Volume? Yes ❑No 7. Correct Containers Used? -Pace Containers Used? �es es ❑No ❑No 8. Containers Intact? Yes ❑No 9. Field Filtered Volume Received for Dissolved Tests? DYes ❑No N/A 10. Is sediment visible in the dissolved container? ❑Yes No Is sufficient information available to reconcile the samples to the COC? Matrix:ater ❑Soil DOH❑Other J /Yes r! ❑No 11. if no, write iD/ Date/Time on Container Below: See Exception • All containers needing acid/base preservation have been checked? All containers needing preservation are found to be in compliance with EPA recommendation? (HNO3, H2SO4, <2pH, NaOH >9 Sulfide, NaOH>12 Cyanide) Exceptions: VOA, Coliform, TOC/DOC Oil and Grease, DRO/8015 (water) and Dioxin/PFAS ❑Yes Dyes Des ❑No NN/A , OW N/A � ❑No yrty/A 12. Sample # Acetate See Exception 0 ■ NaOH ■ HNO3 III H2504 []Zinc Positive for Res. ❑Yes Chlorine? No Headspace in VOA Vials (greater than 6mm)? DYes / ❑No j/A 13. See Exception U Trip Blank Present? Trip Blank Custody Seals Present? Oyes ❑No Oyes ❑No N/ 14. Pace Trip Blank Lot # (if purchased): CLIENT NOTIFICATION/RESOLUTION Person Contacted: Comments/Resolutioe : Date/Time Field Data Required? ❑Yes j_jNo Project Manager Review: l]�u��.: ho c, incorrect preservative, out of ¢errp, ucc: re=c can_z:ne:,). Report No 10466120_8290FC_DFR Date: 3/8/2019 Page 10 of 18 Page 6 of 14 fir / ace Ana6Itical Document Name: SCUR Exception Form — Coolers Above 6°C Document Revised: 04Feb2019 Page 1 of 1 Document No.: F-MN-C-298-Rev.O1 issuing Authority: Pace Minnesota Quality Office SCUR Exceptions: Cont&fler # of . Eva 5 ON0 Out of Temp Sarnple IDs Type COritiners. - Other Issues During sample triage, this form is to be placed in each cooler that arrives above 6.0 degrees Celsius Workorder #: If yes, indicate who was contacted/date/time. If no, indicate reason why. Multiple Cooler Project? informaflan to the Issue. -Type: Sample ID Container - # of Type Containers Sample ID No Temp. Bl Read Temp Corrected Temp Average Temp ! I I c,1 hO [,6 Tracking Number al=! Adjustment Log for Preserved Samples pH Type of Upon Date Time Preserv. Receipt Adjusted Adjusted Amount Added LOT # (mL) 1 Added pH In Compliance After 1 after addition? Elves EINo !Yes riNo initials __yes FIN° . Report No 10466120 8290FC DFR Page 11 of 18 Page 7 of 14 Analytical TM Reporting Flags Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 A = Reporting Limit based on signal to noise B = Less than 10x higher than method blank level C = Result obtained from confirmation analysis D = Result obtained from analysis of diluted sample E = Exceeds calibration range I = Interferencepresent J = Estimated value L = Suppressive interference, analyte may be biased low Nn = Value obtained from additional analysis P = PCDElnterference R = Recovery outside target range S = Peak saturated U = Analyte not detected V = Result verified by confirmation analysis X = %D Exceeds limits Y = Calculated using average of daily RFs * = SeeDiscussion REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466120_8290FC_DFR Page 8 of 14 Tel: 612-607-1700 Fax: 612-607-6444 Page 12 of 18 Appendix B Sample Analysis Summary Report No 10466120_8290FC_Ie Analytical Services, Inc. Page 13 of 18 Page 9 of 14 Analytical Clients Sample ID Lab Sample ID Filename Injected By Total Amount Extracted % Moisture Dry Weight Extracted ICAL ID CCal Filename(s) Method Blank ID Native Isomers 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD TM Metho d 8290 Sample Analysis Results Client - PASI Florida MW-39 35451835001 F190313B_11 SMT 1030 mL NA NA F190112 F190313A_18 & F190313B_17 BLANK-68966 Conc pg/L 1.3 U 1.3 U 1.8 U 1.8 U 1.8 U 0.89 U 1.3 U 1.4 U 1.4 U 1.9 U 2.1 U 2.1 U 2.6 U 2.2 U 2.5 U 2.7 U 2.9 U 2.7 U 3.6 U 6.1 U 4.9 U 3.1 U 3.1 U 11 U 12 U EMPC EDL pg/L pg/L Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612- 607-6444 Matrix Water Dilution NA Collected 03/04/2019 13:04 Received 03/07/2019 08:55 Extracted 03/11/2019 12:00 Analyzed 03/14/2019 04:10 Internal ng's Standards Added Percent Recovery 1.3 2,3,7,8-TCDF-13C 1.3 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 1.8 2,3,4,7,8-PeCDF-13C 1.8 1,2, 3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 1.8 1,2,3,6,7, 8-HxCDF-13C 0.89 2,3,4,6,7,8-HxCDF-13C 1.3 1, 2, 3, 7, 8, 9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 1.4 1,2,3,6,7,8-HxCDD-13C 1.4 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 1.9 2.1 2.1 2.6 2.2 2.5 2.7 2.9 2.7 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 2.00 66 2.00 67 2.00 60 2.00 59 2.00 68 2.00 61 2.00 60 2.00 69 2.00 61 2.00 62 2.00 64 2.00 49 2.00 45 2.00 49 4.00 42 2.00 NA 2.00 NA 0.20 85 3.6 Total 2,3,7,8-TCDD 6.1 Equivalence: 0.00 pg/L 4.9 (Lower -bound - Using ITE Factors) 3.1 3.1 11 12 Conc = Concentration (Totals include 2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit ND = Not Detected NA = Not Applicable NC = Not Calculated REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, withoutthewritten consent of Pace Analytical Services, Inc. Report No 10466120_8290FC_DFR Page 14 of 18 Page 10 of 14 Analytical Lab Sample Name Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) Native Isomers TM Method 8290 Blank Analysis Results DFBLKDC BLANK-68966 F190313B_06 945 mL F190112 F190313A_18 & F190313B_17 Conc pg/L EMPC EDL pg/L pg/L Matrix Dilution Extracted Analyzed Injected By Internal Standards Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 TeI:612-607-1700 Fax: 612-607-6444 Water NA 03/11/2019 12:00 03/14/2019 00:29 SMT ng's Percent Added Recovery 2,3,7,8-TCDF Total TCDF 2, 3, 7, 8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD 2.1 U 2.1 U 2.3 U 2.3 U 2.0 U 1.6 U 1.8 U 1.8 U 1.8 U 2.1 U 1.9 U 1.8 U 2.1 U 2.0 U 2.1 U 2.2 U 1.8 U 2.0 U 3.0 U 6.0 U 4.5 U 4.4 U 4.4 U 9.1 U 7.3 U 2.1 2,3,7,8-TCDF-13C 2.1 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 2.3 2,3,4,7,8-PeCDF-13C 2.3 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 2.0 1,2,3,6,7,8-HxCDF-13C 1.6 2,3,4,6,7,8-HxCDF-13C 1.8 1,2, 3, 7, 8, 9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 1.8 1,2, 3,6,7, 8-HxCDD-13C 1.8 1,2, 3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 2.1 1.9 1.8 2.1 2.0 2.1 2.2 1.8 2.0 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 4.00 2.00 2.00 0.20 3.0 Total 2,3,7,8-TCDD 6.0 Equivalence: 0.00 pg/L 4.5 (Lower -bound - Using ITE Factors) 4.4 4.4 9.1 7.3 66 70 62 61 71 64 57 73 63 66 66 51 47 51 44 NA NA 88 Conc= Concentration (Totalsinclude2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466120_8290FC_DFR Page 15 of 18 Page 11 of 14 Analytical Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) Method Blank ID Native Isomers 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD TM Method Method 8290 Laboratory Control Spike Results LCS-68967 F190313B_01 923 mL F190112 F190313A_18 & F190313B_17 BLANK-68966 Qs Qm (ng) (ng) 0.20 0.22 ok Rec. 109 0.20 0.23 117 1.0 1.1 105 1.0 1.1 111 1.0 0.97 97 1.0 1.1 113 1.0 1.1 108 1.0 1.1 105 1.0 1.1 105 1.0 1.1 111 1.0 1.2 120 1.0 1.0 103 1.0 1.1 107 1.0 1.0 102 1.0 1.0 100 2.0 2.2 108 2.0 2.2 109 Matrix Dilution Extracted Analyzed Injected By Internal Standards 2,3,7,8-TCDF-13C 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 2,3,4,7,8-PeCDF-13C 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 1,2,3,6,7,8-HxCDF-13C 2,3,4,6,7, 8-HxCDF-13C 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 1,2,3,6,7,8-HxCDD-13C 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel:612-607-1700 Fax: 612-607-6444 Water NA 03/11/2019 12:00 03/13/2019 20:48 SMT ng's Percent Added Recovery 2.0 58 2.0 60 2.0 52 2.0 51 2.0 58 2.0 52 2.0 49 2.0 60 2.0 49 2.0 55 2.0 54 2.0 41 2.0 37 R 2.0 40 4.0 33 R 2.0 NA 2.0 NA 0.20 80 Qs = Quantity Spiked Qm = Quantity Measured Rec. = Recovery (Expressed as Percent) R = Recovery outside of target range Y = RF averaging used in calculations Nn = Value obtained from additional analysis NA = Not Applicable * = See Discussion REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466120_8290FC_DFR Page 12 of 14 Page 16 of 18 Analytical Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) Method Blank ID Native Isomers TM Method 8290 Laboratory Control Spike Results 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD LCSD-68968 F190313B_02 894 mL F190112 F190313A_18 & F190313B_17 BLANK-68966 Qs Qm (ng) (ng) 0.20 0.22 109 Rec. Matrix Dilution Extracted Analyzed Injected By Internal Standards Pace Analytical Services. LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612-607-6444 Water NA 03/11/2019 12:00 03/13/2019 21:33 SMT 0.20 0.23 116 1.0 1.1 105 1.0 1.1 109 1.0 0.99 99 1.0 1.0 105 1.0 1.0 104 1.0 0.99 99 1.0 0.97 97 1.0 1.1 109 1.0 1.1 115 1.0 1.0 104 1.0 1.0 104 1.0 0.92 92 1.0 0.99 99 2.0 2.1 105 2.0 2.1 106 2,3,7,8-TCDF-13C 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 2,3,4,7,8-PeCDF-13C 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 1,2,3,6,7,8-HxCDF-13C 2,3,4,6,7,8-HxCDF-13C 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 1,2,3,6,7,8-HxCDD-13C 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 ng's Percent Added Recovery 2.0 70 2.0 74 2.0 61 2.0 59 2.0 66 2.0 66 2.0 63 2.0 73 2.0 63 2.0 66 2.0 65 2.0 51 2.0 47 2.0 51 4.0 42 2.0 NA 2.0 NA 0.20 89 Qs = Quantity Spiked Qm = Quantity Measured Rec. = Recovery (Expressed as Percent) R = Recovery outside of target range Y = RF averaging used in calculations Nn = Value obtained from additional analysis NA = Not Applicable = See Discussion REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466120_8290FC_DFR Page 13 of 14 Page 17 of 18 teAnaIyticai1 1 Client Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612-607-6444 Method 8290 Spike Recovery Relative Percent Difference (RPD) Results PASI Florida Spike 1 ID LCS-68967 Spike 2 ID LCSD-68968 Spike 1 Filename F1903136_01 Spike 2 Filename F190313B_02 Spike 1 Spike 2 Compound %REC %REC %RPD 2, 3, 7, 8-TC DF 109 109 0.0 2,3,7,8-TCDD 117 116 0.9 1,2,3,7,8-PeCDF 105 105 0.0 2,3,4,7,8-PeCDF 111 109 1.8 1,2,3,7,8-PeCDD 97 99 2.0 1,2,3,4,7,8-HxCDF 113 105 7.3 1,2,3,6,7,8-HxCDF 108 104 3.8 2,3,4,6,7,8-HxCDF 105 99 5.9 1,2,3,7,8,9-HxCDF 105 97 7.9 1,2,3,4,7,8-HxCDD 111 109 1.8 1,2,3,6,7,8-HxCDD 120 115 4.3 1,2,3,7,8,9-HxCDD 103 104 1.0 1,2,3,4,6,7,8-HpCDF 107 104 2.8 1,2,3,4,7,8,9-HpCDF 102 92 10.3 1,2,3,4,6,7,8-HpCDD 100 99 1.0 OCDF 108 105 2.8 OCDD 109 106 2.8 %REC = Percent Recovered RPD = The difference between the two values divided by the mean value REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466120_8290FC_DFR Page 14 of 14 Page 18 of 18 aceAnalytical www.pacelabs.com March 08, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451855 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 05, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry, EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 11 ceAnalytical® www.pacelabs.com CERTIFICATIONS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451855 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification Ds 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 11 aceAnalytical www.pacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451855 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35451855001 MW-42 Water 03/04/19 11:14 03/05/19 17:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 11 aceAnalytical wwwpacelabs.com SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451855 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35451855001 MW-42 EPA6010 JWP 3 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 11 aceAnalytical www.pacelabs.com SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451855 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters 35451855001 EPA6010 Result MW-42 Barium Units Report Limit Analyzed Qualifiers 20.8 ug/L 10.0 03/07/19 21:03 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 11 aceAnalytkal® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451855 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-42 Lab ID: 35451855001 Collected: 03/04/19 11:14 Received: 03/05/19 17:45 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Arsenic 7.1 U ug/L 10.0 7.1 1 03/07/19 10:29 03/07/19 21:03 7440-38-2 Barium 20.8 ug/L 10.0 0.84 1 03/07/19 10:29 03/07/19 21:03 7440-39-3 Lead 4.6 U ug/L 10.0 4.6 1 03/07/19 10:29 03/07/19 21:03 7439-92-1 Date: 03/08/2019 01:06 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 11 /2ceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451855 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521178 Analysis Method: EPA 6010 QC Batch Method: EPA 3010 Analysis Description: 6010 MET Associated Lab Samples: 35451855001 METHOD BLANK: 2814528 Matrix: Water Associated Lab Samples: 35451855001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic ug/L 7.1 U 10.0 7.1 03/07/19 20:40 Barium ug/L 0.84 U 10.0 0.84 03/07/19 20:40 Lead ug/L 4.6 U 10.0 4.6 03/07/19 20:40 LABORATORY CONTROL SAMPLE: 2814529 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic ug/L 250 251 100 80-120 Barium ug/L 250 250 100 80-120 Lead ug/L 250 260 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2814530 2814531 MS MSD 35451859001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L 7.1 U 250 250 259 252 104 101 75-125 3 20 Barium ug/L 11.5 250 250 266 260 102 99 75-125 2 20 Lead ug/L 4.6 U 250 250 260 255 104 102 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/08/2019 01:06 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 11 aceAnalytical www.pacelabs.com QUALIFIERS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451855 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS U Compound was analyzed for but not detected. Date: 03/08/2019 01:06 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 11 aceAnalytical www.pacelabs.com e QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451855 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID QC Batch Method Analytical QC Batch Analytical Method Batch 35451855001 MW-42 Date: 03/08/2019 01:06 PM EPA 3010 521178 EPA 6010 521271 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 11 aceAnalytical CHAIN-OF-C. - ...�:__1 ,.......� n,., �i.,,ont The Chain-of-CusIWO : 35451855 led accurately. Required Client Information: Required Project Information: ReA RecureB II I I illy 11111 IIII� Page : I Of ComP Y EE&G Environmental Services, LLC Repon To 1„-„r,�,�_ C� J�„'mil Address 5751 Miami Lakes Dr Copy To. c� C � �35451855 C ' Hialeah, FL 33014 L/ , Regulatory Agency Emair Ibex` - ry.Jal` p Lir+ `3. Purchase Order # Pace Quote Phone (305)374-8300 Jx /e (� Project Name: .��t- `'C.'`\r{ '�C,,C5� Pace Project Manager. christina.raschke@pacelabs.com, State / Location Requested Due Date 5-V,...�..ed- -171/4 C Project #: 2018-3057 Face Profile d FL Requested Analysis Filtered (YiN) MATRIX CODE MATRIX CODE (see valid codes to left) \SAMPLE TYPE (G=GRAB C=COMP) COLLECTED SAMPLE TEMP AT COLLECTION 7 i OF CONTAINERS i Preservatives Z >' Drinking Water OW Wntcr WT W.f.Wnlnr WW SAMPLE ID Soil/SolidsL START END Na2S2O3 Other Analyses Test 0- N Q O O co z 0 U # l- — One Character per box. Wage WP (A-Z, 0-91 . -) Air AR Other oT Sample Ids must be unique nasue Ts DATE TIME DATE TIME -2 Z ,v, y c D 3 co _ r7 Z _ U = = 2 e 0 N vt,_.;—? '` Lii‘(1114 1 ; > 2 3 6 10 11 12 ADDITIONAL COMMENTS • RELINQUISHED BY 1 AFFILIATION 1 f • - DATE , TIME ,,ACCEPTED BY / AFFILIATION DATE TIME . . SAMPLE CONDITIONS X ti-/F-----4-C -3/4/Iii kil3ef ,„, i<A7---ZL, '.- /2"i I/9 7)- .: '.(r,' 3, ,U) 1 V Cag.347"-V 'jZ-- 41 '1 q i 1LIS 6' C Ns \iii. SAMPLER NAME AND SIGNATURE Received on Ice (Y/N) Custody Sealed Cooler (Y/N) Samples Intact (Y/N) PRINT Name of SAMPLER: i 4,,\ , ^ +t -I( U c n. SIGNATURE of SAMPLER: /J - J L-1 % ( cs-,, DATE Signed: �. f/// i- iii / i���% - ace Analytical Document Name Sample Condition Upon Rece,ot Form Document Revised IJay 30, 2018 1A _ Document No F-FL-C-007 rev 13 Issuing Authonty Pace Florida Quality Office 35461856 e� t Forfl (SOUR) PM: ow Project # C Project Manager: LIENt: : 0/12j19 36e�� Due pate3 � C Thermometer Used \ C) Date: 5 l Time: ) '...-.' State of rigR(06P C.rj' For WV projecttss,, all containers verified to s6 `C Cooler #1 Temp.`C U (Visual) (�) (Correction Factor) 3, V (Actual) f Samples on ice, cooling process has begun Cooler #2 Temp:C (Visual) 0 0 (Correction Factor) ✓✓✓(0° 0 (Actual) Samples on ice, cooling process has begun Cooler #3 Temp.°C , 5 (Visual) 0 ,0 (Correction Factor) 5,5 (Actual) Samples on ice, cooling process has begun Cooler #4 Temp.°C (Visual) (Correction Factor) (Actual) L Samples on ice, cooling process has begun Cooler #5 Temp.'C (Visual) (Correction Factor) (Actual) ❑ Samples on ice, cooling process has begun Cooler #6 Temp.'C (Visual) (Correction Factor) (Actual) L Samples on ice, cooling process has begun Examining Date and Initials of p contents: Label: Deliver pH: , Initials: t Courier: L Fed Ex rl UPS USPS — Client CommerctaV Pace EI Other Shipping Method: E. First Overnight - Priority Overnight - Standard Overnight _ Ground _ International Pnority Other Billing: - Recipient - Sender E Third Party = Credit Card Tracking # Custody Seal on Cooler/Box Present: Packing Material: '!Bubble Wrap ubble Bags L_-None Samples shorted to lab (If Yes, complete) Shorted Date: Seals intact: ^ Yes Other Comments: Unknown Shorted Time lue Dry None Chain of Custody Present E es _ No ON/A Chain of Custody Filled Out s =i No ON/A Relinquished Signature & Sampler Name COC _, eses''- No DN/A Samples Arrived within Hold Time 4?Yes ;- No DN/A Rush TAT requested on COC EYes - o nN/A Sufficient Volume �i'fes - No ON/A Correct Containers Used - No ON/A ........,;.Wes Containers Intact , 21 es E No ❑N/A Sample Labels match COC (sample IDs & date/time of collection)es r. No ON/A All containers needing acid/base preservation have been checked. es = No ON/A • All Containers needing preservation are found to be in compliance with EPA recommendation - es _ No _N/A Exceptions VOA; Coliform, TOC, O&G, Carbamates Preservation Intormatio Preservative Lot #/Trace # q►j • Date II Initials I l Headspace in VOA Vials? (>6mm): EYes E No w Trip Blank Present: Eyes E. No — /A Client Notification/ Resolution: Person Contacted: Comments/ Resolution (use back for additional comments): Date/Time. Project Manager Review. Date Page 11 of 11 aceAnalytical® www.pacelabs.com March 08, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057Melreese Golf Course Pace Project No.: 35451848 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach. FL 33064 954-582-4300 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 05, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke©pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry, EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 13 www.pacelabs.com CERTIFICATIONS Project: 2018-3057Melreese Golf Course Pace Project No.: 35451848 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 13 aceAnalytical® www.pacelabs.com SAMPLE SUMMARY Project: 2018-3057Melreese Golf Course Pace Project No.: 35451848 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35451848001 MW-42 Water 03/04/19 11:14 03/05/19 17:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 13 aceAnalytical® www.pacelabs.com SAMPLE ANALYTE COUNT Project: 2018-3057Melreese Golf Course Pace Project No.: 35451848 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35451848001 MW-42 EPA6010 JWP 2 PASI-O EPA 300.0 JDM 2 PASI-O EPA 350.1 MAJ 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 13 SUMMARY OF DETECTION Project: 2018-3057Melreese Golf Course Pace Project No.: 35451848 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters 35451848001 EPA 6010 EPA 350.1 Result Units Report Limit Analyzed Qualifiers MW-42 Iron 621 ug/L Nitrogen, Ammonia 0.69 mg/L REPORT OF LABORATORY ANALYSIS 40.0 03/07/19 21:03 0.050 03/06/19 08:27 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 13 72ceAnalj4ical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057Melreese Golf Course Pace Project No.: 35451848 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-42 Lab ID: 35451848001 Collected: 03/04/19 11:14 Received: 03/05/19 17:45 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Aluminum 30.7 U ug/L 100 30.7 1 03/07/19 10:29 03/07/19 21:03 7429-90-5 Iron 621 ug/L 40.0 9.2 1 03/07/19 10:29 03/07/19 21:03 7439-89-6 300.0 IC Anions Analytical Method: EPA 300.0 Nitrate as N 0.025 U mg/L 0.050 0.025 1 03/06/19 08:26 14797-55-8 Nitrite as N 0.025 U mg/L 0.050 0.025 1 03/06/19 08:26 14797-65-0 350.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia 0.69 mg/L 0.050 0.035 1 03/06/19 08:27 7664-41-7 Date: 03/08/2019 12:40 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 13 (/eAnaIYticaI www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057Melreese Golf Course Pace Project No.: 35451848 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521178 Analysis Method: EPA 6010 QC Batch Method: EPA 3010 Analysis Description: 6010 MET Associated Lab Samples: 35451848001 METHOD BLANK: 2814528 Matrix: Water Associated Lab Samples: 35451848001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Aluminum ug/L 30.7 U 100 Iron ug/L 9.2 U 40.0 30.7 03/07/19 20:40 9.2 03/07/19 20:40 LABORATORY CONTROL SAMPLE: 2814529 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Aluminum ug/L 2500 2520 101 80-120 Iron ug/L 2500 2610 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2814530 2814531 MS MSD 35451859001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 30.7 U 2500 2500 2590 2530 103 101 75-125 2 20 Iron ug/L 369 2500 2500 2980 2910 105 102 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/08/2019 12:40 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 13 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057Melreese Golf Course Pace Project No.: 35451848 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: QC Batch Method: 520750 EPA 300.0 Associated Lab Samples: 35451848001 Analysis Method: Analysis Description: EPA 300.0 300.0 IC Anions METHOD BLANK: 2812105 Matrix: Water Associated Lab Samples: 35451848001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrate as N mg/L 0.025 U 0.050 0.025 03/06/19 11:46 Nitrite as N mg/L 0.025 U 0.050 0.025 03/06/19 11:46 LABORATORY CONTROL SAMPLE: 2812106 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/L 5 5.0 100 90-110 Nitrite as N mg/L 5 4.9 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2812128 2812129 MS MSD 35451851001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrate as N mg/L 0.025 U 5 5 4.8 4.8 96 96 90-110 1 20 Nitrite as N mg/L 0.025 U 5 5 4.9 4.9 98 97 90-110 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/08/2019 12:40 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 13 aceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057Melreese Golf Course Pace Project No.: 35451848 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 520730 Analysis Method: EPA 350.1 QC Batch Method: EPA 350.1 Analysis Description: 350.1 Ammonia Associated Lab Samples: 35451848001 METHOD BLANK: 2812044 Matrix: Water Associated Lab Samples: 35451848001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Ammonia mg/L 0.035 U 0.050 0.035 03/06/19 08:14 LABORATORY CONTROL SAMPLE: 2812045 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 1 1.1 105 90-110 MATRIX SPIKE SAMPLE: 2812047 35451845001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 0.58 1 1.6 103 90-110 SAMPLE DUPLICATE: 2812046 35451845001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrogen, Ammonia mg/L 0.58 0.58 0 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/08/2019 12:40 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 13 aceAnalytical wwwpacelabs.com QUALIFIERS Project: 2018-3057Melreese Golf Course Pace Project No.: 35451848 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS U Compound was analyzed for but not detected. Date: 03/08/2019 12:40 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 13 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057Melreese Golf Course Pace Project No.: 35451848 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID QC Batch Method Analytical QC Batch Analytical Method Batch 35451848001 MW-42 EPA 3010 521178 EPA 6010 521271 35451848001 MW-42 EPA 300.0 520750 35451848001 MW-42 EPA 350.1 520730 Date: 03/08/2019 12:40 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 13 PaceAnalytical CHAIN-OF-CUyr 10 35451848..'tr„a.,t The Chain-of-Custod IS :urately. Section A Section B Seetior Required Client Information: Required Project Information: Involct Il I I I111111111111 II III Page : 1 Of 1 Company EERG Environmental Services, LLC Report To. kA.c� \in-rx •2. Attentir Address 5751 Miami Lakes Dr Copy To -,c Cie �k3e.rV Compa 35451848 Hialeah, FL 33014 Address Regulatory Agency t Email Mime, ee a - C ,,,,,N.Purchase Order #. Pace Quote. Phone (305)374-8300 ax v Project Name eAre2;,,I. C c ; (,r,otr$e Pace Project Managerchnstina.raschke(a]pacelabs corn, -.. State 1 Location • • Requested Due Date. :�� t -.., , - �� Project #: 2018-3U5/ Pace Profile # / FL Requ ALI ' Filtered (YIN) MATRIX coon MATRIX CODE (see valid codes 101eal SAMPLE TYPE (G=GRAB C=COMP) COLLECTED SAMPLE TEMP AT COLLECTION 0 OF CONTAINERS Preservatives 2_ % i -7,:""'3 1 l) Drinking Wutrr OW Water WT Waste Water WW Product P SAMPLE ID Sod/Solid a Oil START END Unpreserved 1 Na2S203 Analyses Test 8260 VOC PAH by 8270 SIM TRPH FL -PRO Pesticides 8081(0,,�, Pesticides 81416a, Herbicides 8151(cW , , N co O 0 6010 Ba, Cd, Cr. Se, Ag, 7470 Hg 'jibiss, ?co/c, Al , �z G•t 7V? .r � �` — Residual Chlorine (Y/N) # W — One Character per box. Wipe WPQ. (A-Z, O.3 I r -) Air AR Other Sample Ids must be unique race, O5 DATE TIME DATE TIME v o _ O X U 1 O Z v i L Oi Pt' V• % r 2 3 4 5 6 7 8 9 10 11 12 -,,L ADDITIONAL COMMENTS RELINQUISHED QY f AFFI •TION . DATE TIME' ACCpPTED BY 1 AFFILIATION DATE . TIME . SAMPLE CONDITIONS j / ..D y s SAMPLER NAME AND. SIGNATURE , A I , TEMP in C Received on Ice (Y/N) uMoy Sealed Cooler (Y/N) m E m z N ` > PRINT Name of SAMPLER: 1✓11 \ 1 7) t \ e �-/\. LI2:,��. \ f SIGNATURE of SAMPLER: // --/ ( } s—l� L� X.1 .) ATE Signed: l n III J /( j 0 4) 0_ .....,...r'.Eni RevJsec may 30.20i8 Samples shorted to lab (If Yes, complete) Price Analytical issuing Authcnty Pace FIchca Quality Office wp# : 35451848 Project # PM: CTR CLIENT: 36-EEG Project Manager: Client: Thermometer Used Due Date: 03/12/19 Date3)5) E ° State of rig: V L =,,.r,/,.7,1 proleos aii containers ver,r:eo ,o <c Cooler #1 Temp.'C (Visual) 0. 0 (Correction Factor) 3. V (Actual) SarmoLes on ,ce cooimc process has cecur Cooler #2 Temp.'C (Visual) 0. c (Correction Factor) ( V (Actual) Samoes o- ce cco!,^i: ^-ocess has ft,a^sr Cooler #3 Temp.'C 5. , (Visual) 0 ,-0 (Correction Factor) (Actual) ` I San es o- ice cc: _ p-cce=_s rids cecur Cooler #4 Temp.'C (Visual) (Correction Factor) (Actual) LSer ,es c- :ce_ -c ... ^y process has c gJn L $amp on ,ce. c:., y orocess has tour. L Sar^ptes oh ice. c oang process has tegur Date and Initials of p Examining content: (� Label: Cooler #5 Temp.'C Cooler #6 Temp.'C (Visual) (Visual) (Correction Factor) (Correction Factor) Time (Actual) (Actual) Deliver I�L Courier: — Fed Ex — - UPS USPS — Client L-- - Commercial/' Pace Shipping Method: - First Overnight _ Priority Overnight J. Other Billing: Recipient Tracking # Custody Seal on Cooler/Box Present: Packing Material: -Bubble Wrap ubble Bags LNone Shorted Date = Sender Standard Overnight = Third Party Credit Card Ground Seals intact: _ Yes, -Otther lv/ Comments: Initials {� L Other = International Priority Unknown Shorted Time j J -----Qty Chain of Custody Present es _ No ' N/A Chain of Custody Filled Out .„,,el es = No =N/A Relinquished Signature & Sampler Name COC _ . e= No IiN/A Samples Arrived within Hold Time Yesms = No i:N/A Rush TAT requested on COC _Yes o N/A Sufficient Volume s = No =N/A Correct Containers Used ; = No =N/A Containers Intact _ es IT No =.N/A Sample Labels match COC (sample IDs & date/time of collection) �� .......KS 11 No -_-_'N/A All containers needing acid/base preservation have teen checked _.Yes LT No =N/A All Containers neeo,no preservation are found to be in J/ compliance with EPA. recommendation /Yes = No =N/A Exceptions VOA Carfcrm, TCC. Cis:: Carbamates Pr - Preservation information Preservative Lot #:Trace # Date i:r� Initials Headspace in VOA Vials'? ( >6mm) _Yes _ No Trip Blank Present: -Yes = No : iA Client Notification/ Resolution: Person Contacted Comments/ Resolution (use back for additional comments): Dale/Time Project Manager Review Date Page 13 of 13 aceAnalytical® www.pacelabs.com March 12, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057Melreese Golf Course Pace Project No.: 35451862 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 05, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Some analyses have been subcontracted outside of the Pace Network. The subcontracted laboratory report has been attached. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry, EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 38 PaceAnalytical www.pacelabs.com CERTIFICATIONS Project: 2018-3057Melreese Golf Course Pace Project No.: 35451862 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 38 aceAnalytical wwwpacelabs.com SAMPLE SUMMARY Project: 2018-3057Melreese Golf Course Pace Project No.: 35451862 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35451862001 MW-42 Water 03/04/19 11:14 03/05/19 17:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 38 SAMPLE ANALYTE COUNT Project: 2018-3057Melreese Golf Course Pace Project No.: 35451862 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35451862001 MW-42 EPA 8081 AER 22 PASI-O FL -PRO RJR 3 PASI-O EPA6010 JWP 4 PASI-O EPA 7470 AMS 1 PASI-O EPA 8270 by SIM CB1 20 PASI-O EPA 8260 BTN 69 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 38 / 2 PaceAnalytical ® www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 ANALYTICAL RESULTS Project: 2018-3057Melreese Golf Course Pace Project No.: 35451862 Sample: MW-42 Parameters Lab ID: 35451862001 Collected: 03/04/19 11:14 Received: 03/05/19 17:45 Matrix: Water Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8081 GCS Pesticides Aldrin alpha-BHC beta-BHC delta-BHC gamma-BHC (Lindane) Chlordane (Technical) 4,4'-DDD 4,4'-DDE 4,4'-DDT Dieldrin Endosulfan I Endosulfan 11 Endosulfan sulfate Endrin Endrin aldehyde Endrin ketone Heptachlor 4eptachlor epoxide ,ethoxychlor Toxaphene Surrogates Tetrachloro-m-xylene (S) Decachlorobiphenyl (S) FL -PRO Water, Low Volume Petroleum Range Organics Surrogates o-Terphenyl (S) N-Pentatriacontane (S) 6010 MET ICP Cadmium Chromium Selenium Silver 7470 Mercury Mercury 8270 MSSV PAHLV by SIM Acenaphthene Acenaphthylene Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Date: 03/12/2019 09:09 PM Analytical Method. EPA 8081 Preparation Method: EPA 3510 0.0014 U ug/L 0.0096 0.0014 1 03/06/19 16:26 03/09/19 04:32 309-00-2 1p 0.0020 U ug/L 0.0096 0.0020 1 03/06/19 16:26 03/09/19 04:32 319-84-6 1p 0.0077 U ug/L 0.0096 0.0077 1 03/06/19 16:26 03/09/19 04:32 319-85-7 1p 0.0046 U ug/L 0.0096 0.0046 1 03/06/19 16:26 03/09/19 04:32 319-86-8 1p 0.0021 U ug/L 0.0096 0.0021 1 03/06/19 16:26 03/09/19 04:32 58-89-9 1p 0.17 U ug/L 0.48 0.17 1 03/06/19 16:26 03/09/19 04:32 57-74-9 1p 0.0085 U ug/L 0.0096 0.0085 1 03/06/19 16:26 03/09/19 04:32 72-54-8 1p 0.0048 U ug/L 0.0096 0.0048 1 03/06/19 16:26 03/09/19 04:32 72-55-9 1p 0.0048 U ug/L 0.0096 0.0048 1 03/06/19 16:26 03/09/19 04:32 50-29-3 1p 0.0019 U ug/L 0.0096 0.0019 1 03/06/19 16:26 03/09/19 04:32 60-57-1 1p 0.0049 U ug/L 0.0096 0.0049 1 03/06/19 16:26 03/09/19 04:32 959-98-8 1p 0.0038 U ug/L 0.0096 0.0038 1 03/06/19 16:26 03/09/19 04:32 33213-65-9 1p 0.0060 U ug/L 0.096 0.0060 1 03/06/19 16:26 03/09/19 04:32 1031-07-8 1p 0.0041 U ug/L 0.0096 0.0041 1 03/06/19 16:26 03/09/19 04:32 72-20-8 1p 0.0035 U ug/L 0.096 0.0035 1 03/06/19 16:26 03/09/19 04:32 7421-93-4 1p 0.0048 U ug/L 0.0096 0.0048 1 03/06/19 16:26 03/09/19 04:32 53494-70-5 1p 0.0060 U ug/L 0.0096 0.0060 1 03/06/19 16:26 03/09/19 04:32 76-44-8 1p 0.0050 U ug/L 0.0096 0.0050 1 03/06/19 16:26 03/09/19 04:32 1024-57-3 1p 0.0092 U ug/L 0.0096 0.0092 1 03/06/19 16:26 03/09/19 04:32 72-43-5 1p 0.24 U ug/L 0.48 0.24 1 03/06/19 16:26 03/09/19 04:32 8001-35-2 1p 70 % 27-124 1 03/06/19 16:26 03/09/19 04:32 877-09-8 55 % 10-132 1 03/06/19 16:26 03/09/19 04:32 2051-24-3 Analytical Method: FL -PRO Preparation Method: EPA 3510 0.77 U mg/L 0.96 0.77 1 03/07/19 09:10 03/07/19 17:17 84 % 66-139 1 03/07/19 09:10 03/07/19 17:17 84-15-1 98 % 42-159 1 03/07/19 09:10 03/07/19 17:17 630-07-09 Analytical Method: EPA 6010 Preparation Method: EPA 3010 0.33 U ug/L 1.0 0.33 1 03/07/19 10:29 03/07/19 21:03 7440-43-9 1.7 U ug/L 5.0 1.7 1 03/07/19 10:29 03/07/19 21:03 7440-47-3 8.5 U ug/L 15.0 8.5 1 03/07/19 10:29 03/07/19 21:03 7782-49-2 1.0 U ug/L 5.0 1.0 1 03/07/19 10:29 03/07/19 21:03 7440-22-4 Analytical Method: EPA 7470 Preparation Method: EPA 7470 0.10 U ug/L 0.20 0.10 1 03/07/19 10:25 03/08/19 16:16 7439-97-6 Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3510 0.040 U ug/L 0.030 U ug/L 0.043 U ug/L 0.055 U ug/L 0.12 U ug/L 0.027 U ug/L 0.50 0.040 1 03/07/19 02:41 03/07/19 12:40 83-32-9 0.50 0.030 1 03/07/19 02:41 03/07/19 12:40 208-96-8 0.50 0.043 1 03/07/19 02:41 03/07/19 12:40 120-12-7 0.10 0.055 1 03/07/19 02:41 03/07/19 12:40 56-55-3 0.20 0.12 1 03/07/19 02:41 03/07/19 12:40 50-32-8 0.10 0.027 1 03/07/19 02:41 03/07/19 12:40 205-99-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 38 aceAnalytical wwwpacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 ANALYTICAL RESULTS Project: 2018-3057Melreese Golf Course Pace Project No.: 35451862 Sample: MW-42 Parameters Lab ID: 35451862001 Collected: 03/04/19 11:14 Received: 03/05/19 17:45 Matrix: Water Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8270 MSSV PAHLV by SIM Analytical Method: EPA8270 by SIM Preparation Method: EPA3510 Benzo(g,h,i)perylene 0.15 U ug/L 0.50 0.15 1 03/07/19 02:41 03/07/19 12:40 191-24-2 Benzo(k)fluoranthene 0.16 U ug/L 0.50 0.16 1 03/07/19 02:41 03/07/19 12:40 207-08-9 Chrysene 0.026 U ug/L 0.50 0.026 1 03/07/19 02:41 03/07/19 12:40 218-01-9 Dibenz(a,h)anthracene 0.13 U ug/L 0.15 0.13 1 03/07/19 02:41 03/07/19 12:40 53-70-3 Fluoranthene 0.018 U ug/L 0.50 0.018 1 03/07/19 02:41 03/07/19 12:40 206-44-0 Fluorene 0.088 U ug/L 0.50 0.088 1 03/07/19 02:41 03/07/19 12:40 86-73-7 Indeno(1,2,3-cd)pyrene 0.12 U ug/L 0.15 0.12 1 03/07/19 02:41 03/07/19 12:40 193-39-5 1-Methylnaphthalene 0.19 U ug/L 2.0 0.19 1 03/07/19 02:41 03/07/19 12:40 90-12-0 2-Methylnaphthalene 0.68 U ug/L 2.0 0.68 1 03/07/19 02:41 03/07/19 12:40 91-57-6 Naphthalene 0.29 U ug/L 2.0 0.29 1 03/07/19 02:41 03/07/19 12:40 91-20-3 Phenanthrene 0.16 U ug/L 0.50 0.16 1 03/07/19 02:41 03/07/19 12:40 85-01-8 Pyrene 0.032 U ug/L 0.50 0.032 1 03/07/19 02:41 03/07/19 12:40 129-00-0 Surrogates 2-Fluorobiphenyl (S) 78 % 33-82 1 03/07/19 02:41 03/07/19 12:40 321-60-8 p-Terphenyl-d14 (S) 102 % 49-104 1 03/07/19 02:41 03/07/19 12:40 1718-51-0 8260 MSV Analytical Method: EPA 8260 1.1,1,2-Tetrachloroethane 0.32 U ug/L 1.0 0.32 1 03/06/1916:04 630-20-6 1.1,1-Trichloroethane 0.30 U ug/L 1.0 0.30 1 03/06/19 16:04 71-55-6 1,1,2,2-Tetrachloroethane 0.20 U ug/L 0.50 0.20 1 03/06/19 16:04 79-34-5 1,1,2-Trichloroethane 0.30 U ug/L 1.0 0.30 1 03/06/19 16:04 79-00-5 1,1-Dichloroethane 0.34 U ug/L 1.0 0.34 1 03/06/19 16:04 75-34-3 1,1-Dichloroethene 0.27 U ug/L 1.0 0.27 1 03/06/19 16:04 75-35-4 1,1-Dichloropropene 0.31 U ug/L 1.0 0.31 1 03/06/19 16:04 563-58-6 1,2,3-Trichlorobenzene 0.34 U ug/L 1.0 0.34 1 03/06/19 16:04 87-61-6 1,2,3-Trichloropropane 1.1 U ug/L 2.0 1.1 1 03/06/19 16:04 96-18-4 1,2,3-Trimethylbenzene 0.17 U ug/L 1.0 0.17 1 03/06/19 16:04 526-73-8 1,2,4-Trichlorobenzene 0.32 U ug/L 1.0 0.32 1 03/06/19 16:04 120-82-1 1,2,4-Trimethylbenzene 0.24 U ug/L 1.0 0.24 1 03/06/19 16:04 95-63-6 1.2-Dichlorobenzene 0.29 U ug/L 1.0 0.29 1 03/06/19 16:04 95-50-1 1,2-Dichloroethane 0.27 U ug/L 1.0 0.27 1 03/06/19 16:04 107-06-2 1,2-Dichloropropane 0.23 U ug/L 1.0 0.23 1 03/06/19 16:04 78-87-5 1,3,5-Trimethylbenzene 0.24 U ug/L 1.0 0.24 1 03/06/19 16:04 108-67-8 1,3-Dichlorobenzene 0.33 U ug/L 1.0 0.33 1 03/06/19 16:04 541-73-1 1,3-Dichloropropane 0.26 U ug/L 1.0 0.26 1 03/06/19 16:04 142-28-9 1,4-Dichlorobenzene 0.28 U ug/L 1.0 0.28 1 03/06/19 16:04 106-46-7 2,2-Dichloropropane 0.59 U ug/L 1.0 0.59 1 03/06/19 16:04 594-20-7 2-Butanone (MEK) 7.5 U ug/L 10.0 7.5 1 03/06/19 16:04 78-93-3 2-Chloroethylvinyl ether 1.4 U ug/L 40.0 1.4 1 03/06/19 16:04 110-75-8 c2 2-Chlorotoluene 0.28 U ug/L 1.0 0.28 1 03/06/19 16:04 95-49-8 2-Hexanone 0.85 U ug/L 10.0 0.85 1 03/06/19 16:04 591-78-6 4-Chlorotoluene 0.22 U ug/L 1.0 0.22 1 03/06/19 16:04 106-43-4 4-Methyl-2-pentanone (MIBK) 0.32 U ug/L 10.0 0.32 1 03/06/19 16:04 108-10-1 Acetone 5.3 U ug/L 20.0 5.3 1 03/06/19 16:04 67-64-1 Benzene 0.30 U ug/L 1.0 0.30 1 03/06/19 16:04 71-43-2 Bromobenzene 0.21 U ug/L 1.0 0.21 1 03/06/19 16:04 108-86-1 Date: 03/12/2019 09:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 38 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057Melreese Golf Course Pace Project No.: 35451862 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-42 Parameters Lab ID: 35451862001 Collected: 03/04/19 11:14 Received: 03/05/19 17:45 Matrix: Water Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Dibromochloromethane Dibromomethane Dichlorodifluoromethane Ethylbenzene lodomethane Isopropylbenzene (Cumene) Methyl-tert-butyl ether Methylene Chloride tyrene Tetrachloroethene Toluene Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1, 3-Dichloropropene m&p-Xylene n-Butylbenzene n-Propylbenzene o-Xylene p-Isopropyltoluene sec-Butylbenzene tert-Butylbenzene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 03/12/2019 09:09 PM Analytical Method: EPA 8260 0.37 U 0.19 U 2.6 U 4.0 U 0.45 U 1.1 U 0.35 3.7 0.32 0.97 0.45 0.68 0.26 0.30 9.3 0.30 0.51 2.0 0.26 0.38 0.33 0.36 0.35 0.19 0.39 2.1 0.27 0.17 2.1 0.20 0.37 0.27 0.31 0.17 0.26 0.23 0.17 88 107 99 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ova Ok Ok 1.0 0.60 3.0 5.0 10.0 3.0 1.0 10.0 1.0 1.0 2.0 2.0 1.0 1.0 10.0 1.0 2.0 5.0 1.0 1.0 1.0 1.0 1.0 10.0 1.0 5.0 1.0 0.50 4.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 0.50 70-130 70-130 70-130 0.37 0.19 2.6 4.0 0.45 1.1 0.35 3.7 0.32 0.97 0.45 0.68 0.26 0.30 9.3 0.30 0.51 2.0 0.26 0.38 0.33 0.36 0.35 0.19 0.39 2.1 0.27 0.17 2.1 0.20 0.37 0.27 0.31 0.17 0.26 0.23 0.17 REPORT OF LABORATORY ANALYSIS 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 03/06/19 16:04 74-97-5 75-27-4 75-25-2 74-83-9 v2 75-15-0 v1 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3 v2 124-48-1 74-95-3 75-71-8 100-41-4 74-88-4 v2 98-82-8 1634-04-4 75-09-2 100-42-5 127-18-4 108-88-3 79-01-6 75-69-4 108-05-4 75-01-4 1330-20-7 156-59-2 10061-01-5 179601-23-1 104-51-8 103-65-1 95-47-6 99-87-6 135-98-8 98-06-6 156-60-5 10061-02-6 03/06/19 16:04 460-00-4 03/06/19 16:04 17060-07-0 03/06/19 16:04 2037-26-5 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 38 /!.ceAnaIicaI www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA Project: 2018-3057Melreese Golf Course Pace Project No.: 35451862 QC Batch: 521100 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 35451862001 METHOD BLANK: 2814165 Matrix: Water Associated Lab Samples: 35451862001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L 0.10 U 0.20 0.10 03/08/19 15:31 LABORATORY CONTROL SAMPLE: 2814166 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2 1.9 96 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2814167 2814168 MS MSD 35451633001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L 0.10 U 2 2 1.7 1.8 86 88 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 38 aceAnalytical® www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA Project: 2018-3057Melreese Golf Course Pace Project No.: 35451862 QC Batch: 521178 Analysis Method: EPA 6010 QC Batch Method: EPA 3010 Analysis Description: 6010 MET Associated Lab Samples: 35451862001 METHOD BLANK: 2814528 Matrix: Water Associated Lab Samples: 35451862001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Cadmium ug/L 0.33 U 1.0 0.33 03/07/19 20:40 Chromium ug/L 1.7 U 5.0 1.7 03/07/19 20:40 Selenium ug/L 8.5 U 15.0 8.5 03/07/19 20:40 Silver ug/L 1.0 U 5.0 1.0 03/07/19 20:40 LABORATORY CONTROL SAMPLE: 2814529 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Cadmium ug/L 25 25.7 103 80-120 Chromium ug/L 250 255 102 80-120 Selenium ug/L 250 261 104 80-120 Silver ug/L 25 24.1 96 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2814530 2814531 MS MSD 35451859001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Cadmium ug/L 0.33 U 25 25 26.0 25.4 104 101 75-125 2 20 Chromium ug/L 1.7 U 250 250 262 252 105 101 75-125 4 20 Selenium ug/L 8.5 U 250 250 266 253 106 101 75-125 5 20 Silver ug/L 1.0 U 25 25 24.5 23.7 98 95 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/12/2019 09:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 38 PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA Project: 2018-3057Melreese Golf Course Pace Project No.: 35451862 QC Batch: 520786 Analysis Method: EPA 8260 QC Batch Method: EPA 8260 Analysis Description: 8260 MSV Associated Lab Samples: 35451862001 METHOD BLANK: 2812236 Matrix: Water Associated Lab Samples: 35451862001 Parameter Blank Reporting Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L 0.32 U 1.0 0.32 03/06/19 09:44 1,1,1-Trichloroethane ug/L 0.30 U 1.0 0.30 03/06/19 09:44 1,1,2,2-Tetrachloroethane ug/L 0.20 U 0.50 0.20 03/06/19 09:44 1,1,2-Trichloroethane ug/L 0.30 U 1.0 0.30 03/06/19 09:44 1,1-Dichloroethane ug/L 0.34 U 1.0 0.34 03/06/19 09:44 1,1-Dichloroethene ug/L 0.27 U 1.0 0.27 03/06/19 09:44 1,1-Dichloropropene ug/L 0.31 U 1.0 0.31 03/06/19 09:44 1,2,3-Trichlorobenzene ug/L 0.34 U 1.0 0.34 03/06/19 09:44 1,2,3-Trichloropropane ug/L 1.1 U 2.0 1.1 03/06/19 09:44 1,2,3-Trimethylbenzene ug/L 0.17 U 1.0 0.17 03/06/19 09:44 1,2,4-Trichlorobenzene ug/L 0.32 U 1.0 0.32 03/06/19 09:44 1,2,4-Trimethylbenzene ug/L 0.24 U 1.0 0.24 03/06/19 09:44 1,2-Dichlorobenzene ug/L 0.29 U 1.0 0.29 03/06/19 09:44 1,2-Dichloroethane ug/L 0.27 U 1.0 0.27 03/06/19 09:44 1,2-Dichloropropane ug/L 0.23 U 1.0 0.23 03/06/19 09:44 1,3,5-Trimethylbenzene ug/L 0.24 U 1.0 0.24 03/06/19 09:44 1,3-Dichlorobenzene ug/L 0.33 U 1.0 0.33 03/06/19 09:44 1,3-Dichloropropane ug/L 0.26 U 1.0 0.26 03/06/19 09:44 1,4-Dichlorobenzene ug/L 0.28 U 1.0 0.28 03/06/19 09:44 2,2-Dichloropropane ug/L 0.59 U 1.0 0.59 03/06/19 09:44 2-Butanone (MEK) ug/L 7.5 U 10.0 7.5 03/06/19 09:44 2-Chloroethylvinyl ether ug/L 1.4 U 40.0 1.4 03/06/19 09:44 2-Chlorotoluene ug/L 0.28 U 1.0 0.28 03/06/19 09:44 2-Hexanone ug/L 0.85 U 10.0 0.85 03/06/19 09:44 4-Chlorotoluene ug/L 0.22 U 1.0 0.22 03/06/19 09:44 4-Methyl-2-pentanone (MIBK) ug/L 0.32 U 10.0 0.32 03/06/19 09:44 Acetone ug/L 5.3 U 20.0 5.3 03/06/19 09:44 Benzene ug/L 0.30 U 1.0 0.30 03/06/19 09:44 Bromobenzene ug/L 0.21 U 1.0 0.21 03/06/19 09:44 Bromochloromethane ug/L 0.37 U 1.0 0.37 03/06/19 09:44 Bromodichloromethane ug/L 0.19 U 0.60 0.19 03/06/19 09:44 Bromoform ug/L 2.6 U 3.0 2.6 03/06/19 09:44 Bromomethane ug/L 4.0 U 5.0 4.0 03/06/19 09:44 Carbon disulfide ug/L 0.45 U 10.0 0.45 03/06/19 09:44 Carbon tetrachloride ug/L 1.1 U 3.0 1.1 03/06/19 09:44 Chlorobenzene ug/L 0.35 U 1.0 0.35 03/06/19 09:44 Chloroethane ug/L 3.7 U 10.0 3.7 03/06/19 09:44 Chloroform ug/L 0.32 U 1.0 0.32 03/06/19 09:44 Chloromethane ug/L 0.97 U 1.0 0.97 03/06/19 09:44 cis-1,2-Dichloroethene ug/L 0.27 U 1.0 0.27 03/06/19 09:44 cis-1,3-Dichloropropene ug/L 0.17 U 0.50 0.17 03/06/19 09:44 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/12/2019 09:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 38 QUALITY CONTROL DATA Project: 2018-3057Melreese Golf Course Pace Project No.: 35451862 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 METHOD BLANK: 2812236 Matrix: Water Associated Lab Samples: 35451862001 Parameter Blank Reporting Units Result Limit MDL Analyzed Qualifiers Dibromochloromethane ug/L 0.45 U 2.0 0.45 03/06/19 09:44 Dibromomethane ug/L 0.68 U 2.0 0.68 03/06/19 09:44 Dichlorodifluoromethane ug/L 0.26 U 1.0 0.26 03/06/19 09:44 Ethylbenzene ug/L 0.30 U 1.0 0.30 03/06/19 09:44 lodomethane ug/L 9.3 U 10.0 9.3 03/06/19 09:44 Isopropylbenzene (Cumene) ug/L 0.30 U 1.0 0.30 03/06/19 09:44 m&p-Xylene ug/L 2.1 U 4.0 2.1 03/06/19 09:44 Methyl-tert-butyl ether ug/L 0.51 U 2.0 0.51 03/06/19 09:44 Methylene Chloride ug/L 2.0 U 5.0 2.0 03/06/19 09:44 n-Butylbenzene ug/L 0.20 U 1.0 0.20 03/06/19 09:44 n-Propylbenzene ug/L 0.37 U 1.0 0.37 03/06/19 09:44 o-Xylene ug/L 0.27 U 1.0 0.27 03/06/19 09:44 p-Isopropyltoluene ug/L 0.31 U 5.0 0.31 03/06/19 09:44 sec-Butylbenzene ug/L 0.17 U 1.0 0.17 03/06/19 09:44 Styrene ug/L 0.26 U 1.0 0.26 03/06/19 09:44 tert-Butylbenzene ug/L 0.26 U 1.0 0.26 03/06/19 09:44 Tetrachloroethene ug/L 0.38 U 1.0 0.38 03/06/19 09:44 Toluene ug/L 0.33 U 1.0 0.33 03/06/19 09:44 'ans-1,2-Dichloroethene ug/L 0.23 U 1.0 0.23 03/06/19 09:44 .rans-1,3-Dichloropropene ug/L 0.17 U 0.50 0.17 03/06/19 09:44 Trichloroethene ug/L 0.36 U 1.0 0.36 03/06/19 09:44 Trichlorofluoromethane ug/L 0.35 U 1.0 0.35 03/06/19 09:44 Vinyl acetate ug/L 0.19 U 10.0 0.19 03/06/19 09:44 Vinyl chloride ug/L 0.39 U 1.0 0.39 03/06/19 09:44 Xylene (Total) ug/L 2.1 U 5.0 2.1 03/06/19 09:44 1,2-Dichloroethane-d4 (S) % 103 70-130 03/06/19 09:44 4-Bromofluorobenzene (S) % 94 70-130 03/06/19 09:44 Toluene-d8 (S) % 101 70-130 03/06/19 09:44 LABORATORY CONTROL SAMPLE: 2812237 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 20 20.1 101 70-130 1,1,1-Trichloroethane ug/L 20 18.8 94 70-130 1,1,2,2-Tetrachloroethane ug/L 20 21.3 107 68-125 1,1,2-Trichloroethane ug/L 20 20.1 101 70-130 1,1-Dichloroethane ug/L 20 20.2 101 70-130 1,1-Dichloroethene ug/L 20 18.9 94 66-133 1,1-Dichloropropene ug/L 20 20.3 101 70-130 1,2,3-Trichlorobenzene ug/L 20 21.4 107 64-126 1,2,3-Trichloropropane ug/L 20 21.7 108 62-127 1,2,3-Trimethylbenzene ug/L 20 23.0 115 70-130 1,2,4-Trichlorobenzene ug/L 20 19.4 97 63-124 1,2,4-Trimethylbenzene ug/L 20 20.5 102 70-130 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 38 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057Melreese Golf Course Pace Project No.: 35451862 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE: 2812237 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,2-Dichlorobenzene ug/L 20 19.5 97 70-130 1,2-Dichloroethane ug/L 20 17.7 88 70-130 1,2-Dichloropropane ug/L 20 19.3 97 70-130 1,3,5-Trimethylbenzene ug/L 20 20.2 101 70-130 1,3-Dichlorobenzene ug/L 20 19.5 98 70-130 1,3-Dichloropropane ug/L 20 20.2 101 70-130 1,4-Dichlorobenzene ug/L 20 19.4 97 70-130 2,2-Dichloropropane ug/L 20 20.2 101 59-133 2-Butanone (MEK) ug/L 40 44.2 111 47-143 2-Chloroethylvinyl ether ug/L 20 20.2 I 101 41-140 2-Chlorotoluene ug/L 20 20.1 101 70-130 2-Hexanone ug/L 40 46.8 117 48-145 4-Chlorotoluene ug/L 20 20.1 101 70-130 4-Methyl-2-pentanone (MIBK) ug/L 40 48.9 122 57-132 Acetone ug/L 40 48.2 120 46-148 Benzene ug/L 20 19.7 99 70-130 Bromobenzene ug/L 20 20.1 100 70-130 Bromochloromethane ug/L 20 19.0 95 70-130 Bromodichloromethane ug/L 20 18.4 92 70-130 Bromoform ug/L 20 17.3 87 49-126 Bromomethane ug/L 20 9.7 48 10-165 v2 Carbon disulfide ug/L 20 26.3 131 60-141 v1 Carbon tetrachloride ug/L 20 20.8 104 63-126 Chlorobenzene ug/L 20 19.2 96 70-130 Chloroethane ug/L 20 22.2 111 71-142 Chloroform ug/L 20 19.2 96 70-130 Chloromethane ug/L 20 16.2 81 40-140 v2 cis-1,2-Dichloroethene ug/L 20 19.3 96 70-130 cis-1,3-Dichloropropene ug/L 20 16.3 82 70-130 Dibromochloromethane ug/L 20 15.4 77 62-118 Dibromomethane ug/L 20 18.3 92 70-130 Dichlorodifluoromethane ug/L 20 20.2 101 47-150 Ethylbenzene ug/L 20 20.0 100 70-130 lodomethane ug/L 40 21.7 54 10-164 v2 Isopropylbenzene (Cumene) ug/L 20 19.6 98 70-130 m&p-Xylene ug/L 40 40.4 101 70-130 Methyl-tert-butyl ether ug/L 20 22.3 112 64-124 Methylene Chloride ug/L 20 18.2 91 65-136 n-Butylbenzene ug/L 20 20.5 102 70-130 n-Propylbenzene ug/L 20 21.2 106 70-130 o-Xylene ug/L 20 19.1 96 70-130 p-lsopropyltoluene ug/L 20 17.4 87 70-130 sec-Butylbenzene ug/L 20 20.6 103 70-130 Styrene ug/L 20 18.0 90 70-130 tert-Butylbenzene ug/L 20 20.7 103 70-130 Tetrachloroethene ug/L 20 19.7 98 64-134 Toluene ug/L 20 20.4 102 70-130 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 38 www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057Melreese Golf Course Pace Project No.: 35451862 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE: 2812237 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers trans-1,2-Dichloroethene ug/L 20 19.7 98 68-127 trans-1,3-Dichloropropene ug/L 20 16.0 80 65-121 Trichloroethene ug/L 20 19.2 96 70-130 Trichlorofluoromethane ug/L 20 22.0 110 65-135 Vinyl acetate ug/L 20 24.4 122 60-144 Vinyl chloride ug/L 20 19.1 95 68-131 Xylene (Total) ug/L 60 59.5 99 70-130 1,2-Dichloroethane-d4 (S) % 101 70-130 4-Bromofluorobenzene (S) % 95 70-130 Toluene-d8 (S) % 99 70-130 MATRIX SPIKE SAMPLE: 2812239 Parameter 35451633002 Spike MS MS % Rec Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 0.32 U 20 13.3 67 70-130 J(M1) 1,1,1-Trichloroethane ug/L 0.30 U 20 14.4 72 70-130 1,1,2,2-Tetrachloroethane ug/L 0.20 U 20 14.9 74 68-125 1,1,2-Trichloroethane ug/L 0.30 U 20 13.9 70 70-130 ,1-Dichloroethane ug/L 0.34 U 20 15.4 77 70-130 1,1-Dichloroethene ug/L 0.27 U 20 16.8 84 66-133 1,1-Dichloropropene ug/L 0.31 U 20 14.3 71 70-130 1,2,3-Trichlorobenzene ug/L 0.34 U 20 11.7 59 64-126 J(M1) 1,2,3-Trichloropropane ug/L 1.1 U 20 13.5 68 62-127 1,2,3-Trimethylbenzene ug/L 0.17 U 20 16.3 82 70-130 1,2,4-Trichlorobenzene ug/L 0.32 U 20 10.7 54 63-124 J(M1) 1,2,4-Trimethylbenzene ug/L 0.24 U 20 12.8 64 70-130 J(M1) 1,2-Dichlorobenzene ug/L 0.29 U 20 12.7 64 70-130 J(M1) 1,2-Dichloroethane ug/L 0.27 U 20 13.1 66 70-130 J(M1) 1,2-Dichloropropane ug/L 0.23 U 20 13.9 70 70-130 1,3,5-Trimethylbenzene ug/L 0.24 U 20 13.1 65 70-130 J(M1) 1,3-Dichlorobenzene ug/L 0.33 U 20 12.9 64 70-130 J(M1) 1,3-Dichloropropane ug/L 0.26 U 20 13.4 67 70-130 J(M1) 1,4-Dichlorobenzene ug/L 0.28 U 20 13.0 65 70-130 J(M1) 2,2-Dichloropropane ug/L 0.59 U 20 12.5 62 59-133 2-Butanone (MEK) ug/L 7.5 U 40 30.1 75 47-143 2-Chloroethylvinyl ether ug/L 1.4 U 20 1.4 U 0 41-140 J(M1) 2-Chlorotoluene ug/L 0.28 U 20 13.2 66 70-130 J(M1) 2-Hexanone ug/L 0.85 U 40 28.5 71 48-145 4-Chlorotoluene ug/L 0.22 U 20 13.3 66 70-130 J(M1) 4-Methyl-2-pentanone (MIBK) ug/L 0.32 U 40 0.32 U 0 57-132 J(M1) Acetone ug/L 5.3 U 40 36.7 82 46-148 Benzene ug/L 0.30 U 20 14.2 71 70-130 Bromobenzene ug/L 0.21 U 20 14.0 70 70-130 Bromochloromethane ug/L 0.37 U 20 13.8 69 70-130 J(M1) Bromodichloromethane ug/L 0.19 U 20 13.4 67 70-130 J(M1) Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 38 . aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057Melreese Golf Course Pace Project No.: 35451862 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 MATRIX SPIKE SAMPLE: 2812239 Parameter 35451633002 Spike MS MS % Rec Units Result Conc. Result % Rec Limits Qualifiers Bromoform ug/L 2.6 U 20 11.8 59 49-126 Bromomethane ug/L 4.0 U 20 9.1 46 10-165 v2 Carbon disulfide ug/L 0.45 U 20 22.6 113 60-141 v1 Carbon tetrachloride ug/L 1.1 U 20 15.4 77 63-126 Chlorobenzene ug/L 0.35 U 20 13.5 67 70-130 J(M1) Chloroethane ug/L 3.7 U 20 20.6 103 71-142 Chloroform ug/L 0.32 U 20 14.3 71 70-130 Chloromethane ug/L 0.97 U 20 14.1 70 40-140 v2 cis-1,2-Dichloroethene ug/L 0.27 U 20 14.1 71 70-130 cis-1,3-Dichloropropene ug/L 0.17 U 20 10.3 52 70-130 J(M1) Dibromochloromethane ug/L 0.45 U 20 10.2 51 62-118 J(M1) Dibromomethane ug/L 0.68 U 20 12.4 62 70-130 J(M1) Dichlorodifluoromethane ug/L 0.26 U 20 18.0 90 47-150 Ethylbenzene ug/L 0.30 U 20 13.5 68 70-130 J(M1) lodomethane ug/L 9.3 U 40 9.3 U 21 10-164 v2 Isopropylbenzene (Cumene) ug/L 0.30 U 20 12.2 61 70-130 J(M1) m&p-Xylene ug/L 2.1 U 40 27.0 68 70-130 J(M1) Methyl-tert-butyl ether ug/L 0.51 U 20 14.7 74 64-124 Methylene Chloride ug/L 2.0 U 20 14.4 72 65-136 n-Butylbenzene ug/L 0.20 U 20 12.4 62 70-130 J(M1) n-Propylbenzene ug/L 0.37 U 20 14.2 71 70-130 o-Xylene ug/L 0.27 U 20 11.7 59 70-130 J(M1) p-Isopropyltoluene ug/L 0.31 U 20 10.7 54 70-130 J(M1) sec-Butylbenzene ug/L 0.17 U 20 13.5 68 70-130 J(M1) Styrene ug/L 0.26 U 20 11.5 57 70-130 J(M1) tert-Butylbenzene ug/L 0.26 U 20 13.6 68 70-130 J(M1) Tetrachloroethene ug/L 0.38 U 20 12.8 64 64-134 Toluene ug/L 0.33 U 20 14.3 72 70-130 trans-1,2-Dichloroethene ug/L 0.23 U 20 14.8 74 68-127 trans-1,3-Dichloropropene ug/L 0.17 U 20 10.6 53 65-121 J(M1) Trichloroethene ug/L 0.36 U 20 13.4 67 70-130 J(M1) Trichlorofluoromethane ug/L 0.35 U 20 18.5 92 65-135 Vinyl acetate ug/L 0.19 U 20 15.3 76 60-144 Vinyl chloride ug/L 0.39 U 20 16.4 82 68-131 Xylene (Total) ug/L 2.1 U 60 38.8 65 70-130 MS 1,2-Dichloroethane-d4 (S) % 104 70-130 4-Bromofluorobenzene (S) % 90 70-130 Toluene-d8 (S) % 98 70-130 SAMPLE DUPLICATE: 2812238 35451633001 Dup Parameter Units Result Result RPD Max RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L 0.32 U 0.32 U 40 1,1,1-Trichloroethane ug/L 0.30 U 0.30 U 40 1,1,2,2-Tetrachloroethane ug/L 0.20 U 0.20 U 40 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/12/2019 09:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 38 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057Melreese Golf Course Pace Project No.: 35451862 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 SAMPLE DUPLICATE: 2812238 Parameter 35451633001 Dup Max Units Result Result RPD RPD Qualifiers 1,1,2-Trichloroethane ug/L 0.30 U 0.30 U 40 1,1-Dichloroethane ug/L 0.34 U 0.34 U 40 1,1-Dichloroethene ug/L 0.27 U 0.27 U 40 1,1-Dichloropropene ug/L 0.31 U 0.31 U 40 1,2,3-Trichlorobenzene ug/L 0.34 U 0.34 U 40 1,2,3-Trichloropropane ug/L 1.1 U 1.1 U 40 1,2,3-Trimethylbenzene ug/L 0.17 U 0.17 U 40 1,2,4-Trichlorobenzene ug/L 0.32 U 0.32 U 40 1,2,4-Trimethylbenzene ug/L 0.24 U 0.24 U 40 1,2-Dichlorobenzene ug/L 0.29 U 0.29 U 40 1,2-Dichloroethane ug/L 0.27 U 0.27 U 40 1,2-Dichloropropane ug/L 0.23 U 0.23 U 40 1,3,5-Trimethylbenzene ug/L 0.24 U 0.24 U 40 1,3-Dichlorobenzene ug/L 0.33 U 0.33 U 40 1,3-Dichloropropane ug/L 0.26 U 0.26 U 40 1,4-Dichlorobenzene ug/L 0.28 U 0.28 U 40 2,2-Dichloropropane ug/L 0.59 U 0.59 U 40 2-Butanone (MEK) ug/L 7.5 U 7.5 U 40 2-Chloroethylvinyl ether ug/L 1.4 U 1.4 U 40 ?-Chlorotoluene ug/L 0.28 U 0.28 U 40 .-Hexanone ug/L 0.85 U 0.85 U 40 4-Chlorotoluene ug/L 0.22 U 0.22 U 40 4-Methyl-2-pentanone (MIBK) ug/L 0.32 U 0.32 U 40 Acetone ug/L 5.3 U 5.3 U 40 Benzene ug/L 0.30 U 0.30 U 40 Bromobenzene ug/L 0.21 U 0.21 U 40 Bromochloromethane ug/L 0.37 U 0.37 U 40 Bromodichloromethane ug/L 0.19 U 0.19 U 40 Bromoform ug/L 2.6 U 2.6 U 40 Bromomethane ug/L 4.0 U 4.0 U 40 v2 Carbon disulfide ug/L 0.45 U 0.45 U 40 v1 Carbon tetrachloride ug/L 1.1 U 1.1 U 40 Chlorobenzene ug/L 0.35 U 0.35 U 40 Chloroethane ug/L 3.7 U 3.7 U 40 Chloroform ug/L 0.32 U 0.32 U 40 Chloromethane ug/L 0.97 U 0.97 U 40 v2 cis-1,2-Dichloroethene ug/L 0.27 U 0.27 U 40 cis-1,3-Dichloropropene ug/L 0.17 U 0.17 U 40 Dibromochloromethane ug/L 0.45 U 0.45 U 40 Dibromomethane ug/L 0.68 U 0.68 U 40 Dichlorodifluoromethane ug/L 0.26 U 0.26 U 40 Ethylbenzene ug/L 0.30 U 0.30 U 40 lodomethane ug/L 9.3 U 9.3 U 40 v2 Isopropylbenzene (Cumene) ug/L 0.30 U 0.30 U 40 m&p-Xylene ug/L 2.1 U 2.1 U 40 Methyl-tert-butyl ether ug/L 0.51 U 0.51 U 40 Methylene Chloride ug/L 2.0 U 2.0 U 40 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/12/2019 09:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 38 PaceAnalytical wvnv.pacelabs.corn QUALITY CONTROL DATA Project: 2018-3057Melreese Golf Course Pace Project No.: 35451862 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 SAMPLE DUPLICATE: 2812238 Parameter 35451633001 Dup Max Units Result Result RPD RPD Qualifiers n-Butylbenzene ug/L 0.20 U 0.20 U 40 n-Propylbenzene ug/L 0.37 U 0.37 U 40 o-Xylene ug/L 0.27 U 0.27 U 40 p-Isopropyltoluene ug/L 0.31 U 0.31 U 40 sec-Butylbenzene ug/L 0.17 U 0.17 U 40 Styrene ug/L 0.26 U 0.26 U 40 tert-Butylbenzene ug/L 0.26 U 0.26 U 40 Tetrachloroethene ug/L 0.38 U 0.38 U 40 Toluene ug/L 0.33 U 0.33 U 40 trans-1,2-Dichloroethene ug/L 0.23 U 0.23 U 40 trans-1,3-Dichloropropene ug/L 0.17 U 0.17 U 40 Trichloroethene ug/L 0.36 U 0.36 U 40 Trichlorofluoromethane ug/L 0.35 U 0.35 U 40 Vinyl acetate ug/L 0.19 U 0.19 U 40 Vinyl chloride ug/L 0.39 U 0.39 U 40 Xylene (Total) ug/L 2.1 U 2.1 U 40 1,2-Dichloroethane-d4 (S) % 103 104 0 40 4-Bromofluorobenzene (S) % 89 91 3 40 Y Toluene-d8 (S) % 100 100 0 40 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 38 ceAnalytical www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA Project: 2018-3057Melreese Golf Course Pace Project No.: 35451862 QC Batch: 520947 Analysis Method: EPA 8081 QC Batch Method: EPA3510 Analysis Description: 8081 GCS Pesticides Associated Lab Samples: 35451862001 METHOD BLANK: 2813016 Matrix: Water Associated Lab Samples: 35451862001 Parameter Blank Reporting Units Result Limit MDL Analyzed Qualifiers 4,4'-DDD ug/L 0.0089 U 0.010 0.0089 03/08/19 02:42 4,4'-DDE ug/L 0.0050 U 0.010 0.0050 03/08/19 02:42 4,4'-DDT ug/L 0.0050 U 0.010 0.0050 03/08/19 02:42 Aldrin ug/L 0.0015 U 0.010 0.0015 03/08/19 02:42 alpha-BHC ug/L 0.0021 U 0.010 0.0021 03/08/19 02:42 beta-BHC ug/L 0.0080 U 0.010 0.0080 03/08/19 02:42 Chlordane (Technical) ug/L 0.18 U 0.50 0.18 03/08/19 02:42 delta-BHC ug/L 0.0048 U 0.010 0.0048 03/08/19 02:42 Dieldrin ug/L 0.0020 U 0.010 0.0020 03/08/19 02:42 Endosulfan I ug/L 0.0051 U 0.010 0.0051 03/08/19 02:42 Endosulfan II ug/L 0.0040 U 0.010 0.0040 03/08/19 02:42 Endosulfan sulfate ug/L 0.0062 U 0.10 0.0062 03/08/19 02:42 Endrin ug/L 0.0043 U 0.010 0.0043 03/08/19 02:42 Endrin aldehyde ug/L 0.0036 U 0.10 0.0036 03/08/19 02:42 -ndrin ketone ug/L 0.0050 U 0.010 0.0050 03/08/19 02:42 jamma-BHC (Lindane) ug/L 0.0022 U 0.010 0.0022 03/08/19 02:42 Heptachlor ug/L 0.0062 U 0.010 0.0062 03/08/19 02:42 Heptachlor epoxide ug/L 0.0052 U 0.010 0.0052 03/08/19 02:42 Methoxychlor ug/L 0.0096 U 0.010 0.0096 03/08/19 02:42 Toxaphene ug/L 0.25 U 0.50 0.25 03/08/19 02:42 Decachlorobiphenyl (S) % 48 10-132 03/08/19 02:42 Tetrachloro-m-xylene (S) % 67 27-124 03/08/19 02:42 LABORATORY CONTROL SAMPLE & LCSD: 2813017 2813251 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers 4,4'-DDD ug/L 0.5 0.50 0.52 99 103 67-133 4 40 4,4'-DDE ug/L 0.5 0.48 0.50 96 100 59-125 3 40 4,4'-DDT ug/L 0.5 0.51 0.52 102 104 54-132 2 40 Aldrin ug/L 0.5 0.43 0.44 87 88 25-116 2 40 alpha-BHC ug/L 0.5 0.51 0.54 102 109 53-126 6 40 beta-BHC ug/L 0.5 0.51 0.53 101 107 62-130 5 40 delta-BHC ug/L 0.5 0.47 0.52 95 104 35-122 10 40 Dieldrin ug/L 0.5 0.56 0.59 112 118 66-128 5 40 Endosulfan I ug/L 0.5 0.49 0.51 97 102 67-125 4 40 Endosulfan II ug/L 0.5 0.44 0.47 89 95 67-131 7 40 Endosulfan sulfate ug/L 0.5 0.44 0.48 88 96 62-127 9 40 Endrin ug/L 0.5 0.55 0.58 110 115 66-130 5 40 Endrin aldehyde ug/L 0.5 0.45 0.51 90 102 61-124 12 40 Endrin ketone ug/L 0.5 0.46 0.49 91 98 65-132 7 40 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/12/2019 09:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 38 ace Analytical www.pacelabscom Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA Project: 2018-3057Melreese Golf Course Pace Project No.: 35451862 LABORATORY CONTROL SAMPLE & LCSD: 2813017 2813251 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers gamma-BHC (Lindane) ug/L 0.5 0.54 0.57 108 115 58-127 6 40 Heptachlor ug/L 0.5 0.45 0.48 90 95 35-123 5 40 Heptachlor epoxide ug/L 0.5 0.51 0.53 102 106 62-125 4 40 Methoxychlor ug/L 0.5 0.48 0.50 96 101 59-135 4 40 Decachlorobiphenyl (S) % 47 46 10-132 Tetrachloro-m-xylene (S) % 74 74 27-124 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 38 www,pacelabs.com QUALITY CONTROL DATA Project: 2018-3057Melreese Golf Course Pace Project No.: 35451862 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521006 Analysis Method: EPA 8270 by SIM QC Batch Method: EPA 3510 Analysis Description: 8270 Water PAHLV by SIM MSSV Associated Lab Samples: 35451862001 METHOD BLANK: 2813544 Matrix: Water Associated Lab Samples: 35451862001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1-Methylnaphthalene ug/L 0.19 U 2.0 0.19 03/07/19 08:37 2-Methylnaphthalene ug/L 0.68 U 2.0 0.68 03/07/19 08:37 Acenaphthene ug/L 0.040 U 0.50 0.040 03/07/19 08:37 Acenaphthylene ug/L 0.030 U 0.50 0.030 03/07/19 08:37 Anthracene ug/L 0.043 U 0.50 0.043 03/07/19 08:37 Benzo(a)anthracene ug/L 0.055 U 0.10 0.055 03/07/19 08:37 Benzo(a)pyrene ug/L 0.12 U 0.20 0.12 03/07/19 08:37 Benzo(b)fluoranthene ug/L 0.027 U 0.10 0.027 03/07/19 08:37 Benzo(g,h,i)perylene ug/L 0.15 U 0.50 0.15 03/07/19 08:37 Benzo(k)fluoranthene ug/L 0.16 U 0.50 0.16 03/07/19 08:37 Chrysene ug/L 0.026 U 0.50 0.026 03/07/19 08:37 Dibenz(a,h)anthracene ug/L 0.13 U 0.15 0.13 03/07/19 08:37 Fluoranthene ug/L 0.018 U 0.50 0.018 03/07/19 08:37 Fluorene ug/L 0.088 U 0.50 0.088 03/07/19 08:37 ideno(1,2,3-cd)pyrene ug/L 0.12 U 0.15 0.12 03/07/19 08:37 Naphthalene ug/L 0.29 U 2.0 0.29 03/07/19 08:37 Phenanthrene ug/L 0.16 U 0.50 0.16 03/07/19 08:37 Pyrene ug/L 0.032 U 0.50 0.032 03/07/19 08:37 2-Fluorobiphenyl (S) % 63 33-82 03/07/19 08:37 p-Terphenyl-d14 (S) % 102 49-104 03/07/19 08:37 LABORATORY CONTROL SAMPLE: 2813545 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1-Methylnaphthalene ug/L 5 3.3 66 40-96 2-Methylnaphthalene ug/L 5 3.3 65 40-94 Acenaphthene ug/L 5 3.2 65 42-96 Acenaphthylene ug/L 5 3.2 63 39-90 Anthracene ug/L 5 3.7 75 46-109 Benzo(a)anthracene ug/L 5 4.1 83 50-116 Benzo(a)pyrene ug/L 5 4.1 83 48-117 Benzo(b)fluoranthene ug/L 5 4.2 85 51-124 Benzo(g,h,i)perylene ug/L 5 4.1 83 47-121 Benzo(k)fluoranthene ug/L 5 4.4 88 50-125 Chrysene ug/L 5 4.4 87 53-122 Dibenz(a,h)anthracene ug/L 5 4.0 80 45-123 Fluoranthene ug/L 5 4.5 90 52-119 Fluorene ug/L 5 3.4 68 44-100 Indeno(1,2,3-cd)pyrene ug/L 5 4.0 79 46-121 Naphthalene ug/L 5 3.2 64 40-91 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 38 QUALITY CONTROL DATA Project: 2018-3057Melreese Golf Course Pace Project No.: 35451862 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE: 2813545 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phenanthrene ug/L 5 3.7 73 47-111 Pyrene ug/L 5 4.4 88 51-120 2-Fluorobiphenyl (S) % 71 33-82 p-Terphenyl-d14 (S) % 98 49-104 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2813901 2813902 MS MSD 35452061003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1-Methylnaphthalene ug/L 0.19 U 5 5 3.1 3.1 62 62 40-96 1 40 2-Methylnaphthalene ug/L 0.68 U 5 5 3.2 3.1 64 61 40-94 4 40 Acenaphthene ug/L 0.040 U 5 5 3.0 3.2 60 63 42-96 4 40 Acenaphthylene ug/L 0.030 U 5 5 2.9 3.0 58 61 39-90 4 40 Anthracene ug/L 0.043 U 5 5 3.7 3.9 74 78 46-109 5 40 Benzo(a)anthracene ug/L 0.055 U 5 5 4.0 4.2 81 83 50-116 3 40 Benzo(a)pyrene ug/L 0.12 U 5 5 4.0 4.0 81 79 48-117 2 40 Benzo(b)fluoranthene ug/L 0.027 U 5 5 4.0 4.0 81 80 51-124 1 40 Benzo(g,h,i)perylene ug/L 0.15 U 5 5 4.0 3.8 79 77 47-121 3 40 Benzo(k)fluoranthene ug/L 0.16 U 5 5 4.2 4.1 84 82 50-125 2 40 Chrysene ug/L 0.026 U 5 5 4.2 4.2 84 85 53-122 1 40 Dibenz(a,h)anthracene ug/L 0.13 U 5 5 3.9 3.7 77 74 45-123 4 40 Fluoranthene ug/L 0.018 U 5 5 4.5 4.7 89 94 52-119 5 40 Fluorene ug/L 0.088 U 5 5 3.2 3.4 65 69 44-100 5 40 Indeno(1,2,3-cd)pyrene ug/L 0.12 U 5 5 3.9 3.7 77 75 46-121 3 40 Naphthalene ug/L 0.29 U 5 5 2.9 2.9 58 58 40-91 0 40 Phenanthrene ug/L 0.16 U 5 5 3.7 3.8 73 77 47-111 4 40 Pyrene ug/L 0.032 U 5 5 4.4 4.5 87 91 51-120 4 40 2-Fluorobiphenyl (S) % 68 70 33-82 p-Terphenyl-d14 (S) % 97 98 49-104 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 38 aceAnalytical wwwpacelabs.com QUALITY CONTROL DATA Project: 2018-3057Melreese Golf Course Pace Project No.: 35451862 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521011 Analysis Method: FL -PRO QC Batch Method: EPA 3510 Analysis Description: FL -PRO Water Low Volume Associated Lab Samples: 35451862001 METHOD BLANK: 2813560 Matrix: Water Associated Lab Samples: 35451862001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Petroleum Range Organics mg/L 0.80 U 1.0 0.80 03/07/19 12:40 N-Pentatriacontane (S) % 86 42-159 03/07/19 12:40 o-Terphenyl (S) % 79 66-139 03/07/19 12:40 LABORATORY CONTROL SAMPLE: 2813561 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Petroleum Range Organics N-Pentatriacontane (S) o-Terphenyl (S) mg/L % % 5 4.4 87 66-119 99 42-159 94 66-139 MATRIX SPIKE SAMPLE: 2814271 35452019001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Petroleum Range Organics mg/L 0.73 U 4.6 3.9 80 65-123 N-Pentatriacontane (S) % 89 42-159 o-Terphenyl (S) % 90 66-139 SAMPLE DUPLICATE: 2814272 35451859001 Dup Parameter Units Result Result RPD Max RPD Qualifiers Petroleum Range Organics mg/L 0.79 U 0.77 U N-Pentatriacontane (S) % 97 91 o-Terphenyl (S) % 81 89 9 7 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 21 of 38 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALIFIERS Project: 2018-3057Melreese Golf Course Pace Project No.: 35451862 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: 520947 [M5] A matrix spike/matrix spike duplicate was not performed for this batch due to insufficient sample volume. ANALYTE QUALIFIERS The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. U Compound was analyzed for but not detected. 1 p A matrix spike/matrix spike duplicate was not performed for this batch due to insufficient sample volume. J(M1) Estimated Value. Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. MS Analyte recovery in the matrix spike was outside QC limits for one or more of the constituent analytes used in the calculated result. Y The laboratory analysis was from an improperly preserved sample. c2 Acid preservation may not be appropriate for the analysis of 2-Chloroethylvinyl ether. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. Date: 03/12/2019 09:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 22 of 38 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057Melreese Golf Course Pace Project No.: 35451862 Lab ID Sample ID QC Batch Method Analytical QC Batch Analytical Method Batch 35451862001 MW-42 EPA 3510 520947 EPA 8081 521160 35451862001 MW-42 EPA 3510 521011 FL -PRO 521222 35451862001 MW-42 EPA 3010 521178 EPA 6010 521271 35451862001 MW-42 EPA 7470 521100 EPA 7470 521259 35451862001 MW-42 EPA 3510 521006 EPA 8270 by SIM 521083 35451862001 MW-42 EPA 8260 520786 Date: 03/12/2019 09:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 38 rceAna!}1iral • TCheHWo A ti I ,+iral Request Document • 35451362 'ust be completed accurately. Required Client Information: Required Project Information: 1111 I IIII I' I' III' II'I� Page : 1 Of 1 company EE&G Environmental Services, LLC Report To A kkcis et. ti< 35451862 Address 5751 Miami Lakes Dr Copy To'. �' G1 ,,,6,,.— Hial FL 33014 Regulatory Agency Emaeah. M1%-n e 'FRf,, Purchase Order JJ. GoQ- C'::,urse / Pace Quote Phone' (305)374-8300 I ax L)co,� Project Name eAset'a� Pace Project Manager chrislina raschke@pacelabs.com, (- State / Location • Requested Due Date. �,M ?� l,/Sc 1 Project #: 2018-305 Pace Profile JJ / FL Requ tA al ' Fit ered (Y/N) # W ~ SAMPLE ID One Character per box. (AZ, 0-9I , -) Sample Ids must be unique MATRIX CODE Dnnklnq Wnirr DW Water Wi Wrier VV., WW Product P 011 Sod/Solid�� Moe WP Air A Otncr O7 n,:nr Ts t MATRIX CODE (see valid codes Io left) SAMPLE TYPE (G=GRAG C=COMP) COLLECTED ISAMPLE TEMP AT COLLECTION 1+OF CONTAINERS Preservatives Z >- t) o START END m 2 e O IH2SO4 M p _ = _ O Z 1 Na2S203 c c 2 m 0 Analyses Test 8260 VOC PAH by 8270 SIM TRPH FL -PRO Pesticides 8081Cs,„ „J Pesticides 814 16"L J ) C.) a) '_9 .D 2 / C`S t. o CV`n X O O 6010; Cd, Cr, Se, Ag, 7470 Hg . ?r a/CP .4k .0•t :S Z t U a DATE TIME DATE TIME 1 i !�1 t,,.� � t,�l tl I'i 111/-C lC-' r `, I •) , IC Y X- �/�/ l` Sr l 7G is 2 3 4 5 6 7 •8 9 10' 11 12 ADDITIONAL COMMENTS REUNQUISHEQBY I AFFIU TION . DATE TIME' '� ACCEPTED BY I AFFILIATION DATE TIME, SAMPLE CONDITIONS , G / � Vic' __1 ' Aft // � - --- 1 `t ll l 3 �A, -7 7 „ -j. > V , \.., �J CD A SAMPLER, NAME AND. SIGNATURE' - - -• r TEMP in C Received an Ice (Y/N) Custody Seated Cooler (Y/N) Samples Intact (Y/N) PRINT Name of SAMPLER: ) SIGNATURE of SAMPLERi� �/., j ti I DATE Signed: / 7 /? r � __�/ / .-P Pico Analytical Document Name -ample Condition Upon Receipt Form Document Revised May 30, 2018 _ Document No F-FL-C-007 rev 13 Issuing Authority Pace Fonda Quality Office W0 :35451862 Project # PP1: CTR Project Manager: CLIENT: 36-EEG Client: Date 3) ) Ci P (0-\cla_ Thermometer Used State of rigi (� (� Cooler #1 Temp.°C 11 (Visual) 0..C� (Correction Factor) 3. V (Actual) Cooler #2 Temp.'C (Visual) 0_ 0 (Correction Factor) (0.0 (Actual) Cooler #3 Temp.'C 5.5 (Visual) 0 - V (Correction Factor) ✓i _ "'� ?(Actual) Cooler#4 Temp.°C (Visual) (Correction Factor) (Actual) Cooler#5 Temp.`C (Visual) (Correction Factor) (Actual) Cooler#6 Temp.°C (Visual) (Correction Factor) (Actual) Due Date: 03/12/19 Courier: ❑ Fed Ex UPS CI USPS Client L' CommerciaI,Pace Shipping Method: = First Overnight = Priority Overnight - Standard Overnight Ground Other Billing: Tracking # E. Recipient Custody Seal on Cooler/Box Present: Packing Material: ILiBubble Wrap Samples shorted to lab (If Yes, complete) Sender `; Third Party = Credit Card 0 Seals intact: 1 ; Yes !c ubble Bags LNone Li Other Shorted Date Comments: Date and Initials of(�p -N-'-t Examining contents: Label: Deliver; pH:_ ❑ For WV projects, all containers verified to 56 `C Samples on ice, cooling process has begun Samples on ice, cooling process has beoun /Samples on ice, cooling process has beoun [, Samples on ice, coolino process has begun L Samples on ice, cooling process has begun L Samples on ice, ccotinc process has begun L, Other 12 International Priority - Unknown Shorted Time flue Dry None Oty: Chain of Custody Present es - No rN/A Chain of Custody Filled Out s _ No ON/A Relinquished Signature & Sampler Name COC eL i� No DN/A Samples Arrived within Hold Time vYesms 1 No ❑N/A Rush TAT requested on COC i iYes N/A Sufficient Volume s E No DN/A Correct Containers Used ,Z^(es E No ❑N/A Containers Intacts r_ No EN/A Sample Labels match COC (sample IDs & date/time of collection) �/^^ ✓''es D No CN/A All containers needing acid/base preservation have been checked.s _ No _iN/A All Containers needing preservation are found to be in compliance with EPA recommendation es _. No EN/A Exceptions: VGA, Coliform, TOC, O&G, Carbamates Preservation Information: Preservative Lot VT race #• /Jrr Date i Initials Headspace in VOA Vials? ( >6mm): .Yes = No I/A Trip Blank Present: E.: Yes E No EN/A Client Notification/ Resolution: Person Contacted: Comments/ Resolution (use back for additional comments): Date/Time Project Manager Review Date: Page 25 of 38 /eAnaIyticaI National Center for Testing & Innovation A\ALYT CAL R L '9O RT March 12, 2019 Pace Analytical - Pompano Beach, FL Sample Delivery Group: L1076226 Samples Received: 03/07/2019 Project Number: 35451862 Description: 2018-3057Melreese golf course Site: 001 Report To: Christina Raschke 3610 Park Central Blvd N Pompano Beach, FL 33064 Entire Report Reviewed By: Jason Romer Project Manager Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace National is performed per guidance provided in laboratory standard operating procedures: 060302. 060303, and 060304. 12065 Lebanon Rd Mount Juliet, TN 37122 615-758-5858 800-767-5859 www.pacenational.com TABLE OF CONTENTS ONE LAB. NATIONWIDE. 4111 Cp: Cover Page 1 Tc: Table of Contents 2 Ss: Sample Summary 3 Cn: Case Narrative 4 Sr: Sample Results 5 MW-42 L1076226-01 5 Qc: Quality Control Summary 6 Chlorinated Acid Herbicides (GC) by Method 8151 6 OP Pesticides by Method 8141 7 GI: Glossary of Terms 10 Al: Accreditations & Locations 11 Sc: Sample Chain of Custody 12 ACCOUNT: Pace Analytical - Pompano Beach, FL Cp Ss 4 Cn Qc GI Al Page 27 of 38 PROJECT: SDG: DATE/TIME: PAGE: 35451862 L1076226 03/12/1913:13 2 of 13 SAMPLE SUMMARY ONE LAB. NATIONWIDE. MW-42 L1076226-01 GW Collected by Collected date/time Received date/time 03/04/1911:14 03/07/19 09:00 Method Chlorinated Acid Herbicides (GC) by Method 8151 OP Pesticides by Method 8141 ACCOUNT: Pace Analytical - Pompano Beach, FL Batch Dilution Preparation Analysis Analyst Location date/time date/time WG1247068 1 03/08/19 08:07 03/09/19 02:16 KLM Mt. Juliet, TN WG1246727 1 03/07/1918:03 03/11/19 17:30 HMH Mt. Juliet, TN Ss 4 Cn 5 Sr 6 QC ?GI Al Page 28 of 38 PROJECT: SDG: DATE/TIME: PAGE: 35451862 L1076226 03/12/1913:13 3 of 13 CASE NARRATIVE ONE LAB. NATIONWIDE. al All sample aliquots were received at the correct temperature, in the proper containers, with the appropriate preservatives, and within method specified holding times, unless qualified or notated within the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data. Jason Romer Project Manager ACCOUNT: Pace Analytical - Pompano Beach, FL Cp Ss Cn 5 Sr 6 Qc GI Al Page 29 of 38 PROJECT: SDG: DATE/TIME: PAGE: 35451862 L1076226 03/12/1913:13 4 of 13 MW-42 SAMPLE RESULTS - 01 Collected date/time: 03/04/19 11:14 L1076226 ONE LAB. NATIONWIDE. ilk Chlorinated Acid Herbicides (GC) by Method 8151 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date/time 2,4-0 0.744 U 0.744 2.00 1 03/09/2019 02:16 WG1247068 Dalapon 1.04 U 1.04 2.00 1 03/09/2019 02:16 WG1247068 2,4-DB 0.775 U 0.775 4.00 1 03/09/2019 02:16 WG1247068 Dicamba 0.813 U 0.813 2.00 1 03/09/2019 02:16 WG1247068 Dichloroprop 0.778 U 0.778 2.00 1 03/09/2019 02:16 WG1247068 Dinoseb 0.795 U 0.795 2.00 1 03/09/2019 02:16 WG1247068 MCPA 13.1 J U 13.1 200 1 03/09/2019 02:16 WG1247068 MCPP 7.15 U 7.15 200 1 03/09/2019 02:16 WG1247068 2,4,5-T 0.843 U 0.843 2.00 1 03/09/2019 02:16 WG1247068 2,4,5-TP (Silvex) 0.845 U 0.845 2.00 1 03/09/2019 02:16 WG1247068 (S) 2,4-Dichlorophenyl Acetic 60.9 14.0-158 03/09/2019 02:16 WG1247068 Acid OP Pesticides by Method 8141 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Azinphos-Methyl 0.348 U 0.348 1.00 1 03/11/201917:30 WG1246727 Bolstar (Sulprofos) 0.205 U 0.205 1.00 1 03/11/201917:30 WG1246727 Chlorpyrifos 0.245 U 0.245 1.00 1 03/11/201917:30 WG1246727 Coumaphos 0.277 U 0.277 1.00 1 03/11/201917:30 WG1246727 Demeton,-0 and -S 0.341 J U 0.341 2.00 1 03/11/201917:30 WG1246727 Diazinon 0.377 U 0.377 1.00 1 03/11/201917:30 WG1246727 Dichlorvos 0.212 U 0.212 2.00 1 03/11/201917:30 WG1246727 Dimethoate 0.105 U 0.105 1.00 1 03/11/201917:30 WG1246727 Disulfoton 0.277 U 0.277 1.00 1 03/11/201917:30 WG1246727 EPN 0.261 J U 0.261 1.00 1 03/11/201917:30 WG1246727 Ethoprop 0.354 U 0.354 1.00 1 03/11/201917:30 WG1246727 Ethyl Parathion 0.292 J U 0.292 1.00 1 03/11/201917:30 WG1246727 Fensulfothion 0.130 U 0.130 1.00 1 03/11/201917:30 WG1246727 Fenthion 0.266 U 0.266 1.00 1 03/11/201917:30 WG1246727 Malathion 0.173 U 0.173 1.00 1 03/11/201917:30 WG1246727 Merphos 0.267 U 0.267 2.00 1 03/11/201917:30 WG1246727 Methyl parathion 0.257 J U 0.257 1.00 1 03/11/201917:30 WG1246727 Mevinphos 0.118 U 0.118 1.00 1 03/11/201917:30 WG1246727 Naled 0.289 J U 0.289 1.00 1 03/11/201917:30 WG1246727 Phorate 0.282 U 0.282 1.00 1 03/11/201917:30 WG1246727 Ronnel 0.252 U 0.252 1.00 1 03/11/2019 17:30 WG1246727 Stirophos 0.226 U 0.226 1.00 1 03/11/201917:30 WG1246727 Sulfotep 0.202 U 0.202 1.00 1 03/11/201917:30 WG1246727 TEPP 9.74 J U 9.74 20.0 1 03/11/201917:30 WG1246727 Tokuthion (Prothothiofos) 0.254 U 0.254 1.00 1 03/11/201917:30 WG1246727 Trichloronate 0.213 U 0.213 1.00 1 03/11/2019 17:30 WG1246727 (5) Triphenyl Phosphate 74.8 42.0-129 03/11/201917.30 WG1246727 ACCOUNT: Pace Analytical - Pompano Beach, FL C(�J 4 Cn Sr 6 Qc GI -Al Page 30 of 38 PROJECT: SDG: DATE/TIME: PAGE: 35451862 L1076226 03/12/1913:13 5 of 13 WG12 )68 QUALITY COr ?OL SUMMARY Chlorinate, ._id Herbicides (GC) by Method 8151 L1L z6-01 ONE LAB. t �NWIDE. Method Blank (MB) (MB) R3390374-1 03/09/19 01:08 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I 2,4-D 0.744 U 0.744 2.00 Dalapon 1.04 U 1.04 2.00 2,4-DB 0.775 U 0.775 4.00 Dicamba 0.813 U 0.813 2.00 Dichloroprop 0.778 U 0.778 2.00 Dinoseb 0.795 U 0.795 2.00 MCPA 13.1 U 13.1 200 MCPP 7.15 U 7.15 200 2,4,5-T 0.843 U 0.843 2.00 2,4,5-TP (Silvex) 0.845 U 0.845 2.00 (S) 2,4-Dichlorophenyl Acetic 66.2 14.0 158 Acid Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3390374-2 03/09/19 01:22 • (LCSD) R3390374-3 03/09/19 01:35 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I % % % % 2,4-0 5.00 3.28 3.31 65.6 66.2 50.0-120 0.910 20 Dalapon 5.00 2.64 2.67 52.8 53.4 32.0-120 1.13 20 2,4-DB 5.00 3.73 4.10 74.6 82.0 53.0-140 P 9.45 20 Dicamba 5.00 3.49 3.50 69.8 70.0 51.0-120 0.286 20 Dichloroprop 5.00 3.26 3.30 65.2 66.0 55.0-127 1.22 20 Dinoseb 5.00 2.21 2.18 44.2 43.6 36.0-134 1.37 20 MCPA 50.0 232 193 464 386 10.0-160 J L P J L 18.4 40 MCPP 50.0 19.9 20.5 39.8 41.0 10.0-160 2.97 23 2,4,5-T 5.00 3.72 3.69 74.4 73.8 54.0-120 0.810 20 2,4,5-TP (Silvex) 5.00 3.69 3.68 73.8 73.6 50.0-125 0.271 20 (5)2,4-Dichlorophenyl Acetic 62.8 60.8 14.0-158 Acid ACCOUNT: Pace Analytical - Pompano Beach, FL Cp 3 SS Cn Sr e QC 7 GI Al Page 31 of 38 PROJECT: SDG: DATE/TIME: PAGE: 35451862 L1076226 03/12/1913:13 6 of 13 WG1246727 QUALITY CONTROL SUMMARY OP Pesticides by Method 8141 L1076226-01 ONE LAB. NATIONWIDE. sk Method Blank (MB) (MB) R3390660-1 03/11/19 11:42 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I Azinphos-Methyl 0.348 U 0.348 1.00 Bolstar (Sulprofos) 0.205 U 0.205 1.00 Chlorpyrifos 0.245 U 0.245 1.00 Coumaphos 0.277 U 0.277 1.00 Demeton,-0 and -5 0.341 U 0.341 2.00 Diazinon 0.377 U 0.377 1.00 Dichlorvos 0.212 U 0.212 2.00 Dimethoate 0.105 U 0.105 1.00 Disulfoton 0.277 U 0.277 1.00 EPN 0.261 U 0.261 1.00 Ethoprop 0.354 U 0.354 1.00 Ethyl Parathion 0.292 U 0.292 1.00 Fensulfothion 0.130 U 0.130 1.00 Fenthion 0.266 U 0.266 1.00 Malathion 0.173 U 0.173 1.00 Merphos 0.267 U 0.267 2.00 Methyl parathion 0.257 U 0.257 1.00 Mevinphos 0.118 U 0.118 1.00 Naled 0.289 U 0.289 1.00 Phorate 0.282 U 0.282 1.00 Ronne) 0.252 U 0.252 1.00 Stirophos 0.226 U 0.226 1.00 Sulfotep 0.202 U 0.202 1.00 TEPP 9.74 U 9.74 20.0 Tokuthion (Prothothiofos) 0.254 U 0.254 1.00 Trichloronate 0.213 U 0.213 1.00 (S) Tripheny/ Phosphate 56.4 42.0-129 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3390660-2 03/11/19 12:45 • (LCSD) R3390660-3 03/11/19 13:17 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I % % % % Azinphos-Methyl 5.00 3.70 4.38 74.0 87.6 43.0-142 16.8 20 Bolstar (Sulprofos) 5.00 3.58 4.03 71.6 80.6 47,0-128 11.8 20 Chlorpyrifos 5.00 3.62 4.26 72.4 85.2 50.0-126 16.2 20 Coumaphos 5.00 3.85 4.40 77.0 88.0 37.0-137 P P 13.3 20 Demeton,-0 and -S 2.50 ND ND 0.000 0.000 22.0-150 J J 0.000 24 Diazinon 5.00 4.14 4.41 82.8 88.2 54.0-130 6.32 20 ACCOUNT: E-dce Analytical - Pompano Beach, FL Cp 2 Tc 3 SS 4 Cn 6 Qc GI AI 3( -"?ge 32 of 38 PROJECT: SDG: DATE/TIME: 'AGE: 35451862 L1076226 03/12/1913:13 7 of 13 WG12 727 QUALITY CO' ROL SUMMARY ONE LAB. OP Pestici.... by Method 8141 L1. .26-01 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3390660-2 03/11/19 12:45 • (LCSD) R3390660-3 03/11/19 13:17 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I % % % % % Dichlorvos 5.00 3.88 4.38 77.6 87.6 43.0-135 12.1 24 Dimethoate 5.00 2.17 2.80 43.4 56.0 27.0-120 25.4 27 Disulfoton 5.00 3.59 4.10 71.8 82.0 44.0-136 13.3 21 EPN 5.00 8.45 9.01 169 180 31.0-143 J J 6.41 21 Ethoprop 5.00 3.76 4.05 75.2 81.0 52.0-130 7.43 20 Ethyl Parathion 5.00 7.36 8.02 147 160 42.0-134 J J 8.58 20 Fensulfothion 5.00 3.79 4.36 75.8 87.2 42.0-137 14.0 20 Fenthion 5.00 3.44 4.03 68.8 80.6 53.0-133 P 15.8 20 Malathion 5.00 3.29 3.56 65.8 71.2 47.0-121 7.88 20 Merphos 5.00 3.48 4.14 69.6 82.8 14.0-123 17.3 25 Methyl parathion 5.00 4.92 6.10 98.4 122 43.0-135 J 21.4 20 Mevinphos 5.00 3.57 4.33 71.4 86.6 49.0-123 19.2 23 Naled 5.00 5.47 7.24 109 145 25.0-126 J 27.9 26 Phorate 5.00 3.60 3.74 72.0 74.8 44.0-129 3.81 20 Ronnel 5.00 3.42 3.93 68.4 78.6 51.0-125 13.9 20 Stirophos 5.00 3.77 4.61 75.4 92.2 53.0-125 20.0 20 Sulfotep 5.00 3.87 4.40 77.4 88.0 40.0-140 12.8 22 TEPP 50.0 17.6 34.2 35.2 68.4 18.0-122 J 64.1 32 Tokuthion (Prothothiofos) 5.00 3.59 4.14 71.8 82.8 50.0-128 14.2 20 Trichloronate 5.00 3.74 4.26 74.8 85.2 47.0-130 13.0 21 (S) Triphenyl Phosphate 68.0 74.6 42.0-129 L1075936-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1075936-01 03/11/19 14:52 • (MS) R3390660-4 03/11/19 15:24 • (MSD) R3390660-5 03/11/19 15:55 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I ug/I % % % % % Azinphos-Methyl 5.00 0.348 3.50 3.62 70.0 72.4 1 29.0-157 3.37 20 Bolstar (Sulprofos) 5.00 0.205 3.33 3.39 66.6 67.8 1 37.0-138 1.79 20 Chlorpyrifos 5.00 0.245 3.63 3.62 72.6 72.4 1 42.0-131 0.276 20 Coumaphos 5.00 0.277 3.74 3.57 74.8 71.4 1 31.0-150 P P 4.65 20 Demeton,-0 and -5 2.50 0.341 0.341 0.341 0.000 0.000 1 30.0-152 J U J U 0.000 20 Diazinon 5.00 0.377 4.06 4.04 81.2 80.8 1 47.0-134 0.494 20 Dichlorvos 5.00 0.212 3.92 3.65 78.4 73.0 1 39.0-140 7.13 22 Dimethoate 5.00 0.105 2.54 2.39 50.8 47.8 1 17.0-129 6.09 20 Disulfoton 5.00 0.277 3.45 3.42 69.0 68.4 1 42.0-131 0.873 21 EPN 5.00 0.261 8.45 8.23 169 165 1 17.0-155 J J P 2.64 20 Ethoprop 5.00 0.354 3.68 3.13 73.6 62.6 1 46.0-133 16.2 20 Ethyl Parathion 5.00 0.292 7.11 7.22 142 144 1 30.0-138 J P J P 1.54 20 ACCOUNT: Pace Analytical - Pompano Beach, FL Cp Tc 3Ss 4 Cn 6 Qc GI AI Page 33 of 38 PROJECT: SDG: DATE/TIME: PAGE: 35451862 L1076226 03/12/1913:13 8 of 13 WG1246727 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. OP Pesticides by Method 8141 L1076226-01 L1075936-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1075936-01 03/11/19 14:52 • (MS) R3390660-4 03/11/19 15:24 • (MSD) R3390660-5 03/11/19 15:55 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I ug/I % % % % % Fensulfothion 5.00 0.130 3.68 3.94 73.6 78.8 1 36.0-145 6.82 20 Fenthion 5.00 0.266 3.44 3.43 68.8 68.6 1 46.0-140 P P 0.291 20 Malathion 5.00 0.173 3.69 3.19 73.8 63.8 1 39.0-126 14.5 20 Merphos 5.00 0.267 2.97 2.82 59.4 56.4 1 10.0-120 5.18 27 Methyl parathion 5.00 0.257 4.89 4.98 97.8 99.6 1 28.0-142 1.82 20 Mevinphos 5.00 0.118 3.61 3.39 72.2 67.8 1 38.0-134 6.29 20 Naled 5.00 0.289 5.51 5.11 110 102 1 14.0-130 7.53 20 Phorate 5.00 0.282 3.44 3.33 68.8 66.6 1 38.0-134 3.25 20 Ronnel 5.00 0.252 3.58 3.21 71.6 64.2 1 42.0-131 10.9 20 Stirophos 5.00 0.226 3.89 3.63 77.8 72.6 1 33.0-143 6.91 20 Sulfotep 5.00 0.202 3.98 3.72 79.6 74.4 1 34.0-143 6.75 20 TEPP 50.0 9.74 30.9 38.7 61.8 77.4 1 38.0-120 22.4 25 Tokuthion (Prothothiofos) 5.00 0.254 3.58 3.48 71.6 69.6 1 35.0-140 2.83 24 Trichloronate 5.00 0.213 3.89 3.58 77.8 71.6 1 41.0-133 8.30 20 (S) Triphenyl Phosphate 67.4 66.0 42.0-129 ACCOUNT: Face Analytical - Pompano Beach, FL ICp 3 SS 4 Cn Sr 7G1 Al ''age 34 of 38 PROJECT: SDG: DATE/TIME: ?AGE: 35451862 L1076226 03/12/19 13:13 9 of 13 GLOSSARY OF TERMS ONE LAB. NATIONWIDE. Guide to Reading and Understanding Your Laboratory Report The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and if you have additional questions please contact your project representative. Abbreviations and Definitions MDL ND RDL Rec. RPD SDG (5) Analyte Dilution Limits Original Sample Qualifier Result Uncertainty (Radiochemistry) Case Narrative (Cn) Quality Control Summary (Qc) Sample Chain of Custody (Sc) Sample Results (Sr) Sample Summary (Ss) Qualifier Method Detection Limit. Not detected at the Reporting Limit (or MDL where applicable). Reported Detection Limit. Recovery. Relative Percent Difference. Sample Delivery Group. Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be detected in all environmental media. The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes reported. If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor. These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or duplicated within these ranges. The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control sample. The Original Sample may not be included within the reported SDG. This column provides a letter and/or number designation that corresponds to additional information concerning the result reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable. The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL" (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte. Confidence level of 2 sigma. A brief discussion about the included sample results, including a discussion of any non -conformances to protocol observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report. This section of the report includes the results of the laboratory quality control analyses required by procedure or analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material. This is the document created in the field when your samples were initially collected. This is used to verify the time and date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the samples from the time of collection until delivery to the laboratory for analysis. This section of your report will provide the results of all testing performed on your samples. These results are provided by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for each sample will provide the name and method number for the analysis reported. This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and times of preparation and/or analysis. Description J L P U The value is outside laboratory established criteria. Off -scale high. Actual value is known to be greater than value given. RPD between the primary and confirmatory analysis exceeded 40%. Indicates the compound was analyzed for but not detected above the method detection limit. ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Pompano Beach, FL 35451862 L1076226 03/12/1913:13 Page 35 of 38 PAGE: 10 of 13 Cp 4 Cn 5 Sr 6 Qc GI Al SC ACCREDITATIONS & LOCATIONS ONE LAB. NATIONWIDE. AIS Pace National is the only environmental laboratory accredited/certified to support your work nationwide from one location. One phone call, one point of contact, one laboratory. No other lab is as accessible or prepared to handle your needs throughout the country. Our capacity and capability from our single location laboratory is comparable to the collective totals of the network laboratories in our industry. The most significant benefit to our one location design is the design of our laboratory campus. The model is conducive to accelerated productivity, decreasing turn -around time, and preventing cross contamination, thus protecting sample integrity. our focus on premium quality and prompt service allows us to be YOUR LAB OF CHOICE. Not all certifications held by the laboratory are applicable to the results reported in the attached report. Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace National. State Accreditations Alabama 40660 Nebraska NE-OS-15-05 Alaska 17-026 Nevada TN-03-2002-34 Arizona AZ0612 New Hampshire 2975 Arkansas 88-0469 New Jersey—NELAP TN002 California 2932 New Mexico' n/a Colorado TN00003 New York 11742 Connecticut PH-0197 North Carolina Env375 Florida E87487 North Carolina' DW21704 Georgia NELAP North Carolina' 41 Georgia' 923 North Dakota R-140 Idaho TN00003 Ohio—VAP CL0069 Illinois 200008 Oklahoma 9915 Indiana C-TN-01 Oregon TN200002 Iowa 364 Pennsylvania 68-02979 Kansas E-10277 Rhode Island LA000356 Kentucky" 90010 South Carolina 84004 Kentucky' 16 South Dakota n/a Louisiana A130792 Tennessee' ° 2006 Louisiana' LA180010 Texas T104704245-18-15 Maine TN0002 Texas6 LAB0152 Maryland 324 Utah TN00003 Massachusetts M-TN003 Vermont VT2006 Michigan 9958 Virginia 460132 Minnesota 047-999-395 Washington C847 Mississippi TN00003 West Virginia 233 Missouri 340 Wisconsin 9980939910 Montana CERT0086 Wyoming A2LA Third Party Federal Accreditations A2LA — ISO 17025 1461.01 A2LA — ISO 17025 6 1461.02 Canada 1461.01 EPA—Crypto TN00003 AIHA-LAP,LLC EMLAP 100789 DOD 1461.01 USDA P330-15-00234 Drinking Water 2 Underground Storage Tanks ' Aquatic Toxicity " Chemical/Microbiological 5 Mold 6 Wastewater n/a Accreditation not applicable Our Locations Pace National has sixty-four client support centers that provide sample pickup and/or the delivery of sampling supplies. If you would like assistance from one of our support offices, please contact our main office. Pace National performs all testing at our central laboratory. ACCOUNT: Pace Analytical - Pompano Beach, FL PROJECT: 35451862 SDG: L1076226 DATE/TIME: 03/12/19 13:13 Ss 4 Cn 5 Sr CC GI Page 36 of 38 PAGE: 11 of 13 0AI Chain of Custody Workorder: 35451862 Workorder Name: Christina Raschke Pace Analytical South Florida 3610 Park Central Blvd N Pompano Beach, FL 33064 Phone (954)582-4300 Email christina.raschke@pacelabs.com State of Sample Origin: FL 2 M W-42 3/4/2019 11:14 2018-3057Melreese Golf Course 35451862001 Water P.O. Results Requested By: 3/12/2019 ace Analytical' www pecelebs. com L10z- LAB USE ONLY' rot 3 4 Transfers 1 Released By Date/Time elf Y3//v/y /ya? Received By 2 Date/Time (9 006 3 rrInlar Temuerature on Receipt °C Custody Seal (Y) or Received on Ice Y or Samples Intact Y or 1.3+0.111- TO L1g1i Dt,- 0 �3 RAD SCREEN: <0.5 rnBI r Wednesday. March 06. 2019 1 56 16 PM FMT-ALL-C-002rev.00 24March2009 Page 1 of Page 37 of 38 Pace Analytical National Center for Testing & Innovation Cooler Receipt Form Client: ?A-C � e FL SDG#: L 1 o t LC( Cooler Received/Opened On: 3 /'-1 /19 'Temperature: l � � Received i;y: Jeremy Webb Signature: :7/-j� - Receipt Check List NP Yes No COC Seal Present / Intact? _ _.- COC Signed / Accurate? - Bottles arrive intact? Correct bottles used? _. Sufficient volume sent? If Applicable VOA Zero headspace? Preservation Correct / Checked? le 38 of 38 aceAnalytical www.pacelabs.com March 28, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451836 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 05, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry, EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 18 aceAnalytical www.pacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451836 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35451836001 MW-42 Water 03/04/19 11:14 03/05/19 17:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 18 2eAnalviical CHAI W°# : 35451836 :ument --. - - 1 he Gha 111 I I III I II I ini )e completed accurately. III Section A Section B Required Client Information: Required Project Information: 35451836 Page : 1 Of 1 Cornpany HAG Environmental Services, I.LC Report To . V.c�af� A,t �'`( ...-. Address 5751 Miami Lakes Dr. Copy To. (' G' e. e rV \ cti qq Company Name Hialeah, FL 33014 U Address Regulatory Agency Email -tgnQTr®rr+y„n ty, , ea�� , C �� �J Purchase Order 5: Pace Quote Phone (305)374-00 lI ax 83 Project Name '1eAr22a _ G ph C z t rse Pace Project Manager. christina raschke@pacelabs. com, /'`. State / Location • Requested Due Dale. ,'j- _..-.:...,— ; f .A- \ Project #: 2018-305/ Pace Profile 1' / FL Requ t l Fil ered (YIN) MATRIX cone MATRIX CODE (see vah d codes to left) ''SAMPLE TYPE (G=GRA.B C=COtdP) COLLECTED SAMPLE TEMP AT COLLECTION OF CONTAINERS Preservatives Z >- �• f) .) Onnking Water OW W;Wr W:rrl-1n Water WW Product P SAMPLE ID Soil/Solid sr oil ol. START END Unpreserved H2SO4 Na2S203 Analyses Test 8260 VOC PAH by 8270 SIM TRPH FL -PRO Pesticides 8081G.A-z ,, Pesticides 81416- Herbicides 8151(6,1. / t on 0.1 co c •x 02. 6010 Ba, Cd, Cr. Se. Ag, 7470 Hg Q-p A5 t :?cola .4k , ce. . G-t '•h -2, ifi Residual Chlorine (Y/N) ill I—Z One Character per box. Wine WP (A-Z, 0.9 I , -) Air AR Sample Ids must be unique ra rr o Sam nszun P q rS DATE TIME DATE TIME m _ u = _ m z °c L m z t O 2 3 4 5 6 7 8 9 10 11 12 ADDITIONAL COMMENTS '. ., RELIN SVED BY/ AFFILIATION - ' DATE c; TIME ', �-.ACCEPTED BY j AFFILIATION..' . - .DATE TIME , -SAMPLE CONDITIONS 6 — '2. ,, �� >>� I(:.): //,7,/�� i' �1.=-11 "- l ; w 3 8 1I ),) Y ( -, - "71-tA,N, \ - LE -) -'))16) rIci-S (s,0 NI i 1, S y jam- % SAMPLER NAME AND SIGNATURE (, TEMP in C Received on Ice (Y/N) usto y Sealed Cooler (Y/N) Samples Intact (YIN) PRINT Name of SAMPLER: 1 \ \ • / C SIGNATURE of SAMPLER: / (.) DATE Signed: co 0 co N m a Sa.m;. Document Rewsec May 30 2018 State ofngii P V" ticia_ Cooler#1 Temp.'C Cooler #2 Temp.'C b�l 11 (Visual) Cooler#3 Temp.'C 51,- , (Visual) t ErriTi (:SCUR) Tine Cooler #4 Temp.'C (Visual) (Correction Factor) (Actual) Cooler#5 Temp.`C (Visual) (Correction Factor) (Actual) Cooler #6 Temp.'C (Visual) (Correction Factor) (Actual) Courier: — Fed Ex - UPS ❑ USPS — Client — Commercial, Pace Shipping Method: - First Overnight i Priority Overnight = Other Billing: = Recipient Tracking # Custody Seal on Cooler/Box Present: Packing Material: _Bubble Wrap Samples shorted to lab (If Yes, complete) 11 Sender ubble Bags ace Analytical WO# 0 384 -- � -,- CTR 51 836 ProjecCL.I6NT: 36-66G OUe Date: 03/15/ Project Manag_ 19 Client: Thermometer Used ' 3 Da:e 3)5) ;eCS a�• Z3—. :,:e"5 ver'':e:: i� � rC _(Visual) , 0 (Correction Factor) 3. C.J (Actual) Samples on ice cxonc process rigs c_ O_ 0 (Correction Factor) ePn_ (J) (Actual) 5ar,ctes a ,ce ccoh p has b__ 0.0 (Correction Factor) 5.5 (Actual) Samoies on ice coolirg process nas ce._ [ Samples on ice, coc:i,ip process has oeoun issuing .Authority Pace Florida Quality O' ice Date and Initials of p Examining content: Label: Deliver pH: , W\i/ [ Samples on ice, coc.. -.. process has Ceou.^ [ Samples or ._.. .,_ _ process has b Other Standard Overnight - Ground = International Priority = Third Party 11 Credit Card Seals intact: — Yes _ i_,None :- Other Shorted Date Comments: Unknown Icy: Wet Blue Dry None Shorted Time Qty Chain of Custody Present es _ No _N/A Chain of Custody Filled Out s = No7iN/A Relinquished Signature & Sampler Name COC e= No =NIA Samples Arrived within Hold Time Yesms - No I N.A Rush TAT requested on COC-YesN/A Sufficient Volume Yes = No =N/A Correct Containers Used es _ No —NIA Containers Intact Miss = No =N/A Sample Labels match COC (sample IDs & date!time of collection) �fes = No =N/A All containers needing acio'case preservation have ceen checked —Yes 11 No ;),d71 All Containers neecino preservation are found to be :n ��� compliance with EPA •ecc�, • e ,._co- _Yes - No sue' " Exceptions \'CA Oolifo . • TOC, C&G Carcamates Preservation Information Preservative rrrlll Lot fl T race • Date i i initials Headspace in VOA Vials? (>6mm): _Yes = No Trip Blank Present. 7Yes = No - �{{A/ Client Notification/ Resolution: Person Contacted Comments( Resolution (use back for additional comments): Date!Time Project Manager Review Da'e Page 4 of 18 72e Analytical www.pacelabs.com Report Prepared for: Christina Raschke PASI Florida 3610 Park Central Blvd N Pompano Beach FL 33064 REPORT OF LABORATORY ANALYSIS FOR PCDD/PCDF Report Prepared Date: March 14, 2019 Report No 104661188290FC_DFR Pace Analytical Services, LLC. 1700 Elm Street Minneapolis, MN 55414 Phone: 612.607.1700 Fax: 612.607.6444 Report Information: Pace Project #: 10466118 Sample Receipt Date: 03/07/2019 Client Project #: 35451836 Client Sub PO #: N/A State Cert #: E87605 Invoicing & Reporting Options: The report provided has been invoiced as a Level 2 PCDD/PCDF Report. If an upgrade of this report package is requested, an additional charge may be applied. Please review the attached invoice for accuracy and forward any questions to Kirsten Hogberg, your Pace Project Manager. This report has been reviewed by: 114-15 March 15, 2019 Kirsten Hogberg, Project Manager (612) 607-6407 (612) 607-6444 (fax) kirsten.hogberg@pacelabs.com Report of Laboratory Analysis Thisreportshouldnotbereproduced,exceptinfull, withoutthewrittenconsentofPaceAnalyticalServices_Inc. Theresultsrelateonlyt othesamplesincludedi nthisreport. Page 5 of 18 Page 1 of 14 /1eAnaIytica/ Pace Analytical Services, LLC. 1700 Elm Street Minneapolis, MN 55414 Phone: 612.607.1700 Fax: 612.607.6444 DISCUSSION This report presents the results from the analysis performed on one sample submitted by a representative of Pace Analytical Services, LLC. The sample was analyzed for the presence or absence of polychlorodibenzo-p-dioxins (PCDDs) and polychlorodibenzofurans (PCDFs) using a modified version of USEPA Method 8290. The reporting limits were based on signal-to-noise measurements. Estimated Maximum Possible Concentration (EMPC) values were treated as positives in the toxic equivalence calculations. Per request, estimated detection limit (EDL) values were provided and flagged "U" where the target analytes were not detected. The recoveries of the isotopically -labeled PCDD/PCDF internal standards in the sample extract ranged from 35-64%. Except for four low values, which were flagged "R" on the results tables, the labeled internal standard recoveries obtained for this project were within the 40-135% target range specified in Method 8290. Also, since the quantification of the native 2,3,7,8-substituted congeners was based on isotope dilution, the data were automatically corrected for recovery and accurate values were obtained. A laboratory method blank was prepared and analyzed with the sample batch as part of our routine quality control procedures. The results show that PCDDs and PCDFs were not detected. These results indicate that the sample preparation procedures did not significantly impact the results of the field sample determinations. Laboratory spike samples were also prepared with the sample batch using clean reference matrix that had been fortified with native standard materials. The results show that the spiked native compounds were recovered at 92-120% with relative percent differences of 0.0-10.3%. These results were within the target ranges for the method. Matrix spikes were not prepared with the sample batch. REPORT OF LABORATORYANALYSIS This report shall not be reproduced, except in full, withoutthe written consent of Pace Analytical Services, Inc. Report No 10466118_8290FC_DFR Page 6 of 18 Page 2 of 14 Minnesota Laboratory Certifications Authority Certificate # Pace Analytical Services. LLC 1700 Elm Street - Suite 200 Minneapolis. MN 55414 Tel: 612-607-1700 Fax:612-607-6444 Authority Certificate # A2LA 2926.01 Minnesota - Pet 1240 Alabama 40770 Mississippi MN00064 Alaska - DW MN00064 Missouri - DW 10100 Alaska - UST 17-009 Montana CERT0092 Arizona AZ0014 Nebraska NE-OS-18-06 Arkansas - DW MN00064 Nevada MN00064 Arkansas - WW 88-0680 New Hampshire 2081 CNMI Saipan MP0003 New Jersey (NE MN002 California 2929 New York 11647 Colorado MN00064 North Carolina 27700 Connecticut PH-0256 North Carolina - 27700 EPA Region 8+ via MN 027-053 North Carolina - 530 Florida (NELAP E87605 North Dakota R-036 Georgia 959 Ohio - DW 41244 Guam 17-001r Ohio - VAP CL101 Hawaii MN00064 Oklahoma 9507 Idaho MN00064 Oregon - Primar MN300001 Illinois 200011 Oregon - Secon MN200001 Indiana C-MN-01 Pennsylvania 68-00563 Iowa 368 Puerto Rico MN00064 Kansas E-10167 South Carolina 74003 Kentucky - DW 90062 South Dakota NA Kentucky - WW 90062 Tennessee TN02818 Louisiana - DE 03086 Texas T104704192 Louisiana - DW MN00064 Utah (NELAP) MN00064 Maine MN00064 Virginia 460163 Maryland 322 Washington C486 Massachusetts M-MN064 West Virginia - 382 Michigan 9909 West Virginia - 9952C Minnesota 027-053-137 Wisconsin 999407970 Minnesota - De via MN 027-053 Wyoming - UST 2926.01 REPORT OF LABORATORYANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466118_8290FC_DFR Page 7 of 18 Page 3 of 14 Appendix A Sample Management Report No 10466118_8290FC_ Analytical Services, Inc. Page 8 of 18 Page 4 of 14 2Ida Od06Z8 81499ti0 L- oN podeei Workorder Name: 2018-3057Melreese Golf Course Chain of Custody II Samples were sent directly to the Subcontracting Laboratory. Workorder: 35451836 Christina Raschke Pace Analytical South Florida 3610 Park Central Blvd N Pompano Beach, FL 33064 Phone (954)582-4300 2 3 4 Transfers 2 3 Released By Cooler Temperature on Receipt l z Pace Analytical Minnesota 1700 Elm Street SE Suite 200 Minneapolis, MN 55414 Phone (612)607-1700 3/4/2019 11:14 35451836001 Water Received By, State Of Origin: FL Cert. Needed: Yes Li No Owner Received Date: 3/5/2019 Date/Time PPG iilh Re nested !ve4..TalyticaI www.peceiabgccom q y 3/15/2019 W011 : 10466118 IIIIIII,YI IIIhNllll _ fclor N Samoles Intacif Y or N —*In order to maintain client confidentiality, location/name of the sampling site, sampler's name and signature may not be provided on this COC documen . This chain of custody is considered complete as is since this information is available in the owner laboratory. 8' LAB USE ONLY Tuesday, March 05, 2019 7:11:20 PM 0 ib Custody Seal Received on ice FMT-ALL-C-002rev.00 24March2009 Page 1 of 1 ��"cc?? P'QcoAn / fCal Document Name: Sample Condition Upon Receipt Form Document Revised: o6Febzol9 Page 1 of 1 Document No.: F-MN-L-213-rev.25 Issuing Authority: Pace Minnesota Quality Office Sample Condition Upon Receipt Courier: Client Name: 11 fare )-06j1 Io�..t(r. Fed Ex CUPS ❑LISPS ❑Client ❑Pace ❑SpeeDee ❑Commercial See Exception Tracking Number: i d ! F f g"Y-Y/ ❑ Custody Seal on Cooler/Box Present? 'es No Seals Intact? Packing Material: (QBubble Wrap �j Thermometer: 0G87A9155100842487A9170600254 Type of Ice: IOiWet Note: Each West Virginia Sample must have temp taken (no temp blanks) Project #: W0# :10466118 PM: KNH Due Date: 03/21/19 CLIENT: PASI—FL Yes DNo Biological Tissue Frozen? ❑Yes END N A Bubble Bags ❑None ❑Other: Temp Blank? ❑YesNo DBlue ❑None ❑Dry ❑Melted Temp should be above freezing to 6°C Correction Factor: Cooler Temp Read w/temp blank: °C Cooler Temp Corrected by/temp blank : oC Average Corrected Temp See Excep ns izr (no to p b ank only): oC USDA Regulated Soil: N/A, water sample/Other: ) Date/Initials of Person Examining Contents: Si 3/ 7 /eT Did samples originate in a quarantine zone within the United States: AL, AR, CA, FL, GA, Did samples originate from a foreign source (internationally, including ID, LA. MS, NC, NM, NY, OK, OR, SC, TN, TX or VA (check maps)? ❑Yes ❑No Hawaii and Puerto Rico)? ❑Yes ❑No If Yes to either question, fill out a Regulated Soil Checklist (F-MN-Q-338) and include with SCUR/COC paperwork. COMMENTS: Chain of Custody Present and Filled Out?diZfc es DNo 1. Chain of Custody Relinquished? ,es DNo 2. Sampler Name and/or Signature on COC? ❑Yes DNo /A 3. Samples Arrived within Hold Time? ,es ❑No 4. Short Hold Time Analysis (<72 hr)? Dyes 2(No a 5. ['Fecal Coliform DHPC ❑Total Coliform/E coli IDBOD/cBOD ❑Hex Chrome ❑Turbidity ❑Nitrate ❑Nitrite ❑Orthophos DOther Rush Turn Around Time Requested? ❑Yes0 6. Sufficient Volume? gy.es ❑N° 7. Correct Containers Used? -Pace Containers Used? Yes ,es ❑No DNo 8. Containers Intact? Xtes DNo 9. Field Filtered Volume Received for Dissolved Tests? ❑Yes DNo /A 10. Is sediment visible in the dissolved container? ❑Yes No Is sufficient information available to reconcile the samples to the COC?/ Matrix: Water ❑Soil ❑Oil ❑Other �/ J 1.1 es s DNo 11. If no, write ID/ Date/Time on Container Below: see Exception El All containers needing acid/base preservation have been checked? All containers needing preservation are found to be in compliance with EPA recommendation? (HNO3, H2SO4, <2pH, NaOH>9 Sulfide, NaOH>12 Cyanide) Exceptions: VOA, Coliform, TOC/DOC Oil and Grease, DRO/8015 (water) and Dioxin/PFAS ❑Yes ❑Yes ❑Yes ❑No ❑No DNo N/A /VA �fd/A 12. Sample # 0 NaOH 1111 HNO3 0H2SO4 ❑zinc Acetate Positive for Res. ❑Yes See Exception Chlorine? 1 No - 0 Headspace in VOA Vials (greater than firm)? JYes [)No l DINIA 13. see Exception III Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes ❑Yes ❑No DNo fffgN/A ./N/A 14. Pace Trip Blank Lot # (if purchased): I CLIENT NOTIFICATION/RESOLUTION Person Contacted: Comments/Resolution: Date/Time: Field Data Required? (!Yes L)ivo Project Manager Review: toce: vrl eia e ,:;-,ace is incorrect preservative, ont of temp, incorrect containers). Date: 3/8/2019 •. .... _.... to :_, : t ... P:c : o!i:. _ H' ^ Ceti..-ation C.fticts l.e Page 10 of 18 Page 6 of 14 Report No 10466118_8290FC_DFR el; / -Pace Analytical Document Name: SCUR Exception Form — Coolers Above 6°C Document Revised: 04Feb2019 Page 1 of I. Document No.: F-11/111I-C-298-Rev.01 issuing Authority: Pace Minnesota Quality Office SCUR Exceptions: During sample triage, this form is to be placed in each cooler that arrives above 6.0 degrees Celsius Workorder #: Out of Temp-Sarriple IDs Container Type # of Contaners If yes, indicate who was contacted/date/time. if no, indicate reason why. Other Issues Issue Type: i Container # of Sample 1D Type Containers Sample ID Multiple Cooler Project? Yes . " ONo_ lliyotFatts* No Temp Blank Read Temp Corrected Temp Average Temp •-'75 Llt,"•-• I D 0 5 tt 1 Tracking Number pH Adjustment Log for Preserved Samples Type of Preserv. pH Amount Upon Date Time Added Lot tt Receipt Adjusted Adjusted (rriL) Added pH In Compliance After after addition? Initials i jYes 0No Lives ON° rives FINo Report No 10466118 8290FC DFR Page 11 of 18 Page 7 of 14 Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 AnalyticalTM Reporting Flags A = Reporting Limit based on signal to noise B = Less than 10x higher than method blank level C = Result obtained from confirmation analysis D = Result obtained from analysis of diluted sample E = Exceeds calibration range I = Interferencepresent J = Estimated value L = Suppressive interference, analyte may be biased low Nn = Value obtained from additional analysis P = PCDEInterference R = Recovery outside target range S = Peak saturated U = Analyte not detected V = Result verified by confirmation analysis X = %D Exceeds limits Y = Calculated using average of daily RFs * = SeeDiscussion REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, withoutthe written consent of Pace Analytical Services, Inc. Report No 10466118_8290FC_DFR Tel: 612-607-1700 Fax: 612-607-6444 Page 12 of 18 Page 8 of 14 Appendix B Sample Analysis Summary Report No 10466118_8290FC_[Ake Analytical Services, Inc. Page 13 of 18 Page 9 of 14 Analytical Client's Sample ID Lab Sample ID Filename Injected By Total Amount Extracted Moisture Dry Weight Extracted ICAL ID CCal Filename(s) Method Blank ID Native Isomers 2,3,7,8-TCDF Total TCDF 2, 3,7, 8-TCD D Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD TM Metho d 8290 Sample Analysis Results Client - PASI Florida MW-42 35451836001 F190313B_12 SMT 1030 mL NA NA F190112 F190313A_18 & F190313B_17 BLANK-68966 Conc pg/L 1.7 U 1.7 U 2.5 U 2.5 U 1.8 U 1.3 U 1.5 U 1.9 U 1.9 U 2.2 U 2.0 U 2.0 U 2.9 U 2.3 U 3.5 U 4.4 U 2.4 U 3.4 U 5.2 U 7.7 U 6.4 U EMPC EDL pg/L pg/L Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612- 607-6444 Matrix Water Dilution NA Collected 03/04/2019 11:14 Received 03/07/2019 08:55 Extracted 03/11/2019 12:00 Analyzed 03/14/2019 04:54 Internal Standards 1.7 2,3,7,8-TCDF-13C 1.7 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 2.5 2,3,4,7,8-PeCDF-13C 2.5 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 1.8 1,2,3,6,7,8-HxCDF-13C 1.3 2,3,4,6,7,8-HxCDF-13C 1.5 1, 2 , 3 , 7, 8, 9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 1.9 1,2, 3,6,7, 8-HxCDD-13C 1.9 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 2.2 2.0 2.0 2.9 2.3 3.5 4.4 2.4 3.4 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 ng's Percent Added Recovery 2.00 60 2.00 61 2.00 53 2.00 52 2.00 59 2.00 57 2.00 54 2.00 64 2.00 55 2.00 56 2.00 56 2.00 43 2.00 38 R 2.00 43 4.00 35 R 2.00 NA 2.00 NA 0.20 87 5.2 Total 2,3,7,8-TCDD 7.7 Equivalence: 0.00 pg/L 6.4 (Lower -bound - Using ITE Factors) 4.5 U 4.5 4.5 U 4.5 OCDF 15 U 15 OCDD 17 U 17 Conc = Concentration (Totals include 2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit R = Recovery outside target range ND = Not Detected NA = Not Applicable NC = Not Calculated REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466118_8290FC_DFR Page 10 of 14 Page 14 of 18 Analytical Lab Sample Name Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) TM Method 8290 Blank Analysis Results DFBLKDC BLANK-68966 F190313B_06 945 mL F190112 F190313A_18 & F190313B_17 Native Conc Isomers pg/L EMPC EDL pg/L pg/L Matrix Dilution Extracted Analyzed Injected By Internal Standards Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis. MN 55414 Tel 612-607-1700 Fax: 612-607-6444 Water NA 03/11/2019 12:00 03/14/2019 00:29 SMT 2,3,7,8-TCDF 2.1 U Total TCDF 2.1 U 2,3,7,8-TCDD 2.3 U Total TCDD 2.3 U 1,2,3,7,8-PeCDF 2.0 U 2,3,4,7,8-PeCDF 1.6 U Total PeCDF 1.8 U 1,2,3,7,8-PeCDD 1.8 U Total PeCDD 1.8 U 1,2,3,4,7,8-HxCDF 2.1 U 1,2,3,6,7,8-HxCDF 1.9 U 2,3,4,6,7,8-HxCDF 1.8 U 1,2,3,7,8,9-HxCDF 2.1 U Total HxCDF 2.0 U 1,2,3,4,7,8-HxCDD 2.1 U 1,2,3,6,7,8-HxCDD 2.2 U 1,2,3,7,8,9-HxCDD 1.8 U Total HxCDD 2.0 U 1,2,3,4,6,7,8-HpCDF 3.0 U 1,2,3,4,7,8,9-HpCDF 6.0 U Total HpCDF 4.5 U 1,2,3,4,6,7,8-HpCDD 4.4 U Total HpCDD 4.4 U OCDF 9.1 U OCDD 7.3 U 2.1 1.9 1.8 2.1 2.0 2.1 2.2 1.8 2.0 2.1 2,3,7,8-TCDF-13C 2.1 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 2.3 2,3,4,7,8-PeCDF-13C 2.3 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 2.0 1,2,3,6,7,8-HxCDF-13C 1.6 2,3,4,6,7,8-HxCDF-13C 1.8 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 1.8 1,2,3,6,7,8-HxCDD-13C 1.8 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C ng's Percent Added Recovery 2.00 66 2.00 70 2.00 62 2.00 61 2.00 71 2.00 64 2.00 57 2.00 73 2.00 63 2.00 66 2.00 66 2.00 51 2.00 47 2.00 51 4.00 44 1,2,3,4-TCDD-13C 2.00 NA 1,2,3,7,8,9-HxCDD-13C 2.00 NA 2,3,7,8-TCDD-37CI4 0.20 88 3.0 Total 2,3,7,8-TCDD 6.0 Equivalence: 0.00 pg/L 4.5 (Lower -bound - Using ITE Factors) 4.4 4.4 9.1 7.3 Conc= Concentration (Totals include2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466118_8290FC_DFR Page 11 of 14 Page 15 of 18 I 1 Analytical Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) Method Blank ID Native Isomers TM Method Method 8290 Laboratory Control Spike Results LCS-68967 F190313B_01 923 mL F190112 F190313A_18 & F190313B_17 BLANK-68966 Matrix Dilution Extracted Analyzed Injected By Qs Qm % Internal (ng) (ng) Rec. Standards Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612-607-6444 Water NA 03/11/2019 12:00 03/13/2019 20:48 SMT ng's Percent Added Recovery 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD 0.20 0.22 109 2,3,7,8-TCDF-130 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 0.20 0.23 117 2,3,4,7,8-PeCDF-13C 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 1.0 1.1 105 1, 2, 3, 6, 7, 8-HxC DF-13C 1.0 1.1 111 2,3,4,6,7,8-HxCDF-13C 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 1.0 0.97 97 1,2,3,6,7,8-HxCDD-13C 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 2.0 2.0 1.1 1.1 1.1 1.1 1.1 1.0 1.0 2.2 2.2 113 108 105 105 111 120 103 107 102 100 108 109 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 4.0 2.0 2.0 0.20 58 60 52 51 58 52 49 60 49 55 54 41 37 R 40 33 R NA NA 80 Qs = Quantity Spiked Qm = Quantity Measured Rec. = Recovery (Expressed as Percent) R = Recovery outside of target range Y = RF averaging used in calculations Nn = Value obtained from additional analysis NA = Not Applicable * = See Discussion REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466118_8290FC_DFR Page 12 of 14 Page 16 of 18 Analytical Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) Method Blank ID Native Isomers TM Method 8290 Laboratory Control Spike Results Qs (ng) LCSD-68968 F190313B_02 894 mL F190112 F190313A_18 & F190313B_17 BLANK-68966 Qm (ng) 0/0 Rec. Matrix Dilution Extracted Analyzed Injected By Internal Standards Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis. MN 55414 Tel:612-607-1700 Fax: 612-607-6444 Water NA 03/11/2019 12:00 03/13/2019 21:33 SMT ng's Percent Added Recovery 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD 0.20 0.20 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 0.22 0.23 1.1 1.1 0.99 1.0 1.0 0.99 0.97 1.1 1.1 1.0 105 104 99 97 109 115 104 1.0 1.0 104 1.0 0.92 92 1.0 0.99 99 2.0 2.1 105 2.0 2.1 106 109 2,3,7,8-TCDF-13C 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 116 2,3,4,7,8-PeCDF-13C 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 105 1,2,3,6,7,8-HxCDF-13C 109 2,3,4,6,7,8-HxCDF-13C 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 99 1,2,3,6,7,8-HxCDD-13C 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 2.0 70 2.0 74 2.0 61 2.0 59 2.0 66 2.0 66 2.0 63 2.0 73 2.0 63 2.0 66 2.0 65 2.0 51 2.0 47 2.0 51 4.0 42 2.0 NA 2.0 NA 0.20 89 Qs = Quantity Spiked Qm = Quantity Measured Rec. = Recovery (Expressed as Percent) R = Recovery outside of target range Y = RF averaging used in calculations Nn = Value obtained from additional analysis NA = Not Applicable = See Discussion REPORT OF LABORATORYANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466118_8290FC_DFR Page 17 of 18 Page 13 of 14 TM Analytical Method 8290 Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Spike Recovery Relative Percent Difference (RPD) Results Client PASI Florida Spike 1 ID LCS-68967 Spike 2 ID LCSD-68968 Spike 1 Filename F190313B_01 Spike 2 Filename F190313B_02 Spike 1 Spike 2 Compound %REC %REC %RPD Tel:612-607-1700 Fax: 612-607-6444 2,3,7,8-TCDF 109 109 0.0 2,3,7,8-TCDD 117 116 0.9 1,2,3,7,8-PeCDF 105 105 0.0 2,3,4,7,8-PeCDF 111 109 1.8 1,2,3,7,8-PeCDD 97 99 2.0 1,2,3,4,7,8-HxCDF 113 105 7.3 1,2,3,6,7,8-HxCDF 108 104 3.8 2,3,4,6,7,8-HxCDF 105 99 5.9 1,2,3,7,8,9-HxCDF 105 97 7.9 1,2,3,4,7,8-HxCDD 111 109 1.8 1,2,3,6,7,8-HxCDD 120 115 4.3 1,2,3,7,8,9-HxCDD 103 104 1.0 1,2,3,4,6,7,8-HpCDF 107 104 2.8 1,2,3,4,7,8,9-HpCDF 102 92 10.3 1,2,3,4,6,7,8-HpCDD 100 99 1.0 OCDF 108 105 2.8 OCDD 109 106 2.8 %REC = Percent Recovered RPD = The difference between the two values divided by the mean value REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466118_8290FC_DFR Page 18 of 18 Page 14 of 14 aceAnalytical www.pacelabs.com March 08, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451856 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 05, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry, EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 11 7eAnaIyticaI www.pacelabacom CERTIFICATIONS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451856 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 11 aceAnalytical wwwpacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451856 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35451856001 MW-44 Water 03/04/19 10:14 03/05/19 17:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 11 aceAnalytical www.pacelabs.com SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451856 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35451856001 MW-44 EPA6010 JWP 3 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 11 aceAnalytical www.pacelabs.com SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451856 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35451856001 EPA 6010 MW-44 Barium 51.2 ug/L 10.0 03/07/19 21:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 11 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451856 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach. FL 33064 954-582-4300 Sample: MW-44 Lab ID: 35451856001 Collected: 03/04/19 10:14 Received: 03/05/19 17:45 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Arsenic 7.1 U ug/L 10.0 7.1 1 03/07/19 10:29 03/07/19 21:00 7440-38-2 Barium 51.2 ug/L 10.0 0.84 1 03/07/19 10:29 03/07/19 21:00 7440-39-3 Lead 4.6 U ug/L 10.0 4.6 1 03/07/19 10:29 03/07/19 21:00 7439-92-1 Date: 03/08/2019 01:06 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 11 ceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451856 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521178 Analysis Method: EPA 6010 QC Batch Method: EPA3010 Analysis Description: 6010 MET Associated Lab Samples: 35451856001 METHOD BLANK: 2814528 Matrix: Water Associated Lab Samples: 35451856001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic ug/L 7.1 U 10.0 7.1 03/07/19 20:40 Barium ug/L 0.84 U 10.0 0.84 03/07/19 20:40 Lead ug/L 4.6 U 10.0 4.6 03/07/19 20:40 LABORATORY CONTROL SAMPLE: 2814529 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic ug/L 250 251 100 80-120 Barium ug/L 250 250 100 80-120 Lead ug/L 250 260 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2814530 2814531 MS MSD 35451859001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L 7.1 U 250 250 259 252 104 101 75-125 3 20 Barium ug/L 11.5 250 250 266 260 102 99 75-125 2 20 Lead ug/L 4.6 U 250 250 260 255 104 102 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/08/2019 01:06 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 11 ceAnalytical® www.pacelabs.com QUALIFIERS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451856 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORI ES PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS U Compound was analyzed for but not detected. Date: 03/08/2019 01:06 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 11 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project 2018-3057/Melreese Golf Course Pace Project No.: 35451856 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID QC Batch Method Analytical QC Batch Analytical Method Batch 35451856001 MW-44 Date: 03/08/2019 01:06 PM EPA 3010 521178 EPA 6010 521271 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 11 PaceAnalytical CHAIN-OF-CUSI Onv 1 AnalvtiraI Reauest Document The Chain -of -Custody is a L WO : 354 ately. Section A Section B Section C Required Client Information: Required Project Information: Invoice In f Page : I Of I Company Environmental Services, LLC Report To o II I I I IIII I I II 1111 Ill III Address 5751 Miami Lakes Dr 5751 Copy To: ' c'et_Z c C 1� � Company o P Y Com an I 35451856 Hialeah, FL 33014 Address Regulatory Agency Email t.-•,!,_ _.,,, _;; ,,. ,y, a v 7 s Purchase Order # Pace Quote Phone. (305)374-8300 Yii� ,> Project Name C.T.A.V''..' �E' Z\i�''w' jam Pace Pro Iect Manager chnshna.raschke@pacelabs com. State f Location Rege:sl-d Due Date Ingt iratim Pro'ect #: 2018-3057 Fare Pmiiie # FL •—,-, Re.uested Anal sis Filtered PYON . MATRIX CODE MATRIX CODE (see valid codes to left) \AMFLE TYPE (G=GRAB C=COMP) COLLECTED SAMPLE TEMP AT COLLECTION j Preservatives Z >- Dnnkrng Water DW Wales WI Wasir WW'r WW Product P SAMPLE ID somsoud sl START END m HCI Na2S203 Analyses Test 6010 As, Pb jL Residual Chlorine (Y/N) ~ One Character per box. Wier wP (A-Z, 0-9 ! , -) Air AR Diner OT Sample Ids must be unique Trncue TS D � TE TIME DATE TIME Ill O LLO n 1' o n O S n ? = 2 O ` � %� % 6 10..- 11 .---..- 12 .---..-1 ADDITIONAL COMMENTS • RELINQUISHED BY / AFFIU TION • DATE TIME ACCtPTEEDD BY //AFFILUITION DATE TIME ONDIITIIONS SAMPLE CONDITIONS...) /,te.-. 1 1151 rl� i ` c, , 6,0 y ti y Of , s y , SAMPLER NAME AND SIGNATURE 1 j TEMP in C Received on Ice (YIN) use y Sealed Cooler YIN PRINT Name of SAMPLER: •4 r•l ( ` liV YL1 '\ •-t. c� ,' t 0 Ti SIGNATURE of SAMPLER: / `-' DATE Signed: / r, E Z f ace Analytical Document Name Sample Condition Upon Receipt Form Document Revisec May 30, 2018 Document No F-FL-C-007 rev 13 Issuing Authonty Pace Florida Quality Office WO#:35451856 Project;'PPl: CTR Project ManagerCLIENT: 36-EEG Client: Thermometer Used Due Date: 03/12/19 Date State of right 1 da— Li For Vt V orotectt�s, all containers verified to <_6 Cooler #1 Temp.'C lif) (Visual) ,Q. 0 (Correction Factor) 3. V (Actual) Cooler #2 Temp.°C (Visual) a 0 (Correction Factor) Co. 0 (Actual) Cooler #3 Temp.'C 5e 5 (Visual) 0 ,0 (Correction Factor) 5,5 (Actual) (Visual) (Correction Factor) (Actual) Cooler #5 Temp.`C (Visual) (Correction Factor) Cooler#6 Temp.'C (Visual) (Correction Factor) Time. Date and Initials of Examining content: Label: Deliver - pH: Cooler #4 Temp.'C Courier: Fed Ex El UPS 11 USPS Client r Commercia — Pace (Actual) (Actual) Shipping Method: - First Overnight _ Priority Overnight- Standard Overnight -, Ground `: Other Billing: Tracking # - Recipient Custody Seal on Cooler/Box Present: Packing Material: 'LiBubbie Wrap Samples shorted to lab (If Yes, complete) LT Sender E Third Party - Credit Card bble Bags L_1None Shorted Date: Seals intact: n Yes ❑Otther t� 1v /-t�' Comments: Initials. t Samples on ice, ccohno process has begun Samples on ice, cooling process has beoun Samples on ice, cooling process has beour. C Samples on ice, cooling process has begun L Samples on ice_ cooling process has begun Samples on ice, cooling process has beoun Other International Priority Unknown is Shorted Time: lue Dry None Qty Chain of Custody Present _ es '_ No I1N/A Chain of Custody Filled Out - 'es =i No ❑N/A Relinquished Signature & Sampler Name COC_ e�s El No t=N/A Samples Arrived within Hold Time Yes 'D No DN/A Rush TAT requested on COC EYes to ❑N/A Sufficient Volume 7s a No ❑N/A Correct Containers Used es D No ❑N/A Containers Intact s D No ❑N/A Sample Labels match COC (sample Ds & date/time of collection)s L=' No DN/A All containers needing acid/base preservation have been checked. .-es -! No ^N/A All Containers needing preservation are found to be in compliance with EPA recommendation eS — No -N/A Exceptions: VOA, Cohtorm, TOC, O&G, Carbamates Preservation information - Preservative Lot #/Trace #• Date i i Irnttats / Headspace in VOA Vials? (>6mm): Yes = No it Trip Blank Present: -Yes = No — /A Client Notification/ Resolution: Person Contacted: Comments/ Resolution (use back for additional comments): Date/Time. Project Manager Review: Date Page 11 of 11 www.pacelabs.com March 08, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451850 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 05, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, 0 Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry, EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 13 aceAnalytical® www.pacelabs.com CERTIFICATIONS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451850 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 13 aceAnalytical www.pacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No 35451850 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35451850001 MW-44 Water 03/04/19 10:14 03/05/19 17:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 13 aceAnalytical www.pacelabs.com SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451850 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35451850001 MW-44 EPA 6010 JWP 2 PASI-O EPA 300.0 JDM 2 PASI-O EPA 350.1 MAJ 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 13 aceAnalytical www.pacelabs.com SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451850 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35451850001 EPA 6010 EPA 350.1 MW-44 Iron Nitrogen, Ammonia 766 ug/L 3.5 mg/L REPORT OF LABORATORY ANALYSIS 40.0 03/07/19 21:00 0.050 03/06/19 08:29 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 13 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451850 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-44 Lab ID: 35451850001 Collected: 03/04/19 10:14 Received: 03/05/19 17:45 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Aluminum 30.7 U ug/L 100 30.7 1 03/07/19 10:29 03/07/19 21:00 7429-90-5 Iron 766 ug/L 40.0 9.2 1 03/07/19 10:29 03/07/19 21:00 7439-89-6 300.0 IC Anions Analytical Method: EPA300.0 Nitrate as N 0.025 U mg/L 0.050 0.025 1 03/06/19 10:39 14797-55-8 Q Nitrite as N 0.025 U mg/L 0.050 0.025 1 03/06/19 10:39 14797-65-0 Q 350.1 Ammonia Analytical Method: EPA350.1 Nitrogen, Ammonia 3.5 mg/L 0.050 0.035 1 03/06/19 08:29 7664-41-7 Date: 03/08/2019 12:41 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 13 aceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451850 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521178 Analysis Method: EPA 6010 QC Batch Method: EPA 3010 Analysis Description: 6010 MET Associated Lab Samples: 35451850001 METHOD BLANK: 2814528 Matrix: Water Associated Lab Samples: 35451850001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Aluminum ug/L 30.7 U 100 Iron ug/L 9.2 U 40.0 30.7 03/07/19 20:40 9.2 03/07/19 20:40 LABORATORY CONTROL SAMPLE: 2814529 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Aluminum ug/L 2500 2520 101 80-120 Iron ug/L 2500 2610 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2814530 2814531 MS MSD 35451859001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 30.7 U 2500 2500 2590 2530 103 101 75-125 2 20 Iron ug/L 369 2500 2500 2980 2910 105 102 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/08/2019 12:41 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 13 aceAnalytical www..pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451850 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 520750 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 35451850001 METHOD BLANK: 2812105 Matrix: Water Associated Lab Samples: 35451850001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrate as N mg/L 0.025 U 0.050 0.025 03/06/19 11:46 Nitrite as N mg/L 0.025 U 0.050 0.025 03/06/19 11:46 LABORATORY CONTROL SAMPLE: 2812106 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/L 5 5.0 100 90-110 Nitrite as N mg/L 5 4.9 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2812128 2812129 MS MSD 35451851001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrate as N mg/L 0.025 U 5 5 4.8 4.8 96 96 90-110 1 20 Nitrite as N mg/L 0.025 U 5 5 4.9 4.9 98 97 90-110 1 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/08/2019 12:41 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 13 712ceAnalytical® wwwpacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451850 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-300 QC Batch: 520730 Analysis Method: EPA 350.1 QC Batch Method: EPA 350.1 Analysis Description: 350.1 Ammonia Associated Lab Samples: 35451850001 METHOD BLANK: 2812044 Matrix: Water Associated Lab Samples: 35451850001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen. Ammonia mg/L 0.035 U 0.050 0.035 03/06/19 08:14 LABORATORY CONTROL SAMPLE: 2812045 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 1 1.1 105 90-110 MATRIX SPIKE SAMPLE: 2812047 35451845001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 0.58 1 1.6 103 90-110 SAMPLE DUPLICATE: 2812046 35451845001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrogen, Ammonia mg/L 0.58 0.58 0 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date 03/08/2019 12:41 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 13 aceAnalytical www.pacelabs.com QUALIFIERS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451850 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PAST-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS U Compound was analyzed for but not detected. Sample held beyond the accepted holding time. Reanalysis conducted in excess of EPA method holding time. Results confirm original analysis performed in hold time. Date: 03/08/2019 12:41 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 13 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451850 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID QC Batch Method Analytical QC Batch Analytical Method Batch 35451850001 MW-44 EPA 3010 521178 EPA 6010 521271 35451850001 MW-44 EPA 300.0 520750 35451850001 MW-44 EPA 350.1 520730 Date: 03/08/2019 12:41 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 13 F'aceAnalylical CHAIN -WO 35451850 The Chain -off - lent mpleted accurately. Client Information: Required ProjeInformation: seruon A Section a 131 I I IIII III� ��I IRequired Page : 1 Of 1 Cnmpany EERG Environmental Services, I.LC ReportTogttitja+++ct n�C� ��Address 5751 Miami Lakes Dr Copy To�'.fekis aiev n(3e-r5451850 Hialeah, FL 33014 - -__ Regulatory Agency Ernail -( Q�rrtngrern• esPtG' f Phone (305)374-8300 ax �J Project Name Lkr 825�. p\ a ,t)rye C— � Pace Project Manager. christina.rase ike @pacelabs com, � State /Location Requested Due Date �.-k�,.�,_-�- ' i, ,.k t Project #: 2018-305 / Pace Profile #: a/l� FL Requ t A yrcy.a Fil ered tY/� MATRIX CODE MATRIX CODE (see valid codes to left) \$AMPLE TYPE (G=GRAB C=COMP) COLLECTED SAMPLE TEMP AT COLLECTION k OF CONTAINERS Preservatives 2 % 5 �,a -0' , t) J Drinking Writer OW Water Wr Wean MilerWW Product P SAMPLE ID $eusord Ofl alL START END Unpreserved HNO3 HCI Na2S203 Methanol Other Analyses Test 8260 VOC PAH by 8270 SIM TRPH FL -PRO Pesticides 8081(0%-ev \I. YQ U d Herbicides 8151(6\ter ` 2-)"vW06ze ulxoia 6010 Ba, Cd, Cr, Se, Ag, 7470 Hg 4cek, As, !'!} )1 +f -� a �Gt , Residual Chlorine (Y/N) # H One Character per box. Wipe WPAir AR (A-Z, 0-9 / , -) Omer oCU Sample Ids must be unique n..ue TS DATE TIME DATE TIME 0 = 0 Z rz 3 4 5 6 7 8 9 10 11 12 1 ADDITIONAL COMMENTS REUNQUISHEDfY I AFFI TION : . DATE .- - .THE . --A • PIED BY I AFFILIATION DATE , TIME • SAMPLE CONDITIONS ,� �� - SAMPLER NAME AND SIGNATURE f 10 PoZ Custody Sealed Cooler (Y/N) E IT: PRINT Name of SAMPLER: f / l r/" / c SIGNATURE of SAMPLER: (-) DATE Signed: /,r // t,, W Page 12 of 13 Pce Analytical Sae w0#:354518 0 Project #p(•i: CTR Due Date: 03/12/19 Project Manager: CLIENT: 36-EEG Client: prThermometer Used ✓ Date 3 State of�nc Pace Q .aiiC, VJR) Date and Initials of p Examining contents: Label: Deliver{ pH: Time I:ILI- Initials tJ 7 For ects an conta;rers verdied is 56 -C Cooler #1 Temp.'C` Jam/ (Visual) ID (Correction Factor) (3. {J (Actual) Cooler #2 Temp.'C (Visual) 0 0 (Correction Factor) `i (Actual) Cooler #3 Temp.'C 5, J (Visual) 0 _ l✓' (Correction Factor) 5 .5 (Actual) (Visual) (Correction Factor) (Actual) Cooler #5 Temp.'C (Visual) (Correction Factor) (Actual) Cooler #6 Temp.'C (Visual) (Correction Factor) (Actual) Cooler #4 Temp.`C Courier: — Fed Ex — UPS n USPS — Client = Commercial/= Pace emcee v _c C7.... 7 process "cs :eau" Saw c e_ g process =_ a.^".^.. e_ 3 _..., p'C_ess ^.aS .b yu^ E Sarcoos on !C_ _..c.ira process has oe^yun Samp!e_s O c.,. _ process 'as begun Sar-p -_ . _ proce.ss `.as b,c a Other Shipping Method: 7 First Overnight Priority Overnight Standard Overnight Ground = International Priority = Other Billing: = Recipient Tracking # Custody Seal on Cooler/Box Present: Packing Material: —Bubble Wrap r ubble Baas !None Samples shorted to lab (If Yes, complete) Shorted Date: = Sender Third Party Credit Card Seals intact: _ Yes '�' Other Comments: Unknown Icy: Wet /3lue Dry None Shorted Time Qty Chain of Custody Present es _ No _N/A Chain of Custody Filled Out s = No NIA Relinquished Signature & Sampler Name COC _ e_: _ No N/A Samples Arrived within Hold Time ill /ses = No N/A Rush TAT requested on COC -Yes _ o _N/A Sufficient Volume es _ No _N/A Correct Containers Used _ es = No :1 N/A Containers Intact — es = No 7N/A Sample Labels match COC (sample IDs & datetime of �� ,// collection) __.res = No _N/A All containers reeding acid,base preservation have teen checked = es = No _NIA All Containers neeirg preservatioe are founc tc be in compliance ‘.�ith EFA recommendaton es = No .N/A Exceptions VOA. Cohform, TOC, C&G, Carbamates Preservation Informal :;, Preservative Lot #1-race r • Date u initials Headspace in VOA Vials? (>6mm) =Yes = No Trip Blank Present: -Yes = No - Client Notification/ Resolution: Person Contacted Comments/ Resolution (use back for additional comments): Date/Time Project Manager Review Date Page 13 of 13 aceAnalytical www.pacelabs.com March 12, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451861 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 05, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Some analyses have been subcontracted outside of the Pace Network. The subcontracted laboratory report has been attached. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry, EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 39 ceAnalytical® www.pacetabs.com CERTIFICATIONS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451861 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 39 aceAnalytical www.pace/abs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451861 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35451861001 MW-44 Water 03/04/19 10:14 03/05/19 17:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 39 aceAnalytical® www.pacelabs.com SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course Pace Project No : 35451861 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35451861001 MW-44 EPA 8081 AER 22 PASI-O FL -PRO RJR 3 PASI-O EPA 6010 JWP 4 PASI-O EPA 7470 AMS 1 PASI-O EPA 8270 by SIM CB1 20 PASI-O EPA 8260 BTN 69 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 39 aceAnalytical www.pacelabs.com SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451861 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters 35451861001 EPA 8260 Result MW-44 Acetone Units Report Limit Analyzed Qualifiers 5.4 I ug/L 20.0 03/06/19 15:40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 39 ace Analytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451861 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-44 Parameters Lab ID: 35451861001 Collected: 03/04/19 10:14 Received: 03/05/19 17:45 Matrix: Water Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8081 GCS Pesticides Aldrin alpha-BHC beta-BHC delta-BHC gamma-BHC (Lindane) Chlordane (Technical) 4,4'-DDD 4,4'-DDE 4,4'-DDT Dieldrin Endosulfan I Endosulfan II Endosulfan sulfate Endrin Endrin aldehyde Endrin ketone Heptachlor Heptachlor epoxide Methoxychlor Toxaphene Surrogates Tetrachloro-m-xylene (S) Decachlorobiphenyl (S) FL -PRO Water, Low Volume Petroleum Range Organics Surrogates o-Terphenyl (S) N-Pentatriacontane (S) 6010 MET ICP Cadmium Chromium Selenium Silver 7470 Mercury Mercury 8270 MSSV PAHLV by SIM Acenaphthene Acenaphthylene Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Date: 03/12/2019 09:17 PM Analytical Method: EPA 8081 Preparation Method: EPA 3510 0.0014 0.0020 0.0077 0.0046 0.0021 0.17 0.0086 0.0048 0.0048 0.0019 0.0049 0.0039 0.0060 0.0041 0.0035 0.0048 0.0060 0.0050 0.0093 0.24 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 68 58 0.0096 0.0014 1 0.0096 0.0020 1 0.0096 0.0077 1 0.0096 0.0046 1 0.0096 0.0021 1 0.48 0.17 1 0.0096 0.0086 1 0.0096 0.0048 1 0.0096 0.0048 1 0.0096 0.0019 1 0.0096 0.0049 1 0.0096 0.0039 1 0.096 0.0060 1 0.0096 0.0041 1 0.096 0.0035 1 0.0096 0.0048 1 0.0096 0.0060 1 0.0096 0.0050 1 0.0096 0.0093 1 0.48 0.24 1 03/06/19 16:26 03/09/19 04:10 03/06/19 16:26 03/09/19 04:10 03/06/19 16:26 03/09/19 04:10 03/06/19 16:26 03/09/19 04:10 03/06/19 16:26 03/09/19 04:10 03/06/19 16:26 03/09/19 04:10 03/06/19 16:26 03/09/19 04:10 03/06/19 16:26 03/09/19 04:10 03/06/19 16:26 03/09/19 04:10 03/06/19 16:26 03/09/19 04:10 03/06/19 16:26 03/09/19 04:10 03/06/19 16:26 03/09/19 04:10 03/06/19 16:26 03/09/19 04:10 03/06/19 16:26 03/09/19 04:10 03/06/19 16:26 03/09/19 04:10 03/06/19 16:26 03/09/19 04:10 03/06/19 16:26 03/09/19 04:10 03/06/19 16:26 03/09/19 04:10 03/06/19 16:26 03/09/19 04:10 03/06/19 16:26 03/09/19 04:10 309-00-2 319-84-6 319-85-7 319-86-8 58-89-9 57-74-9 72-54-8 72-55-9 50-29-3 60-57-1 959-98-8 33213-65-9 1031-07-8 72-20-8 7421-93-4 53494-70-5 76-44-8 1024-57-3 72-43-5 8001-35-2 27-124 1 03/06/19 16:26 03/09/19 04:10 877-09-8 10-132 1 03/06/19 16:26 03/09/19 04:10 2051-24-3 Analytical Method: FL -PRO Preparation Method: EPA 3510 0.78 U mg/L 0.97 0.78 1 03/07/19 09:10 03/07/19 17:17 85 % 66-139 82 % 42-159 1 03/07/19 09:10 03/07/19 17:17 84-15-1 1 03/07/19 09:10 03/07/19 17:17 630-07-09 Analytical Method: EPA 6010 Preparation Method: EPA 3010 0.33 U 1.7 U 8.5 U 1.0 U ug/L ug/L ug/L ug/L 1.0 5.0 15.0 5.0 0.33 1.7 8.5 1.0 03/07/19 10:29 03/07/19 21:00 7440-43-9 03/07/19 10:29 03/07/19 21:00 7440-47-3 03/07/19 10:29 03/07/19 21:00 7782-49-2 03/07/19 10:29 03/07/19 21:00 7440-22-4 Analytical Method: EPA 7470 Preparation Method: EPA 7470 0.10 U ug/L 0.20 0.10 1 03/07/19 10:25 03/08/19 16:14 7439-97-6 Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3510 0.040 U 0.030 U 0.043 U 0.055 U 0.12 U 0.027 U ug/L ug/L ug/L ug/L ug/L ug/L 0.50 0.50 0.50 0.10 0.20 0.10 0.040 0.030 0.043 0.055 0.12 0.027 03/07/19 02:41 03/07/19 12:18 03/07/19 02:41 03/07/19 12:18 03/07/19 02:41 03/07/19 12:18 03/07/19 02:41 03/07/19 12:18 03/07/19 02:41 03/07/19 12:18 03/07/19 02:41 03/07/19 12:18 REPORT OF LABORATORY ANALYSIS 83-32-9 208-96-8 120-12-7 56-55-3 50-32-8 205-99-2 1p 1p 1p 1p 1p 1p 1p 1p 1p 1p 1p 1p 1p 1p 1p 1p 1p 1p 1p 1p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 39 aceAnalytical www. pacelabs. com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451861 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-44 Lab ID: 35451861001 Collected: 03/04/19 10:14 Received: 03/05/19 17:45 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8270 MSSV PAHLV by SIM Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3510 Benzo(g,h.i)perylene 0.15 U ug/L 0.50 0.15 1 03/07/19 02:41 03/07/19 12:18 191-24-2 Benzo(k)fluoranthene 0.16 U ug/L 0.50 0.16 1 03/07/19 02:41 03/07/19 12:18 207-08-9 Chrysene 0.026 U ug/L 0.50 0.026 1 03/07/19 02:41 03/07/19 12:18 218-01-9 Dibenz(a,h)anthracene 0.13 U ug/L 0.15 0.13 1 03/07/19 02:41 03/07/19 12:18 53-70-3 Fluoranthene 0.018 U ug/L 0.50 0.018 1 03/07/19 02:41 03/07/19 12:18 206-44-0 Fluorene 0.088 U ug/L 0.50 0.088 1 03/07/19 02:41 03/07/19 12:18 86-73-7 Indeno(1,2,3-cd)pyrene 0.12 U ug/L 0.15 0.12 1 03/07/19 02:41 03/07/19 12:18 193-39-5 1-Methylnaphthalene 0.19 U ug/L 2.0 0.19 1 03/07/19 02:41 03/07/19 12:18 90-12-0 2-Methylnaphthalene 0.68 U ug/L 2.0 0.68 1 03/07/19 02:41 03/07/19 12:18 91-57-6 Naphthalene 0.29 U ug/L 2.0 0.29 1 03/07/19 02:41 03/07/19 12:18 91-20-3 Phenanthrene 0.16 U ug/L 0.50 0.16 1 03/07/19 02:41 03/07/19 12:18 85-01-8 Pyrene 0.032 U ug/L 0.50 0.032 1 03/07/19 02:41 03/07/19 12:18 129-00-0 Surrogates 2-Fluorobiphenyl (S) 72 % 33-82 1 03/07/19 02:41 03/07/19 12:18 321-60-8 p-Terphenyl-d14 (S) 104 % 49-104 1 03/07/19 02:41 03/07/19 12:18 1718-51-0 8260 MSV Analytical Method: EPA 8260 '.1,1,2-Tetrachloroethane 0.32 U ug/L 1.0 0.32 1 03/06/19 15:40 630-20-6 .1,1-Trichloroethane 0.30 U ug/L 1.0 0.30 1 03/06/19 15:40 71-55-6 1,1,2,2-Tetrachloroethane 0.20 U ug/L 0.50 0.20 1 03/06/19 15:40 79-34-5 1,1,2-Trichloroethane 0.30 U ug/L 1.0 0.30 1 03/06/19 15:40 79-00-5 1,1-Dichloroethane 0.34 U ug/L 1.0 0.34 1 03/06/19 15:40 75-34-3 1,1-Dichloroethene 0.27 U ug/L 1.0 0.27 1 03/06/19 15:40 75-35-4 1,1-Dichloropropene 0.31 U ug/L 1.0 0.31 1 03/06/19 15:40 563-58-6 1,2,3-Trichlorobenzene 0.34 U ug/L 1.0 0.34 1 03/06/19 15:40 87-61-6 1,2,3-Trichloropropane 1.1 U ug/L 2.0 1.1 1 03/06/19 15:40 96-18-4 1,2,3-Trimethylbenzene 0.17 U ug/L 1.0 0.17 1 03/06/19 15:40 526-73-8 1,2,4-Trichlorobenzene 0.32 U ug/L 1.0 0.32 1 03/06/19 15:40 120-82-1 1,2,4-Trimethylbenzene 0.24 U ug/L 1.0 0.24 1 03/06/19 15:40 95-63-6 1,2-Dichlorobenzene 0.29 U ug/L 1.0 0.29 1 03/06/19 15:40 95-50-1 1,2-Dichloroethane 0.27 U ug/L 1.0 0.27 1 03/06/19 15:40 107-06-2 1,2-Dichloropropane 0.23 U ug/L 1.0 0.23 1 03/06/19 15:40 78-87-5 1,3,5-Trimethylbenzene 0.24 U ug/L 1.0 0.24 1 03/06/19 15:40 108-67-8 1,3-Dichlorobenzene 0.33 U ug/L 1.0 0.33 1 03/06/19 15:40 541-73-1 1.3-Dichloropropane 0.26 U ug/L 1.0 0.26 1 03/06/19 15:40 142-28-9 1.4-Dichlorobenzene 0.28 U ug/L 1.0 0.28 1 03/06/19 15:40 106-46-7 2.2-Dichloropropane 0.59 U ug/L 1.0 0.59 1 03/06/19 15:40 594-20-7 2-Butanone (MEK) 7.5 U ug/L 10.0 7.5 1 03/06/19 15:40 78-93-3 2-Chloroethylvinyl ether 1.4 U ug/L 40.0 1.4 1 03/06/19 15:40 110-75-8 c2 2-Chlorotoluene 0.28 U ug/L 1.0 0.28 1 03/06/19 15:40 95-49-8 2-Hexanone 0.85 U ug/L 10.0 0.85 1 03/06/19 15:40 591-78-6 4-Chlorotoluene 0.22 U ug/L 1.0 0.22 1 03/06/19 15:40 106-43-4 4-Methyl-2-pentanone (MIBK) 0.32 U ug/L 10.0 0.32 1 03/06/19 15:40 108-10-1 Acetone 5.4 I ug/L 20.0 5.3 1 03/06/19 15:40 67-64-1 Benzene 0.30 U ug/L 1.0 0.30 1 03/06/19 15:40 71-43-2 Bromobenzene 0.21 U ug/L 1.0 0.21 1 03/06/19 15:40 108-86-1 Date: 03/12/2019 09:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 39 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project 2018-3057/Melreese Golf Course Pace Project No.: 35451861 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-44 Parameters Lab ID: 35451861001 Collected: 03/04/19 10:14 Received: 03/05/19 17:45 Matrix: Water Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Dibromochloromethane Dibromomethane Dichlorodifluoromethane Ethylbenzene lodomethane Isopropylbenzene (Cumene) Methyl-tert-butyl ether Methylene Chloride Styrene Tetrachloroethene Toluene Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene m&p-Xylene n-Butylbenzene n-Propylbenzene o-Xylene p-Isopropyltoluene sec-Butylbenzene tert-Butylbenzene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 03/12/2019 09:17 PM Analytical Method EPA 8260 0.37 0.19 2.6 4.0 0.45 1.1 0.35 3.7 0.32 0.97 0.45 0.68 0.26 0.30 9.3 0.30 0.51 2.0 0.26 0.38 0.33 0.36 0.35 0.19 0.39 2.1 0.27 0.17 2.1 0.20 0.37 0.27 0.31 0.17 0.26 0.23 0.17 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 89 % 105 101 Ok Ok 1.0 0.60 3.0 5.0 10.0 3.0 1.0 10.0 1.0 1.0 2.0 2.0 1.0 1.0 10.0 1.0 2.0 5.0 1.0 1.0 1.0 1.0 1.0 10.0 1.0 5.0 1.0 0.50 4.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 0.50 70-130 70-130 70-130 0.37 0.19 2.6 4.0 0.45 1.1 0.35 3.7 0.32 0.97 0.45 0.68 0.26 0.30 9.3 0.30 0.51 2.0 0.26 0.38 0.33 0.36 0.35 0.19 0.39 2.1 0.27 0.17 2.1 0.20 0.37 0.27 0.31 0.17 0.26 0.23 0.17 REPORT OF LABORATORY ANALYSIS 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 03/06/19 15:40 74-97-5 75-27-4 75-25-2 74-83-9 v2 75-15-0 v1 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3 v2 124-48-1 74-95-3 75-71-8 100-41-4 74-88-4 v2 98-82-8 1634-04-4 75-09-2 100-42-5 127-18-4 108-88-3 79-01-6 75-69-4 108-05-4 75-01-4 1330-20-7 156-59-2 10061-01-5 179601-23-1 104-51-8 103-65-1 95-47-6 99-87-6 135-98-8 98-06-6 156-60-5 10061-02-6 03/06/19 15:40 460-00-4 03/06/19 15:40 17060-07-0 03/06/19 15:40 2037-26-5 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 39 ceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451861 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521100 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 35451861001 METHOD BLANK: 2814165 Matrix: Water Associated Lab Samples: 35451861001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L 0.10 U 0.20 0.10 03/08/19 15:31 LABORATORY CONTROL SAMPLE: 2814166 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2 1.9 96 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2814167 2814168 MS MSD 35451633001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual lercury ug/L 0.10 U 2 2 1.7 1.8 86 88 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 39 PaceAnalytical wwwpace/abs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451861 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521178 Analysis Method: EPA 6010 QC Batch Method: EPA 3010 Analysis Description: 6010 MET Associated Lab Samples: 35451861001 METHOD BLANK: 2814528 Matrix: Water Associated Lab Samples: 35451861001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Cadmium ug/L 0.33 U 1.0 0.33 03/07/19 20:40 Chromium ug/L 1.7 U 5.0 1.7 03/07/19 20:40 Selenium ug/L 8.5 U 15.0 8.5 03/07/19 20:40 Silver ug/L 1.0 U 5.0 1.0 03/07/19 20:40 LABORATORY CONTROL SAMPLE: 2814529 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Cadmium ug/L 25 25.7 103 80-120 Chromium ug/L 250 255 102 80-120 Selenium ug/L 250 261 104 80-120 Silver ug/L 25 24.1 96 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2814530 2814531 MS MSD 35451859001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Cadmium ug/L 0.33 U 25 25 26.0 25.4 104 101 75-125 2 20 Chromium ug/L 1.7 U 250 250 262 252 105 101 75-125 4 20 Selenium ug/L 8.5 U 250 250 266 253 106 101 75-125 5 20 Silver ug/L 1.0 U 25 25 24.5 23.7 98 95 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/12/2019 09:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 39 aceAnalytical www.pacelabscom QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451861 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 520786 Analysis Method: EPA 8260 QC Batch Method: EPA 8260 Analysis Description: 8260 MSV Associated Lab Samples: 35451861001 METHOD BLANK: 2812236 Matrix Water Associated Lab Samples: 35451861001 Parameter Blank Reporting Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L 0.32 U 1.0 0.32 03/06/19 09:44 1,1,1-Trichloroethane ug/L 0.30 U 1.0 0.30 03/06/19 09:44 1,1,2,2-Tetrachloroethane ug/L 0.20 U 0.50 0.20 03/06/19 09:44 1,1,2-Trichloroethane ug/L 0.30 U 1.0 0.30 03/06/19 09:44 1,1-Dichloroethane ug/L 0.34 U 1.0 0.34 03/06/19 09:44 1,1-Dichloroethene ug/L 0.27 U 1.0 0.27 03/06/19 09:44 1,1-Dichloropropene ug/L 0.31 U 1.0 0.31 03/06/19 09:44 1,2,3-Trichlorobenzene ug/L 0.34 U 1.0 0.34 03/06/19 09:44 1,2,3-Trichloropropane ug/L 1.1 U 2.0 1.1 03/06/19 09:44 1,2,3-Trimethylbenzene ug/L 0.17 U 1.0 0.17 03/06/19 09:44 1,2,4-Trichlorobenzene ug/L 0.32 U 1.0 0.32 03/06/19 09:44 1,2,4-Trimethylbenzene ug/L 0.24 U 1.0 0.24 03/06/19 09:44 1,2-Dichlorobenzene ug/L 0.29 U 1.0 0.29 03/06/19 09:44 1,2-Dichloroethane ug/L 0.27 U 1.0 0.27 03/06/19 09:44 ',2-Dichloropropane ug/L 0.23 U 1.0 0.23 03/06/19 09:44 i,3,5-Trimethylbenzene ug/L 0.24 U 1.0 0.24 03/06/19 09:44 1,3-Dichlorobenzene ug/L 0.33 U 1.0 0.33 03/06/19 09:44 1,3-Dichloropropane ug/L 0.26 U 1.0 0.26 03/06/1909:44 1,4-Dichlorobenzene ug/L 0.28 U 1.0 0.28 03/06/19 09:44 2,2-Dichloropropane ug/L 0.59 U 1.0 0.59 03/06/19 09:44 2-Butanone (MEK) ug/L 7.5 U 10.0 7.5 03/06/19 09:44 2-Chloroethylvinyl ether ug/L 1.4 U 40.0 1.4 03/06/19 09:44 2-Chlorotoluene ug/L 0.28 U 1.0 0.28 03/06/19 09:44 2-Hexanone ug/L 0.85 U 10.0 0.85 03/06/19 09:44 4-Chlorotoluene ug/L 0.22 U 1.0 0.22 03/06/19 09:44 4-Methyl-2-pentanone (MIBK) ug/L 0.32 U 10.0 0.32 03/06/19 09:44 Acetone ug/L 5.3 U 20.0 5.3 03/06/19 09:44 Benzene ug/L 0.30 U 1.0 0.30 03/06/19 09:44 Bromobenzene ug/L 0.21 U 1.0 0.21 03/06/19 09:44 Bromochloromethane ug/L 0.37 U 1.0 0.37 03/06/19 09:44 Bromodichloromethane ug/L 0.19 U 0.60 0.19 03/06/19 09:44 Bromoform ug/L 2.6 U 3.0 2.6 03/06/19 09:44 Bromomethane ug/L 4.0 U 5.0 4.0 03/06/19 09:44 Carbon disulfide ug/L 0.45 U 10.0 0.45 03/06/19 09:44 Carbon tetrachloride ug/L 1.1 U 3.0 1.1 03/06/19 09:44 Chlorobenzene ug/L 0.35 U 1.0 0.35 03/06/19 09:44 Chloroethane ug/L 3.7 U 10.0 3.7 03/06/19 09:44 Chloroform ug/L 0.32 U 1.0 0.32 03/06/19 09:44 Chloromethane ug/L 0.97 U 1.0 0.97 03/06/19 09:44 cis-1,2-Dichloroethene ug/L 0.27 U 1.0 0.27 03/06/19 09:44 cis-1,3-Dichloropropene ug/L 0.17 U 0.50 0.17 03/06/19 09:44 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 39 ace Analytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451861 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 METHOD BLANK: 2812236 Matrix: Water Associated Lab Samples: 35451861001 Parameter Blank Reporting Units Result Limit MDL Analyzed Qualifiers Dibromochloromethane ug/L 0.45 U 2.0 0.45 03/06/19 09:44 Dibromomethane ug/L 0.68 U 2.0 0.68 03/06/19 09:44 Dichlorodifluoromethane ug/L 0.26 U 1.0 0.26 03/06/19 09:44 Ethylbenzene ug/L 0.30 U 1.0 0.30 03/06/19 09:44 lodomethane ug/L 9.3 U 10.0 9.3 03/06/19 09:44 Isopropylbenzene (Cumene) ug/L 0.30 U 1.0 0.30 03/06/19 09:44 m&p-Xylene ug/L 2.1 U 4.0 2.1 03/06/19 09:44 Methyl-tert-butyl ether ug/L 0.51 U 2.0 0.51 03/06/19 09:44 Methylene Chloride ug/L 2.0 U 5.0 2.0 03/06/19 09:44 n-Butylbenzene ug/L 0.20 U 1.0 0.20 03/06/19 09:44 n-Propylbenzene ug/L 0.37 U 1.0 0.37 03/06/19 09:44 o-Xylene ug/L 0.27 U 1.0 0.27 03/06/19 09:44 p-Isopropyltoluene ug/L 0.31 U 5.0 0.31 03/06/19 09:44 sec-Butylbenzene ug/L 0.17 U 1.0 0.17 03/06/19 09:44 Styrene ug/L 0.26 U 1.0 0.26 03/06/19 09:44 tert-Butylbenzene ug/L 0.26 U 1.0 0.26 03/06/19 09:44 Tetrachloroethene ug/L 0.38 U 1.0 0.38 03/06/19 09:44 Toluene ug/L 0.33 U 1.0 0.33 03/06/19 09:44 trans-1,2-Dichloroethene ug/L 0.23 U 1.0 0.23 03/06/19 09:44 trans-1,3-Dichloropropene ug/L 0.17 U 0.50 0.17 03/06/19 09:44 Trichloroethene ug/L 0.36 U 1.0 0.36 03/06/19 09:44 Trichlorofluoromethane ug/L 0.35 U 1.0 0.35 03/06/19 09:44 Vinyl acetate ug/L 0.19 U 10.0 0.19 03/06/19 09:44 Vinyl chloride ug/L 0.39 U 1.0 0.39 03/06/19 09:44 Xylene (Total) ug/L 2.1 U 5.0 2.1 03/06/19 09:44 1,2-Dichloroethane-d4 (S) % 103 70-130 03/06/19 09:44 4-Bromofluorobenzene (S) % 94 70-130 03/06/19 09:44 Toluene-d8 (S) % 101 70-130 03/06/19 09:44 LABORATORY CONTROL SAMPLE: 2812237 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 20 20.1 101 70-130 1,1,1-Trichloroethane ug/L 20 18.8 94 70-130 1,1,2,2-Tetrachloroethane ug/L 20 21.3 107 68-125 1,1,2-Trichloroethane ug/L 20 20.1 101 70-130 1,1-Dichloroethane ug/L 20 20.2 101 70-130 1,1-Dichloroethene ug/L 20 18.9 94 66-133 1,1-Dichloropropene ug/L 20 20.3 101 70-130 1,2,3-Trichlorobenzene ug/L 20 21.4 107 64-126 1,2,3-Trichloropropane ug/L 20 21.7 108 62-127 1,2,3-Trimethylbenzene ug/L 20 23.0 115 70-130 1,2,4-Trichlorobenzene ug/L 20 19.4 97 63-124 1,2,4-Trimethylbenzene ug/L 20 20.5 102 70-130 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 39 www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451861 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE: 2812237 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,2-Dichlorobenzene ug/L 20 19.5 97 70-130 1,2-Dichloroethane ug/L 20 17.7 88 70-130 1,2-Dichloropropane ug/L 20 19.3 97 70-130 1,3,5-Trimethylbenzene ug/L 20 20.2 101 70-130 1,3-Dichlorobenzene ug/L 20 19.5 98 70-130 1,3-Dichloropropane ug/L 20 20.2 101 70-130 1,4-Dichlorobenzene ug/L 20 19.4 97 70-130 2,2-Dichloropropane ug/L 20 20.2 101 59-133 2-Butanone (MEK) ug/L 40 44.2 111 47-143 2-Chloroethylvinyl ether ug/L 20 20.2 I 101 41-140 2-Chlorotoluene ug/L 20 20.1 101 70-130 2-Hexanone ug/L 40 46.8 117 48-145 4-Chlorotoluene ug/L 20 20.1 101 70-130 4-Methyl-2-pentanone (MIBK) ug/L 40 48.9 122 57-132 Acetone ug/L 40 48.2 120 46-148 Benzene ug/L 20 19.7 99 70-130 Bromobenzene ug/L 20 20.1 100 70-130 Bromochloromethane ug/L 20 19.0 95 70-130 Bromodichloromethane ug/L 20 18.4 92 70-130 Bromoform ug/L 20 17.3 87 49-126 ,romomethane ug/L 20 9.7 48 10-165 v2 Carbon disulfide ug/L 20 26.3 131 60-141 v1 Carbon tetrachloride ug/L 20 20.8 104 63-126 Chlorobenzene ug/L 20 19.2 96 70-130 Chloroethane ug/L 20 22.2 111 71-142 Chloroform ug/L 20 19.2 96 70-130 Chloromethane ug/L 20 16.2 81 40-140 v2 cis-1,2-Dichloroethene ug/L 20 19.3 96 70-130 cis-1,3-Dichloropropene ug/L 20 16.3 82 70-130 Dibromochloromethane ug/L 20 15.4 77 62-118 Dibromomethane ug/L 20 18.3 92 70-130 Dichlorodifluoromethane ug/L 20 20.2 101 47-150 Ethylbenzene ug/L 20 20.0 100 70-130 lodomethane ug/L 40 21.7 54 10-164 v2 Isopropylbenzene (Cumene) ug/L 20 19.6 98 70-130 m&p-Xylene ug/L 40 40.4 101 70-130 Methyl-tert-butyl ether ug/L 20 22.3 112 64-124 Methylene Chloride ug/L 20 18.2 91 65-136 n-Butylbenzene ug/L 20 20.5 102 70-130 n-Propylbenzene ug/L 20 21.2 106 70-130 o-Xylene ug/L 20 19.1 96 70-130 p-Isopropyltoluene ug/L 20 17.4 87 70-130 sec-Butylbenzene ug/L 20 20.6 103 70-130 Styrene ug/L 20 18.0 90 70-130 tert-Butylbenzene ug/L 20 20.7 103 70-130 Tetrachloroethene ug/L 20 19.7 98 64-134 Toluene ug/L 20 20.4 102 70-130 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 39 ceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451861 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE: 2812237 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers trans-1,2-Dichloroethene ug/L 20 19.7 98 68-127 trans-1,3-Dichloropropene ug/L 20 16.0 80 65-121 Trichloroethene ug/L 20 19.2 96 70-130 Trichlorofluoromethane ug/L 20 22.0 110 65-135 Vinyl acetate ug/L 20 24.4 122 60-144 Vinyl chloride ug/L 20 19.1 95 68-131 Xylene (Total) ug/L 60 59.5 99 70-130 1,2-Dichloroethane-d4 (S) % 101 70-130 4-Bromofluorobenzene (S) % 95 70-130 Toluene-d8 (S) % 99 70-130 MATRIX SPIKE SAMPLE: 2812239 Parameter 35451633002 Spike MS MS % Rec Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 0.32 U 20 13.3 67 70-130 J(M1) 1,1,1-Trichloroethane ug/L 0.30 U 20 14.4 72 70-130 1,1,2,2-Tetrachloroethane ug/L 0.20 U 20 14.9 74 68-125 1,1,2-Trichloroethane ug/L 0.30 U 20 13.9 70 70-130 1,1-Dichloroethane ug/L 0.34 U 20 15.4 77 70-130 1,1-Dichloroethene ug/L 0.27 U 20 16.8 84 66-133 1,1-Dichloropropene ug/L 0.31 U 20 14.3 71 70-130 1,2,3-Trichlorobenzene ug/L 0.34 U 20 11.7 59 64-126 J(M1) 1,2,3-Trichloropropane ug/L 1.1 U 20 13.5 68 62-127 1,2,3-Trimethylbenzene ug/L 0.17 U 20 16.3 82 70-130 1,2,4-Trichlorobenzene ug/L 0.32 U 20 10.7 54 63-124 J(M1) 1,2,4-Trimethylbenzene ug/L 0.24 U 20 12.8 64 70-130 J(M1) 1,2-Dichlorobenzene ug/L 0.29 U 20 12.7 64 70-130 J(M1) 1,2-Dichloroethane ug/L 0.27 U 20 13.1 66 70-130 J(M1) 1,2-Dichloropropane ug/L 0.23 U 20 13.9 70 70-130 1 ,3,5-Tri methylbenzene ug/L 0.24 U 20 13.1 65 70-130 J(M1) 1,3-Dichlorobenzene ug/L 0.33 U 20 12.9 64 70-130 J(M1) 1,3-Dichloropropane ug/L 0.26 U 20 13.4 67 70-130 J(M1) 1,4-Dichlorobenzene ug/L 0.28 U 20 13.0 65 70-130 J(M1) 2,2-Dichloropropane ug/L 0.59 U 20 12.5 62 59-133 2-Butanone (MEK) ug/L 7.5 U 40 30.1 75 47-143 2-Chloroethylvinyl ether ug/L 1.4 U 20 1.4 U 0 41-140 J(M1) 2-Chlorotoluene ug/L 0.28 U 20 13.2 66 70-130 J(M1) 2-Hexanone ug/L 0.85 U 40 28.5 71 48-145 4-Chlorotoluene ug/L 0.22 U 20 13.3 66 70-130 J(M1) 4-Methyl-2-pentanone (MIBK) ug/L 0.32 U 40 0.32 U 0 57-132 J(M1) Acetone ug/L 5.3 U 40 36.7 82 46-148 Benzene ug/L 0.30 U 20 14.2 71 70-130 Bromobenzene ug/L 0.21 U 20 14.0 70 70-130 Bromochloromethane ug/L 0.37 U 20 13.8 69 70-130 J(M1) Bromodichloromethane ug/L 0.19 U 20 13.4 67 70-130 J(M1) Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 39 aceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451861 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 MATRIX SPIKE SAMPLE: 2812239 Parameter 35451633002 Spike MS MS % Rec Units Result Conc. Result % Rec Limits Qualifiers Bromoform ug/L 2.6 U 20 11.8 59 49-126 Bromomethane ug/L 4.0 U 20 9.1 46 10-165 v2 Carbon disulfide ug/L 0.45 U 20 22.6 113 60-141 v1 Carbon tetrachloride ug/L 1.1 U 20 15.4 77 63-126 Chlorobenzene ug/L 0.35 U 20 13.5 67 70-130 J(M1) Chloroethane ug/L 3.7 U 20 20.6 103 71-142 Chloroform ug/L 0.32 U 20 14.3 71 70-130 Chloromethane ug/L 0.97 U 20 14.1 70 40-140 v2 cis-1,2-Dichloroethene ug/L 0.27 U 20 14.1 71 70-130 cis-1,3-Dichloropropene ug/L 0.17 U 20 10.3 52 70-130 J(M1) Dibromochloromethane ug/L 0.45 U 20 10.2 51 62-118 J(M1) Dibromomethane ug/L 0.68 U 20 12.4 62 70-130 J(M1) Dichlorodifluoromethane ug/L 0.26 U 20 18.0 90 47-150 Ethylbenzene ug/L 0.30 U 20 13.5 68 70-130 J(M1) lodomethane ug/L 9.3 U 40 9.3 U 21 10-164 v2 lsopropylbenzene (Cumene) ug/L 0.30 U 20 12.2 61 70-130 J(M1) m&p-Xylene ug/L 2.1 U 40 27.0 68 70-130 J(M1) Methyl-tert-butyl ether ug/L 0.51 U 20 14.7 74 64-124 Methylene Chloride ug/L 2.0 U 20 14.4 72 65-136 el-Butylbenzene ug/L 0.20 U 20 12.4 62 70-130 J(M1) -Propylbenzene ug/L 0.37 U 20 14.2 71 70-130 o-Xylene ug/L 0.27 U 20 11.7 59 70-130 J(M1) p-Isopropyltoluene ug/L 0.31 U 20 10.7 54 70-130 J(M1) sec-Butylbenzene ug/L 0.17 U 20 13.5 68 70-130 J(M1) Styrene ug/L 0.26 U 20 11.5 57 70-130 J(M1) tert-Butylbenzene ug/L 0.26 U 20 13.6 68 70-130 J(M1) Tetrachloroethene ug/L 0.38 U 20 12.8 64 64-134 Toluene ug/L 0.33 U 20 14.3 72 70-130 trans-1,2-Dichloroethene ug/L 0.23 U 20 14.8 74 68-127 trans-1,3-Dichloropropene ug/L 0.17 U 20 10.6 53 65-121 J(M1) Trichloroethene ug/L 0.36 U 20 13.4 67 70-130 J(M1) Trichlorofluoromethane ug/L 0.35 U 20 18.5 92 65-135 Vinyl acetate ug/L 0.19 U 20 15.3 76 60-144 Vinyl chloride ug/L 0.39 U 20 16.4 82 68-131 Xylene (Total) ug/L 2.1 U 60 38.8 65 70-130 MS 1,2-Dichloroethane-d4 (S) % 104 70-130 4-Bromofluorobenzene (S) % 90 70-130 Toluene-d8 (S) % 98 70-130 SAMPLE DUPLICATE: 2812238 35451633001 Dup Parameter Units Result Result RPD Max RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L 0.32 U 0.32 U 40 1,1,1-Trichloroethane ug/L 0.30 U 0.30 U 40 1,1,2,2-Tetrachloroethane ug/L 0.20 U 0.20 U 40 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/12/2019 09:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 39 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451861 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 SAMPLE DUPLICATE: 2812238 35451633001 Dup Max Parameter Units Result Result RPD RPD Qualifiers 1,1,2-Trichloroethane ug/L 0.30 U 0.30 U 40 1,1-Dichloroethane ug/L 0.34 U 0.34 U 40 1,1-Dichloroethene ug/L 0.27 U 0.27 U 40 1,1-Dichloropropene ug/L 0.31 U 0.31 U 40 1,2,3-Trichlorobenzene ug/L 0.34 U 0.34 U 40 1,2,3-Trichloropropane ug/L 1.1 U 1.1 U 40 1,2,3-Trimethylbenzene ug/L 0.17 U 0.17 U 40 1,2,4-Trichlorobenzene ug/L 0.32 U 0.32 U 40 1,2,4-Trimethylbenzene ug/L 0.24 U 0.24 U 40 1,2-Dichlorobenzene ug/L 0.29 U 0.29 U 40 1,2-Dichloroethane ug/L 0.27 U 0.27 U 40 1,2-Dichloropropane ug/L 0.23 U 0.23 U 40 1,3,5-Trimethylbenzene ug/L 0.24 U 0.24 U 40 1,3-Dichlorobenzene ug/L 0.33 U 0.33 U 40 1,3-Dichloropropane ug/L 0.26 U 0.26 U 40 1,4-Dichlorobenzene ug/L 0.28 U 0.28 U 40 2,2-Dichloropropane ug/L 0.59 U 0.59 U 40 2-Butanone (MEK) ug/L 7.5 U 7.5 U 40 2-Chloroethylvinyl ether ug/L 1.4 U 1.4 U 40 2-Chlorotoluene ug/L 0.28 U 0.28 U 40 2-Hexanone ug/L 0.85 U 0.85 U 40 4-Chlorotoluene ug/L 0.22 U 0.22 U 40 4-Methyl-2-pentanone (MIBK) ug/L 0.32 U 0.32 U 40 Acetone ug/L 5.3 U 5.3 U 40 Benzene ug/L 0.30 U 0.30 U 40 Bromobenzene ug/L 0.21 U 0.21 U 40 Bromochloromethane ug/L 0.37 U 0.37 U 40 Bromodichloromethane ug/L 0.19 U 0.19 U 40 Bromoform ug/L 2.6 U 2.6 U 40 Bromomethane ug/L 4.0 U 4.0 U 40 v2 Carbon disulfide ug/L 0.45 U 0.45 U 40 v1 Carbon tetrachloride ug/L 1.1 U 1.1 U 40 Chlorobenzene ug/L 0.35 U 0.35 U 40 Chloroethane ug/L 3.7 U 3.7 U 40 Chloroform ug/L 0.32 U 0.32 U 40 Chloromethane ug/L 0.97 U 0.97 U 40 v2 cis-1,2-Dichloroethene ug/L 0.27 U 0.27 U 40 cis-1,3-Dichloropropene ug/L 0.17 U 0.17 U 40 Dibromochloromethane ug/L 0.45 U 0.45 U 40 Dibromomethane ug/L 0.68 U 0.68 U 40 Dichlorodifluoromethane ug/L 0.26 U 0.26 U 40 Ethylbenzene ug/L 0.30 U 0.30 U 40 lodomethane ug/L 9.3 U 9.3 U 40 v2 Isopropylbenzene (Cumene) ug/L 0.30 U 0.30 U 40 m&p-Xylene ug/L 2.1 U 2.1 U 40 Methyl-tert-butyl ether ug/L 0.51 U 0.51 U 40 Methylene Chloride ug/L 2.0 U 2.0 U 40 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 39 /9, aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451861 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 SAMPLE DUPLICATE: 2812238 Parameter 35451633001 Dup Max Units Result Result RPD RPD Qualifiers n-Butylbenzene ug/L 0.20 U 0.20 U 40 n-Propylbenzene ug/L 0.37 U 0.37 U 40 o-Xylene ug/L 0.27 U 0.27 U 40 p-Isopropyltoluene ug/L 0.31 U 0.31 U 40 sec-Butylbenzene ug/L 0.17 U 0.17 U 40 Styrene ug/L 0.26 U 0.26 U 40 tert-Butylbenzene ug/L 0.26 U 0.26 U 40 Tetrachloroethene ug/L 0.38 U 0.38 U 40 Toluene ug/L 0.33 U 0.33 U 40 trans-1,2-Dichloroethene ug/L 0.23 U 0.23 U 40 trans-1,3-Dichloropropene ug/L 0.17 U 0.17 U 40 Trichloroethene ug/L 0.36 U 0.36 U 40 Trichlorofluoromethane ug/L 0.35 U 0.35 U 40 Vinyl acetate ug/L 0.19 U 0.19 U 40 Vinyl chloride ug/L 0.39 U 0.39 U 40 Xylene (Total) ug/L 2.1 U 2.1 U 40 1,2-Dichloroethane-d4 (S) % 103 104 0 40 4-Bromofluorobenzene (S) % 89 91 3 40 Y Toluene-d8 (S) % 100 100 0 40 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 39 72eAnaIyticaI www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451861 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 520947 Analysis Method: EPA 8081 QC Batch Method: EPA 3510 Analysis Description: 8081 GCS Pesticides Associated Lab Samples: 35451861001 METHOD BLANK: 2813016 Matrix: Water Associated Lab Samples: 35451861001 Parameter Blank Reporting Units Result Limit MDL Analyzed Qualifiers 4,4'-DDD ug/L 0.0089 U 0.010 0.0089 03/08/19 02:42 4,4'-DDE ug/L 0.0050 U 0.010 0.0050 03/08/19 02:42 4,4'-DDT ug/L 0.0050 U 0.010 0.0050 03/08/19 02:42 Aldrin ug/L 0.0015 U 0.010 0.0015 03/08/19 02:42 alpha-BHC ug/L 0.0021 U 0.010 0.0021 03/08/19 02:42 beta-BHC ug/L 0.0080 U 0.010 0.0080 03/08/19 02:42 Chlordane (Technical) ug/L 0.18 U 0.50 0.18 03/08/19 02:42 delta-BHC ug/L 0.0048 U 0.010 0.0048 03/08/19 02:42 Dieldrin ug/L 0.0020 U 0.010 0.0020 03/08/19 02:42 Endosulfan I ug/L 0.0051 U 0.010 0.0051 03/08/19 02:42 Endosulfan II ug/L 0.0040 U 0.010 0.0040 03/08/19 02:42 Endosulfan sulfate ug/L 0.0062 U 0.10 0.0062 03/08/19 02:42 Endrin ug/L 0.0043 U 0.010 0.0043 03/08/19 02:42 Endrin aldehyde ug/L 0.0036 U 0.10 0.0036 03/08/19 02:42 Endrin ketone ug/L 0.0050 U 0.010 0.0050 03/08/19 02:42 gamma-BHC (Lindane) ug/L 0.0022 U 0.010 0.0022 03/08/19 02:42 Heptachlor ug/L 0.0062 U 0.010 0.0062 03/08/19 02:42 Heptachlor epoxide ug/L 0.0052 U 0.010 0.0052 03/08/19 02:42 Methoxychlor ug/L 0.0096 U 0.010 0.0096 03/08/19 02:42 Toxaphene ug/L 0.25 U 0.50 0.25 03/08/19 02:42 Decachlorobiphenyl (S) % 48 10-132 03/08/19 02:42 Tetrachloro-m-xylene (S) % 67 27-124 03/08/19 02:42 LABORATORY CONTROL SAMPLE & LCSD: 2813017 2813251 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers 4,4'-DDD ug/L 0.5 0.50 0.52 99 103 67-133 4 40 4,4'-DDE ug/L 0.5 0.48 0.50 96 100 59-125 3 40 4,4'-DDT ug/L 0.5 0.51 0.52 102 104 54-132 2 40 Aldrin ug/L 0.5 0.43 0.44 87 88 25-116 2 40 alpha-BHC ug/L 0.5 0.51 0.54 102 109 53-126 6 40 beta-BHC ug/L 0.5 0.51 0.53 101 107 62-130 5 40 delta-BHC ug/L 0.5 0.47 0.52 95 104 35-122 10 40 Dieldrin ug/L 0.5 0.56 0.59 112 118 66-128 5 40 Endosulfan I ug/L 0.5 0.49 0.51 97 102 67-125 4 40 Endosulfan II ug/L 0.5 0.44 0.47 89 95 67-131 7 40 Endosulfan sulfate ug/L 0.5 0.44 0.48 88 96 62-127 9 40 Endrin ug/L 0.5 0.55 0.58 110 115 66-130 5 40 Endrin aldehyde ug/L 0.5 0.45 0.51 90 102 61-124 12 40 Endrin ketone ug/L 0.5 0.46 0.49 91 98 65-132 7 40 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 39 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451861 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE & LCSD: 2813017 2813251 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers gamma-BHC (Lindane) ug/L 0.5 0.54 0.57 108 115 58-127 6 40 Heptachlor ug/L 0.5 0.45 0.48 90 95 35-123 5 40 Heptachlor epoxide ug/L 0.5 0.51 0.53 102 106 62-125 4 40 Methoxychlor ug/L 0.5 0.48 0.50 96 101 59-135 4 40 Decachlorobiphenyl (S) % 47 46 10-132 Tetrachloro-m-xylene (S) % 74 74 27-124 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 39 ceAnalytical® wwwpacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451861 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521006 Analysis Method: EPA 8270 by SIM QC Batch Method: EPA 3510 Analysis Description: 8270 Water PAHLV by SIM MSSV Associated Lab Samples: 35451861001 METHOD BLANK: 2813544 Matrix: Water Associated Lab Samples: 35451861001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1-Methylnaphthalene ug/L 0.19 U 2.0 0.19 03/07/19 08:37 2-Methylnaphthalene ug/L 0.68 U 2.0 0.68 03/07/19 08:37 Acenaphthene ug/L 0.040 U 0.50 0.040 03/07/19 08:37 Acenaphthylene ug/L 0.030 U 0.50 0.030 03/07/19 08:37 Anthracene ug/L 0.043 U 0.50 0.043 03/07/19 08:37 Benzo(a)anthracene ug/L 0.055 U 0.10 0.055 03/07/19 08:37 Benzo(a)pyrene ug/L 0.12 U 0.20 0.12 03/07/19 08:37 Benzo(b)fluoranthene ug/L 0.027 U 0.10 0.027 03/07/19 08:37 Benzo(g,h,i)perylene ug/L 0.15 U 0.50 0.15 03/07/19 08:37 Benzo(k)fluoranthene ug/L 0.16 U 0.50 0.16 03/07/19 08:37 Chrysene ug/L 0.026 U 0.50 0.026 03/07/19 08:37 Dibenz(a,h)anthracene ug/L 0.13 U 0.15 0.13 03/07/19 08:37 Fluoranthene ug/L 0.018 U 0.50 0.018 03/07/19 08:37 Fluorene ug/L 0.088 U 0.50 0.088 03/07/19 08:37 Indeno(1,2,3-cd)pyrene ug/L 0.12 U 0.15 0.12 03/07/1908:37 Naphthalene ug/L 0.29 U 2.0 0.29 03/07/19 08:37 Phenanthrene ug/L 0.16 U 0.50 0.16 03/07/19 08:37 Pyrene ug/L 0.032 U 0.50 0.032 03/07/19 08:37 2-Fluorobiphenyl (S) % 63 33-82 03/07/19 08:37 p-Terphenyl-d14 (S) % 102 49-104 03/07/19 08:37 LABORATORY CONTROL SAMPLE: 2813545 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1-Methylnaphthalene ug/L 5 3.3 66 40-96 2-Methylnaphthalene ug/L 5 3.3 65 40-94 Acenaphthene ug/L 5 3.2 65 42-96 Acenaphthylene ug/L 5 3.2 63 39-90 Anthracene ug/L 5 3.7 75 46-109 Benzo(a)anthracene ug/L 5 4.1 83 50-116 Benzo(a)pyrene ug/L 5 4.1 83 48-117 Benzo(b)fluoranthene ug/L 5 4.2 85 51-124 Benzo(g,h,i)perylene ug/L 5 4.1 83 47-121 Benzo(k)fluoranthene ug/L 5 4.4 88 50-125 Chrysene ug/L 5 4.4 87 53-122 Dibenz(a,h)anthracene ug/L 5 4.0 80 45-123 Fluoranthene ug/L 5 4.5 90 52-119 Fluorene ug/L 5 3.4 68 44-100 Indeno(1,2,3-cd)pyrene ug/L 5 4.0 79 46-121 Naphthalene ug/L 5 3.2 64 40-91 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 39 www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451861 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE: 2813545 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phenanthrene ug/L 5 3.7 73 47-111 Pyrene ug/L 5 4.4 88 51-120 2-Fluorobiphenyl (S) % 71 33-82 p-Terphenyl-d14 (S) % 98 49-104 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2813901 2813902 MS MSD 35452061003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1-Methylnaphthalene ug/L 0.19 U 5 5 3.1 3.1 62 62 40-96 1 40 2-Methylnaphthalene ug/L 0.68 U 5 5 3.2 3.1 64 61 40-94 4 40 Acenaphthene ug/L 0.040 U 5 5 3.0 3.2 60 63 42-96 4 40 Acenaphthylene ug/L 0.030 U 5 5 2.9 3.0 58 61 39-90 4 40 Anthracene ug/L 0.043 U 5 5 3.7 3.9 74 78 46-109 5 40 Benzo(a)anthracene ug/L 0.055 U 5 5 4.0 4.2 81 83 50-116 3 40 Benzo(a)pyrene ug/L 0.12 U 5 5 4.0 4.0 81 79 48-117 2 40 Benzo(b)fluoranthene ug/L 0.027 U 5 5 4.0 4.0 81 80 51-124 1 40 Benzo(g,h,i)perylene ug/L 0.15 U 5 5 4.0 3.8 79 77 47-121 3 40 'enzo(k)fluoranthene ug/L 0.16 U 5 5 4.2 4.1 84 82 50-125 2 40 .;hrysene ug/L 0.026 U 5 5 4.2 4.2 84 85 53-122 1 40 Dibenz(a,h)anthracene ug/L 0.13 U 5 5 3.9 3.7 77 74 45-123 4 40 Fluoranthene ug/L 0.018 U 5 5 4.5 4.7 89 94 52-119 5 40 Fluorene ug/L 0.088 U 5 5 3.2 3.4 65 69 44-100 5 40 Indeno(1,2,3-cd)pyrene ug/L 0.12 U 5 5 3.9 3.7 77 75 46-121 3 40 Naphthalene ug/L 0.29 U 5 5 2.9 2.9 58 58 40-91 0 40 Phenanthrene ug/L 0.16 U 5 5 3.7 3.8 73 77 47-111 4 40 Pyrene ug/L 0.032 U 5 5 4.4 4.5 87 91 51-120 4 40 2-Fluorobiphenyl (S) % 68 70 33-82 p-Terphenyl-d14 (S) % 97 98 49-104 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/12/2019 09:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 21 of 39 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451861 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521011 Analysis Method: FL -PRO QC Batch Method: EPA 3510 Analysis Description: FL -PRO Water Low Volume Associated Lab Samples: 35451861001 METHOD BLANK: 2813560 Matrix: Water Associated Lab Samples: 35451861001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Petroleum Range Organics mg/L 0.80 U 1.0 0.80 03/07/19 12:40 N-Pentatriacontane (S) % 86 42-159 03/07/19 12:40 o-Terphenyl (S) % 79 66-139 03/07/19 12:40 LABORATORY CONTROL SAMPLE: 2813561 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Petroleum Range Organics mg/L N-Pentatriacontane (S) o-Terphenyl (S) 5 4.4 87 66-119 99 42-159 94 66-139 MATRIX SPIKE SAMPLE: 2814271 35452019001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Petroleum Range Organics mg/L 0.73 U 4.6 3.9 80 65-123 N-Pentatriacontane (S) % 89 42-159 o-Terphenyl (S) % 90 66-139 SAMPLE DUPLICATE: 2814272 35451859001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Petroleum Range Organics mg/L 0.79 U 0.77 U N-Pentatriacontane (S) % 97 91 9 o-Terphenyl (S) % 81 89 7 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 22 of 39 (/eAna/YticaI www.pacelabs.com QUALIFIERS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451861 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PAST-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: 520947 [M5] A matrix spike/matrix spike duplicate was not performed for this batch due to insufficient sample volume. ANALYTE QUALIFIERS The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. U Compound was analyzed for but not detected. 1 p A matrix spike/matrix spike duplicate was not performed for this batch due to insufficient sample volume. J(M1) Estimated Value. Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. MS Analyte recovery in the matrix spike was outside QC limits for one or more of the constituent analytes used in the calculated result. Y The laboratory analysis was from an improperly preserved sample. c2 Acid preservation may not be appropriate for the analysis of 2-Chloroethylvinyl ether. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. Date: 03/12/2019 09:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 39 aceAnalytical® www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451861 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID QC Batch Method Analytical QC Batch Analytical Method Batch 35451861001 MW-44 EPA 3510 520947 EPA 8081 521160 35451861001 MW-44 EPA 3510 521011 FL -PRO 521222 35451861001 MW-44 EPA 3010 521178 EPA 6010 521271 35451861001 MW-44 EPA 7470 521100 EPA 7470 521259 35451861001 MW-44 EPA 3510 521006 EPA 8270 by SIM 521083 35451861001 MW-44 EPA 8260 520786 Date: 03/12/2019 09:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 24 of 39 PceAnai}4ical CHAIN-OF-Ct The Chain-of-CustodWO# : 35451861 1 accurately. Section A Required Client Information: Section B St Required Project Information: In` 111\ III 1111 Mil 111 35451861dc. Page : 1 Of 1 Company EE&G Environmental Services, I -LC Report To. .=1{ k1\!C Q.F.A. Vet. -.A Alt Address 5751 Miami Lakes Dr Copy To' C' .�L . Gl.C..IC,+1` e.,-- Co Hialeah, FL 33014 LJ A Regulatory Agency �j Email m}rpSrrtary..e r ian eecr3n�4. C o,„� Purchase Order R. Project Name- Me,`re,Zye_. G—c - (.nurse Project #: 2018-3U5 / Pace Or.role Phone' (305)374-83Q0 l ax - J Pace Project Manager chnslina raschke@tpacelabs. com, f'- - State 1 Location • Requested Due Date , ,la�-l-,r..'L 1A-( Pace Profile tf / •;` FL Requ t aI Fil ored (YIN) c C ~ SAMPLE ID One Character per box. Sample Ids must be unique MATRIX. CODE Drinemq Wntnr OW Water WT W,ste Wnrer WW e. Product oL Wine wR Air AR Other OT Tissue T5 MATRIX CODE (see vald codes to left) 'SAMPLE TYPE (G=GRAB C=COMP) COLLECTED SAMPLE TEMP AT COLLECTION T OF CONTAINERS Preservatives Z _ } l ) `� START END Unpreserjed Nr 0 _ rh _ = = OZ Na2S2O3 c L :70 -.. ID l' Analyses Test 8260 VOC PAH by 8270 SIM TRPH FL -PRO Pesticides 8081(c; w, Pesticides 81416,- Herbicides 8151(\ \ `l cn r0 'R 0 0 6010$a, Cd, Cr, Se, Ag, 7470 Hg `y()g.I !? blc .41 :e— . G-1 ^r5 �y/1 H --4T ^� -z I Residual Chlorine (Y/N) I DATE TIME DATE TIME 1 Lril ' - q&r -;.4 lc( io,"', • ` x)6 >C ,4 2 3 4 5 6 7 8 9 10 11 12 ADDITIONAL COMMENTS -. , RELINQUISH DBY/rAfFW TION -,. , % . DATE, • •TIME �ACCEP1Eo BY (AFFILIATION DATE TIME. SAMPLE CONDITIONS _� � `: �` " ?I J `r / >� �( i �—�= >l-'� `,� r , N., L,' 7 4 \/ Iv \; 1 f 9 / • C3 �r i \� ? o N 01 C. SAMPLER NAME AND, SIGNATURE... , - ITEMP in C Received on Ice (YIN) Custody Sealed Cooler (YIN) Samples Intact (Y/N) PRINT Name of SAMPLER: I �L'<"/l":: k j /�1.1: SIGNATURE of SAMPLER: / - i� J DATE Signed: 3 I / q ii. Li, --/-=� viceA/72/)/1/C3/ „., Document Name Sample Condition Upon Receipt Form Document Revise° May 30. 2018 Document No F-FL-C-007 rev 13 Issuing Authority Pace Florida Quality Office ImmummimmIWN:35451861 Project # PM: CTR Project Manager: CLIENT : 36—EEC Client: Thermometer Used: D Stale of rigi ; P VA\Va_ C� Cooler #1 Temp.`C (Visual) (J, D (Correction Factor) 3. �7 (Actual) Cooler #2 Temp.'C (Visual) 0 0� (Correction Factor) (0. 0 (Actual) Cooler #3 Temp.'C 5s 5 (Visual) 7 /_(Correction Factor) 5,5 (Actual) Cooler #4 Temp.'C (Visual) (Correction Factor) _ (Actual) Cooler#5 Temp.'C (Visual) (Correction Factor) (Actual) Cooler#6 Temp.'C (Visual) (Correction Factor) (Actual) Courier: �- Fed Ex UPS USPS - Client ▪ ▪ Commercia. Shipping Method: E. First Overnight Other Billing: IT Recipient Tracking # Priority Overnight T Sender Custody Seal on Cooler/Box Present: des Packing Material: ❑Bubble Wrap Samples shorted to lab (If Yes, complete) — Pace Standard Overnight T Ground CT Third Party - Credit Card Seals intact: ni Yes ubble Bags LNone 0Other Shorted Date: 1\.)' Comments: Due Date: 03/12/19 Dater 3 11 Time Date and Initials of p Examining contents: Label:_ Deliver' pH: J For VA'V projects, all containers verified to <_ii `C Samples on ice, cooling process has begun Samples on ice, cooling process has begun Samples on ice, cooking process has begun • Samples on ice, cooking process has begun • Samples on ice; cooling process has begun • Samples on ice, cooling process has begun 0 Other International Priority Unknown Shorted Time. Chain of Custody Present E es _ No ❑N/A Chain of Custody Filled Out s _ No ON/A Relinquished Signature & Sampler Name COC eNo DN/A Samples Arrived within Hold Time ms Yes ;Ell No ❑N/A Rush TAT requested on COC DYes = o nN/A Sufficient Volume ..,...;21res _; No ON/A Correct Containers Used . Ves D No ON/A Containers Intact fees _ No ❑N/A Sample Labels match COC (sample Ds & date/time of collection)s i : No ON/A All containers needing acid/base preservation have beer. checked. Yes =• No 3N/A All Containers needing preservation are found to be in / compliance with EPA recommendation .Yes = No ❑N/A Exceptions VOA, Coliform, TOC, OBG, Carbamates Preservation Preservative Information Lot #!Trace # Date i initials Headspace in VOA Vials? ( >6mm): Ei Yes _ No_/A Trip Blank Present: GYes = No _N/A Client Notification/ Resolution: Person Contacted: Comments/ Resolution (use back for additional comments): Date/Time Project Manager Review Date Page 26 of 39 aceAnalytical® National Center for Testing & Innovation A\ALYT CAL RHDORT March 12, 2019 Pace Analytical - Pompano Beach, FL Sample Delivery Group L1076231 Samples Received: 03/07/2019 Project Number: 35451861 Description: 2018-3057Melreese golf course Site: 001 Report To: Christina Raschke 3610 Park Central Blvd N Pompano Beach, FL 33064 Entire Report Reviewed By: Jason Romer Project Manager Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace National is performed per guidance provided in laboratory standard operating procedures: 060302, 060303, and 060304. 12065 Lebanon Rd Mount Juliet, TN 37122 615-758-5858 800-767-5859 www.pacenational.com TABLE OF CONTENTS ONE LAB. NATIONWIDE. Cp:Cover%=age 1 Tc: Table of Contents 2 Ss: Sample Summary 3 Cn: Case Narrative 4 Sr: Sample Results 5 MW-44 L1076231-01 5 Qc: Quality Control Summary 6 Chlorinated Acid Herbicides (GC) by Method 8151 6 OP Pesticides by Method 8141 7 GI: Glossary of Terms 10 Al: Accreditations & Locations 11 Sc: Sample Chain of Custody 12 Cn Qc GI Al ACCOUNT: Pace Analytical - Pompano Beach, FL Page 28 of 39 PROJECT: SDG: DATE/TIME: PAGE: 35451861 L1076231 03/12/1915:51 2 of 13 SAMPLE SUMMARY ONE LAB. NATIONWIDE. AO MW-44 L1076231-01 GW _,Ili cted by Collected date/time Received d h° time 03/04/1910:14 0307/19 09:00 ',od Chlorinated Acid Herbicides (GC) by Method 8151 OP Pesticides by Method 8141 ACCOUNT: Pace Analytical - Pompano Beach, FL Batch Dilution Preparation Analysis Analyst Location date/time date/time WG1247068 1 03/08/19 08:07 03/09/19 02:29 KLM Mt. Juliet, TN WG1246727 1 03/07/19 18:03 03/11/1919:44 HMH Mt. Juliet, TN Cp Tc Cn 5 Sr 6 Qc GI Al Page 29 of 39 PROJECT: SDG: DATE/TIME: PAGE: 35451861 L1076231 03/12/1915:51 3 of 13 CASE NARRATIVE ONE LAB. NATIONWIDE. All sample aliquots were received at the correct temperature, in the proper containers, with the appropriate preservatives, and within method specified holding times, unless qualified or notated within the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data. Jason Romer Project Manager ACCOUNT: Pace Analytical - Pompano Beach, FL Ss Cn GI Al Page 30 of 39 PROJECT: SDG: DATE/TIME: PAGE: 35451861 L1076231 03/12/1915:51 4 of 13 MW-44 SAMPLE RESULTS - 01 Collected date/time: 03/04/19 10:14 L1076231 ONE LAB. NATIONWIDE. Mk Chlorinated Acid Herbicides (GC) by Method 8151 Result Qualifier MDL RDL Dilution Analysis Batch to ug/I ug/I ug/I date / time _, .-1) 0.744 U 0.744 2.00 1 03/09/2019 02:29 WG1247068 Dalapon 1.04 U 1.04 2.00 1 03/09/2019 02:29 WG1247068 2,4-DB 0.775 U 0.775 4.00 1 03/09/2019 02:29 WG1247068 Dicamba 0.813 U 0.813 2.00 1 03/09/2019 02:29 WG1247068 Dichloroprop 0.778 U 0.778 2.00 1 03/09/2019 02:29 WG1247068 Dinoseb 0.795 U 0.795 2.00 1 03/09/2019 02:29 WG1247068 MCPA 13.1 J U 13.1 200 1 03/09/2019 02:29 WG1247068 MCPP 7.15 U 7.15 200 1 03/09/2019 02:29 WG1247068 2,4,54 0.843 U 0.843 2.00 1 03/09/2019 02:29 WG1247068 2,4,5-TP (Silvex) 0.845 U 0.845 2.00 1 03/09/2019 02:29 WG1247068 (S) 2,4 Dichlorophenyl Acetic 60.0 14.0-158 03/09/2019 02:29 WG1247068 Acid OP Pesticides by Method 8141 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date/time Azinphos-Methyl 0.348 U 0.348 1.00 1 03/11/201919:44 WG1246727 Bolstar (Sulprofos) 0.205 U 0.205 1.00 1 03/11/201919:44 WG1246727 Chlorpyrifos 0.245 U 0.245 1.00 1 03/11/201919:44 WG1246727 Coumaphos 0.277 U 0.277 1.00 1 03/11/201919:44 WG1246727 Demeton,-0 and -S 0.341 J U 0.341 2.00 1 03/11/201919:44 WG1246727 Diazinon 0.377 U 0-377 1.00 1 03/11/201919:44 WG1246727 Dichlorvos 0.212 U 0.212 2.00 1 03/11/201919:44 WG1246727 Dimethoate 0.105 U 0.105 1.00 1 03/11/201919:44 WG1246727 Disulfoton 0.277 U 0.277 1.00 1 03/11/2019 19:44 WG1246727 '" 0.261 J U 0.261 1.00 1 03/11/201919:44 WG1246727 ,crop 0.354 U 0.354 1.00 1 03/11/201919:44 WG1246727 Ethyl Parathion 0.292 J U 0.292 1.00 1 03/11/201919:44 WG1246727 Fensulfothion 0.130 U 0.130 1.00 1 03/11/201919:44 WG1246727 Fenthion 0.266 U 0.266 1.00 1 03/11/201919:44 WG1246727 Malathion 0.173 U 0.173 1.00 1 03/11/201919:44 WG1246727 Merphos 0.267 U 0.267 2.00 1 03/11/201919:44 WG1246727 Methyl parathion 0.257 J U 0.257 1.00 1 03/11/201919:44 WG1246727 Mevinphos 0.118 U 0.118 1.00 1 03/11/201919:44 WG1246727 Naled 0.289 J U 0.289 1.00 1 03/11/201919:44 WG1246727 Phorate 0.282 U 0.282 1.00 1 03/11/201919:44 WG1246727 Ronnel 0.252 U 0.252 1.00 1 03/11/2019 19:44 WG1246727 Stirophos 0.226 U 0.226 1.00 1 03/11/201919:44 WG1246727 Sulfotep 0.202 U 0.202 1.00 1 03/11/2019 19:44 WG1246727 TEPP 9.74 J U 9.74 20.0 1 03/11/2019 19:44 WG1246727 Tokuthion (Prothothiofos) 0.254 U 0.254 1.00 1 03/11/201919:44 WG1246727 Trichloronate 0.213 U 0.213 1.00 1 03/11/201919:44 WG1246727 (S) Triphenyl Phosphate 82.4 42.0-129 03/11/2019 19:44 WG1246727 ACCOUNT: Pace Analytical - Pompano Beach, FL Cp 4 Cn 5 Sr 6 Qc GI Al Page 31 of 39 PROJECT: SDG: DATE/TIME: PAGE: 35451861 L1076231 03/12/1915:51 5 of 13 WG1247068 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE.All Chlorinated Acid Herbicides (GC) by Method 8151 L1076231-01 Method Blank (MB) (MB) R3390374-1 03/09/19 01:08 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I 2,4-0 0.744 U 0.744 2.00 Dalapon 1.04 U 1.04 2.00 2,4-DB 0.775 U 0.775 4.00 Dicamba 0.813 U 0.813 2.00 Dichloroprop 0.778 U 0.778 2.00 Dinoseb 0.795 U 0.795 2.00 MCPA 13.1 U 13.1 200 MCPP 7.15 U 7.15 200 2,4,5-T 0.843 U 0.843 2.00 2,4,5-TP (Silvex) 0.845 U 0.845 2.00 (S) 2,4-Dichlorophenyl Acetic 66.2 14.0-158 Acid Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3390374-2 03/09/19 01:22 • (LCSD) R3390374-3 03/09/19 01:35 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I % % % % 2,4-0 5.00 3.28 3.31 65.6 66.2 50.0-120 0.910 20 Dalapon 5.00 2.64 2.67 52.8 53.4 32.0-120 1.13 20 2,4-08 5.00 3.73 4.10 74.6 82.0 53.0-140 P 9.45 20 Dicamba 5.00 3.49 3.50 69.8 70.0 51.0-120 0.286 20 Dichloroprop 5.00 3.26 3.30 65.2 66.0 55.0-127 1.22 20 Dinoseb 5.00 2.21 2.18 44.2 43.6 36.0-134 1.37 20 MCPA 50.0 232 193 464 386 10.0-160 J L P J L 18.4 40 MCPP 50.0 19.9 20.5 39.8 41.0 10.0-160 2.97 23 2,4,5-T 5.00 3.72 3.69 74.4 73.8 54.0-120 0.810 20 2,4,5-TP (Silvex) 5.00 3.69 3.68 73.8 73.6 50.0-125 0.271 20 (S) 2,4-Dichlorophenyl Acetic Acid 62.8 60.8 14.0-158 ACCOUNT: Pace Analytical - Pompano Beach, FL Cp 2 Tc 3 SS 4 Cn a Sr GI Al SC age 32 of 39 PROJECT: SDG: DATE/TIME: AGE: 35451861 L1076231 03/12/1915:51 6 of 13 WG12 727 QUALITY COS ROL SUMMARY OP Pestici,. _ by Method 8141 L1,. .31-01 Method Blank (MB) ONE LAB. f' 0NWIDE. (MB) R3390660-1 03/11/19 11:42 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I Azinphos-Methyl 0.348 U 0.348 1.00 Bolstar (Sulprofos) 0.205 U 0.205 1.00 Chlorpyrifos 0.245 U 0.245 1.00 Coumaphos 0.277 U 0.277 1.00 Demeton,-0 and -S 0.341 U 0.341 2.00 Diazinon 0.377 U 0.377 1.00 Dichlorvos 0.212 U 0.212 2.00 Dimethoate 0.105 U 0.105 1.00 Disulfoton 0.277 U 0.277 1.00 EPN 0.261 U 0.261 1.00 Ethoprop 0.354 U 0.354 1.00 Ethyl Parathion 0.292 U 0.292 1.00 Fensulfothion 0.130 U 0.130 1.00 Fenthion 0.266 U 0.266 1.00 Malathion 0.173 U 0.173 1.00 Merphos 0.267 U 0.267 2.00 Methyl parathion 0.257 U 0.257 1.00 Mevinphos 0.118 U 0.118 1.00 Naled 0.289 U 0.289 1.00 Phorate 0.282 U 0.282 1.00 Ronnel 0.252 U 0.252 1.00 Stirophos 0.226 U 0.226 1.00 Sulfotep 0.202 U 0.202 1.00 TEPP 9.74 U 9.74 20.0 Tokuthion (Prothothiofos) 0.254 U 0.254 1.00 Trichloronate 0.213 U 0.213 1.00 (S) Tripheny/ Phosphate 56.4 42.0-129 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3390660-2 03/11/19 12:45 • (LCSD) R3390660-3 03/11/19 13:17 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I % % % % % Azinphos-Methyl 5.00 3.70 4.38 74.0 87.6 43.0-142 16.8 20 Bolster (Sulprofos) 5.00 3.58 4.03 71.6 80.6 47.0-128 11.8 20 Chlorpyrifos 5.00 3.62 4.26 72.4 85.2 50.0-126 16.2 20 Coumaphos 5.00 3.85 4.40 77.0 88.0 37.0-137 P P 13.3 20 Demeton,-0 and -5 2.50 ND ND 0.000 0.000 22.0-150 J J 0.000 24 Diazinon 5.00 4.14 4.41 82.8 88.2 54.0-130 6.32 20 Cp °Ss 4 Cn 6 QC GI AI Page 33 of 39 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Pompano Beach, FL 35451861 L1076231 03/12/19 15:51 7 of 13 WG1246727 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. sk OP Pesticides by Method 8141 L1076231-01 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3390660-2 03/11/19 12:45 • (LCSD) R3390660-3 03/11/19 13:17 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I % % % % % Dichlorvos 5.00 3.88 4.38 77.6 87.6 43.0-135 12.1 24 Dimethoate 5.00 2.17 2.80 43.4 56.0 27.0-120 25.4 27 Disulfoton 5.00 3.59 4.10 71.8 82.0 44.0-136 13.3 21 EPN 5.00 8.45 9.01 169 180 31.0-143 J J 6.41 21 Ethoprop 5.00 3.76 4.05 75.2 81.0 52.0-130 7.43 20 Ethyl Parathion 5.00 7.36 8.02 147 160 42.0-134 J J 8.58 20 Fensulfothion 5.00 3.79 4.36 75.8 87.2 42.0-137 14.0 20 Fenthion 5.00 3.44 4.03 68.8 80.6 53.0-133 P 15.8 20 Malathion 5.00 3.29 3.56 65.8 71.2 47.0-121 7.88 20 Merphos 5.00 3.48 4.14 69.6 82.8 14.0-123 17.3 25 Methyl parathion 5.00 4.92 6.10 98.4 122 43.0-135 J 21.4 20 Mevinphos 5.00 3.57 4.33 71.4 86.6 49.0-123 19.2 23 Naled 5.00 5.47 7.24 109 145 25.0-126 J 27.9 26 Phorate 5.00 3.60 3.74 72.0 74.8 44.0-129 3.81 20 Ronnel 5.00 3.42 3.93 68.4 78.6 51.0-125 13.9 20 Stirophos 5.00 3.77 4.61 75.4 92.2 53.0-125 20.0 20 Sulfotep 5.00 3.87 4.40 77.4 88.0 40.0-140 12.8 22 TEPP 50.0 17.6 34.2 35.2 68.4 18.0-122 J 64.1 32 Tokuthion (Prothothiofos) 5.00 3.59 4.14 71.8 82.8 50.0-128 14.2 20 Trichloronate 5.00 3.74 4.26 74.8 85.2 47.0-130 13.0 21 (S) Triphenyl Phosphate 68.0 74.6 42.0-129 L1075936-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1075936-01 03/11/19 14:52 • (MS) R3390660-4 03/11/19 15:24 • (MSD) R3390660-5 03/11/19 15:55 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I ug/I % % % % % Azinphos-Methyl 5.00 0.348 3.50 3.62 70.0 72.4 1 29.0-157 3.37 20 Bolstar (Sulprofos) 5.00 0.205 3.33 3.39 66.6 67.8 1 37.0-138 1.79 20 Chlorpyrifos 5.00 0.245 3.63 3.62 72.6 72.4 1 42.0-131 0.276 20 Coumaphos 5.00 0.277 3.74 3.57 74.8 71.4 1 31.0-150 P P 4.65 20 Demeton,-0 and -S 2.50 0.341 0.341 0.341 0.000 0.000 1 30.0-152 J U J U 0.000 20 Diazinon 5.00 0.377 4.06 4.04 81.2 80.8 1 47.0-134 0.494 20 Dichlorvos 5.00 0.212 3.92 3.65 78.4 73.0 1 39.0-140 7.13 22 Dimethoate 5.00 0.105 2.54 2.39 50.8 47.8 1 17.0-129 6.09 20 Disulfoton 5.00 0.277 3.45 3.42 69.0 68.4 1 42.0-131 0.873 21 EPN 5.00 0.261 8.45 8.23 169 165 1 17.0-155 J J P 2.64 20 Ethoprop 5.00 0.354 3.68 3.13 73.6 62.6 1 46.0-133 16.2 20 Ethyl Parathion 5.00 0.292 7.11 7.22 142 144 1 30.0-138 J P J P 1.54 20 ACCOUNT: Pace Analytical - Pompano Beach, FL Cp 3SS 4 Cn Sr 7GI Al ge34of39 PROJECT: SDG: DATE/TIME: AGE: 35451861 L1076231 03/12/19 15:51 8 of 13 WG12 727 QUALITY COr R0L SUMMARY ONE LAB. ""�NWIDE. a OP Pestici,. . by Method 8141 L1. .31-01 L1075936-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1075936-01 03/11/1914:52 • (MS) R3390660-4 03/11/19 15:24 • (MSD) R3390660-5 03/11/1915:55 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I ug/I % % % % % Fensulfothion 5.00 0.130 3.68 3.94 73.6 78.8 1 36.0-145 6.82 20 Fenthion 5.00 0.266 3.44 3.43 68.8 68.6 1 46.0-140 P P 0.291 20 Malathion 5.00 0.173 3.69 3.19 73.8 63.8 1 39.0-126 14.5 20 Merphos 5.00 0.267 2.97 2.82 59.4 56.4 1 10.0-120 5.18 27 Methyl parathion 5.00 0.257 4.89 4.98 97.8 99.6 1 28.0-142 1.82 20 Mevinphos 5.00 0.118 3.61 3.39 72.2 67.8 1 38.0-134 6.29 20 Naled 5.00 0.289 5.51 5.11 110 102 1 14.0-130 7.53 20 Phorate 5.00 0.282 3.44 3.33 68.8 66.6 1 38.0-134 3.25 20 Ronnel 5.00 0.252 3.58 3.21 71.6 64.2 1 42.0-131 10.9 20 Stirophos 5.00 0.226 3.89 3.63 77.8 72.6 1 33.0-143 6.91 20 Sulfotep 5.00 0.202 3.98 3.72 79.6 74.4 1 34.0-143 6.75 20 TEPP 50.0 9.74 30.9 38.7 61.8 77.4 1 38.0-120 22.4 25 Tokuthion (Prothothiofos) 5.00 0.254 3.58 3.48 71.6 69.6 1 35.0-140 2.83 24 Trichloronate 5.00 0.213 3.89 3.58 77.8 71.6 1 41.0-133 8.30 20 (S) Triphenyl Phosphate 67.4 66.0 42.0-129 ACCOUNT: Pace Analytical - Pompano Beach, FL Cp 2 Tc 3Ss 4 Cn Sr 6 Qc 7GI Al Page 35 of 39 PROJECT: SDG: DATE/TIME: PAGE: 35451861 L1076231 03/12/19 15:51 9 of 13 GLOSSARY OF TERMS Guide to Reading and Understanding Your Laboratory Report ONE LAB. NATIONWIDE.Alt Cp] The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and if you have additional questions please contact your project representative. Abbreviations and Definitions MDL ND RDL Rec. RPD SDG (S) Analyte Dilution Limits Original Sample Qualifier Result Uncertainty (Radiochemistry) Case Narrative (Cn) Quality Control Summary (Qc) Sample Chain of Custody (Sc) Sample Results (Sr) Sample Summary (Ss) Qualifier Method Detection Limit. Not detected at the Reporting Limit (or MDL where applicable). Reported Detection Limit. Recovery. Relative Percent Difference. Sample Delivery Group. Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be detected in all environmental media. The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes reported. If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor. These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or duplicated within these ranges. The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control sample. The Original Sample may not be included within the reported SDG. This column provides a letter and/or number designation that corresponds to additional information concerning the result reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable. The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL" (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte. Confidence level of 2 sigma. A brief discussion about the included sample results, including a discussion of any non -conformances to protocol observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report. This section of the report includes the results of the laboratory quality control analyses required by procedure or analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material. This is the document created in the field when your samples were initially collected. This is used to verify the time and date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the samples from the time of collection until delivery to the laboratory for analysis. This section of your report wit provide the results of all testing performed on your samples. These results are provided by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for each sample will provide the name and method number for the analysis reported. This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and times of preparation and/or analysis. Description J L P U The value is outside laboratory established criteria. Off -scale high. Actual value is known to be greater than value given. RPD between the primary and confirmatory analysis exceeded 40%. Indicates the compound was analyzed for but not detected above the method detection limit. ACCOUNT: PROJECT: SDG: Pace Analytical - Pompano Beach, FL 35451861 L1076231 DATE/TIME: 03/12/1915:51 I �1 SS 4 Cn 5 Sr 6 Qc GI uAl Page 36 of 39 PAGE: 10 of 13 ACCREDITATIONS & LOCATIONS ONE LAB. NATIONWIDE.1111 Pace National is the only environmental laboratory accredited/certified to support your work nationwide from one location. One phone call, one point of contact, one laboratory. No other lab is as accessible or prepared to handle your needs throughout the country. our capacity and capability from our single location laboratory is comparable to the collective totals of the network laboratories in our industry. The most significant benefit to our one location design is the design of our laboratory campus. The model is conducive to accelerated productivity, decreasing turn -around time, and preventing cross contamination, thus protecting sample integrity. Our focus on premium quality and prompt service allows us to be YOUR LAB OF CHOICE. * Not all certifications held by the laboratory are applicable to the results reported in the attached report. Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace National. State Accreditations Alabama 40660 Nebraska NE-0S-15-05 Alaska 17-026 Nevada TN-03-2002-34 Arizona AZ0612 New Hampshire 2975 Arkansas 88-0469 New Jersey—NELAP TN002 California 2932 New Mexico' n/a Colorado TN00003 New York 11742 Connecticut PH-0197 North Carolina Env375 Florida E87487 North Carolina' DW21704 Georgia NELAP North Carolina' 41 Georgia' 923 North Dakota R-140 Idaho TN00003 Ohio—VAP CL0069 Illinois 200008 Oklahoma 9915 Indiana C-TN-01 Oregon TN200002 Iowa 364 Pennsylvania 68-02979 Kansas E-10277 Rhode Island LA000356 Kentucky" 90010 South Carolina 84004 Kentucky 5 16 South Dakota n/a Louisiana A130792 Tennessee14 2006 Louisiana' LA180010 Texas T104704245-18-15 Maine TN0002 Texas 5 LAB0152 Maryland 324 Utah TN00003 Massachusetts M-TN003 Vermont VT2006 Michigan 9958 Virginia 460132 Minnesota 047-999-395 Washington C847 Mississippi TN00003 West Virginia 233 Missouri 340 Wisconsin 9980939910 Montana CERT0086 Wyoming A2LA Third Party Federal Accreditations A2LA — ISO 17025 1461.01 A2LA — ISO 17025 5 1461.02 Canada 1461.01 EPA—Crypto TN00003 AIHA-LAP,LLC EMLAP 100789 DOD 1461.01 USDA P330-15-00234 ' Drinking Water 2 Underground Storage Tanks 3 Aquatic Toxicity ° Chemical/Microbiological 5 Mold c Wastewater n/a Accreditation not applicable Our Locations Pace National has sixty-four client support centers that provide sample pickup and/or the delivery of sampling supplies. If you would like assistance from one of our support offices, please contact our main office. Pace National performs all testing at our central laboratory. ACCOUNT: Pace Analytical - Pompano Beach, FL PROJECT: 35451861 SDG: L1076231 DATE/TIME: 03/12/1915:51 O 4 Cn 5 Sr 6 Qc GI 5Al Page 37 of 39 PAGE: 11 of 13 Chain of Custody Workorder: 35451861 Workorder Name: Christina Raschke Pace Analytical South Florida 3610 Park Central Blvd N Pompano Beach, FL 33064 Phone (954)582-4300 Email christina.raschke@pacelabs.com State of Sample Origin: FL M W-44 3/4/2019 10:14 2018-3057Melreese Golf Course 35451861001 P.O. Water 2 3 4 Transfers 1 2 Released By Date/Time g3/4409 /y/ Received By Results Requested By: 3/12/2019 v m tr CJ aceAnalytical w. peceiabs.cam 1-40-4,43 LAB USE ONLY DatelTime �ha 0,64 3 Cooler Temperature on Receipt 0 Custody Seal ro or i- 34 o • I I .y ;3 Received on Ice Y or t_kabl y1-yg _ R Samples Intact Y or Wednesday. March 06. 2019 1 55 42 PM FMT-ALL-C-002rev.00 24March2009 Page 1 of 1 r 38 of 39 Pace Analytical National Center for Testing & Innovation Cooler Receipt Form c:i;enl• Pi>(-4-1)A0- six;n: Llo_76,23( Cooler Received/Opened On: 3 / l /19 Temperature: 1 Received By: Jeremy Webb Signature: (,i /' Receipt Check List NP Yes No COC Seal Present / Intact? ' COC Signed / Accurate? l'— Bottles arrive intact? `' Correct bottles used? ___--_, --- Sufficient volume sent? If Applicable VOA Zero headspace? Preservation Correct / Checked? Page 39 of 39 www pacelabs. com March 28, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451837 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Dear Craig Clevenger: Enclosed are the analytical results for samples) received by the laboratory on March 05, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, n Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry, EE&G Environmental Services. LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 18 aceAnalytical www.pacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451837 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35451837001 MW-44 Water 03/04/19 10:14 03/05/19 17:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 18 PaceMalylical CHAIN-OF-CUST(W0# : 35451837 rately -� v�vvVJVV� Section A Section B Section C Required Client Information: Required Project Information: Invoice Ir 0111111111111011111 35451837 III Page : 1 Of 1 Company EERG Environmental Services, LLC Report To k\,Lh 4,4'ck Attention Address 5751 Miami Lakes Ur Copy To C' eLi3 al .4 .-16e r- Company Name Hialeah, FL 33014 Address. Regulatory Agency #.k Pace Quote Email r J ...n r e + e ,,� C,,„,_ Purchase Order Phone (305)374-8'y00 l ax pp Project Name L`r g,2,i,.•✓ C—c. ' (r,La a Pace Project Managerchristina.raschke a pacelabs corn. State l Location • Requested Due Date. .�!T�- --,—,"l , '- Project #: 2018-30/ / Pace Profile # FL Requ t al Filtered (YIN) MATRIX CODE MATRIX CODE (see valid codes to left) 'SAMPLE TYPE (G=GRAB C=COMP) COLLECTED SAMPLE TEMP AT COLLECTION # OF CONTAINERS Preservatives Z >' a e t) `3 J Dunking Ventre OW Wsmr Wr Waste Wale! WW SAMPLE ID Pomsom SI. START END H2SO4 HNO3 HCI Na2S203 Methanol Other rAnalyses Test 8260 VOC PAH by 8270 SIM TRPH FL -PRO Pesticides 8081(0.0k„, Pesticides 814 K to — Herbicides 8151 C. C4i `lam cn co C X Q L6010 Ba, Cd, Cr, Se, Ag, 7470 Hg' N A5, e, At, • G-t 2, Residual Chlorine (Y/N) U.IH One Character per box. w4 r WP (A-Z, 0-9 l , 192 Otrncr OT Sample Ids must be unique Tissue Ts DATE TIME DATE TIME a L m w c 2 2 0 cci Z 1 I"l\ !, ` �1�- '� > Li 1-i (t'I `1 p f 2 3 4 5 6 7 8 9 10 11 12 ADDITIONAL COMMENTS • RELINQU)SHED By r AFFILIATION - r 7 DATE TIME .rr7 AC PTED BY/AFFILIATION •. C/�J .DATE TIME SAMPLE CONDITIONS � /����. L/:.,^�n.l. ff/F-��L +�J 1t / '�P�l[E,l /L'��--• r/ sty/ .�\4Y1/ i 'C.�. /'-;.11‘'_ 3J /':-1' ✓.`/J:) 1 ,�.1 ) j� \' �( F ' I /e � (Cti,ill'� /P ( ,) 4 /,c) 1 I!-�"u'5 c . U 1� �'% 1' � I i , ( 1 . `") \I , 1 . J SAMPLER NAME AND SIGNATURE TEMP In C u } usto y Sealed Cooler (YIN) Samples Intact (YIN) PRINT Name of SAMPLER: 1 lc, ` SIGNATURE of SAMPLER j �' • / "I , / I DATE Signed: 7-,Ju / ' co ce 0 :carmen: Sample Conditio.. Upon Recagp Form 2313 Pace Analytical Document No FL-C-O07rev 13 # PM: CTR Project Manager: CLIENT: 36®EE( Client: Thermometer Used A o35451837 19 Due Date: 03/15/19 Date 3) ri State of. rig; ( W6cia_ Time ,ce Quality Office Date and Initials of p Examining contents: Label: Deliver pH: Initials 7 Tor projects all pontairers ver,fert to <t `C ( Cooler #1 Temp.'C (Visual) O. 0 (Correction Factor) (Actual) Cooler #2 Temp.'C (Visual) 0 0 (Correction Factor) Co. 0 (Actual) Cooler #3 Temp.'C 5 3 (Visual) 0,0 (Correction Factor) Vi _ 5 (Actual) Cooler #4 Temp.'C (Visual) (Correction Factor) (Actual) Cooler #5 Temp.'C Cooler #6 Temp.'C Courier: — Shipping Method: Billing: Tracking # Custody Seal on Cooler/Box Present: Packing Material: -Bubble Wrap 4 Samples shorted to lab (If Yes, complete) (Visual) (Correction Factor) (Actual) (Visual) (Correction Factor) (Actual) Fed Ex — - UPS ❑ USPS — - Client - Commercia — Pace First Overnight _ Priority Overnight 7 Standard Overnight -. Ground _ Other Recipient Sender _ Third Party ubbte Baas !—.None Shorted Date _ Credit Card Seals intact: _ Yes Other Comments: Sarioies on ce, cooling a" lc „_ .. •„_. cooling Shingle_ cco'irg C L Samdies on ice c000ng L Saes _cooing SamCies on ice cooing L Other process "as begu process `as beC process ray begun proctes5 has begur crocess ^as begun crocess .as beau International Priority Unknown tue Dry None Shorted Time Qty-- Chain of Custody Present es IT No _N/A Chain of Custody Filled Out _l es _ No _N/A Relinquished Signature & Sampler Name COC _ ems _ No _N/A Samples Arrived within Hold Time ?Yes — No :=N/A Rush TAT requested on COC YesN/A Sufficient Volume metes T No LT N/A Correct Containers Used „fes _ No _N/A Containers Intacts _ No _N/A Sample Labe s match COC (sample IDs & date time of collection)YLs _N1$ Ali containers needing acidf'base preservation have teen �1\' `� / NI checked - es NaA All Containers needing oreser a - r are founc to be in compliance with EPA recommendation No _ /A Exceptions VOA Conform, TOC C&G. Cap.. tes Preservation Preservative Information Lot r?rece qqq r. Date >�\� I dials Headspace in VOA Vials? ( >6mm) _Yes _ No - Trip Blank Present _Yes _ No L Client Notification/ Resolution: Person Contacted Comments/ Resolution (use back for additional comments): Date/Time Project Manager Review Date Page 4 of 18 ace Analytical T www.pacelabs.com www.pacelabs.com Report Prepared for: Christina Raschke PASI Florida 3610 Park Central Blvd N Pompano Beach FL 33064 REPORT OF LABORATORY ANALYSIS FOR PCDD/PCDF Report Prepared Date: March 14, 2019 Report No 10466119_8290FC_DFR Pace Analytical Services, LLC. 1700 Elm Street Minneapolis, MN 55414 Phone: 612.607.1700 Fax: 612.607.6444 Report Information: Pace Project #: 10466119 Sample Receipt Date: 03/07/2019 Client Project #: 35451837 Client Sub PO #: N/A State Cert #: E87605 Invoicing & Reporting Options: The report provided has been invoiced as a Level 2 PCDD/PCDF Report. If an upgrade of this report package is requested, an additional charge may be applied. Please review the attached invoice for accuracy and forward any questions to Kirsten Hogberg, your Pace Project Manager. This report has been reviewed by: March 15, 2019 Kirsten Hogberg, Project Manager (612) 607-6407 (612) 607-6444 (fax) kirsten.hogberg@pacelabs.com Report of Laboratory Analysis Thisreportshouldnotbereproduced,exceptinfull, withoutthewrittenconsentofPaceAnalyticalServices,Inc. Theresultsrelateonlyt othesamplesincludedinthisreport. Page 5 of 18 Page 1 of 14 ace Analytical Pace Analytical Services, LLC. 1700 Elm Street Minneapolis, MN 55414 Phone: 612.607.1700 Fax: 612.607.6444 DISCUSSION This report presents the results from the analysis performed on one sample submitted by a representative of Pace Analytical Services, LLC. The sample was analyzed for the presence or absence of polychlorodibenzo-p-dioxins (PCDDs) and polychlorodibenzofurans (PCDFs) using a modified version of USEPA Method 8290. The reporting limits were based on signal-to-noise measurements. Estimated Maximum Possible Concentration (EMPC) values were treated as positives in the toxic equivalence calculations. Per request, estimated detection limit (EDL) values were provided and flagged "U" where the target analytes were not detected. The recoveries of the isotopically -labeled PCDD/PCDF internal standards in the sample extract ranged from 44-68%. Except for two low values, which were flagged "R" on the results table, the labeled internal standard recoveries obtained for this project were within the 40-135% target range specified in Method 8290. Also, since the quantification of the native 2,3,7,8-substituted congeners was based on isotope dilution, the data were automatically corrected for recovery and accurate values were obtained. A laboratory method blank was prepared and analyzed with the sample batch as part of our routine quality control procedures. The results show that PCDDs and PCDFs were not detected. These results indicate that the sample preparation procedures did not significantly impact the results of the field sample determinations. Laboratory spike samples were also prepared with the sample batch using clean reference matrix that had been fortified with native standard materials. The results show that the spiked native compounds were recovered at 92-120% with relative percent differences of 0.0-10.3%. These results were within the target ranges for the method. Matrix spikes were not prepared with the sample batch. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Page 6 of 18 Page 2 of 14 Report No 10466119_8290FC_DFR TM Minnesota Laboratory Certifications Pace Analytical Services. LLC 1700 Elm Street - Suite 200 Minneapolis. MN 55414 TeI:612-607-1700 Fax: 612-607-6444 Authority Certificate # Authority Certificate # A2LA 2926.01 Minnesota - Pet 1240 Alabama 40770 Mississippi MN00064 Alaska - DW MN00064 Missouri - DW 10100 Alaska - UST 17-009 Montana CERT0092 Arizona AZ0014 Nebraska NE-OS-18-06 Arkansas - DW MN00064 Nevada MN00064 Arkansas - WW 88-0680 New Hampshire 2081 CNMI Saipan MP0003 New Jersey (NE MN002 California 2929 New York 11647 Colorado MN00064 North Carolina 27700 Connecticut PH-0256 North Carolina - 27700 EPA Region 8+ via MN 027-053 North Carolina - 530 Florida (NELAP E87605 North Dakota R-036 Georgia 959 Ohio - DW 41244 Guam 17-001r Ohio - VAP CL101 Hawaii MN00064 Oklahoma 9507 Idaho MN00064 Oregon - Primar MN300001 Illinois 200011 Oregon - Secon MN200001 Indiana C-MN-01 Pennsylvania 68-00563 Iowa 368 Puerto Rico MN00064 Kansas E-10167 South Carolina 74003 Kentucky - DW 90062 South Dakota NA Kentucky - WW 90062 Tennessee TN02818 Louisiana - DE 03086 Texas T104704192 Louisiana - DW MN00064 Utah (NELAP) MN00064 Maine MN00064 Virginia 460163 Maryland 322 Washington C486 Massachusetts M-MN064 West Virginia - 382 Michigan 9909 West Virginia - 9952C Minnesota 027-053-137 Wisconsin 999407970 Minnesota - De via MN 027-053 Wyoming - UST 2926.01 REPORT OF LABORATORYANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466119_8290FC_DFR Page 7 of 18 Page 3 of 14 Appendix A Sample Management Report No 10466119_8290FC_e Analytical Services, Inc. Page 8 of 18 Page 4 of 14 2:1dC1 Od06Z8 6�1.99ti0L oN pode v m 0 0 Chain of Custody II Samples were sent directly to the Subcontracting Laboratory. Workorder: 35451837 Christina Raschke Pace Analytical South Florida 3610 Park Central Blvd N Pompano Beach, FL 33064 Phone (954)582-4300 2 3 4 Transfers 2 3 Cooler Tem Workorder Name: 2018-3057Melreese Goff Course Pace Analytical Minnesota 1700 Elm Street SE Suite 200 Minneapolis, MN 55414 Phone (612)607-1700 Released By DatelTi e Received By `` State Of Origin: FL Cert. Needed: I1 Yes Li No Owner Received Date: 3/5/2019 Date/Time Results Requested By• WOR:10466119 11161j1111111111 III ceAnalytica! Simi a LAB USE ONLY or N Samples Intact or ***In order to maintain client confidentiality, location/name of the sampling site, sampler's name and signature may not be provided on this COC document. This chain of custody is considered complete as is since this information is available in the owner laboratory. erature on Recei .t Custod Seal Received on Ice Y Tuesday, March 05, 2019 7:30:37 PM FMT-ALL-C-002rev.00 24March2009 Page 1 of 1 - dceAnr?L}/t7Ccil Document Name: Sample Condition Upon Receipt Form Document Revised: 06Feb2019 Page 1 of 1 Document No.: F-MN-L-213-rev.25 Issuing Authority: Pace Minnesota Quality Office Sample Condition Upon Receipt Courier: Project : WO# :10466119 ❑LISPS ❑Client ['Pace ❑SpeeDee ['Commercial see Exception Track ing Number: Thermometer: Custody Seal on Cooler/Box Present? �es DNo Packing Material: (Bubble Wrap Bubble Bags ['None ❑ G87A9155100842 G87A9170600254 Type of Ice: .f 5745 375/ Seals Intact? Yes DNo Biological Tissue Frozen? ❑Yes ❑No N/A Pit: KNH Due Date: 03/21/19 CLIENT: PASI—FL ❑Other: Note: Each West Virginia Sample must have temp taken (no temp blanks) Wet ❑Blue Temp Blank? Eyes ❑None ❑Dry ❑Melted Temp should be above freezing to e'C Cooler Temp Read w/temp blank: Correction Factor: 4lf r ! Cooler Temp Corrected w/temp blank : • Client Name: Fed Ex OM oc oC Average Corrected Temp See Exce ions (no temp b nk only): USDA Regulated Soil: (XN/A, water sample/Other: ) Date/Initials of Person Examining Contents: K i ...I3/ .7 / -/ Did samples originate in a quarantine zone within the United States: AL, AR, CA, FL, GA, Did samples originate from a foreign source (internationally, including ID, LA. MS, NC, NM, NY, OK, OR, SC, TN, TX or VA (check maps)? ['Yes DNo Hawaii and Puerto Rico)? ❑Yes DNo If Yes to either question, fill out a Regulated Soil Checklist {F-MN-Q-336) and include with SCUR/COC paperwork. • COMMENTS: Chain of Custody Present and Filled Out? es ❑No 1. Chain of Custody Relinquished? fijces DNo 2. Sampler Name and/or Signature on COC? Oyes DNo /A 3. Samples Arrived within Hold Time? .es ❑No 4. Short Hold lime Analysis (<72 hr)? ❑Yes No 5• ❑fecal Coliform ❑HPC ❑Total Coliform/E coli ❑BOD/cBOD ❑Hex Chrome ❑Turbidity ❑Nitrate :Nitrite ❑Orthophos ❑Other Rush rum Around Time Requested? ❑Yes0 6. Sufficient Volume? "es DNo 7. _Correct Containers Used? -Pace Containers Used? / es DNo „tees ❑No 8. Containers Intact? ❑No 9. Field Filtered Volume Received for Dissolved Tests? iVes Yes DNo 'N/A 10. is sediment visible in the dissolved container? Des ❑ No Is sufficient information available to reconcile the samples to the CO1? Matrix: V IWater ❑Soil 0011 ['Other Yes ❑No 11. if no, write iD/ Date/Time on container Below: See Exception ❑ All containers needing acid/base preservation have been checked? All containers needing preservation are found to be in compliance with EPA recommendation? (HNO3, H2SO4, <2pH, NaOH >9 Sulfide, NaOH>12 Cyanide) Exceptions: VOA, Coliform, TOC/DOC Oil and Grease, DRO/8015 (water) and Dioxin/PFAS ❑Yes DNo N/A ❑Yes DNo N/A :Yes ❑NoJ�jN/A 12. Sample # ❑ NaOH ❑ HNO3 ❑H2504 ❑Zinc Acetate Positive for Res. ❑Yes see Exception Chlorine? No Ell Headspace in VOA Vials (greater than 6mm)? Y ]Yes ❑No 13. see Exception !. Blank Present? Trio Blank Custody Seals Present? 0/ATrip ❑ves ❑NoA ❑Yes ❑No N/A 14. Pace Trip Blank Lot # (if purchased): CLIENT NOTIFICATION/RESOLUTION Person Contacted: Comments/Resolu tier: Date/Timc: Field Data Required? UYes DNo Project Manager Review: Note: Whenever 'there Is r uisc(apanc\. s Ya-ct..nt; North CEli J.,. is c hold, incorrect preservative, out of temp, incorrect containers). Date: 3/8/2019 1a,,ce r„ies, za willbe cant . _.. trot:r.:.')=HNF:Ce..-._s:._r.Office ('_..._. Page 10 of 18 Page 6 of 14 Report No 10466119_8290FC_DFR /02 ,- ,raceAnalytical . .- Document Name: 1 Document Revised: 04Feb2019 SCUR Exception Form — Coolers Above 6°C I Page 1 Of 1 Document No.: F-MN-C-298-Rev.01 Issuing Authority: Pace Minnesota Quality Office During sample triage, this form is to be placed in each cooler that arrives above 6.0 degrees Celsius SCUR Exceptions: Workorder #: COntakiet # of PM Notified? Out of TioteiOsairotO:io$'_Type Containers If yes, indicate who was contacted/date/time. If no, indicate reason why. Other Issues Issue Type: _ Container # of Sample ID Type Contairiers Multiple j)ecrCYs.,'EON0 Ifyougswerdyes,fitI out information toihe left. - , . . No Temp Read Temp Corrected Temp Average Temp I I. 1.4 a 11 cc t, 6,25, Tracking Number pH Adjustment Log for Preserved Samples Sample ID pH Type of Upon Preserv. Receipt Date Adjusted Time Adjusted Amount Added (mL) Lot44 pH Added After • In Compliance after addition? 1 nitials EYes EINo Oyes No L Wes EINo Page 11 of 18 Page 7 of 14 Report No 10466119 8290FC DFR TM Anal4Vtical Reporting Flags Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 A = Reporting Limit based on signal to noise B = Less than 10x higher than method blank level C = Result obtained from confirmation analysis D = Result obtained from analysis of diluted sample E = Exceeds calibration range I = Interferencepresent J = Estimated value L = Suppressive interference, analyte may be biased low Nn = Value obtained from additional analysis P = PCDEInterference R = Recovery outside target range S = Peak saturated U = Analyte not detected V = Result verified by confirmation analysis X = %D Exceeds limits Y = Calculated using average of daily RFs * = SeeDiscussion REPORT OF LABORATORYANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466119_8290FC_DFR Tel: 612-607-1700 Fax: 612-607-6444 Page 12 of 18 Page 8 of 14 Appendix B Sample Analysis Summary Report No 10466119_8290FC_e Analytical Services, Inc. Page 13 of 18 Page 9 of 14 Analytical Client's Sample ID Lab Sample ID Filename Injected By Total Amount Extracted % Moisture Dry Weight Extracted ICAL ID CCal Filename(s) Method Blank ID Native Isomers 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD TM Metho d 8290 Sample Analysis Results Client - PASI Florida MW-44 35451837001 F190313B_13 SMT 1030 mL NA NA F190112 F190313A_18 & BLANK-68966 Conc EMPC pg/L pg/L 1.1 U 1.1 U 2.3 U 2.3 U 1.5 U 1.1 U 1.3 U 1.9 U 1.9 U 2.0 U 1.8 U 1.6 U 2.1 U 1.9 U 2.8 U 3.0 U 2.5 U 2.7 U 3.5 U 5.6 U 4.6 U 3.6 U 3.6 U 11 U 13 U Matrix Dilution Collected Received F190313B_17 Extracted Analyzed EDL Internal pg/L Standards 1.1 2,3,7,8-TCDF-13C 1.1 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 2.3 2,3,4,7,8-PeCDF-13C 2.3 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 1.5 1,2,3,6,7,8-HxCDF-13C 1.1 2,3,4,6,7,8-HxCDF-13C 1.3 1, 2, 3, 7, 8, 9-HxC DF-13C 1,2,3,4,7,8-HxCDD-13C 1.9 1,2, 3,6,7,8-HxCDD-13C 1.9 1, 2, 3,4,6, 7, 8-H pC D F-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 2.0 1.8 1.6 2.1 1.9 2.8 3.0 2.5 2.7 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis. MN 55414 Tel: 612-607-1700 Fax: 612- 607-6444 Water NA 03/04/2019 10:14 03/07/2019 08:55 03/11/2019 12:00 03/14/2019 05:38 ng's Percent Added Recovery 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 4.00 2.00 2.00 0.20 3.5 Total 2,3,7,8-TCDD 5.6 Equivalence: 0.00 pg/L 4.6 (Lower -bound - Using ITE Factors) 3.6 3.6 11 13 64 67 60 58 65 61 58 68 61 62 64 49 45 51 44 NA NA 87 Conc = Concentration (Totals include 2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit ND = Not Detected NA = Not Applicable NC = Not Calculated REPORT OF LABORATORYANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466119_8290FC_DFR Page 10 of 14 Page 14 of 18 ace Analytical TM Lab Sample Name Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) Method 8290 Blank Analysis Results DFBLKDC BLANK-68966 F190313B_06 945 mL F190112 F190313A_18 & F190313B_17 Native Conc Isomers pg/L EMPC EDL pg/L pg/L Matrix Dilution Extracted Analyzed Injected By Internal Standards Pace Analytical Services. LLC 1700 Elm Street - Suite 200 Minneapolis. MN 55414 Tel: 612-607-1700 Fax: 612-607-6444 Water NA 03/11/2019 12:00 03/14/2019 00:29 SMT 2,3,7,8-TCDF 2.1 U Total TCDF 2.1 U 2,3,7,8-TCDD 2.3 U Total TCDD 2.3 U 1,2,3,7,8-PeCDF 2.0 U 2,3,4,7,8-PeCDF 1.6 U Total PeCDF 1.8 U 1,2,3,7,8-PeCDD 1.8 U Total PeCDD 1.8 U 1,2,3,4,7,8-HxCDF 2.1 U 1,2,3,6,7,8-HxCDF 1.9 U 2,3,4,6,7,8-HxCDF 1.8 U 1,2,3,7,8,9-HxCDF 2.1 U Total HxCDF 2.0 U 1,2,3,4,7,8-HxCDD 2.1 U 1,2,3,6,7,8-HxCDD 2.2 U 1,2,3,7,8,9-HxCDD 1.8 U Total HxCDD 2.0 U 1,2,3,4,6,7,8-HpCDF 3.0 U 1,2,3,4,7,8,9-HpCDF 6.0 U Total HpCDF 4.5 U 1,2,3,4,6,7,8-HpCDD 4.4 U Total HpCDD 4.4 U OCDF 9.1 U OCDD 7.3 U 2.1 1.9 1.8 2.1 2.0 2.1 2.2 1.8 2.0 2.1 2,3,7,8-TCDF-13C 2.1 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 2.3 2,3,4,7,8-PeCDF-13C 2.3 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 2.0 1,2,3,6,7,8-HxCDF-13C 1.6 2,3,4,6,7,8-HxCDF-13C 1.8 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 1.8 1,2,3,6,7,8-HxCDD-13C 1.8 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C ng's Percent Added Recovery 2.00 66 2.00 70 2.00 62 2.00 61 2.00 71 2.00 64 2.00 57 2.00 73 2.00 63 2.00 66 2.00 66 2.00 51 2.00 47 2.00 51 4.00 44 1,2,3,4-TCDD-13C 2.00 NA 1,2,3,7,8,9-HxCDD-13C 2.00 NA 2,3,7,8-TCDD-37CI4 0.20 88 3.0 Total 2,3,7,8-TCDD 6.0 Equivalence: 0.00 pg/L 4.5 (Lower -bound - Using ITE Factors) 4.4 4.4 9.1 7.3 Conc. Concentration (Totals include 2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit REPORT OF LABORATORYANALYSIS This report shall not be reproduced, except in full. without the written consent of Pace Analytical Services, Inc. Report No 10466119_8290FC_DFR Page 11 of 14 Page 15 of 18 AnalyticalTM Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) Method Blank ID Native Isomers 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD Method 82! Method 8290 Laboratory Control Spike Results Qs (ng) 0.20 0.20 1.0 1.0 1.0 1.0 1.0 1.0 1.0 LCS-68967 F190313B_01 923 mL F190112 F190313A_18 & F190313B_17 BLANK-68966 Qm (ng) 0.22 0.23 1.1 1.1 0.97 1.1 1.1 1.1 1.1 Rec. 109 2,3,7,8-TCDF-13C 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 117 2,3,4,7,8-PeCDF-13C 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 105 1,2,3,6,7,8-HxCDF-13C 111 2,3,4,6,7,8-HxCDF-13C 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 97 1,2, 3,6,7,8-HxCDD-13C 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 113 1,2,3,4,6,7,8-HpCDD-13C 108 OCDD-13C 105 105 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C Matrix Dilution Extracted Analyzed Injected By Internal Standards 1.0 1.1 111 2,3,7,8-TCDD-37C14 1.0 1.2 120 1.0 1.0 103 1.0 1.1 107 1.0 1.0 102 1.0 1.0 100 2.0 2.2 108 2.0 2.2 109 Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612-607-6444 Water NA 03/11/2019 12:00 03/13/2019 20:48 SMT ng's Percent Added Recovery 2.0 58 2.0 60 2.0 52 2.0 51 2.0 58 2.0 52 2.0 49 2.0 60 2.0 49 2.0 55 2.0 54 2.0 41 2.0 37 R 2.0 40 4.0 33 R 2.0 NA 2.0 NA 0.20 80 Qs = Quantity Spiked Qm = Quantity Measured Rec. = Recovery (Expressed as Percent) R = Recovery outside of target range Y = RF averaging used in calculations Nn = Value obtained from additional analysis NA = Not Applicable = See Discussion REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466119_8290FC_DFR Page 16 of 18 Page 12 of 14 Analytical Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) Method Blank ID Native Isomers TM Method 8290 Laboratory Control Spike Results Qs (ng) LCSD-68968 F190313B_02 894 mL F190112 F190313A_18 & F190313B_17 BLANK-68966 Qm (ng) Rec. Matrix Dilution Extracted Analyzed Injected By Internal Standards Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis. MN 55414 Tel: 612-607-1700 Fax: 612-607-6444 Water NA 03/11/2019 12:00 03/13/2019 21:33 SMT ng's Percent Added Recovery 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD 0.20 0.22 0.20 0.23 1.0 1.0 1.1 1.1 1.0 0.99 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 0.99 0.97 1.1 1.1 1.0 109 2,3,7,8-TCDF-13C 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 116 2,3,4,7,8-PeCDF-13C 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 105 1,2,3,6,7,8-HxCDF-13C 109 2,3,4,6,7,8-HxCDF-13C 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 99 1,2,3,6,7,8-HxCDD-13C 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 105 104 99 97 109 115 104 1.0 1.0 104 1.0 0.92 92 1.0 0.99 99 2.0 2.1 105 2.0 2.1 106 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 4.0 2.0 2.0 0.20 70 74 61 59 66 66 63 73 63 66 65 51 47 51 42 NA NA 89 Qs = Quantity Spiked Qm = Quantity Measured Rec. = Recovery (Expressed as Percent) R = Recovery outside of target range Y = RF averaging used in calculations Nn = Value obtained from additional analysis NA = Not Applicable * = See Discussion REPORT OF LABORATORYANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466119_8290FC_DFR Page 13 of 14 Page 17 of 18 Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 TM Analytical Method 8290 Spike Recovery Relative Percent Difference (RPD) Results Client PASI Florida Spike 1 ID LCS-68967 Spike 2 ID LCSD-68968 Spike 1 Filename F190313B_01 Spike 2 Filename F190313B_02 Spike 1 Spike 2 Compound %REC %REC %RPD Tel: 612-607-1700 Fax: 612-607-6444 2, 3, 7, 8-TC D F 109 109 0.0 2,3,7,8-TCDD 117 116 0.9 1,2,3,7,8-PeCDF 105 105 0.0 2,3,4,7,8-PeCDF 111 109 1.8 1,2,3,7,8-PeCDD 97 99 2.0 1,2,3,4,7,8-HxCDF 113 105 7.3 1,2,3,6,7,8-HxCDF 108 104 3.8 2,3,4,6,7,8-HxCDF 105 99 5.9 1,2,3,7,8,9-HxCDF 105 97 7.9 1,2,3,4,7,8-HxCDD 111 109 1.8 1,2,3,6,7,8-HxCDD 120 115 4.3 1,2,3,7,8,9-HxCDD 103 104 1.0 1,2,3,4,6,7,8-HpCDF 107 104 2.8 1,2,3,4,7,8,9-HpCDF 102 92 10.3 1,2,3,4,6,7,8-HpCDD 100 99 1.0 OCDF 108 105 2.8 OCDD 109 106 2.8 %REC = Percent Recovered RPD = The difference between the two values divided by the mean value REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466119_8290FC_DFR Page 18 of 18 Page 14 of 14 aceAnalytical www.pacelabs.com April 11, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457299 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 28, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Kelsey Cortina, EE&G Environmental Solutions, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 13 ceAnalytical® www.pacelabs.com CERTIFICATIONS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457299 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alaska DEC- CS/UST/LUST Alabama Certification #: 41320 Arizona Certification# AZ0819 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 13 7'eAnaIyticaI www.pacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457299 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35457299001 MW-44 Water 03/27/19 07:51 03/28/19 17:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 13 aceAnalytical www.pace/abs.com SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457299 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35457299001 MW-44 EPA 8081 TCB 22 PASI-O EPA6010 JWP 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 13 aceAnalytical www.pacelabs.com SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457299 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters 35457299001 EPA 6010 Result MW-44 Iron Units Report Limit Analyzed Qualifiers 795 ug/L 40.0 04/03/19 16:39 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 13 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457299 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-44 Lab ID: 35457299001 Collected: 03/27/19 07:51 Received: 03/28/19 17:45 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8081 GCS Pesticides Analytical Method: EPA 8081 Preparation Method: EPA 3510 Aldrin 0.0014 U ug/L 0.0096 0.0014 1 04/03/19 17:20 04/09/19 15:05 309-00-2 1p alpha-BHC 0.0020 U ug/L 0.0096 0.0020 1 04/03/19 17:20 04/09/19 15:05 319-84-6 1p beta-BHC 0.0077 U ug/L 0.0096 0.0077 1 04/03/19 17:20 04/09/19 15:05 319-85-7 1p delta-BHC 0.0046 U ug/L 0.0096 0.0046 1 04/03/19 17:20 04/09/19 15:05 319-86-8 1p gamma-BHC (Lindane) 0.0021 U ug/L 0.0096 0.0021 1 04/03/19 17:20 04/09/19 15:05 58-89-9 1p Chlordane (Technical) 0.17 U ug/L 0.48 0.17 1 04/03/19 17:20 04/09/19 15:05 57-74-9 1p 4,4'-DDD 0.0085 U ug/L 0.0096 0.0085 1 04/03/19 17:20 04/09/19 15:05 72-54-8 1p 4,4'-DDE 0.0048 U ug/L 0.0096 0.0048 1 04/03/19 17:20 04/09/19 15:05 72-55-9 1p 4.4'-DDT 0.0048 U ug/L 0.0096 0.0048 1 04/03/19 17:20 04/09/19 15:05 50-29-3 1p Dieldrin 0.0019 U ug/L 0.0096 0.0019 1 04/03/19 17:20 04/09/19 15:05 60-57-1 1p Endosulfan I 0.0049 U ug/L 0.0096 0.0049 1 04/03/19 17:20 04/09/19 15:05 959-98-8 1p Endosulfan II 0.0038 U ug/L 0.0096 0.0038 1 04/03/19 17:20 04/09/19 15:05 33213-65-9 1p Endosulfan sulfate 0.0060 U ug/L 0.096 0.0060 1 04/03/19 17:20 04/09/19 15:05 1031-07-8 1p Endrin 0.0041 U ug/L 0.0096 0.0041 1 04/03/19 17:20 04/09/19 15:05 72-20-8 1p Endrin aldehyde 0.0035 U ug/L 0.096 0.0035 1 04/03/19 17:20 04/09/19 15:05 7421-93-4 1p Endrin ketone 0.0048 U ug/L 0.0096 0.0048 1 04/03/19 17:20 04/09/19 15:05 53494-70-5 1p Heptachlor 0.0060 U ug/L 0.0096 0.0060 1 04/03/19 17:20 04/09/19 15:05 76-44-8 1p Heptachlor epoxide 0.0050 U ug/L 0.0096 0.0050 1 04/03/19 17:20 04/09/19 15:05 1024-57-3 1p Methoxychlor 0.0092 U ug/L 0.0096 0.0092 1 04/03/19 17:20 04/09/19 15:05 72-43-5 1p Toxaphene 0.24 U ug/L 0.48 0.24 1 04/03/19 17:20 04/09/19 15:05 8001-35-2 1p Surrogates Tetrachloro-m-xylene (S) 75 % 27-124 1 04/03/19 17:20 04/09/19 15:05 877-09-8 Decachlorobiphenyl (S) 47 % 10-132 1 04/03/19 17:20 04/09/19 15:05 2051-24-3 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3010 Iron Date: 04/11/2019 09:45 PM 795 ug/L 40.0 9.2 1 04/03/19 07:51 04/03/19 16:39 7439-89-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 13 7PceAna/yticaI www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457299 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 528000 Analysis Method: EPA6010 QC Batch Method: EPA 3010 Analysis Description: 6010 MET Associated Lab Samples: 35457299001 METHOD BLANK: 2857698 Matrix: Water Associated Lab Samples: 35457299001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Iron ug/L 9.2 U 40.0 9.2 04/03/19 15:56 LABORATORY CONTROL SAMPLE: 2857699 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Iron ug/L 2000 2010 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2857700 2857701 MS MSD 35457297001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual on ug/L 347 2000 2000 2320 2260 99 96 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/11/2019 09:45 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 13 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457299 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 528202 Analysis Method: EPA 8081 QC Batch Method: EPA 3510 Analysis Description: 8081 GCS Pesticides Associated Lab Samples: 35457299001 METHOD BLANK: 2858737 Matrix: Water Associated Lab Samples: 35457299001 Parameter Blank Reporting Units Result Limit MDL Analyzed Qualifiers 4,4'-DDD ug/L 0.0089 U 0.010 0.0089 04/09/19 11:33 CU 4,4'-DDE ug/L 0.0050 U 0.010 0.0050 04/09/19 11:33 4,4'-DDT ug/L 0.0050 U 0.010 0.0050 04/09/19 11:33 CU Aldrin ug/L 0.0015 U 0.010 0.0015 04/09/19 11:33 alpha-BHC ug/L 0.0021 U 0.010 0.0021 04/09/19 11:33 beta-BHC ug/L 0.0080 U 0.010 0.0080 04/09/19 11:33 Chlordane (Technical) ug/L 0.18 U 0.50 0.18 04/09/19 11:33 delta-BHC ug/L 0.0048 U 0.010 0.0048 04/09/19 11:33 Dieldrin ug/L 0.0020 U 0.010 0.0020 04/09/19 11:33 Endosulfan I ug/L 0.0051 U 0.010 0.0051 04/09/19 11:33 Endosulfan II ug/L 0.0040 U 0.010 0.0040 04/09/19 11:33 CU Endosulfan sulfate ug/L 0.0062 U 0.10 0.0062 04/09/19 11:33 CU Endrin ug/L 0.0043 U 0.010 0.0043 04/09/19 11:33 Endrin aldehyde ug/L 0.013 I 0.10 0.0036 04/09/19 11:33 CU Endrin ketone ug/L 0.0050 U 0.010 0.0050 04/09/19 11:33 CU gamma-BHC (Lindane) ug/L 0.0022 U 0.010 0.0022 04/09/19 11:33 Heptachlor ug/L 0.0062 U 0.010 0.0062 04/09/19 11:33 Heptachlor epoxide ug/L 0.0052 U 0.010 0.0052 04/09/19 11:33 Methoxychlor ug/L 0.0096 U 0.010 0.0096 04/09/19 11:33 CU Toxaphene ug/L 0.25 U 0.50 0.25 04/09/19 11:33 Decachlorobiphenyl (S) % 53 10-132 04/09/19 11:33 Tetrachloro-m-xylene (S) % 66 27-124 04/09/19 11:33 LABORATORY CONTROL SAMPLE & LCSD: 2858738 2858834 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers 4,4'-DDD ug/L 0.5 0.52 0.49 104 98 67-133 6 40 CH 4,4'-DDE ug/L 0.5 0.47 0.43 94 87 59-125 8 40 4,4'-DDT ug/L 0.5 0.57 0.52 113 104 54-132 8 40 CH Aldrin ug/L 0.5 0.31 0.30 63 60 25-116 5 40 alpha-BHC ug/L 0.5 0.50 0.46 100 92 53-126 9 40 beta-BHC ug/L 0.5 0.56 0.51 112 103 62-130 9 40 delta-BHC ug/L 0.5 0.25 0.23 50 47 35-122 6 40 Dieldrin ug/L 0.5 0.51 0.48 102 96 66-128 6 40 Endosulfan I ug/L 0.5 0.51 0.48 103 96 67-125 6 40 Endosulfan II ug/L 0.5 0.52 0.49 103 98 67-131 6 40 CH Endosulfan sulfate ug/L 0.5 0.54 0.51 108 102 62-127 6 40 CH Endrin ug/L 0.5 0.53 0.49 106 98 66-130 8 40 Endrin aldehyde ug/L 0.5 0.60 0.56 120 113 61-124 6 40 CH Endrin ketone ug/L 0.5 0.57 0.55 115 109 65-132 5 40 CH Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/11/2019 09:45 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 13 aceAnalytical www.pace/abs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457299 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE & LCSD: 2858738 2858834 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers gamma-BHC (Lindane) ug/L 0.5 0.53 0.48 106 96 58-127 10 40 Heptachlor ug/L 0.5 0.39 0.36 79 72 35-123 9 40 Heptachlor epoxide ug/L 0.5 0.51 0.47 102 95 62-125 7 40 Methoxychlor ug/L 0.5 0.56 0.52 111 105 59-135 6 40 CH Decachlorobiphenyl (S) % 48 56 10-132 Tetrachloro-m-xylene (S) % 77 70 27-124 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/11/2019 09:45 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 13 aceAnalytical www.pacelabs.com QUALIFIERS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457299 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: 528202 [M5] A matrix spike/matrix spike duplicate was not performed for this batch due to insufficient sample volume. ANALYTE QUALIFIERS The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. U Compound was analyzed for but not detected. 1 p A matrix spike/matrix spike duplicate was not performed for this batch due to insufficient sample volume. CH The continuing calibration for this compound is outside of Pace Analytical acceptance limits. The results may be biased high. CU The continuing calibration for this analyte is above laboratory acceptance limits. Analyte was not detected above the reporting limit in any of the associated samples. Date: 04/11/2019 09:45 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 13 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457299 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID QC Batch Method Analytical QC Batch Analytical Method Batch 35457299001 MW-44 35457299001 MW-44 Date: 04/11/2019 09:45 PM EPA 3510 528202 EPA 8081 529083 EPA 3010 528000 EPA 6010 528101 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 13 PaceAnalytical www.pacelabs.com WO#:35457299 1111111111111111111111! Company Name: Address: PO# Sample Page of, LAB ANALy iS City: Attn: email: State: ,- ` Zip: Fax Phone: Project , Name Sampler Signature `Prof # - Circle One Event: Daily Weekly Monthly • Quartely Semi -Annual Annual N/A qt E t/) 2 3 4 5 6 7 8 9 10 Sample ID Collect Collect Date Time Matrix Code* IL LL G � 'off u� 0 0 TRC pH Pres Codes n Il n n n u # of Containers Size/Type u n u II t, 1— 1ozP II II n II n LJ n In II ❑ ❑ LJ I1 u n II n II n II 11 II LJ II 11 Il Li 11 II n II u 11 11 n n u LJ 11 CO Container Type Codes o AV Anther V,.,1 ES Lribute S.00pito CV Crum Vial PPV Prpn,::mod vrol P PL,::lrc PL C PL,5Hc wnLun,•r AL Aniblr, Lll,•r PL.I Pla::llc Jar Cl Clour Lail Z Ziploc barl AP Alobor Pl:c:ln, TB I,Nl.lr b.ql AG Arnim, U).u.:. WO WWI Pak SJ Soil J:rr G 04111011 JUq 011u,r _ TC iurr;,/rurr• PPV Proproronvod v1111 su IS) 2 :, 404. HU, WO, 34!1/4, or 1L. Mbar 40m1 500r0I 'LII0,1 125 ml Example: 4ozP a 4oz Plastic, 8ozSJ= 8oz Soil Jar N 11 SD GW EFF AFW WW OW SW ML Matrix Codes OI. on -�, SL Skalqu SO Soil S,rd,,nunl i . , • li.'n AU Aquouu;: NA Nonnq,omu:; PE P,:Imhwn 0 ow,,, Preservative Type Codes A. None B. HNO3 C.H2SO4 D. NaOH E. HCL F. McOH G. Na2S2O3 H. NaHSO4 I. Ice J. MCAA K. znAculale O. Other REMARKS 4.1444/1.1 N Item 1 2 3 4 I „day 1D JD II: .II) sD Short Hold N /40vished by Pompano Lab 954-582-4300 Affiliation Circle QA/QC Report Level 1 2 3 •) CLP AFCEE QAPP Other Date ff 72, G 3124 Revision: F•ALL•C•007- Rev.00 re Time 1t,37- t EDD (Fees May Apply) ADuPr SEDD ERPIMS TSV CSV Olhur Received by 1 lion COC Condition RConi ical onequired to Coolers #'s - Temp °C FL GA SC NC NJ PA LA IX IL 1 / i7 2 3 _ 4 _ 5 Time Non Coblonnnncu 101111 ' :+4n,4,i1/, IN1 AC upun.u:ly„I' Roalvnd m, Wei lc1.10 Pr,rl,1/I Pln::,,,y:,b°n::l„w,..nn,r, I0•cnrvud within hoklu,q limo, Cue.Iooy :amin VoLlIllu:; toed without In+o15parn7 Propw , ,,l.un,.,:. 044v1' C.O.C. Serial 12 5 9 7 -T ceAnalytical .7.tonc,tpc Ucoc ne:e,o: ca Document No a :36457299 Project # Pil: CTR CLIENT : 36—EEG Project Manager: Client: Thermometer Used Brae Date: 04/04/19 Pace : io uR) Date and Initials of person: Examining contents: Label: Deliver: pH: Time J) 9 I Lals State of ffOrrii}gin ror .':rt projects all contair..ers vet Pied to 56 `C Cooler #1 Temp.'L`�t• /� (Visual) e • 0 (Correction Factor) ° 2 (Actual) [ Samples c- :-ecco: ng process has becur Cooler #2 Temp.`C _ (Visual) (Correction Factor) (Actual) C Same es c- ce coolino process has begun Cooler #3 Temp.'C (Visual) (Correction Factor) (Actual) 1 Samoes c- ce cconnc process has begun Cooler #4 Temp.'C (Visual) (Correction Factor) (Actual) [ Samples on ce. cooling process has beoun Cooler #5 Temp.`C (Visual) (Correction Factor) (Actual) [ Sar-pies on cuing process has begun Cooler #6 Temp.'C (Visual) (Correction Factor) (Actual) C Sarcc es cc ce. cooing process has beoue Courier: — Fed Ex UPS ❑ USPS — Client L Commercial Pace L Other Shipping Method: = First Overnight = Priority Overnight = Standard Overnight = Ground = International Priority = Other Billing: Tracking # = Recipient Sender Custody Seal on Cooler/Box Present: —iYes Packing Material: -Bubble Wrap ❑ Bubble Bags = Third Party = Credit Card = Unknown Seals intact: - Yes _ No Ice: Blue Dry None _None n Other Samples shorted to lab (If Yes, complete) Shorted Date Comments: Shorted Time Qty Chain of Custody Present LYes = No =NIA Chain of Custody Filled Out — eses = No N/A Relinquished Signature & Sampler Name COC ?Yes 11 No =N/A Samples Arrived within Hold Time !Yes = No EN/A Rush TAT requested on COC =Yes /No EN/A Sufficient Volume :Yes = No =NIA Correct Containers Used 2 es = No =N/A Containers Intact 2yes = No =N/A Sample Labels maicn COC (sample IDs & date/time of collection) .Zes = No =NIA. AN containers needing acidlbase preservation have ceer. �� checked JTeS Ali Containers needing preservation are found to be in compliance with EPA recommendation Exceptions VOA Coliform, TOC. O&G Carbamates = No =N/A = No = N/A Preservation Information Preservative Lot #trace # Date Time Initials Headspace in VOA Vials? (>6mm) =Yes = NO N/A Trip Blank Present =Yes = No/A Client Notification/ Resolution: Person Contacted Comments/ Resolution (use back for additional comments): Date/Time Project Manager Review Date Page 13 of 13 aceAnalytical www.pacelabs.com March 08, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451852 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 05, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry, EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 11 CERTIFICATIONS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451852 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 11 7eAnaIyticaI www.pacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451852 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35451852001 SCS-MW-1 Water 03/04/19 12:14 03/05/19 17:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 11 aceAnalytical www.pacelabs.com SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451852 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35451852001 SCS-MW-1 EPA 6010 SC1 3 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 11 aceAnalytical www.pacelabs.com SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451852 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters 35451852001 EPA 6010 Result SCS-MW-1 Barium Units Report Limit Analyzed Qualifiers 41.4 ug/L 10.0 03/07/19 21:29 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 11 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451852 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SCS-MW-1 Lab ID: 35451852001 Collected: 03/04/19 12:14 Received: 03/05/19 17:45 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Arsenic 7.1 U ug/L 10.0 7.1 1 03/07/19 10:29 03/07/19 21:29 7440-38-2 Barium 41.4 ug/L 10.0 0.84 1 03/07/19 10:29 03/07/19 21:29 7440-39-3 Lead 4.6 U ug/L 10.0 4.6 1 03/07/19 10:29 03/07/19 21:29 7439-92-1 Date: 03/08/2019 12:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 11 PceAnalytical ® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451852 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521178 Analysis Method: EPA 6010 QC Batch Method: EPA 3010 Analysis Description: 6010 MET Associated Lab Samples: 35451852001 METHOD BLANK: 2814528 Matrix: Water Associated Lab Samples: 35451852001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic ug/L 7.1 U 10.0 7.1 03/07/19 20:40 Barium ug/L 0.84 U 10.0 0.84 03/07/19 20:40 Lead ug/L 4.6 U 10.0 4.6 03/07/19 20:40 LABORATORY CONTROL SAMPLE: 2814529 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic ug/L 250 251 100 80-120 Barium ug/L 250 250 100 80-120 Lead ug/L 250 260 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2814530 2814531 MS MSD 35451859001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L 7.1 U 250 250 259 252 104 101 75-125 3 20 Barium ug/L 11.5 250 250 266 260 102 99 75-125 2 20 Lead ug/L 4.6 U 250 250 260 255 104 102 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/08/2019 12:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 11 aceAnalytical® www.pacelabs.com QUALIFIERS Project: 2018-3057/Melreese Golf Course Pace Project No. 35451852 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS U Compound was analyzed for but not detected. Date: 03/08/2019 12:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 11 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451852 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID QC Batch Method Analytical QC Batch Analytical Method Batch 35451852001 SCS-MW-1 Date: 03/08/2019 12:42 PM EPA 3010 521178 EPA 6010 521271 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 11 ceAnalylical • CHAIN-OF-CI.1S ',Inv I A..-r- — The Chain-of-CustLO# : 35451852 ted accurately. - --.. - aecoon o Required Client Information: Required Project Information: III I li Page : I Of i Company EE&G Environmental Services, LLC Report To (1;u„ " y" iG-�� n r �I I I I 1111i1111 Address 5751 Miami Lakes Dr. Copy To: Cr'ee.Ck``f•-• Hialeah, FL 33014 35451852 Regulatory Agency n , Elnail tn W,,- «,>1Purchase � MJc Order # Pace Quote Phone (305)374-8300 Ix Project Narne !Aar l� .C, ryA N\ztC 'w'7i.- � \la. `;;,JS•'je. Pace Project Manager. Christina.raschke(Eilpacelabs.com, State! Location Requ•:stud Due Date S-Vv.,,,..E,4 1.-NT Project #: 2018-3057 Face P'oii.e # FL .,_... Requested Analysis Filtered {YrN) MATRIX CODE I MATRIX CODE (see valid codes to left) [SAMPLE TYPE (G=GRAS C=COMP) COLLECTED SAMPLE TEMP AT COLLECTION 7 OF CONTAINERS i Preservatives 2 %' Dnnktng Water ow Walrr WT Wrrr Water WW Prarlun P SAMPLE ID somsoad sL 011 OL START END Unpreserved H2SO4 HNO3 NaOH Methanol Other Analyses Test _ x �]� El- Q m Residual Chlorine (YIN) I * W F One Character per box. Wppo WP Arr AR Sample Ids must be unique Other suo Ts DATE TIME DATE TIME = O c Z ,/ 2 3 4 5 6 7 8 9 10 11 12 ADDITIONAL COMMENTS RELIINNNQUISHED BYI AFFILIAT�IOON DATE TIME !_--ACCEPTED BY !AFFILIATION DATE SAMPLEA/CONDITIONS / (� }TIME i / LLB ,�k_ ki;,.- I ' �, I �I 11 r� !� . N y SAMPLER NAME AND SIGNATURE c 0 d Z Custody Sealed Cooler (Y/N) m E 2 Z PRINT Name of SAMPLER: , .'A t C.�C-z_- v.:„...,..V-1 1 o c n. SIGNATURE of SAMPLER: r 1 /f ( ( ,j�. DATE Signed: W --4 % ace Analytical Document Name Sample Condition Upon Receipt Form Document Revisea May 30, 2018 Document No F-FL-C-007 rev 13 Issuing Authority Pace Floriaa Quality Office mmimmlimmiW04:35451852 Project # PP1: CTR Project Manager: CLIENT: 36-EEG Client: Thermometer Used \ 3 Q Date: j3) .� Time State of rib 1 c1_ Cooler #1 Temp.°C (p Cooler#2 Temp.°C (Visual) Cooler #3 Temp.°C(Visual) Cooler #4 Temp.'C (Visual) Due Date: 03/12/19 Date and Initials of Examining content: Label: Deliver•, pH: ((�� Eli For WV projects, all containers verified to s6 °C (Visual) O. l,! (Correction Factor) 3. B (Actual) Q. 0 (Correction Factor) (.0 0 (Actual) (Correction Factor) (Actual) (Correction Factor) (Actual) Cooler #5 Temp.`C (Visual) (Correction Factor) (Actual) Cooler#6 Temp.'C (Visual) (Correction Factor) (Actual) Courier: L Fed Ex UPS ❑ USPS Client - Commercia Pace Shipping Method: = First Overnight _ Priority Overnight Standard Overnight Ground Other Billing: Tracking # = Recipient Custody Seal on Cooler/Box Present: Packing Material: L i`Bubble Wrap Lrrrsubble Bags L None _JOther Samples shorted to lab (If Yes, complete) Shorted Date. ) J / Shorted Time Sender D Third Party = Credit Card Samples on ice, cooling process has begun Samples on ice, cooling process has begun Samples or ice, cooling process has begun C Samples on ice, cooling process has begun • Samples on ice, cooling process has begun • Samples on ice, cooling process has begun L; Other International Priority Unknown Seals intact: 7 Yes Comments: lue Dry None Chain of Custody Present _ es - No EJN/A Chain of Custody Filled Out s E No ❑N/A Relinquished Signature & Sampler Name COC es�E] No ON/A Samples Arrived within Hold Time v/Yes = No ❑N/A Rush TAT requested on COC _Yes o C+N/A Sufficient Volume (es - No EN/A Correct Containers Used (es 'I; No LIN/A Containers Intact — es E No ON/A Sample Labels match COC (sample IDs & date/time of collection) :Yes E.; No _N/A All containers needing acid/base preservation have been � checked. e .. No ' N/A All Containers needing preservation are found to be in compliance with EPA recommendation Yes '_ No EN/A Exceptions: VOA: Coliform, TOO, O&G, Carbamates Preservation Information' Preservative Lot ll/Trace # Dale i Initials f ` Headspace in VOA Vials? (>6mm): _Yes = o7g. Trip Blank Present: 1Yes = No — !A Client Notification/ Resolution: Person Contacted: Comments/ Resolution (use back for additional comments): Date/Time Project Manager Review. Date Page 11 of 11 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 March 08, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451847 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 05, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, (?1-t2 ,J2 Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry, EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 13 aceAnaI ical www..pacelabs.com CERTIFICATIONS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451847 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 13 aceAnalytical® www.pacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451847 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35451847001 SCS-MW-1 Water 03/04/19 12:14 03/05/19 17:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 13 _ aceAnalytical l www. paceabs.com SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451847 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35451847001 SCS-MW-1 EPA 6010 SC1 2 PASI-O EPA 300.0 JDM 2 PASI-O EPA 350.1 MAJ 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 13 aceAnalytical® www.pacelabs.com SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451847 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35451847001 SCS-MW-1 EPA 6010 Iron 1350 ug/L EPA 350.1 Nitrogen, Ammonia 0.23 mg/L REPORT OF LABORATORY ANALYSIS 40.0 03/07/19 21:29 0.050 03/06/19 08:25 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 13 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451847 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-562-4300 Sample: SCS-MW-1 Lab ID: 35451847001 Collected: 03/04/19 12:14 Received: 03/05/19 17:45 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Aluminum 30.7 U ug/L 100 30.7 1 03/07/19 10:29 03/07/19 21:29 7429-90-5 Iron 1350 ug/L 40.0 9.2 1 03/07/19 10:29 03/07/19 21:29 7439-89-6 300.0 IC Anions Analytical Method: EPA 300.0 Nitrate as N Nitrite as N 350.1 Ammonia Nitrogen, Ammonia Date: 03/08/2019 12:39 PM 0.025 U mg/L 0.050 0.025 1 0.025 U mg/L 0.050 0.025 1 Analytical Method: EPA 350.1 0.23 mg/L 0.050 0.035 1 REPORT OF LABORATORY ANALYSIS 03/06/19 08:04 14797-55-8 03/06/19 08:04 14797-65-0 03/06/19 08:25 7664-41-7 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 13 c=_ aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451847 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521178 Analysis Method: EPA 6010 QC Batch Method: EPA 3010 Analysis Description: 6010 MET Associated Lab Samples: 35451847001 METHOD BLANK: 2814528 Matrix: Water Associated Lab Samples: 35451847001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Aluminum ug/L 30.7 U 100 Iron ug/L 9.2 U 40.0 30.7 03/07/19 20:40 9.2 03/07/19 20:40 LABORATORY CONTROL SAMPLE: 2814529 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Aluminum ug/L 2500 2520 101 80-120 Iron ug/L 2500 2610 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2814530 2814531 MS MSD 35451859001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 30.7 U 2500 2500 2590 2530 103 101 75-125 2 20 Iron ug/L 369 2500 2500 2980 2910 105 102 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/08/2019 12:39 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 13 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451847 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 520750 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 35451847001 METHOD BLANK: 2812105 Matrix: Water Associated Lab Samples: 35451847001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrate as N mg/L 0.025 U 0.050 0.025 03/06/19 11:46 Nitrite as N mg/L 0.025 U 0.050 0.025 03/06/19 11:46 LABORATORY CONTROL SAMPLE: 2812106 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/L 5 5.0 100 90-110 Nitrite as N mg/L 5 4.9 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2812128 2812129 MS MSD 35451851001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrate as N mg/L 0.025 U 5 5 4.8 4.8 96 96 90-110 1 20 Nitrite as N mg/L 0.025 U 5 5 4.9 4.9 98 97 90-110 1 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/08/2019 12:39 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 13 (_PaceAnalytical® wwwpacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451847 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 520730 Analysis Method: EPA 350.1 QC Batch Method: EPA 350.1 Analysis Description: 350.1 Ammonia Associated Lab Samples: 35451847001 METHOD BLANK: 2812044 Matrix: Water Associated Lab Samples: 35451847001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Ammonia mg/L 0.035 U 0.050 0.035 03/06/19 08:14 LABORATORY CONTROL SAMPLE: 2812045 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 1 1.1 105 90-110 MATRIX SPIKE SAMPLE: 2812047 35451845001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 0.58 1 1.6 103 90-110 SAMPLE DUPLICATE: 2812046 35451845001 Dup Parameter Units Result Result RPD Max RPD Qualifiers Nitrogen, Ammonia mg/L 0.58 0.58 0 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/08/2019 12:39 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 13 aceAnalytical www.pacelabs.com QUALIFIERS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451847 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS U Compound was analyzed for but not detected. Date: 03/08/2019 12 39 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 13 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451847 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID QC Batch Method Analytical QC Batch Analytical Method Batch 35451847001 SCS-MW-1 EPA 3010 521178 EPA 6010 521271 35451847001 SCS-MW-1 EPA 300.0 520750 35451847001 SCS-MW-1 EPA 350.1 520730 Date: 03/08/2019 12:39 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 13 eA»alyfic2) CHAIN-OF-CUSTOD)WO# : 35451847 The Chain -of -Custody is a LEGA 111111111 Section A Section B Section C 111111111 I I II IIIIII III Required Client Information: Required Project Information: Invoice Inforrna 35451 age : 1 Of 1 Company EE&G Environmental Services, LLC Report To. 1 Attention +847 Address n �rC�0.� �� 5751 Miami Lakes Dr Copy To �f"0.! . Gl wide.--,e r- Company Name Hialeah, FL 33014 ) �J Address Email Purchase Order #. Pace Quote Regulatory Agency Phone' (305)374-8300 iI ax cJ Project Name _,k.:2,2.'�kl. G-Ok " (;,;,L rye Pace Project Manager christina.raschke@pacelabs.com, / State / Location t • Requested Due Date-�;Y,,.,—!�, I Project #: 2018-305/ Pace Profile 8 FL Requ tAal Fil ored (YIN) Z_ a) MATRIX cone COLLECTED Preservatives ,., `3 Orinking Water OW 711 Worm Wr Walt! WOO WW `lam 2 SAMPLE ID Sias htl Sl oL START END o :.a - One Character per box. WIar Wn C) o (A-Z, O.91 , -) Other OAir T NW J O # Sample Ids must be unique •X P 9 na.vr 75 m c m _ x UJ 0 .c o_ ~ DATE TIME DATE TIME ,/ f = Z l' Oa CC 2 3 4 5 6 7 8 9 10 11 12 ADDITIONAL COMMENTS LINQUIHED B IAFFIUATI N DATE - TIME.". ,ACCEPTED BY IAFFIL.IATION' DATE TIME SAMPLECONDITIONS •5c, \l '/ SAMPLER NAME AND SIGNATURE' ` e I PRINT Name of SAMPLER: vi 1 / , ` ��� � c. v' '— - \ I' ''�'' /� r t a. m SIGNATURE of SAMPLER: ._ ( I '� DATE Signed: ,� I �. W E z �.�F,r�I I��li. / �?> roc • e sec May 30 20:8 Nice Ar ralylical WO#:3j45 847 Project # PM: CTR Project Manager: Client: Thermometer Used State of Cooler #1 Temp.'C CLIENT: 36-EEG igO P ( =,C% �lj(Visual) (Correction Factor) 3. s (Actual) 0 0 (Correction Factor) (0. 0 (Actual) 0 .0 (Correction Factor) (Actual) Date Cooler #2 Temp!C In—( 1 (Visual) Cooler #3 Temp.`C 5,5 (Visual) Cooler #4 Temp.'C Cooler #5 Temp.`C (Visual) Cooler #6 Temp.`C (Visual) Courier: Shipping Method: Billing: Tracking # (Visual) (Correction Factor) (Correction Factor) (Correction Factor) Fed Ex — UPS USPS - Client First Overnight _ Priority Overnight = Other Recipient Custody Seal on Cooler/Box Present: Packing Material: —Bubble Wrap Samples shorted to lab (If Yes, complete) - Sender (Actual) (Actual) (Actual) Commerc!al% Pace - Standard Overnight - Ground = Third Party = Credit Card ubble Bags LNone Shorted Date. Seals intact: Yes tv/-14:=7— Comments: Due Date: 03/12/19 Issuino Authority Pace Florida Quality Office CUR Time Per .. Joects all containers \e. `led io Date and Initials of p Examining content: (1 Label: Deliver San oies 0 ccoinC process ^as neguri Sarrc c_ or _ cooliric process -a5 tegur Tom; Santo-_ on ice _ process 'as oe._ur. I Sari or coc _ process!' as :e^yun Samples oc ice coo: - c process cess -as teoun Ser o es rocess `as regun 7 Other International Priority = Unknown Shorted TimeOty Chain of Custody Present es = No 'N/A ....24. Chain of Custody Filled Out s = No =N/A Relinquished Signature & Sampler Name COC _ e= No =N/A �s Samples Arrived within Hold Time vYes = No =N/A Rush TAT requested on COC -Yes `_ o _N/A Sufficient Volume _t3s = No =N/A Correct Containers Used es = No =N/A Containers Intact es = No =N/A Sample Labels match COC (sample IDs & date time of collection) — es = No -N/A Alf containers needino acid/base preservation have teen checked YL� = No =N/A o All Containers nee•rc preservation are founc to be ir. ••� � compliance wan EPA -ecornmencation = = No -N/A Exceptions VGA Coliform, TOC, O&G, Cat, a/mates Presevation Information Preservative Lot #r7race r mate 0diaa Headspace in VOA Vials" (>6mm) =Yes = No ' Trip Blank Present = Yes _ No ; Client Notification/ Resolution: Person Contacted Comments/ Resolution (use back for additional comments): Date!Time Project Manager Review Date Page 13 of 13 www.pacelabs.com March 12, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057Melreese Golf Course Pace Project No.: 35451864 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 05, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Some analyses have been subcontracted outside of the Pace Network. The subcontracted laboratory report has been attached. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry, EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 39 aceAnalytical www.pacelabs.com CERTIFICATIONS Project: 2018-3057Melreese Golf Course Pace Project No.: 35451864 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 39 wwwpacelabs.com SAMPLE SUMMARY Project: 2018-3057Melreese Golf Course Pace Project No.: 35451864 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35451864001 SCS-MW-1 Water 03/04/19 12:14 03/05/19 17:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 39 /162ceAnalytical® www.pacelabs.com SAMPLE ANALYTE COUNT Project: 2018-3057Melreese Golf Course Pace Project No.: 35451864 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35451864001 SCS-MW-1 EPA 8081 AER 22 PASI-O FL -PRO BP2 3 PASI-O EPA6010 SC1 4 PASI-O EPA 7470 AMS 1 PASI-O EPA 8270 by SIM CB1 20 PASI-O EPA 8260 BTN 69 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 39 aceAnalytical www.pacelabs.com SUMMARY OF DETECTION Project: 2018-3057Melreese Golf Course Pace Project No.: 35451864 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters 35451864001 EPA 8081 Result SCS-MW-1 Dieldrin Units Report Limit Analyzed Qualifiers 0.0032 I ug/L 0.0097 03/09/19 05:15 1p REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 39 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057Melreese Golf Course Pace Project No. 35451864 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SCS-MW-1 Lab ID: 35451864001 Collected: 03/04/19 12:14 Received: 03/05/19 17:45 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8081 GCS Pesticides Analytical Method: EPA8081 Preparation Method: EPA3510 Aldrin 0.0015 U ug/L 0.0097 0.0015 1 03/06/19 16:26 03/09/19 05:15 309-00-2 1p alpha-BHC 0.0020 U ug/L 0.0097 0.0020 1 03/06/19 16:26 03/09/19 05:15 319-84-6 1p beta-BHC 0.0077 U ug/L 0.0097 0.0077 1 03/06/19 16:26 03/09/19 05:15 319-85-7 1p delta-BHC 0.0046 U ug/L 0.0097 0.0046 1 03/06/19 16:26 03/09/19 05:15 319-86-8 1p gamma-BHC (Lindane) 0.0021 U ug/L 0.0097 0.0021 1 03/06/19 16:26 03/09/19 05:15 58-89-9 1p Chlordane (Technical) 0.17 U ug/L 0.48 0.17 1 03/06/19 16:26 03/09/19 05:15 57-74-9 1p 4,4'-DDD 0.0086 U ug/L 0.0097 0.0086 1 03/06/19 16:26 03/09/19 05:15 72-54-8 1p 4,4'-DDE 0.0048 U ug/L 0.0097 0.0048 1 03/06/19 16:26 03/09/19 05:15 72-55-9 1p 4,4'-DDT 0.0048 U ug/L 0.0097 0.0048 1 03/06/19 16:26 03/09/19 05:15 50-29-3 1p Dieldrin 0.0032 I ug/L 0.0097 0.0019 1 03/06/19 16:26 03/09/19 05:15 60-57-1 1p Endosulfan I 0.0049 U ug/L 0.0097 0.0049 1 03/06/19 16:26 03/09/19 05:15 959-98-8 1p Endosulfan II 0.0039 U ug/L 0.0097 0.0039 1 03/06/19 16:26 03/09/19 05:15 33213-65-9 1p Endosulfan sulfate 0.0060 U ug/L 0.097 0.0060 1 03/06/19 16:26 03/09/19 05:15 1031-07-8 1p Endrin 0.0042 U ug/L 0.0097 0.0042 1 03/06/19 16:26 03/09/19 05:15 72-20-8 1p Endrin aldehyde 0.0035 U ug/L 0.097 0.0035 1 03/06/19 16:26 03/09/19 05:15 7421-93-4 1p Endrin ketone 0.0048 U ug/L 0.0097 0.0048 1 03/06/19 16:26 03/09/19 05:15 53494-70-5 1p Heptachlor 0.0060 U ug/L 0.0097 0.0060 1 03/06/19 16:26 03/09/19 05:15 76-44-8 1p Heptachlor epoxide 0.0050 U ug/L 0.0097 0.0050 1 03/06/19 16:26 03/09/19 05:15 1024-57-3 1p Methoxychlor 0.0093 U ug/L 0.0097 0.0093 1 03/06/19 16:26 03/09/19 05:15 72-43-5 1p Toxaphene 0.24 U ug/L 0.48 0.24 1 03/06/19 16:26 03/09/19 05:15 8001-35-2 1p Surrogates Tetrachloro-m-xylene (S) 72 % 27-124 1 03/06/19 16:26 03/09/19 05:15 877-09-8 Decachlorobiphenyl (S) 50 % 10-132 1 03/06/19 16:26 03/09/19 05:15 2051-24-3 FL -PRO Water, Low Volume Analytical Method: FL -PRO Preparation Method: EPA 3510 Petroleum Range Organics 0.77 U mg/L 0.96 0.77 1 03/07/19 09:10 03/08/19 08:57 Surrogates o-Terphenyl (S) 85 % 66-139 1 03/07/19 09:10 03/08/19 08:57 84-15-1 N-Pentatriacontane (S) 87 % 42-159 1 03/07/19 09:10 03/08/19 08:57 630-07-09 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3010 Cadmium 0.33 U ug/L 1.0 0.33 1 03/07/19 10:29 03/07/19 21:29 7440-43-9 Chromium 1.7 U ug/L 5.0 1.7 1 03/07/19 10:29 03/07/19 21:29 7440-47-3 Selenium 8.5 U ug/L 15.0 8.5 1 03/07/19 '10:29 03/07/19 21:29 7782-49-2 Silver 1.0 U ug/L 5.0 1.0 1 03/07/19 10:29 03/07/19 21:29 7440-22-4 7470 Mercury Analytical Method: EPA7470 Preparation Method: EPA7470 Mercury 0.10 U ug/L 0.20 0.10 1 03/07/19 10:25 03/08/19 16:20 7439-97-6 8270 MSSV PAHLV by SIM Analytical Method: EPA8270 by SIM Preparation Method: EPA3510 Acenaphthene 0.040 U ug/L 0.50 0.040 1 03/07/19 02:41 03/07/19 13:24 83-32-9 Acenaphthylene 0.030 U ug/L 0.50 0.030 1 03/07/19 02:41 03/07/19 13:24 208-96-8 Anthracene 0.043 U ug/L 0.50 0.043 1 03/07/19 02:41 03/07/19 13:24 120-12-7 Benzo(a)anthracene 0.055 U ug/L 0.10 0.055 1 03/07/19 02:41 03/07/19 13:24 56-55-3 Benzo(a)pyrene 0.12 U ug/L 0.20 0.12 1 03/07/19 02:41 03/07/19 13:24 50-32-8 Benzo(b)fluoranthene 0.027 U ug/L 0.10 0.027 1 03/07/19 02:41 03/07/19 13:24 205-99-2 Date: 03/12/2019 09:12 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 39 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057Melreese Golf Course Pace Project No.: 35451864 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SCS-MW-1 Lab ID: 35451864001 Collected: 03/04/19 12:14 Received: 03/05/19 17:45 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8270 MSSV PAHLV by SIM Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3510 Benzo(g,h,i)perylene 0.15 U ug/L 0.50 0.15 1 03/07/19 02:41 03/07/19 13:24 191-24-2 Benzo(k)fluoranthene 0.16 U ug/L 0.50 0.16 1 03/07/19 02:41 03/07/19 13:24 207-08-9 Chrysene 0.026 U ug/L 0.50 0.026 1 03/07/19 02:41 03/07/19 13:24 218-01-9 Dibenz(a,h)anthracene 0.13 U ug/L 0.15 0.13 1 03/07/19 02:41 03/07/19 13:24 53-70-3 Fluoranthene 0.018 U ug/L 0.50 0.018 1 03/07/19 02:41 03/07/19 13:24 206-44-0 Fluorene 0.088 U ug/L 0.50 0.088 1 03/07/19 02:41 03/07/19 13:24 86-73-7 Indeno(1,2,3-cd)pyrene 0.12 U ug/L 0.15 0.12 1 03/07/19 02:41 03/07/19 13:24 193-39-5 1-Methylnaphthalene 0.19 U ug/L 2.0 0.19 1 03/07/19 02:41 03/07/19 13:24 90-12-0 2-Methylnaphthalene 0.68 U ug/L 2.0 0.68 1 03/07/19 02:41 03/07/19 13:24 91-57-6 Naphthalene 0.29 U ug/L 2.0 0.29 1 03/07/19 02:41 03/07/19 13:24 91-20-3 Phenanthrene 0.16 U ug/L 0.50 0.16 1 03/07/19 02:41 03/07/19 13:24 85-01-8 Pyrene 0.032 U ug/L 0.50 0.032 1 03/07/19 02:41 03/07/19 13:24 129-00-0 Surrogates 2-Fluorobiphenyl (S) 70 % 33-82 1 03/07/19 02:41 03/07/19 13:24 321-60-8 p-Terphenyl-d14 (S) 105 % 49-104 1 03/07/19 02:41 03/07/19 13:24 1718-51-0 S3 8260 MSV Analytical Method: EPA 8260 1,1,1,2-Tetrachloroethane 0.32 U ug/L 1.0 0.32 1 03/06/19 16:51 630-20-6 ,1,1-Trichloroethane 0.30 U ug/L 1.0 0.30 1 03/06/19 16:51 71-55-6 1,1,2,2-Tetrachloroethane 0.20 U ug/L 0.50 0.20 1 03/06/19 16:51 79-34-5 1,1,2-Trichloroethane 0.30 U ug/L 1.0 0.30 1 03/06/19 16:51 79-00-5 1,1-Dichloroethane 0.34 U ug/L 1.0 0.34 1 03/06/19 16:51 75-34-3 1,1-Dichloroethene 0.27 U ug/L 1.0 0.27 1 03/06/19 16:51 75-35-4 1,1-Dichloropropene 0.31 U ug/L 1.0 0.31 1 03/06/19 16:51 563-58-6 1,2.3-Trichlorobenzene 0.34 U ug/L 1.0 0.34 1 03/06/19 16:51 87-61-6 1,2,3-Trichloropropane 1.1 U ug/L 2.0 1.1 1 03/06/19 16:51 96-18-4 1,2,3-Trimethylbenzene 0.17 U ug/L 1.0 0.17 1 03/06/19 16:51 526-73-8 1,2,4-Trichlorobenzene 0.32 U ug/L 1.0 0.32 1 03/06/19 16:51 120-82-1 1,2,4-Trimethylbenzene 0.24 U ug/L 1.0 0.24 1 03/06/19 16:51 95-63-6 1,2-Dichlorobenzene 0.29 U ug/L 1.0 0.29 1 03/06/19 16:51 95-50-1 1,2-Dichloroethane 0.27 U ug/L 1.0 0.27 1 03/06/19 16:51 107-06-2 1.2-Dichloropropane 0.23 U ug/L 1.0 0.23 1 03/06/19 16:51 78-87-5 1,3,5-Trimethylbenzene 0.24 U ug/L 1.0 0.24 1 03/06/19 16:51 108-67-8 1,3-Dichlorobenzene 0.33 U ug/L 1.0 0.33 1 03/06/19 16:51 541-73-1 1,3-Dichloropropane 0.26 U ug/L 1.0 0.26 1 03/06/19 16:51 142-28-9 1,4-Dichlorobenzene 0.28 U ug/L 1.0 0.28 1 03/06/19 16:51 106-46-7 2,2-Dichloropropane 0.59 U ug/L 1.0 0.59 1 03/06/19 16:51 594-20-7 2-Butanone (MEK) 7.5 U ug/L 10.0 7.5 1 03/06/19 16:51 78-93-3 2-Chloroethylvinyl ether 1.4 U ug/L 40.0 1.4 1 03/06/19 16:51 110-75-8 c2 2-Chlorotoluene 0.28 U ug/L 1.0 0.28 1 03/06/19 16:51 95-49-8 2-Hexanone 0.85 U ug/L 10.0 0.85 1 03/06/19 16:51 591-78-6 4-Chlorotoluene 0.22 U ug/L 1.0 0.22 1 03/06/19 16:51 106-43-4 4-Methyl-2-pentanone (MIBK) 0.32 U ug/L 10.0 0.32 1 03/06/19 16:51 108-10-1 Acetone 5.3 U ug/L 20.0 5.3 1 03/06/19 16:51 67-64-1 Benzene 0.30 U ug/L 1.0 0.30 1 03/06/19 16:51 71-43-2 Bromobenzene 0.21 U ug/L 1.0 0.21 1 03/06/19 16:51 108-86-1 Date: 03/12/2019 09:12 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 39 ceAnalytical® www. pacelabs. com ANALYTICAL RESULTS Project: 2018-3057Melreese Golf Course Pace Project No.: 35451864 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SCS-MW-1 Parameters Lab ID: 35451864001 Collected: 03/04/19 12:14 Received: 03/05/19 17:45 Matrix: Water Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Dibromochloromethane Dibromomethane Dichlorodifluoromethane Ethylbenzene lodomethane Isopropylbenzene (Cumene) Methyl-tert-butyl ether Methylene Chloride Styrene Tetrachloroethene Toluene Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene m&p-Xylene n-Butylbenzene n-Propylbenzene o-Xylene p-Isopropyltoluene sec-Butylbenzene tert-Butylbenzene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 03/12/2019 09:12 PM Analytical Method: EPA 8260 0.37 U ug/L 1.0 0.19 U ug/L 0.60 2.6 U ug/L 3.0 4.0 U ug/L 5.0 0.45 U ug/L 10.0 1.1 U ug/L 3.0 0.35 U ug/L 1.0 3.7 U ug/L 10.0 0.32 U ug/L 1.0 0.97 U ug/L 1.0 0.45 U ug/L 2.0 0.68 U ug/L 2.0 0.26 U ug/L 1.0 0.30 U ug/L 1.0 9.3 U ug/L 10.0 0.30 U ug/L 1.0 0.51 U ug/L 2.0 2.0 U ug/L 5.0 0.26 U ug/L 1.0 0.38 U ug/L 1.0 0.33 U ug/L 1.0 0.36 U ug/L 1.0 0.35 U ug/L 1.0 0.19 U ug/L 10.0 0.39 U ug/L 1.0 2.1 U ug/L 5.0 0.27 U ug/L 1.0 0.17 U ug/L 0.50 2.1 U ug/L 4.0 0.20 U ug/L 1.0 0.37 U ug/L 1.0 0.27 U ug/L 1.0 0.31 U ug/L 5.0 0.17 U ug/L 1.0 0.26 U ug/L 1.0 0.23 U ug/L 1.0 0.17 U ug/L 0.50 87 106 100 ova ova 70-130 70-130 70-130 0.37 0.19 2.6 4.0 0.45 1.1 0.35 3.7 0.32 0.97 0.45 0.68 0.26 0.30 9.3 0.30 0.51 2.0 0.26 0.38 0.33 0.36 0.35 0.19 0.39 2.1 0.27 0.17 2.1 0.20 0.37 0.27 0.31 0.17 0.26 0.23 0.17 REPORT OF LABORATORY ANALYSIS 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 03/06/19 16:51 74-97-5 75-27-4 75-25-2 74-83-9 v2 75-15-0 v1 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3 v2 124-48-1 74-95-3 75-71-8 100-41-4 74-88-4 v2 98-82-8 1634-04-4 75-09-2 100-42-5 127-18-4 108-88-3 79-01-6 75-69-4 108-05-4 75-01-4 1330-20-7 156-59-2 10061-01-5 179601-23-1 104-51-8 103-65-1 95-47-6 99-87-6 135-98-8 98-06-6 156-60-5 10061-02-6 03/06/19 16:51 460-00-4 03/06/19 16:51 17060-07-0 03/06/19 16:51 2037-26-5 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 39 71eAnaIyticaI www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057Melreese Golf Course Pace Project No.: 35451864 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521100 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 35451864001 METHOD BLANK: 2814165 Matrix: Water Associated Lab Samples: 35451864001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L 0.10 U 0.20 0.10 03/08/19 15:31 LABORATORY CONTROL SAMPLE: 2814166 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2 1.9 96 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2814167 2814168 MS MSD 35451633001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual lercury ug/L 0.10 U 2 2 1.7 1.8 86 88 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:12 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 39 ceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057Melreese Golf Course Pace Project No.: 35451864 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521178 Analysis Method: EPA 6010 QC Batch Method: EPA 3010 Analysis Description: 6010 MET Associated Lab Samples: 35451864001 METHOD BLANK: 2814528 Matrix: Water Associated Lab Samples: 35451864001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Cadmium ug/L 0.33 U 1.0 0.33 03/07/19 20:40 Chromium ug/L 1.7 U 5.0 1.7 03/07/19 20:40 Selenium ug/L 8.5 U 15.0 8.5 03/07/19 20:40 Silver ug/L 1.0 U 5.0 1.0 03/07/19 20:40 LABORATORY CONTROL SAMPLE: 2814529 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Cadmium ug/L 25 25.7 103 80-120 Chromium ug/L 250 255 102 80-120 Selenium ug/L 250 261 104 80-120 Silver ug/L 25 24.1 96 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2814530 2814531 MS MSD 35451859001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Cadmium ug/L 0.33 U 25 25 26.0 25.4 104 101 75-125 2 20 Chromium ug/L 1.7 U 250 250 262 252 105 101 75-125 4 20 Selenium ug/L 8.5 U 250 250 266 253 106 101 75-125 5 20 Silver ug/L 1.0 U 25 25 24.5 23.7 98 95 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/12/2019 09:12 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 39 tPaceAnalytical www.pacelabscom QUALITY CONTROL DATA Project: 2018-3057Melreese Golf Course Pace Project No.: 35451864 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 520786 Analysis Method: EPA 8260 QC Batch Method: EPA 8260 Analysis Description: 8260 MSV Associated Lab Samples: 35451864001 METHOD BLANK: 2812236 Matrix: Water Associated Lab Samples: 35451864001 Parameter Blank Reporting Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L 0.32 U 1.0 0.32 03/06/19 09:44 1,1,1-Trichloroethane ug/L 0.30 U 1.0 0.30 03/06/19 09:44 1,1,2,2-Tetrachloroethane ug/L 0.20 U 0.50 0.20 03/06/19 09:44 1,1,2-Trichloroethane ug/L 0.30 U 1.0 0.30 03/06/19 09:44 1,1-Dichloroethane ug/L 0.34 U 1.0 0.34 03/06/19 09:44 1,1-Dichloroethene ug/L 0.27 U 1.0 0.27 03/06/19 09:44 1,1-Dichloropropene ug/L 0.31 U 1.0 0.31 03/06/19 09:44 1,2,3-Trichlorobenzene ug/L 0.34 U 1.0 0.34 03/06/19 09:44 1,2,3-Trichloropropane ug/L 1.1 U 2.0 1.1 03/06/19 09:44 1,2,3-Trimethylbenzene ug/L 0.17 U 1.0 0.17 03/06/19 09:44 1,2,4-Trichlorobenzene ug/L 0.32 U 1.0 0.32 03/06/19 09:44 1,2,4-Trimethylbenzene ug/L 0.24 U 1.0 0.24 03/06/19 09:44 1,2-Dichlorobenzene ug/L 0.29 U 1.0 0.29 03/06/19 09:44 1,2-Dichloroethane ug/L 0.27 U 1.0 0.27 03/06/19 09:44 ',2-Dichloropropane ug/L 0.23 U 1.0 0.23 03/06/19 09:44 l,3,5-Trimethylbenzene ug/L 0.24 U 1.0 0.24 03/06/19 09:44 1,3-Dichlorobenzene ug/L 0.33 U 1.0 0.33 03/06/19 09:44 1,3-Dichloropropane ug/L 0.26 U 1.0 0.26 03/06/19 09:44 1,4-Dichlorobenzene ug/L 0.28 U 1.0 0.28 03/06/19 09:44 2,2-Dichloropropane ug/L 0.59 U 1.0 0.59 03/06/19 09:44 2-Butanone (MEK) ug/L 7.5 U 10.0 7.5 03/06/19 09:44 2-Chloroethylvinyl ether ug/L 1.4 U 40.0 1.4 03/06/19 09:44 2-Chlorotoluene ug/L 0.28 U 1.0 0.28 03/06/19 09:44 2-Hexanone ug/L 0.85 U 10.0 0.85 03/06/19 09:44 4-Chlorotoluene ug/L 0.22 U 1.0 0.22 03/06/19 09:44 4-Methyl-2-pentanone (MIBK) ug/L 0.32 U 10.0 0.32 03/06/19 09:44 Acetone ug/L 5.3 U 20.0 5.3 03/06/19 09:44 Benzene ug/L 0.30 U 1.0 0.30 03/06/19 09:44 Bromobenzene ug/L 0.21 U 1.0 0.21 03/06/19 09:44 Bromochloromethane ug/L 0.37 U 1.0 0.37 03/06/19 09:44 Bromodichloromethane ug/L 0.19 U 0.60 0.19 03/06/19 09:44 Bromoform ug/L 2.6 U 3.0 2.6 03/06/19 09:44 Bromomethane ug/L 4.0 U 5.0 4.0 03/06/19 09:44 Carbon disulfide ug/L 0.45 U 10.0 0.45 03/06/19 09:44 Carbon tetrachloride ug/L 1.1 U 3.0 1.1 03/06/19 09:44 Chlorobenzene ug/L 0.35 U 1.0 0.35 03/06/19 09:44 Chloroethane ug/L 3.7 U 10.0 3.7 03/06/19 09:44 Chloroform ug/L 0.32 U 1.0 0.32 03/06/19 09:44 Chloromethane ug/L 0.97 U 1.0 0.97 03/06/19 09:44 cis-1,2-Dichloroethene ug/L 0.27 U 1.0 0.27 03/06/19 09:44 cis-1,3-Dichloropropene ug/L 0.17 U 0.50 0.17 03/06/19 09:44 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:12 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 39 .2ceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057Melreese Golf Course Pace Project No.: 35451864 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 METHOD BLANK: 2812236 Matrix: Water Associated Lab Samples: 35451864001 Parameter Blank Reporting Units Result Limit MDL Analyzed Qualifiers Dibromochloromethane ug/L 0.45 U 2.0 0.45 03/06/19 09:44 Dibromomethane ug/L 0.68 U 2.0 0.68 03/06/19 09:44 Dichlorodifluoromethane ug/L 0.26 U 1.0 0.26 03/06/19 09:44 Ethylbenzene ug/L 0.30 U 1.0 0.30 03/06/19 09:44 lodomethane ug/L 9.3 U 10.0 9.3 03/06/19 09:44 Isopropylbenzene (Cumene) ug/L 0.30 U 1.0 0.30 03/06/19 09:44 m&p-Xylene ug/L 2.1 U 4.0 2.1 03/06/19 09:44 Methyl-tert-butyl ether ug/L 0.51 U 2.0 0.51 03/06/19 09:44 Methylene Chloride ug/L 2.0 U 5.0 2.0 03/06/19 09:44 n-Butylbenzene ug/L 0.20 U 1.0 0.20 03/06/19 09:44 n-Propylbenzene ug/L 0.37 U 1.0 0.37 03/06/19 09:44 o-Xylene ug/L 0.27 U 1.0 0.27 03/06/19 09:44 p-lsopropyltoluene ug/L 0.31 U 5.0 0.31 03/06/19 09:44 sec-Butylbenzene ug/L 0.17 U 1.0 0.17 03/06/19 09:44 Styrene ug/L 0.26 U 1.0 0.26 03/06/19 09:44 tert-Butylbenzene ug/L 0.26 U 1.0 0.26 03/06/19 09:44 Tetrachloroethene ug/L 0.38 U 1.0 0.38 03/06/19 09:44 Toluene ug/L 0.33 U 1.0 0.33 03/06/19 09:44 trans-1,2-Dichloroethene ug/L 0.23 U 1.0 0.23 03/06/19 09:44 trans-1,3-Dichloropropene ug/L 0.17 U 0.50 0.17 03/06/19 09:44 Trichloroethene ug/L 0.36 U 1.0 0.36 03/06/19 09:44 Trichlorofluoromethane ug/L 0.35 U 1.0 0.35 03/06/19 09:44 Vinyl acetate ug/L 0.19 U 10.0 0.19 03/06/19 09:44 Vinyl chloride ug/L 0.39 U 1.0 0.39 03/06/19 09:44 Xylene (Total) ug/L 2.1 U 5.0 2.1 03/06/19 09:44 1,2-Dichloroethane-d4 (S) % 103 70-130 03/06/19 09:44 4-Bromofluorobenzene (S) % 94 70-130 03/06/19 09:44 Toluene-d8 (S) % 101 70-130 03/06/19 09:44 LABORATORY CONTROL SAMPLE: 2812237 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 20 20.1 101 70-130 1,1,1-Trichloroethane ug/L 20 18.8 94 70-130 1,1,2,2-Tetrachloroethane ug/L 20 21.3 107 68-125 1,1,2-Trichloroethane ug/L 20 20.1 101 70-130 1,1-Dichloroethane ug/L 20 20.2 101 70-130 1,1-Dichloroethene ug/L 20 18.9 94 66-133 1,1-Dichloropropene ug/L 20 20.3 101 70-130 1,2,3-Trichlorobenzene ug/L 20 21.4 107 64-126 1,2,3-Trichloropropane ug/L 20 21.7 108 62-127 1,2,3-Trimethylbenzene ug/L 20 23.0 115 70-130 1,2,4-Trichlorobenzene ug/L 20 19.4 97 63-124 1,2,4-Trimethylbenzene ug/L 20 20.5 102 70-130 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:12 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 39 71eAnaIyticaI wwwpacelabs.com QUALITY CONTROL DATA Project: 2018-3057Melreese Golf Course Pace Project No.: 35451864 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE: 2812237 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,2-Dichlorobenzene ug/L 20 19.5 97 70-130 1,2-Dichloroethane ug/L 20 17.7 88 70-130 1,2-Dichloropropane ug/L 20 19.3 97 70-130 1,3,5-Trimethylbenzene ug/L 20 20.2 101 70-130 1,3-Dichlorobenzene ug/L 20 19.5 98 70-130 1,3-Dichloropropane ug/L 20 20.2 101 70-130 1,4-Dichlorobenzene ug/L 20 19.4 97 70-130 2,2-Dichloropropane ug/L 20 20.2 101 59-133 2-Butanone (MEK) ug/L 40 44.2 111 47-143 2-Chloroethylvinyl ether ug/L 20 20.2 I 101 41-140 2-Chlorotoluene ug/L 20 20.1 101 70-130 2-Hexanone ug/L 40 46.8 117 48-145 4-Chlorotoluene ug/L 20 20.1 101 70-130 4-Methyl-2-pentanone (MIBK) ug/L 40 48.9 122 57-132 Acetone ug/L 40 48.2 120 46-148 Benzene ug/L 20 19.7 99 70-130 Bromobenzene ug/L 20 20.1 100 70-130 Bromochloromethane ug/L 20 19.0 95 70-130 Bromodichloromethane ug/L 20 18.4 92 70-130 Bromoform ug/L 20 17.3 87 49-126 ;romomethane ug/L 20 9.7 48 10-165 v2 Carbon disulfide ug/L 20 26.3 131 60-141 v1 Carbon tetrachloride ug/L 20 20.8 104 63-126 Chlorobenzene ug/L 20 19.2 96 70-130 Chloroethane ug/L 20 22.2 111 71-142 Chloroform ug/L 20 19.2 96 70-130 Chloromethane ug/L 20 16.2 81 40-140 v2 cis-1,2-Dichloroethene ug/L 20 19.3 96 70-130 cis-1,3-Dichloropropene ug/L 20 16.3 82 70-130 Dibromochloromethane ug/L 20 15.4 77 62-118 Dibromomethane ug/L 20 18.3 92 70-130 Dichlorodifluoromethane ug/L 20 20.2 101 47-150 Ethylbenzene ug/L 20 20.0 100 70-130 lodomethane ug/L 40 21.7 54 10-164 v2 Isopropylbenzene (Cumene) ug/L 20 19.6 98 70-130 m&p-Xylene ug/L 40 40.4 101 70-130 Methyl-tert-butyl ether ug/L 20 22.3 112 64-124 Methylene Chloride ug/L 20 18.2 91 65-136 n-Butylbenzene ug/L 20 20.5 102 70-130 n-Propylbenzene ug/L 20 21.2 106 70-130 o-Xylene ug/L 20 19.1 96 70-130 p-Isopropyltoluene ug/L 20 17.4 87 70-130 sec-Butylbenzene ug/L 20 20.6 103 70-130 Styrene ug/L 20 18.0 90 70-130 tert-Butylbenzene ug/L 20 20.7 103 70-130 Tetrachloroethene ug/L 20 19.7 98 64-134 Toluene ug/L 20 20.4 102 70-130 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:12 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 39 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057Melreese Golf Course Pace Project No.: 35451864 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE: 2812237 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers trans-1,2-Dichloroethene ug/L 20 19.7 98 68-127 trans-1,3-Dichloropropene ug/L 20 16.0 80 65-121 Trichloroethene ug/L 20 19.2 96 70-130 Trichlorofluoromethane ug/L 20 22.0 110 65-135 Vinyl acetate ug/L 20 24.4 122 60-144 Vinyl chloride ug/L 20 19.1 95 68-131 Xylene (Total) ug/L 60 59.5 99 70-130 1,2-Dichloroethane-d4 (S) % 101 70-130 4-Bromofluorobenzene (S) % 95 70-130 Toluene-d8 (S) % 99 70-130 MATRIX SPIKE SAMPLE: 2812239 Parameter 35451633002 Spike MS MS % Rec Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 0.32 U 20 13.3 67 70-130 J(M1) 1,1,1-Trichloroethane ug/L 0.30 U 20 14.4 72 70-130 1,1,2,2-Tetrachloroethane ug/L 0.20 U 20 14.9 74 68-125 1,1,2-Trichloroethane ug/L 0.30 U 20 13.9 70 70-130 1,1-Dichloroethane ug/L 0.34 U 20 15.4 77 70-130 1,1-Dichloroethene ug/L 0.27 U 20 16.8 84 66-133 1,1-Dichloropropene ug/L 0.31 U 20 14.3 71 70-130 1,2,3-Trichlorobenzene ug/L 0.34 U 20 11.7 59 64-126 J(M1) 1,2,3-Trichloropropane ug/L 1.1 U 20 13.5 68 62-127 1,2,3-Trimethylbenzene ug/L 0.17 U 20 16.3 82 70-130 1,2,4-Trichlorobenzene ug/L 0.32 U 20 10.7 54 63-124 J(M1) 1,2,4-Trimethylbenzene ug/L 0.24 U 20 12.8 64 70-130 J(M1) 1,2-Dichlorobenzene ug/L 0.29 U 20 12.7 64 70-130 J(M1) 1,2-Dichloroethane ug/L 0.27 U 20 13.1 66 70-130 J(M1) 1,2-Dichloropropane ug/L 0.23 U 20 13.9 70 70-130 1,3,5-Trimethylbenzene ug/L 0.24 U 20 13.1 65 70-130 J(M1) 1,3-Dichlorobenzene ug/L 0.33 U 20 12.9 64 70-130 J(M1) 1,3-Dichloropropane ug/L 0.26 U 20 13.4 67 70-130 J(M1) 1,4-Dichlorobenzene ug/L 0.28 U 20 13.0 65 70-130 J(M1) 2,2-Dichloropropane ug/L 0.59 U 20 12.5 62 59-133 2-Butanone (MEK) ug/L 7.5 U 40 30.1 75 47-143 2-Chloroethylvinyl ether ug/L 1.4 U 20 1.4 U 0 41-140 J(M1) 2-Chlorotoluene ug/L 0.28 U 20 13.2 66 70-130 J(M1) 2-Hexanone ug/L 0.85 U 40 28.5 71 48-145 4-Chlorotoluene ug/L 0.22 U 20 13.3 66 70-130 J(M1) 4-Methy1-2-pentanone (MIBK) ug/L 0.32 U 40 0.32 U 0 57-132 J(M1) Acetone ug/L 5.3 U 40 36.7 82 46-148 Benzene ug/L 0.30 U 20 14.2 71 70-130 Bromobenzene ug/L 0.21 U 20 14.0 70 70-130 Bromochloromethane ug/L 0.37 U 20 13.8 69 70-130 J(M1) Bromodichloromethane ug/L 0.19 U 20 13.4 67 70-130 J(M1) Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:12 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 39 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057Melreese Golf Course Pace Project No.: 35451864 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 MATRIX SPIKE SAMPLE: 2812239 Parameter 35451633002 Spike MS MS % Rec Units Result Conc. Result % Rec Limits Qualifiers Bromoform ug/L 2.6 U 20 11.8 59 49-126 Bromomethane ug/L 4.0 U 20 9.1 46 10-165 v2 Carbon disulfide ug/L 0.45 U 20 22.6 113 60-141 v1 Carbon tetrachloride ug/L 1.1 U 20 15.4 77 63-126 Chlorobenzene ug/L 0.35 U 20 13.5 67 70-130 J(M1) Chloroethane ug/L 3.7 U 20 20.6 103 71-142 Chloroform ug/L 0.32 U 20 14.3 71 70-130 Chloromethane ug/L 0.97 U 20 14.1 70 40-140 v2 cis-1,2-Dichloroethene ug/L 0.27 U 20 14.1 71 70-130 cis-1,3-Dichloropropene ug/L 0.17 U 20 10.3 52 70-130 J(M1) Dibromochloromethane ug/L 0.45 U 20 10.2 51 62-118 J(M1) Dibromomethane ug/L 0.68 U 20 12.4 62 70-130 J(M1) Dichlorodifluoromethane ug/L 0.26 U 20 18.0 90 47-150 Ethylbenzene ug/L 0.30 U 20 13.5 68 70-130 J(M1) lodomethane ug/L 9.3 U 40 9.3 U 21 10-164 v2 Isopropylbenzene (Cumene) ug/L 0.30 U 20 12.2 61 70-130 J(M1) m&p-Xylene ug/L 2.1 U 40 27.0 68 70-130 J(M1) Methyl-tert-butyl ether ug/L 0.51 U 20 14.7 74 64-124 Methylene Chloride ug/L 2.0 U 20 14.4 72 65-136 i-Butylbenzene ug/L 0.20 U 20 12.4 62 70-130 J(M1) -Propylbenzene ug/L 0.37 U 20 14.2 71 70-130 o-Xylene ug/L 0.27 U 20 11.7 59 70-130 J(M1) p-Isopropyltoluene ug/L 0.31 U 20 10.7 54 70-130 J(M1) sec-Butylbenzene ug/L 0.17 U 20 13.5 68 70-130 J(M1) Styrene ug/L 0.26 U 20 11.5 57 70-130 J(M1) tert-Butylbenzene ug/L 0.26 U 20 13.6 68 70-130 J(M1) Tetrachloroethene ug/L 0.38 U 20 12.8 64 64-134 Toluene ug/L 0.33 U 20 14.3 72 70-130 trans-1,2-Dichloroethene ug/L 0.23 U 20 14.8 74 68-127 trans-1,3-Dichloropropene ug/L 0.17 U 20 10.6 53 65-121 J(M1) Trichloroethene ug/L 0.36 U 20 13.4 67 70-130 J(M1) Trichlorofluoromethane ug/L 0.35 U 20 18.5 92 65-135 Vinyl acetate ug/L 0.19 U 20 15.3 76 60-144 Vinyl chloride ug/L 0.39 U 20 16.4 82 68-131 Xylene (Total) ug/L 2.1 U 60 38.8 65 70-130 MS 1,2-Dichloroethane-d4 (S) % 104 70-130 4-Bromofluorobenzene (S) % 90 70-130 Toluene-d8 (S) % 98 70-130 SAMPLE DUPLICATE: 2812238 35451633001 Dup Parameter Units Result Result RPD Max RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L 0.32 U 0.32 U 40 1,1,1-Trichloroethane ug/L 0.30 U 0.30 U 40 1,1,2,2-Tetrachloroethane ug/L 0.20 U 0.20 U 40 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:12 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 39 aceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057Melreese Golf Course Pace Project No.: 35451864 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 SAMPLE DUPLICATE: 2812238 Parameter 35451633001 Dup Max Units Result Result RPD RPD Qualifiers 1,1,2-Trichloroethane ug/L 0.30 U 0.30 U 40 1,1-Dichloroethane ug/L 0.34 U 0.34 U 40 1,1-Dichloroethene ug/L 0.27 U 0.27 U 40 1,1-Dichloropropene ug/L 0.31 U 0.31 U 40 1,2,3-Trichlorobenzene ug/L 0.34 U 0.34 U 40 1,2,3-Trichloropropane ug/L 1.1 U 1.1 U 40 1,2,3-Trimethylbenzene ug/L 0.17 U 0.17 U 40 1,2,4-Trichlorobenzene ug/L 0.32 U 0.32 U 40 1,2,4-Trimethylbenzene ug/L 0.24 U 0.24 U 40 1,2-Dichlorobenzene ug/L 0.29 U 0.29 U 40 1,2-Dichloroethane ug/L 0.27 U 0.27 U 40 1,2-Dichloropropane ug/L 0.23 U 0.23 U 40 1,3,5-Trimethylbenzene ug/L 0.24 U 0.24 U 40 1,3-Dichlorobenzene ug/L 0.33 U 0.33 U 40 1,3-Dichloropropane ug/L 0.26 U 0.26 U 40 1,4-Dichlorobenzene ug/L 0.28 U 0.28 U 40 2,2-Dichloropropane ug/L 0.59 U 0.59 U 40 2-Butanone (MEK) ug/L 7.5 U 7.5 U 40 2-Chloroethylvinyl ether ug/L 1.4 U 1.4 U 40 2-Chlorotoluene ug/L 0.28 U 0.28 U 40 2-Hexanone ug/L 0.85 U 0.85 U 40 4-Chlorotoluene ug/L 0.22 U 0.22 U 40 4-Methyl-2-pentanone (MIBK) ug/L 0.32 U 0.32 U 40 Acetone ug/L 5.3 U 5.3 U 40 Benzene ug/L 0.30 U 0.30 U 40 Bromobenzene ug/L 0.21 U 0.21 U 40 Bromochloromethane ug/L 0.37 U 0.37 U 40 Bromodichloromethane ug/L 0.19 U 0.19 U 40 Bromoform ug/L 2.6 U 2.6 U 40 Bromomethane ug/L 4.0 U 4.0 U 40 v2 Carbon disulfide ug/L 0.45 U 0.45 U 40 v1 Carbon tetrachloride ug/L 1.1 U 1.1 U 40 Chlorobenzene ug/L 0.35 U 0.35 U 40 Chloroethane ug/L 3.7 U 3.7 U 40 Chloroform ug/L 0.32 U 0.32 U 40 Chloromethane ug/L 0.97 U 0.97 U 40 v2 cis-1,2-Dichloroethene ug/L 0.27 U 0.27 U 40 cis-1,3-Dichloropropene ug/L 0.17 U 0.17 U 40 Dibromochloromethane ug/L 0.45 U 0.45 U 40 Dibromomethane ug/L 0.68 U 0.68 U 40 Dichlorodifluoromethane ug/L 0.26 U 0.26 U 40 Ethylbenzene ug/L 0.30 U 0.30 U 40 lodomethane ug/L 9.3 U 9.3 U 40 v2 Isopropylbenzene (Cumene) ug/L 0.30 U 0.30 U 40 m&p-Xylene ug/L 2.1 U 2.1 U 40 Methyl-tert-butyl ether ug/L 0.51 U 0.51 U 40 Methylene Chloride ug/L 2.0 U 2.0 U 40 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/12/2019 09:12 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 39 aceAnalytical wwwpacelabs.com QUALITY CONTROL DATA Project: 2018-3057Melreese Golf Course Pace Project No.: 35451864 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 SAMPLE DUPLICATE: 2812238 Parameter 35451633001 Dup Units Result Result RPD Max RPD Qualifiers n-Butylbenzene ug/L 0.20 U 0.20 U 40 n-Propylbenzene ug/L 0.37 U 0.37 U 40 o-Xylene ug/L 0.27 U 0.27 U 40 p-Isopropyltoluene ug/L 0.31 U 0.31 U 40 sec-Butylbenzene ug/L 0.17 U 0.17 U 40 Styrene ug/L 0.26 U 0.26 U 40 tert-Butylbenzene ug/L 0.26 U 0.26 U 40 Tetrachloroethene ug/L 0.38 U 0.38 U 40 Toluene ug/L 0.33 U 0.33 U 40 trans-1,2-Dichloroethene ug/L 0.23 U 0.23 U 40 trans-1,3-Dichloropropene ug/L 0.17 U 0.17 U 40 Trichloroethene ug/L 0.36 U 0.36 U 40 Trichlorofluoromethane ug/L 0.35 U 0.35 U 40 Vinyl acetate ug/L 0.19 U 0.19 U 40 Vinyl chloride ug/L 0.39 U 0.39 U 40 Xylene (Total) ug/L 2.1 U 2.1 U 40 1,2-Dichloroethane-d4 (S) % 103 104 0 40 4-Bromofluorobenzene (S) % 89 91 3 40 Y Toluene-d8 (S) % 100 100 0 40 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/12/2019 09:12 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 39 QUALITY CONTROL DATA Project: 2018-3057Melreese Golf Course Pace Project No.: 35451864 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 520947 Analysis Method: EPA 8081 QC Batch Method: EPA 3510 Analysis Description: 8081 GCS Pesticides Associated Lab Samples: 35451864001 METHOD BLANK: 2813016 Matrix: Water Associated Lab Samples: 35451864001 Parameter Blank Reporting Units Result Limit MDL Analyzed Qualifiers 4,4'-DDD ug/L 0.0089 U 0.010 0.0089 03/08/19 02:42 4,4'-DDE ug/L 0.0050 U 0.010 0.0050 03/08/19 02:42 4,4'-DDT ug/L 0.0050 U 0.010 0.0050 03/08/19 02:42 Aldrin ug/L 0.0015 U 0.010 0.0015 03/08/19 02:42 alpha-BHC ug/L 0.0021 U 0.010 0.0021 03/08/19 02:42 beta-BHC ug/L 0.0080 U 0.010 0.0080 03/08/19 02:42 Chlordane (Technical) ug/L 0.18 U 0.50 0.18 03/08/19 02:42 delta-BHC ug/L 0.0048 U 0.010 0.0048 03/08/19 02:42 Dieldrin ug/L 0.0020 U 0.010 0.0020 03/08/19 02:42 Endosulfan I ug/L 0.0051 U 0.010 0.0051 03/08/19 02:42 Endosulfan II ug/L 0.0040 U 0.010 0.0040 03/08/19 02:42 Endosulfan sulfate ug/L 0.0062 U 0.10 0.0062 03/08/19 02:42 Endrin ug/L 0.0043 U 0.010 0.0043 03/08/19 02:42 Endrin aldehyde ug/L 0.0036 U 0.10 0.0036 03/08/19 02:42 Endrin ketone ug/L 0.0050 U 0.010 0.0050 03/08/19 02:42 gamma-BHC (Lindane) ug/L 0.0022 U 0.010 0.0022 03/08/19 02:42 Heptachlor ug/L 0.0062 U 0.010 0.0062 03/08/19 02:42 Heptachlor epoxide ug/L 0.0052 U 0.010 0.0052 03/08/19 02:42 Methoxychlor ug/L 0.0096 U 0.010 0.0096 03/08/19 02:42 Toxaphene ug/L 0.25 U 0.50 0.25 03/08/19 02:42 Decachlorobiphenyl (S) % 48 10-132 03/08/19 02:42 Tetrachloro-m-xylene (S) % 67 27-124 03/08/19 02:42 LABORATORY CONTROL SAMPLE & LCSD: 2813017 2813251 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers 4,4'-DDD ug/L 0.5 0.50 0.52 99 103 67-133 4 40 4,4'-DDE ug/L 0.5 0.48 0.50 96 100 59-125 3 40 4,4'-DDT ug/L 0.5 0.51 0.52 102 104 54-132 2 40 Aldrin ug/L 0.5 0.43 0.44 87 88 25-116 2 40 alpha-BHC ug/L 0.5 0.51 0.54 102 109 53-126 6 40 beta-BHC ug/L 0.5 0.51 0.53 101 107 62-130 5 40 delta-BHC ug/L 0.5 0.47 0.52 95 104 35-122 10 40 Dieldrin ug/L 0.5 0.56 0.59 112 118 66-128 5 40 Endosulfan I ug/L 0.5 0.49 0.51 97 102 67-125 4 40 Endosulfan II ug/L 0.5 0.44 0.47 89 95 67-131 7 40 Endosulfan sulfate ug/L 0.5 0.44 0.48 88 96 62-127 9 40 Endrin ug/L 0.5 0.55 0.58 110 115 66-130 5 40 Endrin aldehyde ug/L 0.5 0.45 0.51 90 102 61-124 12 40 Endrin ketone ug/L 0.5 0.46 0.49 91 98 65-132 7 40 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/12/2019 09:12 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 39 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057Melreese Golf Course Pace Project No.: 35451864 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE & LCSD: 2813017 2813251 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers gamma-BHC (Lindane) ug/L 0.5 0.54 0.57 108 115 58-127 6 40 Heptachlor ug/L 0.5 0.45 0.48 90 95 35-123 5 40 Heptachlor epoxide ug/L 0.5 0.51 0.53 102 106 62-125 4 40 Methoxychlor ug/L 0.5 0.48 0.50 96 101 59-135 4 40 Decachlorobiphenyl (S) % 47 46 10-132 Tetrachloro-m-xylene (S) % 74 74 27-124 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/12/2019 09:12 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 39 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057Melreese Golf Course Pace Project No.: 35451864 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521006 Analysis Method: EPA 8270 by SIM QC Batch Method: EPA 3510 Analysis Description: 8270 Water PAHLV by SIM MSSV Associated Lab Samples: 35451864001 METHOD BLANK: 2813544 Matrix: Water Associated Lab Samples: 35451864001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1-Methylnaphthalene ug/L 0.19 U 2.0 0.19 03/07/19 08:37 2-Methylnaphthalene ug/L 0.68 U 2.0 0.68 03/07/19 08:37 Acenaphthene ug/L 0.040 U 0.50 0.040 03/07/19 08:37 Acenaphthylene ug/L 0.030 U 0.50 0.030 03/07/19 08:37 Anthracene ug/L 0.043 U 0.50 0.043 03/07/19 08:37 Benzo(a)anthracene ug/L 0.055 U 0.10 0.055 03/07/19 08:37 Benzo(a)pyrene ug/L 0.12 U 0.20 0.12 03/07/19 08:37 Benzo(b)fluoranthene ug/L 0.027 U 0.10 0.027 03/07/19 08:37 Benzo(g,h,i)perylene ug/L 0.15 U 0.50 0.15 03/07/19 08:37 Benzo(k)fluoranthene ug/L 0.16 U 0.50 0.16 03/07/19 08:37 Chrysene ug/L 0.026 U 0.50 0.026 03/07/19 08:37 Dibenz(a,h)anthracene ug/L 0.13 U 0.15 0.13 03/07/19 08:37 Fluoranthene ug/L 0.018 U 0.50 0.018 03/07/19 08:37 Fluorene ug/L 0.088 U 0.50 0.088 03/07/19 08:37 Indeno(1,2,3-cd)pyrene ug/L 0.12 U 0.15 0.12 03/07/19 08:37 Naphthalene ug/L 0.29 U 2.0 0.29 03/07/19 08:37 Phenanthrene ug/L 0.16 U 0.50 0.16 03/07/19 08:37 Pyrene ug/L 0.032 U 0.50 0.032 03/07/19 08:37 2-Fluorobiphenyl (S) % 63 33-82 03/07/19 08:37 p-Terphenyl-d14 (S) % 102 49-104 03/07/19 08:37 LABORATORY CONTROL SAMPLE: 2813545 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1-Methylnaphthalene ug/L 5 3.3 66 40-96 2-Methylnaphthalene ug/L 5 3.3 65 40-94 Acenaphthene ug/L 5 3.2 65 42-96 Acenaphthylene ug/L 5 3.2 63 39-90 Anthracene ug/L 5 3.7 75 46-109 Benzo(a)anthracene ug/L 5 4.1 83 50-116 Benzo(a)pyrene ug/L 5 4.1 83 48-117 Benzo(b)fluoranthene ug/L 5 4.2 85 51-124 Benzo(g,h,i)perylene ug/L 5 4.1 83 47-121 Benzo(k)fluoranthene ug/L 5 4.4 88 50-125 Chrysene ug/L 5 4.4 87 53-122 Dibenz(a,h)anthracene ug/L 5 4.0 80 45-123 Fluoranthene ug/L 5 4.5 90 52-119 Fluorene ug/L 5 3.4 68 44-100 Indeno(1,2,3-cd)pyrene ug/L 5 4.0 79 46-121 Naphthalene ug/L 5 3.2 64 40-91 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:12 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 39 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057Melreese Golf Course Pace Project No.: 35451864 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE: 2813545 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phenanthrene ug/L 5 3.7 73 47-111 Pyrene ug/L 5 4.4 88 51-120 2-Fluorobiphenyl (S) % 71 33-82 p-Terphenyl-d14 (S) % 98 49-104 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2813901 2813902 MS MSD 35452061003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1-Methylnaphthalene ug/L 0.19 U 5 5 3.1 3.1 62 62 40-96 1 40 2-Methylnaphthalene ug/L 0.68 U 5 5 3.2 3.1 64 61 40-94 4 40 Acenaphthene ug/L 0.040 U 5 5 3.0 3.2 60 63 42-96 4 40 Acenaphthylene ug/L 0.030 U 5 5 2.9 3.0 58 61 39-90 4 40 Anthracene ug/L 0.043 U 5 5 3.7 3.9 74 78 46-109 5 40 Benzo(a)anthracene ug/L 0.055 U 5 5 4.0 4.2 81 83 50-116 3 40 Benzo(a)pyrene ug/L 0.12 U 5 5 4.0 4.0 81 79 48-117 2 40 Benzo(b)fluoranthene ug/L 0.027 U 5 5 4.0 4.0 81 80 51-124 1 40 Benzo(g,h,i)perylene ug/L 0.15 U 5 5 4.0 3.8 79 77 47-121 3 40 'enzo(k)fluoranthene ug/L 0.16 U 5 5 4.2 4.1 84 82 50-125 2 40 .;hrysene ug/L 0.026 U 5 5 4.2 4.2 84 85 53-122 1 40 Dibenz(a,h)anthracene ug/L 0.13 U 5 5 3.9 3.7 77 74 45-123 4 40 Fluoranthene ug/L 0.018 U 5 5 4.5 4.7 89 94 52-119 5 40 Fluorene ug/L 0.088 U 5 5 3.2 3.4 65 69 44-100 5 40 Indeno(1,2,3-cd)pyrene ug/L 0.12 U 5 5 3.9 3.7 77 75 46-121 3 40 Naphthalene ug/L 0.29 U 5 5 2.9 2.9 58 58 40-91 0 40 Phenanthrene ug/L 0.16 U 5 5 3.7 3.8 73 77 47-111 4 40 Pyrene ug/L 0.032 U 5 5 4.4 4.5 87 91 51-120 4 40 2-Fluorobiphenyl (S) % 68 70 33-82 p-Terphenyl-d14 (S) % 97 98 49-104 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/12/2019 09:12 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 21 of 39 aceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057Melreese Golf Course Pace Project No.: 35451864 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521011 Analysis Method: FL -PRO QC Batch Method: EPA 3510 Analysis Description: FL -PRO Water Low Volume Associated Lab Samples: 35451864001 METHOD BLANK: 2813560 Matrix: Water Associated Lab Samples: 35451864001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Petroleum Range Organics N-Pentatriacontane (S) o-Terphenyl (S) mg/L ok 0.80 U 1.0 0.80 03/07/19 12:40 86 42-159 03/07/19 12:40 79 66-139 03/07/19 12:40 LABORATORY CONTROL SAMPLE: 2813561 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Petroleum Range Organics N-Pentatriacontane (S) o-Terphenyl (S) mg/L % % 5 4.4 87 66-119 99 42-159 94 66-139 MATRIX SPIKE SAMPLE: 2814271 35452019001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Petroleum Range Organics N-Pentatriacontane (S) o-Terphenyl (S) mg/L ok 0.73 U 4.6 3.9 80 65-123 89 42-159 90 66-139 SAMPLE DUPLICATE: 2814272 35451859001 Dup Parameter Units Result Result RPD Max RPD Qualifiers Petroleum Range Organics N-Pentatriacontane (S) o-Terphenyl (S) mg/L % % 0.79 U 0.77 U 97 91 81 89 9 7 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/12/2019 09:12 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 22 of 39 aceAnalytical wwwpacelabscom QUALIFIERS Project: 2018-3057Melreese Golf Course Pace Project No.: 35451864 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: 520947 [M5] A matrix spike/matrix spike duplicate was not performed for this batch due to insufficient sample volume. ANALYTE QUALIFIERS The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. U Compound was analyzed for but not detected. 1 p A matrix spike/matrix spike duplicate was not performed for this batch due to insufficient sample volume. J(M1) Estimated Value. Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. MS Analyte recovery in the matrix spike was outside QC limits for one or more of the constituent analytes used in the calculated result. S3 Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated samples. Y The laboratory analysis was from an improperly preserved sample. c2 Acid preservation may not be appropriate for the analysis of 2-Chloroethylvinyl ether. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. Date: 03/12/2019 09:12 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 39 aceAnalytical® www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057Melreese Golf Course Pace Project No.: 35451864 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID QC Batch Method Analytical QC Batch Analytical Method Batch 35451864001 SCS-MW-1 EPA 3510 520947 EPA 8081 521160 35451864001 SCS-MW-1 EPA 3510 521011 FL -PRO 521222 35451864001 SCS-MW-1 EPA 3010 521178 EPA 6010 521271 35451864001 SCS-MW-1 EPA 7470 521100 EPA 7470 521259 35451864001 SCS-MW-1 EPA 3510 521006 EPA 8270 by SIM 521083 35451864001 SCS-MW-1 EPA 8260 520786 Date: 03/12/2019 09:12 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 24 of 39 � r,.__. analytical CHAIN-OF-C iJ4# 35451.864 The Chain -of -Custody is c urately. Section A Section B Required Client Information: Required Project Information: InvoiceSection I il I I I Ell I I III I I II I 111 Company EE&G Environmental Services. LLC Report To 11:C�r Attention35451864 Page 1 Of 1 Address 5751 Miami Lakes Dr y`11 V V Copy To �' .ai• Cleve.." q e-r Company Hialeah, FL 33014 J [mail ' mar. "" r✓14, ~ eeca.,,,,N . G,,.s, Purchase Order #. Address Pace Quote Regulatory Agency Phone- (305)374-8300 ax � Project Name `� //�; a 'l� �,. Requested Due Date. � ;, �.4_G 1 l f" O wUry^e Project #: 2018-305 Pace Project Manager Christina raschke(ulparelabs com, /-. State /Location • �/�. (2'x. / Pace Profile it Regti 4al Fil FL MATRIX CODE9 I. in a 6 o COLLECTED Z Preservatives Z % - —a.1DnnMng ered (Y/N) t) Wt., OW whirr WT SAMPLE ID sooasoid st of o U c? START END 2 ti 11/ o , n- a M( O co n r U V o tC? J M > Z It One Character per box. wrr,r WP (A-Z 0-91 -) Alt AR Alt OT Sample Ids must be unique Other Ts p O x a Y N d < w ` :r z Q o LL O 8 8 C v O N O O O m O N t0 -8 G N N L N N N m C Q (� Oj (O N N a 2 Q 0 J D- D_ rn N a N N w N p. , N W r! A N o m N x -o U m ca O 2 o r O)'CI yy `'r. M 7 `' , ^1 y ���fff 9 O y DATE TIME DATE TIME y > i i 2 z z i 0 m 0 I— Q 0_ 2 0 m Q Ry-idlt 2 ct 2 3 4. 5 6 7 -8 9 10 11 12 ADDITIONAL COMMENTS RELINQUISHED BY 1 AFFIUATION DATE TIME '---,ACCEPTED BY I AFFILIATION DATE TIME SAMPLE CONDITIONS 'l[�- / 1.l .. (, t LY 3 (-1 Ci c is c' S\i ` / �y Y � SAMPLER NAME AND SIGNATURE . r TEMP in C Custody Sealed Cooler (Y/N) E. c }E. ¢a) co CD PRINT Name of SAMPLER: ri cn oN SIGNATURE of SAMPLER: Y ��' I� % IRATE Signed: � / �' / `1 CO Document Name Sample Condition Upon Receipt Form Document No F-FL-C-007 rev 13 ImimmJ0# : 35451864 Project # M: CTR I.IENT : 36-EEc Project Manager: Client: Thermometer Used Due Date: 03/12/19 0. Date: Time: Document Revised May 30. 2018 Issuing Authority Pace Florida Quality Office SCUR) Date and Initials of p Examining content: Label: Deliver' pH: State of rigi `do ;J For VAN protects, all containers verified to so `C Cooler #1 Temp.°C (Visual) 0. 0 (Correction Factor) 3. V (Actual) Cooler #2 Temp.°C (Visual) 0 0 (Correction Factor) (, 0 (Actual) Cooler #3 Temp.°C 5.5 (Visual) _(Correction Factor) (Actual) (Visual) (Correction Factor) (Actual) Cooler #4 Temp.°C Cooler #5 Temp.°C (Visual) (Correction Factor) (Actual) Cooler #6 Temp.°C (Visual) (Correction Factor) (Actual) Courier: L Fed Ex UPS El USPS E Client Commercia Pace Shipping Method: = First Overnight - Priority Overnight -_ Standard Overnight Other Billing: C Recipient Tracking # Sender Custody Seal on Cooler/Box Present: Lives Packing Material: ❑Bubble Wrap Samples shorted to lab (If Yes, complete) Third Party ubble Bags 1 'None Shorted Date: = Credit Card Seals intact: L Yes ❑Other 1 v ' A - Comments: Ground G Samples on ice, cooling process has beoun Samples on ice, cooling process has begun Samples on ice. cooling process has begun Samples on ice. cooling process has begun Samples on ice cooling process has beoun Samples on ice, cooling process has begun Other E International Priority Unknown lue Dry None Shorted Time. ) Qty: Chain of Custody Present _ es _ No EN/A Chain of Custody Filled Out s E No ❑N/A Relinquished Signature & Sampler Name COC e0 No ❑N/A Samples Arrived within Hold Time ms Yes ` No DN/A Rush TAT requested on COC DYes N/A Sufficient Volume _s E No DN/A Correct Containers Used _Yes E No DN/A Containers Intacts 3 No DN/A Sample Labels match COC (sample IDs & date/time of collection) �// Yes D' No DN/A All containers needing acid/base preservation have been checked. — es -3 No DN/A All Containers needing preservation are found to be in / compliance with EPA recommendation es _• No EN/A Exceptions. VOA, Coliform, TOC, O&G, Carbamates Preservation Information Preservative f Lot #r race # Date b Initials if Headspace in VOA Vials? (>6mm) 1Yes - No IN/A Trip Blank Present DYes E. No EN/A Client Notification/ Resolution: Person Contacted' Comments/ Resolution (use back for additional comments): Date/Time Project Manager Review Date: Page 26 of 39 /eAna/yticaI U National Center for Testing & Innovation A\ALYT CAL RI - March 12, 2019 DORT Pace Analytical - Pompano Beach, FL Sample Delivery Group: L1076221 Samples Received: 03/07/2019 Project Number: 35451864 Description: 2018-3057Melreese Gold Course Site: 001 Report To: Christina Raschke 3610 Park Central Blvd N Pompano Beach, FL 33064 Entire Report Reviewed By: Jason Romer Project Manager Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace National is performed per guidance provided in laboratory standard operating procedures: 060302, 060303, and 060304. 12065 Lebanon Rd Mount Juliet, TN 37122 615-758-5858 800-767-5859 www.pacenational.com TABLE OF CONTENTS ONE LAB. NATIONWIDE. 110 Cp: Cover Page 1 Tc: Table of Contents 2 Ss: Sample Summary 3 Cn: Case Narrative 4 Sr: Sample Results 5 SCS-MW-1 L1076221-01 5 Qc: Quality Control Summary 6 Chlorinated Acid Herbicides (GC) by Method 8151 6 OP Pesticides by Method 8141 7 GI: Glossary of Terms 10 Al: Accreditations & Locations 11 Sc: Sample Chain of Custody 12 ACCOUNT: Pace Analytical - Pompano Beach, FL Cp Cn Qc GI Al Page 28 of 39 PROJECT: SDG: DATE/TIME: PAGE: 35451864 L1076221 03/12/1912:12 2 of 13 SAMPLE SUMMARY ONE LAB. NATIONWIDE. .41, ��Ilc r_d date/time SCS-MW-1 L1076221-01 GW • od Chlorinated Acid Herbicides (GC) by Method 8151 OP Pesticides by Method 8141 Batch Dilution Preparation Analysis Analyst Location date/time date/time WG1247068 1 03/08/19 08:07 03/09/19 01:49 KLM Mt. Juliet, TN WG1246727 1 03/07/1918:03 03/11/1916:27 HMH Mt. Juliet, TN Cp 4 Cn 5 Sr 6 QC GI Al Page 29 of 39 PROJECT: SDG: DATE/TIME: PAGE: 35451864 L1076221 03/12/1912:12 3 of 13 ACCOUNT: Pace Analytical - Pompano Beach, FL CASE NARRATIVE ONE LAB. NATIONWIDE. JO All sample aliquots were received at the correct temperature, in the proper containers, with the appropriate preservatives, and within method specified holding times, unless qualified or notated within the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data. Jason Romer Project Manager ACCOUNT: Pace Analytical - Pompano Beach. FL l' cPJ —31 Ss Qc GI HI Page 30 of 39 PROJECT: SDG: DATE/TIME: PAGE: 35451864 L1076221 03/12/1912:12 4 of 13 SCS-MW-1 Collected date/time: 03/04/19 12:14 SAMPLE RESULTS - 01 L1076221 ONE LAB NATIONWIDE. Chlorinated Acid Herbicides (GC) by Method 8151 Result Qualifier MDL RDL Dilution Analysis Batch to ug/I ug/I ug/I date/time 0.744 U 0.744 2.00 1 03/09/2019 01:49 WG1247068 Dalapon 1.04 U 1.04 2.00 1 03/09/2019 01:49 WG1247068 2,4-DB 0.775 U 0.775 4.00 1 03/09/2019 01:49 WG1247068 Dicamba 0.813 U 0.813 2.00 1 03/09/2019 01:49 WG1247068 Dichloroprop 0.778 U 0.778 2.00 1 03/09/2019 01:49 WG1247068 Dinoseb 0.795 U 0.795 2.00 1 03/09/2019 01:49 WG1247068 MCPA 13.1 J U 13.1 200 1 03/09/2019 01:49 WG1247068 MCPP 7.15 U 7.15 200 1 03/09/2019 01:49 WG1247068 2,4,5-1 0.843 U 0.843 2.00 1 03/09/2019 01:49 WG1247068 2,4,5-TP (Silvex) 0.845 U 0.845 2.00 1 03/09/2019 01:49 WG1247068 (S)2,4-Dichloropheny/Acetic 127 14.0-158 03/09/2019 01:49 WG1247068 Acid OP Pesticides by Method 8141 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Azinphos-Methyl 0.348 U 0.348 1.00 1 03/11/201916:27 WG1246727 Bolstar (Sulprofos) 0.205 U 0.205 1.00 1 03/11/201916:27 WG1246727 Chlorpyrifos 0.245 U 0.245 1.00 1 03/11/201916:27 WG1246727 Coumaphos 0.277 U 0.277 1.00 1 03/11/201916:27 WG1246727 Demeton,-0 and -S 0.341 J U 0.341 2.00 1 03/11/201916:27 WG1246727 Diazinon 0.377 U 0.377 1.00 1 03/11/201916:27 WG1246727 Dichlorvos 0.212 U 0.212 2.00 1 03/11/2019 16:27 WG1246727 Dimethoate 0.105 U 0.105 1.00 1 03/11/201916:27 WG1246727 Disulfoton 0.277 U 0.277 1.00 1 03/11/201916:27 WG1246727 '' 0.261 J U 0.261 1.00 1 03/11/201916:27 WG1246727 prop 0.354 U 0.354 1.00 1 03/11/20191627 WG1246727 Ethyl Parathion 0.292 J U 0.292 1.00 1 03/11/201916:27 WG1246727 Fensulfothion 0.130 U 0.130 1.00 1 03/11/201916:27 WG1246727 Fenthion 0.266 U 0.266 1.00 1 03/11/201916:27 WG1246727 Malathion 0.173 U 0.173 1.00 1 03/11/201916:27 WG1246727 Merphos 0.267 U 0.267 2.00 1 03/11/2019 16:27 WG1246727 Methyl parathion 0.257 J U 0.257 1.00 1 03/11/201916:27 WG1246727 Mevinphos 0118 U 0.118 1.00 1 03/11/201916:27 WG1246727 Naled 0.289 J U 0.289 1.00 1 03/11/201916:27 WG1246727 Phorate 0.282 U 0.282 1.00 1 03/11/201916:27 WG1246727 Ronnel 0.252 U 0.252 1.00 1 03/11/201916:27 WG1246727 Stirophos 0.226 U 0.226 1.00 1 03/11/201916:27 WG1246727 Sulfotep 0.202 U 0.202 1.00 1 03/11/201916:27 WG1246727 TEPP 9.74 J U 9.74 20.0 1 03/11/201916:27 WG1246727 Tokuthion (Prothothiofos) 0.254 U 0.254 1.00 1 03/11/201916:27 WG1246727 Trichloronate 0.213 U 0.213 1.00 1 03/11/201916:27 WG1246727 (S) Triphenyl Phosphote 56.2 42.0-129 03/71/201916:27 WG1246727 Tc Cn 5 Sr 6 Qc GI Al ACCOUNT: Pace Analytical - Pompano Beach, FL Page 31 of 39 PROJECT: SDG: DATE/TIME: PAGE: 35451864 L1076221 03/12/1912:12 5 of 13 WG1247068 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. arA Chlorinated Acid Herbicides (GC) by Method 8151 L1076221-01 Method Blank (MB) (MB) R3390374-1 03/09/19 01:08 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I 2,4-0 0.744 U 0.744 2.00 Dalapon 1.04 U 1.04 2.00 2,4-DB 0.775 U 0.775 4.00 Dicamba 0.813 U 0.813 2.00 Dichloroprop 0.778 U 0.778 2.00 Dinoseb 0.795 U 0.795 2.00 MCPA 13.1 U 13.1 200 MCPP 7.15 U 7.15 200 2,4,5-1 0.843 U 0.843 2.00 2,4,5-TP (Silvex) 0.845 U 0.845 2.00 (S) 2,4-Dichlorophenyl Acetic 66.2 14.0-158 Acid Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3390374-2 03/09/19 01:22 • (LCSD) R3390374-3 03/09/19 01:35 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I % % % % % 2,4-D 5.00 3.28 3.31 65.6 66.2 50.0-120 0.910 20 Dalapon 5.00 2.64 2.67 52.8 53.4 32.0-120 1.13 20 2,4-08 5.00 3.73 4.10 74.6 82.0 53.0-140 P 9.45 20 Dicamba 5.00 3.49 3.50 69.8 70.0 51.0-120 0.286 20 Dichloroprop 5.00 3.26 3.30 65.2 66.0 55.0-127 1.22 20 Dinoseb 5.00 2.21 2.18 44.2 43.6 36.0-134 1.37 20 MCPA 50.0 232 193 464 386 10.0-160 J L P J L 18.4 40 MCPP 50.0 19.9 20.5 39.8 41.0 10.0-160 2.97 23 2,4,5-1 5.00 3.72 3.69 74.4 73.8 54.0-120 0.810 20 2,4,5-TP (Silvex) 5.00 3.69 3.68 73.8 73.6 50.0-125 0.271 20 (S) 2,4-Dichlorophenyl Acetic Acid 62.8 60.8 14.0-158 ACCOUNT: I -ace Analytical - Pompano Beach, FL Cp 3 SS 4 Cn 6 Qc GI Al =`qge 32 of 39 PROJECT: SDG: DATE/TIME: AGE: 35451864 L1076221 03/12/19 12:12 6 of 13 WG12 727 OP Pesticic._- by Method 8141 QUALITY COS ROL SUMMARY L1, _21-01 ONE LAB. r- "7NWIDE. Method Blank (MB) (MB) R3390660-1 03/11/19 11:42 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I Azinphos-Methyl 0.348 U 0.348 1.00 Bolstar (Sulprofos) 0.205 U 0.205 1.00 Chlorpyrifos 0.245 U 0.245 1.00 Coumaphos 0.277 U 0.277 1.00 Demeton,-0 and -S 0.341 U 0.341 2.00 Diazinon 0.377 U 0.377 1.00 Dichlorvos 0.212 U 0.212 2.00 Dimethoate 0.105 U 0.105 1.00 Disulfoton 0.277 U 0.277 1.00 EPN 0.261 U 0.261 1.00 Ethoprop 0.354 U 0.354 1.00 Ethyl Parathion 0.292 U 0.292 1.00 Fensulfothion 0.130 U 0.130 1.00 Fenthion 0.266 U 0.266 1.00 Malathion 0.173 U 0.173 1.00 Merphos 0.267 U 0.267 2.00 Methyl parathion 0.257 U 0.257 1.00 Mevinphos 0.118 U 0.118 1.00 Naled 0.289 U 0.289 1.00 Phorate 0.282 U 0.282 1.00 Ronnel 0.252 U 0.252 1.00 Stirophos 0.226 U 0.226 1.00 Sulfotep 0.202 U 0.202 1.00 TEPP 9.74 U 9.74 20.0 Tokuthion (Prothothiofos) 0.254 U 0.254 1.00 Trichloronate 0.213 U 0.213 1.00 (S) Tripheny/ Phosphate 56.4 42.0-129 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3390660-2 03/11/19 12:45 • (LCSD) R3390660-3 03/11/19 13:17 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I % % % % % Azinphos-Methyl 5.00 3.70 4.38 74.0 87.6 43.0-142 16.8 20 Bolstar (Sulprofos) 5.00 3.58 4.03 71.6 80.6 47.0-128 11.8 20 Chlorpyrifos 5.00 3.62 4.26 72.4 85.2 50.0-126 16.2 20 Coumaphos 5.00 3.85 4.40 77.0 88.0 37.0-137 P P 13.3 20 Demeton,-0 and -S 2.50 ND ND 0.000 0.000 22.0-150 J J 0.000 24 Diazinon 5.00 4.14 4.41 82.8 88.2 54.0-130 6.32 20 ACCOUNT: Pace Analytical - Pompano Beach, FL Cp Tc 4 Cn c Qc 7GI Al Page 33 of 39 PROJECT: SDG: DATE/TIME: PAGE: 35451864 L1076221 03/12/19 12:12 7 of 13 WG1246727 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. al OP Pesticides by Method 8141 L1076221-01 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3390660-2 03/11/19 12:45 • (LCSD) R3390660-3 03/11/19 13:17 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I % % % % % Dichlorvos 5.00 3.88 4.38 77.6 87.6 43.0-135 12.1 24 Dimethoate 5.00 2.17 2.80 43.4 56.0 27.0-120 25.4 27 Disulfoton 5.00 3.59 4.10 71.8 82.0 44.0-136 13.3 21 EPN 5.00 8.45 9.01 169 180 31.0-143 J J 6.41 21 Ethoprop 5.00 3.76 4.05 75.2 81.0 52.0-130 7.43 20 Ethyl Parathion 5.00 7.36 8.02 147 160 42.0-134 J J 8.58 20 Fensulfothion 5.00 3.79 4.36 75.8 87.2 42.0-137 14.0 20 Fenthion 5.00 3.44 4.03 68.8 80.6 53.0-133 P 15.8 20 Malathion 5.00 3.29 3.56 65.8 71.2 47.0-121 7.88 20 Merphos 5.00 3.48 4.14 69.6 82.8 14.0-123 17.3 25 Methyl parathion 5.00 4.92 6.10 98.4 122 43.0-135 J 21.4 20 Mevinphos 5.00 3.57 4.33 71.4 86.6 49.0-123 19.2 23 Naled 5.00 5.47 7.24 109 145 25.0-126 J 27.9 26 Phorate 5.00 3.60 3.74 72.0 74.8 44.0-129 3.81 20 Ronnel 5.00 3.42 3.93 68.4 78.6 51.0-125 13.9 20 Stirophos 5.00 3.77 4.61 75.4 92.2 53.0-125 20.0 20 Sulfotep 5.00 3.87 4.40 77.4 88.0 40.0-140 12.8 22 TEPP 50.0 17.6 34.2 35.2 68.4 18.0-122 J 64.1 32 Tokuthion (Prothothiofos) 5.00 3.59 4.14 71.8 82.8 50.0-128 14.2 20 Trichloronate 5.00 3.74 4.26 74.8 85.2 47.0-130 13.0 21 (S) Triphenyl Phosphate 68.0 74.6 42.0-129 L1075936-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1075936-01 03/11/19 14:52 • (MS) R3390660-4 03/11/19 15:24 • (MSD) R3390660-5 03/11/19 15:55 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I ug/I % % % % Azinphos-Methyl 5.00 0.348 3.50 3.62 70.0 72.4 1 29.0-157 3.37 20 Bolstar (Sulprofos) 5.00 0.205 3.33 3.39 66.6 67.8 1 37.0-138 1.79 20 Chlorpyrifos 5.00 0.245 3.63 3.62 72.6 72.4 1 42.0-131 0.276 20 Coumaphos 5.00 0.277 3.74 3.57 74.8 71.4 1 31.0-150 P P 4.65 20 Demeton,-0 and -S 2.50 0.341 0.341 0.341 0.000 0.000 1 30.0-152 J U J U 0.000 20 Diazinon 5.00 0.377 4.06 4.04 81.2 80.8 1 47.0-134 0.494 20 Dichlorvos 5.00 0.212 3.92 3.65 78.4 73.0 1 39.0-140 7.13 22 Dimethoate 5.00 0.105 2.54 2.39 50.8 47.8 1 17.0-129 6.09 20 Disulfoton 5.00 0.277 3.45 3.42 69.0 68.4 1 42.0-131 0.873 21 EPN 5.00 0.261 8.45 8.23 169 165 1 17.0-155 J J P 2.64 20 Ethoprop 5.00 0.354 3.68 3.13 73.6 62.6 1 46.0-133 16.2 20 Ethyl Parathion 5.00 0.292 7.11 7.22 142 144 1 30.0-138 J P J P 1.54 20 ACCOUNT: Nace Analytical - Pompano Beach, FL Cp 2 Tc 3 SS Cn 6 Qc GI Al -.age 34 of 39 PROJECT: SDG: DATE/TIME: ?AGE: 35451864 L1076221 03/12/19 12:12 8 of 13 WG12 727 QUALITY COf ROL SUMMARY OP Pestick . by Method 8141 L1L. 21-01 ONE LAB. r 3NWIDE. L1075936-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1075936-01 03/11/1914:52 • (MS) R3390660-4 03/11/19 15:24 • (MSD) R3390660-5 03/11/1915:55 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I ug/I % % % % % Fensulfothion 5.00 0.130 3.68 3.94 73.6 78.8 1 36.0-145 6.82 20 Fenthion 5.00 0.266 3.44 3.43 68.8 68.6 1 46.0-140 P P 0.291 20 Malathion 5.00 0.173 3.69 3.19 73.8 63.8 1 39.0-126 14.5 20 Merphos 5.00 0.267 2.97 2.82 59.4 56.4 1 10.0-120 5.18 27 Methyl parathion 5.00 0.257 4.89 4.98 97.8 99.6 1 28.0-142 1.82 20 Mevinphos 5.00 0.118 3.61 3.39 72.2 67.8 1 38.0-134 6.29 20 Naled 5.00 0.289 5.51 5.11 110 102 1 14.0-130 7.53 20 Phorate 5.00 0.282 3.44 3.33 68.8 66.6 1 38.0-134 3.25 20 Ronnel 5.00 0.252 3.58 3.21 71.6 64.2 1 42.0-131 10.9 20 Stirophos 5.00 0.226 3.89 3.63 77.8 72.6 1 33.0-143 6.91 20 Sulfotep 5.00 0.202 3.98 3.72 79.6 74.4 1 34.0-143 6.75 20 TEPP 50.0 9.74 30.9 38.7 61.8 77.4 1 38.0-120 22.4 25 Tokuthion (Prothothiofos) 5.00 0.254 3.58 3.48 71.6 69.6 1 35.0-140 2.83 24 Trichloronate 5.00 0.213 3.89 3.58 77.8 71.6 1 41.0-133 8.30 20 (5) Triphenyl Phosphate 67.4 66.0 42.0-129 ACCOUNT: Pace Analytical - Pompano Beach, FL Cp z Tc 3SS Cn 6 Qc GI Page 35 of 39 PROJECT: SDG: DATE/TIME: PAGE: 35451864 L1076221 03/12/19 12:12 9 of 13 GLOSSARY OF TERMS ONE LAB. NATIONWIDE. sk Guide to Reading and Understanding Your Laboratory Report The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and if you have additional questions please contact your project representative. Abbreviations and Definitions MDL ND RDL Rec. RPD SDG (S) Analyte Dilution Limits Original Sample Qualifier Result Uncertainty (Radiochemistry) Case Narrative (Cn) Quality Control Summary (Qc) Sample Chain of Custody (Sc) Sample Results (Sr) Sample Summary (Ss) Qualifier Method Detection Limit. Not detected at the Reporting Limit (or MDL where applicable). Reported Detection Limit. Recovery. Relative Percent Difference. Sample Delivery Group. Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be detected in all environmental media. The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes reported. If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor. These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or duplicated within these ranges. The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control sample. The Original Sample may not be included within the reported SDG. This column provides a letter and/or number designation that corresponds to additional information concerning the result reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable. The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL" (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte. Confidence level of 2 sigma. A brief discussion about the included sample results, including a discussion of any non -conformances to protocol observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report. This section of the report includes the results of the laboratory quality control analyses required by procedure or analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material. This is the document created in the field when your samples were initially collected. This is used to verify the time and date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the samples from the time of collection until delivery to the laboratory for analysis. This section of your report will provide the results of all testing performed on your samples. These results are provided by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for each sample will provide the name and method number for the analysis reported. This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and times of preparation and/or analysis. Description J L P u The value is outside laboratory established criteria. Off -scale high. Actual value is known to be greater than value given. RPD between the primary and confirmatory analysis exceeded 40%. Indicates the compound was analyzed for but not detected above the method detection limit. ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Pompano Beach, FL 35451864 L1076221 03/12/1912:12 SS 4Cn 5 Sr 6 Qc GI s Al Page 36 of 39 PAGE: 10 of 13 ACCREDITATIONS & LOCATIONS ONE LAB. NATIONWIDE.ilk Pace National is the only environmental laboratory accreditedkertified to support your work nationwide from one location. One phone call, one point of contact, one laboratory. No other lab is as accessible or prepared to handle your needs throughout the country. our capacity and capability from our single location laboratory is comparable to the collective totals of the network laboratories in our industry. The most significant benefit to our one location design is the design of our laboratory campus. The model is conducive to accelerated productivity, decreasing turn -around time, and preventing cross contamination, thus protecting sample integrity. Our focus on premium quality and prompt service allows us to be YOUR LAB OF CHOICE. ' Not all certifications held by the laboratory are applicable to the results reported in the attached report. ' Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace National. State Accreditations Alabama 40660 Nebraska NE-OS-15-05 Alaska 17-026 Nevada TN-03-2002-34 Arizona A20612 New Hampshire 2975 Arkansas 88-0469 New Jersey—NELAP TN002 California 2932 New Mexico' n/a Colorado TN00003 New York 11742 Connecticut PH-0197 North Carolina Env375 Florida E87487 North Carolina' DW21704 Georgia NELAP North Carolina' 41 Georgia' 923 North Dakota R-140 Idaho TN00003 Ohio—VAP CL0069 Illinois 200008 Oklahoma 9915 Indiana C-TN-01 Oregon TN200002 Iowa 364 Pennsylvania 68-02979 Kansas E-10277 Rhode Island LA000356 Kentucky' 5 90010 South Carolina 84004 Kentucky 2 16 South Dakota n/a Louisiana A130792 Tennessee 14 2006 Louisiana' LA180010 Texas T104704245-18-15 Maine TN0002 Texas LAB0152 Maryland 324 Utah TN00003 Massachusetts M-TN003 Vermont VT2006 Michigan 9958 Virginia 460132 Minnesota 047-999-395 Washington C847 Mississippi TN00003 West Virginia 233 Missouri 340 Wisconsin 9980939910 Montana CERT0086 Wyoming A2LA Third Party Federal Accreditations A2LA — ISO 17025 1461.01 A2LA — ISO 17025 5 1461.02 Canada 1461.01 EPA—Crypto TN00003 AIHA-LAP,LLC EMLAP 100789 DOD 1461.01 USDA P330-15-00234 Drinking Water 2 Underground Storage Tanks ' Aquatic Toxicity " Chemical/Microbiological 5 Mold 5 Wastewater n/a Accreditation not applicable Our Locations Pace National has sixty-four client support centers that provide sample pickup and/or the delivery of sampling supplies. If you would like assistance from one of our support offices, please contact our main office. Pace National performs all testing at our central laboratory. Ss 4 Cn 5Sr 6 Qc GI Page 37 of 39 PAGE: 11 of 13 oAl ACCOUNT: Pace Analytical - Pompano Beach, FL PROJECT: 35451864 SDG: L1076221 DATE/TIME: 03/12/1912:12 Chain of Custody Workorder: 35451864 Workorder Name: Christina Raschke Pace Analytical South Florida 3610 Park Central Blvd N Pompano Beach, FL 33064 Phone (954)582-4300 Email. christina.raschke@pacelabs.com State of Sample Origin: FL Sample to SCS-MW-1 2 Coiioct Date/Time 3/4/2019 12:14 C` 71 2018-3057Melreese Golf Course Results Requested By: 3/12/2019 Lab ID 35451864001 Water P.O. ace Analytical® www .corn —1o7 LI LAB USE ONLY --O 3 4 Transfers Released By 1 2 Date/Time ReceivBy Date/Time hqogto 3 Cooler Temperature on Receipt I Custody Seal or yqo 513s ,40 r Received on Ice Y or N Samples Intact Y or RAD SCRLL!`d: <G.5 rnR, Wednesday March 06, 2019 1.57:46 PM FMT-ALL-C-002rev.00 24March2009 I,ago 11 n( 1 'e 38 of 39 Pace Analytical National Center for Testing & Innovation Cooler Receipt Form client: r% p,(. 11 I P l" Slx;#: 10-1(o7,L 1 (;ogler Received/Opened On: 3 / 7/19 Temperature: 1 .L1 Received Ily: Jeremy Wehh Signature: (2 � j� Receipt Check List NP Yes No COC Seal Present / Intact? , COC Signed / Accurate? -'" Bottles arrive intact? Correct bottles used? Sufficient volume sent? If Applicable VOA Zero headspace? Preservation Correct / Checked? Page 39 of 39 aceAnalytical www.pacelabs.com March 28, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melresse Golf Course Pace Project No.: 35451833 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 05, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry, EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 18 aceAnalytical www.pacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melresse Golf Course Pace Project No.: 35451833 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35451833001 SCS-MW-1 Water 03/04/19 12:14 03/05/19 17:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 18 ' 2eAnalyttcal CHAIN -OWN : 35451833 lent I ne unain-or-I Section A HI I I I Elm III 0 11 11 III npleted accurately. Section B Required Client Information: Required Project Information: 35451833 Page : 1 Of Company EERG Environmental Services, LLC Report To =MS= N\14,6,4 Y` 1 Address 5751 Miami Lakes Dr C..\ Copy To e�•, C`evnge-r- Company Name Hialeah. FL 33014 J Address Regulatory Agency E-mail - M44 ^ , e �„a • , ow, Purchase Order Al, Pace Quote: Phone (305)374-8300 ax Project Name eArZ,�y� pig (r;,ur -e 1`x1 G y Pace Project Manager 1 9 Christina raschke@pacelabs.com. /� State / Location Requested Due Date ,k...,,�•�-.,_, ,1.K ` Project*: 2018-305/ Pace Profile tt 1 FL Requ aS Fil ered (Y/N) MATRIX CODE MATRIX CODE (see valid c ades to left) !SAMPLE TYPE (G=GRAB C=COMP) COLLECTED SAMPLE TEMP AT COLLECTION C OF CONTAINERS Preservatives Z >- /�yyyyysccccy��Ii��s� - c) `� DIInY,ing Water OW Wate, Wr W.I. Water WW Product P SAMPLE ID Soil/Solid sr Oil OL START END Unpreserved H2SO4 HCI Na2S203 Methanol Analyses Test 8260 VOC PAH by 8270 SIM TRPH FL -PRO Pesticides 8081(cA- ,,,� Pesticides 81416010,,, V /L ai 0 u n a`) 1 Dioxin 8290/ a. I 6010 Ba, Cd, Cr, Se, Ag, 7470 Hg.lhii Arj t ?col c. , Ce- ;Yy •4 :Z Residual Chlorine (Y/N) # w F_ One Character per box. WIPa WP (A-Z, 0.9 1 , -) Alt AR Sample Ids must be unique Other P 9 Tissue TTSs DATE TIME DATE TIME " z = = 0 Z t O 2 3 4. 5 6 7 8 9 10 11 12 ADDITIONAL COMMENTS REUNQUISHED 87/ AFFIUATE3N -' 1, DATE. TIME EPTED BY / AFFIUATION • DATE TIME SAMPLE CONDITIONS ,_:---/ ---6 - , f---;;A::.r;',(..,-: 5/? /L.,„'-••=-:;::: , /- i '-' )Iq CMG/C i� `/ - -- iy SAMPLER NAME AND SIGNATURE • t TEMP in C Received on Ice (Y/N) Custody Sealed Cooler (YIN) Samples Intact (YIN) PRINT Name of SAMPLER: r.7) /L��: i• SIGNATURE of SAMPLER: / / (J DATE Signed; f;L:r'/Ul.;h 1icy it Samples shorted to lab (If Yes. complete) WO## : 35451833 PM: CTR Project # CLIENT: 36-EEC Project Manager: Client: 4ser: i F Lc Date Due Date: 03/15/19 Tme 01-i Date and Initials of p Examining content: , Label: Deliver ` , ► ` pH: yy�1 Cooler #1 Temp.'C (Visual)�f--/(Correction Factor) (Actual) Cooler #2 Temp.'C (Visual) O. 0 (Correction Factor) ( U(Actual) Cooler #3 Temp.'C 51. C5 (Visual) 0 _ 0 (Correction Factor) , . 5 (Actual) Cooler #4 Temp.'C (Visual) (Correction Factor) (Actual) Cooler #5 Temp.'C (Visual) (Correction Factor) (Actual) Cooler #6 Temp.'C (Visual) (Correction Factor) (Actual) Courier: — Fea Ex — UPS -- USPS — Shipping Method: Billing: Tracking Custody Seal on Cooler/Box Present: Se:x:e• Packing Material: — ?u:.c!e ,7 a �l'Bubn.e Faos _None Snciea Date — Co7e Tra- - Pac. Seals intact: — Yes Comments: — r� e Dry None S''c eu Tie Vs.)) -� e5 N 4. ., ./'e` _ ' ._. .:. ... :. COC es tic N ✓Yes No N .t,..: J -S - No Cor es No N A Co—.:-.,.-- .es i No N A es No NA Yes No -h -.,_..._.. ieadspace r• VOA i >m','es No ]c::. T nt; Stank Present Yes No A Client Notification/ Resolution: Pe:sor Contacted Comments/ Resolution (use back for additional comments) :tale Time "rote�1 i.:anager Re, ot•o Dale Page 4 of 18 ace Analytical 'M www.pacelabs.com www.pacelabs.com Report Prepared for: Christina Raschke PASI Florida 3610 Park Central Blvd N Pompano Beach FL 33064 REPORT OF LABORATORY ANALYSIS FOR PCDD/PCDF Report Prepared Date: March 14, 2019 Report No 104661178290FCDFR Pace Analytical Services, LLC. 1700 Elm Street Minneapolis, MN 55414 Phone: 612.607.1700 Fax: 612.607.6444 Report Information: Pace Project #: 10466117 Sample Receipt Date: 03/07/2019 Client Project #: 35451833 Client Sub PO #: N/A State Cert #: E87605 Invoicing & Reporting Options: The report provided has been invoiced as a Level 2 PCDD/PCDF Report. If an upgrade of this report package is requested, an additional charge may be applied. Please review the attached invoice for accuracy and forward any questions to Kirsten Hogberg, your Pace Project Manager. This report has been reviewed by: March 15, 2019 Kirsten Hogberg, Project Manager (612) 607-6407 (612) 607-6444 (fax) kirsten.hogberg@pacelabs.com Report of Laboratory Analysis Thisreportshouldnotbereproduced,exceptinfuil, withoutthewrittenconsentofPaceAnalyticalServices,Inc. Th eresultsrelateonlyt othesamplesincludedinthisreport. Page 5 of 18 Page 1 of 14 ace Analytical DISCUSSION Pace Analytical Services, LLC. 1700 Elm Street Minneapolis, MN 55414 Phone: 612.607.1700 Fax: 612.607.6444 This report presents the results from the analysis performed on one sample submitted by a representative of Pace Analytical Services, LLC. The sample was analyzed for the presence or absence of polychlorodibenzo-p-dioxins (PCDDs) and polychlorodibenzofurans (PCDFs) using a modified version of USEPA Method 8290. The reporting limits were based on signal-to-noise measurements. Estimated Maximum Possible Concentration (EMPC) values were treated as positives in the toxic equivalence calculations. Per request, estimated detection limit (EDL) values were provided and flagged "U" where the target analytes were not detected. The recoveries of the isotopically -labeled PCDD/PCDF internal standards in the sample extract ranged from 40-69%. Except for two low values, which were flagged "R" on the results table, the labeled internal standard recoveries obtained for this project were within the 40-135% target range specified in Method 8290. Also, since the quantification of the native 2,3,7,8-substituted congeners was based on isotope dilution, the data were automatically corrected for recovery and accurate values were obtained. A laboratory method blank was prepared and analyzed with the sample batch as part of our routine quality control procedures. The results show that PCDDs and PCDFs were not detected. These results indicate that the sample preparation procedures did not significantly impact the results of the field sample determinations. Laboratory spike samples were also prepared with the sample batch using clean reference matrix that had been fortified with native standard materials. The results show that the spiked native compounds were recovered at 92-120% with relative percent differences of 0.0-10.3%. These results were within the target ranges for the method. Matrix spikes were not prepared with the sample batch. REPORT OF LABORATORYANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466117_8290FC_DFR Page 6 of 18 Page 2 of 14 TM Minnesota Laboratory Certifications Authority Certificate # Pace Analytical Services. LLC 1700 Elm Street - Suite 200 Minneapolis. MN 55414 Tel: 612-607-1700 Fax:612-607-6444 Authority Certificate # A2LA 2926.01 Minnesota - Pet 1240 Alabama 40770 Mississippi MN00064 Alaska - DW MN00064 Missouri - DW 10100 Alaska - UST 17-009 Montana CERT0092 Arizona AZ0014 Nebraska NE-OS-18-06 Arkansas - DW MN00064 Nevada MN00064 Arkansas - WW 88-0680 New Hampshire 2081 CNMI Saipan MP0003 New Jersey (NE MN002 California 2929 New York 11647 Colorado MN00064 North Carolina 27700 Connecticut PH-0256 North Carolina - 27700 EPA Region 8+ via MN 027-053 North Carolina - 530 Florida (NELAP E87605 North Dakota R-036 Georgia 959 Ohio - DW 41244 Guam 17-001r Ohio - VAP CL101 Hawaii MN00064 Oklahoma 9507 Idaho MN00064 Oregon - Primar MN300001 Illinois 200011 Oregon - Secon MN200001 Indiana C-MN-01 Pennsylvania 68-00563 Iowa 368 Puerto Rico MN00064 Kansas E-10167 South Carolina 74003 Kentucky - DW 90062 South Dakota NA Kentucky - WW 90062 Tennessee TN02818 Louisiana - DE 03086 Texas T104704192 Louisiana - DW MN00064 Utah (NELAP) MN00064 Maine MN00064 Virginia 460163 Maryland 322 Washington C486 Massachusetts M-MN064 West Virginia - 382 Michigan 9909 West Virginia - 9952C Minnesota 027-053-137 Wisconsin 999407970 Minnesota - De via MN 027-053 Wyoming - UST 2926.01 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466117_8290FC_DFR Page 7 of 18 Page 3 of 14 Appendix A Sample Management Report No 10466117_8290FC_ Analytical Services, Inc. Page 8 of 18 Page 4 of 14 Report No 10466117_8290FC_DFR lv oD m 0 Chain of Custody Samples were sent directly to the Subcontracting Laboratory. Workorder: 35451 Rs3 Christina Raschke Pace Analytical South Florida 3610 Park Central Blvd N Pompano Beach, EL 33064 Phone (954)582-4300 1 SCS-MW-1 2 3 4 5 Transfers Released By 1 2 Workorder Name: 2018-3057Melresse Golf Course PS Pace Analytical Minnesota 1700 Elm Street SE Suite 200 Minneapolis, MN 55414 Phone (612)607-1700 3/4/2019 12:14 Date/Time 1%/rt:✓ 13-5' 35451833001 Water Received By ee;iafyticat State Of Origin: FL Cert. Needed: I I Yes I No Owner Received Date: 3/5/2019 Results Requested By: 3/15/2019 Date/me 75. 3 rr nlor Tamnerature on Receipt f ,.:'2 °C 1 Custody Seal ( Y)or N I Received on Ice woa:1046e117 Y ') or N LAB USE ONLY Samples Intact$ Y yor N *""in order to maintain client confidentiality, location/name of the sampling site, sampler's name and signature may not be provided on this COC document. This chain of custody is considered complete as is since this information is available in the owner laboratory. v CD CD 9 Tuesday, March 05, 2019 7:32:41 PM FMT-ALL-C-002rev.00 24March2009 Page 1 of 1 / : aceAnalytical Document Name: Sample Condition Upon Receipt Form Document No.: F-MN-L-213-rev.25 Document Revised: 06Feb2019 Page 1 of 1 Issuing Authority: Pace Minnesota Quality Office Sample Condition Upon Receipt Courier: Tracking Number: Client Name: / )00 I it '/0/-II ❑LISPS ['Client ❑Pace ❑SpeeDee ❑Commercial See Exception )'ed Ex ❑UPS Project #: Custody Seal on Cooler/Box Present? WO#:10466117 PM: KNH Due Date: 03/21/19 CLIENT: PASI-FL es DNo Seals Intact? �Yes ❑No Packing Material: (Bubble Wrap grBubble Bags El None ❑Other: Thermometer: ❑G87A9155100842 G87A9170600254 Type of Ice: Note: Each West Virginia Sample must have temp taken (no temp blanks) Wet ['Blue Biological Tissue Frozen? ❑Yes ❑No,Z Temp Blank? ❑Yes ,Vo ❑None ['Dry ❑Melted Temp should be above freezing to 6°C Cooler Temp Read w/temp blank: °C Correction Factor: `! 0r I Cooler Temp Corrected w/temp blank : oC N/A Average Corrected Temp See Excep 'ons (no telrip b ink only): USDA Regulated Soil: ( N/A, water sample/Other: ) Date/initials of Person Examining Contents: Did samples originate in a quarantine zone within the United States: AL, AR, CA, FL, GA, Did samples originate from a foreign source (internationally, including ID, LA. MS, NC, NM, NY, OK, OR, SC, TN, TX or VA (check maps)? DYes DNo Hawaii and Puerto Rico)? Dyes DNo If Yes to either question, fill out a Regulated Soil Checklist (F-MN-Q-338) and include with SCUR/COC paperwork. COMMENTS: Chain of Custody Present and Filled Out? es [(No 1. Chain of Custody Relinquished? Oes No 2. Sampler Name and/or Signature on COC? DYes DNo /A 3. Samples Arrived within Hold Time? Oes ❑No 4. Short Hold Time Analysis (<72 hr)? DYes 0 ffffff```"` 5. [(Fecal Coliform ❑HPC [(Total Coliform/E coli ❑BOD/cBOD [(Hex Chrome [(Turbidity [(Nitrate ❑Nitrite ❑Orthophos DOther Rush Turn Around Time Requested? Dyes 6. Sufficient Volume? es ❑No 7. Correct Containers Used? -Pace Containers Used? /Yes ' Ja,'es DNo DNo 8. Containers Intact? ,es DNo 9. Field Filtered Volume Received for Dissolved Tests? DYes DNo N/A 10. Is sediment visible in the dissolved container? IIIII Yes 111 No Is sufficient information available to reconcile the samples to the COCC , Mstrix later ❑Soil ❑Oil ❑Other /es DNo 11. If no, write ID/ Date/Time on Container Below: See Exception containers needing acid/base preservation have been checked? All containers needing preservation are found to be in compliance with EPA recommendation? (HNO3, H2SO4, <2pH, NaOH >9 Sulfide, NaOH>12 Cyanide) Exceptions: VOA, Coliform, TOC/DOC Oil and Grease, DRO/8015 (water) and Dioxin/PFAS DYes DYes DYes DNo DNo DNo N/A /A �/ y5N/A 12. Sample ii ❑ NaOH ❑ HNO3 ■ H2SO4 •Zinc Acetate See Exception Positive for Res. Yes Chlorine? I No • Headspace in VOA Vials (greater than 6mm)? DYes DNo d1 VIN/A 13. See Exception II Trip Blank Present? Trip Blank Custody Seals Present? Dyes Dyes ❑No DNo rrj�Z /A N/A 14. Pace Trip Blank Lot # (if purchased): CLIENT NOTIFICATION/RESOLUTION Person Contacted: Comments/Resolution: Date/Time: Field Data Required? Des ❑No Project Manager Review: /�/�� k moles, a copy ofDate: 3/8/2019 Note: Whenever there is a discrepancy of ecting orth Carolina co lance this form will be sent to the North Carolina DEHNR Certification Office (i.e out of hold, incorrect preservative, out of temp, incorrect containers). Labeled by: Report No 10466117_8290FC_DFR Page 10 of 18 Page 6 of 14 . Pace Analytical Document Name: SCUR Exception Form —Coolers Above 6°C Document Revised: 04Feb2019 Page 1 of 1 Document No.: F-MN-C-298-Rev.01 Issuing Authority: Pace Minnesota Quality Office SCUR Exceptions: During sample triage, this form is to be placed in each cooler that arrives above 6.0 degrees Celsius Workorder #: out of Temp p Sample IDs Container Type # of Containers PM Notified? ■Yea EN. If yes, indicate who was contacted/date/time. If no, indicate reason why. Multiple Cooler If you answered yes, Project? "[Yes •No fill out information to the left. No Temp Blank Read Temp Corrected Temp Average i Temp C Cyr- JF ,-i t d .f [� I,, v: . 0,1 Other Issues Issue Type: Sample ID Container Type # of Containers Tracking Number pH Adjustment Log for Preserved Samples Sample ID Type of Preserv. pH Upon Receipt Date Adjusted Time Adjusted Amount Added (mL) Lot pH Added After In Compliance after addition? initials ❑Yes ❑No in Yes D:No •Yes ❑No •Yes ❑No Report No 10466117_8290FC_DFR Page 11 of 18 Page 7 of 14 Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 AnalyticalTM Reporting Flags A = Reporting Limit based on signal to noise B = Less than 10x higher than method blank level C = Result obtained from confirmation analysis D = Result obtained from analysis of diluted sample E = Exceeds calibration range I = Interferencepresent J = Estimated value L = Suppressive interference, analyte may be biased low Nn = Value obtained from additional analysis P = PCDEInterference R = Recovery outside target range S = Peak saturated U = Analyte not detected V = Result verified by confirmation analysis X = %D Exceeds limits Y = Calculated using average of daily RFs * = SeeDiscussion REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466117_8290FC_DFR Page 8 of 14 Tel: 612-607-1700 Fax: 612- 607-6444 Page 12 of 18 Appendix B Sample Analysis Summary Report No 10466117_8290FC_e Analytical Services, Inc. Page 13 of 18 Page 9 of 14 Analytical Clients Sample ID Lab Sample ID Filename Injected By Total Amount Extracted % Moisture Dry Weight Extracted ICAL ID CCal Filename(s) Method Blank ID Native Isomers 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD TM Metho d 8290 Sample Analysis Results Client - PASI Florida SCS-MW-1 35451833001 F190313B_10 SMT 1040 mL NA NA F190112 F190313A_18 & F190313B_17 BLANK-68966 Conc EMPC pg/L pg/L 1.3 U 1.3 U 2.0 U 2.0 U 1.4 U 1.0 U 1.2 U 1.6 U 1.6 U 2.3 U 1.8 U 1.5 U 2.1 U 1.9 U 1.7 U 2.1 U 2.1 U 2.0 U 3.2 U 5.1 U 4.1 U 3.7 U 3.7 U 11 U 11 U Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612- 607-6444 Matrix Water Dilution NA Collected 03/04/2019 12:14 Received 03/07/2019 08:55 Extracted 03/11/2019 12:00 Analyzed 03/14/2019 03:26 EDL Internal ng's pg/L Standards Added Percent Recovery 1.3 2,3,7,8-TCDF-13C 1.3 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 2.0 2,3,4,7,8-PeCDF-13C 2.0 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 1.4 1,2,3,6,7, 8-HxCDF-13C 1.0 2,3,4,6,7,8-HxCDF-13C 1.2 1,2,3,7,8, 9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 1.6 1,2, 3,6,7,8-HxCDD-13C 1.6 1,2,3,4,6,7,8-HpC DF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 2.3 1.8 1.5 2.1 1.9 1.7 2.1 2.1 2.0 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 2.00 67 2.00 69 2.00 61 2.00 59 2.00 67 2.00 63 2.00 57 2.00 69 2.00 60 2.00 63 2.00 62 2.00 47 2.00 44 2.00 49 4.00 40 2.00 NA 2.00 NA 0.20 86 3.2 Total 2,3,7,8-TCDD 5.1 Equivalence: 0.00 pg/L 4.1 (Lower -bound - Using ITE Factors) 3.7 3.7 11 11 Conc = Concentration (Totals include 2,3,7.8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit ND = Not Detected NA = Not Applicable NC = Not Calculated REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466117_8290FC_DFR Page 10 of 14 Page 14 of 18 ace Analytical TM Lab Sample Name Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) Method 8290 Blank Analysis Results DFBLKDC BLANK-68966 F190313B_06 945 mL F190112 F190313A_18 & F190313B_17 Native Conc Isomers pg/L EMPC EDL pg/L pg/L Matrix Dilution Extracted Analyzed Injected By Internal Standards Pace Analytical Services. LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax:612-607-6444 Water NA 03/11/2019 12:00 03/14/2019 00:29 SMT 2,3,7,8-TCDF 2.1 U Total TCDF 2.1 U 2,3,7,8-TCDD 2.3 U Total TCDD 2.3 U 1,2,3,7,8-PeCDF 2.0 U 2,3,4,7,8-PeCDF 1.6 U Total PeCDF 1.8 U 1,2,3,7,8-PeCDD 1.8 U Total PeCDD 1.8 U 1,2,3,4,7,8-HxCDF 2.1 U 1,2,3,6,7,8-HxCDF 1.9 U 2,3,4,6,7,8-HxCDF 1.8 U 1,2,3,7,8,9-HxCDF 2.1 U Total HxCDF 2.0 U 1,2,3,4,7,8-HxCDD 2.1 U 1,2,3,6,7,8-HxCDD 2.2 U 1,2,3,7,8,9-HxCDD 1.8 U Total HxCDD 2.0 U 1,2,3,4,6,7,8-HpCDF 3.0 U 1,2,3,4,7,8,9-HpCDF 6.0 U Total HpCDF 4.5 U 1,2,3,4,6,7,8-HpCDD 4.4 U Total HpCDD 4.4 U OCDF 9.1 U OCDD 7.3 U 2.1 1.9 1.8 2.1 2.0 2.1 2.2 1.8 2.0 2.1 2,3,7,8-TCDF-13C 2.1 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 2.3 2,3,4,7,8-PeCDF-13C 2.3 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 2.0 1,2,3,6,7,8-HxCDF-13C 1.6 2,3,4,6,7,8-HxCDF-13C 1.8 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 1.8 1,2,3,6,7,8-HxCDD-13C 1.8 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C ng's Percent Added Recovery 2.00 66 2.00 70 2.00 62 2.00 61 2.00 71 2.00 64 2.00 57 2.00 73 2.00 63 2.00 66 2.00 66 2.00 51 2.00 47 2.00 51 4.00 44 1,2,3,4-TCDD-13C 2.00 NA 1,2,3,7,8,9-HxCDD-13C 2.00 NA 2,3,7,8-TCDD-37CI4 0.20 88 3.0 Total 2,3,7,8-TCDD 6.0 Equivalence: 0.00 pg/L 4.5 (Lower -bound - Using ITE Factors) 4.4 4.4 9.1 7.3 Conc= Concentration (Totals include2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit REPORT OF LABORATORYANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466117_8290FC_DFR Page 11 of 14 Page 15 of 18 7/e Analytic Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) Method Blank ID Native Qs Isomers (ng) LCS-68967 F190313B_01 923 mL F190112 F190313A_18 & F190313B_17 BLANK-68966 2,3,7,8-TCDF 0.20 Total TCDF 2,3,7,8-TCDD 0.20 Total TCDD 1,2,3,7,8-PeCDF 1.0 2,3,4,7,8-PeCDF 1.0 Total PeCDF 1,2,3,7,8-PeCDD 1.0 Total PeCDD 1,2,3,4,7,8-HxCDF 1.0 1,2,3,6,7,8-HxCDF 1.0 2,3,4,6,7,8-HxCDF 1.0 1,2,3,7,8,9-HxCDF 1.0 Total HxCDF 1,2,3,4,7,8-HxCDD 1.0 1,2, 3,6,7,8-HxCDD 1.0 1,2,3,7,8,9-HxCDD 1.0 Total HxCDD 1,2,3,4,6,7,8-HpCDF 1.0 1,2,3,4,7,8,9-HpCDF 1.0 Total HpCDF 1,2,3,4,6,7,8-HpCDD 1.0 Total HpCDD OCDF 2.0 OCDD 2.0 TM Method 8 Method 8290 Laboratory Control Spike Results Matrix Dilution Extracted Analyzed Injected By Qm Internal (ng) Standards 0.22 109 2,3,7,8-TCDF-13C 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 0.23 117 2,3,4,7,8-PeCDF-13C 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 1.1 105 1,2,3,6,7,8-HxCDF-13C 1.1 111 2,3,4,6,7,8-HxCDF-13C 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 0.97 97 1,2,3,6,7,8-HxCDD-13C 1.1 1.1 1.1 1.1 1.1 1.0 1.0 2.2 2.2 % Rec. 113 108 105 105 111 120 103 107 102 100 108 109 Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612-607-6444 Water NA 03/11/2019 12:00 03/13/2019 20:48 SMT ng's Percent Added Recovery 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 4.0 2.0 2.0 0.20 58 60 52 51 58 52 49 60 49 55 54 41 37 R 40 33 R NA NA 80 Qs = Quantity Spiked Qm = Quantity Measured Rec. = Recovery (Expressed as Percent) R = Recovery outside of target range Y = RF averaging used in calculations Nn = Value obtained from additional analysis NA = Not Applicable = See Discussion REPORT OF LABORATORYANALYSIS This report shall not be reproduced, except in full, withoutthewritten consent of Pace Analytical Services, Inc. Report No 10466117_8290FC_DFR Page 12 of 14 Page 16 of 18 Analytical Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) Method Blank ID Native Isomers 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD TM Method 8290 Laboratory Control Spike Results LCSD-68968 F190313B_02 894 mL F190112 F190313A18 & F190313B_17 BLANK-68966 Matrix Dilution Extracted Analyzed Injected By Qs Internal (ng) Standards 0.20 109 2,3,7,8-TCDF-13C 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 0.20 0.23 116 2,3,4,7,8-PeCDF-13C 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 1.0 1.1 105 1,2,3,6,7, 8-HxCDF-13C 1.0 1.1 109 2,3,4,6,7,8-HxCDF-13C 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 1.0 0.99 99 1,2,3,6,7,8-HxCDD-13C 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 Qm (ng) 0.22 1.0 1.0 0.99 0.97 1.1 1.1 1.0 1.0 1.0 0.92 1.0 0.99 2.0 2.0 2.1 2.1 Rec. 105 104 99 97 109 115 104 104 92 99 105 106 Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612-607-6444 Water NA 03/11/2019 12:00 03/13/2019 21:33 SMT 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 ng's Percent Added Recovery 2.0 70 2.0 74 2.0 61 2.0 59 2.0 66 2.0 66 2.0 63 2.0 73 2.0 63 2.0 66 2.0 65 2.0 51 2.0 47 2.0 51 4.0 42 2.0 NA 2.0 NA 0.20 89 Qs = Quantity Spiked Qm = Quantity Measured Rec. = Recovery (Expressed as Percent) R = Recovery outside of target range Y = RF averaging used in calculations Nn = Value obtained from additional analysis NA = Not Applicable = See Discussion REPORT OF LABORATORYANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466117_8290FCDFR Page 13 of 14 Page 17 of 18 Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 TM ace Analytical i Method 8290 Spike Recovery Relative Percent Difference (RPD) Results Client PASI Florida Spike 1 ID LCS-68967 Spike 2 ID LCSD-68968 Spike 1 Filename F190313B_01 Spike 2 Filename F190313B_02 Spike 1 Spike 2 Compound %REC %REC %RPD Tel: 612-607-1700 Fax:612-607-6444 2,3,7,8-TCDF 109 109 0.0 2,3,7,8-TCDD 117 116 0.9 1,2,3,7,8-PeCDF 105 105 0.0 2,3,4,7,8-PeCDF 111 109 1.8 1,2,3,7,8-PeCDD 97 99 2.0 1,2,3,4,7,8-HxCDF 113 105 7.3 1,2,3,6,7,8-HxCDF 108 104 3.8 2,3,4,6,7,8-HxCDF 105 99 5.9 1,2,3,7,8,9-HxCDF 105 97 7.9 1,2,3,4,7,8-HxCDD 111 109 1.8 1,2,3,6,7,8-HxCDD 120 115 4.3 1,2,3,7,8,9-HxCDD 103 104 1.0 1,2,3,4,6,7,8-HpCDF 107 104 2.8 1,2,3,4,7,8,9-HpCDF 102 92 10.3 1,2,3,4,6,7,8-HpCDD 100 99 1.0 OCDF 108 105 2.8 OCDD 109 106 2.8 %REC = Percent Recovered RPD = The difference between the two values divided by the mean value REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, withoutthe written consent of Pace Analytical Services, Inc. Report No 10466117_8290FC_DFR Page 18 of 18 Page 14 of 14 aceAnalytical www.pacelabs.com April 11, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457300 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 28, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Kelsey Cortina, EE&G Environmental Solutions, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 13 CERTIFICATIONS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457300 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alaska DEC- CS/UST/LUST Alabama Certification #: 41320 Arizona Certification# AZ0819 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 13 e SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457300 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35457300001 SCS-MW-1 Water 03/27/19 09:01 03/28/19 17:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 13 aceAnalytical www.pacelabs.com SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457300 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35457300001 SCS-MW-1 EPA 8081 TCB 22 PASI-O EPA6010 JWP 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 13 °aceAnalytical wwwpacelabs.com SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457300 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35457300001 SCS-MW-1 EPA 6010 Iron 2950 ug/L 40.0 04/03/19 16:42 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 13 ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457300 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SCS-MW-1 Lab ID: 35457300001 Collected: 03/27/19 09:01 Received: 03/28/19 17:45 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8081 GCS Pesticides Analytical Method: EPA 8081 Preparation Method: EPA 3510 Aldrin 0.0014 U ug/L 0.0096 0.0014 1 04/03/19 17:20 04/09/19 15:24 309-00-2 1p alpha-BHC 0.0020 U ug/L 0.0096 0.0020 1 04/03/19 17:20 04/09/19 15:24 319-84-6 1p beta-BHC 0.0076 U ug/L 0.0096 0.0076 1 04/03/19 17:20 04/09/19 15:24 319-85-7 1p delta-BHC 0.0046 U ug/L 0.0096 0.0046 1 04/03/19 17:20 04/09/19 15:24 319-86-8 1p gamma-BHC (Lindane) 0.0021 U ug/L 0.0096 0.0021 1 04/03/19 17:20 04/09/19 15:24 58-89-9 1p Chlordane (Technical) 0.17 U ug/L 0.48 0.17 1 04/03/19 17:20 04/09/19 15:24 57-74-9 1p 4,4'-DDD 0.0085 U ug/L 0.0096 0.0085 1 04/03/19 17:20 04/09/19 15:24 72-54-8 1p 4,4'-DDE 0.0048 U ug/L 0.0096 0.0048 1 04/03/19 17:20 04/09/19 15:24 72-55-9 1p 4,4'-DDT 0.0048 U ug/L 0.0096 0.0048 1 04/03/19 17:20 04/09/19 15:24 50-29-3 1p Dieldrin 0.0019 U ug/L 0.0096 0.0019 1 04/03/19 17:20 04/09/19 15:24 60-57-1 1p Endosulfan I 0.0049 U ug/L 0.0096 0.0049 1 04/03/19 17:20 04/09/19 15:24 959-98-8 1p Endosulfan II 0.0038 U ug/L 0.0096 0.0038 1 04/03/19 17:20 04/09/19 15:24 33213-65-9 1p Endosulfan sulfate 0.0059 U ug/L 0.096 0.0059 1 04/03/19 17:20 04/09/19 15:24 1031-07-8 1p Endrin 0.0041 U ug/L 0.0096 0.0041 1 04/03/19 17:20 04/09/19 15:24 72-20-8 1p Endrin aldehyde 0.0034 U ug/L 0.096 0.0034 1 04/03/19 17:20 04/09/19 15:24 7421-93-4 1p Endrin ketone 0.0048 U ug/L 0.0096 0.0048 1 04/03/19 17:20 04/09/19 15:24 53494-70-5 1p Heptachlor 0.0059 U ug/L 0.0096 0.0059 1 04/03/19 17:20 04/09/19 15:24 76-44-8 1p Heptachlor epoxide 0.0050 U ug/L 0.0096 0.0050 1 04/03/19 17:20 04/09/19 15:24 1024-57-3 1 p Methoxychlor 0.0092 U ug/L 0.0096 0.0092 1 04/03/19 17:20 04/09/19 15:24 72-43-5 1p Toxaphene 0.24 U ug/L 0.48 0.24 1 04/03/19 17:20 04/09/19 15:24 8001-35-2 1p Surrogates Tetrachloro-m-xylene (S) 130 % 27-124 1 04/03/19 17:20 04/09/19 15:24 877-09-8 S3 Decachlorobiphenyl (S) 60 % 10-132 1 04/03/19 17:20 04/09/19 15:24 2051-24-3 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3010 Iron 2950 ug/L 40.0 9.2 1 04/03/19 07:51 04/03/19 16:42 7439-89-6 Date: 04/11/2019 09:46 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 13 (6- aceAnalytical wvrw.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457300 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 528000 Analysis Method: EPA 6010 QC Batch Method: EPA 3010 Analysis Description: 6010 MET Associated Lab Samples: 35457300001 METHOD BLANK: 2857698 Matrix: Water Associated Lab Samples: 35457300001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Iron ug/L 9.2 U 40.0 9.2 04/03/19 15:56 LABORATORY CONTROL SAMPLE: 2857699 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Iron ug/L 2000 2010 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2857700 2857701 MS MSD 35457297001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual -on ug/L 347 2000 2000 2320 2260 99 96 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/11/2019 09:46 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 13 aceAnalytical www.pacolabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457300 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 528202 Analysis Method: EPA 8081 QC Batch Method: EPA 3510 Analysis Description: 8081 GCS Pesticides Associated Lab Samples: 35457300001 METHOD BLANK: 2858737 Matrix: Water Associated Lab Samples: 35457300001 Parameter Blank Reporting Units Result Limit MDL Analyzed Qualifiers 4,4'-DDD ug/L 0.0089 U 0.010 0.0089 04/09/19 11:33 CU 4,4'-DDE ug/L 0.0050 U 0.010 0.0050 04/09/19 11:33 4,4'-DDT ug/L 0.0050 U 0.010 0.0050 04/09/19 11:33 CU Aldrin ug/L 0.0015 U 0.010 0.0015 04/09/19 11:33 alpha-BHC ug/L 0.0021 U 0.010 0.0021 04/09/19 11:33 beta-BHC ug/L 0.0080 U 0.010 0.0080 04/09/19 11:33 Chlordane (Technical) ug/L 0.18 U 0.50 0.18 04/09/19 11:33 delta-BHC ug/L 0.0048 U 0.010 0.0048 04/09/19 11:33 Dieldrin ug/L 0.0020 U 0.010 0.0020 04/09/19 11:33 Endosulfan I ug/L 0.0051 U 0.010 0.0051 04/09/19 11:33 Endosulfan II ug/L 0.0040 U 0.010 0.0040 04/09/19 11:33 CU Endosulfan sulfate ug/L 0.0062 U 0.10 0.0062 04/09/19 11:33 CU Endrin ug/L 0.0043 U 0.010 0.0043 04/09/19 11:33 Endrin aldehyde ug/L 0.013 I 0.10 0.0036 04/09/19 11:33 CU Endrin ketone ug/L 0.0050 U 0.010 0.0050 04/09/19 11:33 CU gamma-BHC (Lindane) ug/L 0.0022 U 0.010 0.0022 04/09/19 11:33 Heptachlor ug/L 0.0062 U 0.010 0.0062 04/09/19 11:33 Heptachlor epoxide ug/L 0.0052 U 0.010 0.0052 04/09/19 11:33 Methoxychlor ug/L 0.0096 U 0.010 0.0096 04/09/19 11:33 CU Toxaphene ug/L 0.25 U 0.50 0.25 04/09/19 11:33 Decachlorobiphenyl (S) % 53 10-132 04/09/19 11:33 Tetrachloro-m-xylene (S) % 66 27-124 04/09/19 11:33 LABORATORY CONTROL SAMPLE & LCSD: 2858738 2858834 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers 4,4'-DDD ug/L 0.5 0.52 0.49 104 98 67-133 6 40 CH 4,4'-DDE ug/L 0.5 0.47 0.43 94 87 59-125 8 40 4,4'-DDT ug/L 0.5 0.57 0.52 113 104 54-132 8 40 CH Aldrin ug/L 0.5 0.31 0.30 63 60 25-116 5 40 alpha-BHC ug/L 0.5 0.50 0.46 100 92 53-126 9 40 beta-BHC ug/L 0.5 0.56 0.51 112 103 62-130 9 40 delta-BHC ug/L 0.5 0.25 0.23 50 47 35-122 6 40 Dieldrin ug/L 0.5 0.51 0.48 102 96 66-128 6 40 Endosulfan I ug/L 0.5 0.51 0.48 103 96 67-125 6 40 Endosulfan II ug/L 0.5 0.52 0.49 103 98 67-131 6 40 CH Endosulfan sulfate ug/L 0.5 0.54 0.51 108 102 62-127 6 40 CH Endrin ug/L 0.5 0.53 0.49 106 98 66-130 8 40 Endrin aldehyde ug/L 0.5 0.60 0.56 120 113 61-124 6 40 CH Endrin ketone ug/L 0.5 0.57 0.55 115 109 65-132 5 40 CH Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/11/2019 09:46 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 13 aceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457300 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE & LCSD: 2858738 2858834 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers gamma-BHC (Lindane) ug/L 0.5 0.53 0.48 106 96 58-127 10 40 Heptachlor ug/L 0.5 0.39 0.36 79 72 35-123 9 40 Heptachlor epoxide ug/L 0.5 0.51 0.47 102 95 62-125 7 40 Methoxychlor ug/L 0.5 0.56 0.52 111 105 59-135 6 40 CH Decachlorobiphenyl (S) % 48 56 10-132 Tetrachloro-m-xylene (S) % 77 70 27-124 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/11/2019 09:46 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 13 aceAnalytical wwwpacelabs.com QUALIFIERS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457300 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: 528202 [M5] A matrix spike/matrix spike duplicate was not performed for this batch due to insufficient sample volume. ANALYTE QUALIFIERS The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. U Compound was analyzed for but not detected. 1 p A matrix spike/matrix spike duplicate was not performed for this batch due to insufficient sample volume. CH The continuing calibration for this compound is outside of Pace Analytical acceptance limits. The results may be biased high. CU The continuing calibration for this analyte is above laboratory acceptance limits. Analyte was not detected above the reporting limit in any of the associated samples. S3 Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated samples. Date: 04/11/2019 09:46 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 13 aceAnalytical® wwwpacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457300 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach. FL 33064 954-582-4300 Lab ID Sample ID QC Batch Method Analytical QC Batch Analytical Method Batch 35457300001 SCS-MW-1 35457300001 SCS-MW-1 Date: 04/11/2019 09:46 PM EPA 3510 528202 EPA 8081 529083 EPA 3010 528000 EPA 6010 528101 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 13 0#:354573 J ofcdrw'.4rc ' Request Document evant fields must be completed accurately. Section A Section B 35457300 Required Client Information: Required Project Informatic invoice Information: Page : Of Company i±i.gG Report To Crorg Clevenger Attention Address 5751 Miami Lakes Dove. Warn! Lakes FL Copy To Company Narne Address Regulatory Agency C mad r;r;Ievl'n(ir'r '!e:iI111r i.nhii Purchase Order 7' Pace Quote Phone (305) 374-8300 1Fax Project Narne Melrese Golf Course Pace Project Manager State / Location Requested Due Date - Project N 2018-3057 Pace Profiler; FL Requested Analysis Fil cred (Y/N) a*Sample E W - r.v.i WY. cool. In. nq w... OW bv.,r�r WI W.r. ,. win,-, ww SAMPLE ID o�i.in°0° o� One Character per box. wir.• wr' IA-Z. 0-9 1, -1 Ids must be unique `r'o,�� o, .. ATRIX CODE (see cat,d cedes to lee) SAMPLE TYPE (G=GRAB C=COMP) COLLECTED S:. ;1PLE TEMP .AT COLLECTION e OF CONTAINERS Preservatives Z_ r START END ‘2`)_ d EN 0 0 N _ HNO3 U = = O Z Na2S2O3 0 . O Analyses Test _ _ -p---Li - z c _ j ',III- IX DATE TIME DATE TIME 1 Pa 2 - 3 4 5 6 7 8 9 10 11 12 1 ADDITIONAL COMMENTS RELINQUISHED BY I AFFILIATION DATE TIME ACCEPTED BY 1 AFFLlAUON DATE TIME SAMPLE CONDITIONS ���� 1� >�-- 1`! !1, �? �� (4ih11 <t '1'-.)/1a4 /' . , Si rzt....-Z: Received on Ice (YIN) SAMPLER NAME AND SIGNATURE v c c. w �, o v `m o z m o 0 N U } m Z. _ E m N = ? PRINT Name of SAMPLER: - - SIGNATURE of SAMPLER: - DATE Signed: _.. Page 12 of 13 boir-rent Name Sample Coro:! or Upon Receipt For - Document Revised tvlay 30 2018 ace Analytical Project # Project Manager: Client: Thermometer Used State of Origin Cooler #1 Temp.'C°• Z (Visual) ei • 0 (Correction Factor) 0Z (Actual) Cooler#2 Temp.`C (Visual) (Correction Factor) (Actual) Cooler#3 Temp.`C (Visual) (Correction Factor) (Actual) Cooler #4 Temp.`C (Visual) (Correction Factor) (Actual) Cooler #5 Temp.`C (Visual) (Correction Factor) (Actual) Cooler #6 Temp.'C (Visual) (Correction Factor) (Actual) Crs.Jment No LI0 :35457300 PM: CTR CLIENT: 36-EEG Date Courier: Fed Ex = - UPS USPS — Client C Commercial Pace Shipping Method: = First Overnight = Other Due Date: 04/04/19 Issuing Authority Pace Flcr as Qiranp• Office Date and Initials of person: Examining contents: Label: Deliver: pH: Terre /) J Forprotects al! containers verifier': to s6 °C Steals C Samples on coon.^._ ,.c__ L. Samples or , coaling process "E._ • Samples or ice cooling process nes t__ ., • Samples on ,ce, cooling process has begun I— Samples on ice, cooling process nes begun C Samples on ice, cooling process nes begun C Other Priority Overnight 1 Standard Overnight = Ground 11 international Priorty Billing: = Recipient = Sender = Third Party 1 Credit Card = Unknown Tracking # Custody Seal on Cooler/Box Present: L3Yes Seals intact: ^ Yes ! No Ice: Packing Material: EBubble Wrap ❑ Bubble Bags ENone E Other Samples shorted to lab (If Yes, complete) Shorted Date. Comments: Shorted Time Blue Dry None Qty Chain of Custody Present = No EN!A Chain of Custody Filled Out _Yes = No ENIA Relinquished Signature & Sampler Name COC ?l'ess E. No =N/A Samples Arrived within Hold Time 4es = No =N/A Rush TAT requested on COC i iY�es /No =N/A Sufficient Volume js = No :=NIA Correct Containers Used 2<es 1: No =N/A Containers Intact 7es = No =N/A Sample Labels match COC (sample !Ds & date/time of collection) .Zes = No =N/A All containers needing acicioase preserver on cave teen checked - es = No = N/A AU Containers needing preservation are found to be in compliance with EPA recommendation es _ No =N/A Exceptions VOA Cotiform, TOC, O&G Caroamates Preservation Information Preservative Lot #irraoe # Date Time Initials Headspace in VOA Vials' ( >6mm) // E EYesNoTN/A Trip Blank Present =Yes = No -/A Client Notification/ Resolution: Person Contacted Comments/ Resolution (use back for additional comments): Date/Time Project Manager Review Date ye 13 of 13 aceAnalytical® www.pacelabs.com March 08, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451858 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 05, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry, EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 11 7eAnaIyticaI www.pacelabs.com CERTIFICATIONS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451858 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 11 aceAnalytical® wwwpace!abs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451858 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35451858001 SCS-MW-2 Water 03/04/19 14:12 03/05/19 17:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 11 aceAnalytical www.pacelabs.com SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451858 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35451858001 SCS-MW-2 EPA 6010 JWP 3 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 11 aceAnalytical www.pacelabs.com SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451858 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35451858001 SCS-MW-2 EPA 6010 Barium 23.0 ug/L 10.0 03/07/19 20:58 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 11 /'1eAnaIYticaI www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451858 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SCS-MW-2 Lab ID: 35451858001 Collected: 03/04/19 14:12 Received: 03/05/19 17:45 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Arsenic 7.1 U ug/L 10.0 7.1 1 03/07/19 10:29 03/07/19 20:58 7440-38-2 Barium 23.0 ug/L 10.0 0.84 1 03/07/19 10:29 03/07/19 20:58 7440-39-3 Lead 4.6 U ug/L 10.0 4.6 1 03/07/19 10:29 03/07/19 20:58 7439-92-1 Date: 03/08/2019 01:08 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 11 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451858 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521178 Analysis Method: EPA 6010 QC Batch Method: EPA3010 Analysis Description: 6010 MET Associated Lab Samples: 35451858001 METHOD BLANK: 2814528 Matrix: Water Associated Lab Samples: 35451858001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic ug/L 7.1 U 10.0 7.1 03/07/19 20:40 Barium ug/L 0.84 U 10.0 0.84 03/07/19 20:40 Lead ug/L 4.6 U 10.0 4.6 03/07/19 20:40 LABORATORY CONTROL SAMPLE: 2814529 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic ug/L 250 251 100 80-120 Barium ug/L 250 250 100 80-120 Lead ug/L 250 260 104 80-120 `/IATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2814530 2814531 MS MSD 35451859001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L 7.1 U 250 250 259 252 104 101 75-125 3 20 Barium ug/L 11.5 250 250 266 260 102 99 75-125 2 20 Lead ug/L 4.6 U 250 250 260 255 104 102 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/08/2019 01:08 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 11 ceAnalytical® www.pacelabs.com QUALIFIERS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451858 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS U Compound was analyzed for but not detected. Date: 03/08/2019 01:08 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 11 aceAnalytical® www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451858 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID QC Batch Method Analytical QC Batch Analytical Method Batch 35451858001 SCS-MW-2 Date: 03/08/2019 01:08 PM EPA 3010 521178 EPA 6010 521271 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 11 eAnalytical CHAIN-OF-CW(14 35451858 The Chain-of-Custc ed accurately. SectionA Section B 1111111111111111111111 ed Client Information: Required Protect Information: Required Page : I Of Company EESG Environmental Services, LLC Report To - — _ r f''�i4r"� Vd -.. 35451858 Address 5751 Miami Lakes Dr Copy To. Cce,f, • C� C`ej L Hialeah, FL 33014 J �,Je��' Address. Regulatory Agency Email. tpg.000y.,M40 (` pF,,eLi,,. - t•c, .Purchase Order # Pace Quote Phone (305)374-8300 �, ry Project Name: ,v`�'r , l-TCr�"t `,' ..,L.A Pace Project Manager christina.raschke gpacelabs com, State !Location Requested Due Date. S-j,,' . .e TV Project #: 2018-3057 Fare. Profile # FL Requested Analysis Filtered CON) MATRIX CODE id4TRIX CODE (see valid codes to lefl) 1 SAMPLE TYPE (G=GRAB C=COMP) COLLECTED SAMPLE TEMP AT COLLECTION j # OF CONTAINERS Preservatives Z >' : Dunking Wafer DW Water WT Waalr Water WW Pro SAMPLE ID o"usam OL START END Unpreserved H2SO4 NaOH Methanol Other Analyses Test d O O IResidual Chlorine (Y/N) 4t I L F One Character per box. Wipe WP Other OT Sample Ids must be unique n;;ue TS DATE TIME DATE TIME OZ _ U = ed 01 en m Z 1 cjC j - !\''\l, — �?�, v i �i\ij j" �;'— g •,% /' �(/ /�, 2 3 4 5 6 7 8 9 10 11 12 ADDITIONAL COMMENTS: - :,- RELINQUISHED BY (AFFILIATION ': DATE , -•.TIME ACCEPTED BY !AFFILIATION DATE • TIME . - SAMPLE CONDITIONS ! �--� .,_ =-�-, ' �Ir ��:- ���r `� i _3C /.!% ( >/ / a'�'�' o t,b - y / / - • ' , araL (� -r.._. - i-\ ; { P ' tiz .. e ��" J l" i-5 c o �. � t " `i.. / SAMPLER NAME AND SIGNATURE Received on Ice (YIN) use y Sealed Cooler (YM) ? c PRINT Name of SAMPLER: ) I . 1, (! ! l/.' U c SIGNATURE of SAMPLER: �' i' ) O G. DATE Signed: I /1r I, Cr W Thermometer Used State ofArigi Cooler #1 Temp.'C f9 -Pace Analytical Document Name Sample Condition Upon Receipt Form Document Revised May 30 2018 Document No F-FL-C-007 rev 13 Issuing Authority Pace Honda Quality Office Wiz 3r451 55 Project #PM: CTR Project Manager 36-EEC Client: I Date3).5) IC P (Visual) Cooler#2 Temp.°C Ini J (Visual) Cooler #3 Temp.'C 5e a(Visual) Cooler #4 Temp.'C (Visual) Cooler #5 Temp. ° C Cooler #6 Temp.'C (Visual) (Visual) Due Date: 03/12/19 Time: Date and Initials oft Examining contents: Label: Deliver; pH: C For WV projects, all containers verified to <6 `C 0.0 (Correction Factor) 3, 9 (Actual) 0 0 (Correction Factor) (o 0 (Actual) 0 (Correction Factor) 5(Actual) (Correction Factor) (Actual) Courier: Li Fed Ex E UPS (Correction Factor) (Correction Factor) (Actual) (Actual) USPS Client C CommerciaJPace Shipping Method: = First Overnight - Priority Overnight _ Standard Overnight Other Billing: Tracking # Recipient _ Sender Custody Seal on Cooler/Box Present: Packing Material: DBubble Wrap 4 Samples shorted to lab (If Yes, complete) LT Third Party 0 ubble Bags LiNone Shorted Date Credit Card Seals intact: L� Yes Other • Ground C C C Samples on ice, cooling process has begun Samples on ice, cooling process has beoun Samples on ice, cooling process has begun Samples on ice, cooling process has begun Samples on ice_ cooling process has begun Samples on ice ccoling process has begun C Other International Pnority Unknown Icy: Wet ,clue Dry None Shorted Time ety: Chain of Custody Present fl es _ No ❑N/A Chain of Custody Filled Out es E No ON/A Relinquished Signature & Sampler Name COC e CI No EN/A Samples Arrived within Hold Time �s Yes No ON/A Rush TAT requested on COC Yes Vo -N/A Sufficient Volumes E. No �°N/A Correct Containers Used _ es - No ❑N/A Containers Intact S E. No =,N/A Sample Labels match COC (sample IDs & date/time of collection) .) es - No 'Li N/A All containers needing acid/base preservation have been checked. sCYes All Containers needing preservation are found to be in compliance with EPA recommendation s Exceptions: VOA, Cohform, TOC, O&G, Cerbamates LE NoN/A = No =N/A Preservation Informal on Preservative Lot #rrrace # t Date. i i Initials Headspace in VOA Vials? (>6mm): -Yes - No Trip Blank Present: _•Yes - No/ Client Notification/ Resolution: Person Contacted: Comments/ Resolution (use back for additional comments): Date/Time Project Manager Review: Date: Page 11 of 11 aceAnalytical www.pacelabs.com March 08, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451851 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 05, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry, EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 13 aceAnalytical www.pacelabs.com CERTIFICATIONS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451851 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 13 aceAnalytical wwwpacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451851 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach. FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35451851001 SCS-MW-2 Water 03/04/19 14:12 03/05/19 17:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 13 aceAnalytical® www.pacelabs.com SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451851 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35451851001 SCS-MW-2 EPA 6010 JWP 2 PASI-O EPA 300.0 JDM 2 PASI-O EPA 350.1 MAJ 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 13 aceAnalytical0 www.pacelabs.com SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451851 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters 35451851001 EPA 6010 EPA 350.1 Result SCS-MW-2 Iron Nitrogen, Ammonia Units Report Limit Analyzed Qualifiers 208 ug/L 1.1 mg/L REPORT OF LABORATORY ANALYSIS 40.0 03/07/19 20:58 0.050 03/06/19 08:30 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 13 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451851 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SCS-MW-2 Lab ID: 35451851001 Collected: 03/04/19 14:12 Received: 03/05/19 17:45 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Aluminum 30.7 U ug/L 100 30.7 1 03/07/19 10:29 03/07/19 20:58 7429-90-5 Iron 208 ug/L 40.0 9.2 1 03/07/19 10:29 03/07/19 20:58 7439-89-6 300.0 IC Anions Analytical Method: EPA 300.0 Nitrate as N 0.025 U mg/L 0.050 0.025 1 03/06/19 09:11 14797-55-8 Nitrite as N 0.025 U mg/L 0.050 0.025 1 03/06/19 09:11 14797-65-0 350.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia 1.1 mg/L 0.050 0.035 1 03/06/19 08:30 7664-41-7 Date: 03/08/2019 12:41 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 13 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451851 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521178 Analysis Method: EPA 6010 QC Batch Method: EPA 3010 Analysis Description: 6010 MET Associated Lab Samples: 35451851001 METHOD BLANK: 2814528 Matrix: Water Associated Lab Samples: 35451851001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Aluminum ug/L 30.7 U 100 Iron ug/L 9.2 U 40.0 30.7 03/07/19 20:40 9.2 03/07/19 20:40 LABORATORY CONTROL SAMPLE: 2814529 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Aluminum ug/L 2500 2520 101 80-120 Iron ug/L 2500 2610 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2814530 2814531 MS MSD 35451859001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 30.7 U 2500 2500 2590 2530 103 101 75-125 2 20 Iron ug/L 369 2500 2500 2980 2910 105 102 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/08/2019 12:41 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 13 _ aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451851 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 520750 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 35451851001 METHOD BLANK: 2812105 Matrix: Water Associated Lab Samples: 35451851001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrate as N mg/L 0.025 U 0.050 0.025 03/06/19 11:46 Nitrite as N mg/L 0.025 U 0.050 0.025 03/06/19 11:46 LABORATORY CONTROL SAMPLE: 2812106 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/L 5 5.0 100 90-110 Nitrite as N mg/L 5 4.9 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2812128 2812129 MS MSD 35451851001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrate as N mg/L 0.025 U 5 5 4.8 4.8 96 96 90-110 1 20 Nitrite as N mg/L 0.025 U 5 5 4.9 4.9 98 97 90-110 1 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/08/2019 12:41 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 13 aceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451851 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 520730 Analysis Method: EPA 350.1 QC Batch Method: EPA 350.1 Analysis Description: 350.1 Ammonia Associated Lab Samples: 35451851001 METHOD BLANK: 2812044 Matrix: Water Associated Lab Samples: 35451851001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Ammonia mg/L 0.035 U 0.050 0.035 03/06/19 08:14 LABORATORY CONTROL SAMPLE: 2812045 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 1 1.1 105 90-110 MATRIX SPIKE SAMPLE: 2812047 35451845001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 0.58 1 1.6 103 90-110 SAMPLE DUPLICATE: 2812046 35451845001 Dup Parameter Units Result Result RPD Max RPD Qualifiers Nitrogen, Ammonia mg/L 0.58 0.58 0 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/08/2019 12:41 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 13 ace Analytical www.pacelabs.com QUALIFIERS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451851 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS U Compound was analyzed for but not detected. Date: 03/08/2019 12:41 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 13 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451851 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID QC Batch Method Analytical QC Batch Analytical Method Batch 35451851001 SCS-MW-2 EPA 3010 521178 EPA 6010 521271 35451851001 SCS-MW-2 EPA 300.0 520750 35451851001 SCS-MW-2 EPA 350.1 520730 Date: 03/08/2019 12:41 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 13 ' FraceMalyrical CHAIN-OF-C Wu# : 35451351 ..... .' i tic �iiau ru ri,umui I 111 a aCGUl alely. Section A Section 8 S Required Client Information: Required Project Information: le III 35451851 I Ell 111111 III Page 1 Of Company EE&G Environmental Services, I.LC Report To AA,c....,,ej A,,., AI Address 5751 Miami Lakes Dr. Copy To: ai• Company Name: Hialeah, FL 33014 vr Address Regulatory Agency Email Purchase Order 4. Pace Quote. Phone (305)374-831M ax CJ Project Name: Lkrg2je, lu o p - C,-.0r5e Pace Project Manager. christina.raschke@pacelabs.com. - State / Location • Requested Due Date 1,-= ' % -Pace 7-�- � � . t Project #: 2018-305/ Profile tl. FL Roqu t al Fil °rod (Y/N) MATRIX CODE MATRIX CODE (see valid codes to left) 'SAMPLE TYPE (G=GRAR C=CO).'P) COLLECTED SAMPLE TEMP AT COLLECTION d OF CONTAINERS Preservatives Z_ 5.--J � _ I) Drinking Water DW Water Wr ( in W WMOPW Product P SAMPLE ID soomo se �rr ` START END Unpreserved H2SO4 HNO3 HOeN Na2S203 Analyses Test 8260 VOC PAH by 8270 SIM TRPH FL -PRO Pesticides 8081(1.:,,,,, Pesticides 8141{ , Herbicides 8151(6,L .l'� CV-i co 0 0 6010 Ba, Cd, Cr, Se, Ag, 7470 Hg crt,, A5I G-t .vw' ��) —{f� �] .:,z Residual Chlorine (Y/N) lit W I- WipWP One Character per box. e (A-Z, 0-9 1 , -) nu AR Ids must be unique assure Ts DATE TIME DATE TIME U = i 2'0 'a-, t 1 y 2%2 3 4 5 6 7 8 9 10 11 12 ADDITIONAL COMMENTS RELINQUISHED BY 1 AFFILIATIOty DATE TIME -A CEPTED BY I AAFFFIUATION . - DATE TIME - SAMPLE CONDITIONS ' i f� L -`=-r, y ` `-?' -iO�' `i I l:= .-i` ( 7,i ,f7/ i (A. I) ` i! r` y r �• K2 y : 3 ) i�4� car c i �% 1 SAMPLER NAME AND SIGNATURE 1 TEMP in C Received on Ice (Y/N) usto y Sealed Cooler Y/N)_ Samples Intact (YIN) ��PRINT Name of SAMPLER: t L C.L..-.z/� \ L— 1< , SIGNATURE of SAMPLER:� /. / / (ATE Signed: -/4/ // ` 0 CV 0) ca CeArralytiCal Sa—,L t _., o,:c- „-.a" .,�- ._ -. 2,ocurrent riewsec Way 30 2018 1 ipa ea Document No -FL_C_OC7 rev "_ Issuing Authority Pace Fiance Quality Office 11.11.11 wvi:35451851 PM: CTR Project #CLIENT: 36-EEG Project Manager. Client: Thermometer Used State of Cooler #1 Temp.'C (Visual) O. 0 (Correction Factor) ^1. U (Actual) Cooler #2 Temp.'C (Visual) O. 0 (Correction Factor) (0 0 (Actual) Cooler #3 Temp.'C 5 5 (Visual) 0 _0 (Correction Factor) 5.5 (Actual) Cooler #4 Temp.'C (Visual) (Correction Factor) (Actual) i Due Date: 03/12/19 Cooler #5 Temp.`C (Visual) (Correction Factor) Cooler #6 Temp.'C (Visual) (Correction Factor) (Actual) (Actual) Courier: — Fed Ex — UPS USPS — Client L Commercia — Pace Shipping Method: - First Overnight 7 Priority Overnight - Other - Recipient Billing: Tracking # Custody Seal on Cooler/Box Present: Sender Time 1:=H- Label: Deliveri \k, For p•c cts al;..on:a.r.ers ._.if.e to S5'C E r Date and Initials of p Examining content: Initials. J Samples or+ e ccoirc process ras C__un Samoies ce _co irc z s ras te r, Se.- ole_ on . _ ,ess ^....ttegur Samo:es c' :Ce c... crooess has tegun Samples on .ce coo = crocess has begun Samples o cooking orocess has begch Other Standard Overnight _ Ground - International Priority - Third Party LT Credit Card Seals intact: _ Ye Packing Material: —Bubble Wrap ubble Bags ENone _Other Samples shorted to lab (If Yes, complete) Shorted Date Comments: Unknown Shorted Tmte Chain of Custody Present - es - No -N/A Chain of Custody Filled Out s - No 11N!A Relinquished Signature & Sampler Name COC e. _ No _N/A Samples Arrived within Hold Time Yes's = No N/A Rush TAT requested on COC -YesN/A Sufficient Volume , _ es _ No -N/A Correct Containers Used s - No -N/A Containers Intact s ii No -N/A Sample Labels match COC ;sample IDs & date'time of collection) /_ res - No -N(A All containers needing acid -base preservation have teen checked ads - No -N/P. All Containers needing preservation are found to be in compliance with EPA recommendation Ytss - No .-N!A Exceptions VGA, Coliform TOC G&G, Caroamates Preservation Infor na: co Preservative#r rt a Lott#; irac=_ , Date Init a s Headspace in VOA Vials? ( >6mm). =Yes - No/ Trip Blank Present. =Yes 1 No ,DNFC Client Notification/ Resolution: Person Contacted Comments/ Resolution (use back for additional comments): Date/Time Project Manager Review Date Page 13 of 13 aceAnalytical www.pacelabs.com March 19, 2019 0 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451860 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 05, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Some analyses have been subcontracted outside of the Pace Network. The subcontracted laboratory report has been attached. If you have any questions concerning this report, please feel free to contact me. Sincerely, Jeff Baylor for Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry, EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 37 PaceAnalytical ® J wwwpacelabs.com CERTIFICATIONS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451860 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 37 aceAnalytical www.pacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451860 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach. FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35451860001 SCS-MW-2 Water 03/04/19 14:12 03/05/19 17:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 37 aceAnalytical® www.pacelabs.com SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451860 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35451860001 SCS-MW-2 EPA 8081 AER 22 PASI-O FL -PRO RJR 3 PASI-O EPA6010 JWP 4 PASI-O EPA 7470 AMS 1 PASI-O EPA 8270 by SIM CB1 20 PASI-O EPA8260 BTN 70 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 37 (a SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451860 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35451860001 SCS-MW-2 EPA 8081 Endosulfan I 0.014 ug/L 0.0096 03/14/19 12:57 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 37 PaceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451860 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SCS-MW-2 Parameters Lab ID: 35451860001 Collected: 03/04/19 14:12 Received: 03/05/19 17:45 Matrix: Water Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8081 GCS Pesticides Aldrin alpha-BHC beta-BHC delta-BHC gamma-BHC (Lindane) Chlordane (Technical) 4,4'-DDD 4,4'-DDE 4,4'-DDT Dieldrin Endosulfan I Endosulfan II Endosulfan sulfate Endrin Endrin aldehyde Endrin ketone Heptachlor Heptachlor epoxide Methoxychlor Toxaphene Surrogates Tetrachloro-m-xylene (S) Decachlorobiphenyl (S) FL -PRO Water, Low Volume Petroleum Range Organics Surrogates o-Terphenyl (S) N-Pentatriacontane (S) 6010 MET ICP Cadmium Chromium Selenium Silver 7470 Mercury Mercury 8270 MSSV PAHLV by SIM Acenaphthene Acenaphthylene Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Date: 03/19/2019 05:18 PM Analytical Method: EPA 8081 Preparation Method: EPA 3510 0.0014 U ug/L 0.0096 0.0014 1 03/07/19 11:22 03/14/19 12:57 0.0020 U ug/L 0.0096 0.0020 1 03/07/19 11:22 03/14/19 12:57 0.0077 U ug/L 0.0096 0.0077 1 03/07/19 11:22 03/14/19 12:57 0.0046 U ug/L 0.0096 0.0046 1 03/07/19 11:22 03/14/19 12:57 0.0021 U ug/L 0.0096 0.0021 1 03/07/19 11:22 03/14/19 12:57 0.17 U ug/L 0.48 0.17 1 03/07/19 11:22 03/14/19 12:57 0.0086 U ug/L 0.0096 0.0086 1 03/07/19 11:22 03/14/19 12:57 0.0048 U ug/L 0.0096 0.0048 1 03/07/19 11:22 03/14/19 12:57 0.0048 U ug/L 0.0096 0.0048 1 03/07/19 11:22 03/14/19 12:57 0.0019 U ug/L 0.0096 0.0019 1 03/07/19 11:22 03/14/19 12:57 0.014 ug/L 0.0096 0.0049 1 03/07/19 11:22 03/14/19 12:57 0.0039 U ug/L 0.0096 0.0039 1 03/07/19 11:22 03/14/19 12:57 0.0060 U ug/L 0.096 0.0060 1 03/07/19 11:22 03/14/19 12:57 0.0041 U ug/L 0.0096 0.0041 1 03/07/19 11:22 03/14/19 12:57 0.0035 U ug/L 0.096 0.0035 1 03/07/19 11:22 03/14/19 12:57 0.0048 U ug/L 0.0096 0.0048 1 03/07/19 11:22 03/14/19 12:57 0.0060 U ug/L 0.0096 0.0060 1 03/07/19 11:22 03/14/19 12:57 0.0050 U ug/L 0.0096 0.0050 1 03/07/19 11:22 03/14/19 12:57 0.0093 U ug/L 0.0096 0.0093 1 03/07/19 11:22 03/14/19 12:57 0.24 U ug/L 0.48 0.24 1 03/07/19 11:22 03/14/19 12:57 309-00-2 319-84-6 319-85-7 319-86-8 58-89-9 57-74-9 72-54-8 72-55-9 50-29-3 60-57-1 959-98-8 33213-65-9 1031-07-8 72-20-8 7421-93-4 53494-70-5 76-44-8 1024-57-3 72-43-5 8001-35-2 72 % 27-124 1 03/07/19 11:22 03/14/19 12:57 877-09-8 72 % 10-132 1 03/07/19 11:22 03/14/19 12:57 2051-24-3 Analytical Method: FL -PRO Preparation Method: EPA 3510 0.76 U mg/L 0.95 0.76 1 03/07/19 09:10 03/07/19 17:02 77 % 66-139 1 03/07/19 09:10 03/07/19 17:02 84-15-1 80 % 42-159 1 03/07/19 09:10 03/07/19 17:02 630-07-09 Analytical Method: EPA 6010 Preparation Method: EPA 3010 0.33 U ug/L 1.0 0.33 1 03/07/19 10:29 03/07/19 20:58 1.7 U ug/L 5.0 1.7 1 03/07/19 10:29 03/07/19 20:58 8.5 U ug/L 15.0 8.5 1 03/07/19 10:29 03/07/19 20:58 1.0 U ug/L 5.0 1.0 1 03/07/19 10:29 03/07/19 20:58 Analytical Method: EPA 7470 Preparation Method: EPA 7470 0.10 U ug/L 7440-43-9 7440-47-3 7782-49-2 7440-22-4 0.20 0.10 1 03/07/19 10:25 03/08/19 16:12 7439-97-6 Analytical Method: EPA8270 by SIM Preparation Method: EPA3510 0.040 U ug/L 0.030 U ug/L 0.043 U ug/L 0.055 U ug/L 0.12 U ug/L 0.027 U ug/L 0.50 0.040 1 03/07/19 02:41 03/07/19 11:56 83-32-9 0.50 0.030 1 03/07/19 02:41 03/07/19 11:56 208-96-8 0.50 0.043 1 03/07/19 02:41 03/07/19 11:56 120-12-7 0.10 0.055 1 03/07/19 02:41 03/07/19 11:56 56-55-3 0.20 0.12 1 03/07/19 02:41 03/07/19 11:56 50-32-8 0.10 0.027 1 03/07/19 02:41 03/07/19 11:56 205-99-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 37 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451860 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SCS-MW-2 Parameters Lab ID: 35451860001 Collected: 03/04/19 14:12 Received: 03/05/19 17:45 Matrix: Water Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8270 MSSV PAHLV by SIM Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3510 Benzo(g,h,i)perylene 0.15 U ug/L 0.50 0.15 1 03/07/19 02:41 03/07/19 11:56 191-24-2 Benzo(k)fluoranthene 0.16 U ug/L 0.50 0.16 1 03/07/19 02:41 03/07/19 11:56 207-08-9 Chrysene 0.026 U ug/L 0.50 0.026 1 03/07/19 02:41 03/07/19 11:56 218-01-9 Dibenz(a,h)anthracene 0.13 U ug/L 0.15 0.13 1 03/07/19 02:41 03/07/19 11:56 53-70-3 Fluoranthene 0.018 U ug/L 0.50 0.018 1 03/07/19 02:41 03/07/19 11:56 206-44-0 Fluorene 0.088 U ug/L 0.50 0.088 1 03/07/19 02:41 03/07/19 11:56 86-73-7 Indeno(1,2,3-cd)pyrene 0.12 U ug/L 0.15 0.12 1 03/07/19 02:41 03/07/19 11:56 193-39-5 1-Methylnaphthalene 0.19 U ug/L 2.0 0.19 1 03/07/19 02:41 03/07/19 11:56 90-12-0 2-Methylnaphthalene 0.68 U ug/L 2.0 0.68 1 03/07/19 02:41 03/07/19 11:56 91-57-6 Naphthalene 0.29 U ug/L 2.0 0.29 1 03/07/19 02:41 03/07/19 11:56 91-20-3 Phenanthrene 0.16 U ug/L 0.50 0.16 1 03/07/19 02:41 03/07/19 11:56 85-01-8 Pyrene 0.032 U ug/L 0.50 0.032 1 03/07/19 02:41 03/07/19 11:56 129-00-0 Surrogates 2-Fluorobiphenyl (S) 69 % 33-82 1 03/07/19 02:41 03/07/19 11:56 321-60-8 p-Terphenyl-d14 (S) 102 % 49-104 1 03/07/19 02:41 03/07/19 11:56 1718-51-0 8260 MSV Analytical Method: EPA 8260 1.1,1.2-Tetrachloroethane 0.32 U ug/L 1.0 0.32 1 03/06/19 15:16 630-20-6 ,1,1-Trichloroethane 0.30 U ug/L 1.0 0.30 1 03/06/19 15:16 71-55-6 1,1,2,2-Tetrachloroethane 0.20 U ug/L 0.50 0.20 1 03/06/19 15:16 79-34-5 1,1,2-Trichloroethane 0.30 U ug/L 1.0 0.30 1 03/06/19 15:16 79-00-5 1.1-Dichloroethane 0.34 U ug/L 1.0 0.34 1 03/06/19 15:16 75-34-3 1,1-Dichloroethene 0.27 U ug/L 1.0 0.27 1 03/06/19 15:16 75-35-4 1,1-Dichloropropene 0.31 U ug/L 1.0 0.31 1 03/06/19 15:16 563-58-6 1,2,3-Trichlorobenzene 0.34 U ug/L 1.0 0.34 1 03/06/19 15:16 87-61-6 1,2,3-Trichloropropane 1.1 U ug/L 2.0 1.1 1 03/06/19 15:16 96-18-4 1,2,3-Trimethylbenzene 0.17 U ug/L 1.0 0.17 1 03/06/19 15:16 526-73-8 1,2,4-Trichlorobenzene 0.32 U ug/L 1.0 0.32 1 03/06/19 15:16 120-82-1 1,2,4-Trimethylbenzene 0.24 U ug/L 1.0 0.24 1 03/06/19 15:16 95-63-6 1,2-Dichlorobenzene 0.29 U ug/L 1.0 0.29 1 03/06/19 15:16 95-50-1 1,2-Dichloroethane 0.27 U ug/L 1.0 0.27 1 03/06/19 15:16 107-06-2 1,2-Dichloropropane 0.23 U ug/L 1.0 0.23 1 03/06/19 15:16 78-87-5 1,3,5-Trimethylbenzene 0.24 U ug/L 1.0 0.24 1 03/06/19 15:16 108-67-8 1,3-Dichlorobenzene 0.33 U ug/L 1.0 0.33 1 03/06/19 15:16 541-73-1 1,3-Dichloropropane 0.26 U ug/L 1.0 0.26 1 03/06/19 15:16 142-28-9 1,4-Dichlorobenzene 0.28 U ug/L 1.0 0.28 1 03/06/19 15:16 106-46-7 2,2-Dichloropropane 0.59 U ug/L 1.0 0.59 1 03/06/19 15:16 594-20-7 2-Butanone (MEK) 7.5 U ug/L 10.0 7.5 1 03/06/19 15:16 78-93-3 2-Chloroethylvinyl ether 1.4 U ug/L 40.0 1.4 1 03/06/19 15:16 110-75-8 c2 2-Chlorotoluene 0.28 U ug/L 1.0 0.28 1 03/06/19 15:16 95-49-8 2-Hexanone 0.85 U ug/L 10.0 0.85 1 03/06/19 15:16 591-78-6 4-Chlorotoluene 0.22 U ug/L 1.0 0.22 1 03/06/19 15:16 106-43-4 4-Methyl-2-pentanone (MIBK) 0.32 U ug/L 10.0 0.32 1 03/06/19 15:16 108-10-1 Acetone 5.3 U ug/L 20.0 5.3 1 03/06/19 15:16 67-64-1 Acetonitrile 24.5 U ug/L 40.0 24.5 1 03/06/19 15:16 75-05-8 Benzene 0.30 U ug/L 1.0 0.30 1 03/06/19 15:16 71-43-2 Date: 03/19/2019 05:18 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 37 aceAnalytical Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451860 Sample: SCS-MW-2 Parameters Lab ID: 35451860001 Collected: 03/04/19 14:12 Received: 03/05/19 17:45 Matrix: Water Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Dibromochloromethane Dibromomethane Dichlorodifluoromethane Ethylbenzene lodomethane Isopropylbenzene (Cumene) Methyl-tert-butyl ether Methylene Chloride Styrene Tetrachloroethene Toluene Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene m&p-Xylene n-Butylbenzene n-Propylbenzene o-Xylene p-Isopropyltoluene sec-Butylbenzene tert-Butylbenzene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 03/19/2019 05:18 PM Analytical Method: EPA 8260 0.21 U ug/L 1.0 0.21 1 0.37 U ug/L 1.0 0.37 1 0.19 U ug/L 0.60 0.19 1 2.6 U ug/L 3.0 2.6 1 4.0 U ug/L 5.0 4.0 1 0.45 U ug/L 10.0 0.45 1 1.1 U ug/L 3.0 1.1 1 0.35 U ug/L 1.0 0.35 1 3.7 U ug/L 10.0 3.7 1 0.32 U ug/L 1.0 0.32 1 0.97 U ug/L 1.0 0.97 1 0.45 U ug/L 2.0 0.45 1 0.68 U ug/L 2.0 0.68 1 0.26 U ug/L 1.0 0.26 1 0.30 U ug/L 1.0 0.30 1 9.3 U ug/L 10.0 9.3 1 0.30 U ug/L 1.0 0.30 1 0.51 U ug/L 2.0 0.51 1 2.0 U ug/L 5.0 2.0 1 0.26 U ug/L 1.0 0.26 1 0.38 U ug/L 1.0 0.38 1 0.33 U ug/L 1.0 0.33 1 0.36 U ug/L 1.0 0.36 1 0.35 U ug/L 1.0 0.35 1 0.19 U ug/L 10.0 0.19 1 0.39 U ug/L 1.0 0.39 1 2.1 U ug/L 5.0 2.1 1 0.27 U ug/L 1.0 0.27 1 0.17 U ug/L 0.50 0.17 1 2.1 U ug/L 4.0 2.1 1 0.20 U ug/L 1.0 0.20 1 0.37 U ug/L 1.0 0.37 1 0.27 U ug/L 1.0 0.27 1 0.31 U ug/L 5.0 0.31 1 0.17 U ug/L 1.0 0.17 1 0.26 U ug/L 1.0 0.26 1 0.23 U ug/L 1.0 0.23 1 0.17 U ug/L 0.50 0.17 1 89 % 70-130 1 105 % 70-130 1 101 % 70-130 1 REPORT OF LABORATORY ANALYSIS 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 03/06/19 15:16 108-86-1 74-97-5 75-27-4 75-25-2 74-83-9 v2 75-15-0 v1 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3 v2 124-48-1 74-95-3 75-71-8 100-41-4 74-88-4 v2 98-82-8 1634-04-4 75-09-2 100-42-5 127-18-4 108-88-3 79-01-6 75-69-4 108-05-4 75-01-4 1330-20-7 156-59-2 10061-01-5 179601-23-1 104-51-8 103-65-1 95-47-6 99-87-6 135-98-8 98-06-6 156-60-5 10061-02-6 03/06/19 15:16 460-00-4 03/06/19 15:16 17060-07-0 03/06/19 15:16 2037-26-5 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 37 QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451860 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521100 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 35451860001 METHOD BLANK: 2814165 Matrix: Water Associated Lab Samples: 35451860001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L 0.10 U 0.20 0.10 03/08/1915:31 LABORATORY CONTROL SAMPLE: 2814166 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2 1.9 96 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2814167 2814168 MS MSD 35451633001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual lercury ug/L 0.10 U 2 2 1.7 1.8 86 88 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/19/2019 05:18 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 37 /r PaceAnalytical www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451860 QC Batch: 521178 Analysis Method: EPA 6010 QC Batch Method: EPA 3010 Analysis Description: 6010 MET Associated Lab Samples: 35451860001 METHOD BLANK: 2814528 Matrix: Water Associated Lab Samples: 35451860001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Cadmium ug/L 0.33 U 1.0 0.33 03/07/19 20:40 Chromium ug/L 1.7 U 5.0 1.7 03/07/19 20:40 Selenium ug/L 8.5 U 15.0 8.5 03/07/19 20:40 Silver ug/L 1.0 U 5.0 1.0 03/07/19 20:40 LABORATORY CONTROL SAMPLE: 2814529 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Cadmium ug/L 25 25.7 103 80-120 Chromium ug/L 250 255 102 80-120 Selenium ug/L 250 261 104 80-120 Silver ug/L 25 24.1 96 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2814530 2814531 MS MSD 35451859001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Cadmium ug/L 0.33 U 25 25 26.0 25.4 104 101 75-125 2 20 Chromium ug/L 1.7 U 250 250 262 252 105 101 75-125 4 20 Selenium ug/L 8.5 U 250 250 266 253 106 101 75-125 5 20 Silver ug/L 1.0 U 25 25 24.5 23.7 98 95 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/19/2019 05:18 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 37 aceAnalytkal® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451860 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 520786 Analysis Method: EPA 8260 QC Batch Method: EPA 8260 Analysis Description: 8260 MSV Associated Lab Samples: 35451860001 METHOD BLANK: 2812236 Matrix: Water Associated Lab Samples: 35451860001 Parameter Blank Reporting Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L 0.32 U 1.0 0.32 03/06/19 09:44 1,1,1-Trichloroethane ug/L 0.30 U 1.0 0.30 03/06/19 09:44 1,1,2,2-Tetrachloroethane ug/L 0.20 U 0.50 0.20 03/06/19 09:44 1,1,2-Trichloroethane ug/L 0.30 U 1.0 0.30 03/06/19 09:44 1,1-Dichloroethane ug/L 0.34 U 1.0 0.34 03/06/19 09:44 1,1-Dichloroethene ug/L 0.27 U 1.0 0.27 03/06/19 09:44 1,1-Dichloropropene ug/L 0.31 U 1.0 0.31 03/06/19 09:44 1,2,3-Trichlorobenzene ug/L 0.34 U 1.0 0.34 03/06/19 09:44 1,2,3-Trichloropropane ug/L 1.1 U 2.0 1.1 03/06/19 09:44 1,2,3-Trimethylbenzene ug/L 0.17 U 1.0 0.17 03/06/19 09:44 1,2,4-Trichlorobenzene ug/L 0.32 U 1.0 0.32 03/06/19 09:44 1,2,4-Trimethylbenzene ug/L 0.24 U 1.0 0.24 03/06/19 09:44 1,2-Dichlorobenzene ug/L 0.29 U 1.0 0.29 03/06/19 09:44 1,2-Dichloroethane ug/L 0.27 U 1.0 0.27 03/06/19 09:44 ,2-Dichloropropane ug/L 0.23 U 1.0 0.23 03/06/19 09:44 1,3,5-Trimethylbenzene ug/L 0.24 U 1.0 0.24 03/06/19 09:44 1,3-Dichlorobenzene ug/L 0.33 U 1.0 0.33 03/06/19 09:44 1,3-Dichloropropane ug/L 0.26 U 1.0 0.26 03/06/19 09:44 1,4-Dichlorobenzene ug/L 0.28 U 1.0 0.28 03/06/19 09:44 2,2-Dichloropropane ug/L 0.59 U 1.0 0.59 03/06/19 09:44 2-Butanone (MEK) ug/L 7.5 U 10.0 7.5 03/06/19 09:44 2-Chloroethylvinyl ether ug/L 1.4 U 40.0 1.4 03/06/19 09:44 2-Chlorotoluene ug/L 0.28 U 1.0 0.28 03/06/19 09:44 2-Hexanone ug/L 0.85 U 10.0 0.85 03/06/19 09:44 4-Chlorotoluene ug/L 0.22 U 1.0 0.22 03/06/19 09:44 4-Methyl-2-pentanone (MIBK) ug/L 0.32 U 10.0 0.32 03/06/19 09:44 Acetone ug/L 5.3 U 20.0 5.3 03/06/19 09:44 Acetonitrile ug/L 24.5 U 40.0 24.5 03/06/19 09:44 Benzene ug/L 0.30 U 1.0 0.30 03/06/19 09:44 Bromobenzene ug/L 0.21 U 1.0 0.21 03/06/19 09:44 Bromochloromethane ug/L 0.37 U 1.0 0.37 03/06/19 09:44 Bromodichloromethane ug/L 0.19 U 0.60 0.19 03/06/19 09:44 Bromoform ug/L 2.6 U 3.0 2.6 03/06/19 09:44 Bromomethane ug/L 4.0 U 5.0 4.0 03/06/19 09:44 Carbon disulfide ug/L 0.45 U 10.0 0.45 03/06/19 09:44 Carbon tetrachloride ug/L 1.1 U 3.0 1.1 03/06/19 09:44 Chlorobenzene ug/L 0.35 U 1.0 0.35 03/06/19 09:44 Chloroethane ug/L 3.7 U 10.0 3.7 03/06/19 09:44 Chloroform ug/L 0.32 U 1.0 0.32 03/06/19 09:44 Chloromethane ug/L 0.97 U 1.0 0.97 03/06/19 09:44 cis-1,2-Dichloroethene ug/L 0.27 U 1.0 0.27 03/06/19 09:44 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/19/2019 05:18 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 37 PaceAnalytical vfww pacelabs. cam QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451860 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 METHOD BLANK: 2812236 Matrix: Water Associated Lab Samples: 35451860001 Parameter Blank Reporting Units Result Limit MDL Analyzed Qualifiers cis-1,3-Dichloropropene ug/L 0.17 U 0.50 0.17 03/06/19 09:44 Dibromochloromethane ug/L 0.45 U 2.0 0.45 03/06/19 09:44 Dibromomethane ug/L 0.68 U 2.0 0.68 03/06/19 09:44 Dichlorodifluoromethane ug/L 0.26 U 1.0 0.26 03/06/19 09:44 Ethylbenzene ug/L 0.30 U 1.0 0.30 03/06/19 09:44 lodomethane ug/L 9.3 U 10.0 9.3 03/06/19 09:44 Isopropylbenzene (Cumene) ug/L 0.30 U 1.0 0.30 03/06/19 09:44 m&p-Xylene ug/L 2.1 U 4.0 2.1 03/06/19 09:44 Methyl-tert-butyl ether ug/L 0.51 U 2.0 0.51 03/06/19 09:44 Methylene Chloride ug/L 2.0 U 5.0 2.0 03/06/19 09:44 n-Butylbenzene ug/L 0.20 U 1.0 0.20 03/06/19 09:44 n-Propylbenzene ug/L 0.37 U 1.0 0.37 03/06/19 09:44 o-Xylene ug/L 0.27 U 1.0 0.27 03/06/19 09:44 p-Isopropyltoluene ug/L 0.31 U 5.0 0.31 03/06/19 09:44 sec-Butylbenzene ug/L 0.17 U 1.0 0.17 03/06/19 09:44 Styrene ug/L 0.26 U 1.0 0.26 03/06/19 09:44 tert-Butylbenzene ug/L 0.26 U 1.0 0.26 03/06/19 09:44 Tetrachloroethene ug/L 0.38 U 1.0 0.38 03/06/19 09:44 Toluene ug/L 0.33 U 1.0 0.33 03/06/19 09:44 trans-1,2-Dichloroethene ug/L 0.23 U 1.0 0.23 03/06/19 09:44 trans-1,3-Dichloropropene ug/L 0.17 U 0.50 0.17 03/06/19 09:44 Trichloroethene ug/L 0.36 U 1.0 0.36 03/06/19 09:44 Trichlorofluoromethane ug/L 0.35 U 1.0 0.35 03/06/19 09:44 Vinyl acetate ug/L 0.19 U 10.0 0.19 03/06/19 09:44 Vinyl chloride ug/L 0.39 U 1.0 0.39 03/06/19 09:44 Xylene (Total) ug/L 2.1 U 5.0 2.1 03/06/19 09:44 1,2-Dichloroethane-d4 (S) % 103 70-130 03/06/19 09:44 4-Bromofluorobenzene (S) % 94 70-130 03/06/19 09:44 Toluene-d8 (S) % 101 70-130 03/06/19 09:44 LABORATORY CONTROL SAMPLE: 2812237 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 20 20.1 101 70-130 1,1,1-Trichloroethane ug/L 20 18.8 94 70-130 1,1,2,2-Tetrachloroethane ug/L 20 21.3 107 68-125 1,1,2-Trichloroethane ug/L 20 20.1 101 70-130 1,1-Dichloroethane ug/L 20 20.2 101 70-130 1,1-Dichloroethene ug/L 20 18.9 94 66-133 1,1-Dichloropropene ug/L 20 20.3 101 70-130 1,2,3-Trichlorobenzene ug/L 20 21.4 107 64-126 1,2,3-Trichloropropane ug/L 20 21.7 108 62-127 1,2,3-Trimethylbenzene ug/L 20 23.0 115 70-130 1,2,4-Trichlorobenzene ug/L 20 19.4 97 63-124 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/19/2019 05:18 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 37 Pace Analytical wvnv pacelabs. corn QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451860 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE: 2812237 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,2,4-Trimethylbenzene ug/L 20 20.5 102 70-130 1,2-Dichlorobenzene ug/L 20 19.5 97 70-130 1,2-Dichloroethane ug/L 20 17.7 88 70-130 1,2-Dichloropropane ug/L 20 19.3 97 70-130 1,3,5-Trimethylbenzene ug/L 20 20.2 101 70-130 1,3-Dichlorobenzene ug/L 20 19.5 98 70-130 1,3-Dichloropropane ug/L 20 20.2 101 70-130 1,4-Dichlorobenzene ug/L 20 19.4 97 70-130 2,2-Dichloropropane ug/L 20 20.2 101 59-133 2-Butanone (MEK) ug/L 40 44.2 111 47-143 2-Chloroethylvinyl ether ug/L 20 20.2 I 101 41-140 2-Chlorotoluene ug/L 20 20.1 101 70-130 2-Hexanone ug/L 40 46.8 117 48-145 4-Chlorotoluene ug/L 20 20.1 101 70-130 4-Methyl-2-pentanone (MIBK) ug/L 40 48.9 122 57-132 Acetone ug/L 40 48.2 120 46-148 Acetonitrile ug/L 200 230 115 33-175 Benzene ug/L 20 19.7 99 70-130 Bromobenzene ug/L 20 20.1 100 70-130 Bromochloromethane ug/L 20 19.0 95 70-130 ;romodichloromethane ug/L 20 18.4 92 70-130 Bromoform ug/L 20 17.3 87 49-126 Bromomethane ug/L 20 9.7 48 10-165 v2 Carbon disulfide ug/L 20 26.3 131 60-141 v1 Carbon tetrachloride ug/L 20 20.8 104 63-126 Chlorobenzene ug/L 20 19.2 96 70-130 Chloroethane ug/L 20 22.2 111 71-142 Chloroform ug/L 20 19.2 96 70-130 Chloromethane ug/L 20 16.2 81 40-140 v2 cis-1,2-Dichloroethene ug/L 20 19.3 96 70-130 cis-1,3-Dichloropropene ug/L 20 16.3 82 70-130 Dibromochloromethane ug/L 20 15.4 77 62-118 Dibromomethane ug/L 20 18.3 92 70-130 Dichlorodifluoromethane ug/L 20 20.2 101 47-150 Ethylbenzene ug/L 20 20.0 100 70-130 lodomethane ug/L 40 21.7 54 10-164 v2 Isopropylbenzene (Cumene) ug/L 20 19.6 98 70-130 m&p-Xylene ug/L 40 40.4 101 70-130 Methyl-tert-butyl ether ug/L 20 22.3 112 64-124 Methylene Chloride ug/L 20 18.2 91 65-136 n-Butylbenzene ug/L 20 20.5 102 70-130 n-Propylbenzene ug/L 20 21.2 106 70-130 o-Xylene ug/L 20 19.1 96 70-130 p-lsopropyltoluene ug/L 20 17.4 87 70-130 sec-Butylbenzene ug/L 20 20.6 103 70-130 Styrene ug/L 20 18.0 90 70-130 tert-Butylbenzene ug/L 20 20.7 103 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/19/2019 05:18 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 37 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451860 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE: 2812237 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers Tetrachloroethene ug/L 20 19.7 98 64-134 Toluene ug/L 20 20.4 102 70-130 trans-1,2-Dichloroethene ug/L 20 19.7 98 68-127 trans-1,3-Dichloropropene ug/L 20 16.0 80 65-121 Trichloroethene ug/L 20 19.2 96 70-130 Trichlorofluoromethane ug/L 20 22.0 110 65-135 Vinyl acetate ug/L 20 24.4 122 60-144 Vinyl chloride ug/L 20 19.1 95 68-131 Xylene (Total) ug/L 60 59.5 99 70-130 1,2-Dichloroethane-d4 (S) % 101 70-130 4-Bromofluorobenzene (S) % 95 70-130 Toluene-d8 (S) % 99 70-130 MATRIX SPIKE SAMPLE: 2812239 Parameter 35451633002 Spike MS MS % Rec Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 0.32 U 20 13.3 67 70-130 J(M1) 1,1,1-Trichloroethane ug/L 0.30 U 20 14.4 72 70-130 1,1,2,2-Tetrachloroethane ug/L 0.20 U 20 14.9 74 68-125 1,1,2-Trichloroethane ug/L 0.30 U 20 13.9 70 70-130 1,1-Dichloroethane ug/L 0.34 U 20 15.4 77 70-130 1,1-Dichloroethene ug/L 0.27 U 20 16.8 84 66-133 1,1-Dichloropropene ug/L 0.31 U 20 14.3 71 70-130 1,2,3-Trichlorobenzene ug/L 0.34 U 20 11.7 59 64-126 J(M1) 1,2,3-Trichloropropane ug/L 1.1 U 20 13.5 68 62-127 1,2,3-Trimethylbenzene ug/L 0.17 U 20 16.3 82 70-130 1,2,4-Trichlorobenzene ug/L 0.32 U 20 10.7 54 63-124 J(M1) 1,2,4-Trimethylbenzene ug/L 0.24 U 20 12.8 64 70-130 J(M1) 1,2-Dichlorobenzene ug/L 0.29 U 20 12.7 64 70-130 J(M1) 1,2-Dichloroethane ug/L 0.27 U 20 13.1 66 70-130 J(M1) 1,2-Dichloropropane ug/L 0.23 U 20 13.9 70 70-130 1,3,5-Trimethylbenzene ug/L 0.24 U 20 13.1 65 70-130 J(M1) 1,3-Dichlorobenzene ug/L 0.33 U 20 12.9 64 70-130 J(M1) 1,3-Dichloropropane ug/L 0.26 U 20 13.4 67 70-130 J(M1) 1,4-Dichlorobenzene ug/L 0.28 U 20 13.0 65 70-130 J(M1) 2,2-Dichloropropane ug/L 0.59 U 20 12.5 62 59-133 2-Butanone (MEK) ug/L 7.5 U 40 30.1 75 47-143 2-Chloroethylvinyl ether ug/L 1.4 U 20 1.4 U 0 41-140 J(M1) 2-Chlorotoluene ug/L 0.28 U 20 13.2 66 70-130 J(M1) 2-Hexanone ug/L 0.85 U 40 28.5 71 48-145 4-Chlorotoluene ug/L 0.22 U 20 13.3 66 70-130 J(M1) 4-Methyl-2-pentanone (MIBK) ug/L 0.32 U 40 0.32 U 0 57-132 J(M1) Acetone ug/L 5.3 U 40 36.7 82 46-148 Acetonitrile ug/L 24.5 U 200 176 88 33-175 Benzene ug/L 0.30 U 20 14.2 71 70-130 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/19/2019 05:18 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 37 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451860 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 MATRIX SPIKE SAMPLE: 2812239 Parameter 35451633002 Spike MS MS % Rec Units Result Conc. Result % Rec Limits Qualifiers Bromobenzene ug/L 0.21 U 20 14.0 70 70-130 Bromochloromethane ug/L 0.37 U 20 13.8 69 70-130 J(M1) Bromodichloromethane ug/L 0.19 U 20 13.4 67 70-130 J(M1) Bromoform ug/L 2.6 U 20 11.8 59 49-126 Bromomethane ug/L 4.0 U 20 9.1 46 10-165 v2 Carbon disulfide ug/L 0.45 U 20 22.6 113 60-141 v1 Carbon tetrachloride ug/L 1.1 U 20 15.4 77 63-126 Chlorobenzene ug/L 0.35 U 20 13.5 67 70-130 J(M1) Chloroethane ug/L 3.7 U 20 20.6 103 71-142 Chloroform ug/L 0.32 U 20 14.3 71 70-130 Chloromethane ug/L 0.97 U 20 14.1 70 40-140 v2 cis-1,2-Dichloroethene ug/L 0.27 U 20 14.1 71 70-130 cis-1,3-Dichloropropene ug/L 0.17 U 20 10.3 52 70-130 J(M1) Dibromochloromethane ug/L 0.45 U 20 10.2 51 62-118 J(M1) Dibromomethane ug/L 0.68 U 20 12.4 62 70-130 J(M1) Dichlorodifluoromethane ug/L 0.26 U 20 18.0 90 47-150 Ethylbenzene ug/L 0.30 U 20 13.5 68 70-130 J(M1) lodomethane ug/L 9.3 U 40 9.3 U 21 10-164 v2 Isopropylbenzene (Cumene) ug/L 0.30 U 20 12.2 61 70-130 J(M1) m&p-Xylene ug/L 2.1 U 40 27.0 68 70-130 J(M1) lethyl-tert-butyl ether ug/L 0.51 U 20 14.7 74 64-124 Methylene Chloride ug/L 2.0 U 20 14.4 72 65-136 n-Butylbenzene ug/L 0.20 U 20 12.4 62 70-130 J(M1) n-Propylbenzene ug/L 0.37 U 20 14.2 71 70-130 o-Xylene ug/L 0.27 U 20 11.7 59 70-130 J(M1) p-Isopropyltoluene ug/L 0.31 U 20 10.7 54 70-130 J(M1) sec-Butylbenzene ug/L 0.17 U 20 13.5 68 70-130 J(M1) Styrene ug/L 0.26 U 20 11.5 57 70-130 J(M1) tert-Butylbenzene ug/L 0.26 U 20 13.6 68 70-130 J(M1) Tetrachloroethene ug/L 0.38 U 20 12.8 64 64-134 Toluene ug/L 0.33 U 20 14.3 72 70-130 trans-1,2-Dichloroethene ug/L 0.23 U 20 14.8 74 68-127 trans-1,3-Dichloropropene ug/L 0.17 U 20 10.6 53 65-121 J(M1) Trichloroethene ug/L 0.36 U 20 13.4 67 70-130 J(M1) Trichlorofluoromethane ug/L 0.35 U 20 18.5 92 65-135 Vinyl acetate ug/L 0.19 U 20 15.3 76 60-144 Vinyl chloride ug/L 0.39 U 20 16.4 82 68-131 Xylene (Total) ug/L 2.1 U 60 38.8 65 70-130 MS 1,2-Dichloroethane-d4 (S) % 104 70-130 4-Bromofluorobenzene (S) % 90 70-130 Toluene-d8 (S) % 98 70-130 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/19/2019 05:18 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 37 aceAnalytical® www pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451860 SAMPLE DUPLICATE: 2812238 Parameter 35451633001 Dup Max Units Result Result RPD RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L 0.32 U 0.32 U 40 1,1,1-Trichloroethane ug/L 0.30 U 0.30 U 40 1,1,2,2-Tetrachloroethane ug/L 0.20 U 0.20 U 40 1,1,2-Trichloroethane ug/L 0.30 U 0.30 U 40 1,1-Dichloroethane ug/L 0.34 U 0.34 U 40 1,1-Dichloroethene ug/L 0.27 U 0.27 U 40 1,1-Dichloropropene ug/L 0.31 U 0.31 U 40 1,2,3-Trichlorobenzene ug/L 0.34 U 0.34 U 40 1,2,3-Trichloropropane ug/L 1.1 U 1.1 U 40 1,2,3-Trimethylbenzene ug/L 0.17 U 0.17 U 40 1,2,4-Trichlorobenzene ug/L 0.32 U 0.32 U 40 1,2,4-Trimethylbenzene ug/L 0.24 U 0.24 U 40 1,2-Dichlorobenzene ug/L 0.29 U 0.29 U 40 1,2-Dichloroethane ug/L 0.27 U 0.27 U 40 1,2-Dichloropropane ug/L 0.23 U 0.23 U 40 1,3,5-Trimethylbenzene ug/L 0.24 U 0.24 U 40 1,3-Dichlorobenzene ug/L 0.33 U 0.33 U 40 1,3-Dichloropropane ug/L 0.26 U 0.26 U 40 1,4-Dichlorobenzene ug/L 0.28 U 0.28 U 40 2,2-Dichloropropane ug/L 0.59 U 0.59 U 40 2-Butanone (MEK) ug/L 7.5 U 7.5 U 40 2-Chloroethylvinyl ether ug/L 1.4 U 1.4 U 40 2-Chlorotoluene ug/L 0.28 U 0.28 U 40 2-Hexanone ug/L 0.85 U 0.85 U 40 4-Chlorotoluene ug/L 0.22 U 0.22 U 40 4-Methyl-2-pentanone (MIBK) ug/L 0.32 U 0.32 U 40 Acetone ug/L 5.3 U 5.3 U 40 Acetonitrile ug/L 24.5 U 24.5 U 40 Benzene ug/L 0.30 U 0.30 U 40 Bromobenzene ug/L 0.21 U 0.21 U 40 Bromochloromethane ug/L 0.37 U 0.37 U 40 Bromodichloromethane ug/L 0.19 U 0.19 U 40 Bromoform ug/L 2.6 U 2.6 U 40 Bromomethane ug/L 4.0 U 4.0 U 40 v2 Carbon disulfide ug/L 0.45 U 0.45 U 40 v1 Carbon tetrachloride ug/L 1.1 U 1.1 U 40 Chlorobenzene ug/L 0.35 U 0.35 U 40 Chloroethane ug/L 3.7 U 3.7 U 40 Chloroform ug/L 0.32 U 0.32 U 40 Chloromethane ug/L 0.97 U 0.97 U 40 v2 cis-1,2-Dichloroethene ug/L 0.27 U 0.27 U 40 cis-1,3-Dichloropropene ug/L 0.17 U 0.17 U 40 Dibromochloromethane ug/L 0.45 U 0.45 U 40 Dibromomethane ug/L 0.68 U 0.68 U 40 Dichlorodifluoromethane ug/L 0.26 U 0.26 U 40 Ethylbenzene ug/L 0.30 U 0.30 U 40 lodomethane ug/L 9.3 U 9.3 U 40 v2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/19/2019 05:18 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 37 aceAnalytical wwwpacetabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451860 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 SAMPLE DUPLICATE: 2812238 Parameter 35451633001 Dup Max Units Result Result RPD RPD Qualifiers Isopropylbenzene (Cumene) ug/L 0.30 U 0.30 U 40 m&p-Xylene ug/L 2.1 U 2.1 U 40 Methyl-tert-butyl ether ug/L 0.51 U 0.51 U 40 Methylene Chloride ug/L 2.0 U 2.0 U 40 n-Butylbenzene ug/L 0.20 U 0.20 U 40 n-Propylbenzene ug/L 0.37 U 0.37 U 40 o-Xylene ug/L 0.27 U 0.27 U 40 p-Isopropyltoluene ug/L 0.31 U 0.31 U 40 sec-Butylbenzene ug/L 0.17 U 0.17 U 40 Styrene ug/L 0.26 U 0.26 U 40 tert-Butylbenzene ug/L 0.26 U 0.26 U 40 Tetrachloroethene ug/L 0.38 U 0.38 U 40 Toluene ug/L 0.33 U 0.33 U 40 trans-1,2-Dichloroethene ug/L 0.23 U 0.23 U 40 trans-1,3-Dichloropropene ug/L 0.17 U 0.17 U 40 Trichloroethene ug/L 0.36 U 0.36 U 40 Trichlorofluoromethane ug/L 0.35 U 0.35 U 40 Vinyl acetate ug/L 0.19 U 0.19 U 40 Vinyl chloride ug/L 0.39 U 0.39 U 40 Xylene (Total) ug/L 2.1 U 2.1 U 40 ,2-Dichloroethane-d4 (S) % 103 104 0 40 4-Bromofluorobenzene (S) % 89 91 3 40 Y Toluene-d8 (S) % 100 100 0 40 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/19/2019 05:18 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 37 r' _-Pace Analytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451860 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521132 Analysis Method: EPA8081 QC Batch Method: EPA 3510 Analysis Description: 8081 GCS Pesticides Associated Lab Samples: 35451860001 METHOD BLANK: 2814313 Matrix: Water Associated Lab Samples: 35451860001 Parameter Blank Reporting Units Result Limit MDL Analyzed Qualifiers 4,4'-DDD ug/L 0.0089 U 0.010 0.0089 03/14/19 11:52 4,4'-DDE ug/L 0.0050 U 0.010 0.0050 03/14/19 11:52 4,4'-DDT ug/L 0.0050 U 0.010 0.0050 03/14/19 11:52 Aldrin ug/L 0.0015 U 0.010 0.0015 03/14/19 11:52 alpha-BHC ug/L 0.0021 U 0.010 0.0021 03/14/19 11:52 beta-BHC ug/L 0.0080 U 0.010 0.0080 03/14/19 11:52 Chlordane (Technical) ug/L 0.18 U 0.50 0.18 03/14/19 11:52 delta-BHC ug/L 0.0048 U 0.010 0.0048 03/14/19 11:52 Dieldrin ug/L 0.0020 U 0.010 0.0020 03/14/19 11:52 Endosulfan I ug/L 0.0051 U 0.010 0.0051 03/14/19 11:52 Endosulfan II ug/L 0.0040 U 0.010 0.0040 03/14/19 11:52 Endosulfan sulfate ug/L 0.0062 U 0.10 0.0062 03/14/19 11:52 Endrin ug/L 0.0043 U 0.010 0.0043 03/14/19 11:52 Endrin aldehyde ug/L 0.0036 U 0.10 0.0036 03/14/19 11:52 Endrin ketone ug/L 0.0050 U 0.010 0.0050 03/14/19 11:52 gamma-BHC (Lindane) ug/L 0.0022 U 0.010 0.0022 03/14/19 11:52 Heptachlor ug/L 0.0062 U 0.010 0.0062 03/14/19 11:52 Heptachlor epoxide ug/L 0.0052 U 0.010 0.0052 03/14/19 11:52 Methoxychlor ug/L 0.0096 U 0.010 0.0096 03/14/19 11:52 Toxaphene ug/L 0.25 U 0.50 0.25 03/14/19 11:52 Decachlorobiphenyl (S) % 61 10-132 03/14/19 11:52 Tetrachloro-m-xylene (S) % 84 27-124 03/14/19 11:52 LABORATORY CONTROL SAMPLE & LCSD: 2814314 2814376 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers 4,4'-DDD ug/L 0.5 0.53 0.49 105 97 67-133 7 40 4,4'-DDE ug/L 0.5 0.47 0.44 95 88 59-125 8 40 4,4'-DDT ug/L 0.5 0.51 0.48 102 97 54-132 5 40 Aldrin ug/L 0.5 0.43 0.39 86 79 25-116 9 40 alpha-BHC ug/L 0.5 0.46 0.43 92 87 53-126 6 40 beta-BHC ug/L 0.5 0.49 0.45 97 90 62-130 8 40 delta-BHC ug/L 0.5 0.41 0.39 83 79 35-122 5 40 Dieldrin ug/L 0.5 0.53 0.51 106 101 66-128 5 40 Endosulfan I ug/L 0.5 0.46 0.43 92 86 67-125 7 40 Endosulfan 11 ug/L 0.5 0.47 0.45 94 89 67-131 5 40 Endosulfan sulfate ug/L 0.5 0.54 0.51 107 101 62-127 6 40 Endrin ug/L 0.5 0.52 0.49 103 98 66-130 5 40 Endrin aldehyde ug/L 0.5 0.57 0.54 115 107 61-124 7 40 Endrin ketone ug/L 0.5 0.55 0.53 111 106 65-132 4 40 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/19/2019 05:18 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 37 /eAnaI}icaI www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451860 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE & LCSD: 2814314 2814376 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers gamma-BHC (Lindane) ug/L 0.5 0.50 0.47 99 94 58-127 5 40 Heptachlor ug/L 0.5 0.44 0.42 88 83 35-123 6 40 Heptachlor epoxide ug/L 0.5 0.49 0.47 98 94 62-125 4 40 Methoxychlor ug/L 0.5 0.57 0.55 113 109 59-135 3 40 Decachlorobiphenyl (S) % 66 56 10-132 Tetrachloro-m-xylene (S) % 71 66 27-124 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/19/2019 05:18 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 37 PaceAnalytical wow pacelabs. corn Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451860 QC Batch: 521006 Analysis Method: EPA 8270 by SIM QC Batch Method: EPA 3510 Analysis Description: 8270 Water PAHLV by SIM MSSV Associated Lab Samples: 35451860001 METHOD BLANK: 2813544 Matrix: Water Associated Lab Samples: 35451860001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1-Methylnaphthalene ug/L 0.19 U 2.0 0.19 03/07/19 08:37 2-Methylnaphthalene ug/L 0.68 U 2.0 0.68 03/07/19 08:37 Acenaphthene ug/L 0.040 U 0.50 0.040 03/07/19 08:37 Acenaphthylene ug/L 0.030 U 0.50 0.030 03/07/19 08:37 Anthracene ug/L 0.043 U 0.50 0.043 03/07/19 08:37 Benzo(a)anthracene ug/L 0.055 U 0.10 0.055 03/07/19 08:37 Benzo(a)pyrene " ug/L 0.12 U 0.20 0.12 03/07/19 08:37 Benzo(b)fluoranthene ug/L 0.027 U 0.10 0.027 03/07/19 08:37 Benzo(g,h,i)perylene ug/L 0.15 U 0.50 0.15 03/07/19 08:37 Benzo(k)fluoranthene ug/L 0.16 U 0.50 0.16 03/07/19 08:37 Chrysene ug/L 0.026 U 0.50 0.026 03/07/19 08:37 Dibenz(a,h)anthracene ug/L 0.13 U 0.15 0.13 03/07/19 08:37 Fluoranthene ug/L 0.018 U 0.50 0.018 03/07/19 08:37 Fluorene ug/L 0.088 U 0.50 0.088 03/07/19 08:37 Indeno(1,2,3-cd)pyrene ug/L 0.12 U 0.15 0.12 03/07/19 08:37 Naphthalene ug/L 0.29 U 2.0 0.29 03/07/19 08:37 Phenanthrene ug/L 0.16 U 0.50 0.16 03/07/19 08:37 Pyrene ug/L 0.032 U 0.50 0.032 03/07/19 08:37 2-Fluorobiphenyl (S) % 63 33-82 03/07/19 08:37 p-Terphenyl-d14 (S) % 102 49-104 03/07/19 08:37 LABORATORY CONTROL SAMPLE: 2813545 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1-Methylnaphthalene ug/L 5 3.3 66 40-96 2-Methylnaphthalene ug/L 5 3.3 65 40-94 Acenaphthene ug/L 5 3.2 65 42-96 Acenaphthylene ug/L 5 3.2 63 39-90 Anthracene ug/L 5 3.7 75 46-109 Benzo(a)anthracene ug/L 5 4.1 83 50-116 Benzo(a)pyrene ug/L 5 4.1 83 48-117 Benzo(b)fluoranthene ug/L 5 4.2 85 51-124 Benzo(g,h,i)perylene ug/L 5 4.1 83 47-121 Benzo(k)fluoranthene ug/L 5 4.4 88 50-125 Chrysene ug/L 5 4.4 87 53-122 Dibenz(a,h)anthracene ug/L 5 4.0 80 45-123 Fluoranthene ug/L 5 4.5 90 52-119 Fluorene ug/L 5 3.4 68 44-100 Indeno(1,2,3-cd)pyrene ug/L 5 4.0 79 46-121 Naphthalene ug/L 5 3.2 64 40-91 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/19/2019 05:18 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 37 aceAnalytkal® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451860 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE: 2813545 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phenanthrene ug/L 5 3.7 73 47-111 Pyrene ug/L 5 4.4 88 51-120 2-Fluorobiphenyl (S) % 71 33-82 p-Terphenyl-d14 (S) % 98 49-104 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2813901 2813902 MS MSD 35452061003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1-Methylnaphthalene ug/L 0.19 U 5 5 3.1 3.1 62 62 40-96 1 40 2-Methylnaphthalene ug/L 0.68 U 5 5 3.2 3.1 64 61 40-94 4 40 Acenaphthene ug/L 0.040 U 5 5 3.0 3.2 60 63 42-96 4 40 Acenaphthylene ug/L 0.030 U 5 5 2.9 3.0 58 61 39-90 4 40 Anthracene ug/L 0.043 U 5 5 3.7 3.9 74 78 46-109 5 40 Benzo(a)anthracene ug/L 0.055 U 5 5 4.0 4.2 81 83 50-116 3 40 Benzo(a)pyrene ug/L 0.12 U 5 5 4.0 4.0 81 79 48-117 2 40 Benzo(b)fluoranthene ug/L 0.027 U 5 5 4.0 4.0 81 80 51-124 1 40 Benzo(g,h,i)perylene ug/L 0.15 U 5 5 4.0 3.8 79 77 47-121 3 40 'enzo(k)fluoranthene ug/L 0.16 U 5 5 4.2 4.1 84 82 50-125 2 40 ,;hrysene ug/L 0.026 U 5 5 4.2 4.2 84 85 53-122 1 40 Dibenz(a,h)anthracene ug/L 0.13 U 5 5 3.9 3.7 77 74 45-123 4 40 Fluoranthene ug/L 0.018 U 5 5 4.5 4.7 89 94 52-119 5 40 Fluorene ug/L 0.088 U 5 5 3.2 3.4 65 69 44-100 5 40 Indeno(1,2,3-cd)pyrene ug/L 0.12 U 5 5 3.9 3.7 77 75 46-121 3 40 Naphthalene ug/L 0.29 U 5 5 2.9 2.9 58 58 40-91 0 40 Phenanthrene ug/L 0.16 U 5 5 3.7 3.8 73 77 47-111 4 40 Pyrene ug/L 0.032 U 5 5 4.4 4.5 87 91 51-120 4 40 2-Fluorobiphenyl (S) % 68 70 33-82 p-Terphenyl-d14 (S) % 97 98 49-104 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 03/19/2019 05.18 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 21 of 37 aceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451860 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 521011 Analysis Method: FL -PRO QC Batch Method: EPA 3510 Analysis Description: FL -PRO Water Low Volume Associated Lab Samples: 35451860001 METHOD BLANK: 2813560 Matrix: Water Associated Lab Samples: 35451860001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Petroleum Range Organics N-Pentatriacontane (S) o-Terphenyl (S) mg/L % % 0.80 U 1.0 0.80 03/07/19 12:40 86 42-159 03/07/19 12:40 79 66-139 03/07/19 12:40 LABORATORY CONTROL SAMPLE: 2813561 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Petroleum Range Organics mg/L 5 4.4 87 66-119 N-Pentatriacontane (S) % 99 42-159 o-Terphenyl (S) % 94 66-139 MATRIX SPIKE SAMPLE: 2814271 35452019001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Petroleum Range Organics mg/L 0.73 U 4.6 3.9 80 65-123 N-Pentatriacontane (S) % 89 42-159 o-Terphenyl (S) % 90 66-139 SAMPLE DUPLICATE: 2814272 35451859001 Dup Parameter Units Result Result RPD Max RPD Qualifiers Petroleum Range Organics mg/L 0.79 U 0.77 U N-Pentatriacontane (S) % 97 91 o-Terphenyl (S) % 81 89 9 7 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 03/19/2019 05:18 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 22 of 37 PaceAnalytical www.pacelabs.com QUALIFIERS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451860 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS U J(M1) MS Y c2 v1 v2 The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. Compound was analyzed for but not detected. Estimated Value. Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. Analyte recovery in the matrix spike was outside QC limits for one or more of the constituent analytes used in the calculated result. The laboratory analysis was from an improperly preserved sample. Acid preservation may not be appropriate for the analysis of 2-Chloroethylvinyl ether. The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. Date: 03/19/2019 05:18 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 37 aceAnaVical® www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451860 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID QC Batch Method Analytical QC Batch Analytical Method Batch 35451860001 SCS-MW-2 EPA 3510 521132 EPA 8081 521859 35451860001 SCS-MW-2 EPA 3510 521011 FL -PRO 521222 35451860001 SCS-MW-2 EPA 3010 521178 EPA 6010 521271 35451860001 SCS-MW-2 EPA 7470 521100 EPA 7470 521259 35451860001 SCS-MW-2 EPA 3510 521006 EPA 8270 by SIM 521083 35451860001 SCS-MW-2 EPA 8260 520786 Date: 03/19/2019 05:18 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 24 of 37 1'a,,cAllajy1ica) Section A Required Client Information: Section B Required Project Information: cHAIWO4 35451860 The Ch Company EERG Environmental Services, I.LC Address 5751 Miami Lakes Dr Hialeah, FL 33014 Email Mq, n 4rr'' FX.Llrs Phone (305)374-8300 Ilax (J Report To. t �.cI1A.P� 1i� 35451860 Copy To (4ic• Ce-r Requested Due Dale w 1-- 2 3 4 5 -n q Purchase Orderu. Project Name eNr2.'L,' - & c (..c.,urSe Project #: 2018-305/ SAMPLE ID One Character per box. (A-Z, O-9 / r -) Sample Ids must be unique MATRIX CODE Onnxmg Wnhrr OW Water WT Waste Wntrr WW Product F Sod/Sold SL od OL WIpn wP Nr AR Other OT Thor TS ADDITIONAL COMMENTS RELIN QUIS COLLECTED START DATE RED BYI TIME AFFIUATIO N END DATE TIME DATE gi 11111111111111111111 Address cument be completed accurately. Pace Quote Pace Project Manager Pace Profile 4 TIME 0 0 S chrislina raschke@pacelabs corn, n Preservatives x O z 0 co co ry Z >- Analyses Test 0 0 CO Requ rn O CO a 2 0- \I TRPH FL -PRO „,--ACCEPTED BY FILIATION IAF co v7 0 d m 0 U 2 Page: Of Regulatory Agency Filtered (Y/N) 1, co co 0 DATE rn CD V-r CD TIME State / Location • FL (-a SAMPLE CONDITIONS J r> LE Jo gZ abed SAMPLER NAME AND SIGNATURE 2'.t'fA t- � f •J J 1 * r 1• )C) Ru y PRINT Name of SAMPLER: SIGNATURE of SAMPLER: X �! l.L fi' (I DATE Signed: .� Document Name Sample Condition Upon Recap: orrn Document No F-FL-C-007 rev 13 W J# : 3 45186O Project # pm: CTR Project Manager: CLIENT: 36-EEG Client: Thermometer Used: Due Date: 03/12/19 0 Date lfl State of • rigi2 P _f For WV protects, all containers verified to <_6 `C Cooler #1 Temp.°C as (Visual) (). 00 (Correction Factor) 3. V (Actual) (-'Samples on ice, cooling process has begun Cooler #2 Temp.'C • (Visual) 0_ (Correction Factor) (. 0 (Actual) ! Samples on ice, cooling process has begun Cooler #3 Temp.'C 5,..5 (Visual) 0 -0 (Correction Factor) 5,5 (Actual) Samples on ice, cooling process has begun Cooler #4 Temp.'C (Visual) (Correction Factor) (Actual) L Samples on ice, cooling process has begun Document Revised_ May 30, 2018 Issuing Authority Pace Florida Quality Office (ice),= Cooler#5 Temp.°C (Visual) (Correction Factor) Cooler #6 Temp.'C (Visual) (Correction Factor) Time. (Actual) (Actual) Courier: ❑ Fed Ex ❑ UPS n USPS E Client L Commercia Pace Shipping Method: 2 First Overnight - Priority Overnight Other Billing: Tracking # Recipient Sender Custody Seal on Cooler/Box Present: des Packing Material: ❑Bubble Wrap Samples shorted to lab (If Yes, complete) Date and Initials of p Examining contents: Label: Deliver- pH: • Samples on ice, cocking process has begun [' Samples on ice, cooling process has begun D Other _. Standard Overnight Ground International Priority Third Party = Credit Card O Seals intact: i Yes ubble Bags L)None ❑Other Shorted Date' Comments: = Unknown Shorted Time: e Dry None Chain of Custody Present 7 es _ No tN/A Chain of Custody Filled Out s - No LLN/A Relinquished Signature & Sampler Name COC e_s No EtN/A Samples Arrived within Hold Time vl e/s i7I No uN/A Rush TAT requested on COC EtYes o QN/A Sufficient Volume s _ No ON/A Correct Containers Used 2esas No ON/A Containers Intact — 'es _ No ❑N/A Sample Labels match COC (sample IDs & date/time of collection) es D No ❑N/A AU containers needing acid/base preservation have been checked. s = No DN/A All Containers needing preservation are found to be in comp! ance with EPA recommendation '— es -• No EN/A Exceptions. VOA, Colrform, TOC, O&G, Carbamates Preservation Information Preservative Lot #!Trace # 1p`\�(1 Date u Initials Headspace in VOA Vials? (>6mm): DYes - No /A Trip Blank Present: CYes - No LiN/A Client Notification/ Resolution: Person Contacted: Comments/ Resolution (use back for additional comments): Date/Time. Project Manager Review: Date: Page 26 of 37 atiaceAnalytical Naonal Center for Testing & Innovation A\ALYTICAL RI SORT March 12, 2019 Pace Analytical - Pompano Beach, FL Sample Delivery Group: Samples Received: Project Number: Description: Site: Report To: L1076241 03/07/2019 35451860 2018-3057Melreese golf course 001 Christina Raschke 3610 Park Central Blvd N Pompano Beach, FL 33064 Entire Report Reviewed By: Jason Romer Project Manager Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace National is performed per guidance provided in laboratory standard operating procedures: 060302, 060303, and 060304. 12065 Lebanon Rd Mount Juliet, TN 37122 615-758-5858 800-767-5859 TABLE OF CONTENTS ONE LAB. NATIONWIDE. Cp: Cover Page 1 Tc: Table of Contents 2 Ss: Sample Summary 3 Cn: Case Narrative 4 Sr: Sample Results 5 SCS-MW-2 L1076241-01 5 Qc: Quality Control Summary 6 Chlorinated Acid Herbicides (GC) by Method 8151 6 GI: Glossary of Terms 7 AI: Accreditations & Locations 8 Sc: Sample Chain of Custody 9 Cn 5 Qc GI - Al Sc Page 28 of 37 PROJECT: SDG: DATE/TIME: PAGE: 35451860 L1076241 03/12/1915:52 2 of 11 ACCOUNT: Pace Analytical - Pompano Beach, FL SAMPLE SUMMARY ONE LAB. NATIONWIDE. 40 SCS-MW-2 L1076241-01 GW u_ii cted datetime Received date/time 03/04/19 14:12 03107/19 09:00 ' 'hod Chlorinated Acid Herbicides (GC) by Method 8151 ACCOUNT: Pace Analytical - Pompano Beach, FL Batch Dilution Preparation Analysis Analyst Location date/time date/time WG1247068 1 03/08/19 08:07 03/09/19 02:56 KLM Mt. Juliet, TN Cp Cn s Sr QC GI Al Page 29 of 37 PROJECT: SDG: DATE/TIME: PAGE: 35451860 L1076241 03/12/1915:52 3 of 11 CASE NARRATIVE ONE LAB. NATIONWIDE. Sk All sample aliquots were received at the correct temperature, in the proper containers, with the appropriate preservatives, and within method specified holding times, unless qualified or notated within the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data. Jason Romer Project Manager ACCOUNT: Pace Analytical - Pompano Beach, FL Ss GI Al Page 30 of 37 PROJECT: SDG: DATE/TIME: PAGE: 35451860 L1076241 03/12/1915:52 4 of 11 SCS-MW-2 SAMPLE RESULTS - 01 Collected date/time: 03/04/19 14:12 L1076241 ONE LAB. NATIONWIDE. Chlorinated Acid Herbicides (GC) by Method 8151 Result Qualifier MDL RDL Dilution Analysis Batch to ug/I ug/I ug/I date / time ,,-,-0 0.744 U 0.744 2.00 1 03/09/2019 02:56 WG1247068 Dalapon 1.04 U 1.04 2.00 1 03/09/2019 02:56 WG1247068 2,4-DB 0.775 U 0.775 4.00 1 03/09/2019 02:56 WG1247068 Dicamba 0.813 U 0.813 2.00 1 03/09/2019 02:56 WG1247068 Dichloroprop 0.778 U 0.778 2.00 1 03/09/2019 02:56 WG1247068 Dinoseb 0.795 U 0.795 2.00 1 03/09/2019 02:56 WG1247068 MCPA 13.1 J U 13.1 200 1 03/09/2019 02:56 WG1247068 MCPP 7.15 U 7.15 200 1 03/09/2019 02:56 WG1247068 2,4,5-1 0.843 U 0.843 2.00 1 03/09/2019 02:56 W61247068 2,4,5-TP (Silvex) 0.845 U 0.845 2.00 1 03/09/2019 02:56 WG1247068 (S)2,4-Dichlorophenyl Acetic 53.4 14.0-158 03/09/2019 02:56 WG1247068 Acid ACCOUNT: Pace Analytical - Pompano Beach, FL Cp Tc SS 4 Cn Sr 6 Qc GI JAl Page 31 of 37 PROJECT: SDG: DATE/TIME: PAGE: 35451860 L1076241 03/12/1915:52 5 of 11 WG1247068 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. Chlorinated Acid Herbicides (GC) by Method 8151 L1076241-01 Method Blank (MB) (MB) R3390374-1 03/09/19 01:08 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I 2,4-D 0.744 U 0.744 2.00 Dalapon 1.04 U 1.04 2.00 2,4-DB 0.775 U 0.775 4.00 Dicamba 0.813 U 0.813 2.00 Dichloroprop 0.778 U 0.778 2.00 Dinoseb 0.795 U 0.795 2.00 MCPA 13.1 U 13.1 200 MCPP 7.15 U 7.15 200 2,4,5-T 0.843 U 0.843 2.00 2,4,5-TP (Silvex) 0.845 U 0.845 2.00 (S) 2,4-Dichloropheny/Acetic 66.2 14.0 158 Acid Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3390374-2 03/09/19 01:22 • (LCSD) R3390374-3 03/09/19 01:35 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I % % % % 2,4-D ' 5.00 3.28 3.31 65.6 66.2 50.0-120 0.910 20 Dalapon 5.00 2.64 2.67 52.8 53.4 32.0-120 1.13 20 2,4-DB 5.00 3.73 4.10 74.6 82.0 53.0-140 P 9.45 20 Dicamba 5.00 3.49 3.50 69.8 70.0 51.0-120 0.286 20 Dichloroprop 5.00 3.26 3.30 65.2 66.0 55.0-127 1.22 20 Dinoseb 5.00 2.21 2.18 44.2 43.6 36.0-134 1.37 20 MCPA 50.0 232 193 464 386 10.0-160 J L P J L 18.4 40 MCPP 50.0 19.9 20.5 39.8 41.0 10.0-160 2.97 23 2,4,5-T 5.00 3.72 3.69 74.4 73.8 54.0-120 0.810 20 2,4,5-TP (Silvex) 5.00 3.69 3.68 73.8 73.6 50.0-125 0.271 20 (S) 2,4-Dichloraphenyl Acetic Acid 62.8 60.8 14.0-158 ACCOUNT: Faye Analytical - Pompano Beach, FL Cp Tc 3Ss 4 Cn Sr 6 Qc GI Al -le 32 of 37 PROJECT: SDG: DATE/TIME: AGE: 35451860 L1076241 03/12/19 15:52 6 of 11 GLOSSARY OF TERMS ONE LAB. NATIONWIDE. 40 Guide to Reading and Understanding Your Laboratory Report The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and if you have additional questions please contact your project representative. Abbreviations and Definitions MDL RDL Rec. RPD SDG (S) Analyte Dilution Limits Qualifier Result Uncertainty (Radiochemistry) Case Narrative (Cn) Quality Control Summary (Qc) Sample Chain of Custody (Sc) Sample Results (Sr) Sample Summary (Ss) Qualifier Method Detection Limit. Reported Detection Limit. Recovery. Relative Percent Difference. Sample Delivery Group. Surrogate (Surrogate Standard) - Analyses added to every blank, sample, Laboratory Control Sample/Duplicate and Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be detected in all environmental media. The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes reported. If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor. These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or duplicated within these ranges. This column provides a letter and/or number designation that corresponds to additional information concerning the result reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable. The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL" (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte. Confidence level of 2 sigma. A brief discussion about the included sample results, including a discussion of any non -conformances to protocol observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report. This section of the report includes the results of the laboratory quality control analyses required by procedure or analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material. This is the document created in the field when your samples were initially collected. This is used to verify the time and date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the samples from the time of collection until delivery to the laboratory for analysis. This section of your report will provide the results of all testing performed on your samples. These results are provided by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for each sample will provide the name and method number for the analysis reported. This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and times of preparation and/or analysis. Description J L P U The value is outside laboratory established criteria. Off -scale high. Actual value is known to be greater than value given. RPD between the primary and confirmatory analysis exceeded 40%. Indicates the compound was analyzed for but not detected above the method detection limit. ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Pompano Beach, FL 35451860 L1076241 03/12/1915:52 Cp SS 4 Cn 5Sr Qc GI Page 33 of 37 PAGE: 7 of 11 ACCREDITATIONS & LOCATIONS ONE LAB. NATIONWIDE. III Pace National is the only environmental laboratory accredited/certified to support your work nationwide from one location. One phone call, one point of contact, one laboratory. No other lab is as accessible or prepared to handle your needs throughout the country. Our capacity and capability from our single location laboratory is comparable to the collective totals of the network laboratories in our industry. The most significant benefit to our one location design is the design of our laboratory campus. The model is conducive to accelerated productivity, decreasing turn -around time, and preventing cross contamination, thus protecting sample integrity. our focus on premium quality and prompt service allows us to be YOUR LAB OF CHOICE. ' Not all certifications held by the laboratory are applicable to the results reported in the attached report. *Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace National. State Accreditations Alabama 40660 Nebraska NE-OS-15-05 Alaska 17-026 Nevada TN-03-2002-34 Arizona AZ0612 New Hampshire 2975 Arkansas 88-0469 New Jersey—NELAP TN002 California 2932 New Mexico' n/a Colorado TN00003 New York 11742 Connecticut PH-0197 North Carolina Env375 Florida E87487 North Carolina' DW21704 Georgia NELAP North Carolina' 41 Georgia' 923 North Dakota R-140 Idaho TN00003 Ohio—VAP CL0069 Illinois 200008 Oklahoma 9915 Indiana C-TN-01 Oregon TN200002 Iowa 364 Pennsylvania 68-02979 Kansas E-10277 Rhode Island LA000356 Kentucky 16 90010 South Carolina 84004 Kentucky 2 16 South Dakota n/a Louisiana A130792 Tennessee' ` 2006 Louisiana' LA180010 Texas T104704245-18-15 Maine TN0002 Texas 5 LAB0152 Maryland 324 Utah TN00003 Massachusetts M-TN003 Vermont VT2006 Michigan 9958 Virginia 460132 Minnesota 047-999-395 Washington C847 Mississippi TN00003 West Virginia 233 Missouri 340 Wisconsin 9980939910 Montana CERT0086 Wyoming A2LA Third Party Federal Accreditations A2LA — ISO 17025 1461.01 A2LA — ISO 17025 6 1461.02 Canada 1461.01 EPA—Crypto TN00003 AIHA-LAP,LLC EMLAP 100789 DOD 1461.01 USDA P330-15-00234 Drinking Water 2 Underground Storage Tanks 3 Aquatic Toxicity ° Chemical/Microbiological 5 Mold 6 Wastewater n/a Accreditation not applicable Our Locations Pace National has sixty-four client support centers that provide sample pickup and/or the delivery of sampling supplies. If you would like assistance from one of our support offices, please contact our main office. Pace National performs all testing at our central laboratory. ACCOUNT: Pace Analytical - Pompano Beach, FL PROJECT: 35451860 SDG: L1076241 DATE/TIME: 03/12/19 15:52 Ss Cn Qc GI Page 34 of 37 PAGE: 8 of 11 8 Al Chain of Custody Workorder: 35451860 Workorder Name: 2018-3057Melreese Golf Course C3 Results Requested By: 3/12/2019 ace Analytical www pacelabs .com Chn:tn R cr:kp Pace Analytical South Florida 3610 Park Central Blvd N Pompano Beach, FL 33064 Phone (954)582-4300 Email. christina.raschke@pacelabs.com State of Sample Origin: FL SC S-M W-2 Transfers 2 3 Released By 3/4/2019 14:12 P.O. � 7112 35451860001 Water Date/Time e/04/(f ( ''•9 Cooler Temperature on Receipt a Recejx$d By Custody Seal /YY] or • LLo Z`i LAB USE ONLY Date/Time i9 Received on Ice Y or Samples Intact Y or 1. 34o L :1- y z siN RAD SCREEN: <0,5 mR'ilI Wednesday. March 06. 2019 1:54:10 PM FMT-ALL-C-002rev.00 24March2009 o Page 35 of 37 Pace Analytical National Center for Testing & Innovation Cooler Receipt Form Client: (1 A( £/2 rL SI)C;#: li�b� .� Cooler Received/Opened On: 3 /' /19 'Temperature: , ,9 Received liy: .Jeremy Webb Signature: �04-f/ V Receipt Check List NP Yes No COC Seal Present / Intact? , COC Signed / Accurate? ----2 Bottles arrive intact? , —' Correct bottles used? — "—' Sufficient volume sent? If Applicable VOA Zero headspace? Preservation Correct / Checked? le 36 of 37 Andy Vann ace Anal vtical National Center for Testing & Innovation Login #: 11076241 Client: PACEPBFL Date: 03/07/19 Evaluated by: Chrystan Lyle IVUI1-LUIIIUi Ii/Ulli,c la.■•a.a.a. urr••a.•.•.•.. Sample Integrity —••--J Chain of Custody Clarification Parameter(s) past holding time Login Clarification Needed If Broken Container: Temperature not in range Chain of custody is incomplete Insufficient packing material around container Improper container t pH not in range. Please specify TCLP requested. X Improper handling by carrier (FedEx / UPS / Co I Insufficient sample volume. Received additional samples not listed on coc. Sample was frozen Sample is biphasic. Sample ids on containers do not match ids on coc Container lid not intact Vials received with headspace. Trip Blank not received. If no Chain of Custody: Broken container Client did not "X" analysis. Received by: X Broken container: Chain of Custody is missing Date/Time: Sufficient sample remains Temp./Cont. Rec./pH: Carrier: Tracking# Login Comments: 1 of 2 1L amb containers received broken for ID "SCS-MW-2" Client informed by: TSR Initials: NM Call Email X Voice Mail Client Contact: Christina Raschke Date: 3/7/19 Login Instructions: Remove 8141 and run 8151 only. Client will recollect for 8141. LE bo LE a6ed 1 Time: 2:32pm aceAnalytical www.pacelabs.com March 28, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35453239 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 11, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Some analyses have been subcontracted outside of the Pace Network. The subcontracted laboratory report has been attached. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry, EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 16 aceAnalytical www.pacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35453239 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35453239001 SCS-MW-2 Water 03/11/19 10:26 03/11/19 11:50 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 16 WO##35453239Container) : OF- CUSTODY RECORD .;odes Face Analytic? www.pacelahs.Cen 1111 I 1111 I 1111 I I I I I c Quote: Page 1 of 1 III AV Amt., Vial ES Encore Sampler CV Clear vcn PPV Propreserved vial P Amber PL C Plaslic container AL Amber Liter PL J Plaslic Jar CL Clear Liter Z Zlanli beg Amber TB illarbag 35453239 — AAP G Amber Glass WP hirl pak SJ Sod Jar G Gallon Jug Other TC Tnrm•cnro PPV Proproonrvod vial S eoz, 16oz. 32oz or IL. other 40m1 SOOmI 250m1 125 ml Esamplo: doxP= lox Plastic, BoxSJ= Box Solt Jar Address: 5 f `5 .�. I )0„,- - L� C.‘.� "V r' Sample City: !„'li4..-- -,:. I-.•cbi+'•"y State:'ik-- Zip: .5:,t'.fv! TRC Matrix Codes Attn: (�� jr---,. It •S-- tifJ Cn.,'L ti.� iC:`r, "Ear N„/.t�q�L�' pH SD Solid Wnsln SL Oii GW Ground Water SL Sludge -5 J_ �' av-'7/ email: fy1L CiYI!-�iI ('t <': j CCAM Phone: •-�,;) ", �JL, 1 Pres Codes ? EFF Effluent SO Soil Sediment AFW Annlyte Free H2O AO Aqueous. J Parameters 1 EXAMPLE Diss. Lead 6010 DWW W DrnnNmgWalnr PE Petroleum SW Surface Walar 0 Other Project �J J P � Name .L„e 1.,i.c'i 'k C•V Proj # -=yoi—'3L�-j•7 In --- , ML Misc. Liquid ml,eee',coy, ^!�,: Samp er �• / Circle One Event: Daily Weekly Monthly g � & ' Ouartel Si na ure(` .�,� j y Semi -Annual Annual N/A %' =. u� Preservative Type Codes Sample # /� (Jl Sample ID Collect Date Collect Time Matrix Code' - 1. a z �O , r x le 8 ^ vA?rim `_ J- A. None E. HCL I. Ice B. HNO3 F. McOH J. MCAA D. NaOH H. NaHS043 O?Otherlm # of Containers1 SI aRn I I 1 I REMARKS • ❑ ❑ I I I I LJ ❑ 2 11 Li I n I I I I LJ Li Li 3 I I I I 1 1 Li 11 I I ❑ ❑ 7 4 ❑ n LI 1 1 I I I I 1 I I I I I 5 El1I n n II II Li❑ Li 6 ❑ I I 11 n I I LiI n I-1 7 u n n❑ I I n I I ❑ 1 l 8 ❑ H n n 1 1 1 1 u❑ I I 9 MIII I1 II 11 II Li MI MI 10 11 II ❑ ❑ Li1I II I ❑ ,mT.A.i I nna EUUEBT (Ruth Foot Apprnvaq RUMH Short Hold Circle QA/QC Report Level p EDD(Fees MayApply) pp y) COC Condition Required State Certification Coolers #'s - Temp C p e N Today 10 2D 3D 4D 5D y N 1 2 3 4 CLP AFCEE OAPP Other ADIPT SEDD ERPIMS TSV CSV Other OK Incomplete PA GA SC LA TX IL LC J 1 2 3 4 5 _ Item Re quisIr ed by Affiliation Dfik ii. Time I Received by Affiliation at&f ._ Time ��/ //�� `/ bb +•�� ice` �; .-, t ` \ 1 i) t] \\\iii l !". J- 51•l . --1...�—+�;..�_ _ •" / J �-� I (r f 47 it c) Nnn-Cuninrm:mcn Found? Samples INTACT 1-.i l 1 r / I I ! c-7J -- ,. upon arrival? Rncmivro on Wnl Ica? Proper Pre::nmliven � / • Indicated? Rnrniwd within holdmq limn? Custody Intact? N4 - - :main Volnllles reed wear! hnndnpnce? Propmr Containers Used, bV r to CIIIV LGU JJY JVG fJVV rn evasion: F•ALL•C•007- Rev.00 C.O.C. Serial # - ace Analytical - Document -Name: Sample Condition Upon Receipt Form moment No.: F-FL-C-007 rev. 13 Document -Revised. May 30, 2018 Issuing Authority: Pace Florida Quality Office Sample Conditi. Proje�W®# 3545323� Due Date: 03/15/19 Project IVianagPM: CYR ClierCLIENY : 36-EEG Thermometer Used: State of Origin: Cooler#1 Temp.°C Cooler #2 Temp.'C Cooler #3 Temp.°C Cooler #4 Temp.°C Cooler #5 Temp.°C Cooler #6 Temp.°C • rm (SCUR) Date: Time: Date and Initials of person: Examining contents: Label: Deliver: pH: ❑ For WV projects, all containers verified to <_6 °C (Visual) (Correction Factor) (Actual) (Visual) (Correction Factor) (Actual) (Visual) (Correction Factor) (Actual) (Visual) (Correction Factor) (Actual) (Visual) (Correction Factor) (Actual) (Visual) (Correction Factor) (Actual) Courier: Fed Ex ❑ UPS Shipping Method: 0 First Overnight 0 Other Billing: Tracking # ❑ USPS ❑ Client , Commercial ❑ Pace 0 Priority Overnight ❑ Standard Ovemight ❑ Ground 0 Recipient ❑ Sender 0 Third Party 0 Credit Card Initials: ❑ Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun ❑ Other 0 International Priority 0 Unknown Custody Seal on Cooler/Box Present: [Yes ❑No Seals intact: ❑ Yes ❑ No Ice: Wet Blue Dry None Packing Material: ❑Bubble Wrap ❑ Bubble Bags ❑None ❑ Other Samples shorted to lab (If Yes, complete) Shorted Date: Comments: Shorted Time: Qty: Chain of Custody Present ❑Yes 0 No ❑N/A Chain of Custody Filled Out • ❑Yes 0 No ❑N/A Relinquished Signature & Sampler Name COC ❑Yes 0 No ❑N/A Samples Arrived within Hold Time ❑Yes 0 No ❑N/A Rush TAT requested on COC ❑Yes 0 No ❑N/A Sufficient Volume ❑Yes 0 No ❑N/A Correct Containers Used ❑Yes 0 No ❑N/A Containers Intact IYes 0 No ❑N/A Sample Labels match COC (sample IDs & date/time of collection) QYes 0 No ❑N/A All containers needing acid/base preservation have been checked. ❑Yes All Containers needing preservation are found to be in compliance with EPA recommendation: ❑Yes Exceptions: VOA, Califon, TOC, O&G, Carbamates ❑ No ❑N/A 0 No ❑N/A Preservation Information: Preservative: Lot #/Trace #: Date: Time: Initials: Headspace in VOA Vials? ( >6mm): ❑Yes 0 No [lN/A Trip Blank Present: ❑Yes 0 No ON/A Client Notification/ Resolution: Person Contacted: Comments! Resolution (use back for additional comments): Date/Time: Date: Page 4 of 16 Project Manager Review: /1ceAnalytical® National Center for Testing & Innovation A\ALYTICAL March 20, 2019 R Pace Analytical - Pompano Beach, FL Sample Delivery Group: Samples Received: Project Number: Description: Report To: L1078672 03/14/2019 35453239 Melreese Golf Course O RT Christina Raschke 3610 Park Central Blvd N Pompano Beach, FL 33064 Entire Report Reviewed By: wVt Nancy McLain Project Manager Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace National is performed per guidance provided in laboratory standard operating procedures: 060302, 060303, and 060304. Mount Ju iet, TN 37122 TABLE OF CONTENTS ONE LAB. NATIONWIDE. al Cp: Cover Page 1 Tc: Table of Contents 2 Ss: Sample Summary 3 Cn: Case Narrative 4 Sr: Sample Results 5 SCS-MW-2 L1078672-01 5 Qc: Quality Control Summary 6 OP Pesticides by Method 8141 6 GI: Glossary of Terms 9 Al: Accreditations & Locations 10 Sc: Sample Chain of Custody 11 ACCOUNT: Pace Analytical - Pompano Beach, FL Cn GI Al Page 6 of 16 PROJECT: SDG: DATE/TIME: PAGE: 35453239 L1078672 03/20/19 08:10 2 of 12 SAMPLE SUMMARY ONE LAB. NATIONWIDE. lit SCS-MW-2 L1078672-01 GW ull a: o; Collected date;time Received date/time 03/11'1910:26 03/14/19 09:30 'od OP Pesticides by Method 8141 ACCOUNT: Pace Analytical - Pompano Beach, FL Batch Dilution Preparation Analysis Analyst Location date/time date/time WG1250246 1 03/14/19 21:36 03/18/19 19:22 HMH Mt. Juliet, TN Cp Tc 4 Cn Sr 6 Qc GI AI Page 7 of 16 PROJECT: SDG: DATE/TIME: PAGE: 35453239 L1078672 03/20/19 08:10 3 of 12 CASE NARRATIVE ONE LAB. NATIONWIDE. 40 All sample aliquots were received at the correct temperature, in the proper containers, with the appropriate preservatives, and within method specified holding times, unless qualified or notated within the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data. Cuit Nancy McLain Project Manager ACCOUNT: Pace Analytical - Pompano Beach, FL Cp] Ss 5 Sr GI Al Page 8 of 16 PROJECT: SDG: DATE/TIME: PAGE: 35453239 L1078672 03/20/19 08:10 4 of 12 SCS-MW-2 Collected date/time: 03/11/19 10:26 OP Pesticides by Method 8141 SAMPLE RESULTS - 01 L1078672 ONE LAB. NATIONWIDE. Result Qualifier MDL RDL Dilution Analysis Batch to ug/I ug/I ug/I date / time .._...phos-Methyl 0.348 U 0.348 1.00 1 03/18/2019 19:22 WG1250246 Bolstar (Sulprofos) 0.205 U 0.205 1.00 1 03/18/2019 19:22 WG1250246 Chlorpyrifos 0.245 U 0.245 1.00 1 03/18/2019 19:22 WG1250246 Coumaphos 0.277 U 0.277 1.00 1 03/18/201919:22 WG1250246 Demeton,-0 and -S 0.341 U 0.341 2.00 1 03/18/2019 19:22 WG1250246 Diazinon 0.377 U 0.377 1.00 1 03/18/201919:22 WG1250246 Dichlorvos 0.212 U 0.212 2.00 1 03/18/201919:22 WG1250246 Dimethoate 0.105 U 0.105 1.00 1 03/18/201919:22 WG1250246 Disulfoton 0.277 U 0.277 1.00 1 03/18/2019 19:22 WG1250246 EPN 0.261 U 0.261 1.00 1 03/18/2019 19:22 WG1250246 Ethoprop 0.354 U 0.354 1.00 1 03/18/2019 19:22 WG1250246 Ethyl Parathion 0.292 U 0.292 1.00 1 03/18/201919:22 WG1250246 Fensulfothion 0.130 U 0.130 1.00 1 03/18/2019 19:22 WG1250246 Fenthion 0.266 U 0.266 1.00 1 03/18/2019 19:22 WG1250246 Malathion 0.173 U 0.173 1.00 1 03/18/2019 19:22 WG1250246 Merphos 0.267 U 0.267 2.00 1 03/18/201919:22 WG1250246 Methyl parathion 0.257 U 0.257 1.00 1 03/18/2019 19:22 WG1250246 Mevinphos 0.118 U 0.118 1.00 1 03/18/2019 19:22 WG1250246 Naled 0.289 U 0.289 1.00 1 03/18/201919:22 WG1250246 Phorate 0.282 U 0.282 1.00 1 03/18/201919:22 WG1250246 Ronnel 0.252 U 0.252 1.00 1 03/18/201919:22 WG1250246 Stirophos 0.226 U 0.226 1.00 1 03/18/201919:22 WG1250246 Sulfotep 0.202 U 0.202 1.00 1 03/18/201919:22 WG1250246 TEPP 9.74 U 9.74 20.0 1 03/18/201919:22 WG1250246 Tokuthion (Prothothiofos) 0.254 U 0.254 1.00 1 03/18/2019 19:22 WG1250246 T- hloronate 0.213 U 0.213 1.00 1 03/18/201919:22 WG1250246 -Triphenyl Phosphate 89.6 42.0-129 03/18/2019 19:22 W61250246 ACCOUNT: Pace Analytical - Pompano Beach, FL Cp Tc SS 4 Cn SSr 6 Qc GI Al Page 9 of 16 PROJECT: SDG: DATE/TIME: PAGE: 35453239 L1078672 03/20/19 08:10 5 of 12 WG1250246 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. OP Pesticides by Method 8141 L1078672-01 Method Blank (MB) (MB) R3393056-1 03/18/19 17:47 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I Azinphos-Methyl 0.348 U 0.348 1.00 Bolstar (Sulprofos) 0.205 U 0.205 1.00 Chlorpyrifos 0.245 U 0.245 1.00 Coumaphos 0.277 U 0.277 1.00 Demeton,-0 and -S 0.341 U 0.341 2.00 Diazinon 0.377 U 0.377 1.00 Dichlorvos 0.212 U 0.212 2.00 Dimethoate 0.105 U 0.105 1.00 Disulfoton 0.277 U 0.277 1.00 EPN 0.261 U 0.261 1.00 Ethoprop 0.354 U 0.354 1.00 Ethyl Parathion 0.292 U 0.292 1.00 Fensulfothion 0.130 U 0.130 1.00 Fenthion 0.266 U 0.266 1.00 Malathion 0.173 U 0.173 1.00 Merphos 0.267 U 0.267 2.00 Methyl parathion 0.257 U 0.257 1.00 Mevinphos 0.118 U 0.118 1.00 Naled 0.289 U 0.289 1.00 Phorate 0.282 U 0.282 1.00 Ronnel 0.252 U 0.252 1.00 Stirophos 0.226 U 0.226 1.00 Sulfotep 0.202 U 0.202 1.00 TEPP 9.74 U 9.74 20.0 Tokuthion (Prothothiofos) 0.254 U 0.254 1.00 Trichloronate 0.213 U 0.213 1.00 (S) Triphenyl Phosphate 92.6 42.0-129 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3393056-2 03/18/19 18:19 • (LCSD) R3393056-3 03/18/19 18:51 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I % % % % % Azinphos-Methyl 5.00 4.41 4.45 88.2 89.0 43.0-142 0.903 20 Bolstar (Sulprofos) 5.00 4.30 4.45 86.0 89.0 47.0-128 3.43 20 Chlorpyrifos 5.00 4.58 4.70 91.6 94.0 50.0-126 2.59 20 Coumaphos 5.00 4.79 4.78 95.8 95.6 37.0-137 0.209 20 Demeton,-0 and -S 2.50 2.01 1.96 80.4 78.4 22.0-150 2.52 24 Diazinon 5.00 4.70 4.55 94.0 91.0 54.0-130 3.24 20 Cp 3 SS 4Cn Cn �I 6 Qc GI ^AI "-,ge10of16 ACCOUNT: PROJECT: SDG: DATE/TIME: 'AGE: Pace Analytical - Pompano Beach, FL 35453239 L1078672 03/20/19 08:10 6 of 12 WG12 246 QUALITY CO' ROL SUMMARY OP Pesticl. _ by Method 8141 L1. ./2-01 ONE LAB.'' - DNWIDE. Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3393056-2 03/18/19 18:19 • (LCSD) R3393056-3 03/18/19 18:51 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I % % % % % Dichlorvos 5.00 4.77 4.79 95.4 95.8 43.0-135 0.418 24 Dimethoate 5.00 3.20 3.27 64.0 65.4 27.0-120 2.16 27 Disulfoton 5.00 4.09 3.96 81.8 79.2 44.0-136 3.23 21 EPN 5.00 5.16 5.18 103 104 31.0-143 0.387 21 Ethoprop 5.00 4.55 4.47 91.0 89.4 52.0-130 1.77 20 Ethyl Parathion 5.00 4.71 4.72 94.2 94.4 42.0-134 0.212 20 Fensulfothion 5.00 4.67 4.74 93.4 94.8 42.0-137 1.49 20 Fenthion 5.00 4.23 4.22 84.6 84.4 53.0-133 0.237 20 Malathion 5.00 4.36 4.36 87.2 87.2 47.0-121 0.000 20 Merphos 5.00 3.78 3.64 75.6 72.8 14.0-123 3.77 25 Methyl parathion 5.00 4.54 4.61 90.8 92.2 43.0-135 1.53 20 Mevinphos 5.00 4.35 4.24 87.0 84.8 49.0-123 2.56 23 Naled 5.00 4.45 4.49 89.0 89.8 25.0-126 0.895 26 Phorate 5.00 4.15 3.94 83.0 78.8 44.0-129 5.19 20 Ronnel 5.00 4.28 4.31 85.6 86.2 51.0-125 0.698 20 Stirophos 5.00 4.64 4.54 92.8 90.8 53.0-125 2.18 20 Sulfotep 5.00 4.74 4.72 94.8 94.4 40.0-140 0.423 22 TEPP 50.0 31.3 33.1 62.6 66.2 18.0-122 5.59 32 Tokuthion (Prothothiofos) 5.00 4.61 4.56 92.2 91.2 50.0-128 1.09 20 Trichloronate 5.00 4.34 4.42 86.8 88.4 47.0-130 1.83 21 (S) Trlphenyl Phosphate 93.4 94.4 42.0-129 L1078672-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1078672-01 03/18/19 19:22 • (MS) R3393056-4 03/18/19 19:54 • (MSD) R3393056-5 03/18/19 20:26 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I ug/I % % % % % Azinphos-Methyl 5.00 0.348 4.37 4.32 87.4 86.4 1 29.0-157 1.15 20 Bolster (Sulprofos) 5.00 0.205 4.19 4.25 83.8 85.0 1 37.0-138 1.42 20 Chlorpyrifos 5.00 0.245 4.31 4.39 86.2 87.8 1 42.0-131 1.84 20 Coumaphos 5.00 0.277 4.58 4.60 91.6 92.0 1 31.0-150 0.436 20 Demeton,-0 and -S 2.50 0.341 3.17 3.16 127 126 1 30.0-152 0.316 20 Diazinon 5.00 0.377 4.47 4.54 89.4 90.8 1 47.0-134 1.55 20 Dichlorvos 5.00 0.212 4.34 4.35 86.8 87.0 1 39.0-140 0.230 22 Dimethoate 5.00 0.105 3.44 3.31 68.8 66.2 1 17.0-129 3.85 20 Disulfoton 5.00 0.277 4.45 4.43 89.0 88.6 1 42.0-131 0.450 21 EPN 5.00 0.261 5.05 5.11 101 102 1 17.0-155 1.18 20 Ethoprop 5.00 0.354 4.27 4.26 85.4 85.2 1 46.0-133 0.234 20 Ethyl Parathion 5.00 0.292 4.49 4.56 89.8 91.2 1 30.0-138 1.55 20 ACCOUNT: Pace Analytical - Pompano Beach, FL Cp 7c Ss 4 Cn 5 Sr Qc 7GI 3AI Page 11 of 16 PROJECT: SDG: DATE/TIME: PAGE: 35453239 L1078672 03/20/19 08:10 7 of 12 WG1250246 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. SA OP Pesticides by Method 8141 L1078672-01 L1078672-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1078672-01 03/18/19 19:22 • (MS) R3393056-4 03/18/19 19:54 • (MSD) R3393056-5 03/18/19 20:26 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I ug/I % % % % % Fensulfothion 5.00 0.130 4.71 4.53 94.2 90.6 1 36.0-145 3.90 20 Fenthion 5.00 0.266 3.99 4.01 79.8 80.2 1 46.0-140 0.500 20 Malathion 5.00 0.173 4.14 4.23 82.8 84.6 1 39.0-126 2.15 20 Merphos 5.00 0.267 3.32 3.69 66.4 73.8 1 10.0-120 10.6 27 Methyl parathion 5.00 0.257 4.30 4.34 86.0 86.8 1 28.0-142 0.926 20 Mevinphos 5.00 0.118 4.01 4.08 80.2 81.6 1 38.0-134 1.73 20 Naled 5.00 0.289 4.05 4.21 81.0 84.2 1 14.0-130 P 3.87 20 Phorate 5.00 0.282 3.86 3.81 77.2 76.2 1 38.0-134 1.30 20 Ronnel 5.00 0.252 4.09 4.11 81.8 82.2 1 42.0-131 0.488 20 Stirophos 5.00 0.226 4.44 4.53 88.8 90.6 1 33.0-143 2.01 20 Sulfotep 5.00 0.202 4.46 4.45 89.2 89.0 1 34.0-143 0.224 20 TEPP 50.0 9.74 39.9 38.7 79.8 77.4 1 38.0-120 3.05 25 Tokuthion (Prothothiofos) 5,00 0.254 4.30 4.35 86.0 87.0 1 35.0-140 1.16 24 Trichloronate 5.00 0.213 4.15 4.09 83.0 81.8 1 41.0-133 1.46 20 (S) Triphenyl Phosphate 86.8 89.4 42.0-129 ACCOUNT: Pace Analytical - Pompano Beach, FL Cp 3 Ss Cn 6 Qc GI -Al ,---. 'ge12of16 PROJECT: SDG: DATE/TIME: AGE: 35453239 L1078672 03/20/19 08:10 8 of 12 GLOSSARY OF TERMS ONE LAB. NATIONWIDE. AO Guide to Reading and Understanding Your Laboratory Report The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and if you have additional questions please contact your project representative. Abbreviations and Definitions MDL RDL Rec. RPD SDG (S) Analyte Dilution Limits Original Sample Qualifier Result Uncertainty (Radiochemistry) Case Narrative (Cn) Quality Control Summary (Qc) Sample Chain of Custody (Sc) Sample Results (Sr) Sample Summary (Ss) Qualifier Method Detection Limit. Reported Detection Limit. Recovery. Relative Percent Difference. Sample Delivery Group. Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be detected in all environmental media. The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes reported. If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor. These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or duplicated within these ranges. The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control sample. The Original Sample may not be included within the reported SDG. This column provides a letter and/or number designation that corresponds to additional information concerning the result reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable. The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL" (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte. Confidence level of 2 sigma. A brief discussion about the included sample results, including a discussion of any non -conformances to protocol observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report. This section of the report includes the results of the laboratory quality control analyses required by procedure or analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material. This is the document created in the field when your samples were initially collected. This is used to verify the time and date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the samples from the time of collection until delivery to the laboratory for analysis. This section of your report will provide the results of all testing performed on your samples. These results are provided by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for each sample will provide the name and method number for the analysis reported. This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and times of preparation and/or analysis. Description P U RPD between the primary and confirmatory analysis exceeded 40%. Indicates the compound was analyzed for but not detected above the method detection limit. ACCOUNT: PROJECT: SDG: Pace Analytical - Pompano Beach, FL 35453239 L1078672 DATE/TIME: 03/20/19 08:10 Cp Tc Ss 4 Cn SSr Qc GI Al Page 13 of 16 PAGE: 9 of 12 ACCREDITATIONS & LOCATIONS ONE LAB. NATIONWIDE. .40 Pace National is the only environmental laboratory accredited/certified to support your work nationwide from one location. One phone call, one point of contact, one laboratory. No other lab is as accessible or prepared to handle your needs throughout the country. Our capacity and capability from our single location laboratory is comparable to the collective totals of the network laboratories in our industry. The most significant benefit to our one location design is the design of our laboratory campus. The model is conducive to accelerated productivity, decreasing turn -around time, and preventing cross contamination, thus protecting sample integrity. Our focus on premium quality and prompt service allows us to be YOUR LAB OF CHOICE. ' Not all certifications held by the laboratory are applicable to the results reported in the attached report. • Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace National. State Accreditations Alabama 40660 Nebraska NE-0S-15-05 Alaska 17-026 Nevada TN-03-2002-34 Arizona AZ0612 New Hampshire 2975 Arkansas 88-0469 New Jersey—NELAP TN002 California 2932 New Mexico' n/a Colorado TN00003 New York 11742 Connecticut PH-0197 North Carolina Env375 Florida E87487 North Carolina' DW21704 Georgia NELAP North Carolina' 41 Georgia' 923 North Dakota R-140 Idaho TN00003 Ohio—VAP CL0069 Illinois 200008 Oklahoma 9915 Indiana C-TN-01 Oregon TN200002 Iowa 364 Pennsylvania 68-02979 Kansas E-10277 Rhode Island LA000356 Kentucky" 90010 South Carolina 84004 Kentucky' 16 South Dakota n/a Louisiana A130792 Tennessee' ° 2006 Louisiana' LA180010 Texas T104704245-18-15 Maine TN0002 Texas LAB0152 Maryland 324 Utah TN00003 Massachusetts M-TN003 Vermont VT2006 Michigan 9958 Virginia 460132 Minnesota 047-999-395 Washington C847 Mississippi TN00003 West Virginia 233 Missouri 340 Wisconsin 9980939910 Montana CERT0086 Wyoming A2LA Third Party Federal Accreditations A2LA — ISO 17025 1461.01 A2LA— ISO 17025 5 1461.02 Canada 1461.01 EPA—Crypto TN00003 AIHA-LAP,LLC EMLAP 100789 DOD 1461.01 USDA P330-15-00234 Drinking Water 2 Underground Storage Tanks ' Aquatic Toxicity ° Chemical/Microbiological 5 Mold ` Wastewater n/a Accreditation not applicable Our Locations Pace National has sixty-four client support centers that provide sample pickup and/or the delivery of sampling supplies. If you would like assistance from one of our support offices, please contact our main office. Pace National performs all testing at our central laboratory. WA MT VA" Az T UT NE Cod �l Ss 4 Cn GI 3 Al ACCOUNT: Pace Analytical - Pompano Beach, FL Page 14 of 16 PROJECT: SDG: DATE/TIME: PAGE 35453239 L1078672 03/20/19 08:10 10 of 12 Chain of Custody Workorder: 35453239 Workorder Name: Christina Reschke Pace Analytical South Florida 3610 Park Central Blvd N Pompano Beach, FL 33064 Phone (954)582-4300 Email: christina.raschke@pacelabs.com State of Sample Origin: FL pact 1110111110111111111 ime 1 SCS-MW.2 3/11/2019 10 26 2 3 4 1 2 3 Released By INV ), t ce Cooler Temperature on Receipt i °C v. L Date/Time Melreese Golf Course Lab ID 35453239001 Matrix Water Received By Custody Seal Y or 60 1 Results Requested By: 3/15/2019 a u Date/Time 4/eihi) aceAnalytical www Paoelabs.com LAB USE ONLY L Io7S.j472• �1 Received on Ice Log9, 3Q�qi .,?3Cc7 FIAEI • mP,/! r Tuesday. March 12, 2019 11 36.40 AM Y or N 1 13p75 Samples Intact Y or N FMT-ALL-C-002rev 00 24March2009 Page 1 of Page 15 of 16 Pace Analytical National Center for Testing & Innovation Cooler Receipt Form client.(,126 I-- L SDG' ir __f/ -) l+ cooler Received/Opened On: 3 / / 11l I emperaturc: Received By: Kristin Willis Signature: ' +L :, Receipt Check List NP Yes No COC Seal Present / Intact? COC Signed / Accurate? Bottles arrive intact? Correct bottles used? Sufficient volume sent? if Applicable VOA Zero headspace? Preservation Correct / Checked? —age 16 of 16 aceAnalytical www.pacelabs.com March 28, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451839 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 05, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry, EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 18 aceAnalytical www.pacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35451839 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35451839001 SCS-MW-2 Water 03/04/19 14:12 03/05/19 17:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 18 ' laaceAna/y1ical CHAIN-OF-CU1WO# : 35451839 I ne unatn-ot-custody iics 131 I Ili II III I iilin :curately. Section A Section B Sect Required Client Information: Required Project Information: Involc 35451839 Page : 1 Of 1 Company EERG Environmental Services, LLC Report To =OF= kkcin A4.A. V"�Y Attenuc. Address 5751 Miami Lakes Dr. Copy To: -0 j G`t ,�6,r. Company Name Hialeah, FL 33014 Address. Rogulatory Agency Email ,4_n,.,` ei,Ai ,off Purchase Order #: Pace Quote Phone (305)374-8300 !Flax ff Project Name Z`CZ2y� r o (�.-,ryl' -e2 C— 9t S Pace Project Manager. ©p /". 1 9 christine.raschke acelabs.com, State! Location • • Requested Due Date �-�.. -> " i ;%\. Project #: 2018-305/ Pace Profile # / FL Requ A al Filtered (YIN MATRIX cone MATRIX CODE (sea valid codes to left) ISAMPLE TYPE (G=GRAB C=COMP) COLLECTED SAMPLE TEMP AT COLLECTION et OF CONTAINERS Preservatives , 2 >- i c) `0 Diinknnp Water OW Water WT War.. Water WW Product P SAMPLE ID olmsmm soL START END Unpreserved 1 HNO3 Na2S203 I Other Analyses Test 8260 VOC PAH by 8270 SIM TRPH FL -PRO Pesticides 8081(1„,v,, ' Pesticides 8141(-1 Herbicides 8151(CWp� tr ,. o cO OSam xI- 0N 0— 6010 Ba, Cd, Cr, Se, Ag, 7470 Hg vt, As, 7b/C .10,Ce- o.i CV} 'Z •$# -'' Residual Chlonne VON) One Character per box. "Pe WP Air R(A-Z, 0-9 ! , -) other O le Ids must be unique TIue Ts DATE TIME DATE TIME c _ UH = 0 Z m 1 Git / i 1/ /' 2 3 4. 5 6 7 8 9 10 11 12 ADDITIONAL COMMENTS. REUNQUISHED BY f AFFIUATJON DATE TIME - :_. --ACCEPTED BY !AFFILIATION DATE . . TIME SAMPLE CONDITIONS r ,f �5 `I ti Y SAMPLER NAME AND SIGNATURE • TEMP in C v u z o z E z PRINT Name of SAMPLER: 1 N 1 `� / SIGNATURE of SAMPLER: - ( ,' (, / A /DATE Signed: co 0 CO a) d Document Nerve Sample Condition Upon Rec_i.,. _ ent Revise,. '. ay 30 2018 —i Pace Al OCi.r ent Fva WO#:35451839 PM: CTR Project tCLIENT : 36-EEO Project Manager. Client: Thermometer Used I l_J J Date ssaing Authcnty. cica Quality Office Due Date: 03/15/19 Time IR- Date and Initials of p Examining contents: Label: Deliver; ►` / State of ngi ! \ 1Ct( `— , , l'or VV.,' p c;ectttss G _. e s verified to s^c Cooler #1 Temp.`C�(Visual) 0(Correction Factor) 3. V (Actual) j 5arnr.es or ice cooling Process as oeoun Cooler #2 Temp:C Intel )) (Visual) �. 0 (Correction Factor} �. 0 (Actual) Sa77E,S'S 7,7 ce cooling process.".as cecun Cooler #3 Temp.'C 5 , (Visual) 0 _0 (Correction Factor) , . 5 (Actual) SET:::__ ce coara process nes beau-. (Correction Factor) (Actual) L S2-.c:e=_ c7 ice, cooling process has begun (Correction Factor) (Actual) [ Saoe_ 27 ice. coc!ing c•c:ess'las begun (Correction Factor) (Actual) [ Sarnpies on ice, cooling c.00__s -as beach, Cooler #4 Temp.'C Cooler #5 Temp.'C Cooler #6 Temp.'C Courier: — Fed Ex (Visual) (Visual) (Visual) — - UPS U USPS — - Client Shipping Method: - First Overnight _ Priority Overnight Other Billing: Recipient Tracking # Custody Seal on Cooler!Box Present: Packing Material: Buoole Wrap Samples shorted to lab (If Yes, complete) = Sender CommerciatX Pace Standard Overnight - Ground = Third Party IT Credit Card Seals intact: Yes ubble Bags ENone Other 1 v I Shorted Date Comments: 5In:hals t [ Other International Priority Unknown lue Dry None Shorted Time \)) Chain of Custody Present es _ No =N/A Chain of Custody Filled Out _ 'es = No N/A Relinquished Signature & Sampler Name COC _ e= No =N/A �s Samples Arrived within Hold Time Yes - No IN/A Rush TAT requested on COC _Yes N/A Sufficient Volume s = No :-N/A Correct Containers Used _ es _ No =N/A Containers Intact es = No -N/A Sample Labels match COC (semp!e IDs & date!time of �/ collection) ,�'rs N/A ,j9�1�1QJ'p` All containers needing acid -base preservation have been checked Yes _ No _ /A All Containers needing preservation are found elk compliance with EPA recommendation 3 es hYCl� No (A Exceptions VGA Coi tcrm T C, O&G Carbamates Preservation Information Preservative Lot `a; T race;# + i.-/ Date i i $ Initials Headspace in VOA Vials'? (>6mm) -Yes = No = /A Trip Blank Present: =Yes _ o /A Client Notification/ Resolution: Person Contacted Comments/ Resolution (use back for additional comments): Date+Time Project Manager Review Date Page 4 of 18 ace Analytical T wH.v.pacelabs.com www.pacelabs.com Report Prepared for: Christina Raschke PASI Florida 3610 Park Central Blvd N Pompano Beach FL 33064 REPORT OF LABORATORY ANALYSIS FOR PCDD/PCDF Report Prepared Date: March 14, 2019 Report No 10466121_8290FC_DFR Pace Analytical Services, LLC. 1700 Elm Street Minneapolis, MN 55414 Phone: 612.607.1700 Fax: 612.607.6444 Report Information: Pace Project #: 10466121 Sample Receipt Date: 03/07/2019 Client Project #: 35451839 Client Sub PO #: N/A State Cert #: E87605 Invoicing & Reporting Options: The report provided has been invoiced as a Level 2 PCDD/PCDF Report. If an upgrade of this report package is requested, an additional charge may be applied. Please review the attached invoice for accuracy and forward any questions to Kirsten Hogberg, your Pace Project Manager. This report has been reviewed by: March 15, 2019 Kirsten Hogberg, Project Manager (612) 607-6407 (612) 607-6444 (fax) kirsten.hogberg@pacelabs.com Report of Laboratory Analysis Thisreportshould notbereproduced,excepti nfull, withoutthewrittenconsentofPaceAnalyticalServices,Inc. Theresultsrelateonlyt othesamplesincludedinthisreport. Page 5 of 18 Page 1 of 14 aceAnalytical Pace Analytical Services, LLC. 1700 Elm Street Minneapolis, MN 55414 Phone: 612.607.1700 Fax: 612.607.6444 DISCUSSION This report presents the results from the analysis performed on one sample submitted by a representative of Pace Analytical Services, LLC. The sample was analyzed for the presence or absence of polychlorodibenzo-p-dioxins (PCDDs) and polychlorodibenzofurans (PCDFs) using a modified version of USEPA Method 8290. The reporting limits were based on signal-to-noise measurements. Estimated Maximum Possible Concentration (EMPC) values were treated as positives in the toxic equivalence calculations. Per request, estimated detection limit (EDL) values were provided and flagged "U" where the target analytes were not detected. The recoveries of the isotopically -labeled PCDD/PCDF internal standards in the sample extract ranged from 34-63%. Except for four low values, which were flagged "R" on the results tables, the labeled internal standard recoveries obtained for this project were within the 40-135% target range specified in Method 8290. Also, since the quantification of the native 2,3,7,8-substituted congeners was based on isotope dilution, the data were automatically corrected for recovery and accurate values were obtained. A laboratory method blank was prepared and analyzed with the sample batch as part of our routine quality control procedures. The results show that PCDDs and PCDFs were not detected. These results indicate that the sample preparation procedures did not significantly impact the results of the field sample determinations. Laboratory spike samples were also prepared with the sample batch using clean reference matrix that had been fortified with native standard materials. The results show that the spiked native compounds were recovered at 92-120% with relative percent differences of 0.0-10.3%. These results were within the target ranges for the method. Matrix spikes were not prepared with the sample batch. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466121_8290FC_DFR Page 6 of 18 Page 2 of 14 TM Minnesota Laboratory Certifications Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612-607-6444 Authority Certificate # Authority Certificate # A2LA 2926.01 Minnesota - Pet 1240 Alabama 40770 Mississippi MN00064 Alaska - DW MN00064 Missouri - DW 10100 Alaska - UST 17-009 Montana CERT0092 Arizona AZ0014 Nebraska N E-OS-18-06 Arkansas - DW MN00064 Nevada MN00064 Arkansas - WW 88-0680 New Hampshire 2081 CNMI Saipan MP0003 New Jersey (NE MN002 California 2929 New York 11647 Colorado MN00064 North Carolina 27700 Connecticut PH-0256 North Carolina - 27700 EPA Region 8+ via MN 027-053 North Carolina - 530 Florida (NELAP E87605 North Dakota R-036 Georgia 959 Ohio - DW 41244 Guam 17-001r Ohio - VAP CL101 Hawaii MN00064 Oklahoma 9507 Idaho MN00064 Oregon - Primar MN300001 Illinois 200011 Oregon - Secon MN200001 Indiana C-MN-01 Pennsylvania 68-00563 Iowa 368 Puerto Rico MN00064 Kansas E-10167 South Carolina 74003 Kentucky - DW 90062 South Dakota NA Kentucky - WW 90062 Tennessee TN02818 Louisiana - DE 03086 Texas T104704192 Louisiana - DW MN00064 Utah (NELAP) MN00064 Maine MN00064 Virginia 460163 Maryland 322 Washington C486 Massachusetts M-MN064 West Virginia - 382 Michigan 9909 West Virginia - 9952C Minnesota 027-053-137 Wisconsin 999407970 Minnesota - De via MN 027-053 Wyoming - UST 2926.01 REPORT OF LABORATORYANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466121_8290FC_DFR Page 7 of 18 Page 3 of 14 Appendix A Sample Management Report No 10466121_8290FC_IiW Analytical Services, Inc. Page 8 of 18 Page 4 of 14 Ida 3d06Z8 1Z1-991701, ON pode Chain of Custody Samples were sent directly to the Subcontracting Laboratory. Workorder: 35451839 Workorder Name: 2018-3057Melreese Golf Course State Of Origin: FL Cert. Needed: Yes No Owner Received Date: 3/5/2019 ceAnalytical' Www.aacelaea,corn Results Requested By: 3/15/2019 �9. Christina Raschke Pace Analytical South Florida 3610 Park Central Blvd N Pompano Beach, FL 33064 Phone (954)582-4300 Pace Analytical Minnesota 1700 Elm Street SE Suite 200 Minneapolis, MN 55414 Phone (612)607-1700 1111111211111111 am PS 3/4/2019 14:12 35451839001 Water 2 3 Cooler Tem' erature on Recei • t : , °C WOti:10466121 II�,� I I I II I NI I I tll I I I 0■ ■■©MBE■■ ■■■NI■ ■■ ■■■■■■■■■■■■■■ ■■ ■■■■■■.■■■■■■■ OHM M1111111111111111111111111MMEMMIIIII ■■■■■■■■■■■■■■■■■■ LAB USE ONLY ul+'\ Custod Seal Y or N "**In order to maintain client confidentiality, location/name of the sampling site, sampler's name and signature may not be provided on this COC document. This chain of custody is considered complete as is since this information is available in the owner laboratory. CD co Tuesday, March 05, 2019 7:19:27 PM FMT-ALL-C-002rev.00 24March2009 Page 1 of 1 Ai a / ..PaceAnalytical Document Name: Sample Condition Upon Receipt Form 1 I Document Revised: 06Febzo1.9 _ Page 1 of 1 Document No.: F-MN-L-213-rev.25 I I Issuing Authority: Pace Minnesota Quality Office Sample Condition Upon Receipt Courier: Project #: W011:10466121 PM: KNH Due Date: 03/21/19 ❑LISPS ❑Client CLIENT: PASI-FL ❑Pace_ ❑SpeeDee ❑Commercial see Exception Z t I Tracking Number: ! _ ,e7-1 ❑ Client Name: ioo, ‘0,--,f( Fed Ex UPS Custody Seal on Cooler/Box Present? es ❑ No Seals Intact? v[fYes []No Biological Tissue Frozen? ❑Yes ❑No N/A rr Packing Material: Bubble Wrap ,,ubble Bags :None ❑Othher1Jo /: Temp Blank? Eves , Thermometer: 0 G87A9155100842 J 87A91706002S4 Type oflce: I/IWet ❑Blue ❑None Dry :Welted Note: Each West Virginia Sample must have temp taken (no temp blanks) d� Temp should be above freezing to 6°C Cooler Temp Read w/temp blank: ° Correction Factor: Cooler Temp Corrected w/temp blank : °C Average Corrected Temp See Excel 'ons (no temp blank only): oC USDA Regulated Soli: (( N/A, water sample/Other: ) Date/Initials of Person Examining Contents: Did samples originate in a quarantine zone within the United States: At, AR, CA, FL, GA, Did samples originate from a foreign source (internationally, including ID, LA. MS, NC, NM, NY, OK, OR, SC, TN, TX or VA (check maps)? ❑Yes ❑No. Hawaii and Puerto Rico)? ❑Yes No If Yes to either question, fill out a Regulated Soil Checklist (F-MN-Q-338) and include with SCUR/COC paperwork. COMMENTS: Chain of Custody Present and Filled Out? es DNo 1. Chain of Custody Relinquished? es ❑No 2. Sampler Name and/or Signature on CDC? ❑Yes DNo AA 3. Samples Arrived within Hold Time? .es DNo 4. Short Hold Time Analysis (<72 hr)? ['Yes 211N'0 5. ❑Fecal Coliform ❑HPC ❑Total Coliform/E colt ❑BOD/cBOD ❑Hex Chrome ❑Turbidity ❑Nitrate ❑Nitrite ❑Orthophos ❑Other Rush Turn Around Time Requested? Oyes 0 6. Sufficient Volume? DNo 7. Correct Containers Used? -Pace Containers Used? .'es Wives jZes ❑No ❑No 8. Containers Intact? ��Ves Cl No 9. Field Filtered Volume Received for Dissolved Tests? ❑Yes ❑No /N/A 10. Is sediment visible in the dissolved container? IIYes No Is sufficient information available to reconcile the samples to the COC Matrix: Water ❑Soil ❑Oil pother es DNo 11. If no, write ID/ Date/Time on Container Below: See Exception =—I All cont iners needing acid/base preservation have been checked? All containers needing preservation are found to be in compliance with EPA recommendation? (HNO3, H2SO4, <2pH, NaOH >9 Sulfide, NaOH>12 Cyanide) Exceptions: VOA, Coliform, TOC/DOC Oil and Grease, DRO/8015 (water) and Dioxin/PFAS ❑Yes ❑Yes ❑Yes DNo DNo DNo /A �/ �N/A N/A 12. Sample # Acetate See Exception ❑ NaOH II HNO3 • H2SO4 ❑Zinc Positive For Res. Yes Chlorine? No Headspace in VOA Visis (greater than 6mm)? ❑ves 0No jhIA 13. See Exception ❑ Trip Blank Present? ❑ves f'lv... DNo riv,, n hj /A 14, r7(nI IA onro Trin R'.-n!e ! nt fif i irrhxori'• CLIENT NOTIFICATION/RESOLUTION Person Contacted: Co; .,ants/Reso!utien: Dzte/Time: Field Data Required? ❑Yes I]No Project Manager Review: Note: !e E disc epana wi ho!cl„ incur r ec'i preservative, Out of temp, !nco, rocs r.-.); stainers). Report No 10466121_8290FC_DFR Date: 3/8/2019 be _:. ;. ;.;i:. \.... Cc:_.. _ EHNS Cs :. :_...... Orficz ; Page 10 of 18 Page 6 of 14 .PaceA✓naIyL1cal Document Name: Document Revised: 04Feb2019 SCUR Exception Form — Coolers Above 6°C Page 1 of 1 Document No.: F-Mkt-C-298-Rev.01 Issuing Authority: Pace Minnesota Quality Office During sample triage, this form is to be placed in each cooler that arrives above 6.0 degrees Celsius SCUR Exceptions: Workorder #o Container ## of- PM '' ii? Out of Temp Sample IDs 1 Type [bntainers If yes, indicate who was contacted/date/time. If no, indicate reason why. Other Issues Issue Type: Sample ID -Container- Type ## of Containers:. Sample ID Multiple Cooler Project?`D es`.DNo, If you answered yes; fifi:outinformatiod to the left. No Temp Blank Read Temp Corrected Temp tt Average Temp fj L L r t 0 Tracking_Nurrober pH Adjustment t Log for Preserved Samples i pf Amount Type of I Upon Date Time Added Lott? I p8 In Compliance Preserv. I Receipt j Adjusted Adjusted I (mL) I Added I After after addition? j initials j ElYes ❑i'o Yes ON!o I I IYes LIN'o Report No 104661218290FC_DFR Page 11 of 18 Page 7 of 14 Pace Analytical Services. LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 AnalyticalTM Reporting Flags A = Reporting Limit based on signal to noise B = Less than 10x higher than method blank level C = Result obtained from confirmation analysis D = Result obtained from analysis of diluted sample E = Exceeds calibration range I = Interferencepresent J = Estimated value L = Suppressive interference, analyte may be biased low Nn = Value obtained from additional analysis P = PCDEInterference R = Recovery outside target range S = Peak saturated U = Analyte not detected V = Result verified by confirmation analysis X = %D Exceeds limits Y = Calculated using average of daily RFs * = SeeDiscussion REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466121_8290FC_DFR Tel: 612-607-1700 Fax: 612-607-6444 Page 12 of 18 Page 8 of 14 Appendix B Sample Analysis Summary Report No 10466121_8290FC_CINReAnalytical Services, Inc. Page 13 of 18 Page 9 of 14 Analytical Client's Sample ID Lab Sample ID Filename Injected By Total Amount Extracted % Moisture Dry Weight Extracted ICAL ID CCaI Filename(s) Method Blank ID Native Isomers TM Metho d 8290 Sample Analysis Results Client - PASI Florida SCS-MW-2 35451839001 F190313B_15 SMT 1040 mL NA NA F190112 F190313A_18 & BLANK-68966 Conc EMPC pg/L pg/L Matrix Dilution Collected Received F190313B_17 Extracted Analyzed Internal Standards EDL pg/L Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612- 607-6444 Water NA 03/04/2019 14:12 03/07/2019 08:55 03/11/2019 12:00 03/14/2019 07:07 2,3,7,8-TCDF 1.5 U Total TCDF 1.5 U 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD 2.5 U 2.5 U 1.8 U 1.2 U 1.5 U 2.1 U 2.1 U 2.2 U 1.8 U 2.0 U 2.6 U 2.1 U 3.0 U 2.4 U 2.8 U 2.7 U 5.1 U 7.2 U 6.2 U 4.6 U 4.6 U 14 U 12 U 1.5 2,3,7,8-TCDF-13C 1.5 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 2.5 2,3,4,7,8-PeCDF-13C 2.5 1, 2, 3,7, 8-PeC DD-13C 1,2,3,4,7,8-HxCDF-13C 1.8 1,2,3,6,7,8-HxCDF-13C 1.2 2,3,4,6,7,8-HxCDF-13C 1.5 1,2, 3,7,8, 9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 2.1 1,2,3,6,7,8-HxCDD-13C 2.1 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 2.2 1.8 2.0 2.6 2.1 3.0 2.4 2.8 2.7 ng's Percent Added Recovery 2.00 61 2.00 62 2.00 53 2.00 52 2.00 58 2.00 57 2.00 54 2.00 63 2.00 54 2.00 58 2.00 56 2.00 43 2.00 38 R 2.00 42 4.00 34 R 1,2,3,4-TCDD-13C 2.00 NA 1,2,3,7,8,9-HxCDD-13C 2.00 NA 2,3,7,8-TCDD-37CI4 0.20 88 5.1 Total 2,3,7,8-TCDD 7.2 Equivalence: 0.00 pg/L 6.2 (Lower -bound - Using ITE Factors) 4.6 4.6 14 12 Conc = Concentration (Totals include 2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit R = Recovery outside target range ND = Not Detected NA = Not Applicable NC = Not Calculated REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466121_8290FC_DFR Page 10 of 14 Page 14 of 18 AnalyticalTM Lab Sample Name Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) Native Isomers Method 8290 Blank Analysis Results DFBLKDC BLANK-68966 F190313B_06 945 mL F190112 F190313A_18 & F190313B_17 Conc pg/L EMPC EDL pg/L pg/L Matrix Dilution Extracted Analyzed Injected By Internal Standards Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax:612-607-6444 Water NA 03/11/2019 12:00 03/14/2019 00:29 SMT ng's Percent Added Recovery 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD 2.1 U 2.1 U 2.3 U 2.3 U 2.0 U 1.6 U 1.8 U 1.8 U 1.8 U 2.1 U 1.9 U 1.8 U 2.1 U 2.0 U 2.1 U 2.2 U 1.8 U 2.0 U 3.0 U 6.0 U 4.5 U 4.4 U 4.4 U 9.1 U 7.3 U 2.1 2,3,7,8-TCDF-13C 2.1 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 2.3 2,3,4,7,8-PeCDF-13C 2.3 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 2.0 1,2,3,6,7,8-HxCDF-13C 1.6 2,3,4,6,7,8-HxCDF-13C 1.8 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 1.8 1,2,3,6,7,8-HxCDD-13C 1.8 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 2.1 1.9 1.8 2.1 2.0 2.1 2.2 1.8 2.0 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 4.00 2.00 2.00 0.20 3.0 Total 2,3,7,8-TCDD 6.0 Equivalence: 0.00 pg/L 4.5 (Lower -bound - Using ITE Factors) 4.4 4.4 9.1 7.3 66 70 62 61 71 64 57 73 63 66 66 51 47 51 44 NA NA 88 Conc= Concentration (Totals include 2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL= Estimated Detection Limit REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466121_8290FC_DFR Page 11 of 14 Page 15 of 18 7/e Analytic Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) Method Blank ID Native Isomers 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD LCS-68967 F190313B_01 923 mL F190112 F190313A_18 & F1903136_17 BLANK-68966 Qs Qm (ng) (ng) Rec. 0.20 0.22 109 0.20 0.23 117 1.0 1.1 105 1.0 1.1 111 1.0 0.97 97 1.0 1.1 113 1.0 1.1 108 1.0 1.1 105 1.0 1.1 105 1.0 1.1 111 1.0 1.2 120 1.0 1.0 103 1.0 1.1 107 1.0 1.0 102 1.0 1.0 100 2.0 2.2 108 2.0 2.2 109 TM Method Method 8290 Laboratory Control Spike Results Matrix Dilution Extracted Analyzed Injected By Internal Standards 2,3,7,8-TCDF-13C 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 2,3,4,7,8-PeCDF-13C 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 1,2,3,6,7,8-HxCDF-13C 2,3,4,6,7,8-HxCDF-13C 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 1,2,3,6,7,8-HxCDD-13C 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612-607-6444 Water NA 03/11/2019 12:00 03/13/2019 20:48 SMT ng's Percent Added Recovery 2.0 58 2.0 60 2.0 52 2.0 51 2.0 58 2.0 52 2.0 49 2.0 60 2.0 49 2.0 55 2.0 54 2.0 41 2.0 37 R 2.0 40 4.0 33 R 2.0 NA 2.0 NA 0.20 80 Qs = Quantity Spiked Qm = Quantity Measured Rec. = Recovery (Expressed as Percent) R = Recovery outside of target range Y = RF averaging used in calculations Nn = Value obtained from additional analysis NA = Not Applicable * = See Discussion REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466121_8290FC_DFR Page 16 of 18 Page 12 of 14 Analytical Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) Method Blank ID Native Isomers 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD TM Method 8290 Laboratory Control Spike Results LCSD-68968 F1903136_02 894 mL F190112 F190313A_18 & F190313B_17 BLANK-68966 Qs Qm 0/0 (ng) (ng) 0.20 0.22 0.20 0.23 116 1.0 1.1 105 1.0 1.1 109 1.0 0.99 99 1.0 1.0 105 1.0 1.0 104 1.0 0.99 99 1.0 0.97 97 1.0 1.1 109 1.0 1.1 115 1.0 1.0 104 1.0 1.0 104 1.0 0.92 92 1.0 0.99 99 2.0 2.1 105 2.0 2.1 106 Rec. Matrix Dilution Extracted Analyzed Injected By Internal Standards 109 2,3,7,8-TCDF-13C 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 2,3,4,7,8-PeCDF-13C 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 1,2,3,6,7,8-HxCDF-13C 2,3,4,6,7,8-HxCDF-13C 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 1,2,3,6,7,8-HxCDD-13C 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2, 3,4,6,7,8-HpCDD-13C OCDD-13C 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612-607-6444 Water NA 03/11/2019 12:00 03/13/2019 21:33 SMT ng's Percent Added Recovery 2.0 70 2.0 74 2.0 61 2.0 59 2.0 66 2.0 66 2.0 63 2.0 73 2.0 63 2.0 66 2.0 65 2.0 51 2.0 47 2.0 51 4.0 42 2.0 NA 2.0 NA 0.20 89 Qs = Quantity Spiked Qm = Quantity Measured Rec. = Recovery (Expressed as Percent) R = Recovery outside of target range Y = RF averaging used in calculations Nn = Value obtained from additional analysis NA = Not Applicable * = See Discussion REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466121_8290FC_DFR Page 17 of 18 Page 13 of 14 Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Client AnalyticalTM Method 8290 Spike Recovery Relative Percent Difference (RPD) Results PASI Florida Spike 1 ID LCS-68967 Spike 2 ID LCSD-68968 Spike 1 Filename F190313B_01 Spike 2 Filename F190313B_02 Spike 1 Spike 2 Compound %REC %REC %RPD Tel: 612-607-1700 Fax: 612-607-6444 2, 3, 7, 8-TC D F 109 109 0.0 2,3,7,8-TCDD 117 116 0.9 1,2,3,7,8-PeCDF 105 105 0.0 2,3,4,7,8-PeCDF 111 109 1.8 1,2,3,7,8-PeCDD 97 99 2.0 1,2,3,4,7,8-HxCDF 113 105 7.3 1,2,3,6,7,8-HxCDF 108 104 3.8 2,3,4,6,7,8-HxCDF 105 99 5.9 1,2,3,7,8,9-HxCDF 105 97 7.9 1,2,3,4,7,8-HxCDD 111 109 1.8 1,2,3,6,7,8-HxCDD 120 115 4.3 1,2,3,7,8,9-HxCDD 103 104 1.0 1,2,3,4,6,7,8-HpCDF 107 104 2.8 1,2,3,4,7,8,9-HpCDF 102 92 10.3 1,2,3,4,6,7,8-HpCDD 100 99 1.0 OCDF 108 105 2.8 OCDD 109 106 2.8 %REC = Percent Recovered RPD = The difference between the two values divided by the mean value REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10466121_8290FC_DFR Page 18 of 18 Page 14 of 14 aceAnalytical® www.pacelabs.com April 02, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456929 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 27, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke©pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry, EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 22 aceAnalytical® www.pacelabs.com CERTIFICATIONS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456929 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification Ds 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 22 aceAnalytical® wwwpacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456929 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35456929001 GW-1 Water 03/26/19 09:40 03/27/19 17:15 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 22 aceAnalytical www.pace/abs.com SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456929 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35456929001 GW-1 FL -PRO BP2 3 PASI-O EPA 8270 by SIM CBI 20 PASI-O EPA 8260 SK1 70 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 22 aceAnalytical www.pacelabs.com SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456929 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35456929001 GW-1 EPA 8260 Acetone 6.9 I ug/L 20.0 04/02/19 07:16 EPA 8260 Methyl-tert-butyl ether 2.4 ug/L 2.0 04/02/19 07:16 J EPA 8260 Toluene 0.41 I ug/L 1.0 04/02/19 07:16 J REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 22 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456929 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: GW-1 Lab ID: 35456929001 Collected: 03/26/19 09:40 Received: 03/27/19 17:15 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual FL -PRO Water, Low Volume Analytical Method: FL -PRO Preparation Method: EPA 3510 Petroleum Range Organics Surrogates o-Terphenyl (S) N-Pentatriacontane (S) 0.79 U mg/L 87 85 Ok 0.98 0.79 1 03/29/19 11:37 03/30/19 00:23 66-139 1 03/29/19 11:37 03/30/19 00:23 84-15-1 42-159 1 03/29/19 11:37 03/30/19 00:23 630-07-09 8270 MSSV PAHLV by SIM Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3510 Acenaphthene 0.040 U ug/L 0.50 0.040 1 04/01/19 08:28 04/01/19 13:15 83-32-9 Acenaphthylene 0.030 U ug/L 0.50 0.030 1 04/01/19 08:28 04/01/19 13:15 208-96-8 Anthracene 0.043 U ug/L 0.50 0.043 1 04/01/19 08:28 04/01/19 13:15 120-12-7 Benzo(a)anthracene 0.055 U ug/L 0.10 0.055 1 04/01/19 08:28 04/01/19 13:15 56-55-3 Benzo(a)pyrene 0.12 U ug/L 0.20 0.12 1 04/01/19 08:28 04/01/19 13:15 50-32-8 Benzo(b)fluoranthene 0.027 U ug/L 0.10 0.027 1 04/01/19 08:28 04/01/19 13:15 205-99-2 Benzo(g,h,i)perylene 0.15 U ug/L 0.50 0.15 1 04/01/19 08:28 04/01/19 13:15 191-24-2 Benzo(k)fluoranthene 0.16 U ug/L 0.50 0.16 1 04/01/19 08:28 04/01/19 13:15 207-08-9 Chrysene 0.026 U ug/L 0.50 0.026 1 04/01/19 08:28 04/01/19 13:15 218-01-9 Dibenz(a,h)anthracene 0.13 U ug/L 0.15 0.13 1 04/01/19 08:28 04/01/19 13:15 53-70-3 Fluoranthene 0.018 U ug/L 0.50 0.018 1 04/01/19 08:28 04/01/19 13:15 206-44-0 Fluorene 0.088 U ug/L 0.50 0.088 1 04/01/19 08:28 04/01/19 13:15 86-73-7 Indeno(1,2,3-cd)pyrene 0.12 U ug/L 0.15 0.12 1 04/01/19 08:28 04/01/19 13:15 193-39-5 1-Methylnaphthalene 0.19 U ug/L 2.0 0.19 1 04/01/19 08:28 04/01/19 13:15 90-12-0 2-Methylnaphthalene 0.68 U ug/L 2.0 0.68 1 04/01/19 08:28 04/01/19 13:15 91-57-6 Naphthalene 0.29 U ug/L 2.0 0.29 1 04/01/19 08:28 04/01/19 13:15 91-20-3 Phenanthrene 0.16 U ug/L 0.50 0.16 1 04/01/19 08:28 04/01/19 13:15 85-01-8 Pyrene 0.032 U ug/L 0.50 0.032 1 04/01/19 08:28 04/01/19 13:15 129-00-0 Surrogates 2-Fluorobiphenyl (S) 53 % 33-82 1 04/01/19 08:28 04/01/19 13:15 321-60-8 p-Terphenyl-d14 (S) 82 % 49-104 1 04/01/19 08:28 04/01/19 13:15 1718-51-0 8260 MSV Analytical Method: EPA 8260 1,1.1,2-Tetrachloroethane 0.32 U ug/L 1.0 0.32 1 04/02/19 07:16 630-20-6 1,1,1-Trichloroethane 0.30 U ug/L 1.0 0.30 1 04/02/19 07:16 71-55-6 1,1,2,2-Tetrachloroethane 0.20 U ug/L 0.50 0.20 1 04/02/19 07:16 79-34-5 1,1,2-Trichloroethane 0.30 U ug/L 1.0 0.30 1 04/02/19 07:16 79-00-5 1,1-Dichloroethane 0.34 U ug/L 1.0 0.34 1 04/02/19 07:16 75-34-3 1,1-Dichloroethene 0.27 U ug/L 1.0 0.27 1 04/02/19 07:16 75-35-4 1,1-Dichloropropene 0.31 U ug/L 1.0 0.31 1 04/02/19 07:16 563-58-6 1,2,3-Trichlorobenzene 0.34 U ug/L 1.0 0.34 1 04/02/19 07:16 87-61-6 J(M1) 1.2,3-Trichloropropane 1.1 U ug/L 2.0 1.1 1 04/02/19 07:16 96-18-4 1,2,3-Trimethylbenzene 0.17 U ug/L 1.0 0.17 1 04/02/19 07:16 526-73-8 1,2,4-Trichlorobenzene 0.32 U ug/L 1.0 0.32 1 04/02/19 07:16 120-82-1 1,2,4-Trimethylbenzene 0.24 U ug/L 1.0 0.24 1 04/02/19 07:16 95-63-6 1,2-Dichlorobenzene 0.29 U ug/L 1.0 0.29 1 04/02/19 07:16 95-50-1 J 1,2-Dichloroethane 0.27 U ug/L 1.0 0.27 1 04/02/19 07:16 107-06-2 1,2-Dichloropropane 0.23 U ug/L 1.0 0.23 1 04/02/19 07:16 78-87-5 1,3,5-Trimethylbenzene 0.24 U ug/L 1.0 0.24 1 04/02/19 07:16 108-67-8 1,3-Dichlorobenzene 0.33 U ug/L 1.0 0.33 1 04/02/1907:16 541-73-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/02/2019 06:10 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 22 ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456929 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: GW-1 Lab ID: 35456929001 Collected: 03/26/19 09:40 Received: 03/27/19 17:15 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Analytical Method: EPA 8260 1.3-Dichloropropane 0.26 U ug/L 1.0 0.26 1 04/02/19 07:16 142-28-9 1,4-Dichlorobenzene 0.28 U ug/L 1.0 0.28 1 04/02/1907:16 106-46-7 2,2-Dichloropropane 0.59 U ug/L 1.0 0.59 1 04/02/19 07:16 594-20-7 2-Butanone (MEK) 7.5 U ug/L 10.0 7.5 1 04/02/19 07:16 78-93-3 J 2-Chloroethylvinyl ether 1.4 U ug/L 40.0 1.4 1 04/02/19 07:16 110-75-8 J,J(M1), c2 2-Chlorotoluene 0.28 U ug/L 1.0 0.28 1 04/02/19 07:16 95-49-8 2-Hexanone 0.85 U ug/L 10.0 0.85 1 04/02/19 07:16 591-78-6 4-Chlorotoluene 0.22 U ug/L 1.0 0.22 1 04/02/19 07:16 106-43-4 4-Methyl-2-pentanone (MIBK) 0.32 U ug/L 10.0 0.32 1 04/02/19 07:16 108-10-1 Acetone 6.9 I ug/L 20.0 5.3 1 04/02/19 07:16 67-64-1 Acetonitrile 24.5 U ug/L 40.0 24.5 1 04/02/19 07:16 75-05-8 Benzene 0.30 U ug/L 1.0 0.30 1 04/02/19 07:16 71-43-2 Bromobenzene 0.21 U ug/L 1.0 0.21 1 04/02/19 07:16 108-86-1 Bromochloromethane 0.37 U ug/L 1.0 0.37 1 04/02/19 07:16 74-97-5 Bromodichloromethane 0.19 U ug/L 0.60 0.19 1 04/02/19 07:16 75-27-4 Bromoform 2.6 U ug/L 3.0 2.6 1 04/02/19 07:16 75-25-2 Bromomethane 4.0 U ug/L 5.0 4.0 1 04/02/19 07:16 74-83-9 J arbon disulfide 0.45 U ug/L 10.0 0.45 1 04/02/19 07:16 75-15-0 J .arbon tetrachloride 1.1 U ug/L 3.0 1.1 1 04/02/19 07:16 56-23-5 Chlorobenzene 0.35 U ug/L 1.0 0.35 1 04/02/19 07:16 108-90-7 Chloroethane 3.7 U ug/L 10.0 3.7 1 04/02/19 07:16 75-00-3 Chloroform 0.32 U ug/L 1.0 0.32 1 04/02/19 07:16 67-66-3 Chloromethane 0.97 U ug/L 1.0 0.97 1 04/02/19 07:16 74-87-3 J Dibromochloromethane 0.45 U ug/L 2.0 0.45 1 04/02/19 07:16 124-48-1 Dibromomethane 0.68 U ug/L 2.0 0.68 1 04/02/19 07:16 74-95-3 Dichlorodifluoromethane 0.26 U ug/L 1.0 0.26 1 04/02/19 07:16 75-71-8 Ethylbenzene 0.30 U ug/L 1.0 0.30 1 04/02/19 07:16 100-41-4 lodomethane 9.3 U ug/L 10.0 9.3 1 04/02/19 07:16 74-88-4 J Isopropylbenzene (Cumene) 0.30 U ug/L 1.0 0.30 1 04/02/19 07:16 98-82-8 Methyl-tert-butyl ether 2.4 ug/L 2.0 0.51 1 04/02/19 07:16 1634-04-4 J Methylene Chloride 2.0 U ug/L 5.0 2.0 1 04/02/19 07:16 75-09-2 Styrene 0.26 U ug/L 1.0 0.26 1 04/02/19 07:16 100-42-5 Tetrachloroethene 0.38 U ug/L 1.0 0.38 1 04/02/19 07:16 127-18-4 Toluene 0.41 I ug/L 1.0 0.33 1 04/02/19 07:16 108-88-3 J Trichloroethene 0.36 U ug/L 1.0 0.36 1 04/02/19 07:16 79-01-6 Trichlorofluoromethane 0.35 U ug/L 1.0 0.35 1 04/02/19 07:16 75-69-4 Vinyl acetate 0.19 U ug/L 10.0 0.19 1 04/02/19 07:16 108-05-4 Vinyl chloride 0.39 U ug/L 1.0 0.39 1 04/02/19 07:16 75-01-4 Xylene (Total) 2.1 U ug/L 5.0 2.1 1 04/02/19 07:16 1330-20-7 cis-1,2-Dichloroethene 0.27 U ug/L 1.0 0.27 1 04/02/19 07:16 156-59-2 cis-1,3-Dichloropropene 0.17 U ug/L 0.50 0.17 1 04/02/19 07:16 10061-01-5 m&p-Xylene 2.1 U ug/L 4.0 2.1 1 04/02/19 07:16 179601-23-1 n-Butylbenzene 0.20 U ug/L 1.0 0.20 1 04/02/19 07:16 104-51-8 n-Propylbenzene 0.37 U ug/L 1.0 0.37 1 04/02/19 07:16 103-65-1 o-Xylene 0.27 U ug/L 1.0 0.27 1 04/02/19 07:16 95-47-6 Date: 04/02/2019 06:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 22 %ceAnaJicaI www.pacelabs. com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456929 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: GW-1 Lab ID: 35456929001 Collected: 03/26/19 09:40 Received: 03/27/19 17:15 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Analytical Method: EPA 8260 p-Isopropyltoluene 0.31 U ug/L 5.0 0.31 1 04/02/19 07:16 99-87-6 sec-Butylbenzene 0.17 U ug/L 1.0 0.17 1 04/02/19 07:16 135-98-8 tert-Butylbenzene 0.26 U ug/L 1.0 0.26 1 04/02/19 07:16 98-06-6 trans-1,2-Dichloroethene 0.23 U ug/L 1.0 0.23 1 04/02/19 07:16 156-60-5 trans-1,3-Dichloropropene 0.17 U ug/L 0.50 0.17 1 04/02/19 07:16 10061-02-6 J(L1) Surrogates 4-Bromofluorobenzene (S) 101 % 70-130 1 04/02/19 07:16 460-00-4 1,2-Dichloroethane-d4 (S) 105 % 70-130 1 04/02/19 07:16 17060-07-0 Toluene-d8 (S) 100 % 70-130 1 04/02/19 07:16 2037-26-5 Date: 04/02/2019 06:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 22 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456929 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 527630 Analysis Method: EPA 8260 QC Batch Method: EPA 8260 Analysis Description: 8260 MSV Associated Lab Samples: 35456929001 METHOD BLANK: 2855528 Matrix: Water Associated Lab Samples: 35456929001 Parameter Blank Reporting Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L 0.32 U 1.0 0.32 04/01/19 21:52 1,1,1-Trichloroethane ug/L 0.30 U 1.0 0.30 04/01/19 21:52 1,1,2,2-Tetrachloroethane ug/L 0.20 U 0.50 0.20 04/01/19 21:52 1,1,2-Trichloroethane ug/L 0.30 U 1.0 0.30 04/01/19 21:52 1,1-Dichloroethane ug/L 0.34 U 1.0 0.34 04/01/19 21:52 1,1-Dichloroethene ug/L 0.27 U 1.0 0.27 04/01/19 21:52 1,1-Dichloropropene ug/L 0.31 U 1.0 0.31 04/01/19 21:52 1,2,3-Trichlorobenzene ug/L 0.34 U 1.0 0.34 04/01/19 21:52 1,2,3-Trichloropropane ug/L 1.1 U 2.0 1.1 04/01/19 21:52 1,2,3-Trimethylbenzene ug/L 0.17 U 1.0 0.17 04/01/19 21:52 1,2,4-Trichlorobenzene ug/L 0.32 U 1.0 0.32 04/01/19 21:52 1,2,4-Trimethylbenzene ug/L 0.24 U 1.0 0.24 04/01/19 21:52 1,2-Dichlorobenzene ug/L 0.29 U 1.0 0.29 04/01/19 21:52 J 1,2-Dichloroethane ug/L 0.27 U 1.0 0.27 04/01/19 21:52 ,2-Dichloropropane ug/L 0.23 U 1.0 0.23 04/01/19 21:52 1,3,5-Trimethylbenzene ug/L 0.24 U 1.0 0.24 04/01/19 21:52 1,3-Dichlorobenzene ug/L 0.33 U 1.0 0.33 04/01/1921:52 1,3-Dichloropropane ug/L 0.26 U 1.0 0.26 04/01/19 21:52 1,4-Dichlorobenzene ug/L 0.28 U 1.0 0.28 04/01/1921:52 2,2-Dichloropropane ug/L 0.59 U 1.0 0.59 04/01/19 21:52 2-Butanone (MEK) ug/L 7.5 U 10.0 7.5 04/01/19 21:52 J 2-Chloroethylvinyl ether ug/L 1.4 U 40.0 1.4 04/01/19 21:52 J 2-Chlorotoluene ug/L 0.28 U 1.0 0.28 04/01/19 21:52 2-Hexanone ug/L 0.85 U 10.0 0.85 04/01/19 21:52 4-Chlorotoluene ug/L 0.22 U 1.0 0.22 04/01/19 21:52 4-Methyl-2-pentanone (MIBK) ug/L 0.32 U 10.0 0.32 04/01/19 21:52 Acetone ug/L 5.3 U 20.0 5.3 04/01/19 21:52 Acetonitrile ug/L 24.5 U 40.0 24.5 04/01/19 21:52 Benzene ug/L 0.30 U 1.0 0.30 04/01/19 21:52 Bromobenzene ug/L 0.21 U 1.0 0.21 04/01/19 21:52 Bromochloromethane ug/L 0.37 U 1.0 0.37 04/01/19 21:52 Bromodichloromethane ug/L 0.19 U 0.60 0.19 04/01/19 21:52 Bromoform ug/L 2.6 U 3.0 2.6 04/01/19 21:52 Bromomethane ug/L 4.0 U 5.0 4.0 04/01/19 21:52 J Carbon disulfide ug/L 0.45 U 10.0 0.45 04/01/19 21:52 J Carbon tetrachloride ug/L 1.1 U 3.0 1.1 04/01/19 21:52 Chlorobenzene ug/L 0.35 U 1.0 0.35 04/01/19 21:52 Chloroethane ug/L 3.7 U 10.0 3.7 04/01/19 21:52 Chloroform ug/L 0.32 U 1.0 0.32 04/01/19 21:52 Chloromethane ug/L 0.97 U 1.0 0.97 04/01/19 21:52 J cis-1,2-Dichloroethene ug/L 0.27 U 1.0 0.27 04/01/19 21:52 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/02/2019 06:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 22 /12ceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456929 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 METHOD BLANK: 2855528 Matrix: Water Associated Lab Samples: 35456929001 Parameter Blank Reporting Units Result Limit MDL Analyzed Qualifiers cis-1,3-Dichloropropene ug/L 0.17 U 0.50 0.17 04/01/19 21:52 Dibromochloromethane ug/L 0.45 U 2.0 0.45 04/01/19 21:52 Dibromomethane ug/L 0.68 U 2.0 0.68 04/01/19 21:52 Dichlorodifluoromethane ug/L 0.26 U 1.0 0.26 04/01/19 21:52 Ethylbenzene ug/L 0.30 U 1.0 0.30 04/01/19 21:52 lodomethane ug/L 9.3 U 10.0 9.3 04/01/19 21:52 J Isopropylbenzene (Cumene) ug/L 0.30 U 1.0 0.30 04/01/19 21:52 m&p-Xylene ug/L 2.1 U 4.0 2.1 04/01/19 21:52 Methyl-tert-butyl ether ug/L 0.51 U 2.0 0.51 04/01/19 21:52 J Methylene Chloride ug/L 2.0 U 5.0 2.0 04/01/19 21:52 n-Butylbenzene ug/L 0.20 U 1.0 0.20 04/01/19 21:52 n-Propylbenzene ug/L 0.37 U 1.0 0.37 04/01/19 21:52 o-Xylene ug/L 0.27 U 1.0 0.27 04/01/19 21:52 p-lsopropyltoluene ug/L 0.31 U 5.0 0.31 04/01/19 21:52 sec-Butylbenzene ug/L 0.17 U 1.0 0.17 04/01/19 21:52 Styrene ug/L 0.26 U 1.0 0.26 04/01/19 21:52 tert-Butylbenzene ug/L 0.26 U 1.0 0.26 04/01/19 21:52 Tetrachloroethene ug/L 0.38 U 1.0 0.38 04/01/19 21:52 Toluene ug/L 0.33 U 1.0 0.33 04/01/19 21:52 J trans-1,2-Dichloroethene ug/L 0.23 U 1.0 0.23 04/01/1921:52 trans-1,3-Dichloropropene ug/L 0.17 U 0.50 0.17 04/01/1921:52 Trichloroethene ug/L 0.36 U 1.0 0.36 04/01/19 21:52 Trichlorofluoromethane ug/L 0.35 U 1.0 0.35 04/01/19 21:52 Vinyl acetate ug/L 0.19 U 10.0 0.19 04/01/19 21:52 Vinyl chloride ug/L 0.39 U 1.0 0.39 04/01/19 21:52 Xylene (Total) ug/L 2.1 U 5.0 2.1 04/01/19 21:52 1,2-Dichloroethane-d4 (S) % 104 70-130 04/01/19 21:52 4-Bromofluorobenzene (S) % 100 70-130 04/01/19 21:52 Toluene-d8 (S) % 98 70-130 04/01/19 21:52 LABORATORY CONTROL SAMPLE: 2855529 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 20 18.3 91 70-130 1,1,1-Trichloroethane ug/L 20 16.9 84 70-130 1,1,2,2-Tetrachloroethane ug/L 20 18.2 91 68-125 1,1,2-Trichloroethane ug/L 20 16.5 83 70-130 1,1-Dichloroethane ug/L 20 17.4 87 70-130 1,1-Dichloroethene ug/L 20 17.2 86 66-133 1,1-Dichloropropene ug/L 20 17.0 85 70-130 1,2,3-Trichlorobenzene ug/L 20 18.9 95 64-126 1,2,3-Trichloropropane ug/L 20 18.2 91 62-127 1,2,3-Trimethylbenzene ug/L 20 17.2 86 70-130 1,2,4-Trichlorobenzene ug/L 20 17.4 87 63-124 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/02/2019 06:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 22 aceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456929 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE: 2855529 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,2,4-Trimethylbenzene ug/L 20 17.8 89 70-130 1,2-Dichlorobenzene ug/L 20 23.0 115 70-130 J 1,2-Dichloroethane ug/L 20 16.1 81 70-130 1,2-Dichloropropane ug/L 20 17.3 86 70-130 1,3,5-Trimethylbenzene ug/L 20 17.5 87 70-130 1,3-Dichlorobenzene ug/L 20 16.6 83 70-130 1,3-Dichloropropane ug/L 20 17.6 88 70-130 1,4-Dichlorobenzene ug/L 20 16.8 84 70-130 2,2-Dichloropropane ug/L 20 17.3 87 59-133 2-Butanone (MEK) ug/L 40 33.9 85 47-143 J 2-Chloroethylvinyl ether ug/L 20 14.6 I 73 41-140 J 2-Chlorotoluene ug/L 20 16.5 82 70-130 2-Hexanone ug/L 40 33.1 83 48-145 4-Chlorotoluene ug/L 20 17.0 85 70-130 4-Methyl-2-pentanone (MIBK) ug/L 40 46.7 117 57-132 Acetone ug/L 40 37.2 93 46-148 Acetonitrile ug/L 200 213 106 33-175 Benzene ug/L 20 17.0 85 70-130 Bromobenzene ug/L 20 17.8 89 70-130 Bromochloromethane ug/L 20 16.0 80 70-130 tromodichloromethane ug/L 20 16.2 81 70-130 Bromoform ug/L 20 16.2 81 49-126 Bromomethane ug/L 20 5.0 25 10-165 J Carbon disulfide ug/L 20 15.5 78 60-141 J Carbon tetrachloride ug/L 20 16.4 82 63-126 Chlorobenzene ug/L 20 16.5 82 70-130 Chloroethane ug/L 20 17.6 88 71-142 Chloroform ug/L 20 16.5 82 70-130 Chloromethane ug/L 20 16.0 80 40-140 J cis-1,2-Dichloroethene ug/L 20 17.1 85 70-130 cis-1,3-Dichloropropene ug/L 20 16.9 84 70-130 Dibromochloromethane ug/L 20 16.1 81 62-118 Dibromomethane ug/L 20 15.9 80 70-130 Dichlorodifluoromethane ug/L 20 17.9 89 47-150 Ethylbenzene ug/L 20 17.4 87 70-130 lodomethane ug/L 40 18.4 46 10-164 J Isopropylbenzene (Cumene) ug/L 20 16.4 82 70-130 m&p-Xylene ug/L 40 36.8 92 70-130 Methyl-tert-butyl ether ug/L 20 15.6 78 64-124 J Methylene Chloride ug/L 20 17.1 85 65-136 n-Butylbenzene ug/L 20 24.9 124 70-130 n-Propylbenzene ug/L 20 18.1 90 70-130 o-Xylene ug/L 20 17.5 88 70-130 p-Isopropyltoluene ug/L 20 17.1 85 70-130 sec-Butylbenzene ug/L 20 17.9 90 70-130 Styrene ug/L 20 15.7 78 70-130 tert-Butylbenzene ug/L 20 17.2 86 70-130 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/02/2019 06:10 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 22 aceAnalytical wvnw.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456929 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE: 2855529 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers Tetrachloroethene ug/L 20 21.9 110 64-134 Toluene ug/L 20 25.3 126 70-130 J trans-1,2-Dichloroethene ug/L 20 16.3 82 68-127 trans-1,3-Dichloropropene ug/L 20 25.2 126 65-121 J(L1) Trichloroethene ug/L 20 15.6 78 70-130 Trichlorofluoromethane ug/L 20 18.0 90 65-135 Vinyl acetate ug/L 20 19.1 95 60-144 Vinyl chloride ug/L 20 15.7 78 68-131 Xylene (Total) ug/L 60 54.3 91 70-130 1,2-Dichloroethane-d4 (S) % 104 70-130 4-Bromofluorobenzene (S) % 104 70-130 Toluene-d8 (S) % 98 70-130 MATRIX SPIKE SAMPLE: 2855766 Parameter 35456929001 Spike MS MS % Rec Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 0.32 U 20 18.8 94 70-130 1,1,1-Trichloroethane ug/L 0.30 U 20 18.5 92 70-130 1,1,2,2-Tetrachloroethane ug/L 0.20 U 20 18.1 91 68-125 1,1,2-Trichloroethane ug/L 0.30 U 20 16.2 81 70-130 1,1-Dichloroethane ug/L 0.34 U 20 18.4 92 70-130 1,1-Dichloroethene ug/L 0.27 U 20 19.1 95 66-133 1,1-Dichloropropene ug/L 0.31 U 20 18.6 93 70-130 1,2,3-Trichlorobenzene ug/L 0.34 U 20 11.8 59 64-126 J(M1) 1,2,3-Trichloropropane ug/L 1.1 U 20 16.5 83 62-127 1,2,3-Trimethylbenzene ug/L 0.17 U 20 18.4 92 70-130 1,2,4-Trichlorobenzene ug/L 0.32 U 20 13.0 65 63-124 1,2,4-Trimethylbenzene ug/L 0.24 U 20 19.0 95 70-130 1,2-Dichlorobenzene ug/L 0.29 U 20 16.7 83 70-130 J 1,2-Dichloroethane ug/L 0.27 U 20 16.3 82 70-130 1,2-Dichloropropane ug/L 0.23 U 20 17.9 89 70-130 1,3,5-Trimethylbenzene ug/L 0.24 U 20 18.6 93 70-130 1,3-Dichlorobenzene ug/L 0.33 U 20 16.9 84 70-130 1,3-Dichloropropane ug/L 0.26 U 20 17.9 89 70-130 1,4-Dichlorobenzene ug/L 0.28 U 20 16.7 84 70-130 2,2-Dichloropropane ug/L 0.59 U 20 16.9 85 59-133 2-Butanone (MEK) ug/L 7.5 U 40 31.6 79 47-143 J 2-Chloroethylvinyl ether ug/L 1.4 U 20 1.4 U 0 41-140 J,J(M1) 2-Chlorotoluene ug/L 0.28 U 20 17.6 88 70-130 2-Hexanone ug/L 0.85 U 40 32.7 82 48-145 4-Chlorotoluene ug/L 0.22 U 20 17.9 89 70-130 4-Methyl-2-pentanone (MIBK) ug/L 0.32 U 40 31.9 80 57-132 Acetone ug/L 6.9 I 40 37.1 75 46-148 Acetonitrile ug/L 24.5 U 200 166 83 33-175 Benzene ug/L 0.30 U 20 17.8 89 70-130 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/02/2019 06 10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 22 aceAnalytical® www.pacelabscom QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456929 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 MATRIX SPIKE SAMPLE: 2855766 Parameter 35456929001 Spike MS MS % Rec Units Result Conc. Result % Rec Limits Qualifiers Bromobenzene ug/L 0.21 U 20 18.9 94 70-130 Bromochloromethane ug/L 0.37 U 20 16.3 81 70-130 Bromodichloromethane ug/L 0.19 U 20 17.1 86 70-130 Bromoform ug/L 2.6 U 20 14.7 74 49-126 Bromomethane ug/L 4.0 U 20 4.0 U 16 10-165 J Carbon disulfide ug/L 0.45 U 20 17.0 84 60-141 J Carbon tetrachloride ug/L 1.1 U 20 17.8 89 63-126 Chlorobenzene ug/L 0.35 U 20 17.0 85 70-130 Chloroethane ug/L 3.7 U 20 21.2 106 71-142 Chloroform ug/L 0.32 U 20 17.6 88 70-130 Chloromethane ug/L 0.97 U 20 15.2 76 40-140 J cis-1,2-Dichloroethene ug/L 0.27 U 20 17.8 89 70-130 cis-1,3-Dichloropropene ug/L 0.17 U 20 16.2 81 70-130 Dibromochloromethane ug/L 0.45 U 20 15.8 79 62-118 Dibromomethane ug/L 0.68 U 20 16.4 82 70-130 Dichlorodifluoromethane ug/L 0.26 U 20 20.6 103 47-150 Ethylbenzene ug/L 0.30 U 20 18.1 91 70-130 lodomethane ug/L 9.3 U 40 13.1 32 10-164 J lsopropylbenzene (Cumene) ug/L 0.30 U 20 17.7 88 70-130 m&p-Xylene ug/L 2.1 U 40 38.5 95 70-130 lethyl-tert-butyl ether ug/L 2.4 20 17.6 76 64-124 Methylene Chloride ug/L 2.0 U 20 16.8 84 65-136 n-Butylbenzene ug/L 0.20 U 20 18.3 91 70-130 n-Propylbenzene ug/L 0.37 U 20 19.6 98 70-130 o-Xylene ug/L 0.27 U 20 18.5 92 70-130 p-Isopropyltoluene ug/L 0.31 U 20 18.1 90 70-130 sec-Butylbenzene ug/L 0.17 U 20 19.3 96 70-130 Styrene ug/L 0.26 U 20 15.7 79 70-130 tert-Butylbenzene ug/L 0.26 U 20 19.0 94 70-130 Tetrachloroethene ug/L 0.38 U 20 15.2 76 64-134 Toluene ug/L 0.41 I 20 18.3 90 70-130 J trans-1,2-Dichloroethene ug/L 0.23 U 20 17.2 86 68-127 trans-1,3-Dichloropropene ug/L 0.17 U 20 16.4 82 65-121 Trichloroethene ug/L 0.36 U 20 16.8 84 70-130 Trichlorofluoromethane ug/L 0.35 U 20 20.4 102 65-135 Vinyl acetate ug/L 0.19 U 20 17.0 85 60-144 Vinyl chloride ug/L 0.39 U 20 18.3 92 68-131 Xylene (Total) ug/L 2.1 U 60 57.1 95 70-130 1,2-Dichloroethane-d4 (S) % 104 70-130 4-Bromofluorobenzene (S) % 103 70-130 Toluene-d8 (S) % 98 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/02/2019 06:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 22 ca aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456929 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 SAMPLE DUPLICATE: 2855765 Parameter 35456922001 Dup Max Units Result Result RPD RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L 0.32 U 0.32 U 40 1,1,1-Trichloroethane ug/L 0.30 U 0.30 U 40 1,1,2,2-Tetrachloroethane ug/L 0.20 U 0.20 U 40 1,1,2-Trichloroethane ug/L 0.30 U 0.30 U 40 1,1-Dichloroethane ug/L 0.34 U 0.34 U 40 1,1-Dichloroethene ug/L 0.27 U 0.27 U 40 1,1-Dichloropropene ug/L 0.31 U 0.31 U 40 1,2,3-Trichlorobenzene ug/L 0.34 U 0.34 U 40 1,2,3-Trichloropropane ug/L 1.1 U 1.1 U 40 1,2,3-Trimethylbenzene ug/L 0.17 U 0.17 U 40 1,2,4-Trichlorobenzene ug/L 0.32 U 0.32 U 40 1,2,4-Trimethylbenzene ug/L 0.24 U 0.24 U 40 1,2-Dichlorobenzene ug/L 0.29 U 0.29 U 40 J 1,2-Dichloroethane ug/L 0.27 U 0.27 U 40 1,2-Dichloropropane ug/L 0.23 U 0.23 U 40 1,3,5-Trimethylbenzene ug/L 0.24 U 0.24 U 40 1,3-Dichlorobenzene ug/L 0.33 U 0.33 U 40 1,3-Dichloropropane ug/L 0.26 U 0.26 U 40 1,4-Dichlorobenzene ug/L 0.28 U 0.28 U 40 2,2-Dichloropropane ug/L 0.59 U 0.59 U 40 2-Butanone (MEK) ug/L 7.5 U 7.5 U 40 J 2-Chloroethylvinyl ether ug/L 1.4 U 1.4 U 40 J 2-Chlorotoluene ug/L 0.28 U 0.28 U 40 2-Hexanone ug/L 0.85 U 0.85 U 40 4-Chlorotoluene ug/L 0.22 U 0.22 U 40 4-Methy1-2-pentanone (MIBK) ug/L 0.32 U 0.32 U 40 Acetone ug/L 14.2 I 5.3 U 40 Acetonitrile ug/L 24.5 U 24.5 U 40 Benzene ug/L 0.30 U 0.30 U 40 Bromobenzene ug/L 0.21 U 0.21 U 40 Bromochloromethane ug/L 0.37 U 0.37 U 40 Bromodichloromethane ug/L 0.19 U 0.19 U 40 Bromoform ug/L 2.6 U 2.6 U 40 Bromomethane ug/L 4.0 U 4.0 U 40 J Carbon disulfide ug/L 0.45 U 0.45 U 40 J Carbon tetrachloride ug/L 1.1 U 1.1 U 40 Chlorobenzene ug/L 0.35 U 0.35 U 40 Chloroethane ug/L 3.7 U 3.7 U 40 Chloroform ug/L 0.32 U 0.32 U 40 Chloromethane ug/L 0.97 U 0.97 U 40 J cis-1,2-Dichloroethene ug/L 0.27 U 0.27 U 40 cis-1,3-Dichloropropene ug/L 0.17 U 0.17 U 40 Dibromochloromethane ug/L 0.45 U 0.45 U 40 Dibromomethane ug/L 0.68 U 0.68 U 40 Dichlorodifluoromethane ug/L 0.26 U 0.26 U 40 Ethylbenzene ug/L 0.30 U 0.30 U 40 lodomethane ug/L 9.3 U 9.3 U 40 J Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/02/2019 06:10 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 22 QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456929 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 SAMPLE DUPLICATE: 2855765 Parameter 35456922001 Dup Units Result Result RPD Max RPD Qualifiers Isopropylbenzene (Cumene) ug/L 0.30 U 0.30 U 40 m&p-Xylene ug/L 2.1 U 2.1 U 40 Methyl-tert-butyl ether ug/L 0.58 I 0.61 I 40 J Methylene Chloride ug/L 2.0 U 2.0 U 40 n-Butylbenzene ug/L 0.20 U 0.20 U 40 n-Propylbenzene ug/L 0.37 U 0.37 U 40 o-Xylene ug/L 0.27 U 0.27 U 40 p-Isopropyltoluene ug/L 0.31 U 0.31 U 40 sec-Butylbenzene ug/L 0.17 U 0.17 U 40 Styrene ug/L 0.26 U 0.26 U 40 tert-Butylbenzene ug/L 0.26 U 0.26 U 40 Tetrachloroethene ug/L 0.38 U 0.38 U 40 Toluene ug/L 0.33 U 0.33 U 40 J trans-1,2-Dichloroethene ug/L 0.23 U 0.23 U 40 trans-1,3-Dichloropropene ug/L 0.17 U 0.17 U 40 Trichloroethene ug/L 0.36 U 0.36 U 40 Trichlorofluoromethane ug/L 0.35 U 0.35 U 40 Vinyl acetate ug/L 0.19 U 0.19 U 40 Vinyl chloride ug/L 0.39 U 0.39 U 40 Xylene (Total) ug/L 2.1 U 2.1 U 40 .2-Dichloroethane-d4 (S) % 105 104 1 40 4-Bromofluorobenzene (S) % 100 100 1 40 Toluene-d8 (S) % 98 99 1 40 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/02/2019 06:10 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 22 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456929 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 527190 Analysis Method: EPA 8270 by SIM QC Batch Method: EPA 3510 Analysis Description: 8270 Water PAHLV by SIM MSSV Associated Lab Samples: 35456929001 METHOD BLANK: 2852847 Matrix: Water Associated Lab Samples: 35456929001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1-Methylnaphthalene ug/L 0.19 U 2.0 0.19 04/01/19 11:10 2-Methylnaphthalene ug/L 0.68 U 2.0 0.68 04/01/19 11:10 Acenaphthene ug/L 0.040 U 0.50 0.040 04/01/19 11:10 Acenaphthylene ug/L 0.030 U 0.50 0.030 04/01/19 11:10 Anthracene ug/L 0.043 U 0.50 0.043 04/01/19 11:10 Benzo(a)anthracene ug/L 0.055 U 0.10 0.055 04/01/19 11:10 Benzo(a)pyrene ug/L 0.12 U 0.20 0.12 04/01/19 11:10 Benzo(b)fluoranthene ug/L 0.027 U 0.10 0.027 04/01/19 11:10 Benzo(g,h,i)perylene ug/L 0.15 U 0.50 0.15 04/01/19 11:10 Benzo(k)fluoranthene ug/L 0.16 U 0.50 0.16 04/01/19 11:10 Chrysene ug/L 0.026 U 0.50 0.026 04/01/19 11:10 Dibenz(a,h)anthracene ug/L 0.13 U 0.15 0.13 04/01/19 11:10 Fluoranthene ug/L 0.018 U 0.50 0.018 04/01/19 11:10 Fluorene ug/L 0.088 U 0.50 0.088 04/01/19 11:10 Indeno(1,2,3-cd)pyrene ug/L 0.12 U 0.15 0.12 04/01/19 11:10 Naphthalene ug/L 0.29 U 2.0 0.29 04/01/19 11:10 Phenanthrene ug/L 0.16 U 0.50 0.16 04/01/19 11:10 Pyrene ug/L 0.032 U 0.50 0.032 04/01/19 11:10 2-Fluorobiphenyl (S) % 63 33-82 04/01/19 11:10 p-Terphenyl-d14 (S) % 97 49-104 04/01/19 11:10 LABORATORY CONTROL SAMPLE: 2852848 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1-Methylnaphthalene ug/L 5 2.7 54 40-96 2-Methylnaphthalene ug/L 5 2.7 53 40-94 Acenaphthene ug/L 5 3.1 62 42-96 Acenaphthylene ug/L 5 3.0 59 39-90 Anthracene ug/L 5 3.3 66 46-109 Benzo(a)anthracene ug/L 5 4.1 82 50-116 Benzo(a)pyrene ug/L 5 3.5 71 48-117 Benzo(b)fluoranthene ug/L 5 3.6 73 51-124 Benzo(g,h,i)perylene ug/L 5 3.8 76 47-121 Benzo(k)fluoranthene ug/L 5 3.7 75 50-125 Chrysene ug/L 5 4.1 83 53-122 Dibenz(a,h)anthracene ug/L 5 3.8 75 45-123 Fluoranthene ug/L 5 4.0 79 52-119 Fluorene ug/L 5 3.3 65 44-100 Indeno(1,2,3-cd)pyrene ug/L 5 3.8 76 46-121 Naphthalene ug/L 5 2.9 57 40-91 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/02/2019 06:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 22 aceAnalytical® www pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456929 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE: 2852848 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phenanthrene ug/L 5 3.5 69 47-111 Pyrene ug/L 5 3.9 78 51-120 2-Fluorobiphenyl (S) % 55 33-82 p-Terphenyl-d14 (S) % 85 49-104 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2854238 2854239 MS MSD 35457129002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1-Methylnaphthalene ug/L 1.2 I 5 5 4.3 4.9 63 74 40-96 12 40 2-Methylnaphthalene ug/L 1.2 I 5 5 4.3 4.8 60 71 40-94 12 40 Acenaphthene ug/L 0.040 U 5 5 3.1 3.5 61 69 42-96 11 40 Acenaphthylene ug/L 0.030 U 5 5 3.1 3.5 62 69 39-90 11 40 Anthracene ug/L 0.043 U 5 5 3.4 3.8 68 76 46-109 11 40 Benzo(a)anthracene ug/L 0.055 U 5 5 4.2 4.4 84 88 50-116 5 40 Benzo(a)pyrene ug/L 0.12 U 5 5 3.6 3.9 72 78 48-117 7 40 Benzo(b)fluoranthene ug/L 0.027 U 5 5 3.7 3.8 74 76 51-124 3 40 Benzo(g,h,i)perylene ug/L 0.15 U 5 5 3.8 4.0 76 79 47-121 4 40 lenzo(k)fluoranthene ug/L 0.16 U 5 5 3.8 4.0 75 79 50-125 5 40 .;hrysene ug/L 0.026 U 5 5 4.2 4.4 85 89 53-122 4 40 Dibenz(a,h)anthracene ug/L 0.13 U 5 5 3.8 3.9 77 79 45-123 3 40 Fluoranthene ug/L 0.018 U 5 5 4.0 4.2 80 85 52-119 5 40 Fluorene ug/L 0.088 U 5 5 3.3 3.7 64 72 44-100 11 40 Indeno(1,2,3-cd)pyrene ug/L 0.12 U 5 5 3.8 3.9 76 79 46-121 4 40 Naphthalene ug/L 10.2 5 5 17.6 20.3 148 203 40-91 14 40 J(M1) Phenanthrene ug/L 0.16 U 5 5 3.5 3.8 69 76 47-111 9 40 Pyrene ug/L 0.032 U 5 5 4.0 4.2 80 84 51-120 5 40 2-Fluorobiphenyl (S) % 55 62 33-82 p-Terphenyl-d14 (S) % 84 89 49-104 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date. 04/02/2019 06:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 22 ace Analytical wvnw.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456929 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 526900 Analysis Method: FL -PRO QC Batch Method: EPA 3510 Analysis Description: FL -PRO Water Low Volume Associated Lab Samples: 35456929001 METHOD BLANK: 2850418 Matrix: Water Associated Lab Samples: 35456929001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Petroleum Range Organics N-Pentatriacontane (S) o-Terphenyl (S) mg/L % % 0.80 U 1.0 0.80 03/29/19 23:37 88 42-159 03/29/19 23:37 85 66-139 03/29/19 23:37 LABORATORY CONTROL SAMPLE: 2850419 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Petroleum Range Organics N-Pentatriacontane (S) o-Terphenyl (S) mg/L % % 5 5.0 100 66-119 93 42-159 89 66-139 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2851010 2851011 MS MSD 35457129002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Petroleum Range Organics mg/L 0.76 U 5 4.7 3.9 4.7 66 86 65-123 18 20 N-Pentatriacontane (S) % 85 92 42-159 o-Terphenyl (S) % 77 89 66-139 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/02/2019 06:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 22 ceAnalytical® www.pacelabs.com QUALIFIERS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456929 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. U Compound was analyzed for but not detected. The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. J The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have a low bias. J The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. J(L1) Estimated Value. Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. J(M1) Estimated Value. Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. c2 Acid preservation may not be appropriate for the analysis of 2-Chloroethylvinyl ether. Date: 04/02/2019 06:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 22 aceAnalytical® www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456929 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID QC Batch Method Analytical QC Batch Analytical Method Batch 35456929001 GW-1 EPA 3510 526900 FL -PRO 527131 35456929001 GW-1 EPA 3510 527190 EPA 8270 by SIM 527466 35456929001 GW-1 EPA 8260 527630 Date: 04/02/2019 06:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 22 +'aceMa/ytic f Section A Required Client Information: Company Address EE8G Environmental Services. LLC 5751 Miami Lakes Drive Miami Lakes, FL 33014 WO# : 35455929 SectionB II1I I /III III fhil I II _II Required Project Infon 35456929 Report To: Michael Van Ry Copy To -• Attention' Company Name :al Request Document All relevant fields must be completed accurately. Page Of Email mvanry@eeandg.com Phone (305)374-8300 Requested Due Dale 1 2 3 4 5 6 7 8 9 10 11 12 Address Fax Purchase Order # Project Name Melreese Golf Course Project #: 2018 3057 SAMPLE ID One Character per box. (A-Z, 0-9 / , •) Sample Ids must be unique MATRix CODE Drinkinn Wmnr Dw Water WT Wnsln Walnr WW nwdun P SoWSolid St O,i 01. Wqw we Ar AR Other OT Tisaue TS ADDITIONAL COMMENTS a_ 0 0 0 m 10 a ul a COLLECTED START DATE END O O a TIME DATE TIME vai RELINQUISHED BY / AFFILIATION DATE Pace Quote: Pace Project Manager. ^ace Profile # X OF CONTAINERS TIME U 2 O Z Regulatory Agency christine.raschke@pacelabs corn, O nri z C c O Z } Analyses Test 6010 Al, As, Fe, Pb Requested An itysis Filtcrod CY/ l) 0 0 c0 TRPH FL -PRO 8290 Dioxin & Furans OC Pesticides 8081 OP Pesticides 8141 8151 Herbicides 6010-8a, Cd, Cr, cn iv 0) State / Location ACCEPTED BY/AFFILIATION 1i DATE TIME ' f7 4J FL SAMPLE CONDITIONS SAMPLER NAME AND SIGNATURE PRINT Name of SAMPLER: SIGNATURE of SAMPLER: DATE Signed: c 0 N N 0 (V a) 0) ca i� .ace Analytical - �,;,rnen: Name S.. - ,. �oit.on Upon Receipt Form Document Rev:seo May 30 2018 :ioument No _ • _ . ., .. 1 rev 13 Issuing Authority Pace Florida Quality Office orm SOUR) Project WO# a 3 45 92 Project IUlanagel PM: CTR CLIENT: 36-EEG Client e mometer Used g� State of Origin Cooler #1 Temp.'C (Visual) V • (Correction Factor) y (Actual) 5_ c es or. ;ce cooking process has begun Cooler#2 Temp.'C (Visual) (Correction Factor) ! (Actual) L Sa .dies dry: e dolma process has beaus Cooler #3 Temp.'C (Visual) (Correction Factor) (Actual) [ Sa-o'es x .e 7:ooI:71c process has oeg;.n Cooler #4 Temp.'C (Visual) (Correction Factor) (Actual) r Sa- :es o- ce, coorng process has begun Cooler #5 Temp.'C (Visual) (Correction Factor) (Actual) ` S=-r :es on ice, cocune process has begun Cooler #6 Temp.'C (Visual) (Correction Factor) (Actual) L Sa -1pies on ice coding process hss begun Due Date: 04/03/19 Time Date and Initials of person: Examining contents: Label: Deliver: pH: • v Init ais ects all containers ven` eo to <_E rC Courier: — Fed Ex — UPS ❑ USPS — Client 1- Commerctaly� race Other Shipping Method: - First Overnight - Priority Overnight = Standard Overnight = Ground 7 International Priority Other Billing: Tracking # - Recipient Sender = Third Party - Credit Card = unknown Custody Seal on Cooler/Box Present: _Yes - Ji� Seals intact: _ Yes Packing Material: Bubble Wrap ❑ Bubble Bags None Li Other Samples shorted to lab (If Yes, complete) Shorted Date 1ki Pr Comments: Ice: Shorted Time- / '+i iue Dry None Qty Chain of Custody Present .Yes _ No _N!A Chain of Custody Filled Out s _ No -N/A Relinquished Signature & Sampler Name COC es . _ No -N/A Samples Arnved within Hold Time = es _ No N/A Rush TAT requested on COC =Yes ENO EN/A Sufficient Volume e . No -N/A Correct Containers Used _/Yes/- _ No =N/A Containers Intact _Yes _ No EN/A Sample Labels match COC (sample IDs & cate.'t.me of collection; Yes = No 1-N/A ,All containers needing acid/base preservation nave been checked -Yes - No /A All Containers needing preservation are found to oe in compliance with EPA recommendation Yes LI:_ No /A Exceptions VOA, Col form TDC O&G, Caroamates Preservation Informatic- Preservative Lot #(Trace # Date Initials Headspace in VOA Vials? (>6mm). =Yes Jo -N/A Trip Blank Present. -Yes 7'No =N/A Client Notification! Resolution: Person Contacted Comments/ Resolution (use back for additional comments): Date/Time Project Manager Review Date f aoc 22 of 22 EEG ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) SITE LOCATION: 1802 NW 37'"Ave, Miami, FL 33125 WELL NO: MW-44 SAMPLE ID: PACE DATE: 3/4/2019 PURGING DATA (2/2B/3 WELL ( PVC) DIAMETER (inches): 2.0 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 1.88 feet to 11.88 feet STATIC DEPTH TO WATER (feet BLS): 4.01 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 11.88 feet - 4.01 feet) X 0.16 gallons/foot = 1.26 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + .allons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 8 FINAL PUMP OR TUBING PURGING PURGING DEPTH IN WELL (feet): 8 INITIATED AT: 09:36 ENDED AT: 10:04 TOTAL VOLUME PURGED (gallons): 3.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 09:52 2.0 2.0 0.125 4.15 6.92 0.902 4.16 8.2 25.59 Clear None 09:56 0.5 2.5 0.125 4.15 6.94 0.889 3.62 6.5 25.51 Clear None 10:00 0.5 3.0 0.125 4.15 6.95 0.889 3.33 6.0 25.55 Clear None 10:04 0.5 3.5 0.125 4.15 6.96 0.897 3.22 5.6 25.51 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) /AFFILIATION: Michael Van Ry/ EE&G SAMPLER(S) SIGNATURE(S): _ SAMPLING INITIATED AT: 10:04 SAMPLING ENDED AT: 10:14 PUMP OR TUBING DEPTH IN WELL (feet): 8.0 TUBING FIELD -FILTERED: 0 N FILTER SIZE: MATERIAL CODE: HDPE/S Filtration Equipment Type: 1 µm FIELD DECONTAMINATION: PUMP Y © TUBING Y E (replaced) DUPLICATE: Y N� SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 3 CG 40 mL HCL - < 2 VOC (8260) APP 100 1 AG 250 mL - - - PAHs (8270) APP 500 2 AG 100 mL H2SO4 - < 2 TPH (FL -PRO) APP 500 1 AG 1 L - - - Pest. (8081) APP 500 1 AG 1 L - Organo Pest (8141) APP 500 1 AG 1 L - - - Herb. (8151) APP 500 1 AG 1 L - - - Dioxins (8290) APP 500 1 PE 250 mL HNO3 - < 2 Metals (6010/7470) APP 500 1 PE 250 mL HNO3 < 2 Diss. Metals (6010/7470) APP 500 1 PE 250 mL H2SO4 - < 2 Ammonia (350.1) APP 500 1 PE 250 mL - Nitrates/Nitrites (300.0) APP 500 REMARKS: T.O.0 -0.2' YS/556 MPM#7 7BM#2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 E E - ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-42 SAMPLE ID: PACE SITE LOCATION: 1802 NW 371° Ave, Miami, FL 33125 DATE: 3 / 4 / 2019 PURGING DATA (2 / 2B / 3 WELL ( PVC) DIAMETER (inches): 2.0 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 2.13 feet to 12.13 feet STATIC DEPTH TO WATER (feet BLS): 4.97 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 12.13 feet- 4.97 feet) X 0.16 gallons/foot = 1.15 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 8.5 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 8.5 PURGING PURGING INITIATED AT: 10:36 ENDED AT: 11:04 TOTAL VOLUME PURGED (gallons): 3.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED (% 8aturat on) XYGEN TEMP. (°C) COLOR (describe) ODOR (describe) 10:52 2.0 2.0 0.125 5.54 7.24 0.530 2.23 10.9 25.01 Clear None 10:56 0 5 2.5 0.125 5.54 7.21 0.528 1.97 7.2 25.08 Clear None 11:00 0.5 3.0 0.125 5.54 7.21 0.529 1.63 5.8 25.02 Clear None 11:04 0.5 3.5 0.125 5.54 7.21 0.533 1.49 5.3 25.02 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) /AFFILIATION: Michael Van Ry / EE&G SAMPLER(S) SIGNATURE(S): �!. . , - / SAMPLING INITIATED AT: 11:04 SAMPLING ENDED AT: 11:14 PUMP OR TUBING DEPTH IN WELL (feet): 8.5 TUBING FIELD -FILTERED: 0 N FILTER SIZE: MATERIAL CODE: HDPE/S Filtration Equipment Type: 1 pm FIELD DECONTAMINATION: PUMP Y E TUBING Y QN (replaced) DUPLICATE: Y El SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 3 CG 40 mL HCL - < 2 VOC (8260) APP 100 1 AG 250 mL - - - PAHs (8270) APP 500 2 AG 100 mL H2SO4 - < 2 TPH (FL -PRO) APP 500 1 AG 1 L - - - Pest. (8081) APP 500 1 AG 1 L - - Organo Pest (8141) APP 500 1 AG 1 L - - - Herb. (8151) APP 500 1 AG 1 L - - - Dioxins (8290) APP 500 1 PE 250 mL HNO3 - < 2 Metals (6010/7470) APP 500 1 PE 250 mL HNO3 - <2 Diss. Metals (6010/7470) APP 500 1 PE 250 mL H2SO4 - < 2 Ammonia (350.1) APP 500 1 PE 250 mL - - Nitrates/Nitrites (300.0) APP 500 REMARKS: T.O.C. -015' YS/ 556 MPM # 7 TBM#2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: ± 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 EEG ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) SITE LOCATION: 1802 NW 37tb Ave, Miami, FL 33125 WELL NO: SCS-MW-1 SAMPLE ID: PACE DATE: 3 / 4 / 2019 PURGING DATA (2/2B/3 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 2.1 feet to 12.1 feet STATIC DEPTH TO WATER (feet BLS): 4.15 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 12.1 feet- 4.15 feet) X 0.09 gallons/foot = 0.72 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 8 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 8 PURGING INITIATED AT: 11:40 PURGING ENDED AT: 12:04 TOTAL VOLUME PURGED (gallons): 3.0 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (°� Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 11:52 1.5 1.5 0.125 4.35 7.09 0.590 5.84 8.7 23.58 Clear None 11:56 0.5 2.0 0.125 4.35 7.09 0.577 5.10 6.9 23.65 Clear None 12:00 0.5 2.5 0.125 4.35 7.10 0.575 4.72 6.3 23.61 Clear None 12:04 0.5 3.0 0.125 4.35 7.10 0.574 4.55 5.7 23.52 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Michael Van Ry / EE&G SAMPLER(S) SIGNATURE(S): - % SAMPLING INITIATED AT: 12:04 SAMPLING ENDED AT: 12:14 PUMP OR TUBING DEPTH IN WELL (feet): 8 TUBING FIELD -FILTERED: 0 N FILTER SIZE: MATERIAL CODE: HDPE/S Filtration Equipment Type: 1 pm FIELD DECONTAMINATION: PUMP Y 11 TUBING Y N (replaced) DUPLICATE: Y E SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 3 CG 40 mL HCL - < 2 VOC (8260) APP 100 1 AG 250 mL - - - PAHs (8270) APP 500 2 AG 100 mL H2SO4 - < 2 TPH (FL -PRO) APP 500 1 AG 1 L - - - Pest. (8081) APP 500 1 AG 1 L - Organo Pest (8141) APP 500 1 AG 1 L - - - Herb. (8151) APP 500 1 AG 1 L - - - Dioxins (8290) APP 500 1 PE 250 mL HNO3 - < 2 Metals (6010/7470) APP 500 1 PE 250 mL HNO3 - < 2 Diss. Metals (6010/7470) APP 500 1 PE 250 mL H2SO4 - < 2 Ammonia (350.1) APP 500 1 PE 250 mL - - Nitrates/Nitrites (300.0) APP 500 REMARKS: T.O.0 -04' YS/556 MPM#7 7BM#2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 EE -C3 E ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-39 SAMPLE ID: PACE SITE LOCATION: 1802 NW 37th Ave, Miami, FL 33125 DATE: 3 / 4 / 2019 PURGING DATA ( 2 / 2B / 3 WELL ( PVC) DIAMETER (inches): 1.0 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 1.6 feet to 11.6 feet STATIC DEPTH TO WATER (feet BLS): 3.51 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 11.6 feet- 3.51 feet) X 0.04 gallons/foot = 0.32 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + 9allons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 7.5 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 7.5 PURGING INITIATED AT: 12:42 PURGING ENDED AT: 12:54 TOTAL VOLUME PURGED (gallons): 1.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED °OXYGEN (/o Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 12:48 0.75 0.75 0.125 3.61 7.39 0.394 2.22 15.1 26.41 Clear None 12:50 0.25 1.0 0.125 3.61 7.31 0.391 2.20 10.7 26.16 Clear None 12:52 0.25 1.25 0.125 3.61 7.30 0.389 2.12 9.0 25.92 Clear None 12:54 0.25 1.50 0.125 3.61 7.31 0.389 2.03 8.0 25.87 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Michael Van Ry / EE&G SAMPLER(S) SIGNATURE(S): , SAMPLING INITIATED AT: 12:54 SAMPLING ENDED AT: 13:04 PUMP OR TUBING DEPTH IN WELL (feet): 7.5 TUBING FIELD -FILTERED: 0 N FILTER SIZE: MATERIAL CODE: HDPE/S Filtration Equipment Type: 1 um FIELD DECONTAMINATION: PUMP Y H TUBING Y QN (replaced) DUPLICATE: Y El SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mt.) FINAL pH 3 CG 40 mL HCL - < 2 VOC (8260) APP 100 1 AG 250 mL - - - PAHs (8270) APP 500 2 AG 100 mL H2SO4 - < 2 TPH (FL -PRO) APP 500 1 AG 1 L - - - Pest. (8081) APP 500 1 AG 1 L - Organo Pest (8141) APP 500 1 AG 1 L - - - Herb. (8151) APP 500 1 AG 1 L - - - Dioxins (8290) APP 500 1 PE 250 mL HNO3 - < 2 Metals (6010/7470) APP 500 1 PE 250 mL HNO3 - < 2 Diss. Metals (6010/7470) APP 500 1 PE 250 mL H2SO4 - < 2 Ammonia (350.1) APP 500 1 PE 250 mL - - - Nitrates/Nitrites (300.0) APP 500 REMARKS: TQ.0 -0.3' YS/556 MPM#7 7BM#2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 EE&G ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: SCS-MW-2 SAMPLE ID: PACE SITE LOCATION: 1802 NW 37°i Ave, Miami, FL 33125 DATE: 3 / 4 / 2019 PURGING DATA ( 2 / 2B / 3 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 1.86 feet to 11.86 feet STATIC DEPTH TO WATER (feet BLS): 3.92 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 11.86 feet- 3.92 feet) X 0.09 gallons/foot = 0.71 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 8 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 8 PURGING INITIATED AT: 13:34 [gallons PURGING ENDED AT: 14:02 TOTAL VOLUME PURGED (gallons): 3.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (%Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 13:50 2.0 2.0 0.125 3.95 7.26 0.508 3.97 4.6 26.12 Clear None 13:54 0.5 2.5 0.125 3.95 7.26 0.495 3.11 3.9 26.06 Clear None 13:58 0.5 3.0 0.125 3.95 7.26 0.487 2.73 3.6 25.93 Clear None 14:02 0.5 3.5 0.125 3.95 7.25 0.487 2.44 3.4 26.03 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) /AFFILIATION: Michael Van Ry / EE&G SAMPLER(S) SIGNATURE(S): r'" . i/ SAMPLING INITIATED AT: 14:02 SAMPLING ENDED AT: 14:12 PUMP OR TUBING DEPTH IN WELL (feet): 8 TUBING FIELD-F LTERED: 0 N FILTER SIZE: MATERIAL CODE: HDPE/S Filtration Equipment Type: 1 pill FIELD DECONTAMINATION: PUMP Y 0 TUBING Y g (replaced) DUPLICATE: Y g SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 3 CG 40 mL HCL - < 2 VOC (8260) APP 100 1 AG 250 mL - - - PAHs (8270) APP 500 2 AG 100 mL H2SO4 - < 2 TPH (FL -PRO) APP 500 1 AG 1 L - - - Pest. (8081) APP 500 1 AG 1 L - - Organo Pest (8141) APP 500 1 AG 1 L - - - Herb. (8151) APP 500 1 AG 1 L - - - Dioxins (8290) APP 500 1 PE 250 mL HNO3 - < 2 Metals (6010/7470) APP 500 1 PE 250 mL HNO3 - < 2 Diss. Metals (6010(7470) APP 500 1 PE 250 mL H2SO4 - < 2 Ammonia (350.1) APP 500 1 PE 250 mL Nitrates/Nitrites (300.0) APP 500 REMARKS: T.O.C. -03' YSI556 MPM#7 TBM#2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 31 pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, ± 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 E E ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) SITE LOCATION: 1802 NW 37' Ave, Miami, FL 33125 WELL NO: MW-31 SAMPLE ID: PACE DATE: 3 / 4 / 2019 PURGING DATA ( 2 / 2B / 3 WELL ( PVC) DIAMETER (inches): 2.0 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 2.6 feet to 12.6 feet STATIC DEPTH TO WATER (feet BLS): 4.08 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 12.6 feet- 4.08 feet) X 0.16 gallons/foot = 1.36 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + allons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 8 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 8 PURGING INITIATED AT: 14:38 PURGING ENDED AT: 15:06 TOTAL VOLUME PURGED (gallons): 3.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (%Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 14:54 2.0 2.0 0.125 4.21 7.33 0.536 17.0 24.8 27.65 Clear None 14:58 0.5 2.5 0.125 4.21 7.32 0.536 15.4 11.0 27.60 Clear None 15:02 0.5 3.0 0.125 4.21 7.32 0.536 13.9 7.4 27.57 Clear None 15:06 0.5 3.5 0.125 4.21 7.32 0.536 12.4 6.9 27.60 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) /AFFILIATION: Michael Van Ry / EE&G SAMPLER(S) SIGNATURE(S): SAMPLING INITIATED AT: 15:06 SAMPLING ENDED AT: 15:16 PUMP OR TUBING DEPTH IN WELL (feet): 8 TUBING FIELD -FILTERED: 0 N FILTER MATERIAL CODE: HDPE/S Filtration Equipment Type: SIZE: 1 pm FIELD DECONTAMINATION: PUMP Y QN TUBING Y H (replaced) DUPLICATE: Y 0 SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 3 CG 40 mL HCL - < 2 VOC (8260) APP 100 1 AG 250 mL - - - PAHs (8270) APP 500 2 AG 100 mL H2SO4 - < 2 TPH (FL -PRO) APP 500 1 AG 1 L - - - Pest. (8081) APP 500 1 AG 1 L - - - Organo Pest (8141) APP 500 1 AG 1 L - - - Herb. (8151) APP 500 1 AG 1 L - - - Dioxins (8290) APP 500 1 PE 250 mL HNO3 - < 2 Metals (6010/7470) APP 500 1 PE 250 mL HNO3 - < 2 Diss. Metals (6010/7470) APP 500 1 PE 250 mL H2SO4 - < 2 Ammonia (350.1) APP 500 1 PE 250 mL - - - Nitrates/Nitrites (300.0) APP 500 REMARKS: T.O.0 -0.5' YS/556 MPM#7 TBM#Z MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally ± 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 E E ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course 2018-3057 WELL NO: SCS-MW-2 SITE LOCATION: 1802 NW 37' Ave, Miami, FL 33125 SAMPLE ID: PACE DATE: 3 / 11 / 2019 PURGING DATA (2 / 2B / 3 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 1.86 feet to 11.86 feet STATIC DEPTH TO WATER (feet BLS): 3.83 PURGE PUMP TYPE OR BAILER: PP#4 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 11.86 feet- 3.83 feet) X 0.09 gallons/foot = 0.72 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 8 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 8 PURGING INITIATED AT: 09:56 PURGING ENDED AT: 10:24 TOTAL VOLUME PURGED (gallons): 3.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) PH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 10:12 2.0 2.0 0.125 3.84 6.36 0.430 2.36 11.1 26.08 Clear None 10:16 0.5 2.5 0.125 3.84 6.42 0.426 1.97 11.4 26.04 Clear None 10:20 0.5 3.0 0.125 3.84 6.50 0.420 1.68 10.7 25.13 Clear None 10:24 0.5 3.5 0.125 3.84 6.54 0.420 1.47 11.0 26.07 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Michael Van Ry / EE&G SAMPLER(S) SIGNATURE(S): _ SAMPLING INITIATED AT: 10:24 SAMPLING ENDED AT: 10:26 PUMP OR TUBING DEPTH IN WELL (feet): 8 TUBING FIELD -FILTERED: Y ❑N FILTER SIZE: MATERIAL CODE: HDPE/S Filtration Equipment Type: pm FIELD DECONTAMINATION: PUMP Y NQ TUBING Y ©(replaced) DUPLICATE: Y E SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 AG 1 L - - - Pest. (8141) APP 500 REMARKS: T.O.C. -03' YS/556 MPM#7 IBM#2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, ± 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 E E - ENVIRONMENTAL SERVICES. LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) SITE LOCATION: 1802 NW 37t Avenue Miami, FL 33125 WELL NO: GW-1 (SB-A) SAMPLE ID: PACE DATE: 3 / 26 / 2019 PURGING DATA (2 / 2B / 3 WELL ( SP15) DIAMETER (inches): 0.75 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 6 feet to 10 feet STATIC DEPTH TO WATER (feet BLS): -6.0 PURGE PUMP TYPE OR BAILER: PP#4 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 10 feet- 6 feet) X 0.02 gallons/foot = 0.08 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 9 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 9 PURGING INITIATED AT: 9:26 PURGING ENDED AT: 9:38 TOTAL VOLUME PURGED (gallons): 1.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) 1 PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) I ODOR (describe) 9:34 1.0 1.0 0.125 -6.0 6.87 0.804 OR 6.9 27.09 Cloudy Hydrocarbon 9:36 0.25 1.25 0.125 -6.0 6.99 0.816 OR 8.1 27.14 Cloudy Hydrocarbon 9:38 0.25 1.5 0.125 -6.0 7.02 0.839 227 3.8 27.20 Cloudy Hydrocarbon WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0 65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3116" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Jennifer Vega / EE&G SAMPLER(S) SIGNATURE(S): �ram-- SAMPLING INITIATED AT: 9:38 SAMPLING ENDED AT: 9:40 PUMP OR TUBING DEPTH IN WELL (feet): 9 TUBING FIELD -FILTERED: Y IJ FILTER SIZE: MATERIAL CODE: HDPE/S Filtration Equipment Type: gm FIELD DECONTAMINATION: PUMP Y QN TUBING Y © (replaced) DUPLICATE: Y ND SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 AG 250 mL - - - PAH APP 500 2 AG 125 mL H2SO4 - < 2 TPH APP 500 3 CG 40 mL HCI - < 2 VOC APP 100 REMARKS: T.O.C. YS/556 MPM#7 TBM#2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: ± 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200- 2); optionally, ± 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 EEG ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-1 SITE LOCATION: 1802 NW 37th Avenue Miami, FL 33125 SAMPLE ID: PACE DATE: 3 / 26 / 2019 PURGING DATA (2 / 26 / 3 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 3 feet to 13 feet STATIC DEPTH TO WATER (feet BLS): 4.7 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 13 feet- 4.7 feet) X 0.09 gallons/foot = 0.74 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 9 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 9 PURGING INITIATED AT: 10:17 PURGING ENDED AT: 10:37 TOTAL VOLUME PURGED (gallons): 2.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 10:25 1.0 1.0 0.125 4.7 7.26 0.463 13.7 7.9 26.09 Clear Hydrocarbon 10:29 0.5 1.5 0.125 4.7 7.25 0.461 11.8 7.9 26.13 Clear Hydrocarbon 10:33 0.5 2.0 0.125 4.7 7.19 0.455 7.4 7.19 26.05 Clear Hydrocarbon 10:37 0.5 2.5 0.125 4.7 7.18 0.453 4.9 4.6 26.05 Clear Hydrocarbon WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0 65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Russell Fernandez / EE&G SAMPLER(S) SIGNATURE(S): �-•4- --- SAMPLING INITIATED AT: 10:38 SAMPLING ENDED AT: 10:45 PUMP OR TUBING DEPTH IN WELL (feet): 9 TUBING FIELD -FILTERED: M N FILTER SIZE: MATERIAL CODE: HDPE/S Filtration Equipment Type: 1 µm FIELD DECONTAMINATION: PUMP Y 0 TUBING Y 0 (replaced) DUPLICATE: Y Ill SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total AF, Ba, Pb, APP 500 1 PE 250 mL HNO3 - < 2 Diss. AF, Ba, Pb, APP 500 1 AG 1 L - - - OC Pest. 8081 APP 500 REMARKS: TO.0 -0.3' YS/556 MPM#7 TBM#2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below an Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200- 2); optionally, ± 0.2 mg/L or ± 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally ± 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 EEG ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-2 SITE LOCATION: 1802 NW 37' Avenue Miami, FL 33125 SAMPLE ID: PACE DATE: 3 / 26 / 2019 PURGING DATA (2 / 2B / 3 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 4.69 feet to 14.69 feet STATIC DEPTH TO WATER (feet BLS): 6.66 PURGE PUMP TYPE OR BAILER: PP#4 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 14.69 feet- 6.66 feet) X 0.09 gallons/foot = 0.72 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 11 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 11 PURGING INITIATED AT: 11:07 PURGING ENDED AT: 11:27 TOTAL VOLUME PURGED (gallons): 2.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 11:15 1.0 1.0 0.125 6.66 6.77 0.700 27.3 8.1 25.85 Clear None 11:19 0.5 1.5 0.125 6.66 6.84 0.664 21.8 4.7 25.86 Clear None 11:23 0.5 2.0 0.125 6.66 6.87 0.652 17.8 3.5 25.96 Clear None 11:27 0.5 2.5 0.125 6.66 6.87 0.654 14.6 3.0 25.88 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1 25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0 65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Jennifer Vega / EE&G SAMPLER(S) SIGNATURE(S): _�- J- , 1V --W-- SAMPLING INITIATED AT: 11:27 SAMPLING ENDED AT: 11:30 PUMP OR TUBING DEPTH IN WELL (feet): 11 TUBING MATERIAL CODE: HDPE/S FIELD -FILTERED: d N FILTER SIZE: Filtration Equipment Type: 1 pm FIELD DECONTAMINATION: PUMP Y 0 TUBING Y 0 (replaced) DUPLICATE: Y 111 SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total AFeBa, Pb, APP 500 1 PE 250 mL HNO3 - < 2 Diss. As, Ba, Pb, Fe APP 500 1 AG 1 L - - - OC Pest. 8081 APP 500 REMARKS: T.O.C. -0.28' Y.S/ 556 MPM # 7 TBM# 2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene, PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: ± 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200- 2); optionally, + 0.2 mg/L or ± 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally ± 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 EEG ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-3 SITE LOCATION: 1802 NW 371" Avenue Miami, FL 33125 SAMPLE ID: PACE DATE: 3 / 26 / 2019 PURGING DATA (2 / 2B / 3 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 2.87 feet to 12.87 feet STATIC DEPTH TO WATER (feet BLS): 4.58 PURGE PUMP TYPE OR BAILER: PP#4 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 12.87 feet- 4.58 feet) X 0.09 gallons/foot = 0.75 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 9 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 9 PURGING INITIATED AT: 11:51 PURGING ENDED AT: 12:11 TOTAL VOLUME PURGED (gallons): 2.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 11:59 1.0 1.0 0.125 4.58 6.87 0.744 85.7 11.2 25.70 Clear None 12:03 0.5 1.5 0.125 4.58 6.84 0.723 71.8 5.7 25.40 Clear None 12:07 0.5 2.0 0.125 4.58 6.83 0.714 43.1 4.0 25.26 Clear None 12:11 0.5 2.5 0.125 4.58 6.80 0.711 26.4 3.1 25.28 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1 25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0 65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Jennifer Vega / EE&G SAMPLER(S) SIGNATURE(S): , r'i -- SAMPLING INITIATED AT: 12:11 SAMPLING ENDED AT: 12:14 PUMP OR TUBING DEPTH IN WELL (feet): 9 TUBING FIELD -FILTERED: M N FILTER SIZE: MATERIAL CODE: HDPE/S Filtration Equipment Type: 1 µm FIELD DECONTAMINATION: PUMP Y QN TUBING Y 0 (replaced) DUPLICATE: Y 0 SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total As, Ba, Pb, Fe APP 500 1 PE 250 mL HNO3 - < 2 Diss. As, Ba, Pb, Fe APP 500 1 AG 1 L - - - OC Pest. 8081 APP 500 1 PE 250 mL H2SO4 - < 2 Ammonia (350.1) APP 500 1 AG 1 L - - - Dioxins & Furans APP 500 REMARKS: T.O.C. -027' YS/556 MP/VI # 7 TBM# 2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene: S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: ± 0.2 units Temperature: + 0.2 °C Specific Conductance: ± 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200- 2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally ± 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 EEG ENVIRONMENTAL SERVICES. LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-4 SITE LOCATION: 1802 NW 37th Avenue Miami, FL 33125 SAMPLE ID: PACE DATE: 3 / 26 / 2019 PURGING DATA (2 / 2B / 3 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 2.89 feet to 12.89 feet STATIC DEPTH TO WATER (feet BLS): 4.46 PURGE PUMP TYPE OR BAILER: PP#4 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 12.89 feet - 4.46 feet) X 0.09 gallons/foot = 0.76 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 9 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 9 PURGING INITIATED AT: 13:06 PURGING ENDED AT: 13:26 TOTAL VOLUME PURGED (gallons): 2.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm)(NTUs) TURBIDITY DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 13:14 1.0 1.0 0.125 4.46 7.04 0.510 3.16 8.2 26.01 Clear None 13:18 0.5 1.5 0.125 4.46 7.04 0.509 1.31 5.0 25.91 Clear None 13:22 0.5 2.0 0.125 4.46 7.07 0.509 0.76 4.5 25.93 Clear None 13:26 0.5 2.5 0.125 4.46 7.08 0.509 1.12 3.9 25.90 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0 65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 118" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Jennifer Vega / EE&G SAMPLER(S) SIGNATURE(S): r� - " yi_1?a- SAMPLING INITIATED AT: 13:26 SAMPLING ENDED AT: 13:30 PUMP OR TUBING DEPTH IN WELL (feet): 9 TUBING FIELD -FILTERED: M N FILTER SIZE: MATERIAL CODE: HDPE/S Filtration Equipment Type: 1 µm FIELD DECONTAMINATION: PUMP Y QN TUBING Y QN (replaced) DUPLICATE: Y �N SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total As, Ba, Pb, Fe APP 500 1 PE 250 mL HNO3 - < 2 Diss. As, Ba, Pb, Fe APP 500 1 AG 1 L - - - OC Pest. 8081 APP 500 1 PE 250 mL H2SO4 - < 2 Ammonia (350.1) APP 500 1 AG 1 L - - - Dioxins & Furans APP 500 REMARKS: T.O.C. -0.29' YS/ 556 MPM # 7 TBM# 2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200- 2); optionally, ± 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally ± 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 EE&G ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-38 SITE LOCATION: 1802 NW 37`" Avenue Miami, FL 33125 SAMPLE ID: PACE DATE: 3 / 26 / 2019 PURGING DATA (2 / 2B / 3 WELL ( PVC) DIAMETER (inches): 2.0 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 2.38 feet to 12.38 feet STATIC DEPTH TO WATER (feet BLS): 4.40 PURGE PUMP TYPE OR BAILER: PP#4 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 12.38 feet - 4.40 feet) X 0.16 gallons/foot = 1.28 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 8 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 8 PURGING INITIATED AT: 12:05 PURGING ENDED AT: 12:52 TOTAL VOLUME PURGED (gallons): 9.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (%) Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 12:40 8.0 8.0 0.125 4.48 6.54 0.498 31.8 11.6 26.48 Clear None 12:44 0.5 8.5 0.125 4.48 6.53 0.496 28.2 11.5 26.44 Clear None 12:48 0.5 9.0 0.125 4.48 6.53 0.495 23.6 11.4 26.48 Clear None 12:52 0.5 9.5 0.125 4.48 6.54 0.495 17.1 11.4 26.49 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0 65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Kelsey Cortina / EE&G SAMPLER(S) SIGNATURE(S): Y > �7`�0� SAMPLING INITIATED AT: 12:52 SAMPLING ENDED AT: 12:55 PUMP OR TUBING DEPTH IN WELL (feet): 8 TUBING FIELD -FILTERED: M N FILTER SIZE: MATERIAL CODE: HDPE/S Filtration Equipment Type: 1 µm FIELD DECONTAMINATION: PUMP Y N TUBING Y 0 (replaced) DUPLICATE: Y II SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total AF, Ba, Pb, APP 500 1 PE 250 mL HNO3 - < 2 Diss. As, Ba, Pb, Fe APP 500 1 AG 1 L - - - OC Pest. 8081 APP 500 REMARKS: T.O.C. -C37' YS/ 556 MPM # 7 TBM# / Sediment buildup encountered, well had thick brown water - purge to clear of approximately 8 gallons. MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200- 2); optionally, + 0.2 mg/L or ± 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally ± 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 EEtG ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-5 SITE LOCATION: 1802 NW 37th Avenue Miami, FL 33125 SAMPLE ID: PACE DATE: 3/26/2019 PURGING DATA (2 / 2B / 3 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 3.05 feet to 13.05 feet STATIC DEPTH TO WATER (feet BLS): 4.5 PURGE PUMP TYPE OR BAILER: PP#4 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 13.05 feet - 4.5 feet) X 0.09 gallons/foot = 0.77 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 8 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 8 PURGING INITIATED AT: 13:34 PURGING ENDED AT: 13:54 TOTAL VOLUME PURGED (gallons): 2.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 13:42 1.0 1.0 0.125 4.5 6.85 0.879 22.1 8.6 25.67 Clear Organic 13:46 0.5 1.5 0.125 4.5 6.85 0.881 21.5 8.2 25.71 Clear Organic 13:50 0.5 2.0 0.125 4.5 6.84 0.881 19.8 7.9 25.73 Clear Organic 13:54 0.5 2.5 0.125 4.5 6.84 0.882 18.5 7.8 25.76 Clear Organic WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1 25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0 65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Kelsey Cortina / EE&G SAMPLER(S) SIGNATURE(S): Coo SAMPLING INITIATED AT: 13:54 SAMPLING ENDED AT: 13:57 PUMP OR TUBING DEPTH IN WELL (feet): 8 TUBING FIELD -FILTERED: M N FILTER SIZE: MATERIAL CODE: HDPE/S Filtration Equipment Type: 1 gm FIELD DECONTAMINATION: PUMP Y N TUBING Y Q (replaced) DUPLICATE: Y Q SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total A�eBa, Pb, APP 500 1 PE 250 mL HNO3 - < 2 Diss. AFeBa, Pb, APP 500 1 AG 1 L - - - OC Pest. 8081 APP 500 1 PE 250 mL H2SO4 - < 2 Ammonia (350.1) APP 500 REMARKS: T, O. C -035' YS/556 MPM # 7 TBM# / MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: ± 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200- 2); optionally, ± 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 EEG ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) SITE LOCATION: 1802 NW 37th Avenue Miami, FL 33125 WELL NO: MW-9 SAMPLE ID: PACE DATE: 3 / 26 / 2019 PURGING DATA (2 / 2B / 3 WELL ( PVC) DIAMETER (inches): 2 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 2.97 feet to 12.97 feet STATIC DEPTH TO WATER (feet BLS): 4.07 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 12.97 feet - 4.07 feet) X 0.16 gallons/foot = 1.42 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 8.5 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 8.5 PURGING INITIATED AT: 14:34 PURGING ENDED AT: 15:02 TOTAL VOLUME PURGED (gal ons): 3.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 14:50 2.0 2.0 0.125 4.07 6.92 1.032 12.4 12.5 27.20 Orange Murky Hydrocarbon 14:54 0.5 2.5 0.125 4.07 6.74 1.047 10.3 8.7 27.03 Clear Hydrocarbon 14:58 0.5 3.0 0.125 4.07 6.40 1.054 11.5 5.4 26.96 Clear Hydrocarbon 15:02 0.5 3.5 0.125 4.07 6.37 1.051 9.8 4.8 26.83 Clear Hydrocarbon WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0 65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Russell Fernandez / EE&G SAMPLER(S) SIGNATURE(S): - SAMPLING INITIATED AT: 15:02 SAMPLING ENDED AT: 15:15 PUMP OR TUBING DEPTH IN WELL (feet): 8.5 TUBING FIELD -FILTERED: 0 N FILTER SIZE: MATERIAL CODE: HDPE/S Filtration Equipment Type: 1 um FIELD DECONTAMINATION: PUMP Y QN TUBING Y QN (replaced) DUPLICATE: Y g SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 3 CG 40 mL HCL - < 2 VOC APP 100 1 AG 250 mL - - - PAH APP 500 2 AG 100 mL H2SO4 - < 2 TPH APP 500 1 AG 1 L - - - Pest. 8141 APP 500 1 AG 1 L - - - Herb. 8151 APP 500 1 PE 250 mL H2SO4 - < 2 Ammonia APP 500 1 AG 1 L - - < 2 OC Pest. 8081 APP 500 1 PE 250 mL HNO3 - < 2 As, Ba, Pb, Fe APP 500 1 PE 250 mL HNO3 - < 2 Diss. As, Ba, Pe, Fe APP 500 REMARKS: T.O.0 -027' YS1556 MPM#7 TBM#2 MATERIAL CODES: AG =Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212. SECTION 31 pH: ± 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200- 2); optionally, ± 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally ± 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 3. BLS = Below Land Surface E E ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-44 SAMPLE ID: PACE SITE LOCATION: 1802 NW 37t Ave, Miami, FL 33125 DATE: 3 / 27 / 2019 PURGING DATA (2 / 2B / 3 WELL ( PVC) DIAMETER (inches): 2.0 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 1.88 feet to 11.88 feet STATIC DEPTH TO WATER (feet BLS): 4.0 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 11.88 feet- 4.0 feet) X 0.16 gallons/foot = 1.26 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X 20 feet) + gallons = gallons INITIAL PUMP OR TUB NG DEPTH IN WELL (feet): 8 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 8 PURGING INITIATED AT: 07:27 PURGING ENDED AT: 07:51 TOTAL VOLUME PURGED (gallons): 3.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (9Pm) DEPTH WATER (feet) PH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 07:43 2.0 2.0 0.125 4 6.82 0.967 10.5 8.4 24.20 Clear None 07:47 0.5 2.5 0.125 4 6.84 0.961 7.9 5.8 24.63 Clear None 07:51 0.5 3.0 0.125 4 6.82 0.958 8.3 4.7 24.54 Clear None 07:55 0.5 3.5 0.125 4 6.82 0.957 7.4 4.1 24.58 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25' = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 114" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Russell Fernandez / EE&G SAMPLER(S) SIGNATURE(S): -rCttr--- SAMPLING INITIATED AT: 07:55 SAMPLING ENDED AT: 08:00 PUMP OR TUBING DEPTH IN WELL (feet): 8.0 TUBING MATERIAL CODE: HDPE/S FIELD -FILTERED: 0 N FILTER SIZE: Filtration Equipment Type: 1 um FIELD DECONTAMINATION: PUMP Y 0 TUBING Y g (replaced) DUPLICATE: Y El SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total Fe APP 500 1 PE 250 mL HNO3 - < 2 Diss. Fe APP 500 1 AG 1 L - - - Dieldrin 8081 APP 500 REMARKS: TO.0 -02' YS/556 MPM#7 TBM#2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212. SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 E E G LLC SERVICES, 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: SCS-MW-1 SITE LOCATION: 1802 NW 37`h Avenue Miami, FL 33125 SAMPLE ID: PACE DATE: 3 / 27 / 2019 PURGING DATA (2 / 2B / 3 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 2.1 feet to 12.1 feet STATIC DEPTH TO WATER (feet BLS): 4.0 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 12.1 feet - 4.0 feet) X 0.09 gallons/foot = 0.73 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 8 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 8 PURGING INITIATED AT: 08:45 PURGING ENDED AT: 09:01 TOTAL VOLUME PURGED (gallons): 2.0 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) PH (standard units) COND. (mS/cm) mS/cm TURBIDITY (NTUs)(%(°C) DISSOLVED OXYGEN Saturation) TEMP. COLOR (describe) ODOR (describe) 08:53 1.0 1.0 0.125 4.0 6.89 0.711 48.9 0.5 22.85 Murky / Orange None 08:57 0.5 1.5 0.125 4.0 6.90 0.650 27.6 2.7 22.87 Murky! Orange None 09:01 0.5 2.0 0.125 4.0 6.92 0.702 25.2 3.3 22.92 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1 25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0 65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Russell Fernandez / EE&G SAMPLER(S) SIGNATURE(S): SAMPLING INITIATED AT: 09:01 SAMPLING ENDED AT: 09:10 PUMP OR TUBING DEPTH IN WELL (feet): 8 TUBING FIELD -FILTERED: M N FILTER SIZE: MATERIAL CODE: HDPE/S Filtration Equipment Type: 1 um FIELD DECONTAMINATION: PUMP Y 0 TUBING Y © (replaced) DUPLICATE: Y E SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL ; pH 1 PE 250 mL HNO3 - < 2 Total Fe APP 500 1 PE 250 mL HNO3 - < 2 Diss. Fe APP 500 1 AG 1 L - - - Dieldrin 8081 APP 500 REMARKS: T.O.C. -0.4' YS/556 MPM#7 TBM#2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200- 2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally ± 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 EEG ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-8 SITE LOCATION: 1802 NW 37`" Avenue Miami, FL 33125 SAMPLE ID: PACE DATE: 3 / 27 / 2019 PURGING DATA (2 / 2B / 3 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 2.89 feet to 12.89 feet STATIC DEPTH TO WATER (feet BLS): 4.3 PURGE PUMP TYPE OR BAILER: PP#4 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 12.89 feet- 4.3 feet) X 0.09 gallons/foot = 0.77 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 8 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 8 PURGING INITIATED AT: 09:28 PURGING ENDED AT: 09:48 TOTAL VOLUME PURGED (gallons): 2.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) (standardpH units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 09:36 1.0 1.0 0.125 4.3 7.09 0.614 102 5.7 24.98 Cloudy None 09:40 0.5 1.5 0.125 4.3 7.08 0.611 67.3 4.8 24.95 Cloudy None 09:44 0.5 2.0 0.125 4.3 7.07 0.605 29.5 4.4 24.92 Cloudy None 09:48 0.5 2.5 0.125 4.3 7.09 0.607 17.6 3.0 25.17 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1 25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0 65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Kelsey Cortina / EE&G SAMPLER(S) SIGNATURE(S): SAMPLING INITIATED AT: 09:48 SAMPLING ENDED AT: 09:55 PUMP OR TUBING DEPTH IN WELL (feet): 8 TUBING FIELD -FILTERED: M N FILTER SIZE: MATERIAL CODE: HDPE/S Filtration Equipment Type: 1 gm FIELD DECONTAMINATION: PUMP Y © TUBING Y QN (replaced) DUPLICATE: Y �N SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total AFeBa, Pb, APP 500 1 PE 250 mL HNO3 - < 2 Diss. AFeBa, Pb, APP 500 1 AG 1 L - - - OC Pest. 8081 APP 500 REMARKS: T.O.0 -0 I7' YS/ 556 MPM # 7 TBM# 1 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: ± 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200- 2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally ± 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 EEG ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) SITE LOCATION: 1802 NW 37th Avenue Miami, FL 33125 WELL NO: MW-7 SAMPLE ID: PACE DATE: 3 / 27 / 2019 PURGING DATA (2/2B/3) WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 1.92 feet to 11.92 feet STATIC DEPTH TO WATER (feet BLS): 3.64 PURGE PUMP TYPE OR BAILER: PP#4 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 11.92 feet- 3.64 feet) X 0.09 gallons/foot = 0.75 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 7 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 7 PURGING INITIATED AT: 10:28 PURGING ENDED AT: 10:56 TOTAL VOLUME PURGED (gallons): 3.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. mS/cm(NTUs)(°C) (mS/cm) TURBIDITY DISSOLVED OXYGEN % Saturation) TEMP. COLOR (describe) ODOR (describe) 10:36 1.0 1.0 0.125 7.64 7.32 0.991 213 14.3 25.23 Cloudy None 10:40 0.5 1.5 0.125 7.64 7.20 0.890 124 5.7 25.42 Cloudy None 10:44 0.5 2.0 0.125 7.64 7.20 0.890 72.4 5.5 25.45 Cloudy None 10:48 0.5 2.5 0.125 7.64 7.17 0.880 56.9 3.8 25.35 Cloudy None 10:52 0.5 3.0 0.125 7.64 7.15 0.794 42.1 3.5 25.33 Clear None 10:56 0.5 3.5 0.125 7.64 7.14 0.786 23.6 3.4 25.35 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0 65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Kelsey Cortina / EE&GCint SAMPLER(S) SIGNATURE(S): ro. SAMPLING INITIATED AT: 10:56 SAMPLING ENDED AT: 10:59 PUMP OR TUBING DEPTH IN WELL (feet): 7 TUBING FIELD -FILTERED: 0 N FILTER SIZE: MATERIAL CODE: HDPE/S Filtration Equipment Type: 1 pm FIELD DECONTAMINATION: PUMP Y g TUBING Y QN (replaced) DUPLICATE: Y g SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total AFeBa, Pb, APP 500 1 PE 250 mL HNO3 - < 2 Diss. AFeBa, Pb, APP 500 1 AG 1 L - - - OC Pest. 8081 APP 500 REMARKS: TO.0 -0.2' YSI556 MPM#7 TBM# I MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200- 2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 EE6G ENVIRONMENTAL SERVICES. LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-6 SITE LOCATION: 1802 NW 37th Avenue Miami, FL 33125 SAMPLE ID: PACE DATE: 3 / 27 / 2019 PURGING DATA (2 / 2B / 3 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 3.0 feet to 13.0 feet STATIC DEPTH TO WATER (feet BLS): 5.1 PURGE PUMP TYPE OR BAILER: PP#4 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 13.0 feet- 5.1 feet) X 0.09 gallons/foot = 0.69 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 9 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 9 PURGING INITIATED AT: 11:33 PURGING ENDED AT: 11:57 TOTAL VOLUME PURGED (gallons): 3.0 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 11:41 1.0 1.0 0.125 5.1 7.13 0.416 68.8 6.6 25.74 Cloudy None 11:45 0.5 1.5 0.125 5.1 7.13 0.411 66.7 5.8 25.77 Cloudy None 11:49 0.5 2.0 0.125 5.1 7.14 0.406 76.2 5.0 25.78 Cloudy None 11:53 0.5 2.5 0.125 5.1 7.14 0.400 80.0 4.7 25.76 Cloudy None 11:57 0.5 3.0 0.125 5.1 7.15 0.396 105 4.3 25.75 Cloudy None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0 65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) 1 SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Kelsey Cortina / EE&G SAMPLER(S) SIGNATURE(S): r L ei�r�o� SAMPLING INITIATED AT: 11:57 SAMPLING ENDED AT: 12:00 PUMP OR TUBING DEPTH IN WELL (feet): 9 TUBING FIELD -FILTERED: d N FILTER SIZE: MATERIAL CODE: HDPE/S Filtration Equipment Type: 1 Am FIELD DECONTAMINATION: PUMP Y Q TUBING Y 0 (replaced) DUPLICATE: Y Q SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total As, Ba, Pb, Fe APP 500 1 PE 250 mL HNO3 - < 2 Diss. As, Ba, Pb, Fe APP 500 1 AG 1 L - - - OC Pest. 8081 APP 500 REMARKS: T.O.C. -0.2' YS/556 MPM#7 TBM# l MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: ± 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200- 2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally ± 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 E E ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-31 SITE LOCATION: 1802 NW 37th Ave, Miami, FL 33125 SAMPLE ID: PACE DATE: 3 / 27 / 2019 PURGING DATA (2 / 2B / 3 WELL ( PVC) DIAMETER (inches): 2.0 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 2.6 feet to 12.6 feet STATIC DEPTH TO WATER (feet BLS): 3.85 PURGE PUMP TYPE OR BAILER: PP#4 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 12.6 feet - 3.85 feet) X 0.16 gallons/foot = 1.4 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 8.5 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 8.5 PURGING INITIATED AT: 12:20 PURGING ENDED AT: 12:48 TOTAL VOLUME PURGED (gallons): 3.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (%Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 12:36 2.0 2.0 0.125 3.85 7.07 0.540 33.1 4.9 28.14 Clear None 12:40 0.5 2.5 0.125 3.85 7.07 0.548 14.3 2.7 28.11 Clear None 12:44 0.5 3.0 0.125 3.85 7.07 0.547 14.5 2.6 27.09 Clear None 12:48 0.5 3.5 0.125 3.85 7.07 0.545 12.7 2.1 28.02 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Kelsey Cortina / EE&G SAMPLER(S) SIGNATURE(S): V SAMPLING INITIATED AT: 12:48 SAMPLING ENDED AT: 12:51 PUMP OR TUBING DEPTH IN WELL (feet): 8.5 TUBING MATERIAL CODE: HDPE/S FIELD -FILTERED: M N FILTER SIZE: Filtration Equipment Type: 1 pm FIELD DECONTAMINATION: PUMP Y © TUBING Y QN (replaced) DUPLICATE: Y N� SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE in mper minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total As, Fe APP 500 1 PE 250 mL HNO3 - < 2 Diss. As, Fe APP 500 1 AG 1 L - - - Dieldrin 8081 APP 500 REMARKS: T.O.C. 0.5' YS/556 MPM#7 ZBM# / MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; S = Silicone; T = Teflon; 0 = Other (Specify) LDPE = Low Density Polyethylene; PP = Polypropylene; SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2 STARII IZATION CRITERIA FOR RANGE OF VARIATION OF IAST THREE CONSECUTIVE READINGS (SEE FS 2212. SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 EEG ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-2 SITE LOCATION: 1802 NW 37"' Avenue Miami, FL 33125 SAMPLE ID: PACE DATE: 4 / 8 / 2019 PURGING DATA (2/2B/3 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 4.69 feet to 14.69 feet STATIC DEPTH TO WATER (feet BLS): 6.4 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 14.69 feet- 6.4 feet) X 0.06 gallons/foot = 0.48 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 10.5 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 10.5 PURGING INITIATED AT: 10:15 PURGING ENDED AT: 10:35 TOTAL VOLUME PURGED (gallons): 2.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) PH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 10:23 1.0 1.0 0.125 6.44 6.90 0.724 OR 5.8 25.31 Cloudy None 10:27 0.5 1.5 0.125 6.44 6.91 0.719 OR 5.2 25.39 Cloudy None 10:31 0.5 2.0 0.125 6.44 6.92 0.709 OR 4.4 25.47 Cloudy None 10:35 0.5 2.5 0.125 6.44 6.92 0.711 OR 3.9 25.42 Cloudy None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0 65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Russell Fernandez / EE&G SAMPLER(S) SIGNATURE(S): SAMPLING INITIATED AT: 10:35 SAMPLING ENDED AT: 10:40 PUMP OR TUBING DEPTH IN WELL (feet): 10.5 TUBING FIELD -FILTERED: M N FILTER SIZE: MATERIAL CODE: HDPE/S Filtration Equipment Type: Disposable 1 gm FIELD DECONTAMINATION: PUMP Y QN TUBING Y 0 (replaced) DUPLICATE: Y 0 SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total As, Fe APP 500 1 PE 250 mL HNO3 - < 2 Dissolved As, Fe APP 500 REMARKS: TO.0 -0.28' YS/556 MPM#7 TBM#2 MATERIAL CODES: AG =Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: ± 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200- 2); optionally, ± 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 E E G ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) SITE LOCATION: 1802 NW 37th Ave, Miami, FL 33125 WELL NO: MW-38 SAMPLE ID PACE DATE: 4 / 8 / 2019 PURGING DATA (2 / 2B / 3 WELL ( PVC) DIAMETER (inches): 2.0 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 4.3 feet to 14.3 feet STATIC DEPTH TO WATER (feet BLS): 3.71 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) _ ( 14.3 feet - 3.71 feet) X 0.16 gallons/foot = 1.69 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 9 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 9 PURGING INITIATED AT: 11:29 PURGING ENDED AT: 11:53 TOTAL VOLUME PURGED (gallons): 3.0 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm ) TURBIDITY (NTUs) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 11:45 2.0 2.0 0.125 3.74 7.08 0.577 7.22 4.6 25.77 Clear None 11:49 0.5 2.5 0.125 3.74 7.09 0.554 6.43 3.0 25.76 Clear None 11:53 0.5 3.0 0.125 3.74 7.10 0.549 3.18 2.8 25.75 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37, 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Russell Fernandez / EE&G SAMPLER(S) SIGNATURE(S): SAMPLING INITIATED AT: 11:54 SAMPLING ENDED AT: 12:00 PUMP OR TUBING DEPTH IN WELL (feet): 9 TUBING MATERIAL CODE: HDPE/S FIELD -FILTERED: Q N FILTER SIZE: Filtration Equipment Type: 1 gm FIELD DECONTAMINATION: PUMP Y QN TUBING Y QN (replaced) DUPLICATE: Y II SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE in mper minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total Fe APP 500 1 PE 250 mL HNO3 - < 2 Dissolved Fe APP 500 REMARKS: TQ.0 -0.37' YS1556 MPM # 7 TBM#2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; S = Silicone; T = Teflon; 0 = Other (Specify) LDPE = Low Density Polyethylene; PP = Polypropylene; SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 EEG ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-9 SITE LOCATION: 1802 NW 37th Ave, Miami, FL 33125 SAMPLE ID: PACE DATE: 4/8/2019 PURGING DATA (2 / 2B / 3 ) WELL ( PVC) DIAMETER (inches): 2.0 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 2.97 feet to 12.97 feet STATIC DEPTH TO WATER (feet BLS): 3.73 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 12.97 feet - 3.73 feet) X 0.16 gallons/foot = 1.48 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 8.5 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 8.5 PURGING INITIATED AT: 12:40 PURGING ENDED AT: 13:04 TOTAL VOLUME PURGED (gallons): 3.0 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 12:56 2.0 2.0 0.125 4.23 6.89 1.250 6.3 3.9 26.93 Clear w/ organic debris None 13:00 0.5 2.5 0.125 4.23 6.92 1.187 7.13 3.4 26.90 Clear w/ organic debris None 13:04 0.5 3.0 0.125 4.23 6.94 1.168 7.08 3.8 26.89 Clear w/ organic debris None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Russell Fernandez / EE&G SAMPLER(S) SIGNATURE(S): SAMPLING INITIATED AT: 13:05 SAMPLING ENDED AT: 13:10 PUMP OR TUBING DEPTH IN WELL (feet): 8.5 TUBING MATERIAL CODE: HDPE/S FIELD -FILTERED: 0 N FILTER SIZE: Filtration Equipment Type: 1 µm FIELD DECONTAMINATION: PUMP Y Li TUBING Y QN (replaced) DUPLICATE: Y �N SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total Fe APP 500 1 PE 250 mL HNO3 - < 2 Dissolved Fe APP 500 REMARKS: TO.0 -0.27 YS1556 MPM#7 7BM#2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally ± 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 E E ENVIRONMENTAL SERVICES. LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) SITE LOCATION: 1802 NW 37`h Avenue Miami, FL 33125 WELL NO: MW-5 SAMPLE ID: PACE DATE: 4 / 8 / 2019 PURGING DATA (2 / 2B / 3 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 3.05 feet to 13.05 feet STATIC DEPTH TO WATER (feet BLS): 4.24 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 13.05 feet- 4.24 feet) X 0.09 gallons/foot = 0.79 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME+ (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 8 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 8 PURGING INITIATED AT: 13:48 PURGING ENDED AT: 14:12 TOTAL VOLUME PURGED (gallons): 3.0 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (%Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 13:56 1.0 1.0 0.125 4.26 7.29 0.843 OR 5.0 25.40 Cloudy None 14 00 0.5 1.5 0.125 4.26 7.22 0.792 OR 2.9 25.38 Cloudy None 14:04 0.5 2.0 0.125 4.26 7.22 0.785 OR 2.7 25.38 Cloudy None 14:08 0.5 2.5 0.125 4.26 7.21 0.772 OR 2.3 25.33 Cloudy None 14:12 0.5 3.0 0.125 4.26 7.22 0.769 OR 2.5 25.32 Cloudy None WELL CAPACITY (Gallons Per Foot): 0.75" = 0 02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gat./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5116" = 0.004; 3/8" = 0.006; 1/2" = 0.010 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) /AFFILIATION: Russell Fernandez / EE&G SAMPLER(S) SIGNATURE(S): T -- SAMPLING INITIATED AT: 14:12 SAMPLING ENDED AT: 14:20 PUMP OR TUBING DEPTH IN WELL (feet): 8 TUBING FIELD -FILTERED: 0 N FILTER MATERIAL CODE: HDPE/S Filtration Equipment Type: SIZE: 1 pm FIELD DECONTAMINATION: PUMP Y 11 TUBING Y ® (replaced) DUPLICATE: Y 0 SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE #CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total Fe APP 500 1 PE 250 mL HNO3 - < 2 Diss. Fe APP 500 REMARKS: T.C.C. -035' VS/556 MPM#7 TBM#2 MATERIAL CODES: AG = Amber Glass; S = Silicone; T = CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: ± 0.2 units Temperature: + 0.2 °C Specific Conductance: ± 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, ± 0.2 mg/L or ± 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 EEtG ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-10 SITE LOCATION: 1802 NW 37th Ave, Miami, FL 33125 SAMPLE ID: PACE DATE: 4/9/2019 PURGING DATA (2 / 2B / 3 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 3.6 feet to 13.6 feet STATIC DEPTH TO WATER (feet BLS): 5.75 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 13.6 feet - 5.75 feet) X 0.09 gallons/foot = 0.71 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 9 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 9 PURGING INITIATED AT: 09:36 PURGING ENDED AT: 10:00 TOTAL VOLUME PURGED (gallons): 3.0 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 09:44 1.0 1.0 0.125 5.77 6.98 0.728 OR 17.8 24.73 Cloudy None 09:48 0.5 1.5 0.125 5.77 7.00 0.722 OR 17.0 24.72 Cloudy None 09:52 0.5 2.0 0.125 5.77 7.03 0.715 OR 16.4 24.72 Cloudy None 09:56 0.5 2.5 0.125 5.77 7.04 0.707 OR 16.0 24.71 Cloudy None 10:00 0.5 3.0 0.125 5.77 7.02 0.710 OR 15.7 24.70 Cloudy None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Russell Fernandez / EE&G SAMPLER(S) SIGNATURE(S): SAMPLING INITIATED AT: 10:00 SAMPLING ENDED AT: 10:05 PUMP OR TUBING DEPTH IN WELL (feet): 9 TUBING MATERIAL CODE: HDPE/S FIELD -FILTERED: 0 N FILTER SIZE: Filtration Equipment Type: 1 gm FIELD DECONTAMINATION: PUMP Y QN TUBING Y QN (replaced) DUPLICATE: Y D SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total As, Pb, Fe APP 500 1 PE 250 mL HNO3 - < 2 Diss. As, Pb, Fe APP 500 REMARKS: TO.0 -0.3.2' YS1556 MPM#7 TBM#2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 31 pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 E E tG ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) SITE LOCATION: 1802 NW 37th Ave, Miami, FL 33125 WELL NO: MW-11 SAMPLE ID: PACE DATE: 4 / 9 / 2019 PURGING DATA (2 / 2B / 3 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 1.5 feet to 11.5 feet STATIC DEPTH TO WATER (feet BLS): 3.49 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 11.5 feet- 3.49 feet) X 0.09 gallons/foot = 0.72 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 7.5 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 7.5 PURGING INITIATED AT: 10:33 PURGING ENDED AT: 10:57 TOTAL VOLUME PURGED (gallons): 3.0 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (°� Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 10:41 1.0 1.0 0.125 3.5 7.62 0.483 OR 19.8 25.59 Dark Grey / Cloudy None 10:45 0.5 1.5 0.125 3.5 7.61 0.482 OR 16.1 25.59 Dark Grey / Cloudy None 10:49 0.5 2.0 0.125 3.5 7.56 0.482 OR 13.9 25.61 Dark Grey / Cloudy None 10:53 0.5 2.5 0.125 3.5 7.55 0.481 OR 11.8 25.59 Dark Grey / Cloudy None 10:57 0.5 3.0 0.125 3.5 7.54 0.481 OR 11.2 25.58 Dark Grey / Cloudy None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Russell Fernandez / EE&G SAMPLER(S) SIGNATURE(S): - _ SAMPLING INITIATED AT: 10:58 SAMPLING ENDED AT: 11:04 PUMP OR TUBING DEPTH IN WELL (feet): 7.5 TUBING MATERIAL CODE: HDPE/S FIELD -FILTERED: 0 N FILTER SIZE: Filtration Equipment Type: 1 µm FIELD DECONTAMINATION: PUMP Y QN TUBING Y QN (replaced) DUPLICATE: Y QN SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total As, Pb, Fe APP 500 1 PE 250 mL HNO3 - < 2 Diss. As, Pb, Fe APP 500 REMARKS: T.O. C -0. 19' Y5/ 556 MPM #7 TBM#2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 E E &G ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-12 SITE LOCATION: 1802 NW 37u' Ave, Miami, FL 33125 SAMPLE ID: PACE DATE: 4 / 9 / 2019 PURGING DATA (2 / 2B / 3 ) WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 2.35 feet to 12.35 feet STATIC DEPTH TO WATER (feet BLS): 3.3 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 12.35 feet - 3.3 feet) X 0.09 gallons/foot = 0.81 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 8.0 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 8.0 PURGING INITIATED AT: 11:26 PURGING ENDED AT: 11:50 TOTAL VOLUME PURGED (gallons): 3.0 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 11:34 1.0 1.0 0.125 3.87 7.47 0.807 OR 28.3 25.20 Dark Grey / Cloudy None 11:38 0.5 1.5 0.125 3.87 7.41 0.781 OR 23.5 25.19 Dark Grey / Cloudy None 11:42 0.5 2.0 0.125 3.87 7.37 0.754 OR 19.3 25.18 Dark Grey / Cloudy None 11:46 0.5 2.5 0.125 3.87 7.35 0.748 OR 17.4 25.17 Dark Grey / Cloudy None 11:50 0.5 3.0 0.125 3.87 7.32 0.736 OR 16.0 25.16 Dark Grey / Cloudy None - WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Russell Fernandez / EE&G SAMPLER(S) SIGNATURE(S): -, 'p ---, SAMPLING INITIATED AT: 11:50 SAMPLING ENDED AT: 11:56 PUMP OR TUBING DEPTH IN WELL (feet): 8.0 TUBING MATERIAL CODE: HDPE/S FIELD -FILTERED: 0 N FILTER SIZE: Filtration Equipment Type: 1 µm FIELD DECONTAMINATION: PUMP Y QN TUBING Y © (replaced) DUPLICATE: Y LI SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE in mper minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total As, Pb, Fe APP 500 1 PE 250 mL HNO3 - < 2 Diss. As, Pb, Fe APP 500 REMARKS: TO.C. -0.28' YS/5J6 MPM#7 TBM#2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 31 pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 TABLE 2: SOIL ANALYTICAL SUMMARY Melreese Golf Course Sample SCS Arsenic Ash EE&G Arsenic Location Depth Date (mg/kg) (mg/kg) SB-4A 0-0.5' 9/17/2019 81.9 None 0-0.5' 156 SB-4B 0-0.5' 9/17/2019 83.3 None 0.5-2' 12 ace Analyticar wwwpacefabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 September 20, 2019 Brittney Odom SCS Engineers 1900 NW Corporate Blvd Suite E300 Boca Raton, FL 33431 RE: Project: 09219075.21 Melreese Pace Project No.: 35498754 Dear Brittney Odom: Enclosed are the analytical results for sample(s) received by the laboratory on September 18, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Kole Holman, SCS Engineers Sanaul Khan, SCS Engineers Troy Schick, SCS Engineers David Taylor, SCS Engineers REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 16 (/eAnaIYticaI www.pace&abs.com CERTIFICATIONS Project: 09219075.21 Melreese Pace Project No.: 35498754 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Ormond Beach Certification Ds 8 East Tower Circle, Ormond Beach, FL 32174 Alaska DEC- CS/UST/LUST Alabama Certification #: 41320 Arizona Certification# AZ0819 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 16 (/eAnaIYticaI www.pace&abs.com SAMPLE SUMMARY Project: 09219075.21 Melreese Pace Project No.: 35498754 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35498754001 MW-3 Water 09/18/19 10:54 09/18/19 17:50 35498754002 MW-9 Water 09/18/19 14:32 09/18/19 17:50 35498754003 MW-11 Water 09/18/19 10:10 09/18/19 17:50 35498754004 MW-8 Water 09/18/19 09:27 09/18/19 17:50 35498754005 MW-5 Water 09/18/19 12:57 09/18/19 17:50 35498754006 MW-38 Water 09/18/19 11:55 09/18/19 17:50 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 16 ceAnalytical www.pace&abs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 SAMPLE ANALYTE COUNT Project: 09219075.21 Melreese Pace Project No.: 35498754 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35498754001 MW-3 EPA 6020 KPP 1 PASI-O 35498754002 MW-9 EPA 6020 KPP 1 PASI-O 35498754003 MW-11 EPA 6020 KPP 1 PASI-O 35498754004 MW-8 EPA 6020 KPP 1 PASI-O 35498754005 MW-5 EPA 6020 KPP 1 PASI-O 35498754006 MW-38 EPA 6020 KPP 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 16 ceAnalytical www.pace&abs.cam Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 PROJECT NARRATIVE Project: 09219075.21 Melreese Pace Project No.: 35498754 Method: EPA 6020 Description: 6020 MET ICPMS Client: SCS Engineers Date: September 20, 2019 General Information: 6 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3010 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 16 (/eAnaIYticaI www.pace&abs.com ANALYTICAL RESULTS Project: 09219075.21 Melreese Pace Project No.: 35498754 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Sample: MW-3 Lab ID: 35498754001 Collected: 09/18/19 10:54 Received: 09/18/19 17:50 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3010 Iron 75.0 ug/L 10.0 6.9 1 09/20/19 04:13 09/20/19 12:10 7439-89-6 REPORT OF LABORATORY ANALYSIS Date: 09/20/2019 04:35 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 16 (/eAnaIYticaI www.pace&abs.com ANALYTICAL RESULTS Project: 09219075.21 Melreese Pace Project No.: 35498754 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Sample: MW-9 Lab ID: 35498754002 Collected: 09/18/19 14:32 Received: 09/18/19 17:50 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3010 Iron 695 ug/L 10.0 6.9 1 09/20/19 04:13 09/20/19 12:13 7439-89-6 REPORT OF LABORATORY ANALYSIS Date: 09/20/2019 04:35 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 16 (/eAnaIYticaI www.pace&abs.com ANALYTICAL RESULTS Project: 09219075.21 Melreese Pace Project No.: 35498754 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Sample: MW-11 Lab ID: 35498754003 Collected: 09/18/19 10:10 Received: 09/18/19 17:50 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3010 Iron 22.7 ug/L 10.0 6.9 1 09/20/19 04:13 09/20/19 12:16 7439-89-6 REPORT OF LABORATORY ANALYSIS Date: 09/20/2019 04:35 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 16 (/eAnaIYticaI www.pace&abs.com ANALYTICAL RESULTS Project: 09219075.21 Melreese Pace Project No.: 35498754 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Sample: MW-8 Lab ID: 35498754004 Collected: 09/18/19 09:27 Received: 09/18/19 17:50 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3010 Iron 115 ug/L 10.0 6.9 1 09/20/19 04:13 09/20/19 12:24 7439-89-6 REPORT OF LABORATORY ANALYSIS Date: 09/20/2019 04:35 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 16 (/eAnaIYticaI www.pace&abs.cam ANALYTICAL RESULTS Project: 09219075.21 Melreese Pace Project No.: 35498754 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Sample: MW-5 Lab ID: 35498754005 Collected: 09/18/19 12:57 Received: 09/18/19 17:50 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3010 Iron 2990 ug/L 10.0 6.9 1 09/20/19 04:13 09/20/19 12:27 7439-89-6 REPORT OF LABORATORY ANALYSIS Date: 09/20/2019 04:35 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 16 (/eAnaIYticaI www.pace&abs.com ANALYTICAL RESULTS Project: 09219075.21 Melreese Pace Project No.: 35498754 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Sample: MW-38 Lab ID: 35498754006 Collected: 09/18/19 11:55 Received: 09/18/19 17:50 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3010 Iron 2880 ug/L 10.0 6.9 1 09/20/19 04:13 09/20/19 12:30 7439-89-6 REPORT OF LABORATORY ANALYSIS Date: 09/20/2019 04:35 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 16 ceAnalytical www.pace&abs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 QUALITY CONTROL DATA Project: 09219075.21 Melreese Pace Project No.: 35498754 QC Batch: 571794 Analysis Method: EPA 6020 QC Batch Method: EPA 3010 Analysis Description: 6020 MET Associated Lab Samples: 35498754001, 35498754002, 35498754003, 35498754004, 35498754005, 35498754006 METHOD BLANK: 3107804 Matrix: Water Associated Lab Samples: 35498754001, 35498754002, 35498754003, 35498754004, 35498754005, 35498754006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Iron ug/L 6.9 U 10.0 6.9 09/20/1911:51 LABORATORY CONTROL SAMPLE: 3107805 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Iron ug/L 500 494 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3107806 3107807 MS MSD 35493543002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Iron ug/L 201 500 500 655 660 91 92 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS Date: 09/20/2019 04:35 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 16 (/eAnaIYticaI www.pace&abs.cam QUALIFIERS Project: 09219075.21 Melreese Pace Project No.: 35498754 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL- Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS U Compound was analyzed for but not detected. REPORT OF LABORATORY ANALYSIS Date: 09/20/2019 04:35 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 16 ceAnalytical www.pace&abs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 09219075.21 Melreese Pace Project No.: 35498754 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 35498754001 MW-3 EPA 3010 571794 EPA 6020 571801 35498754002 MW-9 EPA 3010 571794 EPA 6020 571801 35498754003 MW-11 EPA 3010 571794 EPA 6020 571801 35498754004 MW-8 EPA 3010 571794 EPA 6020 571801 35498754005 MW-5 EPA 3010 571794 EPA 6020 571801 35498754006 MW-38 EPA 3010 571794 EPA 6020 571801 REPORT OF LABORATORY ANALYSIS Date: 09/20/2019 04:35 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 16 CIO#:35498754 Container Type Codes taceAnalytical lIlIlIlIlIlIlIl 1111111 www.pacelabs.com 35498i54 F CUSTODY RECORD Quote: Page of Co 'many Name: Ad cress: Cit tvy', r In N r�tifP Po# State: Zip: Attic Fax# emtiil:rtNr 1e J S;e-C,_<./5 Phone: Project Name r .r1, Sampler Signature E co ofi 2 3 1 • Sample ID Nrw} Proj # " 7 ti �1 r. =.'. . "2-1 t pircle One Event: Daily Weekly Monthly .".Quartely Semi -Annual Annual NIA Collect Date Collect Time UL Matrix Code* li u at:2' c p ov nr N Sample TRC pH Pres Codes Parameters L I ❑ F.•, ❑ ❑ LAB ANALYSIS n 0 o W" J IL v 2 co X J W ui to # of Containers SizelType 4 II 5 n n n U 6 ] ❑ u n 7 n ❑ ❑ I U 8 ❑ ❑ 9 ❑ n 10 C,k'b T,A.T. REQUEST (Roan Foos ROise,m0 Srannsrd Y N RUSH Tdduy 1D 20 3D 4D 50 Short Hold Y N / Circle QA/QC Report Level 2 3 4 CLP AFCEE QAPP Other 11 EDD (Fees May Apply) ADOPT SEDD ERPIMS TSV CSV Other Li ❑ Required Stale COC Condition Certification DK Incomplete FL GA SC NC NJ PA LA TX IL AV Amber Vial ES Encore Sampler CV Clear Vial PPV Propresorved vial P Plastic PL C Plastic container AL Amber Liter. PL J Plastic Jar CL Clear Liter Z 2iplee bag AP Amber Plastic TB Tedlar bag AG Amber Glass WP Whirlpak SJ Soil Jar G Gallon Jug Other TC Terra -core PPV Proprosorved vial Sizels): 2oz, 4oz, 0oz, 16oz, 32oz or 1L, other 40m1 50001 250m1 125 ml Example: 4ozP >, 4oz Plastic, liozSJ= Linz Soil Jar Matrix Codes SD Solid Waste OL Oil GW Ground Water SL Sludge EFF Effluent SG Sall Sediment AFW Analyto Free H2O AO Aqueous WW Waste Water NA Nanaqueous OW Drinking Water PE Petrotoum SW Surface Water 0 Other MI_ Misc. Liquid (Plunen :r,.,s1 Preservative Type Codes A. None E. HCL I. Ice B. HNO3 F. McOH J. MCAA C. H2SO4 G. Na2S203 K. in Acetate D. NaOH H. NaHSO4 O. Other REMARKS Coolers #'s - Temp °C 1 L —2 3 4 5 Item 1 A (24 0 Relinquished by mpano Lab 954-582-4300 Illation Date Revision: F-ALL•C•007- Rev.00 Time Received ity ,Affiliation /tote/,, =N.. ° Vie/ /�'f l'irt/tCY Time Nor Cenral -manna Fou,d. Samples INTACT upon vale Received on Wel Ice? Proper Preservatives Indicated? Received within holding rime? Custody seals Intact? Volatiles rocd without headspace? Proper Containers used? C.Q.C. Serial # 151037 ace Analytical' F�vnU:. Lvbri�(o�r Document t : Sample Condition Upon Receipt Form Document I— F-FL-C-007 rev. 13 110#:35498754 Document Revised: May 30, 2018 Issuing Authority: Face Flnrirla ()i rality Office Prof, P)1: CTR Due Date: 09/26/19 ProjectRa an CLIENT: 36-ESCON Colt .. Theometer Used: J rm57 State of Origin: Cooler#1 Temp.°C z 7 (Visual) Cooler#2 Temp,°C (Visual) Cooler #3 Temp.°C (Visual) Cooler #4 Temp.°C (Visual) Cooler #5 Temp.°C (Visual) Cooler #6 Temp.°C (Visual) Date: Date and Initials of person: Examining contents: Labek � Deliver: pH: Timer - ❑ For WV, projects, all containers verified to ss °C (Correction Factor) i if (Actual) (Correction Factor) (Actual) (Correction Factor) (Actual) (Correction Factor) (Actual) (Correction Factor) (Actual) (Correction Factor) (Actual) Courier: 0 Fed Ex J1 UPS ❑ USPS El Client Commercial El Pace Shipping IVlethod: ❑ First Overnight 0 Other 0 Priority Overnight ❑ Standard Overnight 0 Ground Billing: 0 Recipient ❑ Sender Tracking # Custody Seal on Cooler/Box Present: ❑Yes Lfo' ❑ Third Party ❑ Credit Card Initials: 7777-----4--/7 ❑ Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun ❑ Samples an ice, cooling process has begun ❑ Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun • Samples on ice, cooling process has begun ❑ Other ❑ International Priority ❑ Unknown Seals intact: © Yes ❑ No Packing Material: OBubble Wrap ,.l�ubble Bags ❑None AOther Ice: Blue Dry None — Samptes-s es, complete) Shorted Dale: Chain of Custody Present Chain of Custody Filled Out Relinquished Signature & Sampler Name COC Samples Arrived within Hold lime Rush TAT requested on COC Sufficient Volume Correct Containers Used Shorted Time: ElYes ❑ No ❑N/A res i tYes Yes VV❑Yes Yes Containers Intact Sample Labolc match COC (3ompic !Do &-dateltime of collection) Ail containers needing acid/base preservation have been checked. Alt Containers needing preservation are found to be in compliance with EPA recommendation: - - Exceptions: VOA, Coli;omi._ Yes ❑ No ❑N/A ❑ No ❑N/A ❑ No ❑N/A ❑No Id N/A 0 No N/A ❑No ❑N/A Yes 0 No ON/A Yes Yes Yes ❑ No ❑N/A ID No ❑NIA ❑No ON/A Comments: Preservation information: Preservative: Lot #!Trace #: city: Date:�. Time: ---- _ - - . initial$.. Headspace in VOA Vials? (>6mm): ❑Yes 0 No ❑N/A Trip Blank Present: DYes 0 No DN/A Client_Notificationl-Resolution: -- Person Contacted: Comments! Resolution (use back for additronal.commenfs) Date/Time: Project Manager Review: Date: — s- �iioflb ace Analyticar wwwpacefabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 September 20, 2019 Maria Giudici SCS Engineers 9500 S Deland Blvd Suite #610 Miami, FL 33156 RE: Project: 09219075.21/Melrose Golf Cours Pace Project No.: 35498148 Dear Maria Giudici: Enclosed are the analytical results for sample(s) received by the laboratory on September 17, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Safiyah Junaid, SCS Engineers Troy Schick, SCS Engineers REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 13 (/eAnaIYticaI www.pace&abs.com CERTIFICATIONS Project: 09219075.21/Melrose Golf Cours Pace Project No.: 35498148 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Ormond Beach Certification Ds 8 East Tower Circle, Ormond Beach, FL 32174 Alaska DEC- CS/UST/LUST Alabama Certification #: 41320 Arizona Certification# AZ0819 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 13 (/eAnaIYticaI www.pace&abs.com SAMPLE SUMMARY Project: 09219075.21/Melrose Golf Cours Pace Project No.: 35498148 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35498148001 SB-4A (0-0.5) Solid 09/17/19 11:08 09/17/19 17:05 35498148002 SB-4A (0.5-2) Solid 09/17/19 11:08 09/17/19 17:05 35498148003 SB-4B (0-0.5) Solid 09/17/19 11:15 09/17/19 17:05 35498148004 SB-4B (0.5-2) Solid 09/17/19 11:15 09/17/19 17:05 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 13 (/eAnaIYticaI www.pace&abs.com SAMPLE ANALYTE COUNT Project: 09219075.21/Melrose Golf Cours Pace Project No.: 35498148 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35498148001 SB-4A (0-0.5) EPA 6010 ATC 1 PASI-O ASTM D2974-87 CLT 1 PASI-O 35498148003 SB-4B (0-0.5) EPA 6010 ATC 1 PASI-O ASTM D2974-87 CLT 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 13 ceAnalytical www.pace&abs.cam 5 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 PROJECT NARRATIVE Project: 09219075.21/Melrose Golf Cours Pace Project No.: 35498148 Method: EPA 6010 Description: 6010 MET ICP Client: SCS Engineers Date: September 20, 2019 General Information: 2 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 13 aceAnalytical www.pace&abs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 ANALYTICAL RESULTS Project: 09219075.21/Melrose Golf Cours Pace Project No.: 35498148 Sample: SB-4A (0-0.5) Lab ID: 35498148001 Collected: 09/17/19 11:08 Received: 09/17/19 17:05 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 81.9 mg/kg 0.59 0.29 1 09/19/19 01:21 09/20/19 09:22 7440-38-2 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 9.5 % 0.10 0.10 1 09/20/19 09:05 REPORT OF LABORATORY ANALYSIS Date: 09/20/2019 06:57 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 13 (/eAnaIYticaI www.pace&abs.com ANALYTICAL RESULTS Project: 09219075.21/Melrose Golf Cours Pace Project No.: 35498148 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Sample: SB-4B (0-0.5) Lab ID: 35498148003 Collected: 09/17/19 11:15 Received: 09/17/19 17:05 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 83.3 mg/kg 0.68 0.34 1 09/19/19 01:21 09/20/19 09:27 7440-38-2 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 33.5 % 0.10 0.10 1 09/20/19 09:05 REPORT OF LABORATORY ANALYSIS Date: 09/20/2019 06:57 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 13 (/eAnaIYticaI www.pace&abs.com QUALITY CONTROL DATA Project: 09219075.21/Melrose Golf Cours Pace Project No.: 35498148 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 QC Batch: 571279 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 35498148001, 35498148003 METHOD BLANK: 3104350 Matrix: Solid Associated Lab Samples: 35498148001, 35498148003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic mg/kg 0.28 U 0.55 0.28 09/20/19 07:21 LABORATORY CONTROL SAMPLE: 3104351 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic mg/kg 11.2 11.3 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3104352 3104353 MS MSD 35497973005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic mg/kg 5.2 13.6 11.3 16.5 15.0 83 86 75-125 10 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS Date: 09/20/2019 06:57 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 13 (/eAnaIYticaI www.pace&abs.com QUALITY CONTROL DATA Project: 09219075.21/Melrose Golf Cours Pace Project No.: 35498148 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 QC Batch: 571874 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 35498148001, 35498148003 SAMPLE DUPLICATE: 3108271 35497972001 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture % 2.3 1.9 17 10 J(D6) SAMPLE DUPLICATE: 3108272 35498294001 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture % 4.7 4.3 9 10 SAMPLE DUPLICATE: 3108273 35498874003 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture % 10.7 10.3 4 10 SAMPLE DUPLICATE: 3108274 35498884003 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture % 10.4 10.6 2 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS Date: 09/20/2019 06:57 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 13 (/eAnaIYticaI www.pace&abs.cam QUALIFIERS Project: 09219075.21/Melrose Golf Cours Pace Project No.: 35498148 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL- Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS U J(D6) Compound was analyzed for but not detected. Estimated Value. The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. REPORT OF LABORATORY ANALYSIS Date: 09/20/2019 06:57 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 13 (/eAnaIYticaI www.pace&abs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 09219075.21/Melrose Golf Cours Pace Project No.: 35498148 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Lab ID Sample ID QC Batch Method Analytical QC Batch Analytical Method Batch 35498148001 SB-4A (0-0.5) EPA 3050 571279 EPA 6010 571419 35498148003 SB-4B (0-0.5) EPA 3050 571279 EPA 6010 571419 35498148001 SB-4A (0-0.5) ASTM D2974-87 571874 35498148003 SB-4B (0-0.5) ASTM D2974-87 571874 REPORT OF LABORATORY ANALYSIS Date: 09/20/2019 06:57 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 13 , IJ FaceAnalytical n www. acela!s.com p WON : 3i54� ,RQ II ��l • ItNNWI1 Page IOf g Container Type Codes AV Amber Vial ES Encore Sampler CV Cloaf Vkd PPV Praptic Jar d v[sl�� P Plastic PLC Plastic senhtare AL Amber Lear PL J Plastic Jar OL Clear Liter Z Ziplec bag AP Amber Plastic TB Todlar bag AG Amber Gloss WP Whirl Oak 5J Sail Jar G Gallon Jug Other TO Terra core V i - 35�8814a PPV Prepreserved vial Sizo(s). lox, 4oz, aoz, 16oz. 32oz or 1L, other 40m1 509m1 250m1 c. zi 4azP=4oz Plastic. BaxSJ=8rx Sell Jar CompanyName: � r� S , 01, \ I$ 1�' ,r 1►Ys11 p#Es,ample: ' LAB ANALYSIS Address: t n gi o Sample Citylt fi gone/ state: zip: TRC Matrix Codes f�'� j; i Attn: ? 1 i aIy • rJ /fir/ ✓� l'tj t c 1 _ Fax# pH SD Solid Waste OL Oil GW Groa red Water SL Sludge EFF Effluent SO Sol Sediment AFW Analytn Free H2O AO Aqueous WW Waste Water NA Nonaeosouv pW Drinking Water PE Petroleum Surface Wider PEOther ML Misc. Liquid taleaee epeuryl � l ��fll email(''..1 cL vvv �(�` [ a U C S ' r _ �� ,� �y / ,rr.�! l{ ► U(�.$_-?Q l/ !',• odes Y Project Name r Q Proj # Parameters r, EXAMPLE piss. Lead 6010 Preservative Type Codes Sampler Signature Circle One Event Daily Weekly Monthly Ctuartely Semi -Annual Annual N/A � •UJ A. None E. HCL I. Ice B. HNO3 F. McOH J. MCAA C. H2SO4 G. Na2S203 K. zd Acetate D. NaOH H. NaH504 0, Other Sample # `5ampb ID Collect Date Collect Time Matrix Code' -o — 11 it rz E}3 ac = O # m 2 o Containers#afe/Typo a-- Size/Typo �^' zP REMARKS 1 !3F-LIALO-Dr q ,<4i°11;,)7 1 I ❑ ❑ ❑ I I Li Li ❑ 1 I _ y i 2.q5- -iA(0.5-a. j }111 1:c ',: r- I I IA i I I 1 ■ 4 . 3—L18 (O,S`; `P1,. ' C 1: l5 t. I ; ❑ ❑ ❑ ❑ ❑ ❑ I I ❑ I 5 1 1 1 1 1 E. 1 1 ❑ ❑ ❑ ❑ 6 ❑ ❑ f 1 I I ❑ 1 I ❑ ❑ • 7 1 1 ❑ 11 ❑ ❑ ❑ 1 I ❑ I I ❑ 8 11 11 ❑ ❑ ❑ ❑ 11 11 ❑ [1 9 ❑ I I ❑ ❑ 1 I ❑ ❑ ❑ 1 1 1a I I ❑ ❑ 7 ❑ ❑ II ❑ 1I c cis T.A.T,RE41JE8r(Re. sesAspic.* EDD (Fees May Apply) COC Condition Required State Certification Coolers #'s - Temp °C s.,...-° RUSH ShbrtI Hold Circle QAJQC Report Level Y N Today 1p 20 30 4p 60 y -- N 1 2 3 4 CLP AFCEE QAPP Other ADaPT SEDD ERPIMS TSV. CSV Other '.--, ,� OK roomplanr FL GA SC NC NJ PA LA TX IL 1 `f ' 2 3 4 5 Item R�jel11nquished by 1 Afiiafi[�n D t10 Timer Receiued "p (Affiliation )date a Time . r 1„t � YR >1,2 iv 9 Ury�[1 [P 9 Cg 1yti�' J -_, .. _ . '2' i 2 yr /' //'' ' / J. 1�- / Samples INTAnTepaned? Sam 1 INTACTu o arrival? Received en Wet Ice? Proper Preservatives Indicated? Received within holding time? _ Custody seals intact? _ i VaEalEles reed wlEhaul haadspaca7 Proper Containers Usod7 2 ' k. y, ✓✓✓ - 'I.� i.J ! J A; y 1J t (///}` >�J / ,- �L.e -\ 1 _ 'e' -t 1 ".�.f f/ /C d(1 , ii 1 1 ! 1 , II .J f ., + ; 'f�l /f Jf iii(y / N POYnpano Lab 954-582-4300 —11 W Revision: F•ALL•C•007- Rev.00 C.O.C. Serial # 1 5 0 8 7 5 eceEpt Form Document Revisec May 30, 2018 r 9 f'7-)Ge Analytical '3 WAD# 3�5498148 Project ; PM. CTR DUe Date: 09/24/19 Project Manager CLIENT: 36-ESCON Client: Thermometer Used Date (SCUR) issuing Authority. Pace Florida Quality Office Date and Initials of person: Examining contents: f ' S I el/Oh/el Label: Deliver: pH: Tlme 11°S Initials LSJ ) State of Origin For I . 7,,E :__ �:... ._-_ _ .e-f/ tc <6':, Cooler #1 Temp."C (Visual) U `O (Correction Factor) r --, (Actual) L Samples on ice, oaolino process has begun Cooler #2 Temp.°C (Visual) (Correction Factor) (Actual) L Samples on iee, ccolina process has beaun Cooler #3 Temp.°C (Visual) (Correction Factor) (Actual) L Samples on ice, cooling process has begun Cooter #4 Temp.°C (Visual) (Correction Factor) (Actual) L Samples on ice, cooling process has begun Cooler #5 Temp-°C (Visual) (Correction Factor) (Actual} L Samples on ice, cooling process has begun Cooler #6 Temp.°C (Visual) (Correction Factor) (Actual) (— Samples on ice, cooling process has begun Courier: Fed Ex ] UPS CUSPS — Client L Commercial ace 1= Other Shipping Method: First Overnight =- Priority Overnight Standard Overnight Ground :. International Priority Other Billing: -Recipient Sender Third Party :- Credit Card _ Unknown Tracking # i Custody Seal on Cooler/Box Present: JYes No Seals intact:,1. r Yes No Ice: t Blue Dry None Packing Material: -Bubble Wrap E-&bble Bags LNone Other r�.tC} Samples shorted to lab (If Yes, complete) Shorted Date. J Shorted Time: Qty. Chain of Custody Present IYes No. •_-_N!A Chain of Custody Filled Out �s Relinquished Signature & Sampler Name COC YYes Samples Arrived within Hold Time ...._ es Rush TAT requested on CDC -Yesc _- No TNiA = No 7N/A il No _N!A E'N!A ...--- Sufficient Volume -Yes - No _NIA Correct Containers Used Ye No N/A Containers Intact =Ys - No =N/A Sample Labels match COC (sample IDs & date,time of collection) Wires All containers needing acid?base preservation have been decked .;Yes All Containers needing preservation are found to be in compliance with EPA recommendation :Yes txcept,ons VOA C ti`orm : OK.,, C&G, :,erbarnates _ No - _- No . )A ._ No If1A Preservation information Preservative Lot #rf race # Date Time nrt+eds - - - Headspace in VOA Vialsc ( >6mm). -Yes Trip Blank Present LYes : No i f'VA __ No �—hf/A Client Notification) Resolution: Person Contacted: Comments/ Resolution (use back for additional comments): Date/Time. Project Manager Review Date Page 13 of 13 TABLE 1: GROUNDWATER MONITORING WELL ANALYTICAL SUMMARY Melreese Golf Course SCS EE&G Sample Arsenic Iron Turbidity Arsenic Iron Turbidity Location Date (ug/L) (ug/L) NTUs (ug/L) (ug/L) NTUs SCS-MW-1 9/16/2019 NS 3,960 17.4 NS 2,950 25.2 MW-2 09/16/2019 13.5 1,030 13.8 20.9 1,600 OR MW-3 09/18/2019 NS 75.0 <10 NS 785 26.4 MW-5 09/18/2019 NS 2,990 <10 NS 2,560 OR MW-8 09/18/2019 NS 115 <10 NS 793 17.6 MW-9 09/18/2019 NS 695 <10 NS 1,750 <10 MW-10 09/16/2019 NS 62 <10 NS 1,060 OR MW-11 09/18/2019 NS 22.7 <10 NS 842 OR MW-31 9/16/2019 NS 3,120 <10 NS 2,430 12.7 MW-38 09/18/2019 NS 2,880 <10 NS 2,000 17.1 MW-44 9/16/2019 NS 836 <10 NS 795 <10 GCTLs 10 Miami -Dade Background 706 Notes: OR = Out of range for equipment NS = Not sampled GCTLs = Groundwater Cleanup Target Levels specified in Table I of Chapter 62-777, F.A.C. Bold = Exceeds GCTL for Arsenic or Background for Iron aceAnalyticar wwwpacefabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 September 23, 2019 Brittney Odom SCS Engineers 1900 NW Corporate Blvd Suite E300 Boca Raton, FL 33431 RE: Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Dear Brittney Odom: Enclosed are the analytical results for sample(s) received by the laboratory on September 16, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Kole Holman, SCS Engineers Sanaul Khan, SCS Engineers Troy Schick, SCS Engineers David Taylor, SCS Engineers REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 14 (/eAnaIYticaI www.pace&abs.com CERTIFICATIONS Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Ormond Beach Certification Ds 8 East Tower Circle, Ormond Beach, FL 32174 Alaska DEC- CS/UST/LUST Alabama Certification #: 41320 Arizona Certification# AZ0819 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 14 (/eAnaIYticaI www.pace&abs.com SAMPLE SUMMARY Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35498005001 MW-31 Water 09/16/19 11:32 09/16/19 17:35 35498005002 MW-44 Water 09/16/19 12:45 09/16/19 17:35 35498005003 SCS-MW-1 Water 09/16/19 14:10 09/16/19 17:35 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 14 (/eAnaIYticaI www.pace&abs.com SAMPLE ANALYTE COUNT Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35498005001 MW-31 EPA 6020 AMS 1 PASI-O 35498005002 MW-44 EPA 6020 AMS 1 PASI-O 35498005003 SCS-MW-1 EPA 6020 AMS 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 14 ceAnalytical www.pace&abs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 SUMMARY OF DETECTION Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35498005001 MW-31 EPA 6020 Iron 3120 ug/L 10.0 09/23/19 14:42 35498005002 MW-44 EPA 6020 Iron 836 ug/L 10.0 09/23/19 14:45 35498005003 SCS-MW-1 EPA 6020 Iron 3960 ug/L 10.0 09/23/19 14:48 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 14 ceAnalytical www.pace&abs.cam 5 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 PROJECT NARRATIVE Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Method: EPA 6020 Description: 6020 MET ICPMS Client: SCS Engineers Date: September 23, 2019 General Information: 3 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3010 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 14 (/eAnaIYticaI www.pace&abs.com ANALYTICAL RESULTS Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Sample: MW-31 Lab ID: 35498005001 Collected: 09/16/19 11:32 Received: 09/16/19 17:35 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3010 Iron 3120 ug/L 10.0 6.9 1 09/17/19 07:53 09/23/19 14:42 7439-89-6 REPORT OF LABORATORY ANALYSIS Date: 09/23/2019 04:56 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 14 aceAnalytical www.pace&abs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 ANALYTICAL RESULTS Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Sample: MW-44 Lab ID: 35498005002 Collected: 09/16/19 12:45 Received: 09/16/19 17:35 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3010 Iron 836 ug/L 10.0 6.9 1 09/17/19 07:53 09/23/19 14:45 7439-89-6 REPORT OF LABORATORY ANALYSIS Date: 09/23/2019 04:56 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 14 aceAnalytical www.pace&abs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 ANALYTICAL RESULTS Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Sample: SCS-MW-1 Lab ID: 35498005003 Collected: 09/16/19 14:10 Received: 09/16/19 17:35 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3010 Iron 3960 ug/L 10.0 6.9 1 09/17/19 07:53 09/23/19 14:48 7439-89-6 REPORT OF LABORATORY ANALYSIS Date: 09/23/2019 04:56 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 14 aceAnalytical www.pace&abs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 QUALITY CONTROL DATA Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 QC Batch: 570724 Analysis Method: EPA 6020 QC Batch Method: EPA 3010 Analysis Description: 6020 MET Associated Lab Samples: 35498005001, 35498005002, 35498005003 METHOD BLANK: 3101541 Matrix: Water Associated Lab Samples: 35498005001, 35498005002, 35498005003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Iron ug/L 6.9 U 10.0 6.9 09/23/19 14:24 LABORATORY CONTROL SAMPLE: 3101542 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Iron ug/L 500 512 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3101543 3101544 MS MSD 35497980001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Iron ug/L 83.5 500 500 599 617 103 107 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS Date: 09/23/2019 04:56 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 14 (/eAnaIYticaI www.pace&abs.cam QUALIFIERS Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL- Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS U Compound was analyzed for but not detected. REPORT OF LABORATORY ANALYSIS Date: 09/23/2019 04:56 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 14 (/eAnaIYticaI www.pace&abs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 35498005001 MW-31 EPA 3010 570724 EPA 6020 570824 35498005002 MW-44 EPA 3010 570724 EPA 6020 570824 35498005003 SCS-MW-1 EPA 3010 570724 EPA 6020 570824 REPORT OF LABORATORY ANALYSIS Date: 09/23/2019 04:56 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 14 PaceAna!i-Mica! Section A Required Client Information WO#:35498005 llllllllllllllllllllll ;HAIN-OF-CUSTODY I Analytical Request Document he Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section C Invoice Information: Page : Of Cer;ip` ny SCS EnGinc en Address Address 9SD0 S Deland Blvd Copy To Company Nam. Miami FL 33156 Andress Regulator/ Agency Email anrelsen@scseng1necrs_com It Purchase Order # Face Quote Phe^05+-0?.3 ;'S z Pro}eci Name Mele -ec Gulf Ccurn� - Pre=Irr„ Manager chrislina reschke(a?pecelabe com, }Pi;. State 1 Location Nequr, stco De 5)ele Project # �� ��-�. Z - <. !' . iEu k FL • • Requested Analysis Filtered !YIN) ^^ MATRIX CODE MATRIX CODE {see valid codes to left) SAMPLE TYPE (G=ORA.2 C=COMP) COLLECTED SAMPLE TEMP AT COLLECTION Preservatives % Dunking Wahl DW Waist WT Mute Water WN Product P SAMPLE ID SnWSokd SL oil ex G^ I G START END H2SO4 Na2S203 Analyses Test �^ Residual Chlorine (Y!N) One Character per box. Wrpn WP Air AR (A-Z, 0-9 1 • -) Other aT Sample Ids must be unique Twee TS DATE TIME DATE TIME ' O` L)111 0 a m = ro _ z x z °c cos iris 0 M\µ' 1r a CP �p l _ C� 2 1\1\ ` L! W L ..1 1 la akA 5 }(- 'A 3 Sc S — NAAJ — 1 4� L ` IN' } ‘o X - 4 5 I 8 � , 10 11 12 ,7 r", ADDITIONAL COMMENTS RELINQUISHED DY r AF LIATION DATE TIME CCEP FFI ATIQIII D TE TIME SAMPLE CONDITIONS ti, eJ,. 1 1 ( (6 11 m �� (VD w SAMPLER NAME AND SIGNATURE a m °i } a `m -� .� (m c� } a rn PRINT Name of SAMPLER: i yy ,.� U Lt.� fj � 6. -v. ' U a SIGNATURE or SAMPLERjf'j � 1.4 (A DATE Signed: I f IT u2i ace Analytical Flw:4;, L:rLur:>r��y Upon Receipt Form w4#:35498005 Project* P11: CTR Due Date: 09/24/19 Project Manager: CLIENT: 35-LENCOR Client: Thermometer Used: Date: % �/ Time: C' State of Origin: Cooler #1 Temp.°C // L-(Visual) C _(Correction Factor) / <r +. (Actual) Cooler #2 Temp.°C (Visual) (Correction Factor) (Actual) Cooler #3 Temp.°C (Visual) - (Correction Factor) (Actual) Cooler #4 Temp.°C (Visual) (Correction Factor) (Actual) Cooler #5 Temp.°C (Visual) (Correction Factor) (Actual) Cooler #6 Temp.°C - (Visual) (Correction Factor) (Actual) Courier. ❑ Fed Ex ❑ UPS USPS 0 Client l-I Commerciai El Pace Issuing Authonty: Pace Florida Quality office Date and Initials of • Examining contents:- 1' Label: Deliver: pH: ❑ For WV projects, ail containers verified to s6 °C ❑ Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun • Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun Other Shipping Method: ❑ First Ovemight 0 Priority Overnight 0 Standard Overnight ❑ Ground 0 International Priority 0 Other— -_ -. . Billing: 0 Recipient 0 Sender ❑ Third Party ❑ Credit Card 0 Unknown Tracking # Custody Seal on CoolerlBox Present ❑Yes Pt Seals intact ❑Yes ❑ No iceG e) Blue Dry None Packing Material: ❑Bubble Wrap ❑ Bubble Bags one ❑ Other �� Samples shorted to lab (if Yes, complete) Shorted Date: Shorted Time: Comments: : Chain of Custody Present , IYes LI No ON/A Chain ofCustody Filled "Out -�-- —"--- — — es" -CJ No ❑Nll�— - Relinquished Signature & Sampler Name COC l['ges 0 No ON/A Samples Arrived within Hold Time I es 0 No ON/A Rush TAT requested on COC DYes ko/No ON/A Sufficient Volume ,a<fes ❑ No ON/A Correct Containers Used ,0Yes 0 No ON/A - Containers Intact ZYes 0 No ON/A Sample Labels match COC (sample IDs & dateltime of collection) itSYes © No ❑NtA All containers needing acid/base preservation have been checked. E6es 0 No ON/A All Containers needing preservation are found to be in compliance with EPA recommendation: es 0 No ON/A . Excepticrs; Vn& GplWonn: TOC, O&G, Carbemates Preservation Information: Preservative: Lot #frrace#: Date: Time: Initials: .. __ . _ : - .. . , .. Headspace in VOA Vials? ( >6mm): ❑Yes 0 No 1AJA Trip Blank Present: ❑Yes 0 No I24/A Client Notification/ Resolution: Person Contacted: Comments/ Resolution (use back for additional comments): Date/Time: Project Manager Review: Date: Page 14 of 14 aceAnalyticar wwwpacefabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 September 23, 2019 Brittney Odom SCS Engineers 1900 NW Corporate Blvd Suite E300 Boca Raton, FL 33431 RE: Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Dear Brittney Odom: Enclosed are the analytical results for sample(s) received by the laboratory on September 16, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Kole Holman, SCS Engineers Sanaul Khan, SCS Engineers Troy Schick, SCS Engineers David Taylor, SCS Engineers REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 14 (/eAnaIYticaI www.pace&abs.com CERTIFICATIONS Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Ormond Beach Certification Ds 8 East Tower Circle, Ormond Beach, FL 32174 Alaska DEC- CS/UST/LUST Alabama Certification #: 41320 Arizona Certification# AZ0819 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 14 (/eAnaIYticaI www.pace&abs.com SAMPLE SUMMARY Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35498005001 MW-31 Water 09/16/19 11:32 09/16/19 17:35 35498005002 MW-44 Water 09/16/19 12:45 09/16/19 17:35 35498005003 SCS-MW-1 Water 09/16/19 14:10 09/16/19 17:35 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 14 (/eAnaIYticaI www.pace&abs.com SAMPLE ANALYTE COUNT Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35498005001 MW-31 EPA 6020 AMS 1 PASI-O 35498005002 MW-44 EPA 6020 AMS 1 PASI-O 35498005003 SCS-MW-1 EPA 6020 AMS 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 14 ceAnalytical www.pace&abs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 SUMMARY OF DETECTION Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35498005001 MW-31 EPA 6020 Iron 3120 ug/L 10.0 09/23/19 14:42 35498005002 MW-44 EPA 6020 Iron 836 ug/L 10.0 09/23/19 14:45 35498005003 SCS-MW-1 EPA 6020 Iron 3960 ug/L 10.0 09/23/19 14:48 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 14 ceAnalytical www.pace&abs.cam 5 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 PROJECT NARRATIVE Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Method: EPA 6020 Description: 6020 MET ICPMS Client: SCS Engineers Date: September 23, 2019 General Information: 3 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3010 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 14 (/eAnaIYticaI www.pace&abs.com ANALYTICAL RESULTS Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Sample: MW-31 Lab ID: 35498005001 Collected: 09/16/19 11:32 Received: 09/16/19 17:35 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3010 Iron 3120 ug/L 10.0 6.9 1 09/17/19 07:53 09/23/19 14:42 7439-89-6 REPORT OF LABORATORY ANALYSIS Date: 09/23/2019 04:56 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 14 aceAnalytical www.pace&abs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 ANALYTICAL RESULTS Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Sample: MW-44 Lab ID: 35498005002 Collected: 09/16/19 12:45 Received: 09/16/19 17:35 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3010 Iron 836 ug/L 10.0 6.9 1 09/17/19 07:53 09/23/19 14:45 7439-89-6 REPORT OF LABORATORY ANALYSIS Date: 09/23/2019 04:56 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 14 aceAnalytical www.pace&abs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 ANALYTICAL RESULTS Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Sample: SCS-MW-1 Lab ID: 35498005003 Collected: 09/16/19 14:10 Received: 09/16/19 17:35 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3010 Iron 3960 ug/L 10.0 6.9 1 09/17/19 07:53 09/23/19 14:48 7439-89-6 REPORT OF LABORATORY ANALYSIS Date: 09/23/2019 04:56 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 14 aceAnalytical www.pace&abs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 QUALITY CONTROL DATA Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 QC Batch: 570724 Analysis Method: EPA 6020 QC Batch Method: EPA 3010 Analysis Description: 6020 MET Associated Lab Samples: 35498005001, 35498005002, 35498005003 METHOD BLANK: 3101541 Matrix: Water Associated Lab Samples: 35498005001, 35498005002, 35498005003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Iron ug/L 6.9 U 10.0 6.9 09/23/19 14:24 LABORATORY CONTROL SAMPLE: 3101542 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Iron ug/L 500 512 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3101543 3101544 MS MSD 35497980001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Iron ug/L 83.5 500 500 599 617 103 107 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS Date: 09/23/2019 04:56 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 14 (/eAnaIYticaI www.pace&abs.cam QUALIFIERS Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL- Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS U Compound was analyzed for but not detected. REPORT OF LABORATORY ANALYSIS Date: 09/23/2019 04:56 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 14 (/eAnaIYticaI www.pace&abs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 35498005001 MW-31 EPA 3010 570724 EPA 6020 570824 35498005002 MW-44 EPA 3010 570724 EPA 6020 570824 35498005003 SCS-MW-1 EPA 3010 570724 EPA 6020 570824 REPORT OF LABORATORY ANALYSIS Date: 09/23/2019 04:56 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 14 PaceAna!i-Mica! Section A Required Client Information WO#:35498005 llllllllllllllllllllll ;HAIN-OF-CUSTODY I Analytical Request Document he Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section C Invoice Information: Page : Of Cer;ip` ny SCS EnGinc en Address Address 9SD0 S Deland Blvd Copy To Company Nam. Miami FL 33156 Andress Regulator/ Agency Email anrelsen@scseng1necrs_com It Purchase Order # Face Quote Phe^05+-0?.3 ;'S z Pro}eci Name Mele -ec Gulf Ccurn� - Pre=Irr„ Manager chrislina reschke(a?pecelabe com, }Pi;. State 1 Location Nequr, stco De 5)ele Project # �� ��-�. Z - <. !' . iEu k FL • • Requested Analysis Filtered !YIN) ^^ MATRIX CODE MATRIX CODE {see valid codes to left) SAMPLE TYPE (G=ORA.2 C=COMP) COLLECTED SAMPLE TEMP AT COLLECTION Preservatives % Dunking Wahl DW Waist WT Mute Water WN Product P SAMPLE ID SnWSokd SL oil ex G^ I G START END H2SO4 Na2S203 Analyses Test �^ Residual Chlorine (Y!N) One Character per box. Wrpn WP Air AR (A-Z, 0-9 1 • -) Other aT Sample Ids must be unique Twee TS DATE TIME DATE TIME ' O` L)111 0 a m = ro _ z x z °c cos iris 0 M\µ' 1r a CP �p l _ C� 2 1\1\ ` L! W L ..1 1 la akA 5 }(- 'A 3 Sc S — NAAJ — 1 4� L ` IN' } ‘o X - 4 5 I 8 � , 10 11 12 ,7 r", ADDITIONAL COMMENTS RELINQUISHED DY r AF LIATION DATE TIME CCEP FFI ATIQIII D TE TIME SAMPLE CONDITIONS ti, eJ,. 1 1 ( (6 11 m �� (VD w SAMPLER NAME AND SIGNATURE a m °i } a `m -� .� (m c� } a rn PRINT Name of SAMPLER: i yy ,.� U Lt.� fj � 6. -v. ' U a SIGNATURE or SAMPLERjf'j � 1.4 (A DATE Signed: I f IT u2i ace Analytical Flw:4;, L:rLur:>r��y Upon Receipt Form w4#:35498005 Project* P11: CTR Due Date: 09/24/19 Project Manager: CLIENT: 35-LENCOR Client: Thermometer Used: Date: % �/ Time: C' State of Origin: Cooler #1 Temp.°C // L-(Visual) C _(Correction Factor) / <r +. (Actual) Cooler #2 Temp.°C (Visual) (Correction Factor) (Actual) Cooler #3 Temp.°C (Visual) - (Correction Factor) (Actual) Cooler #4 Temp.°C (Visual) (Correction Factor) (Actual) Cooler #5 Temp.°C (Visual) (Correction Factor) (Actual) Cooler #6 Temp.°C - (Visual) (Correction Factor) (Actual) Courier. ❑ Fed Ex ❑ UPS USPS 0 Client l-I Commerciai El Pace Issuing Authonty: Pace Florida Quality office Date and Initials of • Examining contents:- 1' Label: Deliver: pH: ❑ For WV projects, ail containers verified to s6 °C ❑ Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun • Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun Other Shipping Method: ❑ First Ovemight 0 Priority Overnight 0 Standard Overnight ❑ Ground 0 International Priority 0 Other— -_ -. . Billing: 0 Recipient 0 Sender ❑ Third Party ❑ Credit Card 0 Unknown Tracking # Custody Seal on CoolerlBox Present ❑Yes Pt Seals intact ❑Yes ❑ No iceG e) Blue Dry None Packing Material: ❑Bubble Wrap ❑ Bubble Bags one ❑ Other �� Samples shorted to lab (if Yes, complete) Shorted Date: Shorted Time: Comments: : Chain of Custody Present , IYes LI No ON/A Chain ofCustody Filled "Out -�-- —"--- — — es" -CJ No ❑Nll�— - Relinquished Signature & Sampler Name COC l['ges 0 No ON/A Samples Arrived within Hold Time I es 0 No ON/A Rush TAT requested on COC DYes ko/No ON/A Sufficient Volume ,a<fes ❑ No ON/A Correct Containers Used ,0Yes 0 No ON/A - Containers Intact ZYes 0 No ON/A Sample Labels match COC (sample IDs & dateltime of collection) itSYes © No ❑NtA All containers needing acid/base preservation have been checked. E6es 0 No ON/A All Containers needing preservation are found to be in compliance with EPA recommendation: es 0 No ON/A . Excepticrs; Vn& GplWonn: TOC, O&G, Carbemates Preservation Information: Preservative: Lot #frrace#: Date: Time: Initials: .. __ . _ : - .. . , .. Headspace in VOA Vials? ( >6mm): ❑Yes 0 No 1AJA Trip Blank Present: ❑Yes 0 No I24/A Client Notification/ Resolution: Person Contacted: Comments/ Resolution (use back for additional comments): Date/Time: Project Manager Review: Date: Page 14 of 14 aceAnalyticar wwwpacefabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 September 23, 2019 Brittney Odom SCS Engineers 1900 NW Corporate Blvd Suite E300 Boca Raton, FL 33431 RE: Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Dear Brittney Odom: Enclosed are the analytical results for sample(s) received by the laboratory on September 16, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Kole Holman, SCS Engineers Sanaul Khan, SCS Engineers Troy Schick, SCS Engineers David Taylor, SCS Engineers REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 14 (/eAnaIYticaI www.pace&abs.com CERTIFICATIONS Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Ormond Beach Certification Ds 8 East Tower Circle, Ormond Beach, FL 32174 Alaska DEC- CS/UST/LUST Alabama Certification #: 41320 Arizona Certification# AZ0819 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 14 (/eAnaIYticaI www.pace&abs.com SAMPLE SUMMARY Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35498005001 MW-31 Water 09/16/19 11:32 09/16/19 17:35 35498005002 MW-44 Water 09/16/19 12:45 09/16/19 17:35 35498005003 SCS-MW-1 Water 09/16/19 14:10 09/16/19 17:35 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 14 (/eAnaIYticaI www.pace&abs.com SAMPLE ANALYTE COUNT Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35498005001 MW-31 EPA 6020 AMS 1 PASI-O 35498005002 MW-44 EPA 6020 AMS 1 PASI-O 35498005003 SCS-MW-1 EPA 6020 AMS 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 14 ceAnalytical www.pace&abs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 SUMMARY OF DETECTION Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35498005001 MW-31 EPA 6020 Iron 3120 ug/L 10.0 09/23/19 14:42 35498005002 MW-44 EPA 6020 Iron 836 ug/L 10.0 09/23/19 14:45 35498005003 SCS-MW-1 EPA 6020 Iron 3960 ug/L 10.0 09/23/19 14:48 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 14 ceAnalytical www.pace&abs.cam 5 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 PROJECT NARRATIVE Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Method: EPA 6020 Description: 6020 MET ICPMS Client: SCS Engineers Date: September 23, 2019 General Information: 3 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3010 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 14 (/eAnaIYticaI www.pace&abs.com ANALYTICAL RESULTS Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Sample: MW-31 Lab ID: 35498005001 Collected: 09/16/19 11:32 Received: 09/16/19 17:35 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3010 Iron 3120 ug/L 10.0 6.9 1 09/17/19 07:53 09/23/19 14:42 7439-89-6 REPORT OF LABORATORY ANALYSIS Date: 09/23/2019 04:56 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 14 aceAnalytical www.pace&abs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 ANALYTICAL RESULTS Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Sample: MW-44 Lab ID: 35498005002 Collected: 09/16/19 12:45 Received: 09/16/19 17:35 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3010 Iron 836 ug/L 10.0 6.9 1 09/17/19 07:53 09/23/19 14:45 7439-89-6 REPORT OF LABORATORY ANALYSIS Date: 09/23/2019 04:56 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 14 aceAnalytical www.pace&abs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 ANALYTICAL RESULTS Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Sample: SCS-MW-1 Lab ID: 35498005003 Collected: 09/16/19 14:10 Received: 09/16/19 17:35 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3010 Iron 3960 ug/L 10.0 6.9 1 09/17/19 07:53 09/23/19 14:48 7439-89-6 REPORT OF LABORATORY ANALYSIS Date: 09/23/2019 04:56 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 14 aceAnalytical www.pace&abs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 QUALITY CONTROL DATA Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 QC Batch: 570724 Analysis Method: EPA 6020 QC Batch Method: EPA 3010 Analysis Description: 6020 MET Associated Lab Samples: 35498005001, 35498005002, 35498005003 METHOD BLANK: 3101541 Matrix: Water Associated Lab Samples: 35498005001, 35498005002, 35498005003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Iron ug/L 6.9 U 10.0 6.9 09/23/19 14:24 LABORATORY CONTROL SAMPLE: 3101542 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Iron ug/L 500 512 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3101543 3101544 MS MSD 35497980001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Iron ug/L 83.5 500 500 599 617 103 107 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS Date: 09/23/2019 04:56 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 14 (/eAnaIYticaI www.pace&abs.cam QUALIFIERS Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL- Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS U Compound was analyzed for but not detected. REPORT OF LABORATORY ANALYSIS Date: 09/23/2019 04:56 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 14 (/eAnaIYticaI www.pace&abs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 09219075.21/Melreese Golf Cour Pace Project No.: 35498005 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 35498005001 MW-31 EPA 3010 570724 EPA 6020 570824 35498005002 MW-44 EPA 3010 570724 EPA 6020 570824 35498005003 SCS-MW-1 EPA 3010 570724 EPA 6020 570824 REPORT OF LABORATORY ANALYSIS Date: 09/23/2019 04:56 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 14 PaceAna!i-Mica! Section A Required Client Information WO#:35498005 llllllllllllllllllllll ;HAIN-OF-CUSTODY I Analytical Request Document he Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section C Invoice Information: Page : Of Cer;ip` ny SCS EnGinc en Address Address 9SD0 S Deland Blvd Copy To Company Nam. Miami FL 33156 Andress Regulator/ Agency Email anrelsen@scseng1necrs_com It Purchase Order # Face Quote Phe^05+-0?.3 ;'S z Pro}eci Name Mele -ec Gulf Ccurn� - Pre=Irr„ Manager chrislina reschke(a?pecelabe com, }Pi;. State 1 Location Nequr, stco De 5)ele Project # �� ��-�. Z - <. !' . iEu k FL • • Requested Analysis Filtered !YIN) ^^ MATRIX CODE MATRIX CODE {see valid codes to left) SAMPLE TYPE (G=ORA.2 C=COMP) COLLECTED SAMPLE TEMP AT COLLECTION Preservatives % Dunking Wahl DW Waist WT Mute Water WN Product P SAMPLE ID SnWSokd SL oil ex G^ I G START END H2SO4 Na2S203 Analyses Test �^ Residual Chlorine (Y!N) One Character per box. Wrpn WP Air AR (A-Z, 0-9 1 • -) Other aT Sample Ids must be unique Twee TS DATE TIME DATE TIME ' O` L)111 0 a m = ro _ z x z °c cos iris 0 M\µ' 1r a CP �p l _ C� 2 1\1\ ` L! W L ..1 1 la akA 5 }(- 'A 3 Sc S — NAAJ — 1 4� L ` IN' } ‘o X - 4 5 I 8 � , 10 11 12 ,7 r", ADDITIONAL COMMENTS RELINQUISHED DY r AF LIATION DATE TIME CCEP FFI ATIQIII D TE TIME SAMPLE CONDITIONS ti, eJ,. 1 1 ( (6 11 m �� (VD w SAMPLER NAME AND SIGNATURE a m °i } a `m -� .� (m c� } a rn PRINT Name of SAMPLER: i yy ,.� U Lt.� fj � 6. -v. ' U a SIGNATURE or SAMPLERjf'j � 1.4 (A DATE Signed: I f IT u2i ace Analytical Flw:4;, L:rLur:>r��y Upon Receipt Form w4#:35498005 Project* P11: CTR Due Date: 09/24/19 Project Manager: CLIENT: 35-LENCOR Client: Thermometer Used: Date: % �/ Time: C' State of Origin: Cooler #1 Temp.°C // L-(Visual) C _(Correction Factor) / <r +. (Actual) Cooler #2 Temp.°C (Visual) (Correction Factor) (Actual) Cooler #3 Temp.°C (Visual) - (Correction Factor) (Actual) Cooler #4 Temp.°C (Visual) (Correction Factor) (Actual) Cooler #5 Temp.°C (Visual) (Correction Factor) (Actual) Cooler #6 Temp.°C - (Visual) (Correction Factor) (Actual) Courier. ❑ Fed Ex ❑ UPS USPS 0 Client l-I Commerciai El Pace Issuing Authonty: Pace Florida Quality office Date and Initials of • Examining contents:- 1' Label: Deliver: pH: ❑ For WV projects, ail containers verified to s6 °C ❑ Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun • Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun Other Shipping Method: ❑ First Ovemight 0 Priority Overnight 0 Standard Overnight ❑ Ground 0 International Priority 0 Other— -_ -. . Billing: 0 Recipient 0 Sender ❑ Third Party ❑ Credit Card 0 Unknown Tracking # Custody Seal on CoolerlBox Present ❑Yes Pt Seals intact ❑Yes ❑ No iceG e) Blue Dry None Packing Material: ❑Bubble Wrap ❑ Bubble Bags one ❑ Other �� Samples shorted to lab (if Yes, complete) Shorted Date: Shorted Time: Comments: : Chain of Custody Present , IYes LI No ON/A Chain ofCustody Filled "Out -�-- —"--- — — es" -CJ No ❑Nll�— - Relinquished Signature & Sampler Name COC l['ges 0 No ON/A Samples Arrived within Hold Time I es 0 No ON/A Rush TAT requested on COC DYes ko/No ON/A Sufficient Volume ,a<fes ❑ No ON/A Correct Containers Used ,0Yes 0 No ON/A - Containers Intact ZYes 0 No ON/A Sample Labels match COC (sample IDs & dateltime of collection) itSYes © No ❑NtA All containers needing acid/base preservation have been checked. E6es 0 No ON/A All Containers needing preservation are found to be in compliance with EPA recommendation: es 0 No ON/A . Excepticrs; Vn& GplWonn: TOC, O&G, Carbemates Preservation Information: Preservative: Lot #frrace#: Date: Time: Initials: .. __ . _ : - .. . , .. Headspace in VOA Vials? ( >6mm): ❑Yes 0 No 1AJA Trip Blank Present: ❑Yes 0 No I24/A Client Notification/ Resolution: Person Contacted: Comments/ Resolution (use back for additional comments): Date/Time: Project Manager Review: Date: Page 14 of 14 aceAnalyticar wwwpacefabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 September 23, 2019 Brittney Odom SCS Engineers 1900 NW Corporate Blvd Suite E300 Boca Raton, FL 33431 RE: Project: 09219075.21/Melrese Golf Cours-Revised Report Pace Project No.: 35498147 Dear Brittney Odom: Enclosed are the analytical results for sample(s) received by the laboratory on September 17, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Revision: Iron has been added to MW-2 If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Kole Holman, SCS Engineers Sanaul Khan, SCS Engineers Troy Schick, SCS Engineers David Taylor, SCS Engineers REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 13 (/eAnaIYticaI www.pace&abs.com CERTIFICATIONS Project: 09219075.21/Melrese Golf Cours-Revised Report Pace Project No.: 35498147 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Ormond Beach Certification Ds 8 East Tower Circle, Ormond Beach, FL 32174 Alaska DEC- CS/UST/LUST Alabama Certification #: 41320 Arizona Certification# AZ0819 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 13 (/eAnaIYticaI www.pace&abs.com SAMPLE SUMMARY Project: 09219075.21/Melrese Golf Cours-Revised Report Pace Project No.: 35498147 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35498147001 MW-10 Water 09/16/19 15:32 09/17/19 17:05 35498147002 MW-2 Water 09/16/19 16:34 09/17/19 17:05 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 13 ceAnalytical www.pace&abs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 SAMPLE ANALYTE COUNT Project: 09219075.21/Melrese Golf Cours-Revised Report Pace Project No.: 35498147 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35498147001 MW-10 35498147002 MW-2 EPA 6020 EPA 6020 REPORT OF LABORATORY ANALYSIS KPP 1 PASI-O KPP 2 PASI-O This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 13 ceAnalytical www.pace&abs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 SUMMARY OF DETECTION Project: 09219075.21/Melrese Golf Cours-Revised Report Pace Project No.: 35498147 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35498147001 MW-10 EPA 6020 Iron 62.0 ug/L 35498147002 MW-2 EPA 6020 Arsenic 13.5 ug/L EPA 6020 Iron 1030 ug/L REPORT OF LABORATORY ANALYSIS 10.0 09/22/19 21:12 1.0 09/22/19 21:14 10.0 09/22/19 21:14 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 13 ceAnalytical www.pace&abs.cam 5 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 PROJECT NARRATIVE Project: 09219075.21/Melrese Golf Cours-Revised Report Pace Project No.: 35498147 Method: EPA 6020 Description: 6020 MET ICPMS Client: SCS Engineers Date: September 23, 2019 General Information: 2 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3010 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 13 (/eAnaIYticaI www.pace&abs.com ANALYTICAL RESULTS Project: 09219075.21/Melrese Golf Cours-Revised Report Pace Project No.: 35498147 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Sample: MW-10 Lab ID: 35498147001 Collected: 09/16/19 15:32 Received: 09/17/19 17:05 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3010 Iron 62.0 ug/L 10.0 6.9 1 09/19/19 05:48 09/22/19 21:12 7439-89-6 REPORT OF LABORATORY ANALYSIS Date: 09/23/2019 12:41 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 13 (/eAnaIYticaI www.pace&abs.com ANALYTICAL RESULTS Project: 09219075.21/Melrese Golf Cours-Revised Report Pace Project No.: 35498147 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Sample: MW-2 Lab ID: 35498147002 Collected: 09/16/19 16:34 Received: 09/17/19 17:05 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3010 Arsenic 13.5 ug/L 1.0 0.50 1 09/19/19 05:48 09/22/19 21:14 7440-38-2 Iron 1030 ug/L 10.0 6.9 1 09/19/19 05:48 09/22/19 21:14 7439-89-6 REPORT OF LABORATORY ANALYSIS Date: 09/23/2019 12:41 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 13 (/eAnaIYticaI www.pace&abs.com QUALITY CONTROL DATA Project: 09219075.21/Melrese Golf Cours-Revised Report Pace Project No.: 35498147 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 QC Batch: 571418 Analysis Method: EPA 6020 QC Batch Method: EPA 3010 Analysis Description: 6020 MET Associated Lab Samples: 35498147001, 35498147002 METHOD BLANK: 3105671 Matrix: Water Associated Lab Samples: 35498147001, 35498147002 Parameter Blank Reporting Units Result Limit MDL Analyzed Qualifiers Arsenic ug/L 0.50 U 1.0 Iron ug/L 6.9 U 10.0 0.50 09/22/19 21:06 6.9 09/22/19 21:06 LABORATORY CONTROL SAMPLE: 3105672 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic ug/L 50 47.2 94 80-120 Iron ug/L 500 493 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3105673 3105674 MS MSD 35498147001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L 13.9 50 50 62.0 62.2 96 97 75-125 0 20 Iron ug/L 62.0 500 500 563 573 100 102 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS Date: 09/23/2019 12:41 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 13 (/eAnaIYticaI www.pace&abs.cam QUALIFIERS Project: 09219075.21/Melrese Golf Cours-Revised Report Pace Project No.: 35498147 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL- Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS U Compound was analyzed for but not detected. REPORT OF LABORATORY ANALYSIS Date: 09/23/2019 12:41 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 13 ceAnalytical www.pace&abs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 09219075.21/Melrese Golf Cours-Revised Report Pace Project No.: 35498147 Lab ID Sample ID QC Batch Method Analytical QC Batch Analytical Method Batch 35498147001 MW-10 35498147002 MW-2 EPA 3010 571418 EPA 6020 571530 EPA 3010 571418 EPA 6020 571530 REPORT OF LABORATORY ANALYSIS Date: 09/23/2019 12:41 PM This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 13 Container Type Codes Pace Analytical. www.pacelabs.com Company Name: Address: 1 5 City: Attn: PO# State: 'iL.. Zip: ..g-S 1 Fax# email: &V\ q 4a Project S Cr+CflrLe •}- Phone: "Sc- SO�. 1.G itr,iJa,, or iie fr`a7�`jr)�_ Sample TRC pH Pres Codes rvarrle r v •C-1 i c - Sampler 1 Signature ww Lvr.,-,, t.--, • •--, . (��,,', 1 Circle One Event: Daily Weekly Monthly �tF- j , ° fluartely Semi -Annual Annual N/A amp IDg} Collect Date Collect Time Matrix Code* b m a 2 z Y o ` o u a) a _ u'u J rR 1- D. Erf to - y r . 1 PA ,.i - 1 `i `-' ( 2 f\A tiJ . 3 4 I 5 6 7 8 - 9 -I 1ft Chef.'TAT REOUESTIRre±r rea,AFl}I ddi RU$H Y N Item. 2 -e ce3 m N4 Today 1D 2D 3D -ID sD -- Y Sort Hold N_ to w c E ttS d WO## :35498147 IJIli(giiiiuuiiuu u ❑ ❑ LAB ANALYSIS Li I ❑ ❑ 1 n n ❑ ❑ Crcle QAIQC Report Level 2 3 4 CLP AFCEE C APP Other J n EDD (Fees May Apply) ADaPT SEDD ERPIMS TSV CSV Other Li 11 Li u u n 11 u u Page of• # of Containers SIze type II ri 11 u fI LL Li ❑ R4linquished by lompano Lab 954-582-4300 Affiliation Date Time ReceiGed&tiy„,- Affiliatiron 11 II n II 1I II Li U II n n Il ozP AV Amber Vial ES Encore Sampler CV Clear Vial PPV Proproserved vial F Plastic PL C Plastic container AL Amber Lifer PL J Plastic Jar CL Clear Liter z Tploc bag AP Amber Plastic TI3 Todlnr bag AG Amber Glass WP Whirl pak SJ Sail Jar G G2Aon.lug Other TC Terra -core PPV Prepreserved vial Size(s): 2oz, 4az, 8oz, 15oz, 32oz or 1L, other 40m1 500m1 250111 125 ml Example: 4ozP . 4oz Plastic. BozSJ= Bez Soll Jar Matrix Codes SD Solid Waste OL Oil GW Ground Wafer SL Sludge EFF Effluent SO Soll Sediment AFW Analylo Free H2O AO Aqueous WW Waste Water NA Nonaqueous DW Drinking Water PE Petroleum SW Sudoce Water 0 Other s�orr ML Misc, Liquid Preservative Type Codes A. None. E. HCL I. Ice -B. HNO3 F. McOH J. MCAA C. H2SO4 G. N22S203 K. zn Acewto D. NaOH H. NaHSO4 O. Other Required Stale COC Condition _ Certification OK Incomplete fi ate/ FL GA SC NC N PA LA TX 1L — /g/ Time REMARKS Coolers #'s - Temp aC J 5� 1= 2 3� 4____ rNon -Conformance Found? Samples INTACT upon arrival? Received on Wal Ice? 1. — — , — — -- Proper Preservatives Indicated? Received within holding time? Cuslody seals Inracr? Volatiles reed without headspace? —. — — — -- Proper Containers Used? — — Revision: F•ALL•C•007- Rev.GO C.O.C. Serial # 15 0 8 7 6 PP�ice Analytical L 140 • 35498 Document Name Document Revised Se-:cie Condition Upon Receipt Form May 30. 2018 cur j nent No Issuing Authority le n 7 - v 13 Pace Florida QualityOffice 47 �M: Cry Proje CL____71M1111.11=mmi NCr�R Due Date: 09/24/19 Project Mana... Client: Thermometer Used State of Origin. Cooler #1 Temp.°C} Cooler #2 Temp.°C Cooler#3 Temp.°C Cooler #4 Temp.°C Cooler #5 Temp,°C Cooler #6 Temp.°C Courier.— Fed Ex Shipping Method: 7. Firs; T Other Date Date and Initials of person: Examining contents: X_S)) Label: Deliver: ! {'—p H: Time t 1 Initials d74 0 FC7 conielners verifies to (Visual) 0 -O (Correction Factor) t{ i (Actual) (Visual) (Correction Factor) (Actual) (Visual) (Correction Factor) (Actual) (Visual) (Correction Factor) (Actual) (Visual) (Correction Factor) (Actual) (Visual) (Correction Factor) (Actual) UPS a°LISPS — Client LL-- Commercial Pace Overnight Priority Overnight 7. Standard Overnight Billing: ;: Recipient Tracking # Sender L Samples on ice, cooling process has begun L Samples on ice, cooling process has begun L Samples cn Ice, cooling process has begun. E Samples on ice, Cooling process has begun Samples on ice, cooling process has begun. E Samples on ice, cooling process has begun E Other __ Ground T. International Priority Third Party Credit Card Unknown Custody Seal on Cooler/Box Present: LIYes No Seals intact: —' Yes No Packing Material: t;Bubble Wrap Cobble Bags L None Other ! J6tC1) Samples shorted to lab (lf Yes. complete) Shorted Date. Comments: Ice: ) Blue Dry None Shorted Time: Qty. Chain of Custody Present Yes ;E. No. ,—N;A Chain of Custody Filled Out Yes :- No _NIA Relinquished Signature & Sampler Name COC No 1N/A Samples Arrived within Hold Time =1'es No _NIA Rush TAT requested on COC _Yes No .N/A Sufficient Volume :r Cs v: No =NIA Correct Containers Used es -- No -NIA Containers intact Sample Labels match COC (sample IDs & date/time of collection) ▪ Yes = No LE_N/A All containers needing acidrbase preservation have been checked Ali Containers needing preservation are found to be in compliance with EPA recommendation s = No LENIA F'?.es 7. No EN/A -Yes ._ No E N/A €7Cceptions VU.A C:oIi orm TOC, O&G, Carbarnates Headspace in VOA Vials? ( >6mm): Trip Blank Present: Client Notification/ Resolution: Person Contacted_ Preservation Information Preservative Lot #!Trace # Date - Yes No -/A No -N/A Initials Date/Time: sine Comments/Resolution {use back for additional comments). Project Manager Review Date Page 13 of 13