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HomeMy WebLinkAboutBack-Up Documents - Environmental Report Part 1EE&G ENVIRONMENTAL SERVICES. LLC SITE REHABILIATION PLAN OF MIAMI FREEDOM PARK (INTERNATIONAL LINKS MELREESE COUNTRY CLUB) 1802 NW 37TH AVENUE MIAMI, MIAMI-DADE COUNTY, FLORIDA 33125 FOLIO NO: 30-3129-000-0160, 30-3129-000-0050, 01-3132-000-0080, and 01-3132-000-0090 (partial) DERM Facility ID: AW-284/HWR-594 Prepared For: Miami -Dade County Department of Regulatory and Economic Resources Division of Environmental Resources Management (DERM) 701 Northwest 1st Court, Suite 400 Miami, FL 33136-3912 Prepared on Behalf Of: Miami Freedom Park, LLC c/o Greenberg Traurig, P.A. 333 Southeast 2"d Avenue, Suite 4400 Miami, Florida 33131 Prepared by: EE&G Environmental Services, LLC 5751 Miami Lakes Drive Miami Lakes, Florida 33014 (305) 374-8300 Report Date: August 14, 2019 Project No: 2018-3057 EE&G: Site Rehabilitation Plan August 2019 TABLE OF CONTENTS Section Page 1.0 — INTRODUCTION 1 2.0 — REGIONAL HYDROGEOLOGY 2 3.0 — REGULATORY & HISTORICAL REVIEW 3 4.0 — SOIL ASSESSMENT METHODOLOGY & FINDINGS 6 5.0 — GROUNDWATER ASSESSMENT METHODOLOGY & FINDINGS 11 6.0 — SOIL -VAPOR FIELD SCREENING METHODOLOGY & FINDINGS 14 7.0 — RECOMMENDED SITE REHABILITATION STRATEGY 15 8.0 —PROFESSIONAL CERTIFICATION 16 FIGURES 1 Topographic Map 2 2016 Aerial Photograph 3 Site Layout & Sampling Location Map 4 Soil Sampling Location Map 5 Inferred Extent of Buried Debris Map 6 OVA Results Map 7 Soil Results Map (Metals, PAHs, & Dioxin/Furan) 8 Expanded Soil Results Map (Maintenance Area) 9 Monitoring Well Location Map 10 Groundwater Results Map (Metals) 11 Groundwater Results Map (Other Parameters) 12 Groundwater Results Map (Iron) 13 Groundwater Results Map (Arsenic) 14 Groundwater Results Map (Ammonia) 15 Groundwater Flow Map 16 Shallow Monitoring Well Construction Detail 17 Vapor Well Location and Results Map Miami Freedom Park, Miami, FL I EE&G Project: 2018-3057 EE&G: Site Rehabilitation Plan August 2019 TABLES 1 Lithologic Logs 2 OVA/FID Field Screening Results 3 TE Soil Analytical Results 4 TE Benzo(a)pyrene Conversion Tables 5 TE Soil Dioxin/Furan Results 6 SB Soil Analytical Results (As, Ba, Pb) 7 SB Soil Analytical Results (Other COCs) 8 SB Benzo(a)pyrene Conversion Tables 9 SB Soil Dioxin/Furan Results 10 TCLP Results 11 Groundwater Analytical Results 12 Groundwater Dioxin/Furan Results 13 Well Detail and Groundwater Elevation Measurements 14 Vapor Well Field OVA Screening Results 15 Vapor Well 4-Gas Meter Field Screening Results APPENDICES A Property Appraiser Information B Historical and Regulatory Excerpts C Soil Results D Groundwater Results E Preliminary Design Documents Miami Freedom Park, Miami, FL II EE&G Project: 2018-3057 EE&G: Site Rehabilitation Plan August 2019 SECTION 1.0 INTRODUCTION EE&G Environmental Services, LLC (EE&G) was retained by Greenberg Traurig, P.A., on behalf of Miami Freedom Park, LLC, to prepare this Site Rehabilitation Plan (SRP) for the proposed Miami Freedom Park, which is the current location of the International Links Melreese Country Club. The approximately 160-acre golf course is located at 1802 Northwest 37th Avenue, Miami, Miami -Dade County, Florida 33125. The property was identified by the Miami - Dade County Property Appraiser with folio numbers: 30-3129-000-0160, 30-3129-000-0050, 01- 3132-000-0080 and 01-3132-000-0090 (partial — northern half). Miami -Dade County Property Appraiser information is provided in Appendix A. The property is developed with an 18-hole golf course, a driving range, a clubhouse and maintenance building, a small pump -house building and restroom building, and scattered man-made lakes. A Site Location/Topographic Map is provided as Figure 1. A recent aerial photograph is provided as Figure 2. A Site Layout Map is provided as Figure 3. The property is a known contaminated site, and is currently tracked by the Miami -Dade County Division of Environmental Resources Management (DERM) using AW-284, and shares a regulatory file with the southeastern adjoining Grapeland Heights Park (HWR-594). This SRP includes updated site assessment data collected as part of the recent environmental due diligence testing. Additionally, this SRP includes a conceptual site rehabilitation strategy to address the contamination using Engineering Control and Institutional Control tools to achieve a No Further Action with Conditions (NFAC) closure. Miami Freedom Park, Miami, FL 1 EE&G Project: 2018-3057 EE&G: Site Rehabilitation Plan August 2019 SECTION 2.0 AREA SETTING & HYDROGEOLOGIC SETTING The property is surrounded to the east by a residential neighborhood, to the southeast by Grapeland Heights Park, to the south by Interstate 836 (beyond which is a residential neighborhood, to the west NW 42nd Avenue (beyond which is a parking lot), to the northwest by Miami International Airport, and to the north by a canal (beyond which was a hotel and the MIA Intermodal Station). The regional hydrogeology was assessed by reviewing the U.S. Geological Survey Water Resources Investigations Report No. 90-4108, Hydrogeology of the Surficial Aquifer System, Dade County, Florida, dated 1991. The surficial aquifer system, in which an unconfined groundwater flow system exists, is comprised of sediments from surface grade to the top of a regionally persistent zone of low permeability called the intermediate confining unit. The aquifer system materials vary from clays to cavernous limestone in composition, with the upper, more permeable sediments grouped together as the Biscayne Aquifer. The surficial aquifer is approximately 310-feet deep beneath the Property, and consisted of the following formations: • The Pamlico Sand, quartz sand that included marine deposits from grade to approximately sea level. • The Miami Limestone Formation (formerly the Miami Oolite Formation), a limestone formation consisted of an oolitic and a bryozoan facies from sea level to a depth of approximately 10-feet BLS. • The Anastasia Formation, sand with sandstone concretions and marine shells, documented from approximately 10 to 40-feet BLS. • Key Largo Limestone, limestone with rock fragments and marine shells documented from approximately 40 to 60-feet BLS. • The Fort Thompson Formation comprised of a combination of sand, limestone, marine shells and some rock fragments documented from approximately 60 to 110-feet BLS. • The Tamiami Formation comprised of unconsolidated sandstone, porous limestone, and marine shell from approximately 110 to 230-feet BLS. • The Hawthorn Formation comprised of limestone and marine shells, which forms the base of the Biscayne Aquifer at approximately 230 to 310-feet BLS in the vicinity of the Property. The property was not located within a Maximum Drawdown Area of a Miami -Dade County Wellfield Protection area. Depth -to -groundwater was encountered on the average at 4 to 6-feet BLS, with higher/lower measurements as a result of the irregular topography. Miami Freedom Park, Miami, FL 2 EE&G Project: 2018-3057 EE&G: Site Rehabilitation Plan August 2019 SECTION 3.0 REGULATORY & HISTORICAL REVIEW The following is a summary of the site history and regulatory history based on a review of the Miami -Dade County DERM regulatory file. Appendix B contains excerpts of aerial photographs and previous assessment documentation. Based on historical research, the property appeared to be utilized as agricultural and/or pastoral land circa 1938. The 1951 aerial photograph documented evidence of widespread dumping of incineration ash and debris across the property. By the early-1960s the property was redeveloped with a golf course, and lakes were excavated. In the mid-1990s, the golf course was renovated, the topography re -worked, and lakes modified (current condition). The club house was added in the late-2000s. The following is a summary of the DERM regulatory file review: Melreese Golf Course (Ash Investigation) 1802 Northwest 37th Avenue DERM Facility ID: AW-284/HWR-594 • DERM has a combined regulatory file for the Melreese Golf Course (AQ-284) and the southeastern adjoining Grapeland Heights Park (HWR-594). • The presence of incineration debris was initially reported to DERM in March 2005 during an evaluation of the southeastern adjoining Grapeland Heights Park prior to its redevelopment to the current park configuration. Petro Hydro initially conducted the excavation of 12 test pits to assess for the presence of previously landfilled and improperly buried materials. Due to the initial western and northern boundary test results, the assessment expanded to the Melreese Golf Course. • A Limited Phase II ESA, prepared by Petro Hydro and dated October 26, 2005, was the first documentation of incineration debris on the Melreese Golf Course. A Supplemental Site Assessment Report (SSAR), dated September 14, 2006, was conducted to further delineate the impact of the incineration debris on the soil and groundwater at the Property. • Primary contaminants of concern in soils included arsenic, lead, dioxins/furans, and benzo(a)pyrene (BaP), which are common incineration ash compounds. • The presence of arsenic in the soils was also attributed to golf course application of agrochemicals. The SSAR proposed that the arsenic was consistent with other municipal golf courses that were part of a Miami -Dade County DERM study, and that the arsenic was primarily attributed to the legal application of herbicides by the golf course. — EE&G took the arsenic results from Petro Hydro's SSAR and calculated a 95% Upper Confidence Limit (UCL) of 15.11 mg/Kg for the 0 to 0.5-feet BLS interval. • DERM approved the SSAR in February 2007. DERM requested a Remedial Action Plan (RAP) to be submitted. DERM sent numerous letters requesting a response, and in Miami Freedom Park, Miami, FL 3 EE&G Project: 2018-3057 EE&G: Site Rehabilitation Plan August 2019 2013 sent an enforcement letter, and conducted a site inspection during which they identified areas of exposed debris. • In response, SCS Engineers were retained and provided the April 16, 2014 Corrective Action Plan and "temporary" ECP that would mitigate exposure of workers and golfers to solid waste/incineration debris. SCS indicated that the existing fairway/green/sand trap cover provided reasonable protection from exposure to the buried waste. In addition, three to four inches of mulch would be maintained in the landscaped/tree areas. Routine inspections, conducted by golf course maintenance staff would be required to ensure ECP measures were in place. • DERM approved the ECP on December 8, 2015, and has required that periodic inspections of the golf course areas be conducted and updated mulch -covering for the base of trees. • Surface water samples from lakes did not contain concentrations of arsenic or lead above the applicable surface water cleanup target levels. • Groundwater samples were analyzed for arsenic, barium, copper, lead, PAHs, Dioxins/Furans, and PCBs. None of the tested constituents were detected Groundwater Cleanup Target Level (GCTL), with the exception of arsenic. SCS Engineers conducted a groundwater Monitoring Only Plan (MOP) for five quarters. Results on Melresse were below GCTLs. Elevated arsenic was limited to one monitoring well (MW-31) located on the boundary with Grapeland Park, SCE proposed that source of the arsenic was the park and that the ongoing MOP for Grapeland Park should incorporate MW-31 into its sampling protocol. DERM's June 13, 2017 correspondence acknowledged that the groundwater monitoring plan had been discontinued at Melreese, as this was going to be combined with Grapeland for a join restrictive covenant. Monitoring continued at Grapeland. Grapeland Heights Site Development (Southeastern -Adjoining Property) 1550 Northwest 37th Avenue DERM Facility ID: AW-284/HWR-594 • DERM has a combined regulatory file for the Grapeland Heights Site Development and the northwestern adjoining Melreese Golf Course. • Elevated arsenic was detected at the northeastern boundary of Grapeland Park. The area was delineated and excavated. Groundwater monitoring has continued in that area, and elevated arsenic persists in MW-31. DERM issued a letter on March 20, 2019 requesting an additional quarterly groundwater monitoring event. In addition, DERM requested corrective action with regard to the existing engineering control installations. • The presence of incineration debris was initially reported to DERM in March 2005 during an evaluation of the southeastern adjoining Grapeland Park prior to its redevelopment to the current park configuration. As a result of the site assessment activities of the Grapeland Park site, Petro Hydro implemented a soil source removal, which resulted in the excavation and offsite disposal of 86,676 tons of soil contaminated with arsenic mixed with municipal incinerator ash. Miami Freedom Park, Miami, FL 4 EE&G Project: 2018-3057 EE&G: Site Rehabilitation Plan August 2019 Melreese Maintenance Facility FDEP Facility ID: 8622193; DERM Facility ID: UT-3576 FDEP Facility ID: 9602446 • FDEP tank registration records indicated that one 1,000-gallon fuel AST was removed from the Property in March 1995. No further regulatory or tank closure information was available for review. • A Discharge Notification Form (DNF) was submitted following the discovery of petroleum impacted groundwater during the excavation of one 1,000 gasoline UST on April 26, 1995 at the maintenance facility. Tank registration records indicated that the UST was installed in December 1983. In addition, two 500-gallon ASTs, containing gasoline and diesel fuel, were identified as "in service" in 1995. A Tank Closure Assessment Report (TCAR) was submitted to DERM on August 7, 1995. According to the TCAR, once the excavation was complete, no petroleum impacted soil was identified; however elevated levels of benzene and methyl tert-butyl ether (MTBE) were detected above the applicable guidelines in the groundwater referenced in Chapter 62-770, FAC. According to the DERM inspection report, one sample of groundwater from the bottom of the exaction was sampled for analysis. None of the tested constituents, including MTBE and benzene, were identified above the applicable guidelines referenced in Chapter 62- 770, FAC. No records of further testing was identified; however on October 12, 1995, DERM issued a letter approving the TCAR and released the facility from further site investigation. On September 30, 2008 DERM issued a letter to FDEP requesting that the 1995 discharge be deleted based upon the TCAR approval. FDEP responded on October 24, 2008 and issued a No Cleanup Required status to the facility. Delucca Enterprises DERM Facility ID: GDO-3835, IW5-15642 • Delucca Enterprises aka International Links of Miami operated the Melreese Golf Course maintenance facility under the IW5 permit #15642. The maintenance facility operated as an equipment washing and maintenance area as well as a storage facility for pesticides and fertilizers. DERM inspection records, dating back to 1995, indicated that the facility operated utilizing a septic tank system from approximately 1961 until present day. Routine sampling of the septic tank by DERM inspectors revealed evidence of industrial waste discharges. • URS performed an Environmental Site Assessment (ESA) in February 2004 following repeated inspections by DERM where evidence of hazardous waste discharges to the onsite septic tank system was identified. URS installed two soil borings and one monitoring well in the vicinity of the septic tank drainfield. Based upon the analytical data, URS determined that none of the tested constituents were above the applicable soil and/or groundwater guidelines. • Subsequent DERM compliance inspections in 2006, 2011, and 2016 have resulted in enforcement action and the subsequent required pump out of the septic tank. The most recent inspection, conducted in July 2018, identified no compliance violations. Miami Freedom Park, Miami, FL 5 EE&G Project: 2018-3057 EE&G: Site Rehabilitation Plan August 2019 SECTION 4.0 SOIL ASSESSMENT METHODOLOGY & FINDINGS EE&G documented the soil assessment activities that were conducted between March 11 and April 10, 2019. Due to schedule restrictions, access was granted only Monday — Wednesday each week. The soil sampling was done concurrently with NV5's geotechnical evaluation. EE&G provided the environmental oversight of the test excavations being conducted by NV5, and supplemented those findings with additional environmental soil borings. A site map showing the soil sampling locations is provided as Figure 4. Sampling was conducted in accordance with Florida Department of Environmental Protection's (FDEP's) Standard Operating Procedures (SOPs) as specified in Chapter 62-160 of the Florida Administrative Code (FAC). Selected soil samples were collected in laboratory supplied, pre -cleaned sample bottles, placed on ice and transported to National Environmental Laboratory Accreditation Conference (NELAC)-certified laboratories for analyses. Test Excavations (TEs) A total of 33 TEs were excavated using a mini -excavator, labeled TE-1 through TE-33. The TEs were approximately 2.5-feet wide by 6-feet long, and were excavated to depths of approximately 6 to 8 feet below land surface (BLS). The soils were inspected for evidence of incineration - related debris or other environmental concerns. EE&G selected total of 14 soil samples collected from sidewalls of the TEs for confirmation laboratory analyses. The samples were collection from various locations representing the site, and based on field observations. Seven soil samples were collected the surficial interval (0 to 1- ft, 1 to 2-ft, or 0 to 2-ft BLS). A majority of these surficial soil samples selected for analysis contained some evidence of incineration debris. However, three of the samples did not have evidence of debris and were selected to evaluate the golf course cap above the debris. Seven additional soil samples were collected from the underlying 2 to 4-ft BLS interval, a majority of which contained varying amounts of incineration debris. All 14 TE soil samples were analyzed for: • Total Arsenic, Barium and Lead by EPA Method 6010. Additionally, nine of the samples also were analyzed for the following list of expanded parameters: • Volatile Organic Compounds (VOCs) by EPA Method 8260 (only TE-1) • Polynuclear Aromatic Hydrocarbons (PAHs) by EPA Method 8270 • Total Petroleum Hydrocarbons (TPHs) by Method FL -PRO • Total Cadmium, Chromium, Mercury, Selenium and Silver by EPA Methods 6010/7470 • Dioxin/Furans by EPA Method 8290 Three additional TE soil samples collected during the final day of test pits also were analyzed for Dioxin/Furans by EPA Method 8290. Miami Freedom Park, Miami, FL 6 EE&G Project: 2018-3057 EE&G: Site Rehabilitation Plan August 2019 Soil Borings (SBs) EE&G oversaw the advancement of 38 soil borings using a truck -mounted direct -push technology (DPT) drilling rig, labeled SB-1 through SB-37 and SB-A. Soil boring locations were spread across the property to provide additional coverage and fill in gaps between the TE locations, and to focus on the maintenance area. Soil samples were collected from the 0 to 0.5- feet, 0.5 to 2-feet, and 2 to 4-feet BLS interval of 37 borings. Additionally, 21 deeper soil samples were collected from borings advanced on hills and areas with deeper water tables, representing the 4 to 6-feet and a few 6 to 8-feet BLS intervals. • A total of 132 soil samples were analyzed for: - Total Arsenic, Barium and Lead by EPA Method 6010. The soil sample collected from SB-9 (2 to 4-feet BLS), located in the maintenance area septic tank drainfield, was also analyzed for the following list of expanded parameters: • Volatile Organic Compounds (VOCs) by EPA Method 8260 • Organochlorine Pesticides by EPA Method 8081 • Organophosphorus Pesticides by EPA Method 8141 • Chlorinated Herbicides by EPA Method 8151 • Total Cadmium, Chromium, Mercury, Selenium and Silver by EPA Methods 6010/7470 Polynuclear Aromatic Hydrocarbons (PAHs) by EPA Method 8270 • Total Petroleum Hydrocarbons (TPHs) by Method FL -PRO • Dioxin/Furans by EPA Method 8290 The soil sample collected from SB-12 (6 to 7-feet BLS), located in the northern portion of the property adjacent to TE-2 (which contained heavy deep debris), also was analyzed for the following additional parameters: • Total Cadmium, Chromium, Mercury, Selenium and Silver by EPA Methods 6010/7470 • PAHs by EPA Method 8270 • TPHs by Method FL -PRO • Dioxin/Furans by EPA Method 8290 Three additional soil samples from SB-1, SB-3 and SB-4 also were analyzed for: • PAHs by EPA Method 8270 • Dioxin/Furans by EPA Method 8290 Miami Freedom Park, Miami, FL 7 EE&G Project: 2018-3057 EE&G: Site Rehabilitation Plan August 2019 Soil Findings A Site Map illustrating the inferred extent of incineration debris is provided as Figure 5. A summary of field observation is provided in Table 1. A majority of the sampling locations contain visible evidence of incineration debris and/or construction & demolition debris. While there are a few small areas where a soil boring or test excavation did not exhibit debris, they were located in areas that clearly were disturbed in the 1951 and/or 1961 aerial photographs. Therefore, the entire site is considered to be impacted with buried incineration ash debris, and some areas of historic deposition have since been reworked. The ash/debris thicknesses varied from as thin as 1-foot to as thick as 10-feet, with the average thickness of approximately 4-feet. The original deposition of debris was disrupted in the mid-1990s when the golf course was redesigned and the topography altered. Debris extended beneath the water table in several TEs. Debris was encountered in several surficial soils (0 to 2-feet BLS), and debris was found as shallow as 0.5-feet BLS in several locations. The debris included fragments of tile, metal, and glass, mixed with fine-grain sands, which often exhibited a rusty color. Intermittent wood fragments were encountered, along with concrete and other non-native materials, but no evidence of municipal garbage. Native limestone was encountered at a depth of approximately 5 to 8 feet BLS, often directly beneath the debris and sand layer. Soils from 13 soil borings were collected in 2-foot intervals and screened in the field using an Organic Vapor Analyzer (OVA), equipped with a Flame Ionization Detector (FID), to assess for petroleum -affected soils. The OVA/FID was utilized with and without a charcoal filter to assess for the presence of naturally occurring methane interferences. OVA/FID results generated from field-testing of soils were compared with the FDEP's "Guidelines for Assessment and Source Removal of Petroleum Contaminated Soils", dated May 1998, which identified an action level of 10 parts per million (ppm) for petroleum -affected soils collected above the water table. The OVA/FID results are summarized in Table 2 and depicted in Figure 6. • OVA results were detected above the 10-ppm action level in half of the borings. However, no evidence of petroleum odors was observed, except SB-A in the former UST area. It is likely that methane influenced the field readings. Two borings in particular exhibited higher OVA readings, which extinguished the meter, including SB-5 (central - northeastern portion) and SB-11 (northwestern corner). Soil analytical results were compared with the FDEP Contaminant Cleanup Target Levels, per Chapter 62-777, FAC, which regulates Soil Cleanup Target Levels (SCTLs) for residential -use direct exposure (SCTL-R), commercial -use direct exposure (SCTL-C) and leachability (SCTL-L) concerns. A copy of the soil analytical results, chain of custody form and Togs are provided in Appendix C. A summary of the Soil Analytical Results and Benzo(a)pyrene (BaP) Conversion Tables are provided in Tables 3 thru 10. A summary of the soil results maps are provided as Figure 7 (entire site) and Figure 8 (expanded maintenance area map). Miami Freedom Park, Miami, FL 8 EE&G Project: 2018-3057 EEG: Site Rehabilitation Plan August 2019 The following is a summary of the laboratory results for soil assessment (combined both SB and TE samples): Arsenic: 146 soil samples were analyzed for total arsenic. The concentrations ranged from below laboratory method detection limits (MDLs) to a high of 275 milligrams per kilogram (mg/Kg). 90% (131) of the soil samples contained arsenic at concentrations in excess of the 2.1 mg/Kg SCTL-R, and 46% (67)of the soil samples contained concentrations in excess of 12 mg/Kg SCTL-C. • Overall soils in the shallow interval (0 to 0.5-feet BLS) contained higher concentrations of arsenic. 62% of the soils in this shallow interval exceeded the 12 mg/Kg SCTL-C, as compared with the underlying layers, which drop to 36% in 0.5 to 2-feet BLS interval and 35% in the 2 to 4-feet BLS interval. EE&G ran the ProUCL 95% UCL calculator on the SB data and the results are below (see backup in Appendix C): 0 to 0.5-feet BLS — 95% UCL = 26.45 mg/Kg ✓ Note: When the one highest outlier value (156 mg/Kg) was removed from the dataset, the revised 95% UCL = 18.95 mg/Kg. ✓ The revised UCL was relatively similar to the 95% UCL EE&G calculated using the 50 soil samples from the initial 2005 SSAR, which was 15.11 mg/Kg. 0.5 to 2-feet BLS — 95% UCL = 15.5 mg/Kg (Note highest value — 275 mg/Kg — was removed, as program indicated the dataset was not compliant with the options) 2 to 4-feet BLS — 95% UCL = 27.28 mg/Kg 4 to 6-feet BLS — 95% UCL = 33.64 mg/Kg • The three highest arsenic samples (152, 156, and 275 mg/Kg) were selected and reanalyzed using the Toxicity Characteristic Leaching Procedure (TCLP), and results were all below the 5.0 milligram per liter (mg/L) hazardous waste criteria. Barium: 117 soil samples were analyzed for total barium. The concentrations ranged from below laboratory MDLs to a high of 4,000 mg/Kg. 21% (25) of the soil samples contained barium at concentrations in excess of the 120 mg/Kg SCTL-R. Results were below SCTL-C. Lead: 146 soil samples were analyzed for total lead. The concentrations ranged from below laboratory MDLs to a high of 7,650 mg/Kg. 20% (29) of the soil samples contained lead at concentrations in excess of the 400 mg/Kg SCTL-R, and 10% (15) of the soil samples contained concentrations in excess of 1,400 mg/Kg SCTL-C. • 12 soil samples with varying total lead concentrations ranging from 150 mg/Kg to 7,240 mg/Kg, were reanalyzed using the TCLP method. The results were all below the 5.0 mg/L hazardous waste criteria. Miami Freedom Park, Miami, FL 9 EE&G Project: 2018-3057 EE&G: Site Rehabilitation Plan August 2019 Dioxin/Furans: 17 soil samples were analyzed for dioxin/furans. The TEF concentrations ranged from 0.46 nanograms per kilogram (ng/Kg) to a high of 177.47 ng/Kg. Eight of the soil samples (47%) contained dioxin/furan TEF concentrations in excess of the 7.0 ng/Kg SCTL-R. Two soil samples also exceeded the 30 ng/Kg SCTL-C. The following three samples were the three highest detected: • The soil sample SB-1 (3.5 to 4.5-feet BLS), located in the southeastern portion, contained 75.87 ng/Kg. • The soil samples collected from TE-33, located in the central -eastern portion of the golf course north of the maintenance facility, contained 24.58 (0 to 2-feet BLS) and 177.47 ng/Kg (2 to 4-feet BLS). Other COCs: The other COCs tested were below SCTLs, with the exception of SB-9 (2 to 4- feet BLS), which contained 0.0050(1) mg/Kg of dieldrin, which slightly exceeded the 0.002 mg/Kg SCTL-L. The laboratory data, the reported results were qualified (I) as they were below the 0.022 mg/Kg Practical Quantitation Limit (PQL). Therefore, the laboratory was unable to report the actual dieldrin value with certainty. The results were below the 0.06 mg/Kg SCTL-R. Miami Freedom Park, Miami, FL 10 EE&G Project: 2018-3057 EE&G: Site Rehabilitation Plan August 2019 SECTION 5.0 GROUNDWATER ASSESSMENT METHODOLOGY & FINDINGS EE&G supervised the installation of monitoring wells, and collected groundwater samples from pre-existing and newly -installed monitoring wells to assess the groundwater quality. A site map illustrating the monitoring well location is provided as Figure 9. Sampling was conducted in accordance with FDEP's SOPs as specified in Chapter 62-160, FAC. Groundwater samples were collected in laboratory supplied, pre -cleaned sample bottles, placed on ice and transported to NELAC-certified laboratories for analyses. EE&G supervised the installation of five monitoring wells (designated as MW-1 through MW-5) on March 13, 2016. The monitoring wells MW-1, MW-2 and MW-3 were installed at the soil boring locations, SB-1, SB-3 and SB-6, respectively. The monitoring wells MW-4 and MW-5 were located on the southeastern portion of the Property. The monitoring well consisted of a 1.5-inch diameter, pre -pack screened interval (ranging from approximately 2.9 to 12.9-feet BLS to 3.2 to 13.2-feet BLS; screened across the water table interface, which was observed to range from approximately 4.6 to 6.7-feet BLS), and a sufficient solid PVC riser to reach the surface. The riser was sealed with a water -tight cap. The well construction and development logs and the groundwater sampling logs are provided in Appendix D. • EE&G initially collected groundwater samples from six existing monitoring wells on March 4, 2019, including MW-31, MW-39, MW-42, MW-44, SCS-MW-1, and SCS-MW-2. The groundwater samples were analyzed for the following parameters: VOCs by EPA Method 8260 PAHs by EPA Method 8270 TPHs by Method FL -PRO Organochlorine Pesticides by EPA Method 8081 Organophosphorus Pesticides by EPA Method 8141 Chlorinated Herbicides by EPA Method 8151 Total Aluminum, Arsenic, Barium Cadmium, Chromium, Iron, Lead, Mercury, Selenium and Silver by EPA Methods 6010/7470 Dioxin/Furans by EPA Method 8290 Ammonia (as N) by EPA Method 350.1 Nitrates/Nitrites by EPA Method 300.0 Based on these results, EE&G modified the remaining groundwater sampling parameters to focus on the primary COCs. • EE&G collected groundwater samples from a pre-existing monitoring well (labeled MW-9 from this report) on March 26, 2019, located in the maintenance area adjacent to the septic tank. These groundwater samples were analyzed for the following parameters: VOCs by EPA Method 8260 PAHs by EPA Method 8270 TPHs by Method FL -PRO Organochlorine Pesticides by EPA Method 8081 Organophosphorus Pesticides by EPA Method 8141 Chlorinated Herbicides by EPA Method 8151 Total Arsenic, Barium, Iron, Lead, by EPA Method 6010 Ammonia (as N) by EPA Method 350.1 Miami Freedom Park, Miami, FL 11 EE&G Project: 2018-3057 EE&G: Site Rehabilitation Plan August 2019 • EE&G found one additional pre-existing monitoring well, MW-38, which was sampled on March 26, 2019, and analyzed for the following parameters: - Total Arsenic, Barium, Iron, Lead, by EPA Method 6010 - Organochlorine Pesticides by EPA Method 8081 • A total of 11 new monitoring wells were installed, which were labeled MW-1 through 8, and MW-10 through 12. The wells were constructed of 1.5-inch diameter PVC casings, with 10-feet of pre -packed slotted well screen and sufficient solid riser to reach the surface. The wells were topped with water -tight caps within a protective manhole. The shallow monitoring wells were installed to depths of approximately 12 to 15 feet BLS, designed to intersect the groundwater table interface. EE&G collected groundwater samples from the 11 newly -installed monitoring wells on March 26 & 27 and April 8, 2019. Groundwater samples were analyzed for the following parameters: Total Arsenic Iron, Lead, by EPA Method 6010 (all 11 samples) Barium by EPA Method 6010 (only MW-1 through MW-8) Organochlorine Pesticides by EPA Method 8081 (only MW-1 through MW-8) Ammonia (as N) by EPA Method 350.1 (only MW-3, MW-4 and MW-5) Dioxins/Furans by EPA Method 8290 (only MW-3 and MW-4) • EE&G collected one direct -push groundwater grab sample, GW-1, from the former UST area north of the maintenance building, which was analyzed for the following parameters: - VOCs by EPA Method 8260 - PAHs by EPA Method 8270 - TPHs by Method FL -PRO • Based on the sampling results, EE&G resampled the following wells for specific COCs: - Dieldrin - MW-31, MW-44 and SCS-MW-1 on March 27, 2019 - Iron - MW-31, MW-44, SCS-MW-1 on March 27, 2019 - Iron - MW-2, MW-5, MW-9, and MW-38 on April 8, 2019 - Arsenic -MW-2 on April 8, 2019 Groundwater Findings Groundwater analytical results were compared with the FDEP Contaminant Cleanup Target Levels, per Chapter 62-777, FAC, which regulates the Groundwater Cleanup Target Levels (GCTLs, a.k.a. No Further Action criteria) and Natural Attenuation Default Source Concentrations (NADSCs; a.k.a., Monitoring Only criteria). Copies of the groundwater analytical results, sampling logs and chain of custody forms are provided in Appendix D. A summary of the groundwater laboratory results are provided in Tables 11 and 12. Well details and groundwater elevation measurements are provided in Table 13. A summary of the groundwater results map is provided in Figures 10 through 16. The following is a summary of the groundwater sampling results: Former UST Area (GW-1): A hydrocarbon odor was observed during the sampling of GW-1, located in the former UST area on the north side of the maintenance building. However, the VOCs, PAHs, and TPHs were below GCTLs. Miami Freedom Park, Miami, FL 12 EE&G Project: 2018-3057 EE&G: Site Rehabilitation Plan August 2019 Arsenic: Two of the 19 wells sampled contained total arsenic above the 10 microgram per liter (ug/L) GCTL: • MW-2 (southwestern corner) contained 13.2 ug/L of total arsenic. This well was resampled on April 8, 2019 and the result was 20.9 ug/L. • MW-31 (east -southeastern boundary sample — attributed to Grapeland Park) contained 92 ug/L of total arsenic. This well was resampled on April 8, 2019 and the result was 85.2 ug/L. This finding confirmed previous monitoring results on file with DERM. • None of the arsenic concentrations exceeded the 100 ug/L NADSC. Ammonia: Three of the 10 wells sampled contained ammonia above the 2.8 mg/L GCTL: • MW-5 (central -northeastern portion) contained 3.0 mg/L. • MW-9 (maintenance area) contained 9.3 mg/L. • MW-44 (northeastern portion) contained 3.5 mg/L. • None of the ammonia concentrations exceeded the 28 mg/L NADSC. Iron: 12 of the 19 wells sampled contained total iron above the 706 (ug/L Miami -Dade County Natural Background Level: • Four wells (SCS-MW-1, MW-5, MW-31, and MW-35) contained higher total iron concentrations ranging from 2,000 ug/L to 2,950 ug/L. These were isolated areas of exceedances, while a majority of the site concentrations were less than 1,000 ug/L. • None of the iron concentrations were confirmed to exceed the 3,000 ug/L NADSC. Dieldrin: Two of the 16 wells sampled contained low concentrations of dieldrin just above the 0.002 ug/L GCTL. The laboratory data, the reported results were qualified (I) as they were below the Practical Quantitation Limit (PQL). Therefore, the laboratory was unable to report the actual dieldrin value with certainty. These wells were resampled and dieldrin was below the GCTL. Other COCs: The other COCs tested were below laboratory reporting limits and below GCTLs, with the exception of three PAH constituents, which were not detected, but the laboratory MDLs could not meet the GCTLs. Considering no evidence of other petroleum compounds were detected, the MDLs were considered sufficient to demonstrate that a release has not occurred with respect to these compounds. Miami Freedom Park, Miami, FL 13 EE&G Project: 2018-3057 EE&G: Site Rehabilitation Plan August 2019 SECTION 6.0 SOIL GAS VAPOR SCREENING METHODOLOGY & FINDINGS EE&G documented the installation of eight soil -vapor wells, which were designated VW-1 through VW-8. Based on preliminary results, EE&G installed three additional confirmation vapor wells, VW-9 (adjacent to VW-2), VW-10 (adjacent to VW-7), and VW-11 (adjacent to VW-8). A site layout map illustrating the soil vapor well locations is provided as Figure 17. The 1-inch diameter vapor wells were installed to depths ranging from approximately 3-feet to 7-feet BLS (adjusted to terminate above the water table), and included approximately 2-feet to 5-feet of slotted screen and sufficient solid riser to reach the surface. The wells were fitted with gas sampling ports within a protective manhole. On April 2 and 9, 2019, EE&G screened the soil vapor in the field using an OVA/FID and a 4- gas meter. The vapor results are summarized in Tables 14 and 15. The following is a summary of the soil vapor assessment findings: • VW-2 was located in the southwestern corner of the property, and exhibited elevated readings above the 5% LEL for methane. The adjoining confirmation well VW-9 did not exhibit elevated readings above the LEL. • VW-7 was located in the northwestern corner of the property and exhibited elevated readings above the 5% Lower Explosivity Limit (LEL) for methane. The adjoining confirmation well VW-10 also exhibited elevated readings above the LEL. • The other wells did not exhibit elevated LEL readings. Miami Freedom Park, Miami, FL 14 EE&G Project: 2018-3057 EEG: Site Rehabilitation Plan August 2019 SECTION 7.0 RECOMMENDED ITE REHABILITATION STRATEGY The Miami Freedom Park Project will include a soccer stadium, commercial/retail development, and parking across the western/northwestern portion. The Project will also include the construction of a public park across the east -southeastern portion of the property. Miami Freedom Park, LLC and the City of Miami should meet with DERM to develop a site rehabilitation plan. The objective of the site rehabilitation plan would be to implement construction of the proposed Miami Freedom Park Project in an environmentally -safe manner and utilize the proposed development to create an Engineering Control cap across the entire site to obtain a No Further Action with Conditions (NFAC) closure. Miami Freedom Park, Miami, FL 15 EE&G Project: 2018-3057 EE&G: Site Rehabilitation Plan August 2019 SECTION 8.0 PROFESSIONAL CERTIFICATION I, Craig C. Clevenger, P.G. #1666, certify that I currently hold an active license in the state of Florida and am competent through education and experience to provide the geological consulting services documented in the aforementioned Site Rehabilitation Plan (SRP). I further certify that, in my professional judgment, this report meets the general requirements of Chapter 24-44, Code of Miami -Dade County, and Chapter 492, F.S., and was prepared by me with field sampling completed under my direction. Moreover, I certify that EE&G holds an active certificate of authorization #GB483 to provide geological services in the state of Florida. c„, Craig C. Clevenger, P.G. #1666 August 14, 2019 Date Miami Freedom Park, Miami, FL 16 EE&G Project: 2018-3057 EE&G: Site Rehabilitation Plan August 2019 FIGURES EEG Environmental Services, LLC o' �•� 1: ■ .. 1 .21 Proposed Miami Freedom Park (International Links Melreese Country Club) 1802 NW 37th Avenue, Miami, FL 33125 Project #: 2018-3057.JPH1 5751 Miami Lakes Drive Miami Lakes, Florida 33014 Phone (305)374-8300 Fax (305)374-9004 APPROXIMATE PROPERTY LOCATION SITE LAYOUT MAP (USGS TOPOGRAPHIC MAP ) FIGURE 1 om1Miami Lakes Drive Miami Lakes. F/mmaoao14 Phone (305)374-8300 Fax (305)374-9004 Environmental Services, LLC APPROXIMATE PROPERTY LOCATION Proposed Miami Freedom Park (international Links Me|re*oo Country Club) 18O2NYVS7mAvenue, Miami, FL3J12S 2019 AERIAL PHOTOGRAPH EF ENVIRONMENTAL SERVICES, LLC I PROPOSED MIAMI FREEDOM PARK 5751 MIAMI LAKES DRIVE (INTERNATIONAL LINKS MELREESE COUNTRY CLUB) MIAMI LAKES, FLORIDA 33014 1802 NW 37TH AVENUE (305) 374-8300 (305) 374-9004 FAX } MIAMI, MIAMI-D COUNTY, FLORIDA 33125 J SITE LAYOUT MAP 1 (Date: 06/1712019 Project # 2018-3057 Drawn by: JL J `Dwg. Scale: As LEGEND: ♦ = SOIL BORING ■ = TEST EXCAVATION 0' 300' SCALE: 1" = 300' SB-31 TE-3 ■ TE-4 ♦SB-17 TE-13116 TE-15[3 S B-30♦ TE-17 • SB-26 1E-10 10TE-12 TE-161111 SB-5 ■ TE-19 TE-20 ■ • TE-18 ♦SB-10 TE-21 ■♦ SB-27 TE-23 ■ ■ TE-24 SB-21 TE-28 ♦ ■ SB-29♦ ♦ SB-25 ■ TE-22 TE-27 TE-31 ■ SB-22 ♦SB-2 T E-29 ■ GRAPELAND HEIGHTS SPORTS PARK m cn 0 Z SB-16 ♦ SB-15 ♦ ■ TE-5 SB-9 SB-A SB 32 ♦ ♦ TE-8 ■ TE-9 ■ SB-13♦ SB-33 SB-7r !—..-SB-35 SB-36 SB-37 \ SB-23 SB-1 ♦ TE-32A■ EErG EE&G Enviromental Services, LLC 5751 Miami Lakes Drive Miami Lakes. Florida 33014 (305)374-8300 (305)374-9004 FAX PROJECT: PROPOSED MIAMI FREEDOM PARK (INTERNATIONAL LINKS MELREESE COUNTRY CLUB) 1802 NW 37TH AVENUE MIAMI, MIAMI-DADE COUNTY, FLORIDA 33125 SIIIiliTTITLE: SOIL BORING & TEST EXCAVATION LOCATION MAP Dh+g. Date: 6.174019 lob No.: 2018.3057 Dram By: All. App.13y: --- Sole: JMI. Cad Film (I6.4 Revisions: Figum No. 4 LEGEND: = ASH DEBRIS = NO APPARENT �•�' ASH DEBRIS BASED ON INTERPRETATION PREVIOUS PETRO HYDRO & SCS SOIL LOGS & MARCH 2019 CONFIRMATION TEs & SBs 0' I SCAT F 500' EE ENVIRONMENTAL SERVICES, LLC 5751 MIAMI LAKES DRIVE MIAMI LAKES, FLORIDA 33014 (305) 374-8300 (305) 374-9004 FAX \ PROPOSED MIAMI FREEDOM PARK (INTERNATIONAL LINKS MELREESE COUNTRY CLUB) 1802 NW 37TH AVENUE MIAMI, MIAMI-DADE COUNTY, FLORIDA 33125 \ / \ INFERRED EXTENT OF BURIED DEBRIS MAP / \ / Date: 06/17/19 Project # 2018-3057 Drawn by: JL Cad File: FIG5 Dwg. Scale: As Noted 3/26/2019 144 551 365 > 6,000 (0/R) 3,754 SAMPLING INTERVAL 0 to ft BLS 21o4ft BLS 4 to 611 BLS 61o8ft BLS 6 to 10 ft BLS 10 to 12ft BLS UNITS REPORTED IN PARTS PER MILLION LEGEND: ♦ = SOIL BORING O/R = OVER RANGE 3/28/2019 1 2,030 289 23 SB-4 3/25/2019 <1 3/26/2019 SB-8 SB-5 3/28/2019 3/25/2019 > 6,740 (0/R) 3/26/2019 3/25/2019 3/25/2019 SB-A SB-32 3/26/2019 4/08/2019 GRAPELAND HEIGHTS SPORTS PARK 511 GRAPELAND WATER PARK 3/25/2019 3/26/2019 EErG EE&G Enviromental Services, LLC 5751 Miami Lakes Drive Miami hikes, Florida 33014 (305)374-8300 (305)374-9004 :FAX PROJECT: PROPOSED MIAMI FREEDOM PARK (INTERNATIONAL LINKS MELREESE COUNTRY CLUB) 1802 NW 37TH AVENUE MIAMI, MIAMI-DADE COUNTY, FLORIDA 33125 SHEET TITLE: FIELD NET OVA / FID RESULTS MAP Dvcg. Dale: 6172019 lob No.: 2019-3057 Dram Ile: MI. App. Br: --- Scale: WI. Cad File: 11G6 Raisiuns Figure No. 6 LEGEND: ♦ = SOIL BORING • = TEST EXCAVATION BOLD= ANALYTICAL RESULT EXCEEDED THE SCTL.R BOLD= ANALYTICAL RESULT EXCEEDED THE SCTL-C AND/OR SCTL-L NT= NOT TESTED •••= LEACHABILITY DETERMINED VIA SPLP ANALYSIS PARAMETERS SCTL-R SCTL-C SCTL4. ARSENIC 2.1 12 -- BARIUM 120-• 130,000 1,600 LEAD 400 1,400 BaP•TEF 0.1 0.7 N/A DIOXIN-FURANS 7 30 3,000 All values given In mg/kg vi Ih the exception o1 D'osln-Furans which e e reported In ng/kg 500' SCALE: SB-4 325/19 SB-12 326/19 158 12.0 89.4 41.9 48.9_ 527 212 4100 < 0.1145 2 11.21 SB-25 3/27/19 19.4 2.7 7.1 6.8 9.2 22.9 26.2 204 23.9 69,8 41.6 56.5 TE-24 3/1119 0.2FT2.4FT 7.1 35.3 99.7 49.4 00 0.0 5.97 1.97 10.9 0.4 11.3 6.0 8,3 78.1 152 10.3 1,270 28.2 254 4,020 10,8 23.2 62.1 1,900 4,510 < 0.1 10A0 TE-1 3/12/19 1.2FT 14.3 6 105 0.0 S13.11 3/26/19 8.7 6.2 10.0 8.2 38.1 8.5 30.0 41.0 50.7 10.1 92.9 160 64.3 1,850 SB-19 327/19 22.9 8.2 128 SB-20 327/19 0'AS' 0.5'-2' 2'-4' 27.8 12 29.5 18.1 181.37 212 42.1 L00 TE-19 3/18/19 2.4 FT B.1 56.7 69.7 0.0 6.134 2: SB-27 3/27/19 6.6 2.0 2.3 7.2 7.3 7.7 5.1 4.1 14.4 SB-21 327/19 19.5 16.1 49.7 105 242 85.5 12.0 91.2 661 12A 148 298 65.0 507 393 SB-29 4/082019 58.18 3/27/19 13.8 13.3 4.0 6.4 29.7 13 2 13.7 20 9 29.1 276 6.6 29.3 46.0 167 624 4/08/ 119 3/27 0/19 02 • _'2' 2_ 4'-4:-6_ NT 4.3 ft 191 255 96 7-� �5 2 � 542 •699 1 090 27.5 125 2A 7E-31 3 25/19 NT NT NT 2.4FT 5.8 1116 381 _4.0 9.3 14.8 0.0 1,55 SB-30 4/08/2019 SB-8 326/19 5' , 22 4' 28.8 /7.8 26.9 3/27/19, 1I 1 9.6 1.6 14,3 12.6 3.5 29.8 15.3 3.4 TE-27 3/25/19 0-2FT SG, 325/19 r TE.4 3/12/19 2.4 FT 3.8 21.4 181 0.0 11.18 SB-15 3/27/19 0' :0.5 .0 5.2: 3' - 4' 4' _5_ S .5 ) 2.8 120 14.4 40.0 25. 7.7 15.3 124 714 39.3 88 S8-5 3/25119 0•.0_5'0_5'.2_ 2'-4' 47.8 7.0 20.9 168 1870 616 SEE FIGURE fl4 �" loEl 7E.25 3/25/19 0.2 FT SB-34 SB-36-"A S13-37� W 1 T R S T R E E T SB-3 3/25/19 0,.5 0.5.2' 2' - 4' 23.0 6.7 0A3 7.8 44 198 086 <0.1 0.72 SB-22 3/27/19 5.0.5 0.5'-2' 2'-4' 4'-6' 12.8 0,73 0.27U i!. 5,8 4.0 275 93 30 3,180 GRAPELAND HEIGHTS TS PARK TE-29 3H3/19 0.IFT SB-16 327/19 1-0.94 10.4 3.0 3.4 25.3 5,3 10.3 33,4 204 207 ` 5.7 34 113 26.5 4,980 SB-14 327/19 0..05' 0.5_2;?.•4' 31.0 15.8 83.0 145 623 1,110 1,270 - SB-13 327/19 /-- 2.5 1.7 47.0 36 7.8 88.8 19.4 22,3 13,7 11.0 16.6 395 SB-28 3/27/19 0.:0_5-03'2' 2' - 4. 4' • 3.6 029 0.71 4.8 22.9 6.9 4.7 24.1 18_0 13.7 5,0338355.4 EE 0.2FT2.4FT 36.8 58.1 297 329 159 1,890 NT NT 24.66177.47 SB•9 3/26/19 14-9_27.87.8 49 225 129 636 409 <0.1 7.09 SB.7 3/26/19 /8.8 275 32.0 698 560 3,090 SB-24 3/27/19 0 1,1¢.T 2' . 4' 4. 29.3 364 26.4 6.6 20,1 82.4 7 3,140 SB-23 3/27/19 9'-0s_.45`_?_ 30.2 30.4 128 0.56 7.5 14.0 22.1 4.1 16.8 70,7 53.3 3.3 22.57. 150 '99 SB-1 325/19 6.9 /5.5 8.2 NT _ 198 114 41_5 NT 10.1 27.2 98.0 NT TE-9 3/18/19 2.4FT 58.6 141 361 0.0 15.49 75.87 SB-6 3/26/19 U_3 030 U0.52I 20,5 6.2__3.3 18.2 8.7 5.3 EErG EE&G Enviromental Services, LLC 5751 Miami Lakes Drive Miami Lakes. Florida 33014 (305)374-4300 (3051374.9004 FAX PROJECT: PROPOSED MIAMI FREEDOM PARK (INTERNATIONAL LINKS MELREESE COUNTRY CLUB) 1802 NW 37TH AVENUE MIAMI, MIAMI-DADE COUNTY, FLORIDA 33125 SHEET 11117.11: SOIL BORING & TEST EXCAVATION RESULTS MAP Du'g. Date: 6,17'2019 Job No.: 2018.1057 Drawn I3T: JAIL App. By: Scale: JML Cad File: FIG7 Revisions: Figure No. 1 85.7 SB-9 3/26/19 0"-0.5" 0.5"-2' 2'- 4' 2.3 14.9 36.3 225 69.9 636 < 0.1 7.09 7.8 129 409 SB-34 4/08/19 0"-0.5" 0.5"-2' 2'- 4' 9.2 52.8 49.3 NT NT NT 49.8 216 7,650 SB-32 4/08/19 0"-0.5" 0.5"-2' 2'- 4' 7.7 22.7 10.0 NT NT NT 28.2 5,820 1,020 SB-A♦ SB-24 SB-36 4/08/19 0"-0.5" 0.5"-2' 2'- 4' 20.4 12.0 19.1 NT NT NT 21.1 462 106 MAINTENANCE BUILDING L= LJ GRAPELAND HEIGHTS SPORTS PARK SB-6 SB-37 4/08/19 0"-0.5" 0.5"-2' 2' - 4' 12.0 12.7 75.9 NT NT NT 10.0 224 1,920 N W 1 4 T H 500' SCALE: S E SB-33 4/08/19 0"-0.5" 0.5"-2' 2' - 4' 0.56 I 1.4 16.6 NT NT NT_ 3.9 3.3 42.0 SB-7 3/26/19 0"-0.5" 0.5"-2' 2' - 4' 18.8 275 132.0 29.2 278 698 174 1,560 3,090 SB-35 4/08/19 0"-0.5" 0.5"-2' 2' - 4' 3.4 7.4 10.4 NT NT NT 6.3 97.7 1,720 LEGEND: ♦ = SOIL BORING BOLD= ANALYTICAL RESULT EXCEEDED THE SCTL-R BOLD= ANALYTICAL RESULT EXCEEDED THE SCTL-C AND/OR SCTL-L NT= NOT TESTED �•• = LEACHABILITY DETERMINED VIA SPLP ANALYSIS PARAMETERS SCTL-R SCTL-C ARSENIC 2.1 12 BARIUM 120"` 130,000 LEAD 400 1,400 BaP-TEF 0.1 0.7 DIOXIN-FURANS 7 I 30 All values given in mg/kg with the exception of Dioxin-Furans which are reported in ng/kg SCTL-L 1.600 N/A 3.000 EErG EE&G Enviromental Services, LLC 5751 Miami lakes Drive Miami Lakes. Florida 33014 (305)374.8300 (3051.374-9004 FAX PROJECT: PROPOSED MIAMI FREEDOM PARK (INTERNATIONAL LINKS MELREESE COUNTRY CLUB) I802NW 37TH AVENUE MIAMI, MIAMI-DADF. COUNTY, FLORIDA 33125 moil. TITLE: SOIL BORING RESULTS MAP (MAINTENANCE AREA) Dw'g. Dale: 6.17:2019 Job No.: 2018.3057 Drawn lie: JML App. By: --- Scale: JML Cad File: FIG.8 Revisions: Figure No. 8 LEGEND: • = MONITORING WELL • = DPT GROUNDWATER SAMPLE SCALE: EFbr MW-39 I/ ENVIRONMENTAL SERVICES, LLC 5751 MIAMI LAKES DRIVE MIAMI LAKES, FLORIDA 33014 (305) 374-8300 (305) 374-9004 FAX SMW-38 SCS-MW-2s SIMW-42 GW-1® MW-9r� MW-7B PROPOSED MIAMI FREEDOM PARK (INTERNATIONAL LINKS MELREESE COUNTRY CLUB) 1802 NW 37TH AVENUE MW-449 MW-31N ' GRAPELAND HEIGHTS SPORTS PARK cuv� GRAPELAND WATER PARK MONITORING WELL LOCATION MIAMI, MIAMI-D :OUNTY, FLORIDA 33125 J MAP x e ue 0 Z (-Date: 06/17/2019 Project # 2018-3057 Drawn by: JL Cad File: FIG 9 \Dwg. Scale' As I FIGURE 9 LEGEND: B = MONITORING WELL = DPT GROUNDWATER SAMPLE NT = NOT TESTED BOLD = ANALYTICAL RESULT EXCEEDED THE GCTL BOLD =ANALYTICAL RESULT EXCEEDED THE NADSC 1 = THE REPORTED VALUE IS BETWEEN THE LMDL & LPOL U = THE REPORTED VALUE IS BETWEEN THE LMDL & LPOL PARAMETERS GCTL NADSC ARSENIC 10 100 BARIUM 2,000 20,000 LEAD 15 150 ALUMINUM 200 2,000 IRON 300 3,000 All values given in ug/L 0' 500' GALE: SCS-MW-1 3/04/19 3/27/19 7.1 U NT 41.4 NT 4.6 U NT 30.7 U NT 1,350 2,960 MW-4 3/26/19 7.1 U 61.7 4.6 U NT 530 MW-11 4/09/19 7.1 U NT 4.6 U NT 842 MW-39 s .L04/19 ., 7.1 U 11.5 4.6 U r---e 30.7 U a 369 - '9 M W-10 4/09/19 951 NT 4.6 U NT 1,060 Z c 9' MW-2 328/19 4/08/19 13.2 20.9 21.9 NT 4.6 U NT NT NT 1,010 1,600 3/26/19 4/08/19 MW-3 3/26/19 7.4 I MW-42 /04/19 7.1 U 20.8 4.6 U 30.7 U MW-8 /27/19 7.1 88.3 4.6 U NT 793 MW-5 3/26/19 4/08/19 7.1 U NT 187 NT 901 NT NT NT 3,420 2,560 GW-1 3/27/19 NT NT NT GRAPELAND HEIGHTS SPORTS PARK SCS•MW-2 MW-1 3/04/1 • 3/26/19 7.1 U 7.1 U 23.0 4.6 U 30.7 U 4.6 1 NT 208 333 MW-44 3/04/19 3/27/19 7.1 U NT 51.2 NT 4.6 U NT 30.7 U 766 MW-6 3/27/19 7.1 U 13.3 4.6 U NT 87.6 NT 795 MW-31 3/04/19 3/27/19 .__.. .-. 92.0 85.2 16.6 NT 4.6 U NT 30.7U NT 2,820 2,430 M W-7 3/27/19 7.1 U 174 6.9 1 NT 884 MW-12 44S/ 7.1 U NT 4.6 U NT 427 EE6-G EE&G Enviromental Services, LLC 5751 Miami Lakes Drive Miami Lakes. Florida 33014 (305)374-9300 (305)374.9004 fAX PROJECT: PROPOSED MIAMI FREEDOM PARK ( INTERNATIONAL LINKS MELREESE COUNTRY CLUB) 1802 NW 37TH AVENUE MIAMI, MIAMI-DADE COUNTY, FLORIDA 33125 SHEET TITLE: GROUNDWATER RESULTS MAP (METALS) Dwg Date: 6,17,1019 Job No.: 2018-7057 Drawn By JML App. By: --- Scak: JML Cad File: F10.10 Rclisions: Figure No. I0 LEGEND: 6 = MONITORING WELL 16 = DPT GROUNDWATER SAMPLE BOLD = VALUE EXCEEDS GCTL GCTL= GROUNDWATER CLEANUP TARGET LEVEL U = ANALYTICAL RESULT BELOW THE LABORATORY METHOD DETECTION LIMIT I = THE REPORTED VALUE IS BETWEEN THE LABORATORY METHOD DETECTION LIMIT AND THE LABORATORY PRACTICAL OUANTITATION LIMIT MW-4 BARIUM 326/19 61.7 SCS-MW-I 04/19 BARIUM LEAD ALUMINUM VOCs 8260 (pg/L) 41 4 4.6 U 30.7 U PAHs 8270 (pg/L) TPH FL -PRO (mg/L) DIE LORIN 077U 0.0032 I 327/19 0.0019 U o cacpau.mnmane 80.8100-1 U U LEAD 4.6 U onesc.to =...eenaee..111 I8.18) GCTL MW-39 3/04/19 BARIUM 5 LEAD I/ ALUMINUM 307U VOCs 8260 (PgIL) PAHs 8270 (pg/L) TPH FL -PRO (mg/L) 0,79U 1.011•48 • name.( DIOXINS - FURANS 8290 (pe/L) a.xo.xo xo 100ee.1.11wll U a,Lwe.Kxo.. n..,.ame.,., lwu DIOXINS - FURA NS 8280 (pg/L) 2.84 MW-38 BARIUM LEAD 3/26/19 75.3 4.6 U ew+.e® Peenao...n. w./4 GCTL MW MW-10 4/09/19 MCI CEO /26/19 BARIUM LEAD 21.9 4.6 U ere.9W4 GCTL 0' S00' SCALE: 2.89 N W MW-42 3/04/19 BARIUM LEAD ALUMINUM 20.8 4.6 U 30.7 U VOCs 8260 (pg/L) PAHs 8270 (pg/L) TPH FL -PRO (mg/L) 00...n,1 DIOXINS - FORAMS 8290 (178/4 S i S T R E E MW-5 326/ 9 1111111ZE EMI MEM aam:mem pumas. w.. wmu MW-11 4/09/19 LEAD' 4.6 U' 327/19 MW-3 BARIUM MW-6 BARIUM U U 0.77 U U 3 327/19 133 LEAD 4.6 U __..... ex.aw.em 1..nax.80. 1pp/U TL 3/26/19 21.8 LEAD 4.6 U u.uneumo ..s. WV.) <GCTL MW-12 4/09/19 ( LEAD 14.6 U SCS-MW-2 N W 3/04/19 BARIUM 23.0 LEAD 4.6 U ALUMINUM 30.7 U VOCs 8260 4 g/LI PAHS 8270 (pg/L) TPH FL -PRO )mg/L) ww.une mnoo...0., lwtl nawm..81wM 0.76 U <GCTL U Cric U DIOXINS - FURANS 8280 (p8/L) 3.85 R ap GRAPELAND HEIGHTS SPORTS PARK �Q` 1 GRAPELAND WATER PARK 0/.; E E 7 MW-44 3/04/19 BARIUM 51.2 LEAD 4.6 U ALUMINUM 30.7 U ACETONE 541 OTHER VOCs 8260 (pq/L) U PAHs 8270 (pg/L) TPH FL -PRO (mg/L) U 0.78 U n.u...ne menam m.,1wA1 U cow xe.xo..xo.00..eman..,., Iwll U cxLenornec.rxmcan.,..luo41 U DIOXINS - FURANS 8290 (p904 3.32 MW-8 327/19 BARIUM 883 LEAD 46U aaaw..m.eenarcneo,� wa MW-31 BARIUM GCTL 3r04/19 16.6 LEAD 4,6 U ALUMINUM 30.7 U VOCs 8260 (pg/L) U PAHs 8270 (pg/L) U TPH FL -PRO (mg)L) 0.77 U 327/19 DIELDRIN 0.00231 0.0019 U en Tea Pas cones...1 U U ORM re co U c,.onempe.e emcees.., lwtl U DIOXINS - FURANS 82901p8/L) 2.87 GW- 326/19 VOCs 8260 (pg/L) PAHs 8270 (pq/L) GCTL TPH FL -PRO (mg/L) MW-9 0.79 U 326/19 MW-1 BARIUM 326/19 46.5 LEAD 4 6 U 0 Arr. nemon. o. MOIL) GCTL BARIUM 95 LEAD 4.6 U VOCs 8260 (pg/L) GCTL PAHs 8270 (pg/L) TPH FL -PRO (mg/L) 0.88 U Lam.merim amw., 1•241 <GCTL uvx0..c xwownmam.,.,/899-1 U U EEb.G EE&G Enviromental Services, LLC 5751 Miami lakes Drive Miami Lakes. Florida 33014 (305)3748300 13051374.9004 fAX PROJECT: PROPOSED MIAMI FREEDOM PARK (INTERNATIONAL LINKS MELREESE COUNTRY CLUB) 1802 NW 37TH AVENUE MIAMI, MIAMI-DADE COUNTY, FLORIDA 33125 srIEETTITLE: GROUNDWATER RESULTS MAP (OTIIER PARAMETERS TESTED) Dwg Dale; 617;2019 Job No.: 2018-1057 Dram 13v: )ML App.13y: -- Seale: 1ML Cad File: FIG.11 Rclisions: Figure No. 11 LEGEND: B =MONITORING WELL ti a EE�G BOLD = ANALYTICAL RESULT EXCEEDED — THE GCTL BOLD = ANALYTICAL RESULT EXCEEDED MW-44 THE NADSC N SCS-MW-1 3/04/19 3/27/19 3/04/19 3/27/19 766 ' 795 1 = THE REPORTED VALUE \\ EE&G Enviromental Services, LLC 575I Miami Lakes Drive Miami Lakes. Flo Florida 33014 IS BETWEEN THE LMDL & LPQL I1,350 � 2,950 I MW-42 nq \ (30S)374•R300TF.L U = BELOW THE LABORATORY DETECTION / 1 1,000 u 1 ‘• g G21 �� ��\ �� 1305)374.4004:FAX LIMITS /0 I ; PARAMETERS GCTL NADSC \ �0---'----- 0 / 706 ug/L Z PROJECT: IRON 300 3,000 -**i I------•--.. 5( / PROPOSED 706* __IZ * MW-4 ,c� —3/27/19 MIAMI FREEDOM PARK *DERM background value for IRON 9 All values given in ug/L o z 0 n 3/26/19 706 ug/L / 793 I 1 1530 , W6 -1 MMW-5 3/27/19 1 706 ug/L 3/26/19 4/08/19 i�--� , / 87.6 / 3,420I2,560I� / MW-11 / 1,000 u /L / 4/09/19 1 g / s-- --{ 842 1 \\\ / y (INTF.RMELIREESE ONAL LINKS COUNTRY CLUB) 1802 NW 37TH AVENUE MIAMI, MIAMI-DADE z G ,—� M W-31 \ 3/04/19 3/27/19 \ x COUNTY, FLORIDA 33125 m M W-38 \ 3/26/19 4/08/19 I2,820 1 2,430 � n a 14.E \ SI1FEF iri.E: .t \\ 1 3,830 2,000 '., .4 .q n INFERRED EXTENT OF 1,000 ug/ MW-39 1 3/04/19 i"-" 1 I 1 i 000 ug/L;) -AFFECTED •'IRON 369 / 1 ` GROUNDWATER / \ 1,000 ug/L 3/26/119406/,9 / ...-0' 4,030 1,750 0. / 3/27/19 c GROUNDWATER RESULTS MAP MW-10 M W-3 3/26/19 / — (IRON) 4/09/19 [l85J---10 ..i GRAPELAND I1,060I / HEIGHTS "1 SPORTS PARK 706 MW-12 ug/L 1 4l9/1.9 I)wr. Date aro 20w / 427 MW-1 loh No.: 21118.3057 \ \ 1 3/26/19 Drawn13c; JML \ \ j SCS-MW-2 333 GRAPELAND App.By: \\ 1 /3/04/19 r Scale: S0URAWING MW-2 \ _�000 ugi 208 I PARKWATER Cad File: /16.12 3/26/19 4/08/19 \� 1,010 1,600 61 Recisions: H W 1 4 T H STREET , Figure No. / 0' 350'12 SCALE:1" = 350' LEGEND: S = MONITORING WELL BOLD = ANALYTICAL RESULT EXCEEDED THE GCTL BOLD = ANALYTICAL RESULT EXCEEDED THE NADSC I = THE REPORTED VALUE IS BETWEEN THE LMDL & LPQL U = BELOW LABORATORY DETECTION LIMITS PARAMETERS GCTL NADSC [ ARSENIC r 10 1 100 I All values given in ug/L 3. m z INFERRED EXTENT OF ARSENIC -AFFECTED GROUNDWATER 0' 350' SCALE:1" = 350' SCS-MW-1 3/04/19 7.1 UJ MW-42 3/04/19 7.1 U MW-4 MW-8 3/26/19 3/27/19 ---S 7.1 U MW-11 4/0S/19 MW-38 3/26/19 M W-39 [ 7.1 U 3/04/19 _... I7.1 U MW-10 4/09/19 9.5 I MW-3 3/26/19 7.4 I MW-2 •� 3/26/19 4/08/19 13.2 r 20.9 1 1 MW-5 3/26/19 MW-9 3/26N 9 7.1 U SCS-MW-2 3/04/19 171 7.1 U1 MW-44 3/04/19 I7.1U, 1 MW-6 3/27/19 I7.1 U MW-31 3/04/19 3/27/19 192.0 185.2 MW-7 3/27/19 7.1 U MW-12 4/9/19 MW-1 3/26/19 7.1 UT 4 T H INFERRED EXTENT OF ARSENIC -AFFECTED GROUNDWATER GRAPELAND HEIGHTS SPORTS PARK GRAPELAND WATER PARK S T REE T EErG EE&G Enviromental Services, LLC 5751 Miami Ickes Drive Miami lakes. Florida 33014 (305)374-1300 Tel (305)374-9004:FAX FR(/il (T: PROPOSED MIAMI FREEDOM PARK (INTERNATIONAL LINKS MELREESE COUNTRY CLUB) 1802 NW 37TH AVENUE MIAMI, MIAMI-DADE COUNTY, FLORIDA 33125 SI IEIiT TITI.Ii: GROUNDWATER RESULTS MAP (ARSENIC) Dwg Dale: 6171019 Job No.: 2018.3037 Drawn 133: IML App. 8r: Scale: DAL Cad File: F10.13 Recisions: Figure No. 13 LEGEND: = MONITORING WELL BOLD = VALUE EXCEEDS GCTL BOLD = VALUE EXCEEDS NADSC NT = NOT TESTED GCTL = GROUNDWATER CLEANUP TARGET LEVEL NADSC = NATURAL ATTENUATION DEFAULT SOURCE CONCENTRATION U = BELOW THE LABORATORY DETECTION LIMIT PARAMETERS GCTL NADSC [AMMONIA (as N)I 2.8 I 28 I All values given in mg/L 0' 350' L L SCALE:1" = 350' a / MW-44 `` ± / 3/04/19 i STREET NW SCS-MW-1 3/04/19 —I 0.23� 2 1 S T M W-42 3/04/19 0.69 M W-8 t 1 I MW-4 " % Si 3/26/19 / 0.64 I 7 / MW-5 I / / 3/26/19 / / (9— 13.0 I / MW-111 / / 1 / 1 MW-9 / MW-31 r� 3/26/19 3/04119 �Li MW-6 u 6 \ 9.3 ll / I_ 0.58 J 3/04/19 1 MW-39 6)—II 0.67 1 MW-7S da M W-38 MW-3 3/26/19 0.47I MW-12s1 SMW-1 GRAPELAND HEIGHTS SPORTS PARK 2 ti x m m INFERRED EXTENT OF AMMONIA -AFFECTED GROUNDWATER EEb.G EE&G Enviromental Services, LLC 5751 Miami Lakes Drive Miami. Florida 33014 (305)3745300 TEL (3051374.9004 FAX PROJECT: PROPOSED MIAMI FREEDOM PARK (INTERNATIONAL LINKS MELREESE COUNTRY CLUB) 1802 NW 37TH AVENUE MIAMI, MIAMI-DADE COUNTY, FLORIDA 33125 SHEET TITLE: GROUNDWATER RESULTS MAP (AMMONIA) 9 9 Date: 6'11i1019 Job No.: 2018.3057 Drmrn IN: JMI. App.13s.: -- Seale: JML Cnd File: FIG.9 Revisions: Figure No. 14 m 0 Z —1 D MW-1 1 4/09/19 LEGEND: = MONITORING WELL = DPT GROUNDWATER SAMPLE NM = NOT MEASURED NOTE: ALL MEASUREMENTS IN FEET SCALE: MW-38 4/09/19 11.95' j MW-10 4/09/19 MW-2 4/09/19. MW-5 4/09/19 11 94' MW-9 4/09/19 12.16' MW-7 MW-3 4/09/19 4/09/19 Li2.12' 1 W/19 19 MW- NM SCS-MW-2 4/09/19 12.00' MW-1 4/09/19 11.93' MW-44 4/09/19 11.03' 4/09/19 GRAPELAND HEIGHTS SPORTS PARK GRAPELAND WATER PARK E E T EEtrG EE&G Environmental Services, LLC 5751 Miami lakes Drive Miami. Florida 33014 (30513748300 :TEL (305)374-9004 FAX PROJECT: PROPOSED MIAMI FREEDOM PARK (INTERNATIONAL LINKS MELREESE COUNTRY CLUB) 1802 NW 37TH AVENUE MIAMI, MIAMI-DADE COUNTY, FLORIDA 33125 SHEET TITLE: GROUNDWATER FLOW MAP Dwg. Date: 617.2019 Joh No.: 2018.3057 Drawn B): IA9. App. By: -- Scale: JML Cad File: 1101S Revisions: Figure No. 15 Flush Mount Well Cover 1 Water -tight Locking cap PVC Riser 1.5-in. Sch 40 4 ft. Section Pre -packed 1.5-in slotted Sch. 40 (10 ft Section) Fine Grain Sand PVC Bottom Plug / i Concrete Pad Concrete Floor Neat Cement Grout Assumed Static Groundwater Table Interface (N 3-6ftBLS) Total Depth Approx. 12 to15 ft BLS ENVIRONMENTAL SERVICES, LLC \ PROPOSED MIAMI FREEDOM PARK \ / \ 5751 MIAMI LAKES DRIVE (INTERNATIONAL LINKS MELREESE COUNTRY CLUB) MONITORING WELL MIAMI LAKES, FLORIDA 33014 1802 NW 37TH AVENUE CONSTRUCTION (305) 374-8300 DIAGRAM (305) 374-9004 FAX J MIAMI, MIAMI-DADE COUNTY, FLORIDA 33125 J Date: 06/17/19 Project # 2018-3057 Drawn by: JL Cad File: FIG16 Dwg. Scale: As Noted / \ FIGURE 16 \ J LEGEND: (= VAPOR WELL LEL= LOWER EXPLOSIVE LIMIT(%) CH. = METHANE(%) Oa = OXYGEN(%) VOC= VOLATILE ORGANIC COMPOUND(ppm) 14/09/19 0' 500' SCALE: VW-7 4/02/19 4/09/19 4/02/19 4/09/19 14/09/19 T R RE T 4/02/19 4/09/19 LEL CH. 0. VOC GRAPELAND HEIGHTS SPORTS PARK GRAPELAND WATER PARK PROPERTY BOUNDARY 4/02/19 4/09/19 0.0 20.1 VW-2 4/02/19 4/09/19 4/02/19 4/09/19 4/09/19 4/02/19 4/09/19 LEL CH. >60 14.5 >100 14.3 T 0. VOC 0.2 0 0.0 0.3 EErG EE&G Enviromental Services, LLC 5751 Miami lakes Drive Miami Lakes. Florida 33014 (3051374.9300 13051374-9004 fAX PROJECT: PROPOSED MIAMI FREEDOM PARK (INTERNATIONAL LINKS MELREESE COUNTRY CLUB) 1802 NW 37TH AVENUE MIAMI, MIAMI-DADE COUNTY, FLORIDA 33125 SIlki; TITLE: VAPOR WELL LOCATION & RESULTS MAP Dwg Dale: 61/1019 Job No.: 2018.1057 Drawn Be: JML App. By: --- Soak: 1ML ('ad File: FIG•17 Recisions: Figure No. 17 EE&G: Site Rehabilitation Plan August 2019 TABLES TABLE 1 TEST EXCAVATION DEBRIS INTERVALS MELREESE GOLF COURSE 1802 NW 37TH AVENUE MIAMI, MIAMI-DADE COUNTY, FLORIDA 33125 PROJECT NO.: 2018-3057 Test Area Designation Date Performed Latitude (N) Longitude (W) Total Depth (feet- BLS) Groundwater Depth (feet -BLS) Debris Interval (feet -BLS) Lithology Soil Sample (feet - BLS) TEST EXCAVATIONS TE-1 12-Mar-2019 25 47.577 -80 15.832 6.0 Not Encountered 0.5 - 6.0+ Golf course base sand 0 - 0.5, incinerator debris 0.5 - 6.0. 1.0 - 2.0 TE-2 12-Mar-2019 25 47.587 -80 15.721 7.0 5 1.5 - 7.0+ Golf course base sand 0 - 1.5, incinerator debris 1.5 - 7.0. N/A TE-3 12-Mar-2019 25 47.621 -80 15.645 5.0 Not Encountered 1.0 - 4.5 Golf course base sand 0 - 1.0, incinerator debris 1.0 - 4.5, tan silty clay w/ trace roots 4.5 - 5.0. N/A TE-4 12-Mar-2019 25 47.612 -80 15.538 5.0 5.0 1.5 - 2.0 Golf course base sand 0 - 1.5, incinerator debris 1.5 - 2.0, organic/peat material 2.0 - 3.0, tan silty clay w/ trace roots 3.0 - 5.0. 2.0 - 4.0 TE-5 18-Mar-2019 25 47.625 -80 15.444 6.0 5.0 2.0 - 4.5 Golf course base sand 0 - 0.5, woody debris & fill 0.5 - 1.5, sandy fill & concrete 1.5 - 2.0, incinerator debris 2.0 - 4.5, silt w/ trace roots 4.5 - 6.0. N/A TE-6 13-Mar-2019 25 47.548 -80 15.773 5.0 4.0 1.0 - 5.0+ Golf course base sand 0 - 1.0, incinerator debris 1.0 - 5.0. N/A TE-7 18-Mar-2019 25 47.583 -80 15.628 6.0 6.0 0.5 - 2.5 Golf course base sand 0 - 0.5, woody & some incinerator debris 0.5 - 2.5, brown sandy limestone 2.5 - 4.0, gray sandy limestone 4.0 - 5.5. N/A TE-8 18-Mar-2019 25 47.583 -80 15.439 5.0 4.5 1.5 - 4.0 Golf course base sand 0 - 0.5, woody debris & fill 0.5 - 1.0, sandy fill 1.0 - 1.5, incinerator debris 1.5 - 4.0, silt w/ trace roots 4.0 - 5.0. N/A TE-9 18-Mar-2019 25 47.584 -80 15.383 6.0 5.5 4.0 - 6.0+ Golf course base sand 0 - 1.5, woody debris & fill 1.5 - 4.0, incinerator debris 4.0 6.0. 2.0 - 4.0 TE-10 13-Mar-2019 25 47.541 -80 15.669 6.5 4.5 1.0 - 6.5+ Golf course base sand & tree roots 0 - 1.0, incinerator debris 1.0 - 6.5. N/A TE-11 18-Mar-2019 25 47.564 -80 15.513 3.5 3.0 1.0 - 3.5+ Golf course base sand 0 - 1.0, incinerator debris 1.0 - 3.5. N/A TE-12 18-Mar-2019 25 47.539 -80 15.618 4.5 4.5 1.0 - 3.0 Golf course base sand 0 - 1.0, incinerator debris 1.0 - 3.0, gray sand & limerock 3.0 - 4.5. N/A TE-13 13-Mar-2019 25 47.500 -80 15.728 6.0 Not Encountered 1.0 - 6.0+ Golf course base sand 0 - 1.0, incinerator debris 1.0 - 6.0. 2.0 - 4.0 TE-14 18-Mar-2019 25 47.521 -80 15.570 5.5 5.0 0.5 - 5.0 Golf course base sand 0 -0.5, incinerator debris 0.5 - 5.0, tan sand 5.0 - 5.5. 0 - 2.0 TE-15 18-Mar-2019 25 47.471 -80 15.801 6.0 5.5 0.5 - 5.5 Golf course base sand 0 - 0.5, incinerator debris 0.5 - 5.5, tan sand & limestone 5.5 - 6.0. N/A TE-16 13-Mar-2019 25 47.480 -80 15.649 6.0 3.5 0.5 - 6.0+ Golf course base sand 0 - 0.5, incinerator debris 0.5 - 6.0. N/A TE-17 13-Mar-2019 25 47.454 -80 15.686 4.0 3.0 0.5 - 4.0+ Golf course base sand and organics 0 - 1.5, incinerator debris 1.5 - 6.0. N/A TE-18 18-Mar-2019 25 47.397 -80 15.829 3.5 3.0 Not Encountered Golf course base sand 0 - 1.5, sand with organics 1.5 - 3.0, tan sand 3.0 - 3.5. N/A TABLE 1 TEST EXCAVATION DEBRIS INTERVALS MELREESE GOLF COURSE 1802 NW 37TH AVENUE MIAMI, MIAMI-DADE COUNTY, FLORIDA 33125 PROJECT NO.: 2018-3057 Test Area Designation Date Performed Latitude (N) Longitude (W) Total Depth (feet- BLS) Groundwater Depth (feet -BLS) Debris Interval (feet -BLS) Lithology Soil Sample (feet - BLS) TEST EXCAVATIONS TE-19 18-Mar-2019 25 47.411 -8015.773 5.0 4.0 1.0 - 3.5 * Golf course base sand 0 -1.0, construction debris (rubble and sand) 1.0 - 3.5, tan sand & limestone 3.5 - 5.0. 2.0 - 4.0 TE-20 13-Mar-2019 25 47.407 -8015.659 3.5 Not Encountered 1.0 - 3.5* Golf course base sand 0 -1.0, tan concrete debris (rubble and sand) 1.0 - 3.5, refusal at former roadway at 3.5. N/A TE-21 25-Mar-2019 25 47.377 -8015.733 5.0 5.0 1.5 - 4.0* Golf course base sand 0 -1.0, construction debris (rubble and sand) 1.0 - 3.5, tan sand & limestone 3.5 - 5.0. N/A TE-22 13-Mar-2019 25 47.388 -8015.601 6.5 5.5 2.5 - 6.5+ Golf course base sand 0 -1.5, tan sand & limestone 1.5 - 2.5, incinerator debris 2.5 - 6.5. N/A TE-23 18-Mar-2019 25 47.358 -8015.787 4.5 4.0 2.0 - 4.0* Golf course base sand 0 - 1.0, organics 1. - 2.0, construction debris 2.0 - 4.0, tan sand & limestone 4.0 - 4.5. N/A TE-24 18-Mar-2019 25 47.319 -8015.827 5.0 5.0 0.5 - 5.0* Golf course base sand 0 - 0.5, tan construction debris (rubble, fiber and sand) 0.5 - 6.0, tan sand and limestone 6.0 - 6.5. 0 - 2.0 , 2.0 - 4.0 TE-25 25-Mar-2019 25 47.329 -80 15.668 4.5 4.0 1.0 - 4.5* Golf course base sand 0 -1.0, tan concrete debris (rubble and sand) 1.0 - 4.0, tan sand and limestone 4.0 - 4.5. 0 - 2.0 TE-26 13-Mar-2019 25 47.310 -80 15.620 5.0 5.0 1.0 - 3.5 Golf course base sand as 0 -1.0, incinerator debris 1.0 - 3.5, organics 3.5 - 4.5, tan sand 4.5 - 5.0. N/A TE-27 25-Mar-2019 25 47.291 -80 15.732 3.0 3.0 0.25 - 2.5* Golf course base sand 0 - 0.2.5, tan concrete debris (rubble and sand) 0.25 - 2.5, tan sand and limestone 2.5 - 3.0. 0 - 2.0 TE-28 25-Mar-2019 25 47.274 -8015.798 6.0 Not Encountered 0.5 - 6.0* Golf course base sand 0 - 0.5, tan concrete debris (rubble and sand) 0.5 - 2.5, tan sand and limestone 2.5 - 3.0. 0 - 2.0 TE-29 13-Mar-2019 25 47.279 -8015.571 5.5 5.0 2.0 - 5.0 Golf course base sand 0 - 2.0, incinerator debris 2.0 - 5.0, tan sand & limerock 5.0 - 5.5. 0 - 1.0 TE-30 25-Mar-2019 25 47.254 -8015.666 6.0 6.0 0.25 - 5.75 Golf course base sand 0 - 0.25, incinerator debris 0.250 - 5.75, tan sand & limerock 5.75 - 6.0. N/A TE-31 25-Mar-2019 25 47.201 -8015.731 6.0 5.5 0.5 - 5.5* Golf course base sand 0 - 0.5, tan sandy fill with some brick, concrete and limerock 0.5 - 5.5, tan sand and limestone 5.5 - 6.0. 2.0 - 4.0 TE-32 13-Mar-2019 25 47.342 -8015.635 3.0 Not Encountered Not Encountered Golf course base sand 0 -1.0, sand and gravel - septic drain field 1.0 - 3.0. N/A TE-32A 25-Mar-2019 25 47.222 -80 15.519 5.5 5.5 1.0 - 5.5* Golf course base sand 0 -1.0, tan concrete debris (rubble and sand) 1.0 - 5.5. N/A TE-33 25-Mar-2019 2547.409 -8015.514 6.5 5.5 1.5-6.0 Golf course base sand 0 -1.5, incinerator debris 1.5 - 6.0, tan sand & limerock 6.0-6.5. 0-2.0, 2.0 4 0 * Denotes tan colored fill material comprised of construction debris, concrete, bricks, fiber (carpet) and sand. TABLE 2 EE SOIL BORING OVA/FID FIELD SCREENING RESULTS MELREESE GOLF COURSE 1802 NORTHWEST 37TH AVENUE MIAMI, MIAMI-DADE COUNTY, FLORIDA 33125 PROJECT NO.: 2018-3057 SOIL BORING DESIGNATION DATE DEPTH (FEET- BLS) PARTS PER MILLION (TOTAL) PARTS PER MILLION (WITH CARBON FILTER) PARTS PER MILLION (NET) SB-1 0-2 <1 NF <1 2 - 4 356 93 263 3?25/2019 4 - 6 408 204 204 6-8 71 31 40 SB-2 0-2 119 42 77 2 - 4 143 64 79 3/25/2019 4-6 18 7 11 6 - 8 208 133 75 SB-3 3'25/2019 0-2 2 NF 2 2-4 <1 NF <1 4-6 <1 NF <1 6-8 <1 NF <1 SB-4 3/25/2019 0-2 <1 NF <1 2-4 <1 NF <1 4 6 219 56 163 6 - 8 651 176 475 SB-5 3/25/2019 0-2 7 NF 7 2 - 4 396 102 294 4 - 6 216 81 135 6 - 8 >6,740 (O/R) NF >6,740 (O/R) 8-10 <1 NF <1 10-12 <1 NF <1 SB-A 3,26/2019 0-2 114 17 97 2-4 18 8 10 4-6 85 16 69 6 - 8 198 104 94 SB-6 3/26/2019 0-2 <1 NF <1 2-4 <1 NF <1 4_ 6 < 1 NF < 1 6-8 <1 NF <1 SB-7 3/26/2019 0-2 1 NF 1 2-4 <1 NF <1 4 - 6 95 46 49 6-8 <1 NF <1 SB-8 3/26/2019 0-2 43 11 32 2-4 <1 NF <1 4-6 29 10 19 6-8 6 NF 6 TABLE 2 EE SOIL BORING OVA/FID FIELD SCREENING RESULTS MELREESE GOLF COURSE 1802 NORTHWEST 37TH AVENUE MIAMI, MIAMI-DADE COUNTY, FLORIDA 33125 PROJECT NO.: 2018-3057 SOIL BORING DESIGNATION DATE DEPTH (FEET- BLS) PARTS PER MILLION (TOTAL) PARTS PER MILLION (WITH CARBON FILTER) PARTS PER MILLION (NET) SB-10 3/26/2019 0 - 2 33 7 26 2 - 4 < 1 NF < 1 4 - 6 18 6 12 6-8 11 2 9 SB-11 3/26/2019 0-2 <1 NF <1 2 - 4 161 17 144 4 - 6 624 73 551 6 - 8 464 79 385 8 - 10 >6,000 (O/R) NF >6,000 (O/R) 10 - 12 4,334 580 3,754 SB-12 3/26/2019 0-2 <1 NF <1 2 - 4 20 3 17 4 - 6 1 NF 1 6 - 8 2,348 318 2,030 8 - 10 298 29 269 10 - 12 27 4 23 SB-32 4/8/2019 0 - 2 1,100 280 820 2 - 4 1,300 540 760 4 - 6 630 52 578 6 - 8 450 103 347 otes: NF = Not Charcoal Filtered O/R = Over Range Bold = Result above 10 parts per million action level TABLE 3 TEST EXCAVATION SOIL ANALYTICAL RESULTS MELREESE GOLF COURSE 1602 NW 37TH AVENUE MIAMI, MIAMI-DADE COUNTY, FLORIDA 33126 PROJECT No.: 2018-3057 Semple Designation: Clete Collected: Depth(Fee1-BLS): TE-1 TES TE-13 TE-29 TE-9 TE.14 TE.24 TE-24 TE-19 TE.31 TE.27 TE-25 TE-33 TE-J3 3/1019 3/12/19 013(19 3/13/19 3/18/19 311019 3/18/19 3/1019 3/18719 3I25/19 N25/19 3I25r19 3/25/19 3r2519 1.2 3.4 2.4 0-1 2.4 0-2 0.2 2.4 2-4 2.4 0-2 0-2 0.2 2 • 4 Parameter Se Reeltlenllal l Clasnup Target Levee (SOT Can mercleNneuaele el LeecMdlky Tofel Meals by 8010 (mono) Needs 2.1 12 '" 14.3 3.8 9.7 47.6 58.6 10 10.9 7.1 6.1 4.0 13.2 35 38.8 56.1 120" 130000 1 800 33.8 21.4 (159 14.4 141 38.8 28.4 35.3 56.7 9.3 29.4 8.9 29.6 329 Barium Ctlnkan Bi 1,700 75 0.61 0.89 1.2 0.44 18 073 0.80 038 0.33 NT NT NT NT NT Ctromier 210 470 38 21.8 8.1 33.9 13.8 34,3 13.5 17.2 29.3 9.9 NT NT NT NT NT Lead 400 1,400 " 105 181 202 28.7 381 120 99.7 49.4 89.7 14.8 180 150 159 1,890 440 11,000 5.2 0.51(U) 0,53N1 0.63N1 0.56(I) 3.0(U) 0.53N1 0.40N1 0.420.1 0.446UI NT NT NT NT NT Se4num Saver 410 8,200 17 0.89 0.73 0.98 0.35 4.2 1.6 0.56 0.67 0.85 NT NT NT NT NT by 7471 Tatal Mauls Molkal Merco5 3 17 21 0.093 0.31 0,14 0,024 0080 0.055 0096 0.075 0.061 NT NT NT NT NT TCLPMeMIs by 1311(mall.) Lead 5.0 50 0.048(U) 0.01E NI 0.046N1 NT 0048(1.1) 0.048(U) NT NT NT NT NT NT NT NT VOCs by 8260 (m89a) MTOE 4,400 24,000 0,009 0.0025(U) NT NT NT NT NT NT NT NT NT NT NT NT NT 1.2 1 7 0, 07 0.0028 (U) NT NT NT NT NT NT NT NT NT NT NT NT NT 8200.Ta Toluene 7,500 60000 0,5 0.0028(U) NT NT NT NT NT NT NT NT NT NT NT NT NT EBd9)emene 1,500 9.200 0.5 0.0029(U) NT NT NT NT NT NT NT NT NT NT NT NT NT 130 700 0.2 0.0053 N) NT NT NT NT NT NT NT NT NT NT NT NT NT Total 8Aenes 8.8 18 003 0.002E NI NT NT NT NT NT NT NT NT NT NT NT NT NT Telr9cybroe6ens (PCE) 8.4 9.3 0.003 0.0029(U) NT NT NT NT NT NT NT NT NT NT NT NT NT TrbNbme8lene(TCE) 33 180 0.4 0.0028N1 NT NT NT NT NT NT NT NT NT NT NT NT NT Cb-1243141117methene 53 290 0.7 0.0031 N) NT NT NT NT NT NT NT NT NT NT NT NT NT Tens-12-0bhbmelhare Vdyl CNedd 0.2 0.8 0.007 0.0028(U) NT NT NT NT NT NT NT NT NT NT NT NT NT Iswrarvl8emene 220 1,200 0.2 0.0030(U) NT NT NT NT NT NT NT NT NT NT NT NT NT 0E8) 11000 68000 25 0.031 NT NT NT NT NT NT NT NT NT NT NT NT NT Acetone OBIS VOCs Tested Vanes Per Constituent (U) NT NT NT NT NT NT NT NT NT NT NT NT NT PAH, by 8270 (m9,991 65 300 1,2 0.013N1 0.015NI 0.021 (I) 0.018(U) 0.14 0.014M 0.012 NI 0.014N1 0.17 NT NT NT NT NT Naphthalene 200 1,500 3.1 0.016011 0.017 N) 0018(U) 0,01501) 0.039(6 0.016 N) 0.014N1 0.015 N1 0.082 NT NT NT NT NT 1-MMh9 Naphthalene 210 2.100 0,6 0.015 (U) 0.017 NI 0018(U) 0.018 NI 0.049 (R 0.018 N) 0.014 NI 0.015 N) 0.077 NT NT NT NT NT 2-Me6M Na9hthalene 20000 2 0.013 N) 0.0156.1) 0.018(U) 0.0160) 0.0240) 0.014 NI 0.012N1 0.014 NI 0.024(11 NT NT NT NT NT Acenaohthene 2,400 1,800 20000 27 0.012 N) 0.014 Nl 0.015 N) 0.015 NI 0.023 (I) 0.013 NI 0.011 (U) 0.012 NI 0.024 0) NT NT NT NT NT Nen2Ohthykne 21.000 300000 2.500 0.014N1 0.016NI 0.017 N) 0.0160.1) 0.018 N1 0.015N1 0.013(U) 0.01401) 0.0250) NT NT NT NT NT Ar8lracere 9 9 0.8 0.011(U) 0.0220) 0.02001 0.015(I) 0.013N1 0.020(1) 0.01101 0.0120) 0.012(I) NT NT NT NT NT 9errmlaWdN4cee 0,1 0.7 8 0.00970.11 0.0180) 0.0140) 0.012(U) 0.011N1 0.014(I) 0.0089N1 0.009E N1 0.0391 N1 NT NT NT NT NT Benrela6PPene tl 8 24 0.010(U) 0.028(I) 0.0210) 001701 0012(U) 0.020(I) 0.0110) 0.010(U) 0.011() NT NT NT NT NT Benm(b)FluoreNhene 2,600 52000 0.0098 N) 0.0150) 0.012 N) 0.012011 0012 N) 0.013(I) 0.00900.11 0.0099 NI 0.009206 NT NT NT NT NT 9enm(9N9a4Mene e e _32.000 24 0.010 N) 0.01201 0.013 N) 0.012011 0012 NI 0.011011 0.0096(U) 0011 NI 0.009808 NT NT NT NT NT Ben0009Fluaanthene 8 e n 0.012 N) 0.010N 0.015(U) 0.015 NI 0.015N1 0.015(I1 0.011(U) 0.01201) 0013(I) NT NT NT NT NT Grosse k e 0.7 0.0090 NI 0.010 N) 0.011 NI 0.011 N) 0.011 NI 00095 N) 0.0082 NI 0.0091 NI 0.0084 (1) NT NT NT NT NT 0B)em0(a h1An5raune 3,200 59,000 1,200 0.013N1 0.0270) 0.0190) 0.015N1 0.020(N 0.014(I) 0.012Ni 0.013 06 0.039 NT NT NT NT NT Flu0mnthene 2,000 33,000 180 0014(U) 0.018 N) 0.017 N) 0.017NI 0.037 (0 0.015(U) 0.0130.) 0.014 N) 0.043 NT NT NT NT NT Rumens 9 8 8.6 0.0089 NI 0.0110) 0.011 NI 0.011 (U) 0.011 N) 0.0095 NI 0.0082 (U) 0.0093 (U) 0.0053 M NT NT NT NT NT Irden0(123c92Py7ene 2200 30000 250 0.013 N) 0.016 (U) 0.015 NI 0.015 (U) 0.083 0.014 NI 0.0121U) 0013 NI 0.099 NT NT NT NT NT PMroMlem Freels 2,400 45,000 BBo 0.012NI 0.02E (I) 0.0190) 0 015(U) 0.024(I) 0014(6 0.011NI 0.012(U) 0.044 NT NT NT NT NT 84P TEFEraMNents 0,1 0.7 0.0 0.0 0.0 0.0 00 0.0 0.0 0.0 0.0 NT NT NT NT NT inn by FL -PRO /mokal TPN Total 480 2700 310 38.1 128 3.6(U) 52.3 /B9 07 4.5 3.0N1 238 NT NT NT NT NT 8290) rIns/Funm by 8da) 0040b900e479, Total 7 30 3000 3.79 11.19 3.23 0,48 1549 442 5.97 1.97 6.84 1.55 NT NT 2458 177.47 Nda: repo • Mlll9nme Der k7opram• raga. •m•0N per Nan n9L9 • nrm4reT• per Sawa,. TCLP• reedy Glummest% l88Wr5 Prace1 BdM 4 • a6M4I resell stated. e6. Re7kbn6el 15 SCTL 9dd• arvMnal recut..seeded the Carmerclel elder leachebeN 6C11. U • Results baba ale Whoreoy mt8o7 detection Omits 1 • The N20400 veers b beeeel Ma womb, them. dtecibn lima and the Nboeby predbd aun6nbn ame NT • Not Teeter( "• Direct Nmasue reue based on ecLte lottery caedaebm ' • le.80bary determined d9 SPLP analysis 9 • Munp9 pvmed8b banm(al WPM not Benzo(a)pyrene Conversion Table 4/30/2019 Benzo(a)pyrene Conversion Table For Direct Exposure Soil Cleanup Target Levels Instructions can be found below the table Facility/Site Name: Melreese Golf Course Site Location: 1802 NW 37th Avenue, Miami, FL 33125 Facility/Site ID No.: TEF = Toxic Equivalency Factor SCTL Type Value Units Residential Direct Exposure SCTL 0.1 mg/kg Industrial Direct Exposure SCTL 0.7 mg/kg Alternative SCTL (Optional) mg/kg Site Specific Background (Optional) mg/kg Soil Sample # TE-1 TE-4 TE-9 TE-14 TE-19 TE-24 TE-24 TE-13 TE-29 Sample Date 3/12/2019 3/12/2019 3/18/2019 3/18/2019 3/18/2019 3/18/2019 3/18/2019 3/13/2019 3/13/2019 Sample Location: Depth(ft): 1.0-2.0 2.0-4.0 2.0-4.0 0.0-2.0 2.0-4.0 0.0-2.0 2.0-4.0 2.0-4.0 0.0-1.0 Contaminant Concentrations Contaminant TEF TE-1 (mg/kg) TE-4 (mg/kg) TE-9 (mg/kg) TE-14 (mg/kg) TE-19 (mg/kg) TE-24 (mg/kg) TE-24 (mg/kg) TE-13 (mg/kg) TE-29 (mg/kg) Benzo(a)pyrene 1.0 0.00485 0.018 0.0055 0.014 0.00455 0.00445 0.0049 0.014 0.006 Benzo(a)anthracene 0.1 0.0055 0.022 0.0065 0.02 0.012 0.011 0.012 0.02 0.015 Benzo(b)fluoranthene 0.1 0.005 0.026 0.006 0.02 0.011 0.011 0.005 0.021 0.017 Benzo(k)fluoranthene 0.01 0.005 0.012 0.006 0.0055 0.0049 0.0048 0.0055 0.0065 0.006 Chrysene 0.001 0.006 0.019 0.0075 0.015 0.013 0.0055 0.006 0.0075 0.0075 Dibenz(a,h)anthracene 1.0 0.0045 0.005 0.0055 0.00475 0.0042 0.0041 0.00455 0.0055 0.0055 Indeno(1,2,3-cd)pyrene 0.1 0.00445 0.011 0.0055 ' 0.00475 0.00415 0.0041 0.0045 0.0055 0.0055 Benzo(a)pyrene Equivalents Contaminant TEF TE-1 (mg/kg) TE-4 (mg/kg) TE-9 (mg/kg) TE-14 (mg/kg) TE-19 (mg/kg) TE-24 (mg/kg) TE-24 (mg/kg) 1 E-13 (mg/kg) TE-29 (mg/kg) Benzo(a)pyrene 1.0 0.0049 0.0180 0.0055 0.0140 0.0046 0.0045 0.0049 0.0140 0.0060 0.0000 Benzo(a)anthracene 0.1 0.0006 0.0022 0.0007 0.0020 0.0012 0.0011 0.0012 0.0020 0.0015 0.0000 Benzo(b)fluoranthene 0.1 0.0005 0.0026 0.0006 0.0020 0.0011 0.0011 0.0005 0.0021 0.0017 0.0000 Benzo(k)fluoranthene 0.01 0.0001 0.0001 0.0001 0.0001 0.0000 0.0000 0.0001 0.0001 0.0001 0.0000 Chrysene 0.001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 Dibenz(a,h)anthracene 1.0 0.0045 0.0050 0.0055 0.0048 0.0042 0.0041 0.0046 0.0055 0.0055 0.0000 Indeno(1,2,3-cd)pyrene 0.1 0.0004 0.0011 0.0006 0.0005 0.0004 0.0004 0.0005 0.0006 0.0006 0.0000 Total Equivalents Total Benzo(a)pyrene Equivalents I 0.0 I 0.0 I 0.0 I 0.0 I 0.0 I 0.0 I 0.0 I 0.0 I 0.0 I 0.0 Comparisons to SCTLs Does This Sample Exceed: TE-1 (mg/kg) TE-4 (mg/kg) TE-9 (mg/kg) TE-14 (mg/kg) TE-19 (mg/kg) TE-24 (mg/kg) TE-24 (mg/kg) TE-13 (mg/kg) TE-29 (mg/kg) The Residential Direct Exposure SCTL of 0.1 mglkg? OK OK OK OK OK OK OK OK OK OK The Industrial Direct Exposure SCTL of 0.7 mglkg? OK OK OK OK OK OK OK OK OK OK No Alternative SCTL Given N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A No Site Specific Background Given N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A Table 4 - BaP TEF Tables (2018-3057)\B(a)p TEQs page ' ' 1 TABLE 5 TEST EXCAVATION DIOXIN)FURAN CONGENER SUMMARY RESULTS MARCH 2O19 MELREESE GOLF COURSE 1802 NW 37TH AVENUE MIAMI, MIAMI-DADE COUNTY, FLORIDA 33126 Congener 2,3,7,8-TCOD 1,2,3,7,8-PeCDD 1,2,3,4,7,8-H%CDD 1,2,3,6,7,8-H%CDD 1,2,3,7,8,9-H%CDD 1,2,3,4,6,7,8-H8000 OCOD 2,3,7,8-TCDF 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCOF 1,2,3,4,7,8-HKCDF 1,2,36,7,8-10CDF 2,3,4,6,7,8-H413F 1,2,3,7,8,9-HzCDF 12,3,4,8,7,8-HPCOF 1,2,3,4,7,8,9-HpCDF OCDF TEF 0.1 0.1 0.1 0.01 0.0001 0.1 0.05 0.5 0.1 0.1 0.1 0.1 0.01 0,01 TEA 11'-2') 0.0001 Total Concentration of DioolnlFuran Congeners • 0.44 0.82 0.88 4.10 2.60 100.00 830.00 0.82 0.38 0.74 0.49 0.53 0.63 0.08 6.10 0.15 13.00 Converted Results' 0.44 0,82 0.088 0.41 0.26 0.083 0.082 0.019 0.37 0.049 0.053 0.063 0.008 0.081 0.00145 0.0013 3.79 TE412'-4') 0.27 1.70 1.90 5.40 3.30 43.00 240.00 2.00 2.10 11.00 3.00 4.90 7.70 1.20 19.00 1.80 15.00 Converted Results' 0.27 1.7 0.19 0.54 0.33 0.43 0.024 02 0.105 5.5 0.3 0.49 0.77 0.12 0.19 0.018 0.0015 11.18 7E0 (2'-4') 1.5 4.6 3.7 14 370 3400 4.3 0.79 1.2 0.91 4.5 1.4 0.12 71 0.375 39 Converted Results' 1,5 4.8 0.37 1.4 1.1 3.7 0.34 0.43 0.0395 0.8 0.091 0.45 0.14 0.012 0.71 0.00375 0.0039 16.49 TE43 (2,41 0.11 0.75 0.80 3.30 1.90 90 690 0.75 0.37 0,81 0.63 0.75 0.78 0.18 7.40 0.45 13.00 Converted Results' 0.105 0.75 0.08 0.33 0.19 0.9 0.069 0.075 0.0185 0.405 0.063 0.075 0.076 0.078 0.074 0.0045 0.0013 3.23 TE-14 (0'-2') 0.35 0.25 1.50 7.20 4.90 190 960 0.45 0.16 0.38 0.45 0.46 0.46 0.07 8.80 0.15 18.00 Converted Results' TE-19 (Z-4') A Converted Results' b 0.35 0.395 0.395 0.25 2,0 0.15 1.8 0.72 7.3 0.49 5.0 1.9 0.096 0.045 0.008 0.18 0.045 0.046 0.048 0.007 0,086 0.0015 0.0018 4.42 190 1200 1.2 0.69 1.0 0.55 1.20 0.95 0.32 5.2 0.81 3 2 0.18 0.73 0.5 1.9 0.12 0.12 0.0345 0.5 0.055 0.12 0.095 0.032 0.052 0.0081 0.0013 6.84 Congener TEF 7E-24 (0'-2') Converted Results' TE-24 (2'-4') Converted Results' 7E-29 (0'-1') Converted Results' 7E41 (2'4') Converted Results' TE-33 (0'-2') Converted Results' TE-33 (2,41 Converted Results' 1 0.18 0.18 0.38 0.38 0.12 0.115 0.09 0.085 1.20 1.2 17.00 17 2,3,7,8-TCDD 1 1.5 1.6 0.225 0.225 0.085 0.065 0.280 0.28 7.100 7.1 43.000 43 1,2,3,7,8-PeCOD 0.1 1.5 0.15 0.38 0.038 0.08 0.0075 0.14 0.0135 8.00 0.8 60.00 6 1,2,3,4,7,0-H%CDD 0.1 5.7 0.57 1.5 0,15 0.5 0.049 1.1 0.11 19.0 1.9 200.0 20 1,2,3,6,7,8-HzCOD 4.3 0.43 1.1 0.11 0.3 0.031 0.7 0.066 13.0 1.3 160.0 16 1,2,3,7,8,9-HzCDD 0.1 0.01 150 1.5 44 0.44 9 0.094 31 0.31 190 1.9 6000 60 1.2,3,4,6,7,8-HPCD0 0.0001 1200 0.12 430 0.043 100 0.01 320 0.032 1100 0.11 69000 6.9 °CDC 0.1 0.97 0.097 0.405 0.0405 0.085 0.0085 0.295 0.0295 4.100 0.41 3.900 0.39 2,3,7,8-TCDF 0.05 0.31 0.0155 0.245 0.01225 0.090 0.0045 0.205 0.01025 5.200 0.28 2.900 0.145 1,2,3,7,8-50007 0.5 1.8 0.8 0.61 0.305 0.07 0.035 0.89 0.345 11.00 5.5 5.80 2.9 2,3,4,7,8-PeCDF 0.1 1.50 0.15 0.48 0.048 0.09 0.009 0.77 0.077 10.00 1 4.10 0.41 1,2,3,4,7,8-HzCDF 0.1 1.40 0.14 0.45 0.045 0.07 0.0065 0.50 0.05 9.60 0.95 2.80 0.28 1,2,3,6,7,8-HzCDF 0.1 1.50 0.15 0.65 0.065 0.07 0.007 0.87 0.087 13.00 1,3 9.70 0.97 2,3,4,8,7,8-HzCDF 0.1 0.11 0.011 0.085 0.0085 0.080 0.008 0.120 0.012 2.800 0.28 1.800 0.18 1,2,3,7,8,9-HzCDF 0.01 14 0.14 5.50 0.055 1.20 0.012 8.20 0.062 52.00 0.52 300.00 3 1,2,3,4,8,7,8-HpCDF 1,1 0.011 0.23 0.0023 0.07 0.0007 0.20 0.002 4,90 0.049 18.00 0.18 1,2,3,4,7,8,9-HpCDF 0.01 0.0001 24 0.0024 1100 0.0011 2.20 0.00022 15.00 0.0015 52.00 0.0052 1100.00 0.11 OCDF Total Concentration of Dlooln/Furan Congeners • 5.97 1.97 0.48 1.55 24.58 17717 SCTL-R • 7 ng/kg SCTLC • 30 ng/kg SCTLL • 3,000 ng/kg Notes: All values given In nanogrems per kilogram (ng/kg) • Compounds that were below laboratory method detection limps were reported as 12 of the method detection limit concentration for assessment of the TEO. SCTLR • Residential 961 Cleanup Target Level SCTL-C • Commercial/industrial Soil Cleanup Target Level SCTLL • Leachability Soil Cleanup Target Level Bold • Analytical result exceeded the Residential SCTL Bold • Analytical result exceeded the Commercial and/or Leachability SCTL TABLE 6 ES/0 SOIL BORING ANALYTICAL RESULTS (ARSEN1C. BARIUM. LEAD) 3ELREESE GOLF COURSE 1002 NW 3TTN AVENUE MIAMI MUJ84DADE COUNTY. FLORMA 33125 PROJECT No.: 20163057 Ale Parameter: CTLC SCTL{ TCVatL 0epe0-941-61153 Anemc I.O210 21 .ream (0wl.) 09e015112591 000 TCLP emc (Oqa) NA TC2Pi.46119 6i1 12 130000 NA NA NA NA NA NA 50 591 25.9 10.8 10.1 NT M 15.5 114 222 NT M 2-A 5.2 61.5 960 M M NT M 117 M M 92 3252019 0.09 12.3 9.3 58 NT fiT 2J 5.0 33 M M 0.92 3.5 65 M NT 52 SS 526 M fiT 592 322219 DO 2.0 MT M 6.T TB 196 M 0e30) 4.4 M NT 265 120 589 .2 145 0071 (U) M 0096(U) M 2-A 522 2510 NT 029 -01 472 175 623 NT 04-2 2.0 163 29 T NT M 2-5 263 586 430 fir M 596 326R019 0-O Ill 2.5 162 NT NT 03-2 -1 O30(U) 052 0) 62 33 82 53 M M NT NT 32262019 12/ 243 174 M NT 226 278 1.560 015 0 12 320 3.000 0 13 59-6 118 23 M NT 152 M M 2.5 26.9 152 520 NT M 32 219 0.05 699 NT M 0.6-Z 14.9 225 636 NT NT x-5 79 138 9910 3202019 0-oar 125 79 NT M 00-2 117 31.5 259 NT NT -t 053 O) 12 9 52 NT 56-11 -0.3 177 8.5 101 NT 8-2 300 42S NT NT 10.0 310 160 M NT 50.7 .3 M NT 282 1.250 NT 5B-12 3O6e219 11.3 10.8 M NT 60 1220 22 M NT 2.5 282 62.1 M NT -6 264 OD0 NT NT 6-] 162 0.020 4.610 0071(U) 03+ 322/2019 0-Db 2.5 13T NT M 04-2 688 110 NT -5 47.0 NT M -6 223 M NT 0.0.5 31.0 25 165 NT M I SD 16s 1.110 NT M 63.0 523 1210 M NT 26 M NT 120 153 85 NT 2-6 124 1. NT 500 714 1.270 M NT 250 .3 618 M NT 56-18 11. 52 M NT 05-2 10A 103 30 M NT -5 327 334 113 M M OA 204 265 M M 6.8 23.3 MIT NT 0-0.6 14.3 92 52 tir M 0A-2 512 142 NT M 2-6 131 699 M 5-6 142 216 LON NT 56-15 3,670 0.04 13.6 132 86 M 0.5-1 123 13T .3 M M 2-1 4.0 20.9 060 M NT 6-6 167 M NT 29.7 278 624 M NT 5015 220 319 195 M NT B2 126 M NT 2.6 126 626 M M 56.20 6071 3.22219 0.0.6 e21 M M 83 NT NT 2.9 -0b 29.5 19.5 212 105 500 120 NT NT M M 161 202 912 2.6 055 661 a-6 124 2911 MT NT 64.0 NT NT 55 3627/2019 124 tiT 073 9.3 NT 30 NT NT 47.7 215 3.180 NT NT 3272019 302 168 NT NT 304 1411 702 NT 128 221 53.3 NT NT NT NT SE 84 3212019 203 66 NT 365 3,610 NT NT 224 226 150 252 NT NT 56,5 3.177/2709 104 92 239 NT NT 27 690 NT 7.1 262 NT NT 69 204 NT NT 56-26 57772016 149 29.0 NT NT 126 NT -11 3.5 34 NT NT 58-27 32712019 72 5.1 NT NT 4.1 NT NT 14.4 NT NT 56.22 1272019 39 229 100 NT 0.2901) 071 69 5.0 NT NT NT NT 85.4 NT 5020 16/2016 27.5 tif 58 NT NT 125 116 NT 14 NT 361 NT NT 56,0 2620. 12.2 NT Mf NT 2. NT NT 4.1 NT NT 56-31 4/041019 NT NT NT 5.1 NT NT NT 192 255 NT NT NT NT 42.019 NT 282 NT 227 NT 5420 NT 12.0 tiT 1.020 NT MT 56-53 NT NT NT lel NT NT NT NT 420 NT NT 26.20/9 NT 490 NT NT 6211 216 NT NT 49.3 NT 7.550 NT 56,5 .42019 NT 63 NT TA NT NT NT 1720 NT NT 56,6 .2019 20.4 NT NT 0.5 1. NT 462 NT NT 19.1 NT 106 NT NT 58.37 .123019 12.0 PiT MT NT 127 NT 224 NT NT 159 NT 4920 NT NT B.- Ana.. 629.1164.661150.462615C11. SC.{ Sol CI.. Tan. LowIC*Erwastra MT. rep.. valmerbetere.1161.129109.8691549.11.6ard fro wan.. hail TABLE 7 EE&G SOIL BORING ANALYTICAL RESULTS MELREESE GOLF COURSE 1802 NW 37TH AVENUE MIAMI, MIAMI-DADE COUNTY, FLORIDA 33125 PROJECT No.: 2018-3057 Sample Designation: 58-1 5B-3 58.4 56-9 SB.12 Date Collected: 3/25/19 3/25/19 3/25/19 3/26119 3126/19 Depth (Feet -BLS): 3.5 - 4.5 0.5-2 0.5-2 2-4 6-7 Cleanup Target Lavoie (SCTLOI TCLP ParameterSolt Residential Commercial/Industrial Leachability Regulatory Level Total Metals by 6010 Ono/km) Arsenic 2.1 12 "' NA NT 6.7 12.0 7.8 152 Barium 120- 130.000 1,600 NA NT 7.8 48.9 129 4,020 Cadmium 82 1,700 7.6 NA NT NT NT 2.2 18.3 Chromium 210 470 38 NA NT NT NT 23.1 78.2 Lead 400 1,400 ^• NA NT 19.6 145 409 4,510 Selenium 440 11,000 5.2 NA NT NT NT 2.1 (U) 63.5 (U) Sliver 410 8,200 17 NA NT NT NT 1.8 7.3 Total Metals by 7471(mp/k0) Mercury 3 17 2.1 NA NT NT NT 0.34 0.42 TCLP Metals by 13/1 (m9/L) Arsenic NA NA NA 5.0 NT NT NT NT 0.071 (U) Lead NA NA NA 5.0 NT NT NT NT 0.34 VOCs by 8260 (mg/kg) MTBE 4.400 24.000 0.009 NA NT NT NT 0.0030(U) NT Benzene 1.2 1.7 0,007 NA NT NT NT 0.0030 (U) NT Toluene 7,500 80,000 0.5 NA NT NT NT 0.0032 (U) NT Ethylbenoone 1.500 9.200 0.8 NA NT NT NT 0.0033 (U) NT Total Xvlenes 130 700 0.2 NA NT NT NT 0.0061 (U) NT Tetrechloroethene (PCE) 8.8 18 0,03 NA NT NT NT 0.011 NT Trlchloroethene (TCE) 6.4 9.3 0.003 NA NT NT NT 0.0033 (U) NT Cie-1,2-Dlchloroethene 33 180 0.4 NA NT NT NT 0.0030(U) NT Trans-1,2-DIchlomethene 53 290 0.7 NA NT NT NT 0.0036(U) NT Vinyl Chloride 0.2 0.8 0.007 NA NT NT NT 0.0032(U) NT l opropylbenzene (IPB) 220 1,200 0.2 NA NT NT NT 0.0034 (U) NT Acetone 11,000 88,000 25 NA NT NT NT 0.083 NT Other VOCs Tested Varies Per Constituent NA NT NT NT (U) NT PAHs by 8270 (m9'k9) Naphthalene 55 300 1.2 NA 0.014 (U) 0,013 (U) 0.013 (U) 0.044 (U) 0.053 (U) 1-Methyl Naphthalene 200 1,800 3.1 NA 0.016 (U) 0.015 (U) 0.015 (U) 0.050 (U) 0.080 (U) 2-Methyl Naphthalene 210 2,100 8.5 NA 0.015(U) 0.015 (U) 0.014(U) 0.049(U) 0.058 (U) Acenaphthene 2,400 20,000 2 NA 0.014 (U) 0.014 (U) 0.013 (V) 0.044 (U) 0.053 (U) Acenaphthylene 1,800 20,000 27 NA 0.012 (U) 0.012 (U) 0.012 (U) 0.040 (U) 0.048 (U) Anthracene 21,000 300,000 2,600 NA 0.014(U) 0.014(U) 0.013(U) 0.046(U) 0.054 (U) Benzo(a)Anthrensne q 0 0.8 NA 0.011 (U) 0.011 (U) 0.014 (1) 0.037 (U) 0.044 (U) Benzo(a)Pyrene 0.1 0.7 6 NA 0.0098 (U) 0.0097 (U) 0.012 (I) 0.032 (U) 0.038 (U) Benzo(b)Fluoranthene 0 0 2.4 NA 0.011 (U) 0.010 (U) 0.020 (I) 0.034 (U) 0.041 (U) Benzo(ghl)Perylene 2,500 52,000 32,000 NA 0.010 (U) 0.0098 (U) 0.0094 (U) 0.032 (U) 0.039 (U) Benzo(k)Flu0renthene p M 24 NA 0.011 (U) 0.010 (U) 0.010 (U) 0.034 (U) 0.041 (U) Chrveene 0 # 77 NA 0.013 (U) 0.012 (U) 0.013 (I) 0.041 (U) 0.049 (U) ie R 0.7 NA 0.0091 (U) 0.0090(U) 0.0086(U) 0.029(U) 0.035(U) Dibenzo(a.h)Anthracene Fluoranthene 3,200 59,000 1.200 NA 0.013 (U) 0.013 (U) 0.017 (I) 0.042 (U) 0.050 (U) Fluorene 2,600 33,000 160 NA 0.014(U) 0.014(U) 0.013(U) 0.048 (U) 0.055 (U) Indeno)123-od)Pyrene # # 6.8 NA 0.0081 (U) 0.0090 (U) 0.0088 O 0.029 (U) 0.035 (U) Phenanthrene 2,200 38.000 250 NA 0.013 (U) 0.013 (U) 0.012 (U) 0.042 (U) 0.050 (U) Pyrene 2,400 45,000 880 NA 0.013 (U) 0.012 (U) 0.016 (I) 0.040 (U) 0.048 (U) FlaPTEF Equivalents 0.1 0.7 NA 0.0 0.0 0.0 0.0 0.0 7PH by FL•PRO frog/kg) TPH. Total 460 2,700 340 NA NT NT NT 222 436 by 8290 Ma/kg) Oloo)oo/Furane Dloslne/Furens, Total 7 30 3,000 NA 75.87 0.72 11.21 7.09 10.40 Chlorineted Pesticides by 8081 (mq/kp) Alddn 0.06 0 0.2 NA NT NT NT 0.00075 (U) NT Chlordane (Technical) 2.8 14 9.6 NA NT NT NT 0.28 NT 4,4'-DDE 2.9 15 16 NA NT NT NT 0.012 (I) NT 4,4'-DDT 2.9 15 11 NA NT NT NT 0.0012 (U) NT Dieldrin 0.06 0 0.002 NA NT NT NT 0.0050(8 NT Other Chlorinated P600641ea Tested Varies Per Constituent NA NT NT NT (U) NT Orpenophosphoroua Pesticides by 8141 (mXkq) All Orgenopho90horous Pesticides Tested Varies Per Constituent NA NT NT NT (U) NT Chlorophenoxy Herbicides by 8151 (mq/k0) All Chlorophenocy Herbicides Tested Varies Per Constituent NA NT NT NT (U) NT Notes: mg/kg • miyreme per kilograms myL • milligrams per Haar ngkg • nenagrems per kb9ams TCLP • Texkey Charcteblk Leaching Preceding Bold • Analysed rearm exceeded the Residential BCTL Bold • Analytical anus exceeded the Car meld ender Leachability SCTL Um Renee below the laboretay method detectbn limes I • The reverted value is between the laboratory method detection IFnll and the leba8oy practical eueni0atice limit NT • Semple net bated for 8dketed manatee • • Direct exposure value bassi on acute bddy considerations • • Leachability adamined vie SPLP anstyeb 4 • Must be converted to benzda)pyrena equivalent Benzo(a)pyrene Conversion Table 4/30/2019 Benzo(a)pyrene Conversion Table For Direct Exposure Soil Cleanup Target Levels Instructions can be found below the table Facility/Site Name: Site Location: Facility/Site ID No.: Melreese Golf Course 1802 NW 37th Avenue, Miami, FL 33125 TEF = Toxic Equivalency Factor SCTL Type Value Units Residential Direct Exposure SCTL 0.1 mg/kg Industrial Direct Exposure SCTL 0.7 mg/kg Alternative SCTL (Optional) mg/kg Site Specific Background (Optional) mg/kg Soil Sample # SB-1 SB-3 SB-4 SB-9 SB-12 Sample Date 3/25/2019 3/25/2019 3/25/2019 3/26/2019 3/26/2019 Sample Location: Depth (ft): 3.5-4.5 0.5-2.0 0.5-2.0 2.0-4.0 6.0-7.0 Contaminant Concentrations Contaminant TEF SB-1 (mg/kg) SB-3 (mg/kg) SB-4 (mg/kg) SB-9 (mg/kg) SB-12 (mg/kg) Benzo(a)pyrene 1.0 0.0049 0.00485 0.012 0.016 0.019 Benzo(a)anthracene 0.1 0.0055 0.0055 0.014 0.0185 0.022 Benzo(b)fluoranthene 0,1 0.0055 0.005 0.02 0.017 0.0205 Benzo(k)fluoranthene 0.01 0.0055 0.005 0.005 0.017 0.0205 Chrysene 0.001 0.0065 0.006 0.013 0.0205 0.0245 Dibenz(a,h)anthracene 1.0 0.00455 0.0045 0.0043 0.0145 0.0175 Indeno(1,2,3-cd)pyrene 0.1 0.00455 0.0045 0.0043 0.0145 0.0175 Benzo(a)pyrene Equivalents Contaminant TEF SB-1 (mg/kg) SB-3 (mg/kg) SB-4 (mg/kg) SB-9 (mg/kg) SB-12 (mg/kg) Benzo(a)pyrene 1.0 0.0049 0.0049 0.0120 0.0160 0.0190 0.0000 0.0000 0.0000 0.0000 0.0000 Benzo(a)anthracene 0.1 0.0006 0.0006 0.0014 0.0019 0.0022 0.0000 0.0000 0.0000 0.0000 0.0000 Benzo(b)fluoranthene 0.1 0.0006 0.0005 0.0020 0.0017 0.0021 0.0000 0.0000 0.0000 0.0000 0.0000 Benzo(k)fluoranthene 0.01 0.0001 0.0001 0.0001 0.0002 0.0002 0.0000 0.0000 0.0000 0.0000 0.0000 Chrysene 0.001 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 Dibenz(a,h)anthracene 1.0 0.0046 0.0045 0.0043 0.0145 0.0175 0.0000 0.0000 0.0000 0.0000 0.0000 Indeno(1,2,3-cd)pyrene 0.1 0.0005 0.0005 0.0004 0.0015 0.0018 0.0000 0.0000 0.0000 0.0000 0.0000 Total Equivalents Total Benzo(a)pyrene Equivalents 1 0.0 I 0.0 I 0.0 I 0.0 I 0.0 I 0.0 I 0.0 I 0.0 I 0.0 I 0.0 Comparisons to SCTLs Does This Sample Exceed: SB-1 (mg/kg) SB-3 (mg/kg) SB-4 (mg/kg) SB-9 (mg/kg) SB-12 (mg/kg) The Residential Direct Exposure SCTL of' OK 0.1 mg/kg? OK OK OK OK OK OK OK OK OK The Industrial Direct Exposure SCTL of 0.7 mg/kg? OK OK OK OK OK OK OK OK OK OK No Alternative SCTL Given N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A No Site Specific Background Given N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A Table 8 - "8G SB BaP TEF Tables (2018-3057)\B(a)p TEQs page' `1 TABLE 9 EE SOIL BORING DIOXIN ANALYTICAL RESULTS MELREESE GOLF COURSE 1802 NW 37TH AVENUE MIAMI, MIAMI-DADE COUNTY, FLORIDA 33125 PROJECT No.: 2018-3057 Congener TEF SB-1 (3.5'-4.5') Converted Results' SB-3 (0.5'-2.0') Converted Results' SB-4 (0.5'-2.0') Converted Results` SB-9 (2.0'-4.0') Converted Results' SB-12 (6.0'-7.0') Converted Results' 2,3,7,8-TCDD 1 3.5 3.5 0.25 0.25 1.4 1.4 0.91 0.91 0.98 0,98 1,2,3,7,8-PeCDD 1 12.00 12 0.21 0.205 3.1 3.1 0.33 0.325 2.70 2.7 1,2,3,4,7,8-HxCDD 0.1 5.50 0.55 0.25 0.0245 2.8 0.28 1.90 0.19 3.00 0.3 1,2,3,6,7,8-HxCDD 0.1 250.00 25 0.25 0,025 11 1.1 9.10 0.91 11.00 1.1 1,2,3,7,8,9-HxCDD 0.1 120.00 12 0.38 0.038 8 0.78 5.80 0.58 8.10 0.81 1,2,3,4,6,7,8-HpCDD 0.01 1200.00 12 3.80 0.038 280 2.8 240 2.4 260 2.6 OCOD 0.0001 6800,00 0.68 20.00 0.002 1900 0.19 1800 0.18 2100 0.21 2,3,7,8-TCDF 0.1 4.20 0.42 0.17 0.017 2.2 0.22 1.50 0.15 2.50 0.25 1,2,3,7,8-PeCDF 0.05 3.00 0.15 0.17 0.00825 0.94 0.047 0.32 0.016 0.22 0.011 2,3,4,7,8-PeCDF 0.5 9.50 4.75 0.09 0.0425 1,6 0.8 1.90 0.95 1.90 0.95 1,2,3,4,7,8-HxCDF 0.1 19.00 1.9 0.18 0.0175 1.40 0.14 0.81 0.081 0.82 0.082 1,2,3,6,7,8-HxCDF 0.1 5.90 0.59 0.17 0.0165 0.9 0.089 1.50 0.15 2.00 0.2 2,3,4,6,7,8-HxCDF 0.1 7,90 0.79 0.12 0.0115 1.1 0.11 1.30 0.13 1.10 0.11 1,2,3,7,8,9-1-1xCDF 0.1 2.70 0.27 0.13 0.013 0.31 0.031 0.17 0.0165 0.10 0.0095 1,2,3,4,6,7,8-HpCDF 0.01 110.00 1.1 0.80 0.008 11 0.11 10.00 0.1 8.00 0.08 1,2,3,4,7.8,9-HpCDF 0,01 15.00 0.15 0.16 0.0016 0.980 0.0098 0.17 0.0017 0.94 0,0094 OCDF 0.0001 210.00 0.021 0.33 0.000033 28 0.0028 23.00 0.0023 16.00 0.0016 Sum Total Concentration of Weighted Dioxin/Furan Congeners = 75.87 0.72 11.21 f' 7.09 10.40 SCTL-R 4.7 nq/kq SCTL-C = 30 ng/kg SCTL-L = 3,000 ng/kg Notes: NI values given in nanograms per kl ogrem (ng/kg) • Compounds that were below laboratory method dectection limits were reported at 1/2 of the method detection limit concentration for assessment of the TEO. SCTL-R = Residential Soli Cleanup Target Level SCTL-C = Commercialllndustrial Soil Cleanup Target Level SCTL-L = Leachability Soil Cleanup Target Level Bold = Analytical result exceeded the Residential SCTL Bold= Analytical result exceeded the Commerdal and/or Leachability SCTL TABLE 10 TCLP ARSENIC & LEAD RESULTS MELREESE GOLF COURSE 1802 NW 37TH AVENUE MIAMI, MIAMI-DADE COUNTY, FLORIDA 33125 PROJECT No.: 2018-3057 Parameter: SCTL-R SCTL-C TCLP-RL Lead (mg/kg) TCLP-Lead (mg/L) 400 NA 1,400 NA NA 5.0 Soil Boring Date Depth (Feet -BLS) SB-4 3/25/2019 0 - 0.5 212 0.046 (U) 2 - 4 2,410 0.29 SB-7 3/26/2019 0.5 - 2 1,560 0.12 2 - 4 3,090 0.13 SB-12 3/26/2019 6 - 7 4,510 0.34 SB-32 4/8/2019 0.5 - 2 5,820 0.17 SB-34 4/8/2019 2 - 4 7,650 0.50 Test Excavation Date Depth (Feet -BLS) TE-1 3/12/2019 1 - 2 105 0.046 (U) TE-4 3/12/2019 2 - 4 181 0.046 (U) TE-9 3/18/2019 2 - 4 361 0.046 (U) TE-13 3/13/2019 2 - 4 202 0.046 (U) TE-14 3/18/2019 0 - 2 120 0.046 (U) Parameter: SCTL-R SCTL-C TCLP-RL Arsenic (mg/kg) TCLP-Arsenic (mg/L) 2.1 NA 12 NA NA 5.0 Soil Boring Date Depth (Feet -BLS) SB-4 SB-7 SB-12 3/25/2019 3/26/2019 3/26/2019 0 - 0.5 156 0.071 (U) 0.5 - 2 275 0.15 6 - 7 152 0.071 (U) Notes: mg/kg = milligrams per kilograms mg/L = milligrams per liter Bold = Analytical result exceeded the Residential SCTL Bold = Analytical result exceeded the Commercial and/or Leachability SCTL SCTL-R = Soil Cleanup Target Level Residential Exposure Limit SCTL-C = Soil Cleanup Target Level Commercial/Industrial Exposure Limit SCTL-L = Soil Cleanup Target Level Leachability Exposure Limit TCLP-RL = Toxicity Characteristic Leaching Procedure Regulatory Level NT = Sample not tested for indicated parameter NA = Not Applicable U = Results below the laboratory method detection limits I = The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit = Direct exposure value based on acute toxicity considerations = Leachability determined via SPLP analysis TABLE11 GROUNDWATER ANALYTICAL RESULTS MELREESE GOLF COURSE 1802 NORTHWEST 3771-1 AVENUE WAIN. MI6MI3360E COUNTY, FLORIDA 33126 306.• 0.60.611 n: MW1 MNa MY. MW4 MW3) MW-6 NW.) PAWS MWa 10W10 MW.)I MW.13 Emu N2M1010 N3M010 IM0010 .6.130 0 L3M1010 NNW. 460010 N3713010 fMR410 WNW. .233010 45/3019 4.2019 aNO01e 4N2010 Om..OrsunO..Yr CYenuP Te5.1.05r NM. At.... 0. 611 60um4 Conan .110n.• TAIIM.W.ev 00101006.1 Antic 0 100 7.106 13.3 AD I.46) 7..1(16 7.106 ].11U) T.INI ].1(0) 31 NI 0.6(1) ].IM 31(U) 601an 2000 i6 300 15 0 441.0 I6M 21 I,D M NI 21 06(U IBN) 617 IBM 0 0001 100 IBM 17I 00111 06.3 I6M bt I.6 NI 16 N1 IBM IA NI Lao 11011 Imo 360 300 3 000 3603 333 1,010 1A00 156 530 3,00 3.630 07.0 04 703 4010 1,750 1610 W 437 CM.. CI... a 103 60 1,W0 711061 Sln.r WO 50 1.OW 002 SMatln 75. 6 Mew. 2 20 Orp- hrOrlm NMbMa Oy MIPPL) 60..0.1 0.060 b 0.20 IA •" 00019M 00049 RD 0400 00010 NI 0004 NI 0.032 0.0010M O3 NI 0.033 00020(0) 0.00 0044038 0.001077) 00010N1 0068 00010N1 JOw01U) 000. NI 0.0019 113 000.0M 000301V) 0.10(0) 0.0319(U) 00(30M 0001011)) 00M01. 0.063 HegrN«04M a0 OM. CNanwea PMIOOMTe..O 0100.) 166ma P. C>954.1 M NI (0) M NI NI (16 M OM Om.n0e7a3pno.a N000.06 Om0131 Owl., 63 03 63 0377 6/1 0.377 NI 0.e10mn PI0M6 Pa0..T.Ms4 14 Wu PM Comment 11 0.202 N) I360)•alq Omm CNenn2.0 C0gmp0.noyy 1•006 da0ylf0f DIOU 70 700 0.7.(U) 21-0 DIN. 360 66 2.000 660 1.01NJ iniEgri------ 01 2.4435 Dlum. 210 36 2,100 360 0.013(13) 0.77006 °Wawrap 7 JD 70 35 a00NI MCPA 4077b MCPP ] 70 70 00 1610043 01 3 06b0) 3A.6T 2A6-. 50 5� Ob6N1 VOC.0y36100g0.) .19E 30 203 W ODB(U 0650) T 400 O30MTor..40 0.30M TwaullIceselnerm TrirMuom.n(TCEI E) 3 70 300 ]00 0.36M 0.27M CI..II47IW07Mmns i7=2101. M MMIM...� 1 1•• Os3M 0.30M Vv.CM.. 1)6One(PSI °100 0.3006 4T0mb1Mrn 73 B.10 10 100 IIII 0.24M ,3,6mmaFNMvero OMmVOC.T.Me. Var. CP00e(4 OM ---- -��----= 0206.0 0,1006 140.1.53114.. 233051).636OM.M 20 24 10 283 200 no 06006 O.040N) Acxu 0 .K.4enndne 2,.00 ,1 0030 N1 0.013N) Pr. M 6.Mg0)30.0 re .10 3 ,93 02 31.000 6 0 A66(u) 0.)01•1012M en0O60.MPe 210 04 2.103 B0 016M 0.10M 66.0(3Flw.rllns CNya. D16r4MM 4.6 0.003 400 0D o036 NI .13OA NA0.055 011074721673 340 360 2400 ma -----\ 0010031 Od.O(I231d1%na 006 210 2.100 . 0.13611 0.10 050 .1.00 Pp.,. 210 2,100 0.aM 0 (0) TPH by FLFNO(m4il . 000 60.030 (.66M Menl• (.. N) 6y 36Af l..) NMa0.n 2.0 26 o,.T OP. 3.0 1.3 N6n400011600v 000D lmPL) NOM1e aN 10.000 100000 N.M.. 1,000 10,g DDIOM m. T4M a Oy6300(0p1) N 3�0 3.a JDB ''••Crm.O•..r b.AP I.yet Ievela a M401I9Nd In CIWA.et.]P 011Fe Flo..AOmINMr.ew Cab (F A. 1 • • Pa provide:In COa1.62A30. F AC. ••• • Or0uro0Mer a4<06 es prr160 In CM..r02.320. FAC.. m1410106 W 1000. 4L • mlao>.m p.r Mar mot • mauoeme pnlllar 606) • 30349961e p.5107 VCC. • VMMII.0r0W 1Can70026 PAN • Pol)udar Arun. N6dlx.6.. TPH • W. Pottle. H14ra:00on WW1 • VMue 43a365 OCTL 6001 • VM00mbb.NADSC (UI•MM . r90I0169a.1. I640M0y.410. 0MnUmll. (0 • MOW. raAN baaenlM I.4tlMay 0.0.134.11016.11..40.1 Umtt (A • Ar1Mykal n.n.e 0.05001 23MayaltlOMO.6110 ease 40 Maim o.en•r.•.na.M•e TABLE 11 OROUNDWATER ANALYTICAL RESULTS MELREESE 001F COURSE 1502 NORTHWEST 37TH AVENUE MIAMI, MWMI-0ADE COUNTY, FLORIDA 33125 SampleOngnnl0n: Del•6empletl: MW4I .2010 6070015 MW38 3/202019 43/2019 MW39 WW1, W.02 .2019 MW 3140019 .M LS76019 SC449 11.0019 1 311712015 508#IW0 .2319 31110010 W 01 N2613019 P.n.. ' 0T•ryel Lew.'l0P Natural0n )04.' Concw931.•` Manic 4.12. 10 2,000 100 4 OW 92.0 15.5 562 7.1(U) 753 71 NI 115 7.15/I 20.5 7.1N 512 7.1N) 41.4 7.1 NI 230 Lealn Alunlru3000 1100 150 40(U) 30.7 N1 48N 46N 30.TN 3046 NI NI tl0NRR! 30.79.7 4ON) 30.7(U) - 46511 30.7(Ul Iron CainC�� lum 300 5 3.000 50 2,510 0.3301) 2.430 SASE 4.000 365 032(20 521 033 N) 256 0.33(U) 295 1,350 03304 1.950 • 205 0 (89 Sher 103 100 t000 LON 1y130 10(1.4 1.7 NI 1.0N 12 N! 10(th 1.2N 1.0NI 11 N) 10N1 1.2 N1 10N) SMenn.n Teo I MOC, 0y 7470(uR41 50 500 664.11 66M 55 N) 5550 (15 ON 5542I 0,1.Nt10.w Pos.. by .0. .9/41 2 20 0.1000 OWN)0.10 N) 0.10(1) 0.10(U) 0.30(30 0140In ..Mo.JWanI 0.00E .2 020 Oi0 0.002301 00369 N) 0001006) 00049N 0.00191U) 0.0019(U) 0.0310130 0.0349(UI 0.40790.) 0..3 (U) 0.0019(38 0,0049(11) 0.03190/1 0.0019 NI 0.003211) 0.034.06 0.00197114 0.01054 0001904 0.014 Nepl•7N8 e0018e MarMarChlorin. PRICIN•T•00 'n1w ••• Par00ti1001 0.035074) NI 000107.7 N 0054 M 0.0030(30 N 0 O05o 0) NI 0.0050(N (10 0000J N1 N) 00050N (N 00050N1 (u) 00 N a0.n00n3ennonl. P5•enW Ov 811t Coal l 0100n 43 83 0.37204 0JT2(10 0.377(10 0.377N) 0.37E 71) 0 377 04 01..to1n Plertle 0.3 IA 3 14 027t(U) 0132(30 Om N) 0252N 0.277(U) 0.282(10 CAMN) 0.262(U) 0.2T2{U_f_ 0.252 N) 02777 02520.4 01. CN0nww Pe.I4.10e41e00 COIam. Roo 14•r8OM•n 005t.t WSJ Wines Nor00 00.9 (J.WNU) - (14617 U) (Jen6'041) (On.. Ul 0w4br1) ILA 24.0 OW. 70 209 i00 2000 0744(UI TO455 0744(L) 1.01N 0.744 NI 1.w N1 0.7. yw(U) 10ON 0yu(ul 1,04 NI 0.TN t0.NOA 1 2.405 1NowN 55 210 5W 2100 D,775(30 0.613(38 C.T25(10 0.013((38 0.TT5N) 0.61301) 0)75(U) 0.510(60 0.175N 031304 0.7750.1) 061304 0.040900 01ro0 35 1 350 TD 0773(V) 0.793(U) - 0.77544 0 795N 0.715721 0.708 N) 0.775(U) 0740(4 0778NI 020504 0.77874 0.795N MCPJ, MCPP 39 O 3} 70 13,111U1 7.15(U) (.13(14 131 715N1) I T(070 1I T.18 NI1.15N1) 1 24.5.7 70 50 700 500 0.543(74 0.845N 0843130 0.615(10 0543 N) 0516 N) 06.3(38 05.61th 054370 0.645N) 0343NI 034570 e0621v(AWLI 010E 2020D 0.51741 0.31(10 051 N) 061(10 0.51(74 05100 2.. BMMew 100 .00 0.20N) 0.33N) 30(30 03300 0.20N 0331(1) 0.30(1) 0.33(U) 030110 0.33(U) 0.30N 033(U) 030(0) 0.41N E11M1.440e Taw%Wnw 30 20 300 0.30N1 2.1(A 0.30(t0 2.I04 0.30N 2.1 N1 0.60(01 2.101) 010(11I 2.1511 - 020(U) 2.1 NI 030(VI 2,1N 750243404Rerc00E) 303 03672) 035(37 0351J_ Oil ILO 035(74 035N 035(U2 TNwlmwSr# RCS) ae120ICNVOtlMe Tr.wt 2-0105ero0rw1• 70 70 300 700 703 0.36(U) 0.27 N) 0.22 N) 0b(3) 027(27 023(0) 0.38 N) 027(U) 0.23(U) 035(3) 027(U) 0231N 0.36(U) 031(U) 023(U) 035(UI 030N1 033(3) 005(V) 027(U) 023(U) Nml CNOtlw 1000211e5ww 0551 018 100 9 OWN) 0,60 74) 0.39(0) 010(1) 0.30 511 0.60 74) 034(U) 0.1005 03404 02000 0.39(u) 0300) 0.29(01 020(0 ACMOn• 134.Tnmen 76,63ne 0300 10 53000 100 3.3(0) 0.24 5.30.4 5301) 3.4(0 5.3N) 5.3(th 6➢10 13674men716•I74n• a...Twbq 10 vs*7r 100 CO0MM9 N) 0.24(U) NI 02444 0141130 (1) 024 NI_ 0.24 N) N) 01441) 0WIN (N 024(U) 01.(IR (09 014(U) 02•(3) N 034(V) 02.1ut (U) P1M Aoy 8270(M20J N•07Y.n 0• r 140 0.29 NI 0291N 0.29 NI 02044 029NA 039(U) 0304.4 144e312N,OW47455e 241/041 50000.2070 25 25 210 250 019 N) 0.55 N) 01.M 066110 064 741 01013 055114 015(10 063(10 015110 0.55101 01504 005114 032740006 A...F0. 20 210 200 2100 0440101 0.030(U) 0043.011 0030011 0.04010 0.030 CU) 0060 701 0030N) 0.040 70) 000 N) 00400J 0030(U) 00.0 0020 Arerwene 9.ZM•9W1yn*2 2.100 .05 21,000 5 004340 54561U) 0043N 056(U/ 00031U1 0.096N SON NI .0051U) 0.0.3 NI 0031(U) O013N) 0.055N) 00.3 N1 0055 NI 00.0(.(0x570 4.000.100... 0.2 005 20 5 012741 0027OA 0.12(14 0027(th 01211.11 0.021N1 01244 4027 N) 0121U1 002E NI 0.12117 002E N) 01241 0021(U) 5.0060I)W7lwe 944/00191000861erc 210 0.3 2160 50 015 N1 0.15 NI 0150/1 0.16(U) 0155/1 0.10N1 0.1400 0.1600 1101111 0154N 0.15104 0.15(U) 015(1)20 0.19(V) a•ywle 018/e(6,8)401Nw.x 48 0.000 WO 0.5 0.028(UI 0.13N1 0.028N 0.13(Ul 0026(10 0.13N) 0.00 )0) 0.13)U1 0 020 NI 0.13411 0 025 NI 0.1310I 0026 N) 0.131UI 000257. Floowe 260 280 3NO 2800 0010(138 0035140 001801) 009544 0915(38 0085N 0016 NI 0 066 NI 0015(0) 0099011 0.018N1 0.0851111 0016117I 0006 NI IrebnM123e06Px«e PMn.111ene 005 210 2(00 0.12(U) 016 N) 0.121.1 016OA 0.1150 015N1 0.12(.1 015I11 0.12(14 019(U) 0.12(0) 015N 0.12 NI 01510I 7701e MN by F1,00 WWI 210 2100 0.032(40 0032NI 0.032(1) 0113E NI 003E NI 00320.1) 003204 X, TM4(C60401 (WOO, 310.t(m0M1t 5000 10000 0.7N) 0.191) 0.TT N1 078110 oTRUI 076N 0791U1 NNn1. W Ay0.N3760678 06 300.0(7 W L) 1.8 25 0,36 OAT ON 3.5 033 1.NNW. NletlewN Nl.11e••N 10000 100200 UMW0029�10 0.03�U_ 0.02601J1_ 0.025(U) 020 NJ e08200)PN1) 020 w i3OW 13,000 0.0251L0 0.025N 0026N 0,026 50O.NSN) 0031N) TOW 30 3.50 2.37 2.64 311 3.32 2.39 355 No. '• F22(d. olowA . . I/n 48MWWin ln Ce•p.r 62.777 of ISFlRd•841/44 n9y COOe(FAl • • As Nwlgtl In CwNM 5482320. 7.4 C. ••• • 00 nOwNe CMR. as own. In Chap. 52.620. F.A.C..,n0MY.tl IN 1003 0NL • m7C11N.m Not Iwr 493 • mI1119.n• )0W p9•L• 023456• pet? I0M VOC•• VMRI4 Ow. 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TAB, 2 GROUNDWATER DIOXIN-FURAN ANALYTICAL RESULTS MELREESE GOLF COURSE 1802 NW 37TH AVENUE MIAMI, MIAMI-DADE COUNTY, FLORIDA 33125 PROJECT No: 2018-3057 MW-3 MW-4 MW-31 MW-39 MW-42 MW-44 SCS-MW-1 SCS-MW-2 Date Sampled 3/26/2019 3/26/2019 3/4/2019 3/4/2019 3/4/2019 3/4/2019 3/4/2019 3/4/2019 Compound TEF Result TEQ Result TEQ Result TEQ Result TEQ Result TEQ Result TEQ Result TEQ Result TEQ 2,3,7,8-TCDD 1 1.3 (U) 0.65 1.3 (U) 0.65 1.7 (U) 0.85 1.8 (U) 0.9 2.5 (U) 1.25 2.3 (U) 1.15 2.0 (U) 1.0 2.5 (U) 1.25 1,2,3,7,8-PeCDD 1 3.4 (U) 1.7 3.2 (U) 1.6 1.7 (U) 0.85 1.4 (U) 0.7 1.9 (U) 0.95 1.9 (U) 0.95 1.6 (U) 0.8 2.1 (U) 1.05 1,2,3,4,7,8-HxCDD 0.1 0.76 (U) 0.038 1.2 (U) 0.06 2.4 (U) 0.12 2.5 (U) 0.125 3.5 (U) 0.175 2.8 (U) 0.14 1.7 (U) 0.085 3.0 (U) 0.15 1,2,3,6,7,8-HxCDD 0.1 2.1 (U) 0.105 1.9 (U) 0.095 2.4 (U) 0.12 2.7 (U) 0.135 4.4 (U) 0.22 3.0 (U) 0.15 2.1 (U) 0.105 2.4 (U) 0.12 1,2,3,7,8,9-HxCDD 0.1 1.4 (U) 0.07 1.9 (U) 0.095 2.7 (U) 0.135 2.9 (U) 0.145 2.4 (U) 0.12 2.5 (U) 0.125 2.1 (U) 0.105 2.8 (U) 0.14 1,2,3,4,6,7,8-HpCDD 0.01 1.6 0.016 1.4 (U) 0.007 4.9 (U) 0.0245 3.1 (U) 0.0155 4.5 (U) 0.0225 3.6 (U) 0.018 3.7 (U) 0.0185 4.6 (U) 0.023 OCDD 0.0001 5.4 0.00054 8.2 0.00082 13 (U) 0.00065 12 (U) 0.0006 17 (U) 0.00085 13 (U) 0.00065 11 (U) 0.00055 12 (U) 0.0006 2,3,7,8-TCDF 0.1 0.91 (U) 0.0455 1.4 (U) 0.07 1.2 (U) 0.06 1.3 (U) 0.065 1.7 (U) 0.085 1.1 (U) 0.055 1.3 (U) 0.065 1.5 (U) 0.075 1,2,3,7,8-PeCDF 0.05 1.8 (U) 0.045 1.7 (U) 0.0425 1.7 (U) 0.0425 1.8 (U) 0.045 1.8 (U) 0.045 1.5 (U) 0.0375 1.4 (U) 0.035 1.8 (U) 0.045 2,3,4,7,8-PeCDF 0.5 1,5 (U) 0.375 1.7 0.85 1.2 (U) 0.3 0.89 (U) 0.2225 1.3 (U) 0.325 1.1 (U) 0.275 1.0 (U) 0.25 1.2 (U) 0.3 1,2,3,4,7,8-HxCDF 0.1 2.4 0.24 0.70 (U) 0.035 1.7 (U) 0.085 1.9 (U) 0.095 2.2 (U) 0.11 2.0 (U) 0.1 2.3 (U) 0.115 2.2 (U) 0.11 1,2,3,6,7,8-HxCDF 0.1 1.4 (U) 0.07 0.98 (U) 0.049 1.5 (U) 0.075 2.1 (U) 0.105 2.0 (U) 0.1 1.8 (U) 0.09 1.8 (U) 0.09 1.8 (U) 0.09 2,3,4,6,7,8-HxCDF 0.1 0.66 (U) 0.033 0.95 (U) 0.0475 1.2 (U) 0.06 2.1 (U) 0.105 2.0 (U) 0.1 1.6 (U) 0.08 1.5 (U) 0.075 2.0 (U) 0.1 1,2,3,7,8,9-HxCDF 0.1 0.53 (U) 0.0265 1.4 (U) 0.07 2.0 (U) 0.1 2.6 (U) 0.13 2.9 (U) 0.145 2.1 (U) 0.105 2.1 (U) 0.105 2.6 (U) 0.13 1,2,3,4,6,7,8-HpCDF 0.01 1.8 (U) 0.009 1.2 (U) 0.006 3.5 (U) 0.0175 3.6 (U) 0.018 5.2 (U) 0.026 3.5 (U) 0.0175 3.2 (U) 0.016 5.1 (U) 0.0255 1,2,3,4,7,8,9-HpCDF 0.01 2.4 (U) 0.012 1.4 (U) 0.007 6.6 (U) 0.033 6.1 (U) 0.0305 7.7 (U) 0.0385 5.6 (U) 0.028 5.1 (U) 0.0255 7.2 (U) 0.036 OCDF 0.0001 3.5 (U) 0.000175 3.0 (U) 0.00015 13 (U) 0.00065 11 (U) 0.00055 15 (U) 0.00075 11 (U) 0.00055 11 (U) 0.00055 14 (U) 0.0007 Total Concentration of Dioxin/Furan Congeners : 3.44 3.68 2.87 2.84 3.71 3.32 2.89 3.65 GCTL = 30 1 NADSC = 3,000 Notes: All results reported in picograms per liter (pg/L) Groundwater Cleanup Target Levels (GCTLs) Regulated Under Chapter 62-777, FAC. * Compounds that were below laboratory method detection limits were reported as 1/2 of the method detection limit concentration for assessment of the TEQ. TEF = Toxicity Equivalent Factor TEQ = Toxicity Equivalent Quotient GCTL = Groundwater Cleanup Target Level NADSC = Natural Attenuation Default Source Concentration U = Below Estimated Detection Limit TABLE 13 WELL DETAIL AND GROUNDWATER ELEVATIONS MELREESE GOLF COURSE 1802 NW 37TH AVENUE MIAMI, MIAMI-DADE COUNTY, FLORIDA 33125 PROJECT No.: 2018-3057 Well Number SCS-MW-1 SCS-MW-2 MW-31 MW-38 MW-39 MW-42 Well Depth 11.77 11.86 12.6 12.38 11.6 12.13 Screen Interval 1.77 to 11.77 1.86 to 11.86 2.6 to 12.6 2.38 to 12.38 1.6 to 11.6 2.13 to 12.13 TOC -0.35 -0.3 -0.5 -0.37 -0.3 -0.15 Date DTW ELEV DTW ELEV DTW ELEV DTW ELEV DTW ELEV DTW ELEV 03/04/19 4.15 3.92 4.08 NM 3.51 4.97 03/26/19 NM NM NM 4.40 NM NM 03/27/19 4.00 NM 3.85 NM NM NM 04/08/19 NM NM NM 3.71 NM NM 04/09/19 3.76 3.44 3.53 3.72 3.02 3.50 Well Number MW-44 MW-1 MW-2 MW-3 MW-4 MW-5 Well Depth 11.88 13 14.69 12.87 12.89 13.05 Screen Interval 1.88 to 11.88 3 to 13 4.69 to 14.69 2.87 to 12.87 2.89 to 12.89 3.05 to 13.05 TOC -0.2 -0.3 -0.28 -0.27 -0.29 -0.35 Date DTW ELEV DTW ELEV DTW ELEV DTW ELEV DTW ELEV DTW ELEV 03/04/19 4.01 NM NM NM NM NM 03/26/19 NM 4.70 6.66 4.58 4.46 4.50 03/27/19 4.00 NM NM NM NM NM 04/08/19 NM NM 6.40 NM NM 4.24 04/09/19 4.53 4.12 6.40 4.25 4.23 4.22 Well Number MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 Wet Depth 13.0 11.92 12.89 12.97 13.6 11.5 Screen Interval 3 to 13 1.92 to 11.92 2.89 to 12.89 2.97 to 12.97 3.6 to 13.6 1.5 to 11.5 TOC -0.2 -0.2 -0.17 -0.27 -0.32 -0.19 Date DTW ELEV DTW ELEV DTW ELEV DTW ELEV DTW ELEV DTW ELEV 03/04/19 NM NM NM NM NM NM 03/26/19 NM NM NM 4.07 NM NM 03/27/19 5.10 3.64 4.30 NM NM NM 04/08/19 NM NM NM 3.73 NM NM 04/09/19 3.61 3.22 4.02 3.76 5.75 3.49 Well Number MW-12 Well Depth 12.35 Screen Interval 2.35 to 12.35 TOC -0.28 Date DTW ELEV 03/04/19 NM 03/26/19 NM 03/27/19 NM 04/08/19 NM 04/09/19 3.3 Notes: All measurements in feet unless otherwise noted NM = Not Measured DTW = Depth to water measurement TOC = Top of well casing measurement ELEV = Elevation = (Top of Casing - Static Depth to Water) TABLE 14 VAPOR WELL OVA/FID FIELD SCREENING RESULTS MELREESE GOLF COURSE 1802 NORTHWEST 37TH AVENUE MIAMI, MIAMI-DADE COUNTY, FLORIDA 33125 PROJECT NO.: 2018-3057 VAPOR WELL DESIGNATION SCREENED INTERVAL (FEET- BLS) Date PARTS PER MILLION (TOTAL) PARTS PER MILLION (WITH CARBON FILTER) PARTS PER MILLION (NET) VW-1 4/2/2019 11.0 1.8 9.2 1 3.5 4/9/2019 22.5 4.1 18.4 VW-2 4/2/2019 "198 NT NT 2 5 4/9/2019 "6,062 (O/R) NT NT VW-3 1 3.5 4/2/2019 1.0 NF 1.0 4/9/2019 <1 NF <1 VW-4 1 3 4/2/2019 <1 NF <1 4/9/2019 <1 NF <1 VW-5 1 3 4/2/2019 NT NT NT 4/9/2019 27.3 2.0 25.3 VW-6 1 3 4/2/2019 <1 NF <1 4/9/2019 1.8 NF 1.8 VW-7 2 7 4/2/2019 *229 NT NT 4/9/2019 "956 NT NT VW-8 1 3 4/2/2019 <1 NF <1 4/9/2019 <1 NF <1 VW-9 I 1- 4 I 4/9/2019 I 599.8 I 448.7 I 151.1 VW-10 I 1- 6 I 4/9/2019 I `1,191 I NT I NT VW-11 I 1- 3 I 4/9/2019 I `1,075 I NT II NT Notes: = Last reading displayed before OVA/FID flame -out. O/R = Over Range NF = Not Charcoal Filtered NT = Not Tested Bold = Result above 10 parts per million action level TABLE 15 VAPOR WELL GAS METER FIELD SCREENING RESULTS MELREESE GOLF COURSE 1802 NORTHWEST 37TH AVENUE MIAMI, MIAMI-DADE COUNTY, FLORIDA 33125 PROJECT NO.: 2018-3057 VAPOR WELL DESIGNATION SCREENED INTERVAL (FEET- BLS) Date *LEL (%) **CH4 (%) **02 (%) *VOC (ppm) VW-1 1 - 3.5 4/2/2019 0.0 0.1 13.7 0.2 4/9/2019 0.0 0.0 19.0 1.0 VW-2 2 5 4/2/2019 >60 (H/A) 14.5 0.2 0.0 4/9/2019 >100 (H/A) 14.3 0.0 0.3 VW-3 1 - 3.5 4/2/2019 2.0 0.2 13.7 0.3 4/9/2019 0.0 0.0 11.5 0.4 VW-4 1 - 3 4/2/2019 0.0 0.2 17.2 0.0 4/9/2019 0.0 0.0 13.0 0.6 VW-5 1 - 3 4/2/2019 4.0 0.3 20.3 0.0 4/9/2019 0.0 0.0 19.8 0.4 VW-6 1 - 3 4/2/2019 0.0 0.1 15.6 0.0 4/9/2019 0.0 0.0 16.7 1.5 VW-7 2 - 7 4/2/2019 >60 (H/A) 4.1 0.9 0.0 4/9/2019 >100 (H/A) 4.1 0.5 0.4 VW-8 1 - 3 4/2/2019 0.0 _ 0.2 1.3 0.0 4/9/2019 0.0 0.0 2.2 1.8 VW-9 I 1- 4 I 4/9/2019 I 0.0 I 0.0 I 20.1 I 0.7 VW-10 I 1- 6 I 4/9/2019 I >100 (H/A) I 3.6 I 0.6 I 0.5 VW-11 I 1- 3 I 4/9/2019 I 15.0 I 0.4 I 0.0 I 0.6 Notes: LEL = Lower Explosive Limit CH4 = Methane 02 = Oxygen VOC = Volatile Organic Compound H/A = High Alarm Equipment: *MultiRae Plus **Landtec GEM EE&G: Site Rehabilitation Plan August 2019 APPENDIX A PROPETY APPRAISER INFORMATION 4/5/2019 Property Search Application - Miami -Dade County OFFICE Of THE PROPERTY APPRAISER Summary Report Property Information Folio: 30-3129-000-0050 Property Address: Owner CITY OF MIAMI-DEPT OF P&D ASSET MANAGEMENT DIVISION Mailing Address 444 SW 2 AVE STE #325 MIAMI, FL 33130-1910 PA Primary Zone 7300 INDUSTRIAL - HEAVY MFG Primary Land Use 8080 VACANT GOVERNMENTAL : VACANT LAND - GOVERNMENTAL Beds / Baths / Half 0/0/0 Floors 0 Living Units 0 Actual Area 0 Sq.Ft Living Area 0 Sq.Ft Adjusted Area 0 Sq.Ft Lot Size 217,800 Sq.Ft Year Built 0 Assessment Information Year 2018 2017 2016 Land Value $3,811,500 $3,811,500 $3,593,700 Building Value $0 $0 $0 XF Value $0 $0 $0 Market Value $3,811,500 $3,811,500 $3,593,700 Assessed Value $3,811,500 $3,811,500 $3,593,700 Benefits Information Benefit Type 2018 2017 2016 Municipal Exemption $3,811,500 $3,811,500 $3,593,700 Note: Not all benefits are applicable to all Taxable Values (i.e County, School Board, City, Regional). Short Legal Description 2953415AC ALL THAT PART OF SE1/4 LYING S OF TAMIAMI CANAL & W OF SAL RY RNV LOT SIZE 217800 SQUARE FEET Generated On : 4/5/2019 Taxable Value Information 2018 2017 2016 County Exemption Value $3,811,500 $3,811,500 $3,593,701 Taxable Value $0 $0 $0 School Board Exemption Value $3,811,500 $3,811,500 $3,593,700 Taxable Value $0 $0 $0 City Exemption Value $0 $0 $0 Taxable Value $0 $0 $0 Regional Exemption Value $3,811,500 $3,811,500 $3,593,700 Taxable Value $0 $0 $0 Sales Information Previous Sale Price OR Book -Page Qualification Description The Office of the Property Appraiser is continually editing and updating the tax roll. This website may not reflect the most current information on record. The Property Appraiser and Miami -Dade County assumes no liability, see full disclaimer and User Agreement at http://www.miamidade.gov/info/disclaimer.asp Version: 4/5/2019 Property Search Application - Miami -Dade County OFFICE OF THE PROPERTY APPRAISER Detailed Report Property Information Folio: 01-3132-000-0080 Property Address: 1400 NW 37 AVE Miami, FL 33125-1738 Owner CITY OF MIAMI-DEPT OF P&D ASSET MANAGEMENT DIVISION Mailing Address 444 SW 2 AVE STE #325 MIAMI, FL 33130-1910 PA Primary Zone 8002 PARKS & RECREATION Primary Land Use 8940 MUNICIPAL : MUNICIPAL Beds / Baths / Half 0/0/0 Floors 1 Living Units 0 Actual Area 7,789 Sq.Ft Living Area 7,789 Sq.Ft Adjusted Area 7,789 Sq.Ft Lot Size 5,677,174.8 Sq.Ft Year Built Multiple (See Building Info.) ssessment Information Year 2018 2017 2016 Land Value $2,345,940 $2,345,940 $2,345,940 Building Value $176,363 $177,716 $170,542 XF Value $0 $0 $0 Market Value $2,522,303 $2,523,656 $2,516,482 Assessed Value $2,522,303 $2,523,656 $2,516,482 Benefits Information Benefit Type 2018 2017 2016 Municipal Exemption $2,522,303 $2,523,656 $2,516,482 Note: Not all benefits are applicable to all Taxable Values (i.e. County, School Board, City, Regional). Generated On : 4/5/2019 Taxable Value Information 2018 2017 2016 County Exemption Value $2,522,303 $2,523,656 $2,516,482 Taxable Value $0 $0 $0 School Board Exemption Value $2,522,303 $2,523,656 $2,516,482 Taxable Value $0 $0 $0 City Exemption Value $2,522,303 $2,523,656 $2,516,482 Taxable Value $0 $0 $0 Regional Exemption Value $2,522,303 $2,523,656 $2,516,482 Taxable Value $0 $0 $0 The Office of the Property Appraiser is continually editing and updating the tax roll. This website may not reflect the most current information on record. The Property Appraiser and Miami -Dade County assumes no liability, see full disclaimer and User Agreement at http://www.miamidade.gov/info/disclaimer.asp Version: 4/5/2019 OFFICE OF THE PROPERTY APPRAISER Property Search Application - Miami -Dade County . Detailed Report Property Information Folio: 01-3132-000-0090 Property Address: 1550 NW 37 AVE Miami, FL 33125-1740 Owner CITY OF MIAMI-DEPT OF P&D ASSET MANAGEMENT DIVISION Mailing Address 444 SW 2 AVE STE #325 MIAMI, FL 33130-1910 PA Primary Zone 8002 PARKS & RECREATION Primary Land Use 8940 MUNICIPAL : MUNICIPAL Beds / Baths / Half 0/0/0 Floors 1 Living Units 0 Actual Area Sq.Ft Living Area Sq.Ft Adjusted Area 39,726 Sq.Ft Lot Size 2,109,175.2 Sq.Ft Year Built Multiple (See Building Info.) Assessment Information Year 2018 2017 2016 Land Value $871,560 $827,982 $827,982 Building Value $3,133,825 $3,167,499 $3,048,737 XF Value $1,825,256 $1,845,013 $1,864,772 Market Value $5,830,641 $5,840,494 $5,741,491 Assessed Value $5,830,641 $5,813,626 $5,285,115 Benefits Information Benefit Type 2018 2017 2016 Non -Homestead Cap Assessment Reduction $26,868 $456,376 Municipal Exemption $5,830,641 $5,813,626 $5,285,115 Note: Not all benefits are applicable to all Taxable Values (i.e. County, School Board, City, Regional). Generated On : 4/5/2019 N:W 200*7H+.rST+ ems• , �t ' .yx-' • • N:W 1,1,9",T441 TTE'R .,r•n N W LC7aT,M Sy N W +1+61T H T NMJ�i1�6 T H -Al 1-5`TH_,ST Agoeste �N Wi�1iT. rts 7e - - � • T L'SC�T• Taxable Value Information 2018 2017 2016 County Exemption Value $5,830,641 $5,813,626 $5,285,11d Taxable Value $0 $0 $0 School Board Exemption Value $5,830,641 $5,840,494 $5,741,491 Taxable Value $0 $0 $0 City Exemption Value $5,830,641 $5,813,626 $5,285,115 Taxable Value $0 $0 $0 Regional Exemption Value $5,830,641 $5,813,626 $5,285,115 Taxable Value $0 $0 $0 The Office of the Property Appraiser is continually editing and updating the tax roll. This website may not reflect the most current information on record. The Property Appraiser and Miami -Dade County assumes no liability, see full disclaimer and User Agreement at http://www.miamidade.gov/info/disclaimer.asp Version: 4/5/2019 Property Search Application - Miami -Dade County OFFICE OF THE PROPERTY APPRAISER Summary Report Property Information Folio: 30-3129-000-0160 Property Address: Owner CITY OF MIAMI-DEPT OF P&D ASSET MANAGEMENT DIVISION Mailing Address 444 SW 2 AVE STE #325 MIAMI, FL 33130-1910 PA Primary Zone 8900 INTERIM -AWAIT SPECIFIC ZO Primary Land Use 8080 VACANT GOVERNMENTAL : VACANT LAND - GOVERNMENTAL Beds / Baths / Half 0/0/0 Floors 0 Living Units 0 Actual Area 0 Sq.Ft Living Area 0 Sq.Ft Adjusted Area 0 Sq.Ft Lot Size 87,120 Sq.Ft Year Built 0 ssessment Information Year 2018 2017 2016 Land Value $871,200 $871,200 $871,200 Building Value $0 $0 $0 XF Value $0 $0 $0 Market Value $871,200 $871,200 $871,200 Assessed Value $871,200 $871,200 $871,200 Benefits Information Benefit Type 2018 2017 2016 Municipal Exemption $871,200 $871,200 $871,200 Note: Not all benefits are applicable to all Taxable Values (i.e. County, School Board, City, Regional). Short Legal Description 29 53 41 2 AC THAT PART OF SE1/4 OF SE1/4 OF SE1/4 LYING S OF CENTER LINE OF TAMIAMI CANAL LOT SIZE 87120 SQUARE FEET Generated On : 4/5/2019 Taxable Value Information 2018 2017 2016 County Exemption Value $871,200 $871,200 $871,200 Taxable Value $0 $0 $0 School Board Exemption Value $871,200 $871,200 $871,200 Taxable Value $0 $0 $0 City Exemption Value $0 $0 $0 Taxable Value $0 $0 $0 Regional Exemption Value $871,200 $871,200 $871,200 Taxable Value $0 $0 $0 Sales Information Previous Sale Price OR Book -Page Qualification Description The Office of the Property Appraiser is continually editing and updating the tax roll. This website may not reflect the most current information on record. The Property Appraiser and Miami -Dade County assumes no liability, see full disclaimer and User Agreement at http://www.miamidade.gov/info/disclaimer.asp Version: EE&G: Site Rehabilitation Plan August 2019 APPENDIX B HISTORICAL & REGULATORY EXCERPTS M IAM I -DADS COUNTY Carlos A. Gimenez, Mayor March 20, 2019 Department of Regulatory and Economic Resources Environmental Resources Management 701 NW 1st Court, 4th Floor Miami, Florida 33136-3912 T 305-372-6700 F 305-372-6982 CERTIFIED MAIL NO. 7014 1200 0002 0826 9220 RETURN RECEIPT REQUESTED miamidade.gov Emilio T. Gonzalez, City Manager City of Miami 444 Southwest 2"d Avenue Miami, Florida 331300 Re: Response to March 5. 2018 DERM letter dated November 30, 2018 and Quarterly Groundwater Monitoring Report dated December 13, 2018 and prepared by E-Sciences for the Grapeland Heights Park (HWR-594/File-9442) located at, near, or in the vicinity of 1550 NW 37 Avenue, Miami, Miami -Dade County , Florida. Dear Mr. Gonzalez: The Department of Regulatory and Economic Resources -Division of Environmental Resources Management (DERM) has reviewed the above -referenced documents received December 3 and December 18, 2018, respectively. The following comments are provided: 1 Previous Engineering Control inspection reports for several of the other City of Miami Parks documented damage to the bonded rubber mulch (BRM). which provides the EC for portions of those sites. In some instances, the BRM layer is no longer present. Additionally, at several locations the BRM was compromised by growing tree roots. Based on these observation, DERM requires the City to re-evaluate the use of the BRM and to propose an alternate or modified EC for existing areas with BRM at the Grapeland Park; or to submit a modified EC Maintenance Plan which will ensure that the BRM can and will be adequately maintained. Please provide for a current inspection of the Areas 1-7 and Area 9 locations at Grapeland Park where BRM was previously installed. Additional corrective action will be required if this product has not been maintained in the approved installation condition. Furthermore and based on the above, DERM cannot accept the proposal for the use of BRM in the additional areas proposed in the report pending the requirements stipulated above being addressed and approved. Be advised that the previously proposed use of 1' of clean fill on top of a high visibility geotextile fabric is an acceptable option. 2. For any area beyond the property boundary where an engineering control is required or where the institutional control must extend, the receiving entity (i.e. Miami Dade Expressway Authority) must accept the condition of the property and the installation and maintenance of any required engineering control. The report indicates that the City of Miami has already been in contact with and has coordinated this effort and installation of the engineering control. Please provide the documentation and details of this agreement along with a timeline for implementation. Please note that the engineering control area extends to the off -site delineating soil borings, not just the small strip of open ground abutting the fence area. In addition, DERM is copying Claudio Diaferia with MDX who was notified of the pending issues pertaining to the NW 14 Street pending issues. L�taGIV Y� rExce-ilcxce i y j 1rr-��J4,y Mr. Gonzalez HWR-594/AW-284 March 20, 2019 Page 2 of 2 3 Provide details and photographs of the existing shrubs to determine if they will provide an adequate engineering control for a portion of the site. Please provide an update to your Figure 4 proposed EC area so that it depicts the location and boundary of each type of engineering control being proposed. Please ensure that the report encompasses all of the remaining proposed or existing engineering controls (i.e. also extending to the off -site delineating borings to the south, etc.) 5. Complete one additional quarterly sampling event for groundwater. Upon receipt of the results, an evaluation can be made if groundwater sampling can be discontinued or the frequency reduced. DERM has the option to split any samples deemed necessary with the consultant or laboratory at the subject site. The consultant collecting the samples shall perform field sampling work in accordance with the Standard Operating Procedures provided in Chapter 62-160, Florida Administrative Code (FAC), as amended. The laboratory analyzing the samples shall perform laboratory analyses pursuant to the National Environmental Laboratory Accreditation Program (NELAP) certification requirements. If the data submitted exhibits a substantial variance from DERM split sample analysis, a complete resampling using two independent certified laboratories will be required. DERM shall be notified in writing a minimum of three (3) working days prior to the implementation of any sampling or field activities. Email notifications shall be directed to DERMPCD@miamidade.gov. Please include the DERM file number on all correspondence. Therefore, within sixty (60) days of receipt of this letter, you are hereby required to submit to DERM for review the next report addressing the above comments. Failure to adhere to the items and timeframes stipulated above may result in enforcement action for this site. Any person aggrieved by any action or decision of the DERM Director may appeal said action or decision to the Environmental Quality Control Board (EQCB) by filing a written notice of appeal along with submittal of the applicable fee, to the Code Coordination and Public Hearings Section of DERM within fifteen (15) days of the date of the action or decision by DERM. If you have any questions concerning the above, please contact Thomas Kux, .P.G., (kuxt@miamidade.gov) of DERM at (305) 372-6700. Sincerely, Wilbur Mayorga, P.E., Chief Environmental Monitoring & Restoration Division TK pc: Nadia Locke, P.E., ESciences, nlocke(c�esciencesinc.com Keith Ng, City of Miami, KeithNq@miamigov.com Claudio Diaferia, MDX, CDiaferia(a mdxway.com M IAM I•DADE COUNTY Carlos A. Gimenez, Mayor June 13, 2017 CERTIFIED MAIL NO. 7014 1200 0002 0826 2306 RETURN RECEIPT REQUESTED Daniel J. Alfonso, City Manager City of Miami 444 Southwest 2nd Avenue Miami, Florida 331300 Department of Regulatory and Economic Resources Environmental Resources Management 701 NW 1st Court, 4th Floor Miami, Florida 33136-3912 T 305-372-6700 F 305-372-6982 miamidade.gov Re: Quarterly Sampling Report (QSR) dated March 20, 2017 and prepared by AECOM for the Grapeland Heights Park and Melreese Golf Course (HWR-594/AW-284/File-9442) located at, near, or in the vicinity of 1550 NW 37 Avenue, Miami, Miami -Dade County, Florida. Dear Mr. Alfonso: The Department of Regulatory and Economic Resources -Division of Environmental Resources Management (DERM) has reviewed the above -referenced document received April 11, 2017. The following comments are provided: 1. The groundwater monitoring program may be amended to only require sampling and analyzing MW-A, MW-B, MW-9R and the irrigation well for Arsenic. 2. As previously elected, the Melreese groundwater monitoring program has been discontinued as both the Melrese and Grapeland Park sites will be addressed under a single No Further Action with Conditions. 3. Be advised that the following reports are past due for this site: • The Interim Monthly Engineering Control Inspection Reports. • The report addressing the southern and off -site contamination impacts from the Grapeland Park site as required per the August 22, 2016 DERM letter. DERM has the option to split any samples deemed necessary with the consultant or laboratory at the subject site. The consultant collecting the samples shall perform field sampling work in accordance with the Standard Operating Procedures provided in Chapter 62-160, Florida Administrative Code (FAC), as amended. The laboratory analyzing the samples shall perform laboratory analyses pursuant to the National Environmental Laboratory Accreditation Program (NELAP) certification requirements. If the data submitted exhibits a substantial variance from DERM split sample analysis, a complete resampling using two independent certified laboratories will be required. DERM shall be notified in writing a minimum of three (3) working days prior to the implementation of any sampling or field activities. Email notifications shall be directed to DERMPCD@miamidade.gov. Please include the DERM file number on all correspondence. tIF1`e'1 '/M Excellexce- Ever 25aEy Mr. Alfonso HWR-594 June 13, 2017 Page 2 of 2 Therefore, within ninety (90) days of receipt of this letter, you are hereby required to submit to DERM for review the next QSR and prepared in accordance with Chapter 24, Code of Miami -Dade County. Failure to adhere to the items and timeframes stipulated above may result in enforcement action for this site. Any person aggrieved by any action or decision of the DERM Director may appeal said action or decision to the Environmental Quality Control Board (EQCB) by filing a written notice of appeal along with submittal of the applicable fee, to the Code Coordination and Public Hearings Section of DERM within fifteen (15) days of the date of the action or decision by DERM. If you have any questions concerning the above, please contact Thomas Kux, P.G., (kuxt@miamidade.gov) of DERM at (305) 372-6700. Wilbur Mayorga, P.E., Chief Environmental Monitoring & Restoration Division TK pc: Harry James, City of Miami, hjames(c�miamigov.com Steve Starke, P.G., AECOM, Steve.Starke@aecom.com ,H IAM I•DADE COUNTY Carlos A. Gimenez, Mayor December 8, 2015 Department of Regulatory and Economic Resources Environmental Resources Management 701 NW 1st Court, 4th Floor Miami, Florida 33136-3912 T 305-372-6700 F 305-372-6982 CERTIFIED MAIL NO. 7013 2630 0001 2416 1757 RETURN RECEIPT REQUESTED Daniel J. Alfonso, City Manager City of Miami 444 Southwest 2nd Avenue Miami, Florida 331300 miamidade.gov Re: Response to June 15, 2015 DERM Review Letter dated September 22, 2015 and updated on November 24, 2015 and prepared by SCS Engineers for the Melreese Golf Course (AW- 284/File-9442) located at, near, or in the vicinity of 1550/1802 NW 37 Avenue, Miami -Dade County, Florida. Dear Mr. Alfonso: The Department of Regulatory and Economic Resources- Division of Environmental Resources Management (DERM) has reviewed the above referenced reports, received October 16, 2015 and November 24, 2015, respectively. The Engineering Control Plan is hereby approved. Therefore, implement the approved engineering control inspection and monitoring program and continue with the required groundwater monitoring plan. Failure to adhere to the items and timeframes stipulated above may result in enforcement action for this site. If you have any questions concerning the above, please contact Thomas Kux, P.G., at (305) 372-6700. Sincerely, Wilbur Mayorga, P.E., Chief Environmental Monitoring and Restoration Division WM/tk ec: Jeovanny Rodriguez, City of Miami, jeovannyrodriquez(a�miamigov.com Eduardo Smith, P.E., SCS, ESmithascsengineers.com MIAMI•DADE COUNTY Carlos A. Gimenez, Mayor May 31, 2016 CERTIFIED MAIL NO. 7013 2630 0001 2416 8800 RETURN RECEIPT REQUESTED Daniel J. Alfonso, City Manager City of Miami 444 Southwest 2nd Avenue Miami, Florida 33130 Department of Regulatory and Economic Resources Environmental Resources Management 701 NW 1st Court, 4th Floor Miami, Florida 33136-3912 T 305-372-6700 F 305-372-6982 miamidade.gov Re: Fifth Quarterly Groundwater Monitoring Report in Support of No Further Action with Conditions (NFAC) dated April 1, 2016 and prepared by SCS Engineers for the Melreese Golf Course (AW- 284/File-9442) located at, near, or in the vicinity of 1550/1802 NW 37 Avenue, Miami -Dade County, Florida. Dear Mr. Alfonso: The Department of Regulatory and Economic Resources- Division of Environmental Resources Management (DERM) has reviewed the above referenced report, April 4, 2016. The following comments are provided: 1. The Grapeland Park site and the Melreese Golf Course are both impacted with groundwater concentrations above applicable cleanup target levels (CTLs). Since both sites are abutting and are under the same ownership, please advise if you intend to obtain separate individual closures, each requiring separate deed restrictions for groundwater and soil impacts. Please note that part of the Grapeland Park site and Melreese Golf Course share the same folio in a North -South direction. Furthermore, if you intend to separate the sites, it will be necessary to establish the current east/west boundary condition. Therefore, obtain a current groundwater sample for arsenic from MW-33, MW-34, MW-35, and MW-36. 2. In response to the request to incorporate MW-31 into the Grapeland Park monitoring program, be advised that MW-32R to the north of MW-31 has already established the northern boundary of the plume. Based on the groundwater data provided, it does not appear that MW-31 will achieve levels below groundwater CTLs and will not be incorporated into the monitoring program as it is not a plume boundary well. 3. Please refer to the RBCA 7F Guidance document on the conditional closure process which may be found at the following website: http://www.miamidade.gov/environment/pollution-remediation.asp DERM has the option to split any samples deemed necessary with the consultant or laboratory at the subject site. The consultant collecting the samples shall perform field sampling work in accordance with the Standard Operating Procedures provided in Chapter 62-160, Florida Administrative Code (FAC), as amended. The laboratory analyzing the samples shall perform laboratory analyses pursuant to the National Environmental Laboratory Accreditation Program (NELAP) certification requirements. If the data submitted exhibits a substantial variance from DERM split sample analysis, a complete resampling using two independent certified laboratories will be required. ., / . f- ri Mr. Alfonso May 31, 2016 AW-284 Page2of2 DERM shall be notified in writing a minimum of three (3) working days prior to the implementation of any sampling or field activities. Email notifications shall be directed to DERMPCD@miamidade.gov. Please include the DERM file number on all correspondence. Therefore, within sixty (60) days upon receipt of this letter, submit to DERM the appropriate report addressing the above comments. Failure to adhere to the items and timeframes stipulated above may result in enforcement action for this site. If you have any questions concerning the above, please contact Thomas Kux, P.G., at (305) 372-6700. Sincerely, Wilbur Mayorga, P.E., Chief Environmental Monitoring and Restoration Division WM/tk ec: John Andersen — DERM Jeovanny Rodriguez, City of Miami, ieovannyrodriquezc miamigov.com Maria Giudici, P.G., SCS, MGiudici@scsengineers.com MIAMI•QADE COUNTY Carlos A. Gimenez, Mayor June 15, 2015 CERTIFIED MAIL NO. 7013 2630 0001 2419 5929 RETURN RECEIPT REQUESTED Alice Bravo, Deputy City Manager City of Miami 444 Southwest 2nd Avenue Miami, Florida 33130 Department of Regulatory and Economic Resources Environmental Resources Management 701 NW 1st Court, 4th Floor Miami, Florida 33136-3912 T 305-372-6700 F 305-372-6982 miamidade.gov Re: Response to DERM May 30 and November 7, 2014 Review Letters dated March 26, 2015 and Second Quarterly Groundwater Monitoring Report dated June 9, 2015 and prepared by SCS Engineers for the Melreese Golf Course (AW-284/File-9442) located at, near, or in the vicinity of 1550/1802 NW 37 Avenue, Miami -Dade County, Florida. Dear Ms. Bravo: The Department of Regulatory and Economic Resources- Division of Environmental Resources Management (DERM) has reviewed the above referenced reports, received March 30, 2015 and June 11, 2015, respectively, and offers the following comments in the same order as presented in the report: 1. DERM will accept the response provided that a Certified Golf Course Superintendent certifies that the required cover of 2 feet of clean fill is in place on all of the greens and shall include the date the fill was placed and that is was completed for all greens. Please note that the current response in the report is specific to only the SCS-14 location. 2. Based on an Inspection conducted by DERM on June 8, 2015, the engineering control in place for the sand traps is approved. Regarding the waste bunkers. Be advised that an approved engineering control is also required for these former areas unless it can be demonstrated that a sufficient cover of 1- foot of clean fill is present and subject to approval based on an inspection verifying the thickness. The grass cover alone is insufficient. You have the option of installing representative soil borings throughout each of the former waste bunkers to establish the depth to solid waste for determining the appropriate remedy, as applicable. 3. DERM acknowledges the use of standard mulch along with the proposed inspection frequency and daily replenishment in the tree areas. 4. DERM will accept a more focused and increased frequency of inspection for the areas identified as not having the minimum 1-foot of cover. However, the engineering control plan and report logs shall clearly identify the boundary of these areas as extending to the next soil boring in each direction that has the minimum of 1-foot of required clean fill cover. Any exposed solid waste shall be immediately removed and disposed. If frequent surface exposure of solid waste is noted during the inspections, DERM will require additional fill cover for these areas. Ms Bravo June 15, 2014 AW-284 Page 2 of 2 5. DERM acknowledges receipt of the groundwater sampling results. Continue with the approved groundwater sampling plan in accordance with the November 7, 2014 DERM approval. However, please include scaled site diagrams and also depicting the entire sampling area in future groundwater sampling reports. The site diagrams shall be consistent with those presented in Figure 4 of the Response to DERM Review Letters report. 6. DERM concurs with the proposal to submit a Site -Specific Work Plan to address sub -surface work on an as -needed basis throughout the golf course. DERM has the option to split any samples deemed necessary with the consultant or laboratory at the subject site. The consultant collecting the samples shall perform field sampling work in accordance with the Standard Operating Procedures provided in Chapter 62-160, Florida Administrative Code (FAC), as amended. The laboratory analyzing the samples shall perform laboratory analyses pursuant to the National Environmental Laboratory Accreditation Program (NELAP) certification requirements. If the data submitted exhibits a substantial variance from DERM split sample analysis, a complete resampling using two independent certified laboratories will be required. DERM shall be notified in writing a minimum of three (3) working days prior to the implementation of any sampling or field activities. Email notifications shall be directed to DERMPCD@miamidade.gov. Please include the DERM file number on all correspondence. Therefore, within sixty (60) days of receipt of this letter, you are hereby required to submit to DERM for review two copies of a supplemental report, one paper and one electronic PDF on CD, prepared in accordance with Section 24-44(2)(j)(iv), Code of Miami -Dade County, which shall address the above comments as applicable. A review fee of $675 shall be included with the submittal. Failure to adhere to the items and timeframes stipulated above may result in enforcement action for this site. If you have any questions concerning the above, please contact Thomas Kux, P.G., at (305) 372-6700. Sincerely, Wilbur Mayorga, P.E., Chief Environmental Monitoring and Restoration Division WM/tk ec: Jose Gonzalez, P.E. — DERM Donna Gordon — DERM Jeovanny Rodriguez, City of Miami, ieovannvrodriquezamiamigov.com Eduardo Smith, P.E., SCS, ESmithascsengineers.com Environmental Consultants and Contractors 7700 N. Kendall Drive Suite 300 Miami, FL 33156 305 412-8185 FAX 305 412-8105 www.scsengineers.com SCS ENGINEERS April 1, 2016 File No. 09213010.65 Mr. Wilbur Mayorga, P.E., Chief Department of Regulatory and Economic Resources Division of Environmental Resources Management 701 Northwest 1st Court, 4th Floor Miami, Florida 33136 Re: Melreese Golf Course (AW-284/File-9442) 1802 NW 37th Avenue Miami, Florida Subject: Fifth Quarterly Groundwater Monitoring Report Dear Mr. Mayorga: RECEIVED April 4, 2016 DLRM SCS Engineers (SCS), on behalf of the City of Miami (the City), submits this Fifth Quarterly Groundwater Monitoring Report (GMR) for the above referenced site (the Site) in response to the December 17, 2015 Department of Regulatory and Economic Resources, Division of Environmental Resource Management (DERM) correspondence (attached). Quarterly groundwater sampling activities are conducted in accordance with the DERM approved Monitoring Only Plan (MOP) dated November 7, 2014. A site location map is provided as Figure 1. The December 17, 2015 DERM correspondence requested groundwater samples from monitoring wells MW-1 and MW-42 however based on the Fourth Quarter Groundwater Sampling Report submitted by SCS on December 2, 2015, MW-1 reported three consecutive quarters of arsenic concentrations below the Groundwater Cleanup Target Level (GCTL) so an additional sampling event did not appear warranted. However, it was recommended by SCS that an additional quarter of sampling be conducted for MW-31 and MW-42, which is described below. GROUNDWATER QUALITY ASSESSMENT GROUNDWATER ELEVATION A Site Plan depicting onsite monitoring wells is included as Figure 2. On February 15, 2016, SCS recorded depth -to -water (DTW) measurements from onsite monitoring wells to determine groundwater elevation. Monitoring well construction details, top -of -casing (TOC) elevation data and depth to water measurements are summarized in Table 1. Groundwater elevations are provided on Figure 3. Offices Nationwide 0 5/0t/]005 3 DAT 5/5n000 up MIS /090 015 U 8/0P/2000 GRAPELAND PARK (NOT PART OF THIS PROJECT) 5/11n01 0/It/;015 59 5/19/2015 11/12/9015 02/15/90 MELREESE GOLF COURSE 5/02 ON 58 64 105 121 5/05/}OW ElleliESEEMIZEI Res Iry NMI 121:31=1.4 MEW "dinarliiii" r.R.,,�� r' r®�IMEW- " / cogl 2. ®` • , t ECEIP 1322:111111111.- S ®© nm/w05 6/25/®®w Auszasimiscie y�L�p� I cEmou , t 0®' ..v.r . ti • id D/YI�' I111:111®• • ' IIO® =0® 40 L. 9 (4,1(Mira i.A YI . �,.ERECIEEMI,.0- '. 9/0/5000 OAT"» 5/15nW9 5/Ina09 5/00n009 10/8/2009 4/12/2010 a1U N5 +/n/SulO 1 5/79/5015 .1 n21/201, /. /1021 0/0/2000 O',Sn009 1/5W9 5n0n009 0/8/2000 s19n009 /0015 +/v/m10 S/29/f015 Lin/500, a 0/15n000 +55 U 7/30/2009 +/19/1010 5/27/2010 5n0/2015 9n1/5015 12/3/2015 DAIf //15/7005 0 /Sn006 //10/IDS 1/1/5009 1/00/0009 10/5/5009 1/19/9010 1/}9/2015 51n015 Ir/,/]n15 92 Im 938 150 000 SCALE 1N FEET LEGEND ® M0M100100 NM LOCATION - 110 APPAENT 531.10 MASK B .i5ma111aSnW OMrM11e10;s 05a1 M1Th AFPARNI Sam MAST oASEOE iAe"ar� viAl O ` "r " TABLE SAME 10 DATE I" GROUNDWATER CLEAN UP TARGET LEVELS (p9/L) A091NT Cn 10 15 NOTES U - - Ma Na n0mt 901..la0 at 10. IabMab9 WOW W.I., 11m11 001_3 I - The 740v1.1.d4e I. b.l.m a. Ma MIN ae WMa1M5 Pr4e11041 SM+ 070111141107 GM an"..te.m.nea 1 a o ntl ales w C.o,1vg1 tn.(CM) OUN 71 . dale 09-500 L.. N C¢-Wan.. 01 Came. •5m dd 4 CITY OF MIAMI Cs 9. CADD p E: DATE. NOVEMBER 2015 SCALE. AS NOTED DRAM,. 00, Fig. 4 SCS ENGINEERS TABLE 2 GROUNDWATER ANALYTICAL SUMMARY MELREESE GOLF COURSE (AW-284/FILE-9442 ) Sample.'` (IIgn) (Pg/L) Groundwater Cleanup Target Levels ..._ .....-.. 10 ..... 15 9-Feb-15 18 2.0 U SCS-MW-1 11-May-15 4.0 U NS 12-Aug-15 4.71 NS 12-Nov-15 4.81 NS 9-Feb-15 4.0 U 2.0 U SCS-MW-2 11-May-15 4.4I NS 12-Aug-15 6.81 NS 12-Nov-15 7.21 NS 11-Feb-15 4.61 2.0 U SCS-MW-3 11-May-15 4.0 U NS 12-Aug-15 4.0 U NS 12-Nov-15 4.0 U NS 9-Feb-15 130 2.0 U 11-May-15 130 NS MW-31 12-Aug-15 150 NS 12-Nov-15 180 NS 15-Feb-16 140 NS 9-Feb-15 9.0 1 2.0 U MW-33 11-May-15 4.0 U NS 12-Aug-15 4.71 NS 12-Nov-15 4.0 U NS 9-Feb-15 4.41 2.0 U 1 1-May-15 4.0 U NS MW-42 12-Aug-15 52 NS 1-Sep-15 15 NS 12-Nov-15 10 NS 15-Feb-16 9.51 NS 9-Feb-15 4.0 U 2.0 U MW-44 11-May-15 4.0 U NS 12-Aug-15 9.1 1 NS 12-Nov-15 4.0 U NS Notes - pg/L - micrograms per liter GCTLs = Groundwater Cleanup Target Levels specified in Table I of Chapter 62-777, F.A.C. U - Not detected at the laboratory method detection limit (MDL) I - Estimated value, the reported value is between the MDL and the practical quantitaion limit (PQL) Bold - Indicates an exceedance of the applicable GCTL NS = Not Sampled Page 1 of 1 MIAMI•DADE COUNTY Carlos A. Gimenez, Mayor October 2, 2013 Department of Regulatory and Economic Resources Environmental Resources Management 701 NW 1st Court, 4th Floor Miami, Florida 331 36-3912 T 305-372-6700 F 305-372-6982 CERTIFIED MAIL NO. 7011 0470 0002 4387 4512 RETURN RECEIPT REQUESTED miamidade.gov Alice Bravo, Assistant City Manager City of Miami 444 Southwest 2nd Avenue Miami, Florida 33130 Re: Melreese Golf Course site (AW-284/File-9442) located at, near, or in the vicinity of 1550/1802 NW 37 Avenue, Miami -Dade County, Florida. Dear Ms. Bravo: Please be advised that the Department of Regulatory and Economic Resources- Division of Environmental Resources Management (DERM) conducted an inspection of this site on September 27, 2013. Based on the Inspection and past due environmental report, DERM is providing the following comments: 1. During the referenced inspection, a random visual survey was conducted of the golf course. Melted glass pieces were observed at the base of one of the Ficus trees. The location of the Ficus tree and the temporary remedy to address this matter was provided to you in an email on September 27, 2013. However, DERM acknowledges receipt of a September 30, 2013 email from City of Miami staff regarding this matter and this issue has been satisfactorily addressed. 2. As also discussed in the September 27, 2013 DERM email, City of Miami park staff were requested to conduct a full visual inspection of the golf course to identify any additional potential incinerator ash material (i.e. melted/fused glass, etc.) exposed at the surface. Please provide the results of this survey within seven (7) days upon receipt of this letter. Please notify DERM of any additional areas identified as a result of that survey. 3. DERM requires that a weekly inspection be conducted for the golf course to ensure that required surface cover remains intact. Schedules may require adjustments such as conducting immediate inspections following significant events (i.e. heavy storms, etc.). Please be advised that there shall be no digging, tree or landscape planting, or any subsurface disturbance activities at this site without prior review and approval from DERM. Notification shall be provided immediately to DERM of findings that require corrective action. Furthermore, monthly reports documenting the inspection results shall be provided to DERM in the interim. Ms Bravo October 2, 2013 AW-284 Page 2 of 2 4. In accordance with the February 21, 2007 Supplemental Site Assessment Report approval letter, DERM requires that a Remedial Action Plan (RAP)/Engineering Control Plan ( ECP) be submitted to address the remaining issues for this site. Therefore, unless otherwise noted above, within sixty (60) days of receipt of this letter, submit to this Department for review the required report addressing the above comments along with the applicable review fee. Failure to adhere to the items and timeframes stipulated above may result in enforcement action for this site. If you have any questions concerning the above, please me at (305) 372-6700. Sincerely, Wilbur Mayorga, P.E., Chief Environmental Monitoring and Restoration Division WM/tk Enclosures ec: Lee Hefty — DERM Donna Gordon - DERM M I AM I-DADE COUNTY AEA Coordination Agenda Coordination Animal Services An in Public Raines Audit and Management Services Aviation Building Building Code Compliance Business Development Capital improvements Citizens' Independent Transportation Trust Commission on Ethics and Public Trust Communications Community Action Agency Con,munity & Economic Development Community Rdabom Consumer Services Corrections & Rehabilitation Cultural Mains Elections Emergency Management Employee Relations Empowerment Trust En$erprise Technology Services Ewvironnawsal Resources Management Fair Employment Practices Finance Fire Rescue General Services Administration Historic Preservation Homeless Trust Honing Agency Housing Finance Authority Human Services Indcpendenr Review Panel tntemauonal Trade Consortium luvenile Services Medical Examiner Metro -Miami Adios Plan Metropolitan Planning Organization Park and Recreation Planning and Zoning Police Procurement Management Property Appraisal Public LIbrary System Public Works Sara Htighbort,o d Parks Seaport Solid Waste Management Strategic Business Management Team Metro Transit Task Face on urban trove* Revitalisation Vizcaya Museum And Gardens Watts & Senver Environmental Resources Management Pollution Control Division Pollution Remediation Section 33 SW 2nd Avenue • 7th Floor Miami, Florida 33130-1540 T 305-372-6700 F 305-372-6729 miamidade.gov February 21, 2007 CERTIFIED MAIL NO. 7006 0810 0000 7018 2950 RETURN RECEIPT REQUESTED Pedro Hemandez, City Manager City of Miami 444 Southwest 2`cl Avenue Miami, Florida 33130 RE: Supplemental Site Assessment Report (SSAR) dated September 14, 2006 and prepared by Petro Hydro, Inc. for the Melreese Golf Course (AW- 284/File-9442) located at, near, or in the vicinity of 1802 NW 371' Ave, Miami, Miami -Dade County, Florida. Dear Mr. Hernandez: The Pollution Remediation Section of the Department of Environmental Resources Management (DERM) has reviewed the referenced submittal, received, January 8, 2007, and hereby approves the report. Pursuant to the above, a Remedial Action Plan (RAP)/Engineering Control Plan (ECP) prepared in accordance with Chapter 24, Code of Miami -Dade County that proposes a course of action in order to successfully remediate/address the property is required. However, DERM requires that a meeting be scheduled to discuss alternatives available for this site. You are required to contact Thomas Kux, P.G., at the number listed below within thirty (30) days upon receipt of this letter to schedule the referenced meeting. Failure to adhere to the items and timeframes stipulated above may result in enforcement action for this site. If you have any questions regarding this letter, please contact me at (305) 372- 6700. Sincerely, Wilbur Mayorga, P.E., Chief Pollution Control Division WM/tk pc: Petro Hydro, 10450 NW 31 Terr., Miami, FL 33172 FCaADE Memorandum MIA"COUNTY Date: July 9, 2013 To: Donna Gordon, Chief Enforcement Section, RER From: Wilbur Mayorga, P.E., Chief Environmental Monitoring & Restoration Division, RER Subject: City of Miami Melrese Golf Course and Grapeland Park HWR-594 AW-284 File-9442 Past Due Reports The Environmental Monitoring and Restoration Division is referring the above two abutting sites to you for enforcement action. The City has not complied with submitting the required reports in accordance with Courtesy Letters issued on January 15, 2009, April 13, 2009, and January 5, 2010 and Extension Request issued on March 2, 2011 provided for this site. Please contact Thomas Kux, P.G. at ext. 6520 if you have any questions. WM/tk ► 11 t AM E•DADE `ct"�i•�t;f Carlos Alvarez, Mayor March 2, 2011 CERTIFIED MAIL NO. 7010 1870 0000 2691 3876 RETURN RECEIPT REQUESTED Environmental Resources Management Pollution Control Division 701 NW 1st Court • 4th Floor Miami, Florida 33136-3912 T 305-372-6700 F 305-372-69012 miamidade.gov Tony E. Crapp Jr., City Manager City of Miami 444 Southwest 2'3 Avenue Miami, Florida 33130 Re: Extension Request dated February 22, 2011 for the Quarterly Monitoring Report at Grapeland Park and submitted by the City of Miami and past due environmental reports for the Melreese Golf Course site (AW-2841File-9442) and Grapeland Park site (HWR-594/File-9442) located at, near, or in the vicinity of 1550/1802 NW 37 Avenue, Miami -Dade County, Florida. Dear Mr. Crapp Jr.: The Environmental Assessment Section (EAS) of the Department of Environmental Resources Management (DERM) has received your request for extension. DERM does not object to granting the sixty (60) day extension to submit the next quarterly groundwater sampling report as required in item 2 of the October 4, 2010 DERM letter. However, item number 1 of the referenced letter is past due and it is critical that the information be provided as soon as possible and without further delay. In addition, be advised that there are additional past due environmental issues still pending for these sites as referenced in the attached DERM letters dated January 5, 2010, April 13, 2009, and January 15, 2009. To date, DERM has. not received the required environmental reports for the above referenced sites. Therefore in addition to the requirements of the October 4, 2010 DERM letter as discussed above, within thirty (30) days upon receipt of this letter, submit the Engineering Control Plan (implemented in July 2008) and outstanding items due for the Grapeland Park and the Remedial Action Plan (RAP) due for the Melreese Golf Course. Failure to comply with the above may result in enforcement action for this site. If you have any questions concerning the above, please contact me at (305) 372-6700.. Sincerely, Wilbur Mayorga, P.E., Chief Pollution Control Division WM/tk Pc Harry James, City of Miami MIAMI•DADE COUNTY Environmental Resources Management Pollution Control Division 701 NW 1st Court • 4th Floor Miami, Florida 33136-3912 T 305-372-6700 F 305-372-6729 Carlos Alvarez, Mayor miamidade.gov January 5, 2010 CERTIFIED MAIL NO. 7007 2680 0000 0620 0783 RETURN RECEIPT REQUESTED Pedro Hemandez, City Manager City of Miami 444 Southwest 2nd Avenue Miami, Florida 33130 Re: Past due environmental reports for the Melreese Golf Course site (AW-284/File-9442) and Grapeland Park site (HWR-594/File-9442) located at, near, or in the vicinity of 1550/1802 NW 37 Avenue, Miami -Dade County, Florida. Dear Mr. Hernandez: The Environmental Assessment Section (EAS) of the Department of Environmental Resources Management (DERM) has not received the required environmental reports for the above referenced sites. These reports are past due as of May 13, 2009 (Melreese Golf Course) and July 31, 2009 (Grapeland Park). Therefore, within thirty (30) days upon receipt of this letter, submit the Engineering Control Plan (implemented in July 2008) and outstanding items due for the Grapeland Park and the Remedial Action Plan (RAP) due for the Melreese Golf Course. Failure to comply with the above may result in enforcement action for this site. If you have any questions concerning the above, please contact me at (305) 372-6700. Sincerely, Wilbur Mayorga, P.E., Chief Pollution Control Division WM/tk Pc Glendon Hall, City of Miami (gphall a(�miamigov.com) M I A M I-DADE COUNTY Carlos Alvarez, Mayor April 13, 2009 CERTIFIED MAIL NO. 7007 2680 0000 0710 9665 RETURN RECEIPT REQUESTED Environmental Resources Management Pollution Control Division 701 NW 1st Court • 4th Floor Miami, Florida 33136-3912 T 305-372-6700 F 305-372-6729 miamidade.gov Pedro Hernandez, City Manager City of Miami 444 Southwest 2"d Avenue Miami, Florida 33130 Re: Environmental reports for the Melreese Golf Course site (AW4TigtFliiig9442Y and Grapeland Park site (HWR-594/File-9442) located at, near, or in the vicinity of 1550/1802 NW 37 Avenue, Miami -Dade County, Florida. Dear Mr. Hernandez: Please be advised that the Environmental Assessment Section (EAS) of the Department of Environmental Resources Management (DERM) has not received the required reports for the above referenced facilities. In accordance with the attached January 15, 2009 courtesy letter issued by DERM, the reports were to be submitted by February 14, 2009. To date, the required documents have not been submitted. Be advised that the levels of groundwater and/or soil analytical results submitted for this site constitute violations of Chapter 24, Code of Miami -Dade County (the Code), specifically, Section 24-44, 24-27, 24-28, and 24-29 of the Code. Based on the above, and pursuant to Sections 24-7(15), 24-7(26), and 24-44(2)(g) of the Code, you are hereby required to submit to this office for review, within thirty (30) days of receipt of this letter, the past due assessment and/or remedial reports required for these sites. Failure to adhere to the items and timeframes stipulated above may result in enforcement action for this site. If you have any questions concerning the above, please contact me at (305) 372-6700. Sincerely, Wilbur Mayorga, P.E., Chief Pollution Control Division WM/tk Attach MIAM IDADE COUNTY Carlos Alvarez, Mayor January 15, 2009 CERTIFIED MAIL NO. 7007 2680 0000 0710 9337 RETURN RECEIPT REQUESTED Pedro Hernandez, City Manager City of Miami 444 Southwest 2nd Avenue Miami, Florida 33130 Environmental Resources Management Pollution Control Division 701 NW 1st Court • 4th Floor Miami, Florida 33136-3912 T 305-372-6700 F 305-372-6729 miamidade.gov Re: Environmental reports for the Melreese Golf Course site (AW-284/File-9442) and Grapeland Park site (HWR-594/File-9442) located at, near, or in the vicinity of 1550/1802 NW 37 Avenue, Miami -Dade County, Florida. Dear Mr. Hemandez: Please be advised that the Environmental Assessment Section of the Department of Environmental Resources Management (DERM) has not received the required reports for the above referenced facilities. In accordance with the October 10, 2008 email form the City of Miami, the reports were to be submitted by December 9, 2008 for the Melreese Golf Course facility and by November 24, 2008 for the Grapeland Park facility. Therefore, within thirty (30) days of receipt of this letter, submit to this Department for review the required documents along with the applicable review fees. Failure to adhere to the items and timeframes stipulated above may result in enforcement action for this site. If you have any questions conceming the above, please me at (305) 372-6700. Sincerely, Wilbur Mayorga, P.E., Chief Pollution Control Division WMltk Attach Environmental Consultants and Contractors 7700 N. Kendall Drive Suite 300 Miami, FL 33156 305 412-8185 Fax 305 412-8105 www.scsengineers.com SCS ENGINEERS April 16, 2014 SCS File No. 09213010.25 Mr. Wilbur Mayorga, P.E., Chief Department of Regulatory and Economic Resources Division of Environmental Resources Management 701 Northwest 1st Court, 4th Floor Miami, Florida 33136-6982 Re: Melreese Golf Course 1802 Northwest 37th Avenue Miami, Florida RECEIV!D April 17, 2014 DEEM Subject: Corrective Action Plan SCS Engineers (SCS), on behalf of the City of Miami (City) and DeLucca Enterprises (DeLucca), herein submits this Corrective Action Plan (CAP) for Melreese Golf Course (site) to the Depaitment of Regulatory and Economic Resources, Division of Environmental Resources Management (DERM). Melreese is an active golf course that is owned by the City and operated by DeLucca. The corrective actions proposed herein are consistent with the remedies discussed with DERM during our February 20, 2014, meeting. PREVIOUS INVESTIGATONS Buried incinerator ash was discovered at the site during a 2005 Limited Phase II Soil Assessment. In response to the discovery, DERM issued a letter, dated December 20, 2005, requiring further delineation and remediation of three localized areas where ash had been reported in the upper six inches of soil. The three localized areas were addressed by source removal on May 8, 2008, and subsequent assessments were conducted to address the delineation requirements. A summary of the assessment findings is as follows: • Buried solid waste (incinerator ash and/or glass and metal fragments) was encountered at various depths throughout the site and has been delineated to the south, east and west by soil borings. The site is bound to the north by the Tamiami Canal. • Concentrations of the chemicals of concern [COCs, i.e., arsenic, barium, copper, lead, polychlorinated biphenyls (PCBs), polynuclear aromatic hydrocarbons (PAHs) and dioxins] in soil samples were generally below the applicable soil cleanup target levels (SCTLs). Arsenic was present throughout the site at concentrations that are generally consistent with levels found at other golf courses. The 95% upper confidence limit of the mean concentration of lead was calculated below the residential SCTL. Copper concentrations were below the residential SCTL, with the exception of one out of 21 samples tested. Total dioxins/furans were reported at concentrations ranging from 2.01 ng/kg to 22.6 ng/kg. The remaining COC concentrations were below the residential SCTLs or the laboratory detection limits. Offices Nationwide j (I Q1 /13 A) MSB- 58 SB-WO-.'. (NONE) TD SW 42nd AVENUE • SCS-25 (2') SCS--4 (0.75) li 17 SB-50W SCS- 26• A (1.5) l (NONE) - - 28-0 ---LC- SCS-20 33/33R� r (0.5) (1.0) 4� 39� NONE (1.0) ^NW-4 y ( )1 (4.0)2 ,r SCS-M(>t)W1 6 C5'3 (05) (0.5 0- SCS-21 SCS-2 SCS-19CC (>1) (1.5) (1.51 SCS-427-5 SCS-22 •J (>Q SCS-17 (1.3) (2') (1.0)\ SB(5oj-� MSB-557 t SCS-28 ,(NONE) 5C5-27 (NONE) MW -39 SO--56 SCS-MW3 (NONE) •(00) g \•(SES 29 MSH 55 MSS-541 (0) 41111111111, SCS-23 (2') SCS-24 (1.5') SB-50N (1.5) m \SB-50E (0.6) SB-WB-4 --II SCS-41`` (NONE) (>1)• SCS-521 M19\ (NONE) (0.5) SC5-5 (1.0) 45 (0.5) SCS 6 41,0)(1.0) SCS-30 • (>t) SCS-31 �(NONI ) ,(1,0)38 MW- 46 SCS-9 (2.0)1 �l1 MW-40 9 (0.5)1 (0.75) KS-1 18/1BR" (0.5) SB-17W (2.0)\ 56-175 (20) 435 SCS-40 40 (NONE) Se- WB-3T (NONE) SCS-32 (NONE) 18 SCS-12 (1.5) r2o (I.0) 24 (0 5) jjj SCS-43 / (>I) RSCj-11 (1,5) SCS-47 d(>t)) SB-17N �(2.0) 23/23R S8-17E (0.5) (2.0) SCS-48 (NONE)\ SC5-13- • (3.5) SC'-51 / • (NONE) SCS-38E (NONE) 18 SCS-39l (NONE) 44 (3.0)\ M58-511 SCS-50 °`l6 (NONE) 115 SCS -300- (0.8') 5C5-38D (NONE) NE) 13 SCS--7? (N0 ASH0 ) (5) ' (2.0) S(5.75) 35 (4 0 15 SCS-33 (NONE)\ SCS-MW2 - (NONE) 2! SCS-38 (0.5') SCS-38A (NONE) SCS-38C (NONE) SB-WB-5 (NONE) 31\ SCS-16 (1) MW-44 MS8-62` L 5C5-18 (NONE) 29/ DRMNQ RANGE SO-WO-1� (NONE) ' �21 (3.0) (2.5) 30 (2.5) SC5-46 / (NONE) \MW--41 (1.0) SO-(25)26W SCS-44 (NONE) MW-43 (1.0) 25 (05) 22 (1.0)1 SCS- 45 (NONE) SCS- 49 (>1) ( MAINTENANCEI SCS-36 • (NONE) 2 (2.0) MW-3311 (3.0) SC5-35C (1.5') SCS-37 34 (NONE) 1 '(1,0) SCS- 350 (NONE) SCS-35B (1 5') 43 LMSB-52 SB-WB-6N2- (NONE) SO- WB- GW (NONE) SCS-34 (NONE) MW-37` R42 (I.5) Y MSB-53-,,, (3.0). 4-, (1.0) 5C (0. ,ttr+i1t.. /3 SCS-35A ♦ (3.5 (NONE) H Wd 6NI (0,5 ) 56 - 50--6 (E.5') 5B-WB 6I (0.25') SA-4WB-651 (I)I rMWt 36 0 (I.0N SB- 26E (2.5) CS IS p (Ii/5) MSB-fiY SC5-14 (2.0) CLUBHOUSE MW-32/ M58-59 W z MS8-60 u1 MW-31� CI 35 ORAPELAND PARK MW-34 (NOT PART OF THIS PROJECT) MW-35 (2.5) MW-301, - -J SCALE M EMT LEGEND • SOIL MOWFOR NAJAL 5FLIMA1IOX 04'L111) MMUSF 29 - .PRIMER 2. 2005 Sol EOM. - x0 APPARMI m.IO WAVE • COMM. AUGUST 29 - MOR119212 2, 26105 APPAMNI SWO WASTE A90M i' BROW OOUM 9,f6ACC 5001 cAAx1FB Aucus129 - S�nuBFR z 2ro5 APPARENT SWO WASR Al OR BFLOII 6 0900 (AO.MO S1FACL IB05) tt4IXA:(EO A00051 29 - SEMEWRER 2, 2005 8 soma M90221. comma,* RMWN1 449505 AEC. 201E M 402101x0 YELL MCA. - N0 AMARENI SCUD WASTE 0421 0NH0 FQL 10020 4 MIN APPAREN4 5010 WASTES nl aR Bnlrxrecs SCS SOS BOINO 0010(100 US&C [MCI PUSS MR W91AL 001NEA001, O CONOUC7E0 01 NAR01 A 2014,FE91Un0Y .i A 4, 2015, JAY 22, 2015, SOS. 503-16 tega101 Y.52 ANO ME JAY 22. 201S M1R 1ERMNAR4 Ai 2 041. SCS SOt SCOW G LOOEN YAM APPER M1 5010 WASTE SIN9N EMIR I' 6 Sal wSmSOlwANrO tiI•OCwRL01.1111 APPAAENI SOLO WASTE SMOKE 9E110210 URA (DISUSES 50. 500000 R0 01 • ROMES 59A-17, 26 A 50 MC 0002-6 INx0p1 26) (X.X) MPM Al 2001 5010 WASTE / A91 WOES /SEAS 2411EM 5010 WASTE Wn51% 1190040 IN ISE 12202 II 0 S0L RESF MESS WARRANT 0¢AIER 5042l111 01aN0 ME ENFAN. CONIR05 INSKCIUN. 5 1 1 1 2 1 b T AMIAMI CANAL MELREESI GOLF COURSE • r aNIMN yI r ! PP*6XIMATVE PROPERTY •. 'BOUNDARY , A ,. 4: NW 19th STREET .,1 „1 150 300 SC/. IN FEES LEGEND MwONPN2 PROPERLY LNuwNLY O NIXES ttE 00S urtL -J ▪ r.01' PMCI N • OM MEA NEAS INEiE .0 PAst PNS 000.ENS0 N PE ti@ 0 • I Cr SOL I ESE NRAS PNMAN1 MUMS $(RUINS 00 NL nE ENCNEE9xG .11.SI30E31101 2 8 4<,< <I CITY OF MIAMI e8 A O000 FILE DAZE: AUGUST 2015 50A1E AS 1101E0 OPAINNG NO. Fig. 3 MIAMFDM COUN TY Carlos A. Gimenez, Mayor May 30, 2014 Department of Regulatory and Economic Resources Environmental Resources Management 701 NW 1st Court, 4th Floor Miami, Florida 33136-3912 T 305-372-6700 F 305-372-6982 CERTIFIED MAIL NO. 7013 2630 0001 2427 5808 RETURN RECEIPT REQUESTED Alice Bravo, Assistant City Manager City of Miami 444 Southwest 2"d Avenue Miami, Florida 33130 miamidade.gov Re: Corrective Action Plan dated April 16, 2014 and prepared by SCS ES Consultants for the Melreese Golf Course (AW-284/File-9442) located at, near, or in the vicinity of 1550/1802 NW 37 Avenue, Miami -Dade County, Florida. 'Dear Ms. Bravo: The Department of Regulatory and Economic Resources- Division of Environmental Resources Management (DERM) has reviewed the above referenced report, received April 17, 2014. The following comments are provided: 1. Provide documentation that each of the 18 greens, including practice greens, were constructed with the 2 feet of cover as depicted in Figure 3 of the report. Please note that the lithology from boring SCS-14 does not correlate with that depicted in Figure 3. 2. The proposed control for the sand traps is approved. However, identify each of the waste bunkers on the site diagram. Be advised that if waste bunkers receive routine play or access as do other areas of the golf course, the same controls proposed for the sand traps will also be necessary for the waste bunkers. 3. The proposed approach to mulch the landscaped tree areas is acceptable. DERM recommends that a bonded rubber mulch be used for increased durability. 4. During previous DERM inspections, considerable elevation changes were noted throughout the golf course, including lower elevations throughout the fairway play area. Furthermore, large distances between soil borings such as at location SCS-4 (several hundred feet between delineating borings) infer potential large areas of solid waste within the surface interval. Therefore, the proposal to not implement additional engineering controls for the fairways, tees, roughs, and approaches is not approved at this time pending further investigation. At a minimum, a plan to provide sufficient soil boring coverage shall be required. Furthermore, those areas with solid r,t ,_;„ f, „tee.L {,„ e : i' y. , 'f,,,1 Ms Bravo May 30, 2014 AW-284 Page 2 of 2 waste in the upper 2-feet will be required to be addressed and the next report shall also include an engineering control proposal. 5. A current round of groundwater samples shall be required for lead and arsenic from all site monitoring wells. 6. Any redevelopment or sub -surface work will require review and approval from DERM. Furthermore, disposal manifest shall be provided to DERM for any solid waste material removed from the site. 7. Although a projected start date to implement some of the engineering controls is provided, a more detailed timeline is required for review and approval that shall include projected completion dates for individual areas. 8. Inspection reports and engineering control maintenance records proposed in Appendix D shall be maintained on -site and available for review. Furthermore, Semi- annual maintenance reports shall be submitted to DERM that document the repair of any engineering controls established for the site. Based on the above, an addendum to the Corrective Action Plan is required to be submitted within thirty (30) days upon receipt of this letter. Failure to adhere to the items and timeframes stipulated above may result in enforcement action for this site. If you have any questions concerning the above, please contact Thomas Kux, P.G., at (305) 372-6700. Sincerely, Wilbur Mayorga, P.E., Chief Environmental Monitoring and Restoration Division WM/tk Enclosures ec: Lee Hefty — DERM Donna Gordon - DERM DV 02-204 L M I A M I•DADE COUNTY ADA Coordination Agenda Coordination Animal Services Art in Public Places Audit and Management Services Aviation Building Building Code Compliance Business Development Capital Improvements Citizens' independent Transportation Trust Commission on Ethics and Public Trust Communications Community Action Agency Community & Economic Development Community Relations Consumer Services Corrections & Rehabilitation Cultural Affairs Elections Emergency Management Employee Relations Empowerment Trust Enterprise Technology Services Environmental Resources Management Fair Employment Practices Finance Fire Rescue General Services Administration Historic Preservation Homeless Trust Housing Agency Housing Finance Authority Human Services Independent Review Panel International Trade Consortium Juvenile Services Medical Examiner Metro -Miami Action Plan Metropolitan Planning Organization Park and Recreation Planning and Zoning Police Procurement Management Property Appraisal Public Library System Public Works Safe Neighborhood Parks Seaport Solid Waste Management Strategic Business Management Team Metro Transit Task Force on Urban Economic Revitalization Vizcaya Museum And Gardens Water & Sewer February 21, 2007 Environmental Resources Management Pollution Control Division Pollution Remediation Section 33 SW 2nd Avenue • 7th Floor Miami, Florida 33130-1540 T 305-372-6700 F 305-372-6729 CERTIFIED MAIL NO. 7006 0810 0000 7018 2950 RETURN RECEIPT REQUESTED Pedro Hernandez, City Manager City of Miami 444 Southwest 2nd Avenue Miami, Florida 33130 miamidade.gov RE: Supplemental Site Assessment Report (SSAR) dated September 14, 2006 and prepared by Petro Hydro, Inc. for the Melreese Golf Course (AW- 284/File-9442) located at, near, or in the vicinity of 1802 NW 37th Ave, Miami, Miami -Dade County, Florida. Dear Mr. Hernandez: The Pollution Remediation Section of the Department of Environmental Resources Management (DERM) has reviewed the referenced submittal, received, January 8, 2007, and hereby approves the report. Pursuant to the above, a Remedial Action Plan (RAP)/Engineering Control Plan (ECP) prepared in accordance with Chapter 24, Code of Miami -Dade County that proposes a course of action in order to successfully remediate/address the property is required. However, DERM requires that a meeting be scheduled to discuss alternatives available for this site. You are required to contact Thomas Kux, P.G., at the number listed below within thirty (30) days upon receipt of this letter to schedule the referenced meeting. Failure to adhere to the items and timeframes stipulated above may result in enforcement action for this site. If you have any questions regarding this letter, please contact me at (305) 372- 6700. Sincerely, Wilbur Mayorga, P.E., Chief Pollution Control Division WM/tk pc: Petro Hydro, 10450 NW 31 Terr., Miami, FL 33172 DV 02-204 Environmental Engireering, General Contractors & Undergrould Utilit es. G.C. Lcense # CG-0051799 TECHNICAL pEPORT PETRO HYDRO, INC. TK ssPr SUPPLEMENTAL SITE ASSESSMENT REPORT Melreese Golf Course Section 1 of 2 1802 Northwest 37th Avenue Miami, Miami -Dade County, Florida 33125 DERM HWR-594/AW-284/File-9442 September 14, 2006 71721W% JAN 0 8 2007 DERM POLLUTION REMEDIATION SECTION Prepared for: City of Miami — Department of Economic Development Miami Riverside Center 444 Southwest 2nd Avenue, 3rd Floor Miami, Florida 33130 Submitted by: Petro Hydro, Inc. 10450 NW 3151 Terrace Miami, Florida 33172 PHI Project #05E031.01 Prepared: n t v x d y: Greg A. 14br,,,P.G PG 1403 Environmental r Divis\igx�.NFa a e ls1 1 I 10450 N.W 31 st Terrace / Miami. FL 33172 / Phone: 305-477-0878 i Fax 305-594-8982 DV 02-204 Supplemental Site Assessment Report Melreese Golf Course 1802 Northwest 37th Avenue Miami, Miami -Dade County, Florida September 14, 2006 5.0 CONCLUSIONS The conclusions provided below are based on the combined information obtained by PHI during implementation of the Limited Phase IT Soil Assessment conducted in August 2005 and this Supplemental Site Assessment investigation. Based upon these investigations, indications are that the burial of the incinerator ash throughout the Site has only resulted in minimal Dioxin/Furans and Lead soil impacts only marginally above the MDC Chapter 24-11 Residential Exposure SCTLs. None of the detected Dioxin/Furans and Lead soil impacts exceeded the MDC Chapter 24-11 Commercial/Industrial Exposure SCTLs. The limited soil Lead impacts detected above the MDC Chapter 24-11 Residential Exposure SCTLs were either delineated horizontally onsite along the property boundaries or vertically by the surface of the water table. Although TCLP Lead concentrations previously suggested the potential for leachate generation, groundwater data from 40 separate monitoring wells failed to detect any groundwater Lead concentrations in excess of the laboratory detection limit of 5 ug/L. Trace Dioxin/Furans groundwater concentrations were consistently detected; however the concentrations detected were significantly below the applicable GCTLs. The combined results of the soil and groundwater PCBs and PAHs analyses were consistently below acceptable laboratory detection limits, or MDC Chapter 24-11 Residential Exposure SCTLs or MDC Chapter 24-11 GCTLs. Arsenic was consistently detected in the soils beneath the Melreese Golf Course, which has been in continuous operation for over 40 years. The detection of the elevated Arsenic concentrations is a common occurrence in Miami -Dade County golf courses and was the subject of a December 2002 DERM Technical Report entitled "Environmental Quality Monitoring at Five Municipal Golf Course in Miami -Dade". This technical report concluded that, based on DERM-sponsored sampling and analyses results, 94% of the surficial soil samples at the five golf courses exceeded the then applicable Residential MDC Chapter 24-11 SCTL of 0.7 mg/kg and that 87% of the soil samples exceeded the MDC Chapter 24-11 Commercial /Industrial SCTL of 3.7 mg/kg. The findings of the report further concluded that the golf course surficial soils contained a medial Arsenic concentration of 15.10 mg/kg and that all golf course soils contained a median Arsenic concentration of 5.6 mg/kg. Arsenic concentrations detected at the Melreese Golf Course are statistically similar to the DERM reported arsenic concentrations present at the five municipal golf courses in Miami Dade County 17 O:,E vironmcntelProjects\City of Miami (all sitesyMelreese Golf Course • 05E031`SSAR Report 9-06\SSA Report 9-06.doc 1 DV 02-204 Supplemental Site Assessment Report Melreese Golf Course 1802 Northwest 37th Avenue Miami, Miami -Dade County, Florida September 14, 2006 6.0 RECOMMENDATIONS Based on the results of this assessment, PHI recommends the City/DERM work together to prepare and implement a No Further Action with Conditions (Conditional Closure) for this Site. A Conditional Closure is recommended for this Site to address the soil Dioxin/Furans and Lead concentrations detected in excess of the applicable MDC Chapter 24-11 Residential Exposure SCTLs. The elevated Arsenic concentrations would be representative of a secondary contaminant source since their presence is partially the result of agrochemicals that were applied over time after the burial of the incinerator ash and in accordance with then -applicable EPA guidelines. Since the City intends to maintain this property as a golf course in perpetuity, it is reasonable to consider scheduling a meeting with DERM to discuss the implications of this potential closure options. 18 o:\Eovironmwtai\Projats\City of Miami (all sitcs) ellecsc Golf Course - O5E03 I'SSAR Rcport 9-)6 SSA Rcport 9-05.doc DV 02-204 Nen um um my Num mu Imo ma mi um me MN 1. LE015111 Soil boring location (conducted August 29 - September 2, 2005) V Apparent Incinerator ash V No apparent Incinerator ash Surface water sample location (conducted October 18, 2005) Surface water sample (S% MSB-51 MSB-52 MSB-53 A Sol boring for ash delineation 0' 250' 500' Scale In feet PC TROO HYDRO, ONC. 10450 NW 31 Terrace, Wain', Florida Phone: 305-477-0878 Fax: 305-594-8982 COTY OF AI1 MELIREESE GOO LP COURSE 1802 NW 37th Avenue Miami, Florida FIGURE 2 S000L oOORNS LOO©A°,T000a MAP DV 02-204 M M M OM N NM 1.1111 ! 11111 MI INN M INN MI M M i MN E LGC nDD Soil boring location (conducted August 29 - September 2, 2005) V Apparent Mdnerator ash 7 No apparent incinerator ash Surface water sample location (conducted October 18, 2005) Surface water sample (SW) -i-!+ Monitoring well 0' 250' 500' Scale In feat PETRO0 HYDRO, QO NC. 90450 NW 31 Terrace, Miami, Florida Phone: 305-477-0878 Fax: 305-594-8982 COW OF fi InkiII MELREESE @OLF COURSE 1802 NW 37th Avenue Miami, Florida FIGURE 3 NOO NOTOO ROa© WELL DV 02-204 IINI NO NM N INN MN I INN — — i i — I INN I IMO NM MSB-73 lLIg gRJR-2) Soil boring location (conducted August 29 - September 2, 2005) V Apparent Incinerator ash Q No apparent Incinerator ash 1B/.18R 50R MSB-69- ,* 23/23R rtS_ 70r`7pMSR 67 _ V 72 -MS —63' Surface water sample location (conducted October 18, 2005) Surface water sample (SW) 26/26R V21 1SB-63 30 "MSB-66VTVMSB-64 MS - 65 r/26/0c,,, 180.4 { 67.7 I G 12.6 5I25R *MSB:61 77 70.0 — 26.8 -1 N S 5 6.35 9/1/05 4.11 IT - 9.19 42 MSB-51 MSB-52 MSB-53 Q Soil boring for ash delineation 8/3/06 4.3 4.3 4.3 Sample Date Pb(mgA(g) Pb(mgfl(g) 1 A'-3.0' Pb(mgXg) m-Nda rrci. 0' 250' 500' Scale In feet REM HYDRO, [INC. 10450 NW 31 Terrace, Miami, Florida Phone: 305-477-0878 Fax: 305-594-8982 ©O1TVOOFPAAPAfl PAELII tME ©OLLF ©ORME 1802 NW 37tr : venue Miami, Florida FIGURE 4 SOO DLL L e D OPAPG,1Cr DIELONEATIIOOII PAW DV 02-204 0.0-0.5 2.25 15.14 1 1.00 2.98 . 212 0.5-1.0 3.98 2.56 !<0� 11.03.0 8.97 1 11.8 `i12.8 6.47 19 18/18 1 50/50R MF-B-69 / MSB 70Y/AMSB-67 MSB-74r'rYMSB-72 MSB 6B MSB-73 0.0-0.5 14.1 0.5-1.0', 4.92 10.5 0.5-1.0 7.61 1.0.3.0; 6.01 12.9 j'16.5 9.46 2.83 1.03.0 4.45 9.18 344 10/10Rf, o.0-0S1 10.9 ; 7.52 8.86 1.43 13.6 �225 1.03.0 1.96 173.7 18.5 1135 0.5-1.0 3.06 i 13A V46 '.5 11.6 �a 3.e9 LEGEND Soil boring location (conducted August 29 - September 2, 2005) V Apparent Incinerator ash 0 No apparent Incinerator ash Surface water sample location (conducted October 18, 2005) Surface water sample (SW) 48 2.58 j 1.16 520 226 714 728 V31 26/26R iY21 MSB-63 / 30 MSB-66YXYMSB-64 emu.. MSB-65 0.0-0.5 5.2 6 3214 32 1 130 0.5-1.0 8.18 '40 ' 37.6 _155 1.0-3.0 822 41.7176.8 1270 MSB-51 MSB-52 MSB-53 p Soll boring for ash delineation irk ArsenicBariurnCopper Lead 0.0-0.5 5.11 9.71 5.11 9.71 0.5-1.0 5.11 9.71 6.11 9.71 1.0-3.0 5.11 9.71 5.11 9.71 Sample Yervi ( Fed ) M mrorrrwr ( manta ) 25/25R a 250' 500' Scaie In feet PLETh© HYDRO, NC. 10450 NW 31 Terrace, Miami, Florida Phone: 305-477-0878 Fax: 305-594-8982 CITY OF MHO MELREESE C OO L[F COURSE MRSE 1802 NW 37th Avenue Miami, Florida FIGURE 5 SOIL AA, Dal, Can, Pb CONC ENT R s 4000 a MAP DV 02-204 T) Dioxin-Furan I Cumulative TEQ=22.60 • 27T 41/41R T I 31cakititFuran Cumulative TEQ=5;26 ng/ Kg;; '. 1,0-3 0 f:eet 26/26R V21 MSB 3 /� 30_: MSB-66v 7MSB-64 ng. Ko 1 17 12 ,1 0 a.0 Feet 1 50/50R MSB-69 �— - MSB 65 w/ 2323R pica-in-0- uran, '� MSE 7t �,� MSB 70 Y z.MS3 67 T I Cu^rutative 1 '1/4. MSB-74Y/'rYMSB-72 MSB 68 T,E�Q 13.20 T �roxin Furc •�:n9/Kg 25/25R 11 MSB 73 Cumulative 1 1.0 3.0 •'Feet MSB 57 TEQ 662 ?, . , no./Kg, -z1 • 3o in- LA ran Cumulative-= TEQ=8.93 s `` ng/Kg 0.5-1.0 Feet OM s is es is s me me is is me s s s s me en s is n T Soil boring location (conducted August 29 - September 2, 2005) Apparent Incinerator ash V No apparent lt*terat r eah Surface water sample location (conducted October 18, 2005) U Surface water sample (SW) 16 T j ➢Icxin I- uran 1-Cumulative EQ=11.66 ✓Ka 'se-3.0 Feet MSB-51 MSB-52 MSB-53 Q Sol boring for ash delineation Soil sampled for Dlordn/Furans on Juty, 2006 Boxes Indicate Cumulative Toxldty Equivalent Quotient (TEQ) for dioxin and furans in soil (ng/Kg) 0.5'-1.0' Feet "cB-59 Cbubhou, 1_ 64 1 _ TM6C 5S ITV r, T 585756 42`31 0' 250' 500° Scale In feet PETROO HYDRO, aO O1©. 10450 NW 31 Terrace, Miami, Florida Phone: 305-477-0878 Fax: 305-594 982 COW OF FAME PAELREISE ©©LE COURSE 1802 NW 37th Avenue Miami, Florida Figure 6 SOILS DOOKE-FURANS C OO NC EN ° 4O OOa MAP DV 02-204 MI i i 1 i i TABLE 7 SOIL ANALYTICAL RESULTS - As & Pb (Page 1 of 6) Melreese Golf Course 1802 Northwest 37th Avenue Miami, Miami -Dade County, Florida DERM AW-284/File-9442 Soil Boring Location & Date Sample Interval (Feet, BG) Percent Moisture Lead mg/kg TCLP Lead ug/L Arsenic mg/kg SPLP Arsenic ug/L 0.0 - 0.5 35.0% 13.2 ns 41 O ns SB-1 0.5 - 1.0 13.6% 68.7 ns ns t`s 8-29-05 1.0 - 3.0 13.3% 464 ns 4ti4 ns 0.0 - 0.5 23.6% 9.91 ns ns SB-2 0.5 - 1.0 17.9% 11.2 ns 1.77 ns 8-29-05 1.0 - 3.0 1.53% 43.1 ns 1.53 ns 0.0 - 0.5 12.6% 46.5 ns 37.9 ' 8 ns 17.0 ns SB-3 0.5 - 1.0 28.2% 51.0 71.5 ns 1.57 ns 8-29-05 1.0 - 3.0 17.7% 0.0-0.5 17.8% 62.5 ns`: 8 SB-4 0.5 - 1.0 13.3% 69.2 ns a_ ns 8-29-05 1.0 - 3.0 23.6% 23.9 ns t Y, - , ns 0.0 - 0.5 26.1 % 3.21 ns ns F r ; ns x r: -' ns SB-5 0.5 - 1.0 20.5% 4.33 ns 0.554 ns 8-29-05 1.0 - 3.0 7.99% 1.00 0.0 - 0.5 41.5% 4.39 ns 13.6 ns SB-6 0.5 -1.0 30.9% 9.34 ns 'xm-�-° ns 8-29-05 1.0-3.0 15.6% 27.2 ns 21.9 ns ns y N_ ns 0.0 - 0.5 36.2% 5.17 SB-7 0.5 - 1.0 27.4% 17.1 ns : ns 8-29-05 1.0 3.0 17.7% 36.6 ns _�_ _a. ns 0.0 - 0.5 37.4% 3.91 ns` ns SB-8 0.5 1.0 9.10% 11.1 ns 4 ns ns ens 8-29-05 1.0 - 3.0 32,7% 10.4 0.0 - 0.5 31.7% 30.3 *130 ns 32.5 ns ns 23.8 ns SB-9 0.5 - 1.0 15.9% _ 12.2 ns 1.06 ns 8-29-05 1.0 - 3.0 10.3% 0.0 - 0.5 23.9% 1.43 ns g ns SB-10 0.5-1.0 27.8% *225 __`` _ ns 8-29-05 1.0 -3.0 11.6% *135 ns 1.95 ns MDC Chapter 24-11, SCTLs (mg/kg) Residential Exposure 400 NA -.;, - NA ` , MDC Chapter 24-11, Commercial/Industrial SCTLs (mg/kg) 1400 NA NA 12 NA 1i§ NA MDC Chapter 24-11 Groundwater Criteria (ug/L) Note: NS - Sample archived at laboratory but Not Submitted for analysis. BDL - Below laboratory detection limit NA - Not applicable DV 02-204 t TABLE 7 SOIL ANALYTICAL RESULTS - As & Pb (Page 2 of 6) Melreese Golf Course 1802 Northwest 37th Avenue Miami, Miami -Dade County, Florida DERM AW-284/File-9442 Soil Boring Location & Date Sample Interval (Feet, BG) Percent Moisture Lead mg/kg TCLP Lead ug/L Arsenic mg/kg SPLP Arsenic ug/L 0.0 - 0.5 14.4% 42.0 ns 34.5 ns SB-11 8-29-05 0.5 -1.0 19.7% 51.3 ns 4i ns 1.0-3.0 19.2% 61.9 ns 343 ns SB-12 0.0 - 0.5 27.8% *135 ns 4L55 ns 8-29-05 0.5 - 1.0 18.8% 30.8 ns 1.37 ns 1.0 - 3.0 13.9% 5.07 ns 1.32 ns 0.0 - 0.5 12.6% 50.9 ns 27.1 _17 SB-13 8-29-05 _-_ 0.5 - 1.0 36.1 % *133 _ ns €+ ns 1.0-3.0 40.3% 16.6 ns s- ns SB-14 0.0-0.5 37.9% 4.25 ns� ns 8-29-05 0.5 - 1.0 31.6% *129 ns 16.5 ns 1.0-3.0 14.3% 61.9 ns ^ ns SB-15 0.0-0.5 32.9% 14.5 ns 16.4 ns 8-30-05 0.5 - 1.0 14.7% 15.9 ns . ns 1.0 - 3.0 29.7% 86.3 ns . �� -," ns 0.0-0.5 - 13.4% 5.98 ns 18.2 SB-16 8-30-05 0.5 - 1.0 16.2% 10.3 ns` a ' ns 1.0 - 3.0 23.8% 9.30 ns 1.93 ns SB-17 0.0 - 0.5 35.1 % 88.3 ns 4s f ns 8.30-05 0.5 -1.0 27.7% 82.8 ns E', ` ns 1.0 - 3.0 28.2% 66.0 ns • ns 0.0 - 0.5 21.6% 52 3 ns 23.5 ns SB-18 8-30-05 0.5 - 1.0 31.6% . 7O -. .,. 219 15.3 ns 1.0-3.0 14.7% *106 _ �'•`_ pp ns SB-19 0.0-0.5 29.7% 10.7 ns ns 0.5 - 1.0 16.6% 66.5 ns ns 8-30-05 1.0 - 3.0 48.4% i5. ns .=_ ns SB-20 0.0 - 0.5 28.9% 2.45 ns 1.15 ns 8-30-05 0.5 -1.0 18.2% 74.6 ns -.* ns 1.0 -3.0 25.3% ns '- ns MDC Chapter 24-11, Residential Exposure _ a '- SCTLs (mg/kg) ° _ NA NA MDC Chapter 24-11, Commercial/Industrial SCTLs (mg/kg) 1400 NA 12 NA MDC Chapter 24-11 Groundwater Criteria (ug/L) NA 115 NA { 1 Note: NS - Sample archived at laboratory but Not Submitted for analysis. BDL - Below laboratory detection limit NA - Not applicable DV 02-204 IM i i 1 t i i TABLE 7 SOIL ANALYTICAL RESULTS - As & Pb (Page 3 of 6) Melreese Golf Course 1802 Northwest 37th Avenue Miami, Miami -Dade County, Florida DERM AW-284/File-9442 Soil Boring Location & Date Sample Interval (Feet, BG) Percent Moisture Lead mg/kg TCLP Lead ug/L Arsenic mg/kg SPLP Arsenic ug/L 8-30 015 0.0-0.5 30.1% 26.1 ns12A - ns 0.5 - 1.0 28.3% 76.2 ns ns 1.0 - 3.0 25.9% 57.6 ns� yip- ns SB-8- 0?05 0.0 - 0.5 18.4% *144 ns 23.4 ns 0.5 - 1.0 12.6% ns .. _- ns 1.0 - 3.0 19.6% :r• ns SB-23 8-30-05 0.0 - 0.5 22.3% 16.5ns 14.1 ns 0.5-1.0 23.2% ns sm:.ns 1.0-3.0 9.65% ns SB-24 8-30-05 0.0 - 0.5 22.9% ns .;; .. ns 0.5 1.0 22.6% 1.0 - 3.0 12.2% 64.4 ns 1.26 ns 8-30-05 0.0 - 0.5 24.5% '«r ns 1.0 - 3.0 30.7% r7 S B-26 8-30-05 0.0 - 0.5 11.5% *186ns 13.9 - ns 0.5-1.0 11.4% *215 ns 1.0-3.0 15.4% *144ns - ns 8-30-05 0.0 0.5 16.8% 8.52ns 20.8 ns 0.5 - 1.0 21.6% 48.1ns 313 ns 1.0 - 3.0 16.4% 33.2 ns. ! ns SB-28ns 840-05 0.0-0.5 12.7% 15.6 ns 15.9 ns 0.5-1.0 17.3% 40.6 ns ` -. , x f 1.0-3.0 8.04% *111 ns 1.87ns SB-29 8-31-05 0.0-0.5 0.5 -1.0 18.1% 1.94 nsns .�s� =_ 17.3% 2.37 ns ----- ' 1.0 - 3.0 17.6% 20.1 ns j .-'.ns SB-30 8-31-05 0.0 - 0.5 13.0% 27.7 ns 16.7 ns ns 0.5 - 1.0 8.24% 27.3 ns 1.0 -3.0 13.3% 12.0 ns ns MDC Chapter 24-11, Residential Exposure SCTLs mg/kg) _ 1400 NA NA • �� .. NA >. MDC Chapter 24-11, Commercial/Industrial SCTLs (mg/kg) NA 15 12 NA NA MDC Chapter 24-11 Groundwater Criteria (ug/L) Note: NS - Sample archived at laboratory but Not Submitted for analysis. BDL - Below laboratory detection limit NA - Not applicable DV 02-204 i TABLE 7 SOIL ANALYTICAL RESULTS - As & Pb (Page 4 of 6) Melreese Golf Course 1802 Northwest 37th Avenue Miami, Miami -Dade County, Florida DERM AW-284/File-9442 Soil Boring Location & Date Sample Interval (Feet, BG) Percent Moisture Lead mg/kg TCLP Lead ug/L Arsenic mg/kg SPLP Arsenic ug/L 0.0 - 0.5 13.5% 62 ns 4' 7 ns SB-31 8-31-05 0.5 - 1.0 - 18.4% 53.0 ns :(1. - ns 1.0-3.0 15.7% *231 ns_32 ns SB-32 0.0 - 0.5 28.7% 4.30 ns t372 ns 8-31-05 0.5 - 1.0 19.2% 67.9 ns _< ns 1.0 - 3.0 11.4% *186 ns ns SB-33 0.0 - 0.5 9.60% 2.98 ns ns 8-31-05..._� 0.5 - 1.0 20.6% 21.2 ns * ns ; 1.0 - 3.0 26.7% '647 ns � .:: Est- ns SB-34 0.0 - 0.5 19.8% 20.6 51.2 ns ns 16.4 ns 8-31-05 0.5 - 1.0 11.5% ' , =.. 6 1.0-3.0 13.7% 89.7 ns •Y ns SB-35 0.0 - 0.5 31.1% 3.97 ns x ; ns 8-31-05 0.5 - 1.0 21.3% 8.42 ns _ ns 1.0 - 3.0 11.9% 9.58 ns 1.37 ns SB-36 0.0 0.5 21,2% 2.06 ns f,�` ns 8-31-05 0.5 - 1.0 21.4% 20.5 ns 14.4 ns 1.0 - 3.0 21.6% 25.4 ns .-•_�' SB-37 0.0-0.5 27.1% 4.36 ns 17.0 ns 8-31-05 0.5 - 1.0 25.4% 21.1 ns _yr_ ns 1.0 - 3.0 11.2% 1.15 ns 0.732 ns SB-38 0.0 - 0.5 19.0% 1.53 ns 21.5 ns 8-31-05 0.5 - 1.0 10.9% 1.55 ns ns 1.0-3.0 16.1% 5.11 ns ns SB-39 0.0 0.5 19.6% 2.54 ns = ns 9-1-05 0.5 - 1.0 29.3% 14.6 ns . ns 1.0-3.0 21.4% 63.8 ns ns SB-40 0.0 - 0.5 29.1% 3.75 ns ns 9-1-05 0.5 - 1.0 21.2% *155 ns - ns 1.0 -3.0 47.2%102 ns # - `. ns MDC Chapter 24-11, Residential Exposure, SCTLs (mg/kg) NA NA z` MDC Chapter 24-11, Commercialllndustrial SCTLs (mg/kg) 1400 NA 12 NA MDC Chapter 24-11 Groundwater Criteria (ug/L) NA rim - yy NA Sty-i3 Note: NS - Sample archived at laboratory but Not Submitted for analysis. BDL - Below laboratory detection limit NA - Not applicable DV 02-204 r• t TABLE 7 SOIL ANALYTICAL RESULTS - As & Pb (Page 5 of 6) Melreese Golf Course 1802 Northwest 37th Avenue Miami, Miami -Dade County, Florida DERM AW-284/File-9442 Soil Boring Location & Date Sample Interval (Feet, BG) Percent Moisture Lead mg/kg TCLP Lead ug/L Arsenic mg/kg SPLP Arsenic ug/L SB-41 9-1-05 0.0 - 0.5 20.4% 6.29 ns = 12.9 ns 1.. ns `..-. 0.5 - 1.0 1.0-3.0 23.4% *205 24.6% 414 136ns SB-42 9-1-05 0.0 - 0.5 44.7% 462ns 0.5 - 1.0 16.2% 4.11 F _sns 1.0 - 3.0 18.9% • SB-43¢ 9-1-05 0.0-0.5 34.7% 06 0.5 - 1.0 16.4% 5.94 _: ns 1.0-3.0 ns 9B5 -44 0.0-0.5 29.6% 2.93ns ns:` 27.4 ns ns 0.5-1.0 '. : 1.05 1.0 - 3.0 1.12ns0.645ns SB-45 9-1.05 0.0-0.5 27.4%1.16 0.5-1.0 a 'ns ' ns 1.0 - 3.0 17.7%4 = SB-46 9-1-05 0.0 - 0.5 24.7% 10.4ns ns 0.5 - 1.0 19.6% 99.2 ns 13.3 ns 1.0-3.0 ° 17.6/° 74.4 yam: . ns SB-47 9-1-05 0.0 - 0.5 20,1 % 8.74ns 17.3 ns 0.5 - 1.0 12.0% 22.0 >- ham; 1.0-3.0 12.6% 2.32 ns`.ns SB-48 9-1-05 0.0 0.5 31.9% 20.0 ns ns 0.5 - 1.0 17.4% 76.6 li• ns 1.0 - 3.0 14.7% 0.879 ns0.774ns SB-49 9-1-05 0.0-0.5 28.5% *213 4.19 13.7 ns 0.5 - 1.0 30.3% _; 1.0 - 3.0 33.5% *117 S B-05 9-1-05 0.0 - 0.5 32.7% -.- ns 23.9 ns ns - 0.5 - 1.0 23.6% *227 ns 1.0 -3.0 24.2% *249 ns'�"ns Y MDC Chapter 24-11, Residential ExposureNA SCTLs m • /kg) r ' NA MDC Chapter 24-11, Commercial/Industrial SCTLs (mg/kg) 1400 NA 12 NA NA r. MDC Chapter 24-11 Groundwater Criteria (ug/L) NA 1 r _ Note: NS - Sample archived at laboratory but Not Submitted for analysis. BDL - Below laboratory detection limit NA - Not applicable DV 02-204 i i i t i t t Limited Phase II Soil Assessment Report Melreese Golf Course 1802 Northwest 37th Avenue Miami, Miami -Dade County, Florida October 26, 2005 4.0 CONCLUSIONS The conclusions provided below are based on information obtained by PHI during implementation of the Limited Phase II Soil Assessment and our experience at somewhat similar sites incinerator ash and agrochemical -applied Arsenic sites in Miami -Dade County. Since the utilization and contaminant history of no two sites are ever the same, PHI reserves the right to make corrections or revisions to our recommendations based upon the availability of new or additional information. Based upon this investigation, indications are that portions of the subject property appear to have been affected through two distinct site activities that have resulted in the detection of elevated levels of Arsenic and Lead. Arsenic Arsenic was detected in the soils beneath the Melreese Golf Course, which has been in continuous operation for over 40 years. The detection of the elevated Arsenic concentrations is a common occurrence in Miami - Dade County golf courses and was the technical subject of a December 2002 DERM Technical Report entitled "Environmental Quality Monitoring at Five Municipal Golf Course in Miami -Dade". This technical report concluded that, based on DERM-sponsored sampling and analyses results, 94% of the surficial soil samples at the five golf courses exceeded the Residential MDC Chapter 24-11 SCTL of 0.7 mg/kg and that 87% of the soil samples exceeded the MDC Chapter 24-11 Commercial /Industrial SCTL of 3.7 mg/kg. The findings of the report further concluded that the golf course surficial soils contained a medial Arsenic concentration of 15.10 mg/kg and that all golf course soils contained a median Arsenic concentration of 5.6 mg/kg. Arsenic concentrations detected at the Melreese Golf Course are statistically similar to the DERM reported arsenic concentrations present at the five municipal golf courses in Miami Dade county summarized by PHI in Table 2, Appendix A. Quite simply the elevated Arsenic concentrations detected at this site are the result of over 40 years of continuous application of various EPA -approved Arsenic -containing agrochemicals. Since these agrochemicals were applied in accordance with then -applicable EPA guidelines, their presence should be no surprise; and based on MDC Chapter 24-11, Section 24-11.1(2)(E)(3) guidelines should not be the source of any future regulatory action. It should also be understood that the City of Miami has no intentions of converting this i A:Ulelreese_SB Asscssmem_Reportl 1),doc 7 DV 02-204 PETRO HYDRO, INC. EnvironmennL3: Enyineeriny General Coltraczors & Underground Utitties G License 4'. CG-0051799 1 Bahrain Armakan, P.E. — Vice President Fla. Reg. Engineer No. 51280 SURFACE WATER QUALITY REPORT Melreese Golf Course 1802 Northwest 37th Avenue Miami, Miami -Dade County, Florida 33125 DERM AW-284/File-9442 PHI Project #05E031 November 2, 2005 Prepared for: TECHNICAL REPORT 17dEPIET) NOV 0 3 2005 DERM POLLUTION CONTROL DIVISION City of Miami — Department of Economic Development Miami Riverside Center 444 Southwest 2nd Avenue, 3rd Floor Miami, Florida 33130 Submitted by: Petro Hydro, Inc. 10450 NW 31s` Terrace Miami, Florida 33172 PHI Project #05E031 Prepared and Reviewed by: Greg A.=Mvlohi R.G. - L pniol•itraject Manager Fla. Lic -moo PU C403 0 z • e/- NL Gov 10450 N.W. 31 st Terrace / M ami, FL 33172 / Phone: 305-477-0878 / Fax: 305-594-8982 DV 02-204 NM INN MIN NMI NE MN 1111.1 NMI INN INN INN 16111 NIII LEGEND Solt boring location (conducted August 29 - September 2, 2005) Apparent Incinerator ash V No apparent Incinerator ash Surface water sample location (conducted October 18, 2005) Surface water sample (SW) Sample Locations Arsenic (uglL) 26 Lead (ugA-) <5 0' 250' 500' Scab In feet PIETROO HYDRO, ©9 [NC. 50 NW 39 Terrace, Miami, Florida Phone: 305-477-0878 Fax: 305-594-8982 MTV OF MGM M LREESE, ©DU ©CURSE 1802 NW 37th Avenue Miami, Florida MUM 2 Bedlam Water Concentration Map 1 r TABLE 1 SURFACE WATER ANALYTICAL RESULTS Melreese Golf Course 1802 Northwest 37th Avenue Miami, Miami -Dade County, Florida DERM AW-284/File-9442 October 18, 2005 Surface Water Location Sample Depth (below surface) Arsenic (ug/L) Lead (ug/L) SW-1 6 - 12 Inches 26 <5 SW-2 6 - 12 Inches 41 <5 SW-3 6 -12 Inches 28 <5 SW-4 6 - 12 Inches 28 <5 SW-5 6 - 12 Inches 27 <5 SW-6 6 - 12 Inches 29 <5 SW-7 6 - 12 Inches 30 <5 SW-8 6 - 12 Inches 20 <5 SW-9 6 - 12 Inches 36 <5 SW-10 6 - 12 Inches <5 <5 SW-11 6 - 12 Inches <5 <5 MDC Chapter 24-11 Groundwater Criteria (ug/L) 10 15 MDC Chapter 24-11 Freshwater Surface Water Criteria (ug/L) 50 '" MDC Chapter 24-11 Marine Surface Water Criteria (ug/L) 50 8.5 Note: *** - Not to exceed 10% above ambient, as set forth in MDC Section 24-42(4). Surface water samples collected in accordance with DEP-SOP-001/01 FS 21000 Surface Water Sampling procedures. DV 02-204 MIAMI-DADE COUNTY, FLORIDA MIAMI-DADE ERM Joe Arriola, City Manager City of Miami 444 Southwest 2nd Avenue Miami, Florida 33130 ENVIRONMENTAL. RESOURCES MANAGEMENT POLLUTION CONTROL DIVISION 33 S.W. 2nd AVENUE SUITE 800 MIAMI, FLORIDA 33130-1540 July 8, 2004 (305) 372-6817 CERTIFIED MAIL NO. 7000 1670 0005 4645 3468 RETURN RECEIPT REQUESTED RE: Site Assessment Report Addendum (SARA)/No Further Action Plan (NFAP) dated June 14, 2004 and prepared by URS Corporation for the Notice of Violation dated March 11, 2003 for the International Links of Miami facility (AW-284/File# 9442) located at, near, or in the vicinity of 1802 NW 37th Avenue, Miami, Miami -Dade County, Florida. Dear Mr. Arriola: The Pollution Remediation Section of the Department of Environmental Resources Management (DERM) has reviewed the analytical results received June 22, 2004, for the above -referenced site. Based on the information, no further remedial action is required by the Pollution Remediation Section at this time. This approval pertains only to that area of this site addressed in the above -referenced report and does not relieve responsibility for any other areas of this site that may be found to be contaminated. If subsequent evidence indicates that undiscovered contamination remains from a previous discharge or if a new discharge has occurred, then further action will be required to address the contamination. You are required to properly abandon all monitoring wells, except compliance wells required by DERM for release detection, within 60 days of receipt of this letter. The monitoring wells must be abandoned in accordance with the requirements of Rule 62-532.500(4), Florida Administrative Code. Any monitoring wells remaining are the responsibility of the property owner(s) and must be equipped with tight -sealing, locking caps and maintained to prevent any direct discharge to the groundwater of Miami - Dade County. If you have any questions regarding this letter, please contact Rodolfo Rego of the Pollution Remediation Section at (305) 372-6700. RR pc: Sincerely, brLd Wilbur Mayorga, P.E., Chief Pollution Remediation Section Alberto Ruder, Director, City of Miami Parks and Recreation Department, 444 SW 2" 1 Ave, 8th Floor, Miami, Florida 33130 Paula Sessions, P.G., URS Corp., 7650 Corporate Center Drive, Suite 401, Miami, FL 33126 Charles DeLucca, Bunkers of Miami, 1802 NW 37th Ave, Miami, FL 33125 DV 02-204 -- = --s--I--a.--- M-- —_— --ram_ L MW-28 LEGEND 200 cr or GI. bona Hs. Phonon Po enwnt Asphalt Concrete Type s-Ip (Thickness As Noted) S. Compacted thwack Bose Course 12' Sla6si>ed Subbase Construct EFNIra6on Trench W/ I5' Di. P.rforaled H.OP.0 Oroe.oge PP. Unless °Menet:e 9o.n On Pions Per Detoi Shorn On Sheol C-15 Constmcl 15' Din Solid 6D.P.E. Dratnage Pipe As Shown On Mon. Conelracl Colcl Born Per Storm Dmimgs Structure Schedule An4 Dolph On C-IJ CB -I Structure MoMor Shod". monitoring roll (MW) ♦ Soi boring (SE - conducted 11/B-9/05 by PH) v Soil boring (SO - conducted 6/22/05 by PIS) (----) I 1P-It Invesligolion onto (June 2005) L — — J April 10-14. 20(18 Source .amount to 3.5' depth BLS 2067.81 tons removed June 2006 Limited♦41 tl source removal to 2.0' depth BLS I1 11 N •gym Impacted soil not exaaoled 11 11 MW-27 MW-26 rH-J MW-24 it 5$' 57'; 42♦\r 62 6364 ♦40 39♦♦ -- ®-5 --59 50 61 117 LF el he hench r-1 34 ♦ I U r1l V33 M -21 II I WW1) ♦29 //1 �/ / I 27� �ir♦261 / // ♦21 r.06-e ♦22 +30 // 1— - _ = — J — G-_— 35V MW 22 ♦38 36 ♦20 MW-20 MW-19 uw-iB.. .7 --.... 15 pad l,M Fd:===__ C8-8 25 50 100 Scale In bet ♦14 ASI:r dt l 49 Vi37 'So 32 •p 31 V• 51 47j 2 W-31 . 16 54 ♦13 45 Original base mop by C3TS & RDC, 2005 PETRO HYDRO, INC. 10450 NW 31 Terrace Miami, Florida 33172 Phone: 305-477-0878 Fax: 305-594-8982 CITY OF MIAMI GRAPELAND HEIGHTS PARK 1550 NW 37 AVENUE, MIAMI, FLORIDA FIGURE 4 SOURCE REMOVAL EXCAVATION MAP Scale as shown Drorm by. ATE 11/2B/05 Checked by. GAM 11/28/05 DV 02-204 M I AM I•DADE COUNTY ADA Coordination Agenda Coordination Animal Services M in Public Places Audit and Management Services Aviation Building Building Code Compliance Business Development Capital Improvements Citizens' Independent Transportation Trust Commission on Ethics and Public Trust Communications Community Action Agency Community & Economic Development Community Relations Consumer Services Corrections & Rehabilitation Cultural Affairs Elections Emergency Management Employee Relations Empowerment Trust Enterprise Technology Services Environmental Resources Management Fair Employment Practices Finance Fire Rescue General Services Administration Historic Preservation Homeless Trust Housing Agency Housing Finance Authority Human Services Independent Review Panel International Trade Consortium Juvenile Assessment Center Medical Examiner Metro -Miami Action Plan Metropolitan Planning Organization Park and Recreation Planning and Zoning Police Procurement Management Propeny Appraisal Public Library System Public Works Safe Neighborhood Parks Seaport Solid Waste Management Strategic Business Management Team Metro Transit Task Force on Urban Economic Revitalization Vizcaya Museum And Gardens Water & Sewer Environmental Resources Management Pollution Control Division 33 SW 2nd Avenue • 7th Floor Miami, Florida 33130-1540 T 305-372-6700 F 305-372-6729 miamidade.gov September 28, 2006 CERTIFIED MAIL NO. 7006 0810 0000 7057 2225 RETURN RECEIPT REQUESTED Pedro Hernandez, City Manager City of Miami 444 Southwest 2nd Avenue Miami, Florida 33130 RE: Northern Arsenic Area Supplemental Site Assessment Report dated August 15, 2006; Soil Sampling and Analyses Plan -Western Tree Area dated August 24, 2006; and Source Removal Soil Waste Disposal Tracking Manifests document dated September 19, 2006 and prepared by Petro Hydro, Inc. for the Grapeland Heights Park (HWR-594/File-9442) located at, near, or in the vicinity of 1550 NW 37th Ave, Miami, Miami -Dade County, Florida. Dear Mr. Hernandez: The Pollution Remediation Section of the Department of Environmental Resources Management (DERM) has reviewed the referenced submittals, received August 16, August 25, and September 19, 2006, respectively, and hereby offers the following comments: Northern (TP-11) Arsenic Area: 1. The arsenic groundwater plume has been adequately defined in this area. Be advised that, based on the conditional closure option elected for this site, a proposal for groundwater monitoring, at a minimum, will be required upon completion of the site assessment activities. Furthermore, monitoring wells that have been destroyed may require replacement upon the proposal for the groundwater remedy (Le. groundwater monitoring). Be advised that DERM does not object to re -sampling the monitoring wells in this area to confirm the results prior to proposing a remedy (Le. groundwater monitoring). However, if this is elected, monitoring well MW-29 shall be replaced and shall be sampled and analyzed for arsenic along with MW-30, MW-31, and MW-32. 2. There are no further requirements for arsenic in soil in this area. Quarterly Groundwater Monitoring Report Grapeland Park Assessment 1550 NW 37th Avenue Miami, Florida HWR-0594/File# 9442 December 13, 2018 E Sciences Project Number 7-0189-008 1 Sciences ENGINEERING ENVIRONMENTAL ECOLOGICAL Prepared for City of Miami 444 SW 2 ' Avenue. 8" Floor Miami, Florida 33130 Submitted to. Miami Dade County Department of Regulatory and Economic Resources 701 NW 1st Court. 4th Floor Miami. Florida 33136 224 SE 9th Street • Fort Lauderdale. FL 33316 • Tel 954-484-8500 • Fax 954-484-5146 • www esciencesinc com 0 Date 11/11/05 6/27/06 3/17/09 7/1/09 7/30/09 10/8/09 4/19/10 1/9/17 12/11/2009 04/19/2010 05/27/2010 08/21/2015 02/102016 07/192017 0926/2017 01/192018 04232018 08/08/2018 Malyte Arsenic (ug/L) ug& - Mcrograms per liter Dissolved -1 MW-32R MW-29R MW-29R Date Arsenic(ug/L) 7/11/05 20 11/11/05 40 3/13/09 <8.5 U 7/1/09 49 7/30109 50 10/8/09 70 4/19/10 51 Arsenic (ug/L) 76 32 360 100 180 280 NS Arsenic (ug/L) 1.49 U 3.61 1.49 U GHP•IW (Former Imgallon Well) tW-R (Replacement Irrigation Well) 4h PH1 Pool Healer Intake U-Analyte was not detected al the laboratory Method Detection Limit (IvDL) The reported value is between the MDL and the laboratory Practical Quanttation Limit (PQL) GCTL - Groundwater Cleanup Target Level as per Chapter 24 of the Mami-Dade County Ordinances NADC - Natural Attenuation Default Concentration as per Table V. Ch. 62 - 777. PAC Bold Black - Indicated an elceedance of the applicable GCTL Bold Red - Indicates an elceedance of the applicable NADC 7/12/05 10/6/06 3/13/09 7/1/09 7/30/09 10/8/09 4/19/10 529/15 8/21/15 12/3/15 3/16/16 1/9/17 626/17 10/12/17 M W-30 R M1N-16 Arsenic (ug/L) Date Arsenic (ug/L) 8/3/06 3/17/09 7/1/09 7/30/09 10/9/09 4/19/10 11/11/05 7/1/09 7/30/09 10/8/09 4/19/10 4/19/10 527/10 529/15 821/15 60A Dissolved- 61.4 12/3115 26.2 3/16/16 1/19/18 29.0 4/23/18 8.7 724/18 5.76 i Legend 9 Monitoring Well Locations Destroyed/Abandoned Monitoring Well Locations ces E Sciences, Incorpornbd FL Engineering Lk. 88861 224 SE 8/0 Sbesl R. L4uden:41c Florida 33318 www./sulenu8lnc.com Phone: 664.184.8600 Fes. 954.484-6146 PROJECTh .• 11: PH2 Pool Heater Recharge Grapeland Park Miami, Miami -Dade County, Florida MW-9R 828/17 10/12/17 1119/18 423/18 7/24/18 11/13/18 <0.36 U 529/15 6/21/15 3/16/16 828/17 10/12/17 1/19/18 724/18 11/13/18 7311 -30R y� Arsenic (ug/L) Arsenic (ug/l) Dissolved -21.71 Date Arsenic (ug/L) 7/13/05 13 10/6/06 <5 3/13/09 <8.5 U 7/1/09 3.4 7/30/09 NS 10/8/09 2.2 4/19/09 NS 8/21/15 6.6 12/3/15 5.0 U 3/16/16 5.0 U 1/9/17 3.1 i 250 Groundwater Analytical Map SCALE: IDATE: 11/2912018 500 FIGURE Feel Table 1: Groundwater Analytical Summary Grapeland Park 1550 NW 37th Avenue, Miami, Florida HWR-0594/File#9442 Sample ID Date Arsenic (pg/L) 04/19/2010 36 MW-A 05/27/2010 39 05/29/2015 100 08/21/2015 80.2 12/03/2015 42.2 03/16/2016 48.5 01/09/2017 21.7 06/26/2017 15.0 10/12/2017 4.5 I 01/19/2018 17.7 04/23/2018 4i 07/24/2018 1.49 U 11/13/2018 1.49 U MW-B 04/22/2010 7.4 05/29/2015 5.0 U 08/21/2015 21.9 12/03/2015 5.2 I 03/16/2016 6.6 I 01/09/2017 7.9 I 06/26/2017 5.0 U 10/12/2017 17.2 01/19/2018 10.00 04/23/2018 8.3 I 07/24/2018 5.59 I 11/13/2018 7.3i MW-3R 07/13/2005 13 10/06/2006 <5 03/13/2009 <8.5 U 07/01/2009 3.4 07/30/2009 NS 10/08/2009 2.2 04/19/2010 NS 08/21/2015 6.6 I 12/03/2015 5.0 U 03/16/2016 5.0 U 01/09/2017 3.1 I Table 1: Groundwater Analytical Summary Grapeland Park 1550 NW 37th Avenue, Miami, Florida HWR-0594/File#9442 Sample ID Date Arsenic (µg/L) !`r,1^, gR 07/12/2005 19 10/06/2006 15 03/13/2009 <5.5 U 07/01/2009 55 07/30/2009 58 10/08/2009 92 04/19/2010 180 05/29/2015 93.8 08/21/2015 99.6 12/03/2015 101 03/16/2016 110 01/09/2017 61.4 06/26/2017 26.2 10/12/2017 19.4 01/19/2018 29.0 04/23/2018 8.71 07/24/2018 5.76 GHP-IW (Former Irrigation Well) 10/22/2009 5.8 12/11/2009 6.4 04/19/2010 14 05/27/2010 4.7 05/29/2015 15.7 08/21/2015 12.1 IW-R (Replacement Irrigation Well) 02/10/2016 5.0 U 01/09/2017 2.5 U 07/19/2017 5.0 U 09/26/2017 1.49 U 01/19/2018 3.6 1 04/23/2018 1.49 U 08/08/2018 1.49U I� \^ 29F 07/11/2005 20 11/11/2005 40 03/13/2009 <8.5 U 07/01/2009 49 07/30/2009 50 10/08/2009 70 04/19/2010 51 NAVV30R 11/11/2005 40 06/29/2006 30 03/13/2009 <8.5 U 07/01/2009 27 07/30/2009 41 10/08/2009 49 04/19/2010 NS Table 1: Groundwater Analytical Summary Grapeland Park 1550 NW 37th Avenue, Miami, Florida HWR-0594/File#9442 Sample ID Date Arsenic (Ng/1.) MW-31 11/11/2005 76 06/27/2006 32 03/17/2009 360 07/01/2009 100 07/30/2009 180 10/08/2009 280 04/19/2010 NS 01/09/2017 114 MW-32R 08/03/2006 <5 03/17/2009 <8.5 U 07/01/2009 1.3 07/30/2009 NS 10/09/2009 <.36 U 04/19/2010 NS GCTL 10 NADC 100 Notes: µg/L: micrograms per liter U: flag indicates concentration Was below the method detection lint (MDL). I: flag indicates concentration was between the MDL and practical quantization lint (PQL). GCTL: Groundwater Cleanup Target Level as per Chapter 24 of Miami -Dade Code of Ordinances NADC: Natural Attenuation Default Concentration as per Table V. Ch. 62-777, FAC. IW-R (Replacement hrigation Well) Bold: Indicates an exceedance of the applicable GCTL. Bold: Indicates an exceedance of the applicable NADC. EEG Environmental Services, LLC 5751 Miami Lakes Drive Miami Lakes, Florida 33014 Phone (305)374-8300 Fax (305)374-9004 Melreese Golf Course 1400 NW 37th Ave & 1550 NW 37th Ave Miami, FL 33125 Project #: 2018-3057.JPH1 1938 AERIAL PHOTOGRAPH EEG Environmental Services, LLC 5751 Miami Lakes Drive Miami Lakes, Florida 33014 Phone (305)374-8300 Fax (305)374-9004 Melreese Golf Course 1400 NW 37th Ave & 1550 NW 37th Ave Miami, FL 33125 Project #: 2018-3057.JPH1 1940 AERIAL PHOTOGRAPH Environmental Services, LLC EEG APPROXIMATE PROPERTY LOCATION Melreese Golf Course 1400 NW 37th Ave & 1550 NW 37th Ave Miami, FL 33125 Project #: 2018-3057.JPH1 5751 Miami Lakes Drive Miami Lakes, Florida 33014 Phone (305)374-8300 Fax (305)374-9004 1951 AERIAL PHOTOGRAPH EE6G Environmental Services, LLC 5751 Miami Lakes Drive Miami Lakes, Florida 33014 Phone (305)374-8300 Fax (305)374-9004 Melreese Golf Course 1400 NW 37th Ave & 1550 NW 37th Ave Miami, FL 33125 Project #: 2018-3057.JPH1 1961 AERIAL PHOTOGRAPH 5751 Miami Lakes Drive Miami Lakes, Florida 33014 Phone (305)374-8300 Fax (305)374-9004 EE6G Environmental Services, LLC APPROXIMATE PROPERTY LOCATION Melreese Golf Course 1400 NW 37th Ave & 1550 NW 37th Ave Miami, FL 33125 Project #: 2018-3057.JPH1 1963 AERIAL PHOTOGRAPH 5751 Miami Lakes Drive Miami Lakes, Florida 33014 Phone (305)374-8300 Fax (305)374-9004 EEG Environmental Services, LLC APPROXIMATE PROPERTY LOCATION Melreese Golf Course 1400 NW 37th Ave & 1550 NW 37th Ave Miami, FL 33125 Project #: 2018-3057.JPH1 1968 AERIAL PHOTOGRAPH EEG Environmental Services, LLC APPROXIMATE PROPERTY LOCATION 5751 Miami Lakes Drive Miami Lakes, Florida 33014 Phone (305)374-8300 Fax (305)374-9004 A • -'• •r••--..F •.•.r •• • a I ice ._ T. ■•. •.• .. • . .. • Melreese Golf Course 1400 NW 37th Ave & 1550 NW 37th Ave Miami, FL 33125 Project #: 2018-3057.JPH1 1971 AERIAL PHOTOGRAPH 5751 Miami Lakes Drive Miami Lakes, Florida 33014 Phone (305)374-8300 Fax (305)374-9004 EE?G Environmental Services, LLC APPROXIMATE PROPERTY LOCATION Melreese Golf Course 1400 NW 37th Ave & 1550 NW 37th Ave Miami, FL 33125 Project #: 2018-3057.JPH1 1973 AERIAL PHOTOGRAPH 5751 Miami Lakes Drive Miami Lakes, Florida 33014 Phone (305)374-8300 Fax (305)374-9004 EEG Environmental Services, LLC APPROXIMATE PROPERTY LOCATION Melreese Golf Course 1400 NW 37th Ave & 1550 NW 37th Ave Miami, FL 33125 Project #: 2018-3057.JPH1 1978 AERIAL PHOTOGRAPH EEG Environmental Services, LLC 5751 Miami Lakes Drive Miami Lakes, Florida 33014 Phone (305)374-8300 Fax (305)374-9004 Melreese Golf Course 1400 NW 37th Ave & 1550 NW 37th Ave Miami, FL 33125 Project #: 2018-3057.JPH1 1985 AERIAL PHOTOGRAPH 5751 Miami Lakes Drive Miami Lakes, Florida 33014 Phone (305)374-8300 Fax (305)374-9004 EE6G Environmental Services, LLC APPROXIMATE PROPERTY LOCATION Melreese Golf Course 1400 NW 37th Ave & 1550 NW 37th Ave Miami, FL 33125 Project #: 2018-3057.JPH1 1991 AERIAL PHOTOGRAPH EE6G Environmental Services, LLC 5751 Miami Lakes Drive Miami Lakes, Florida 33014 Phone (305)374-8300 Fax (305)374-9004 APPROXIMATE PROPERTY LOCATION • ,. 4 .va I� r 4 y { . Pt" _ - 44 Melreese Golf Course 1400 NW 37th Ave & 1550 NW 37th Ave Miami, FL 33125 Project #: 2018-3057.JPH1 1994 AERIAL PHOTOGRAPH EEG Environmental Services, LLC 5751 Miami Lakes Drive Miami Lakes, Florida 33014 Phone (305)374-8300 Fax (305)374-9004 APPROXIMATE PROPERTY LOCATION ifir+l�tY _ r 40 - BSI 1. Melreese Golf Course 1400 NW 37th Ave & 1550 NW 37th Ave Miami, FL 33125 Project #: 2018-3057.JPH1 1998 AERIAL PHOTOGRAPH 5751 Miami Lakes Drive Miami Lakes, Florida 33014 Phone (305)374-8300 Fax (305)374-9004 EE6G Environmental Services, LLC APPROXIMATE PROPERTY LOCATION Melreese Golf Course 1400 NW 37th Ave & 1550 NW 37th Ave Miami, FL 33125 Project #: 2018-3057.JPH1 2003 AERIAL PHOTOGRAPH EE6G Environmental Services, LLC 5751 Miami Lakes Drive Miami Lakes, Florida 33014 Phone (305)374-8300 Fax (305)374-9004 APPROXIMATE PROPERTY LOCATION .). A. A--f -. • .�•T • • w. 4. . Ttcr elta• t.•rt • ter,.-e s, e► tn.• ra . F Melreese Golf Course 1400 NW 37th Ave & 1550 NW 37th Ave Miami, FL 33125 Project #: 2018-3057.JPH1 2006 AERIAL PHOTOGRAPH 5751 Miami Lakes Drive Miami Lakes, Florida 33014 Phone (305)374-8300 Fax (305)374-9004 EE6G Environmental Services, LLC APPROXIMATE PROPERTY LOCATION Melreese Golf Course 1400 NW 37th Ave & 1550 NW 37th Ave Miami, FL 33125 Project #: 2018-3057.JPH1 2007 AERIAL PHOTOGRAPH 5751 Miami Lakes Drive Miami Lakes, Florida 33014 Phone (305)374-8300 Fax (305)374-9004 EE6G Environmental Services, LLC APPROXIMATE PROPERTY LOCATION Melreese Golf Course 1400 NW 37th Ave & 1550 NW 37th Ave Miami, FL 33125 Project #: 2018-3057.JPH1 2010 AERIAL PHOTOGRAPH EEG Environmental Services, LLC APPROXIMATE PROPERTY LOCATION 5751 Miami Lakes Drive Miami Lakes, Florida 33014 Phone (305)374-8300 Fax (305)374-9004 : 11ss•H:1 i's• "ti ✓- Melreese Golf Course 1400 NW 37th Ave & 1550 NW 37th Ave Miami, FL 33125 Project #: 2018-3057.JPH1 2014 AERIAL PHOTOGRAPH 5751 Miami Lakes Drive Miami Lakes, Florida 33014 Phone (305)374-8300 Fax (305)374-9004 EEG Environmental Services, LLC APPROXIMATE PROPERTY LOCATION Melreese Golf Course 1400 NW 37th Ave & 1550 NW 37th Ave Miami, FL 33125 Project #: 2018-3057.JPH1 2017 AERIAL PHOTOGRAPH EEG Environmental Services, LLC 5751 Miami Lakes Drive Miami Lakes, Florida 33014 Phone (305)374-8300 Fax (305)374-9004 Melreese Golf Course 1400 NW 37th Ave & 1550 NW 37th Ave Miami, FL 33125 Project #: 2018-3057.JPH1 2019 AERIAL PHOTOGRAPH EE&G: Site Rehabilitation Plan August 2019 APPENDIX C SOIL FIELD LOGS, 95% UCL CALCUTIONS & RESULTS NOTE: LABORATORY DATA PROVIDED ON SEPARATE FILE DUE TO SIZE RESTRICTIONS Petro Hydro Soil Results - Supplemental SAR - September 2006 Melreese Golf Course 0 to 0.5-feet BLS Interval Normal UCL Statistics for Uncensored Full Data Sets User Selected Options Date/Time of Computation From File Full Precision Confidence Coefficient CO General Statistics Total Number of Observations Minimum Maximum SD Coefficient of Variation ProUCL 5.16/15/2019 12:39:19 AM WorkSheet.xls OFF 95% Normal GOF Test Shapiro Wilk Test Statistic 5% Shapiro Wilk Critical Value Lilliefors Test Statistic 5% Lilliefors Critical Value Data appear Approximate Normal at 5% Significance Level Assuming Normal Distribution 95% Normal UCL 95% Student's-t UCL 50 Number of Distinct Observations Number of Missing Observations 1.15 Mean 37.9 Median 8.848 SD of logged Data 0.68 Skewness 0.916 Shapiro Wilk GOF Test 0.947 Data Not Normal at 5% Significance Level 0.111 Lilliefors GOF Test 0.125 Data appear Normal at 5% Significance Level 95% UCLs (Adjusted for Skewness) 15.11 95% Adjusted-CLT UCL (Chen-1995) 95% Modified-t UCL (Johnson-1978) Suggested UCL to Use 95% Student's-t UCL 15.11 47 0 13.02 11.55 0.795 0.952 15.25 15.14 When a data set follows an approximate (e.g., normal) distribution passing one of the GOF test When applicable, it is suggested to use a UCL based upon a distribution (e.g., gamma) passing both GOF tests in ProUCL Note: Suggestions regarding the selection of a 95% UCL are provided to help the user to select the most appropriate 95% UCL. Recommendations are based upon data size, data distribution, and skewness. These recommendations are based upon the results of the simulation studies summarized in Singh, Maichle, and Lee (2006). However, simulations results will not cover all Real World data sets; for additional insight the user may want to consult a statistician. Data Set 8.09 4.42 37.9 11.5 5.13 13.6 2.32 2.38 32.5 10.9 34.5 4.55 27.1 4.26 16.4 18.2 8.29 23.5 11.2 1.15 12 23.4 14.1 6.19 5.23 13.9 12.9 11.7 8.72 27.4 11.6 3.74 17.3 9.58 13.7 23.9 20.8 15.9 10.6 16.7 4.97 8.72 2.25 16.4 3.63 4.75 17 21.5 3.63 10.7 Table A - 95% UCL Arsenic in Soils @ 0 to 0.5-feet BLS Gamma UCL Statistics for Uncensored Full Data Sets User Selected Options Date/Time of Computation ProUCL 5.15/1/2019 3:43:11 PM From File WorkSheet.xls Full Precision OFF Confidence Coefficient 95% Number of Bootstrap Operations 2000 CO General Statistics Total Number of Observations 37 Number of Distinct Observations 36 Number of Missing Observations 0 Minimum 0.6 Mean 19.67 Maximum 156 Median 14.3 SD 25.41 SD of logged Data 1.1 Coefficient of Variation 1.292 Skewness 4.496 Gamma GOF Test A-D Test Statistic 0.691 Anderson -Darling Gamma GOF Test 5% A-D Critical Value 0.774 Data appear Gamma Distributed at 5% Significance Level K-S Test Statistic 0.149 Kolmogorov-Smirnov Gamma GOF Test 5% K-S Critical Value 0.149 Data Not Gamma Distributed at 5% Significance Level Data appear to Follow Approximate Gamma Distribution at 5% Significance Level Gamma Statistics k hat (MLE) Theta hat (MLE) nu hat (MLE) MLE Mean (bias corrected) Adjusted Level of Significance Assuming Gamma Distribution 95% Approximate Gamma UCL (use when n>=50) Suggested UCL to Use 95% Adjusted Gamma UCL 26.45 1.14 k star (bias corrected MLE) 17.26 Theta star (bias corrected MLE) 84.35 nu star (bias corrected) 19.67 MLE Sd (bias corrected) Approximate Chi Square Value (0.05) 0.0431 Adjusted Chi Square Value 1.066 18.46 78.85 19.06 59.39 58.66 26.12 95% Adjusted Gamma UCL (use when n<50) 26.45 When a data set follows an approximate (e.g., normal) distribution passing one of the GOF test When applicable, it is suggested to use a UCL based upon a distribution (e.g., gamma) passing both GOF tests in ProUCL Note: Suggestions regarding the selection of a 95% UCL are provided to help the user to select the most appropriate 95% UCL. Recommendations are based upon data size, data distribution, and skewness. These recommendations are based upon the results of the simulation studies summarized in Singh, Maichle, and Lee (2006). However, simulations results will not cover all Real World data sets; for additional insight the user may want to consult a statistician. Data Set: 0 - 0.5 (Feet BLS) 16.9 17.3 23.0 156 47.8 13.3 18.8 29.8 2.3 12.6 8.7 11.3 2.5 31.0 2.8 0.94 14.3 13.6 22.9 27.8 19.5 12.8 30.2 29.3 19.4 19.5 5.5 3.6 27.5 27.7 6.0 7.7 0.6 9.2 3.4 20.4 12.0 Table A-2 - 95% UCL Arsenic in Soils @ 0 to 0.5-feet BLS (Less 156 mg/Kg Hotspot - Removed From Dataset) Normal UCL Statistics for Uncensored Full Data Sets User Selected Options Date/Time of Computation ProUCL 5.16/15/2019 12:52:19 AM From File WorkSheet.xls Full Precision OFF Confidence Coefficient 95% CO Note: 156 mg/Kg Removed General Statistics Total Number of Observations 36 Number of Distinct Observations 35 Number of Missing Observations 0 Minimum 0.6 Mean 15.89 Maximum 47.8 Median 13.95 SD 10.89 SD of logged Data 1.025 Coefficient of Variation 0.685 Skewness 0.666 Normal GOF Test Shapiro Wilk Test Statistic 5% Shapiro Wilk Critical Value Lilliefors Test Statistic 5% Lilliefors Critical Value Data appear Normal at 5% Significance Level Assuming Normal Distribution 95% Normal UCL 95%Student's-t UCL 0.944 Shapiro Wilk GOF Test 0.935 Data appear Normal at 5% Significance Level 0.0857 Lilliefors GOF Test 0.145 Data appear Normal at 5% Significance Level 95% UCLs (Adjusted for Skewness) 18.95 95% Adjusted-CLT UCL (Chen-1995) 95% Modified-t UCL (Johnson-1978) Suggested UCL to Use 95% Student's-t UCL 18.95 19.09 18.99 Note: Suggestions regarding the selection of a 95% UCL are provided to help the user to select the most appropriate 95% UCL. Recommendations are based upon data size, data distribution, and skewness. These recommendations are based upon the results of the simulation studies summarized in Singh, Maichle, and Lee (2006). However, simulations results will not cover all Real World data sets; for additional insight the user may want to consult a statistician. Data Set: 0 - 0.5 (Feet BLS) 16.9 17.3 23.0 47.8 13.3 18.8 29.8 2.3 12.6 8.7 11.3 2.5 31.0 2.8 0.94 14.3 13.6 22.9 27.8 19.5 12.8 30.2 29.3 19.4 19.5 5.5 3.6 27.5 27.7 6.0 7.7 0.6 9.2 3.4 20.4 12.0 Table B - 95% UCL Arsenic Soils @ 0.5 to 2-ft BLS (Less Highest Arsenic Value) Gamma UCL Statistics for Uncensored Full Data Sets 0.5 - 2 (Feet BLS) User Selected Options Date/Time of Computation ProUCL 5.15/1/2019 3:52:59 PM From File WorkSheet.xls Full Precision OFF Confidence Coefficient 95% Number of Bootstrap Operations 2000 CO General Statistics Total Number of Observations 36 Number of Distinct Observations 32 Number of Missing Observations 0 Minimum 0.145 Mean 11.26 Maximum 52.8 Median 9.7 SD 10.78 SD of logged Data 1.342 Coefficient of Variation 0.957 Skewness 2.093 Gamma GOF Test A-D Test Statistic 5% A-D Critical Value K-S Test Statistic 5% K-S Critical Value Data appear Gamma Distributed at 5% Significance Level Gamma Statistics k hat (MLE) Theta hat (MLE) nu hat (MLE) MLE Mean (bias corrected) Adjusted Level of Significance Assuming Gamma Distribution 95% Approximate Gamma UCL (use when n>=50) Suggested UCL to Use 95% Adjusted Gamma UCL 15.5 0.548 Anderson -Darling Gamma GOF Test 0.776 Data appear Gamma Distributed at 5% Significance Level 0.111 Kolmogorov-Smirnov Gamma GOF Test 0.151 Data appear Gamma Distributed at 5%Significance Level 1.023 k star (bias corrected MLE) 11.01 Theta star (bias corrected MLE) 73.68 nu star (bias corrected) 11.26 MLE Sd (bias corrected) Approximate Chi Square Value (0.05) 0.0428 Adjusted Chi Square Value 0.957 11.78 68.87 11.52 50.77 50.06 15.28 95%Adjusted Gamma UCL (use when n<50) 15.5 Note: Suggestions regarding the selection of a 95% UCL are provided to help the user to select the most appropriate 95% UCL Recommendations are based upon data size, data distribution, and skewness. These recommendations are based upon the results of the simulation studies summarized in Singh, Maichle, and Lee (2006). However, simulations results will not cover all Real World data sets; for additional insight the user may want to consult a statistician. 15.5 2.3 6.7 12 7 0.15 275 17.9 14.9 13.7 8.2 5 1.7 15.8 12 10.4 9.8 13.3 8.2 1.2 16.1 0.73 30.4 36.4 2.7 9.6 2 0.145 12.5 5.1 5.1 22.7 1.4 52.8 7.4 12 12.7 Removed from Data Set Table C - 95% UCL Arsenic Soil @ 2 to 4-ft BLS Gamma UCL Statistics for Uncensored Full Data Sets User Selected Options Date/Time of Computation ProUCL 5.15/1/2019 4:03:49 PM From File WorkSheet.xls Full Precision OFF Confidence Coefficient 95% Number of Bootstrap Operations 2000 CO General Statistics Total Number of Observations 37 Number of Distinct Observations 35 Number of Missing Observations 0 Minimum 0.135 Mean 18.46 Maximum 89.4 Median 10 SD 22.36 SD of logged Data 1.611 Coefficient of Variation 1.211 Skewness 1.718 Gamma GOF Test A-D Test Statistic 5% A-D Critical Value K-S Test Statistic 5% K-S Critical Value Data appear Gamma Distributed at 5% Significance Level Gamma Statistics k hat (MLE) Theta hat (MLE) nu hat (MLE) MLE Mean (bias corrected) Adjusted Level of Significance Assuming Gamma Distribution 95% Approximate Gamma UCL (use when n>=50) Suggested UCL to Use 95% Adjusted Gamma UCL 27.28 0.208 Anderson -Darling Gamma GOF Test 0.795 Data appear Gamma Distributed at 5% Significance Level 0.0711 Kolmogorov-Smirnov Gamma GOF Test 0.151 Data appear Gamma Distributed at 5% Significance Level 0.678 k star (bias corrected MLE) 27.21 Theta star (bias corrected MLE) 50.19 nu star (bias corrected) 18.46 MLE Sd (bias corrected) Approximate Chi Square Value (0.05) 0.0431 Adjusted Chi Square Value 0.641 28.78 47.46 23.05 32.65 32.11 26.83 95%Adjusted Gamma UCL (use when n<50) 27.28 Note: Suggestions regarding the selection of a 95% UCL are provided to help the user to select the most appropriate 95% UCL. Recommendations are based upon data size, data distribution, and skewness. These recommendations are based upon the results of the simulation studies summarized in Singh, Maichle, and Lee (2006). However, simulations results will not cover all Real World data sets; for additional insight the user may want to consult a statistician. Data Set: 2 to 4-feet BLS 6.2 0.97 0.43 89.4 24.3 0.52 32 26.9 7.8 0.53 10 8.3 47 63 14.4 3.0 9.9 4 12.8 29.5 49.7 0.135 12.8 26.4 7.1 1.6 2.3 0.71 2.4 4.1 3.5 10 16.6 49.3 10.4 19.1 75.9 Table D - 95% UCL Arsenic Soils @ 4 to 6-ft BLS Gamma UCL Statistics for Uncensored Full Data Sets User Selected Options Date/Time of Computation ProUCL 5.15/1/2019 4:13:39 PM From File WorkSheet.xls Full Precision OFF Confidence Coefficient 95% Number of Bootstrap Operations 2000 CO General Statistics Total Number of Observations 15 Number of Distinct Observations 15 Number of Missing Observations 0 Minimum 0.56 Mean 17.27 Maximum 78.1 Median 6.8 SD 21.9 SD of logged Data 1.302 Coefficient of Variation 1.268 Skewness 1.916 Gamma GOF Test A-D Test Statistic 5% A-D Critical Value K-S Test Statistic 5% K-S Critical Value Data appear Gamma Distributed at 5% Significance Level Gamma Statistics k hat (MLE) Theta hat (MLE) nu hat (MLE) MLE Mean (bias corrected) Adjusted Level of Significance Assuming Gamma Distribution 95% Approximate Gamma UCL (use when n>=50) Suggested UCL to Use 95% Adjusted Gamma UCL 33.64 0.456 Anderson -Darling Gamma GOF Test 0.771 Data appear Gamma Distributed at 5% Significance Level 0.186 Kolmogorov-Smirnov Gamma GOF Test 0.229 Data appear Gamma Distributed at 5% Significance Level 0.828 k star (bias corrected MLE) 20.85 Theta star (bias corrected MLE) 24.85 nu star (bias corrected) 17.27 MLE Sd (bias corrected) Approximate Chi Square Value (0.05) 0.0324 Adjusted Chi Square Value 0.707 24.42 21.22 20.54 11.75 10.89 31.18 95% Adjusted Gamma UCL (use when n<50) 33.64 Note: Suggestions regarding the selection of a 95% UCL are provided to help the user to select the most appropriate 95% UCL. Recommendations are based upon data size, data distribution, and skewness. These recommendations are based upon the results of the simulation studies summarized in Singh, Maichle, and Lee (2006). However, simulations results will not cover all Real World data sets; for additional insight the user may want to consult a statistician. Data Set: 4 to 6-ft BLS 4.2 8.2 78.1 3.6 40 3.4 18.2 6.4 12.4 47.7 0.56 22.5 6.8 4.8 2.2 EE&G: Site Rehabilitation Plan August 2019 APPENDIX D GROUNDWATER FIELD LOGS & RESULTS NOTE: LABORATORY DATA PROVIDED ON SEPARATE FILE DUE TO SIZE RESTRICTIONS CALIBRATION AND VERIFICATION LOG (FDEP SOP FT 1000-FT 1500, FD 1000-FD 4000) Meter ID: YSI556 MPM#7 Project: Melreese Golf Course (2018-3057) Boldly"X" this box if there is qualified data on this nnna Notes: (1) Numbers 54, are rounded down; numbers >_ 5 are rounded up (e.g., 5.15 becomes 5.2). (2) Always wait for meter to stabilize before recording any readings. (3) For Calibrations, record calibrated meter reading. Do not record initial meter reading before calibration. Circle/Fill In: Lab Calibration or Calibration/Verification on Site 3-04-2019 Temperature (Quarterly) FT 1400 Date of Last Temperature Verification 2-18-2019 DO DEP SOP FT 1500 Name Date Time CT -ET Temp D.O. Chart mg/L Meter D.O. mg/L % DO Probe Charge Probe Gain Pass / Fail Lab / Field Calibr. Michael Van Ry/EE&G 3-04-2019 0820 25.2 C 100 % 100 p p ICV Michael Van Ry/EE&G 3-04-2019 0825 25.2 C 100 % 100 P p CCV Michael Van Ry/EE&G 3-04-2019 1555 26.7 C 100 % 101 P P CCV Report DO mg/L with one decimal figure and DO % saturation as a whole number with no decimals. DO Acceptance criteria from Table ±0.3 mg/L. Rapid -Pulse Sensors: DO Gain Range 0.7 to 1.4; DO Charge Range 25-75. Optical: DO gain range 0.85 to 1.15; DO charge N/A. Steady-state & Galvanic Sensors: DO Gain & Charge N/A. Spec. Cond. FT 1200 Name Date Time CT -ET Lot # Expir. Date Standard µmhos/cm Meter Reading µmhos/cm Pass / Fail Lab / Field Calibr. Michael Van Ry/EE&G 3-04-2019 0750 8GG805 7/2019 1.413 1.413 P P ICV Michael Van Ry/EE&G 3-04-2019 0755 8GG805 7/2019 1.413 1.413 P P CCV Michael Van Ry/EE&G 3-04-2019 1540 8GG805 7/2019 1.413 1.412 P p CCV Report specific conductance as a whole number with no decimal figure. Conductivity Acceptance criteria ± 5% pH DEP SOP FT 1100 Name Date Time CT -ET Lot # Expir. Date pH Buffer SU Meter reading SU mV Pass / Fail Lab / Field Calibr. Michael Van Ry/EE&G 3-04-2019 0800 8GH706 8/2020 7.0 7.0 P ID Calibr. Michael Van Ry/EE&G 3-04-2019 0805 8GG386 7/2020 4.0 4.0 P ID Calibr. Michael Van Ry/EE&G 3-04-2019 0810 8GG016 7/2020 10.0 10.0 p p ICV Michael Van Ry/EE&G 3-04-2019 0815 8GH706 8/2020 7.0 7.0 p p CCV Michael Van Ry/EE&G 3-04-2019 1536 8GH706 8/2020 7 0 6.9 P P CCV Report pH with one decimal place; pH Acceptance criteria ±0.2 SU; mV pH7 Range 0±50; mV pH 10 Range-180±50; Slope from 7 to 10 and 4 to 7 must be between 165 and 180 mV Depth (Quarterly) Date of Last Depth Verification mV pH 4 Range +180±50; Depth Sensor (Daily) Name Date Time CT -ET Zero the Sensor ICV Value Pass / Fail Lab / Field Pressure mode in air 0.000 ICV acceptance criteria ±5 % or ±0.05m, whichever is greater Turbidity Calibration Log (DEP SOPS FT1000 FT1600) Regional Operations Centers Meter ID: Hach 2100Q Unit #2 Date of Last Calibration: 3-04-2019 Melreese Golf Course Project Name: (2018-3057) QUARTERLY CALIBRATION: Sampler Name: Date: All Times Are : CO3 or CTZ (circle one) Time Performed (24 hr): Standard Value Exp. Date Lot # Calibrated Next Value Shown Pass or Fail? Use Primary Formazin Standards (Yes/No) (Circle One) NTU NTU P F NTU NTU P F NTU NTU P F NTU NTU P F INITIAL CALIBRATION VERIFICATION: Sampler Name: Date/Time (24 hr): Only perform ICV immediately after quarterly calibration. PRIMARY FORMAZIN ICV: Standard Value Exp. Date Lot # Reading Pass or Fail? (circle one) *See Acceptance Criteria Below NTU SECONDARY GEL STANDARD QUARTERLY VERIFICATION: Standard Value Range Previous Reading NTU NTU NTU NTU NTU NTU Exp. Date Lot # NTU P F New Reading Acceptable Range *Calculate using new reading & acceptance criteria below. NTU NTU NTU DAILY CONTINUING CALIBRATION VERIFICATION: Date/Time Sampler Name (24 hr) 3-04-2019 / 0822 Michael Van Ry/EE&G Standard Type Standard Value Exp. Date (circle one) 3-04-2019 / 0822 Michael Van Ry/EE&G 3-04-2019 / 0823 Michael Van Ry/EE&G 3-04-2019 / 0823 Michael Van Ry/EE&G 3-04-2019 / 1600 Michael Van Ry/EE&G Formazin 3-04-2019 / 1600 Michael Van Ry/EE&G 3-04-2019 / 1601 Michael Van Ry/EE&G 3-04-2019 / 1601 Michael Van Ry/EE&G Formazi ormazi Gel / Gel / Gel / Gel Gel 10 NTU Lot # Reading Pass or Fail?* (Circle One) 12/2019 24641-01 10 NTU P F Gel 20 NTU 12/2019 24641-02 NTU pP F NTU NTU �P F 800 NTU 12/2019 24641-04 799 NTU ❑P F 100 10 20 NTU NTU 12/2019 24641-03 19.7 100.2 12/2019 24641-01 10.1 12/2019 24641-02 NTU P F 19.9 NTU F Gel 100 NTU 12/2019 24641-03 100 NTU Q F Gel 800 NTU 12/2019 24641-04 797 NTU P❑ F Formazin / Gel NTU NTU P F Formazin / Gel NTU NTU P F Formazin / Gel NTU NTU P F Formazin / Gel NTU NTU P F *Acceptance Criteria: 0.1-10 NTU 4 ±10 %; 11-40 NTU 4 ±8 %; 41-100 NTU 4 ±6.5 %; >100 NTU 4 ±5 %; Form effective April 1, 2015 CALIBRATION AND VERIFICATION LOG (FDEP SOP FT 1000-FT 1500, FD 1000-FD 4000) Meter ID: YSI 556 MPM # 7 Project: Melreese Golf Course (2018-3057) boldly"X" this box if there is qualified data on this none Notes: (1) Numbers 54, are rounded down; numbers >_ 5 are rounded up (e.g., 5.15 becomes 5.2). (2) Always wait for meter to stabilize before recording any readings. (3) For Calibrations, record calibrated meter reading. Do not record initial meter reading before calibration. Circle/Fill In: Lab Calibration or Calibration/Verification on Site 3-11-2019 Temperature (Quarterly) FT 1400 Date of Last Temperature Verification 2-18-2019 DO DEP SOP FT 1500 Name Date Time CT -ET Temp D.O. Chart mg/L Meter D.O. mg/L % DO Probe Charge Probe Gain Pass / Fail Lab / Field Calibr. Michael Van Ry/EE&G 3-11-2019 0820 26.4 C 100 % 100 p p ICV Michael Van Ry/EE&G 3-11-2019 0825 26.4 C 100 % 100 p P CCV Michael Van Ry/EE&G 3-11-2019 1545 28.9 C 100 % 100 P P CCV Report DO mg/L with one decimal figure and DO % saturation as a whole number with no decimals. DO Acceptance criteria from Table ±0.3 mg/L. Rapid -Pulse Sensors: DO Gain Range 0.7 to 1.4; DO Charge Range 25-75. Optical: DO gain range 0.85 to 1.15; DO charge N/A. Steady-state & Galvanic Sensors: DO Gain & Charge N/A. Spec. Cond. FT 1200 Name Date Time CT -ET Lot # Expir. Date Standard µmhos/cm Meter Reading µmhos/cm Pass / Fail Lab / Field Calibr. Michael Van Ry/EE&G 3-11-2019 0925 8GG805 7/2019 1.413 1.413 P P ICV Michael Van Ry/EE&G 3-11-2019 0930 8GG805 7/2019 1.413 1.413 P P CCV Michael Van Ry/EE&G 3-11-2019 1530 8GG805 7/2019 1.413 1.413 P p CCV Report specific conductance as a whole number with no decimal figure. Conductivity Acceptance criteria ± 5% pH DEP SOP FT 1100 Name Date Time CT -ET Lot # Expir. Date pH Buffer SU Meter reading SU mV Pass / Fail Lab / Field Calibr. Michael Van Ry/EE&G 3-11-2019 0935 8GH706 8/2020 7.0 7.0 P P Calibr. Michael Van Ry/EE&G 3-11-2019 0940 8GG386 7/2020 4.0 4.0 P P Calibr. Michael Van Ry/EE&G 3-11-2019 0945 8GG016 7/2020 10.0 10.0 p p ICV Michael Van Ry/EE&G 3-11-2019 0950 8GH706 8/2020 7.0 7.0 p p CCV Michael Van Ry/EE&G 3-11-2019 1536 8GH706 8/2020 7.0 6.9 P P CCV Report pH with one decimal place; pH Acceptance criteria ±0.2 SU; mV pH7 Range 0±50; mV pH 10 Range-180±50; Slope from 7 to 10 and 4 to 7 must be between 165 and 180 mV Depth (Quarterly) mV pH 4 Range +180±50; Date of Last Depth Verification Depth Sensor (Daily) Name Date Time CT -ET Zero the Sensor ICV Value Pass / Fail Lab / Field Pressure mode in air 0.000 ICV acceptance criteria ±5 % or ±0.05m, whichever is greater Meter ID: Hach 2100Q Unit #2 Turbidity Calibration Log (DEP SOPS FT1000 FT1600) Regional Operations Centers Date of Last Calibration: 3-11-2019 Melreese Golf Course Project Name: (2018-3057) QUARTERLY CALIBRATION: Sampler Name: Date: All Times Are : ® or CTZ (circle one) Time Performed (24 hr): Standard Value Exp. Date Lot # Calibrated Next Value Shown Pass or Fail? Use Primary Formazin Standards (Ves/No) (Circle One) NTU NTU P F NTU NTU P F NTU NTU P F NTU NTU P F INITIAL CALIBRATION VERIFICATION: Sampler Name: Date/Time (24 hr): Only perform ICV immediately after quarterly calibration. PRIMARY FORMAZIN ICV: Standard Value Exp. Date Lot # Readin Pass or Fail? (circle one) *See Acceptance Criteria Below NTU SECONDARY GEL STANDARD QUARTERLY VERIFICATION: Standard Value Range Previous Reading NTU NTU NTU NTU NTU NTU NTU Exp. Date Lot # P F New Reading NTU NTU NTU Acceptable Range *Calculate using new reading & acceptance criteria below. DAILY CONTINUING CALIBRATION VERIFICATION: Date/Time (24 hr) 3-11-2019 / 0830 Sampler Name Standard Type Standard Value Exp. Date (circle one) Michael Van Ry/EE&G 3-11-2019 / 0830 Michael Van Ry/EE&G 3-11-2019 / 0831 Michael Van Ry/EE&G 3-11-2019 / 0831 Michael Van Ry/EE&G 3-11-2019 / 1600 Michael Van Ry/EE&G 3-11-2019 / 1600 Michael Van Ry/EE&G Formazin Formazi ormazi Gel Gel Gel 10 20 100 NTU NTU NTU / Gel 800 NTU / Gel / Gel 10 20 NTU NTU Lot # Reading Pass or Fail?* (Circle One) 12/2019 24641-01 10 NTU P F 12/2019 24641-02 19.9 NTU P F 12/2019 24641-03 100.1 NTU P F 12/2019 24641-04 800 NTU ❑P F 12/2019 24641-01 10.1 12/2019 24641-02 NTU P F 20 NTU 0 F 3-11-2019 / 1601 Michael Van Ry/EE&G 100 12/2019 24641-03 100 �Formazi4 Gel NTU NTU 3-11-2019 / 1601 Michael Van Ry/EE&G Formazin Gel 800 NTU 0 F 12/2019 24641-04 799 NTU P❑ F Formazin / Gel NTU Formazin / Gel NTU Formazin / Gel NTU Formazin / Gel NTU NTU P F NTU P F NTU P F NTU P F *Acceptance Criteria: 0.1-10 NTU 4 ±10 %; 11-40 NTU 4 ±8 %; 41-100 NTU 4 ±6.5 %; >100 NTU 4 ±5 %; Form effective April 1, 2015 CALIBRATION AND VERIFICATION LOG (FDEP SOP FT 1000-FT 1500, FD 1000-FD 4000) Meter ID: YS1 556 MPM # 7 Project: Melreese Golf Course (2018-3057) Boldly"X" this box if there is qualified data on thic nnnv Notes: (1) Numbers 54, are rounded down; numbers >_ 5 are rounded up (e.g., 5.15 becomes 5.2). (2) Always wait for meter to stabilize before recording any readings. (3) For Calibrations, record calibrated meter reading. Do not record initial meter reading before calibration. Circle/Fill In: Lab Calibration or Calibration/Verification on Site 3-26-2019 Temperature (Quarterly) FT 1400 Date of Last Temperature Verification 2-18-2019 DO DEP SOP FT 1500 Name Date Time CT -ET Temp D.O. Chart mg/L Meter D.O. mg/L % DO Probe Charge Probe Gain Pass / Fail Lab / Field Calibr. Jennifer Vega/EE&G 3-26-2019 0825 24.9 C 100 % 100 p p ICV Jennifer Vega/EE&G 3-26-2019 0835 24.9 C 100 % 100 p P CCV Jennifer Vega/EE&G 3-26-2019 0355 26.5 C 100 % 99 P P CCV Report DO mg/L with one decimal figure and DO % saturation as a whole number with no decimals. DO Acceptance criteria from Table ±0.3 mg/L. Rapid -Pulse Sensors: DO Gain Range 0.7 to 1.4; DO Charge Range 25-75. Optical: DO gain range 0.85 to 1.15; DO charge N/A. Steady-state & Galvanic Sensors: DO Gain & Charge N/A. Spec. Cond. FT 1200 Name Date Time CT -ET Lot # Expir. Date Standard µmhos/cm Meter Reading µmhos/cm Pass / Fail Lab / Field Calibr. Jennifer Vega/EE&G 3-26-2019 0745 8GG805 7/2019 1.413 1.413 P P ICV Jennifer Vega/EE&G 3-26-2019 0750 8GG805 7/2019 1.413 1.413 P P CCV Jennifer Vega/EE&G 3-26-2019 0340 8GG805 7/2019 1.413 1.411 P p CCV Report specific conductance as a whole number with no decimal figure. Conductivity Acceptance criteria ± 5% pH DEP SOP FT 1100 Name Date Time CT -ET Lot # Expir. Date pH Buffer SU Meter reading SU mV Pass / Fail Lab / Field Calibr. Jennifer Vega/EE&G 3-26-2019 0755 8GH706 8/2020 7.0 6.9 P P Calibr. Jennifer Vega/EE&G 3-26-2019 0800 8GG386 7/2020 4.0 4.0 P P Calibr. Jennifer Vega/EE&G 3-26-2019 0805 8GG016 7/2020 10.0 10.1 P P ICV Jennifer Vega/EE&G 3-26-2019 0810 8GH706 8/2020 7.0 7.0 p p CCV Jennifer Vega/EE&G 3-26-2019 0345 8GH706 8/2020 7.0 6.9 P P CCV Report pH with one decimal place; pH Acceptance criteria ±0.2 SU; mV pH7 Range 0±50; mV pH 10 Range-180±50; Slope from 7 to 10 and 4 to 7 must be between 165 and 180 mV Depth (Quarterly) mV pH 4 Range +180±50; Date of Last Depth Verification Depth Sensor (Daily) Name Date Time CT -ET Zero the Sensor ICV Value Pass / Fail Lab / Field Pressure mode in air 0.000 ICV acceptance criteria ±5 % or ±0.05m, whichever is greater Meter ID: Hach 2100Q Unit #2 Turbidity Calibration Log (DEP SOPs FT1000 FT1600) Regional Operations Centers Date of Last Calibration: 3-26-2019 Melreese Golf Course Project Name: (2018-3057) QUARTERLY CALIBRATION: Sampler Name: Date: All Times Are : ® or CTZ (circle one) Time Performed (24 hr): Standard Value Exp. Date Lot # Calibrated Next Value Shown Pass or Fail? Use Primary Formazin Standards (Yes/No) (Circle One) NTU NTU P F NTU NTU P F NTU NTU P F NTU NTU P F INITIAL CALIBRATION VERIFICATION: Sampler Name: Date/Time (24 hr): Only perform ICV immediately after quarterly calibration. PRIMARY FORMAZIN ICV: Standard Value Exp. Date Lot # Reading Pass or Fail? (circle one) *See Acceptance Criteria Below NTU NTU P F SECONDARY GEL STANDARD QUARTERLY VERIFICATION: Standard Value Range Previous Reading Exp. Date Lot # New Reading NTU NTU NTU NTU NTU NTU NTU NTU NTU Acceptable Range *Calculate using new reading & acceptance criteria below. DAILY CONTINUING CALIBRATION VERIFICATION: Date/Time (24 hr) 3-26-2019 / 0840 Sampler Name Standard Type Standard Value Exp. Date (circle one) Jennifer Vega/EE&G 3-26-2019 / 0840 Jennifer Vega/EE&G 3-26-2019 / 0841 Jennifer Vega/EE&G 3-26-2019 / 0841 Jennifer Vega/EE&G 3-26-2019 / 1600 Jennifer Vega/EE&G 3-26-2019 / 1600 Jennifer Vega/EE&G 3-26-2019 / 1601 Jennifer Vega/EE&G Gel Formazin Formazi ormazi Gel Gel Gel 10 20 100 NTU NTU NTU Lot # Reading Pass or Fail?* (Circle One) 12/2019 24641-01 12/2019 24641-02 12/2019 24641-03 10 NTU P F 19.7 NTU ❑P F 100.2 NTU P F / Gel 800 .,r, , 12/2019 24641-04 799 ,,T, , El r / Gel / Gel 3-26-2019 / 1601 Jennifer Vega/EE&G Gel Formazin / Gel Formazin / Gel Formazin / Gel Formazin / Gel 10 12/2019 24641-01 10.1 NTU NTU Q F 20 NTU 12/2019 24641-02 19.9 NTU I F 100 NTU 12/2019 24641-03 100 NTU 0 F NTU 12/2019 24641-04 797 NTU P❑ F NTU NTU P F NTU NTU P F NTU NTU P F NTU NTU P F 800 *Acceptance Criteria: 0.1-10 NTU - ±10 %; 11-40 NTU 4 ±8 %; 41-100 NTU 4 ±6.5 %; >100 NTU 4 ±5 %; Form effective April 1, 2015 CALIBRATION AND VERIFICATION LOG (FDEP SOP FT 1000-FT 1500, FD 1000-FD 4000) Meter ID: YSI556 MPM#7 Project: Melreese Golf Course (2018-3057) Boldly "X" this box if there is qualified data on this onne Notes: (1) Numbers 5.4, are rounded down; numbers >_ 5 are rounded up (e.g., 5.15 becomes 5.2). (2) Always wait for meter to stabilize before recording any readings. (3) For Calibrations, record calibrated meter reading. Do not record initial meter reading before calibration. Circle/Fill In: Lab Calibration or Calibration/Verification on Site 3-26-2019 Temperature (Quarterly) FT 1400 Date of Last Temperature Verification 3-02-2019 DO DEP SOP FT 1500 Name Date Time CT -ET Temp D.O. Chart mg/L Meter D.O. mg/L % DO Probe Charge Probe Gain Pass / Fail Lab / Field Calibr. Kelsey Cortina - EE&G 3-26-2019 0915 25.3 C 100 % 100 p p ICV Kelsey Cortina - EE&G 3-26-2019 0925 25.3 C 100 % 100 p P CCV Kelsey Cortina - EE&G 3-26-2019 1350 27.8 C 100 % 97 p p CCV Report DO mg/L with one decimal figure and DO % saturation as a whole number with no decimals. DO Acceptance criteria from Table ±0.3 mg/L. Rapid -Pulse Sensors: DO Gain Range 0.7 to 1.4; DO Charge Range 25-75. Optical: DO gain range 0.85 to 1.15; DO charge N/A. Steady-state & Galvanic Sensors: DO Gain & Charge N/A. Spec. Cond. FT 1200 Name Date Time CT -ET Lot # Expir. Date Standard µmhos/cm Meter Reading µmhos/cm Pass / Fail Lab / Field Calibr. Kelsey Cortina - EE&G 3-26-2019 0840 8GG805 7/2019 1.413 1.413 P P ICV Kelsey Cortina - EE&G 3-26-2019 0845 8GG805 7/2019 1.413 1.413 P p CCV Kelsey Cortina - EE&G 3-26-2019 1330 8GG805 7/2019 1.413 1.410 P p CCV Report specific conductance as a whole number with no decimal figure. Conductivity Acceptance criteria ± 5% pH DEP SOP FT 1100 Name Date Time CT -ET Lot # Expir. Date pH Buffer SU Meter reading SU mV Pass / Fail Lab / Field Calibr. Kelsey Cortina - EE&G 3-26-2019 0850 8GH706 8/2020 7.0 7.0 P P Calibr. Kelsey Cortina - EE&G 3-26-2019 0900 8GG386 7/2020 4.0 4.0 P P Calibr. Kelsey Cortina - EE&G 3-26-2019 0905 8GG016 7/2020 10.0 10.0 p p ICV Kelsey Cortina - EE&G 3-26-2019 0910 8GH706 8/2020 7.0 7.0 p p CCV Kelsey Cortina - EE&G 3-26-2019 1340 8GH706 8/2020 To 6.9 P P CCV Report pH with one decimal place; pH Acceptance criteria ±0.2 SU; mV pH7 Range 0±50; mV pH 10 Range-180±50; Slope from 7 to 10 and 4 to 7 must be between 165 and 180 mV Depth (Quarterly) mV pH 4 Range +180±50; Date of Last Depth Verification Depth Sensor (Daily) Name Date Time CT -ET Zero the Sensor ICV Value Pass / Fail Lab / Field Pressure mode in air 0.000 ICV acceptance criteria ±5 % or ±0.05m, whichever is greater Meter ID: Hach 2100Q Unit #1 Turbidity Calibration Log (DEP SOPs FT1000 FT1600) Regional Operations Centers Date of Last Calibration: 3-26-2019 Melreese Golf Course Project Name: (2018-3057) QUARTERLY CALIBRATION: Sampler Name: Date: All Times Are : ® or CTZ (circle one) Time Performed (24 hr): Standard Value Exp. Date Lot # Calibrated Next Value Shown Pass or Fail? Use Primary Formazin Standards (Yes/No) (Circle One) NTU NTU P F NTU NTU P F NTU NTU P F NTU NTU P F INITIAL CALIBRATION VERIFICATION: Sampler Name: Date/Time (24 hr): Only perform ICV immediately after quarterly calibration. PRIMARY FORMAZIN ICV: Standard Value Exp. Date Lot # Reading Pass or Fail? (circle one) *See Acceptance Criteria Below NTU P F SECONDARY GEL STANDARD QUARTERLY VERIFICATION: Standard Value Range Previous Reading Exp. Date Lot # New Reading NTU NTU NTU NTU NTU NTU NTU NTU NTU NTU Acceptable Range *Calculate using new reading & acceptance criteria below. DAILY CONTINUING CALIBRATION VERIFICATION: Date/Time (24 hr) 3-26-2019 / 0930 Sampler Name Standard Type Standard Value Exp. Date Lot # Reading Pass or Fail?* (circle one) (Circle One) Kelsey Cortina - EE&G 3-26-2019 / 0930 Kelsey Cortina - EE&G 3-26-2019 / 0931 Kelsey Cortina - EE&G 3-26-2019 / 0931 Kelsey Cortina - EE&G 3-26-2019 / 1400 Kelsey Cortina - EE&G 3-26-2019 / 1400 Kelsey Cortina - EE&G 3-26-2019 / 1401 Kelsey Cortina - EE&G 3-26-2019 / 1401 Kelsey Cortina - EE&G Formazin Formazi ormazi Gel Gel Gel /Gel /Gel /Gel 10 20 100 800 10 20 NTU NTU NTU NTU NTU NTU 12/2019 24641-01 12/2019 24641-02 10 20 NTU P❑ F NTU ❑P F 12/2019 24641-03 99.5 NTU P F 12/2019 24641-04 799 12/2019 24641-01 12/2019 24641-02 Gel 100 NTU 12/2019 24641-03 Gel 800 NTU NTU 10.2 NTU El Li F F 19.8 NTU U F 99.8 NTU F 12/2019 24641-04 796 NTU P❑ F Formazin / Gel NTU NTU P F Formazin / Gel NTU NTU P F Formazin / Gel NTU NTU P F Formazin / Gel NTU NTU P F *Acceptance Criteria: 0.1-10 NTU 4 ±10 %; 11-40 NTU 4 ±8 %; 41-100 NTU 4 ±6.5 %; >100 NTU 4 ±5 %; Form effective April 1, 2015 CALIBRATION AND VERIFICATION LOG (FDEP SOP FT 1000-FT 1500, FD 1000-FD 4000) Meter ID: YSI556 MPM#7 Project: Melreese Golf Course (2018-3057) Boldly"X" this box if there is qualified data on Chic nnnn Notes: (1) Numbers <_4, are rounded down; numbers >_ 5 are rounded up (e.g., 5.15 becomes 5.2). (2) Always wait for meter to stabilize before recording any readings. (3) For Calibrations, record calibrated meter reading. Do not record initial meter reading before calibration. Circle/Fill In: Lab Calibration or Calibration/Verification on Site 3-27-2019 Temperature (Quarterly) FT 1400 Date of Last Temperature Verification 3-02-2019 DO DEP SOP FT 1500 Name Date Time CT -ET Temp D.O. Chart mg/L Meter D.O. mg/L % DO Probe Charge Probe Gain Pass / Fail Lab / Field Calibr. Kelsey Cortina - EE&G 3-27-2019 0830 25.3 C 100 % 100 p p ICV Kelsey Cortina - EE&G 3-27-2019 0835 25.3 C 100 % 100 p P CCV Kelsey Cortina - EE&G 3-27-2019 1045 27.8 C 100 % 97 P P CCV Report DO mg/L with one decimal figure and DO % saturation as a whole number with no decimals. DO Acceptance criteria from Table ±0.3 mg/L. Rapid -Pulse Sensors: DO Gain Range 0.7 to 1.4; DO Charge Range 25-75. Optical: DO gain range 0.85 to 1.15; DO charge N/A. Steady-state & Galvanic Sensors: DO Gain & Charge N/A. Spec. Cond. FT 1200 Name Date Time CT -ET Lot # Expir. Date Standard µmhos/cm Meter Reading µmhos/cm Pass / Fail Lab / Field Calibr. Kelsey Cortina - EE&G 3-27-2019 0830 8GG805 7/2019 1.413 1.413 P P ICV Kelsey Cortina - EE&G 3-27-2019 0835 8GG805 7/2019 1.413 1.413 P P CCV Kelsey Cortina - EE&G 3-27-2019 1050 8GG805 7/2019 1.413 1.410 P p CCV Report specific conductance as a whole number with no decimal figure. Conductivity Acceptance criteria ± 5% pH DEP SOP FT 1100 Name Date Time CT -ET Lot # Expir. Date pH Buffer SU Meter reading SU mV Pass / Fail Lab / Field Calibr. Kelsey Cortina - EE&G 3-27-2019 0848 8GH706 8/2020 7.0 7.0 P P Calibr. Kelsey Cortina - EE&G 3-27-2019 0851 8GG386 7/2020 4.0 4.0 P P Calibr. Kelsey Cortina - EE&G 3-27-2019 0854 8GG016 7/2020 10.0 10.0 p p ICV Kelsey Cortina - EE&G 3-27-2019 0858 8GH706 8/2020 7.0 7.0 p p CCV Kelsey Cortina - EE&G 3-27-2019 1055 8GH706 8/2020 7.0 6.9 P P CCV Report pH with one decimal place; pH Acceptance criteria ±0.2 SU; mV pH7 Range 0±50; mV pH 10 Range-180±50; Slope from 7 to 10 and 4 to 7 must be between 165 and 180 mV Depth (Quarterly) mV pH 4 Range +180±50; Date of Last Depth Verification Depth Sensor (Daily) Name Date Time CT -ET Zero the Sensor ICV Value Pass / Fail Lab / Field Pressure mode in air 0.000 ICV acceptance criteria ±5 % or ±0.05m, whichever is greater Meter ID: Hach 21000 Unit #1 Turbidity Calibration Log (DEP SOPS FT1000 FT1600) Regional Operations Centers Date of Last Calibration: 3-27-2019 Melreese Golf Course Project Name: (2018-3057) QUARTERLY CALIBRATION: All Times Are : ® or CTZ (circle one) Standard Value Exp. Date Use Primary Formazin Standards NTU NTU NTU NTU Sampler Name: Lot # Time Performed (24 hr): Calibrated (Yes/No) Date: Next Value Shown NTU NTU NTU NTU Pass or Fail? (Circle One) P F P F P F P F INITIAL CALIBRATION VERIFICATION: Only perform ICV immediately after quarterly calibration. PRIMARY FORMAZIN ICV: Standard Value NTU Exp. Date Sampler Name: Date/Time (24 hr): Lot # SECONDARY GEL STANDARD QUARTERLY VERIFICATION: Standard Value Range Previous Reading Exp. Date NTU NTU NTU NTU NTU NTU Reading NTU Lot # Pass or Fail? (circle one) *See Acceptance Criteria Below P F New Reading NTU NTU NTU Acceptable Range *Calculate using new reading & acceptance criteria below. DAILY CONTINUI NG CALIBRATION VERIFICATION: Date/Tim e (24 hr) 3-27-2019 / 0915 Sampler Name Standard Type Standard Value Exp. Date (circle one) Kelsey Cortina - EE&G 3-27-2019 / 0915 Kelsey Cortina - EE&G 3-27-2019 / 0915 Kelsey Cortina - EE&G 3-27-2019 / 0915 Kelsey Cortina - EE&G 3-27-2019 / 1100 Kelsey Cortina - EE&G 3-27-2019 / 1100 Kelsey Cortina - EE&G 3-27-2019 / 1100 Kelsey Cortina - EE&G 3-27-2019 / 1100 Kelsey Cortina - EE&G Formazin Formazi ormazi Gel Gel Gel / Gel /Gel /Gel Gel Gel Formazin / Gel Formazin / Gel Formazin / Gel Formazin / Gel 10 20 100 800 10 20 100 800 NTU NTU NTU NTU NTU NTU NTU NTU NTU NTU NTU NTU Lot # Reading Pass or Fail?* (Circle One) 12/2019 24641-01 10.1 NTU P F 12/2019 24641-02 19.8 NTU n 12/2019 24641-03 12/2019 24641-04 12/2019 24641-01 12/2019 24641-02 12/2019 24641-03 99.5 797 10.2 19.8 99.5 NTU P F NTU D F NTU D F NTU NTU 12 12 F F 12/2019 24641-04 796 NTU P❑ F NTU P F NTU P F NTU P F NTU P F *Acceptance Criteria: 0.1-10 NTU 4 ±10 %; 11-40 NTU 4 ±8 %; 41-100 NTU 4 ±6.5 %; >100 NTU 4 ±5 %; Form effective April 1, 2015 CALIBRATION AND VERIFICATION LOG (FDEP SOP FT 1000-FT 1500, FD 1000-FD 4000) Meter ID: YS1 556 MPM # 7 Project: Melreese Golf Course (2018-3057) Boldly"X" this box if there is qualified data on this nnnv Notes: (1) Numbers 54, are rounded down; numbers >_ 5 are rounded up (e.g., 5.15 becomes 5.2). (2) Always wait for meter to stabilize before recording any readings. (3) For Calibrations, record calibrated meter reading. Do not record initial meter reading before calibration. Circle/Fill In: Lab Calibration or Calibration/Verification on Site 3-27-2019 Temperature (Quarterly) FT 1400 Date of Last Temperature Verification 2 17-2019 DO DEP SOP FT 1500 Name Date Time CT -ET Temp D.O. Chart mg/L Meter D.O. mg/L % DO Probe Charge Probe Gain Pass / Fail Lab / Field Calibr. Russell Fernandez/EE&G 3-27-2019 0650 24.9 C 100 % 100 p p ICV Russell Fernandez/EE&G 3-27-2019 0700 24.9 C 100 % 100 p P CCV Russell Fernandez/EE&G 3-27-2019 1325 26.5 C 100 % 99 p p CCV Report DO mg/L with one decimal figure and DO % saturation as a whole number with no decimals. DO Acceptance criteria from Table ±0.3 mg/L. Rapid -Pulse Sensors: DO Gain Range 0.7 to 1.4; DO Charge Range 25-75. Optical: DO gain range 0.85 to 1.15; DO charge N/A. Steady-state & Galvanic Sensors: DO Gain & Charge N/A. Spec. Cond. FT 1200 Name Date Time CT -ET Lot # Expir. Date Standard µmhos/cm Meter Reading µmhos/cm Pass / Fail Lab / Field Calibr. Russell Fernandez/EE&G 3-27-2019 0620 8GG805 7/2019 1.413 1.413 P P ICV Russell Fernandez/EE&G 3-27-2019 0625 8GG805 7/2019 1.413 1.413 P P CCV Russell Fernandez/EE&G 3-27-2019 1310 8GG805 7/2019 1.413 1.411 P p CCV Report specific conductance as a whole number with no decimal figure. Conductivity Acceptance criteria ± 5% pH DEP SOP FT 1100 Name Date Time CT -ET Lot # Expir. Date pH Buffer SU Meter reading SU mV Pass / Fail Lab / Field Calibr. Russell Fernandez/EE&G 3-27-2019 0630 8GH706 8/2020 7.0 6.9 P P Calibr. Russell Fernandez/EE&G 3-27-2019 0635 8GG386 7/2020 4.0 4.0 P P Calibr. Russell Fernandez/EE&G 3-27-2019 0640 8GG016 7/2020 10.0 10.1 p p ICV Russell Fernandez/EE&G 3-27-2019 0645 8GH706 8/2020 7.0 7.0 p p CCV Russell Fernandez/EE&G 3-27-2019 1315 8GH706 8/2020 7.0 6.9 P P CCV Report pH with one decimal place; pH Acceptance criteria ±0.2 SU; mV pH7 Range 0±50; mV pH 10 Range-180±50; Slope from 7 to 10 and 4 to 7 must be between 165 and 180 mV Depth (Quarterly) mV pH 4 Range +180±50; Date of Last Depth Verification Depth Sensor (Daily) Name Date Time CT -ET Zero the Sensor ICV Value Pass / Fail Lab / Field Pressure mode in air 0.000 ICV acceptance criteria ±5 % or ±0.05m, whichever is greater Meter ID: Hach 2100Q Unit #2 Turbidity Calibration Log (DEP SOPS FT1000 FT1600) Regional Operations Centers Date of Last Calibration: 3-27-2019 Melreese Golf Course Project Name: (2018-3057) QUARTERLY CALIBRATION: Sampler Name: Date: All Times Are : CO3 or CTZ (circle one) Time Performed (24 hr): Standard Value Exp. Date Lot # Calibrated Next Value Shown Use Primary Formazin Standards (Yes/No) NTU NTU NTU NTU Pass or Fail? (Circle One) NTU P F NTU P F NTU P F NTU P F INITIAL CALIBRATION VERIFICATION: Sampler Name: Date/Time (24 hr): Only perform ICV immediately after quarterly calibration. PRIMARY FORMAZIN ICV: Standard Value Exp. Date Lot # Reading Pass or Fail? (circle one) *See Acceptance Criteria Below NTU SECONDARY GEL STANDARD QUARTERLY VERIFICATION: Standard Value Range Previous Reading Exp. Date NTU NTU NTU NTU NTU NTU NTU Lot # P F New Reading NTU NTU NTU Acceptable Range *Calculate using new reading & acceptance criteria below. DAILY CONTINUING CALIBRATION VERIFICATION: Date/Time (24 hr) Sampler Name 3-27-2019 / 0705 Russell Fernandez/EE&G 3-27-2019 / 0705 Russell Fernandez/EE&G 3-27-2019 / 0706 Russell Fernandez/EE&G 3-27-2019 / 0706 Russell Fernandez/EE&G 3-27-2019 / 1330 Russell Fernandez/EE&G 3-27-2019 / 1330 Russell Fernandez/EE&G Standard Type (circle one) Formazin Formazi ormazi Standard Value Exp. Date Lot # Reading Pass or Fail?* (Circle One) Gel 10 NTU 12/2019 24641-01 10 NTU P❑ F Gel 20 NTU 12/2019 24641-02 19.7 NTU ❑P F Gel 100 NTU 12/2019 24641-03 100.2 NTU pP F /Gel 800 NTU 12/2019 24641-04 800 / Gel / Gel 10 20 NTU NTU 12/2019 24641-01 12/2019 24641-02 NTU 10.1 NTU P U F F 19.9 NTU t F 3-27-2019 / 1331 Russell Fernandez/EE&G IFormazinit Gel 100 NTU 12/2019 24641-03 100 NTU 3-27-2019 / 1311 Russell Fernandez/EE&G Formazin Gel 800 NTU rn F 12/2019 24641-04 798 NTU P❑ F Formazin / Gel NTU NTU P F Formazin / Gel NTU NTU P F Formazin / Gel NTU NTU P F Formazin / Gel NTU NTU P F *Acceptance Criteria: 0.1-10 NTU 4 ±10 %; 11-40 NTU 4 ±8 %; 41-100 NTU 4 ±6.5 %; >100 NTU 4 ±5 %; Form effective April 1, 2015 CALIBRATION AND VERIFICATION LOG (FDEP SOP FT 1000-FT 1500, FD 1000-FD 4000) Meter ID: YSI556 MPM#7 Project: Melreese Golf Course (2018-3057) Boldly"X" this box if there is qualified data on thic nnne Notes: (1) Numbers 54, are rounded down; numbers >_ 5 are rounded up (e.g., 5.15 becomes 5.2). (2) Always wait for meter to stabilize before recording any readings. (3) For Calibrations, record calibrated meter reading. Do not record initial meter reading before calibration. Circle/Fill In: Lab Calibration or Calibration/Verification on Site 4-08-2019 Temperature (Quarterly) FT 1400 Date of Last Temperature Verification 2-17-2019 DO DEP SOP FT 1500 Name Date Time CT -ET Temp D.O. Chart mg/L Meter D.O. mg/L % DO Probe Charge Probe Gain Pass / Fail Lab / Field Calibr. Russell Fernandez/EE&G 4-08-2019 0920 25.5 C 100 % 100 P p ICV Russell Fernandez/EE&G 4-08-2019 0930 25.5 C 100 % 100 P P CCV Russell Fernandez/EE&G 4-08-2019 1450 27.2 C 100 % 99 p P CCV Report DO mg/L with one decimal figure and DO % saturation as a whole number with no decimals. DO Acceptance criteria from Table ±0.3 mg/L. Rapid -Pulse Sensors: DO Gain Range 0.7 to 1.4; DO Charge Range 25-75. Optical: DO gain range 0.85 to 1.15; DO charge N/A. Steady-state & Galvanic Sensors: DO Gain & Charge N/A. Spec. Cond. FT 1200 Name Date Time CT -ET Lot # Expir. Date Standard µmhos/cm Meter Reading µmhos/cm Pass / Fail Lab / Field Calibr. Russell Fernandez/EE&G 4-08-2019 0850 8GG805 7/2019 1.413 1.411 P P ICV Russell Fernandez/EE&G 4-08-2019 0855 8GG805 7/2019 1.413 1.413 P P CCV Russell Fernandez/EE&G 4-08-2019 1430 8GG805 7/2019 1.413 1.413 P p CCV Report specific conductance as a whole number with no decimal figure. Conductivity Acceptance criteria ± 5% pH DEP SOP FT 1100 Name Date Time CT -ET Lot # Expir. Date pH Buffer SU Meter reading SU mV Pass / Fail Lab / Field Calibr. Russell Fernandez/EE&G 4-08-2019 0900 8GH706 8/2020 7.0 7.0 P p Calibr. Russell Fernandez/EE&G 4-08-2019 0905 8GG386 7/2020 4.0 4.2 P P Calibr. Russell Fernandez/EE&G 4-08-2019 0910 8GG016 7/2020 10.0 10.1 p p ICV Russell Fernandez/EE&G 4-08-2019 0915 8GH706 8/2020 7.0 7.1 p p CCV Russell Fernandez/EE&G 4-08-2019 1440 8GH706 8/2020 7.0 7.0 P P CCV Report pH with one decimal place; pH Acceptance criteria ±0.2 SU; mV pH7 Range 0±50; mV pH 4 Range +180±50; mV pH 10 Range-180±50; Slope from 7 to 10 and 4 to 7 must be between 165 and 180 mV Depth (Quarterly) Date of Last Depth Verification Depth Sensor (Daily) Name Date Time CT -ET Zero the Sensor ICV Value Pass / Fail Lab / Field Pressure mode in air 0.000 ICV acceptance criteria ±5 % or ±0.05m, whichever is greater Meter ID: Hach 2100Q Unit #2 Turbidity Calibration Log (DEP SOPS FT1000 FT1600) Regional Operations Centers Date of Last Calibration: 4-08-2019 Melreese Golf Course Project Name: (2018-3057) QUARTERLY CALIBRATION: Sampler Name: Date: All Times Are : ® or CTZ (circle one) Time Performed (24 hr): Standard Value Exp. Date Lot # Calibrated Next Value Shown Pass or Fail? Use Primary Formazin Standards (Yes/No) (Circle One) NTU NTU P F NTU NTU P F NTU NTU P F NTU NTU P F INITIAL CALIBRATION VERIFICATION: Sampler Name: Date/Time (24 hr): Only perform ICV immediately after quarterly calibration. PRIMARY FORMAZIN ICV: Standard Value Exp. Date Lot # Reading Pass or Fail? (circle one) *See Acceptance Criteria Below NTU NTU SECONDARY GEL STANDARD QUARTERLY VERIFICATION: Standard Value Range Previous Reading NTU NTU NTU NTU NTU NTU Exp. Date Lot # P F New Reading NTU NTU NTU Acceptable Range *Calculate using new reading & acceptance criteria below. DAILY CONTINUING CALIBRATION VERIFICATION: Date/Time Sampler Name Standard Type Standard Value Exp. Date Lot # Reading Pass or Fail?* (24 hr) (circle one) (Circle One) 4-08-2019 / 0935 Russell Fernandez/EE&G Formazin Gel 10 NTU 12/2019 24641-01 10.2 NTU El F 4-08-2019 / 0935 Russell FernandezlEE&G Formazin Gel 20 NTU 12/2019 24641-02 19.8 NTU �P F 4-08-2019 / 0936 Russell Fernandez/EE&G 4-08-2019 / 0936 Russell Fernandez/EE&G 4-08-2019 / 1455 Russell Fernandez/EE&G 4-08-2019 / 1455 Russell Fernandez/EE&G 4-08-2019 / 1456 Russell Fernandez/EE&G 4-08-2019 / 1456 Russell Femandez/EE&G Formazin Formazi ormazi Gel / Gel NTU / Gel / Gel 10 NTU 100 NTU 12/2019 24641-03 100 NTU P F 800 12/2019 24641-04 798 NTU 12/2019 24641-01 20 NTU 12/2019 24641-02 10.1 NTU 19.9 Gel 100 NTU 12/2019 24641-03 100 Gel 800 NTU P u F F NTU U F NTU 11 F 12/2019 24641-04 800 NTU P❑ F Formazin / Gel NTU NTU P F Formazin / Gel NTU NTU P F Formazin / Gel NTU NTU P F Formazin / Gel NTU NTU P F *Acceptance Criteria: 0.1-10 NTU 4 ±10 %; 11-40 NTU 4 ±8 %; 41-100 NTU 4 ±6.5 %; >100 NTU 4 ±5 %; Form effective April 1, 2015 CALIBRATION AND VERIFICATION LOG (FDEP SOP FT 1000-FT 1500, FD 1000-FD 4000) Meter ID: YSI556 MPM#7 Project: Melreese Golf Course (2018-3057) Boldly"X" this box if there is qualified data on this nnnv Notes: (1) Numbers <_4, are rounded down; numbers >_ 5 are rounded up (e.g., 5.15 becomes 5.2). (2) Always wait for meter to stabilize before recording any readings. (3) For Calibrations, record calibrated meter reading. Do not record initial meter reading before calibration. Circle/Fill In: Lab Calibration or Calibration/Verification on Site 4-09-2019 Temperature (Quarterly) FT 1400 Date of Last Temperature Verification 2-17-2019 DO DEP SOP FT 1500 Name Date Time CT -ET Temp D.O. Chart mg/L Meter D.O. mg/L % DO Probe Charge Probe Gain Pass / Fail Lab / Field Calibr. Russell Fernandez/EE&G 4-09-2019 0900 24.3 C 100 % 99 p P ICV Russell Fernandez/EE&G 4-09-2019 0910 24.2 C 100 % 100 p P CCV Russell Fernandez/EE&G 4-09-2019 1350 27.0 C 100 % 100 p p CCV Report DO mg/L with one decimal figure and DO % saturation as a whole number with no decimals. DO Acceptance criteria from Table ±0.3 mg/L. Rapid -Pulse Sensors: DO Gain Range 0.7 to 1.4; DO Charge Range 25-75. Optical: DO gain range 0.85 to 1.15; DO charge N/A. Steady-state & Galvanic Sensors: DO Gain & Charge N/A. Spec. Cond. FT 1200 Name Date Time CT -ET Lot # Expir. Date Standard µmhos/cm Meter Reading µmhos/cm Pass / Fail Lab / Field Calibr. Russell Fernandez/EE&G 4-09-2019 0830 8GG805 7/2019 1.413 1.412 P P ICV Russell Fernandez/EE&G 4-09-2019 0835 8GG805 7/2019 1.413 1.413 P p CCV Russell Fernandez/EE&G 4-09-2019 1330 8GG805 7/2019 1.413 1.411 P p CCV Report specific conductance as a whole number with no decimal figure. Conductivity Acceptance criteria ± 5% pH DEP SOP FT 1100 Name Date Time CT -ET Lot # Expir. Date pH Buffer SU Meter reading SU mV Pass / Fail Lab / Field Calibr. Russell Fernandez/EE&G 4-09-2019 0840 8GH706 8/2020 7.0 6.9 P P Calibr. Russell Fernandez/EE&G 4-09-2019 0845 8GG386 7/2020 4.0 3.8 P P Calibr. Russell Fernandez/EE&G 4-09-2019 0850 8GG016 7/2020 10.0 10.0 p p ICV Russell Fernandez/EE&G 4-09-2019 0855 8GH706 8/2020 7.0 7.0 p p CCV Russell Fernandez/EE&G 4-09-2019 1340 8GH706 8/2020 7.0 6.9 P P CCV Report pH with one decimal place; pH Acceptance criteria ±0.2 SU; mV pH7 Range 0±50; mV pH 10 Range-180±50; Slope from 7 to 10 and 4 to 7 must be between 165 and 180 mV Depth (Quarterly) mV pH 4 Range +180±50; Date of Last Depth Verification Depth Sensor (Daily) Name Date Time CT -ET Zero the Sensor ICV Value Pass / Fail Lab / Field Pressure mode in air 0.000 ICV acceptance criteria ±5 % or ±0.05m, whichever is greater Meter ID: Hach 2100Q Unit #2 Turbidity Calibration Log (DEP SOPS FT1000 FT1600) Regional Operations Centers Date of Last Calibration: 4-09-2019 Melreese Golf Course Project Name: (2018-3057) QUARTERLY CALIBRATION: Sampler Name: Date: All Times Are : ® or CTZ (circle one) Time Performed (24 hr): Standard Value Exp. Date Lot # Calibrated Next Value Shown Pass or Fail? Use Primary Formazin Standards (Yes/No) (Circle One) NTU NTU P F NTU NTU P F NTU NTU P F NTU NTU P F INITIAL CALIBRATION VERIFICATION: Sampler Name: Date/Time (24 hr): Only perform 1CV immediately after quarterly calibration. PRIMARY FORMAZIN ICV: Standard Value Exp. Date Lot # Reading Pass or Fail? (circle one) *See Acceptance Criteria Below NTU NTU P F SECONDARY GEL STANDARD QUARTERLY VERIFICATION: Standard Value Range Previous Reading Exp. Date Lot # New Reading Acceptable Range *Calculate using new reading & acceptance criteria below. NTU NTU NTU NTU NTU NTU NTU NTU NTU DAILY CONTINUING CALIBRATION VERIFICATION: Date/Time Sampler Name Standard Type Standard Value Exp. Date Lot # Reading Pass or Fail?* (24 hr) (circle one) (Circle One) 4-09-2019 / 0912 Russell Fernandez/EE&G Formazin Gel 10 NTU 12/2019 24641-01 10.0 NTU P❑ F 4-09-2019 / 0912 Russell Fernandez/EE&G Formazin Gel 20 NTU 12/2019 24641-02 20.0 NTU P F 4-09-2019 / 0913 Russell Fernandez/EE&G ormazin Gel 100 NTU 12/2019 24641-03 100.2 NTU P F 4-09-2019 / 0913 Russell Fernandez/EE&G 4-09-2019 / 1355 Russell Fernandez/EE&G 4-09-2019 / 1355 Russell Fernandez/EE&G Formazin Formazi 4-09-2019 / 1356 Russell Fernandez/EE&G 4-09-2019 / 1356 Russell Fernandez/EE&G / Gel / Gel /Gel Formazin Formazin 800 NTU 12/2019 24641-04 799 NTU ❑P F 10 20 NTU NTU 12/2019 12/2019 24641-01 10.1 24641-02 Gel 100 NTU 12/2019 24641-03 NTU G F 19.9 NTU I F 99.8 NTU F Gel 800 NTU 12/2019 24641-04 800 NTU P❑ F Formazin / Gel NTU NTU P F Formazin / Gel NTU NTU P F Formazin / Gel NTU NTU P F Formazin / Gel NTU NTU P F *Acceptance Criteria: 0.1-10 NTU 4 ±10 %; 11-40 NTU 4 ±8 %; 41-100 NTU ±6.5 %; >100 NTU - ±5 %; Form effective April 1, 2015 E E -G ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-44 SAMPLE ID: PACE SITE LOCATION: 1802 MN 37th Ave, Miami, FL 33125 DATE: 3 / 4 / 2019 PURGING DATA (2/2B/3 WELL ( PVC) DIAMETER (inches): 2.0 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 1.88 feet to 11.88 feet STATIC DEPTH TO WATER (feet BLS): 4.01 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 11.88 feet - 4.01 feet) X 0.16 gallons/foot = 1.26 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + allons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 8 FINAL PUMP OR TUBING PURGING PURGING DEPTH IN WELL (feet): 8 INITIATED AT: 09:36 ENDED AT: 10:04 TOTAL PURGED VOLUME (gallons): COLOR (describe) ) 3.5 ODOR (describe) TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units ) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN ("A Saturation) TEMP. o (C) 09:52 2.0 2.0 0.125 4.15 6.92 0.902 4.16 8.2 25.59 Clear None 09:56 0.5 2.5 0.125 4.15 6.94 0.889 3.62 6.5 25.51 Clear None 10:00 0.5 3.0 0.125 4.15 6.95 0.889 3.33 6.0 25.55 Clear None 10:04 0.5 3.5 0.125 4.15 6.96 0.897 3.22 5.6 25.51 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Michael Van Ry / EE&G SAMPLER(S) SIGNATURE(S): _ - c�--• �jINITIATED MPLING AT: 10:04 SAMPLING ENDED AT: 10:14 PUMP OR TUBING DEPTH IN WELL (feet): 8.0 TUBING FIELD -FILTERED: 0 N FILTER SIZE: MATERIAL CODE: HDPE/S Filtration Equipment Type: 1 pm FIELD DECONTAMINATION: PUMP Y ® TUBING Y 0 (replaced) DUPLICATE: Y SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE 4 CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 3 CG 40 mL HCL - < 2 VOC (8260) APP 100 1 AG 250 mL - - - PAHs (8270) APP 500 2 AG 100 mL H2SO4 - < 2 TPH (FL -PRO) APP 500 1 AG 1 L - - - Pest. (8081) APP 500 1 AG 1 L Organo Pest (8141) APP 500 1 AG 1 L - - - Herb. (8151) APP 500 1 AG 1 L - - - Dioxins (8290) APP 500 1 PE 250 mL HNO3 - < 2 Metals (6010/7470) APP 500 1 PE 250 mL HNO3 - < 2 Diss. Metals (6010/7470) APP 500 1 PE 250 mL H2SO4 - < 2 Ammonia (350.1) APP 500 1 PE 250 mL - - Nitrates/Nitrites (300.0) APP 500 REMARKS: T.O.0 -0.2' YS1556 MPM#7 TBM#2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) : 1. Thea ove do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 31 pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 EE6G Mi57a1 Miami Lak,FL 3 Dr. 01 Miami Lakes, FL 33014 ENVIRONMENTAL SERVICES, LLC Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course 2018-3057 WELL NO: MW-42 SITE LOCATION: 1802 MN 37th Ave, Miami, FL 33125 SAMPLE ID: PACE PURGING DATA (2 / 26 / 3 DATE: 3 / 4 / 2019 WELL ( PVC) DIAMETER (inches): 2.0 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 2.13 feet to 12.13 feet STATIC DEPTH TO WATER (feet BLS): 4.97 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 12.13 feet- 4.97 feet) X 0.16 gallons/foot = 1.15 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 8.5 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 8.5 PURGING PURGING INITIATED AT: 10:36 ENDED AT: 11:04 TOTAL VOLUME PURGED (gallons): 3.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE Wm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 10:52 2.0 2.0 0.125 5.54 7.24 0.530 2.23 10.9 25.01 Clear None 10:56 0.5 2.5 0.125 5.54 7.21 0.528 1.97 7.2 25.08 Clear None 11:00 0.5 3.0 0.125 5.54 7.21 0.529 1.63 5.8 25.02 Clear None 11:04 0.5 3.5 0.125 5.54 7.21 0.533 1.49 5.3 25.02 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer, BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Michael Van Ry / EE&G SAMPLER(S) SIGNATURE(S): = ' ,--.-'-- : i/ SAMPLING INITIATED AT: 11:04 SAMPLING ENDED AT: 11:14 PUMP OR TUBING DEPTH IN WELL (feet): 8.5 TUBING FIELD -FILTERED: 0 N FILTER SIZE: MATERIAL CODE: HDPE/S Filtration Equipment Type: 1 pm FIELD DECONTAMINATION: PUMP Y ® TUBING Y © (replaced) DUPLICATE: Y El SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 3 CG 40 mL HCL - < 2 VOC (8260) APP 100 1 AG 250 mL - - - PAHs (8270) APP 500 2 AG 100 mL H2SO4 - < 2 TPH (FL -PRO) APP 500 1 AG 1 L - - - Pest. (8081) APP 500 1 AG 1 L - - - Organo Pest (8141) APP 500 1 AG 1 L - - - Herb. (8151) APP 500 1 AG 1 L - - - Dioxins (8290) APP 500 1 PE 250 mL HNO3 - < 2 Metals (6010/7470) APP 500 1 PE 250 mL HNO3 - < 2 Diss_ Metals (601on47D) APP 500 1 PE 250 mL H2SO4 - < 2 Ammonia (350.1) APP 500 1 PE 250 mL Nitrates/Nitrites (300.0) APP 500 REMARKS: T.O.C. -0. I5' YS1556 MPM # 7 TBM# 2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212. SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally ± 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 ENVIRONMENTAL SERVICES. LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) SITE LOCATION: 1802 NW 37m Ave, Miami, FL 33125 WELL NO: SCS-MW-1 SAMPLE ID: PACE DATE: 3 / 4 / 2019 PURGING DATA (2 / 2B / 3 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 2.1 feet to 12.1 feet STATIC DEPTH TO WATER (feet BLS): 4.15 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 12.1 feet- 4.15 feet) X 0.09 gallons/foot = 0.72 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 8 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 8 PURGING INITIATED AT: 11:40 PURGING ENDED AT: 12:04 TOTAL VOLUME PURGED (gallons): 3.0 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. mS/cm(NTUs)OXYGEN ( ) TURBIDITY DISSOLVED (%Saturation) TEMP_ (°C) COLOR (describe) ODOR (describe) 11:52 1.5 1.5 0.125 4.35 7.09 0.590 5.84 8.7 23.58 Clear None 11:56 0.5 2.0 0.125 4.35 7.09 0.577 5.10 6.9 23.65 Clear None 12:00 0.5 2.5 0.125 4.35 7.10 0.575 4.72 6.3 23.61 Clear None 12:04 0.5 3.0 0.125 4.35 7.10 0.574 4.55 5.7 23.52 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer, BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Michael Van Ry / EE&G SAMPLER(S) SIGNATURE(S): -- ` - -- - ' SAMPLING INITIATED AT: 12:04 SAMPLING ENDED AT: 12:14 PUMP OR TUBING DEPTH IN WELL (feet): 8 TUBING FIELD -FILTERED: 0 N FILTER SIZE: MATERIAL CODE: HDPE/S Filtration Equipment Type: 1 pm FIELD DECONTAMINATION: PUMP Y ® TUBING Y S (replaced) DUPLICATE: Y S SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 3 CG 40 mL HCL - < 2 VOC (8260) APP 100 1 AG 250 mL - - - PAHs (8270) APP 500 2 AG 100 mL H2SO4 - < 2 TPH (FL -PRO) APP 500 1 AG 1 L - - - Pest. (8081) APP 500 1 AG 1 L - - - Organo(814Pest1) APP 500 1 AG 1 L - - - Herb. (8151) APP 500 1 AG 1 L - - - Dioxins (8290) APP 500 1 PE 250 mL HNO3 - < 2 Metals (6010/7470) APP 500 1 PE 250 mL HNO3 - < 2 Diss. Metals (6010/7470) APP 500 1 PE 250 mL H2SO4 - < 2 Ammonia (350.1) APP 500 1 PE 250 mL - - - Nitrates/Nitrites (300.0) APP 500 REMARKS: T.O. C. -0. 4' YS/ 556 MPM # 7 TBM# 2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene. S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) TES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally ± 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 EEG ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-39 SAMPLE ID: PACE SITE LOCATION: 1802 NW 37th Ave, Miami, FL 33125 DATE: 3 / 4 / 2019 PURGING DATA (2/2B/3 WELL ( PVC) DIAMETER (inches): 1.0 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 1.6 feet to 11.6 feet STATIC DEPTH TO WATER (feet BLS): 3.51 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 11.6 feet- 3.51 feet) X 0.04 gallons/foot = 0.32 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + allons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 7.5 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 7.5 PURGING INITIATED AT: 12:42 PURGING ENDED AT: 12:54 TOTAL VOLUME PURGED (gallons): 1.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 12:48 0.75 0.75 0.125 3.61 7.39 0.394 2.22 15.1 26.41 Clear None 12:50 0.25 1.0 0.125 3.61 7.31 0.391 2.20 10.7 26.16 Clear None 12:52 0.25 1.25 0.125 3.61 7.30 0.389 2.12 9.0 25.92 Clear None 12:54 0.25 1.50 0.125 3.61 7.31 0.389 2.03 8.0 25.87 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (GaL/Ft.): 118" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DA SAMPLED BY (PRINT) / AFFILIATION: Michael Van Ry / EE&G SAMPLER(S) SIGNATURE(S): SAMPLING INITIATED AT: 12:54 SAMPLING ENDED AT: 13:04 PUMP OR TUBING DEPTH IN WELL (feet): 7.5 TUBING MATERIAL CODE: HDPE/S FIELD-F LTERED: 0 N FILTER SIZE: Filtration Equipment Type: 1 pm FIELD DECONTAMINATION: PUMP Y ® TUBING Y ® (replaced) DUPLICATE: Y IR SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 3 CG 40 mL HCL - < 2 VOC (8260) APP 100 1 AG 250 mL - - - PAHs (8270) APP 500 2 AG 100 mL H2SO4 - < 2 TPH (FL -PRO) APP 500 1 AG 1 L - - - Pest. (8081) APP 500 1 AG 1 L - - Organo Pest (8141) APP 500 1 AG 1 L - - - Herb. (8151) APP 500 1 AG 1 L - - - Dioxins (8290) APP 500 1 PE 250 mL HNO3 - < 2 Metals (6010/7470) APP 500 1 PE 250 mL HNO3 < 2 Dins. Metals (601on470) APP 500 1 PE 250 mL H2SO4 - < 2 Ammonia (350.1) APP 500 1 PE 250 mL Nitrates/Nitrites (300.0) APP 500 REMARKS: T.O.C. -0.3' YS/ 556 MPM # 7 TBM# 2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; 5 = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 31 pH: ± 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 E E -G ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course 2018-3057 WELL NO: SCS-MW-2 SITE LOCATION: 1802 NW 37° Ave, Miami, FL 33125 SAMPLE ID: PACE PURGING DATA (2 / 2B / 3 DATE: 3 / 4 / 2019 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 1.86 feet to 11.86 feet STATIC DEPTH TO WATER (feet BLS): 3.92 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 11.86 feet- 3.92 feet) X 0.09 gallons/foot = 0.71 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 8 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 8 PURGING INITIATED AT: 13:34 PURGING ENDED AT: 14:02 TOTAL VOLUME PURGED (gallons): 3.5 TIME VOLUME PURGED (gallons)(gpm) CUMUL. VOLUME PURGED (gallons) PURGE RATE DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN ("� Saturation)(°C) TEMP. COLOR (describe) ODOR (describe) 13:50 2.0 2.0 0.125 3.95 7.26 0.508 3.97 4.6 26.12 Clear None 13:54 0.5 2.5 0.125 3.95 7.26 0.495 3.11 3.9 26.06 Clear None 13:58 0.5 3.0 0.125 3.95 7.26 0.487 2.73 3.6 25.93 Clear None 14:02 0.5 3.5 0.125 3.95 7.25 0.487 2.44 3.4 26.03 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37, 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Michael Van Ry / EE&G SAMPLER(S) SIGNATURE(S): �r t /j SAMPLING INITIATED AT: 14:02 SAMPLING ENDED AT: 14:12 PUMP OR TUBING DEPTH IN WELL (feet): 8 TUBING MATERIAL CODE: HDPE/S FIELD -FILTERED: 0 N FILTER SIZE: Filtration Equipment Type: 1 pm FIELD DECONTAMINATION: PUMP Y ® TUBING Y ® (replaced) DUPLICATE: Y El SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 3 CG 40 mL HCL - < 2 VOC (8260) APP 100 1 AG 250 mL - - - PAHs (8270) APP 500 2 AG 100 mL H2SO4 - < 2 TPH (FL -PRO) APP 500 1 AG 1 L - - - Pest. (8081) APP 500 1 AG 1 L - - - Organo(8141)Pest APP 500 1 AG 1 L - - - Herb. (8151) APP 500 1 AG 1 L - - - Dioxins (8290) APP 500 1 PE 250 mL HNO3 - < 2 Metals (6010/7470) APP 500 1 PE 250 mL HNO3 - < 2 Diss. Metals (6010/7470) APP 500 1 PE 250 mL H2SO4 - < 2 Ammonia (350.1) APP 500 1 PE 250 mL - - - Nitrates/Nitrites (300.0) APP 500 REMARKS: T.O.C. -03' YS/556 MPM#7 TBM#2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) : 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 EE6G ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-31 SITE LOCATION: 1802 NW 37th Ave, Miami, FL 33125 SAMPLE ID: PACE DATE: 3 / 4 / 2019 WELL ( PVC) DIAMETER (inches): 2.0 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 2.6 feet to 12.6 feet STATIC DEPTH TO WATER (feet BLS): 4.08 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 12.6 feet- 4.08 feet) X 0.16 gallons/foot = 1.36 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 8 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 8 PURGING INITIATED AT: 14:38 rations PURGING ENDED AT: 15:06 TOTAL VOLUME PURGED (gallons): 3.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (°� Saturation) TEMP. o (C) COLOR (describe) ODOR (describe) 14:54 2.0 2.0 0.125 4.21 7.33 0.536 17.0 24.8 27.65 Clear None 14:58 0.5 2.5 0.125 4.21 7.32 0.536 15.4 11.0 27.60 Clear None 15:02 0.5 3.0 0.125 4.21 7.32 0.536 13.9 7.4 27.57 Clear None 15:06 0.5 3.5 0.125 4.21 7.32 0.536 12.4 6.9 27.60 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3116" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 112" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLED BY (PRINT) / AFFILIATION: Michael Van Ry / EE&G rf SAMPLER(S) SIGNATURE(S): j-- % SAMPLING INITIATED AT: 15:06 SAMPLING ENDED AT: 15:16 PUMP OR TUBING DEPTH IN WELL (feet): 8 TUBING MATERIAL CODE: HDPE/S FIELD -FILTERED: 0 N FILTER SIZE: 1 um Filtration Equipment Type: FIELD DECONTAMINATION: PUMP Y ® TUBING Y ® (replaced) DUPLICATE: Y 19 SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 3 CG 40 mL HCL - < 2 VOC (8260) APP 100 1 AG 250 mL - - - PAHs (8270) APP 500 2 AG 100 mL H2SO4 - < 2 TPH (FL -PRO) APP 500 1 AG 1 L - - - Pest. (8081) APP 500 1 AG 1 L - - - Organo Pest (8141) APP 500 1 AG 1 L - - - Herb. (8151) APP 500 1 AG 1 L - - - Dioxins (8290) APP 500 1 PE 250 mL HNO3 - < 2 Metals (6010(7470) APP 500 1 PE 250 mL HNO3 - < 2 Diss. Metals (6010/7470) APP 500 1 PE 250 mL H2SO4 - <2 Ammonia (350.1) APP 500 1 PE 250 mL - - - Nitrates/Nitrites (300.0) APP 500 REMARKS: T.O.Q. -05' YSI556 MPM#7 TBM#2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) -B I L dS NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS - e ow an u ace 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally ± 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 E Ei 6G ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: SCS-MW-2 SAMPLE ID: PACE SITE LOCATION: 1802 NW 37th Ave, Miami, FL 33125 DATE: 3 / 11 / 2019 PURGING DATA (2/2B/3 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 1.86 feet to 11.86 feet STATIC DEPTH TO WATER (feet BLS): 3.83 PURGE PUMP TYPE OR BAILER: PP#4 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only rill out if applicable) = ( 11.86 feet- 3.83 feet) X 0.09 gallons/foot = 0.72 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 8 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 8 PURGING INITIATED AT: 09:56 PURGING ENDED AT: 10:24 TOTAL VOLUME PURGED (gallons): 3.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard Siunit COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 10:12 2.0 2.0 0.125 3.84 6.36 0.430 2.36 11.1 26.08 Clear None 10:16 0.5 2.5 0.125 3.84 6.42 0.426 1.97 11.4 26.04 Clear None 10:20 0.5 3.0 0.125 3.84 6.50 0.420 1.68 10.7 25.13 Clear None 10:24 0.5 3.5 0.125 3.84 6.54 0.420 1.47 11.0 26.07 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Michael Van Ry / EE&G SAMPLER(S) SIGNATURE(S): SAMPLING INITIATED AT: 10:24 SAMPLING ENDED AT: 10:26 PUMP OR TUBING DEPTH IN WELL (feet): 8 TUBING FIELD -FILTERED: Y ® FILTER SIZE: MATERIAL CODE: HDPE/S Filtration Equipment Type: µm FIELD DECONTAMINATION: PUMP Y ® TUBING Y ® (replaced) DUPLICATE: Y El SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 AG 1 L - - - Pest. (8141) APP 500 REMARKS: T.O. C. -0.3' YSI556 MPM # 7 TBM# 2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) . 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 E Ei ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: GW-1 (SB-A) SITE LOCATION: 1802 NW 37th Avenue Miami, FL 33125 SAMPLE ID: PACE DATE: 3 / 26 / 2019 PURGING DATA (2 / 2B / 3 WELL (SP15) DIAMETER (inches): 0.75 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 6 feet to 10 feet STATIC DEPTH TO WATER (feet BLS): -6.0 PURGE PUMP TYPE OR BAILER: PP#4 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 10 feet- 6 feet) X 0.02 gallons/foot = 0.08 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 9 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 9 PURGING INITIATED AT: 9:26 PURGING ENDED AT: 9:38 TOTAL VOLUME PURGED (gallons): 1.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) PH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 9:34 1.0 1.0 0.125 -6.0 6.87 0.804 OR 6.9 27.09 Cloudy Hydrocarbon 9:36 0.25 1.25 0.125 -6.0 6.99 0.816 OR 8.1 27.14 Cloudy Hydrocarbon 9:38 0.25 1.5 0.125 -6.0 7.02 0.839 227 3.8 27.20 Cloudy Hydrocarbon WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1 25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0 65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (GaI./Ft ): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Jennifer Vega / EE&G SAMPLER(S) SIGNATURE(S): r� -- 1_ _ . 2 A.g -. SAMPLING INITIATED AT: 9:38 SAMPLING ENDED AT: 9:40 PUMP OR TUBING . DEPTH IN WELL (feet): 9 TUBING MATERIAL CODE: HDPE/S FIELD -FILTERED: Y it4 FILTER SIZE: Filtration Equipment Type: pm FIELD DECONTAMINATION: PUMP Y E TUBING Y ® (replaced) DUPLICATE: Y El SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 AG 250 mL - - - PAH APP 500 2 AG 125 mL H2SO4 - < 2 TPH APP 500 3 CG 40 mL HCI - <2 VOC APP 100 REMARKS: T.O.C. YS/556 MPM#7 TBM#2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below La 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200- 2); optionally, ± 0.2 mg/L or ± 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally ± 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 E E -G ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-1 SITE LOCATION: 1802 NW 37t Avenue Miami, FL 33125 SAMPLE ID: PACE DATE: 3 / 26 / 2019 PURGING DATA (2/2B/3 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 3 feet to 13 feet STATIC DEPTH TO WATER (feet BLS): 4.7 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) _ ( 13 feet- 4.7 feet) X 0.09 gallons/foot = 0.74 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 9 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 9 PURGING INITIATED AT: 10:17 PURGING ENDED AT: 10:37 TOTAL VOLUME PURGED (gallons): 2.5 TIME VOLUME PURGED CUMUL. VOLUME PURGED (gallons) (g ) PURGE RATE (gpm) DEPTH TO WATER (feet) PH (standard units) COND. (mS/cm ) TURBIDITY (NTUs) ( ) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 10:25 1.0 1.0 0.125 4.7 7.26 0.463 13.7 7.9 26.09 Clear Hydrocarbon 10:29 0.5 1.5 0.125 4.7 7.25 0.461 11.8 7.9 26.13 Clear Hydrocarbon 10:33 0.5 2.0 0.125 4.7 7.19 0.455 7.4 7.19 26.05 Clear Hydrocarbon 10:37 0.5 2.5 0.125 4.7 7.18 0.453 4.9 4.6 26.05 Clear Hydrocarbon WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0 65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft ): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; O = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Russell Femandez / EE&G SAMPLER(S) SIGNATURE(S): -- SAMPLING INITIATED AT: 10:38 SAMPLING ENDED AT: 10:45 PUMP OR TUBING DEPTH IN WELL (feet): 9 TUBING MATERIAL CODE: HDPE/S FIELD -FILTERED: M N FILTER SIZE: Filtration Equipment Type: 1 tun FIELD DECONTAMINATION: PUMP Y ® TUBING Y © (replaced) DUPLICATE: Y QN SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total As, Ba, Pb, Fe APP 500 1 PE 250 mL HNO3 - < 2 Diss. As Ba, Pb, Fe APP 500 1 AG 1 L - - - OC Pest. 8081 APP 500 REMARKS: T.O.C. -03' YS/556 MPM#7 TBM#2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) : 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200- 2); optionally, ± 0.2 mg/L or ± 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally ± 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 E E - G LLC ENVIRONMENTAL SERVICES, 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-2 SITE LOCATION: 1802 NW 37"' Avenue Miami, FL 33125 SAMPLE ID: PACE DATE: 3 / 26 / 2019 PURGING DATA (2 / 2B / 3 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 4.69 feet to 14.69 feet STATIC DEPTH TO WATER (feet BLS): 6.66 PURGE PUMP TYPE OR BAILER: PP#4 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 14.69 feet - 6.66 feet) X 0.09 gallons/foot = 0.72 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 11 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 11 PURGING INITIATED AT: 11:07 PURGING ENDED AT: 11:27 TOTAL VOLUME PURGED (gallons): 2.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 11:15 1.0 1.0 0.125 6.66 6.77 0.700 27.3 8.1 25.85 Clear None 11:19 0.5 1.5 0.125 6.66 6.84 0.664 21.8 4.7 25.86 Clear None 11:23 0.5 2.0 0.125 6.66 6.87 0.652 17.8 3.5 25.96 Clear None 11:27 0.5 2.5 0.125 6.66 6.87 0.654 14.6 3.0 25.88 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1 25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0 65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft ): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Jennifer Vega / EE&G SAMPLER(S) SIGNATURE(S): es..-- SAMPLING INITIATED AT: 11:27 SAMPLING ENDED AT: 11:30 PUMP OR TUBING DEPTH IN WELL (feet): 11 TUBING MATERIAL CODE: HDPE/S FIELD -FILTERED: d N FILTER SIZE: Filtration Equipment Type: 1 pm FIELD DECONTAMINATION: PUMP Y QN TUBING Y ® (replaced) DUPLICATE: Y El SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total As, Ba, Pb, Fe APP 500 1 PE 250 mL HNO3 - ` 2 Diss. As, Ba, Pb, Fe APP 500 1 AG 1 L - - - OC Pest. 8081 APP 500 REMARKS: T.O. C -028' YS/ 556 MPM # 7 TBM# 2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200- 2); optionally, ± 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally ± 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 E Ei -G ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-3 SITE LOCATION: 1802 NW 37°' Avenue Miami. FL 33125 SAMPLE ID: PACE DATE 3/26/2019 PURGINGDATA(2/2B/3 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 2.87 feet to 12.87 feet STATIC DEPTH TO WATER (feet BLS): 4.58 PURGE PUMP TYPE OR BAILER: PP#4 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 12.87 feet - 4.58 feet) X 0.09 gallons/foot = 0.75 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 9 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 9 PURGING INITIATED AT: 11:51 PURGING ENDED AT: 12:11 TOTAL VOLUME PURGED (gallons): 2.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) PH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 11:59 1.0 1.0 0.125 4.58 6.87 0.744 85.7 11.2 25.70 Clear None 12:03 0.5 1.5 0.125 4.58 6.84 0.723 71.8 5.7 25.40 Clear None 12:07 0.5 2.0 0.125 4.58 6.83 0.714 43.1 4.0 25.26 Clear None 12:11 0.5 2.5 0.125 4.58 6.80 0.711 26.4 3.1 25.28 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1 25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0 65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft ): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; O = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Jennifer Vega / EE&G SAMPLER(S) SIGNATURE(S): /� *� gt8` SAMPLING INITIATED AT: 12:11 SAMPLING ENDED AT: 12:14 PUMP OR TUBING DEPTH IN WELL (feet): 9 TUBING MATERIAL CODE: HDPE/S FIELD -FILTERED: M N FILTER SIZE: Filtration Equipment Type: 1 µm FIELD DECONTAMINATION: PUMP Y ® TUBING Y © (replaced) DUPLICATE: Y 0 SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total As, Ba, Pb, Fe APP 500 1 PE 250 mL HNO3 - < 2 Diss. As, Ba, Pb, Fe APP 500 1 AG 1 L - - - OC Pest. 8081 APP 500 1 PE 250 mL H2SO4 - < 2 Ammonia (350.1) APP 500 1 AG 1 L - - - Dioxins & Furans APP 500 REMARKS: T.O.C. -027' YS/556 MPM#7 TBM#2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200- 2); optionally, ± 0.2 mg/L or ± 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally ± 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 EEG 5751 Miami Lakes Dr. Miami Lakes, FL 33014 ENVIRONMENTAL SERVICES, LLC Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-4 SITE LOCATION: 1802 NW 37th Avenue Miami, FL 33125 SAMPLE ID: PACE DATE: 3 / 26 / 2019 /2B/3 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 2.89 feet to 12.89 feet STATIC DEPTH TO WATER (feet BLS): 4.46 PURGE PUMP TYPE OR BAILER: PP#4 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 12.89 feet - 4.46 feet) X 0.09 gallons/foot = 0.76 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 9 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 9 PURGING INITIATED AT: 13:06 PURGING ENDED AT: 13:26 TOTAL VOLUME PURGED (gallons): 2.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 13:14 1.0 1.0 0.125 4.46 7.04 0.510 3.16 8.2 26.01 Clear None 13:18 0.5 1.5 0.125 4.46 7.04 0.509 1.31 5.0 25.91 Clear None 13:22 0.5 2.0 0.125 4.46 7.07 0.509 0.76 4.5 25.93 Clear None 13:26 0.5 2.5 0.125 4.46 7.08 0.509 1.12 3.9 25.90 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1 25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0 65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft ): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLED BY (PRINT) / AFFILIATION: Jennifer Vega / EE&G SAMPLER(S) SIGNATURE(S): <: 1J , I,= �� SAMPLING INITIATED AT: 13:26 SAMPLING ENDED AT: 13:30 PUMP OR TUBING DEPTH IN WELL (feet): 9 TUBING MATERIAL CODE: HDPE/S FIELD -FILTERED: 0 N FILTER SIZE: Filtration Equipment Type: 1 µm FIELD DECONTAMINATION: PUMP Y © TUBING Y © (replaced) DUPLICATE: Y 0 SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total As , Ba, Pb, Fe APP 500 1 PE 250 mL HNO3 - ` 2 Diss. As, Ba, Pb, Fe APP 500 1 AG 1 L - - - OC Pest. 8081 APP 500 1 PE 250 mL H2SO4 - < 2 Ammonia (350.1) APP 500 1 AG 1 L - - - Dioxins & Furans APP 500 REMARKS: TO.0 -0.29' YS/556 MPM#7 TBM#2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) - L asrt NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS -Below an u ac 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200- 2); optionally, ± 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally ± 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 EEG ENVIRONMENTAL SERVICES. LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-38 SITE LOCATION: 1802 NW 37`" Avenue Miami, FL 33125 SAMPLE ID: PACE DATE: 3 / 26 / 2019 PURGING DATA (2/2B/3 WELL ( PVC) DIAMETER (inches): 2.0 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 2.38 feet to 12.38 feet STATIC DEPTH TO WATER (feet BLS): 4.40 PURGE PUMP TYPE OR BAILER: PP#4 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 12.38 feet- 4.40 feet) X 0.16 gallonslfoot = 1.28 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 8 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 8 PURGING INITIATED AT: 12:05 PURGING ENDED AT: 12:52 TOTAL VOLUME PURGED (gallons): 9.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) PH (standard ) COND. (mS/cm) TURBIDITY (NTUs) ) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 12:40 8.0 8.0 0.125 4.48 6.54 0.498 31.8 11.6 26.48 Clear None 12:44 0.5 8.5 0.125 4.48 6.53 0.496 28.2 11.5 26.44 Clear None 12:48 0.5 9.0 0.125 4.48 6.53 0.495 23.6 11.4 26.48 Clear None 12:52 0.5 9.5 0.125 4.48 6.54 0.495 17.1 11.4 26.49 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0 65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft ): 1/8" = 0.0006; 3/16' = 0.0014; 1/4" = 0.0026; 5/16" = 0 004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Kelsey Cortina / EE&G SAMPLER(S) SIGNATURE(S): Gcslra SAMPLING INITIATED AT: 12:52 SAMPLING ENDED AT: 12:55 PUMP OR TUBING DEPTH IN WELL (feet): 8 TUBING FIELD -FILTERED: 0 N FILTER SIZE: MATERIAL CODE: HDPE/S Filtration Equipment Type: 1 im FIELD DECONTAMINATION: PUMP Y QN TUBING Y ®(replaced) DUPLICATE: Y QN SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total As, Ba, Pb, Fe APP 500 1 PE 250 mL HNO3 - < 2 Diss. As, Ba, Pb, Fe APP 500 1 AG 1 L - - - OC Pest. 8081 APP 500 REMARKS: T.O.C. -037 YSI556 MPM#7 TBM# I Sediment buildup encountered, well had thick brown water - purge to clear of approximately 8 gallons. MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HOPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) : 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 31 pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200- 2); optionally, ± 0.2 mg/L or ± 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally ± 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 EEG ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-5 SITE LOCATION: 1802 NW 37"' Avenue Miami, FL 33125 SAMPLE ID: PACE DATE: 3/26/2019 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 3.05 feet to 13.05 feet STATIC DEPTH TO WATER (feet BLS): 4.5 PURGE PUMP TYPE OR BAILER: PP#4 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 13.05 feet - 4.5 feet) X 0.09 gallons/foot = 0.77 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 8 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 8 PURGING INITIATED AT: 13:34 PURGING ENDED AT: 13:54 TOTAL VOLUME PURGED (gallons): 2.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standardts) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 13:42 1.0 1.0 0.125 4.5 6.85 0.879 22.1 8.6 25.67 Clear Organic 13:46 0.5 1.5 0.125 4.5 6.85 0.881 21.5 8.2 25.71 Clear Organic 13:50 0.5 2.0 0.125 4.5 6.84 0.881 19.8 7.9 25.73 Clear Organic 13:54 0.5 2.5 0.125 4.5 6.84 0.882 18.5 7.8 25.76 Clear Organic WELL CAPACITY TUBING INSIDE (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1 25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0 65; 5" = 1.02; 6" = 1.47; 12" = 5.88 DIA. CAPACITY (Gal./Ft ): 1/8" = 0.0006; 3116" = 0.0014; 114" = 0.0026; 5116" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; O = Other (Specify) SAMPLED BY (PRINT) / AFFILIATION: KelseyCortina / EE&G SAMPLER(S) SIGNATURE(S): SAMPLING INITIATED AT: 13:54 SAMPLING ENDED AT: 13:57 PUMP OR TUBING DEPTH IN WELL (feet): 8 TUBING FIELD -FILTERED: M N FILTER SIZE: MATERIAL CODE: HDPE/S Filtration Equipment Type: 1 µm FIELD DECONTAMINATION: PUMP Y ® TUBING Y ® (replaced) DUPLICATE: Y 0 SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total As, Ba, Pb, Fe APP 500 1 PE 250 mL HNO3 - < 2 Diss. As, Ba, Pb, Fe APP 500 1 AG 1 L - - - OC Pest. 8081 APP 500 1 PE 250 mL H2SO4 - < 2 Ammonia (350.1) APP 500 REMARKS: T O C -0.35' YSI556 MPM # 7 TBM# I MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) 3 BLS = Below Land Surface NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A C. 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200- 2); optionally, ± 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 E Ei 6G ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) SITE LOCATION: 1802 NW 37m Avenue Miami, FL 33125 WELL NO: MW-9 SAMPLE ID: PACE DATE: 3 / 26 / 2019 PURGING DATA (2 / 2B / 3 WELL ( PVC) DIAMETER (inches): 2 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 2.97 feet to 12.97 feet STATIC DEPTH TO WATER (feet BLS): 4.07 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 12.97 feet - 4.07 feet) X 0.16 gallons/foot = 1.42 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 8.5 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 8.5 PURGING INITIATED AT: 14:34 PURGING ENDED AT: 15:02 TOTAL VOLUME PURGED (gallons): 3.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) PH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 14:50 2.0 2.0 0.125 4.07 6.92 1.032 12.4 12.5 27.20 Orange Murky Hydrocarbon 14:54 0.5 2.5 0.125 4.07 6.74 1.047 10.3 8.7 27.03 Clear Hydrocarbon 14:58 0.5 3.0 0.125 4.07 6.40 1.054 11.5 5.4 26.96 Clear Hydrocarbon 15:02 0.5 3.5 0.125 4.07 6.37 1.051 9.8 4.8 26.83 Clear Hydrocarbon WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0 65; 5" = 1.02; 6" = 1.47 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft ): 1/8" = 0.0006; 3/16' = 0.0014; 1/4" = 0.0026; 5/16" = 0 004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Russell Fernandez / EE&G SAMPLER(S) SIGNATURE(S): SAMPLING INITIATED AT: 15:02 SAMPLING ENDED AT: 15:15 PUMP OR TUBING DEPTH IN WELL (feet): 8.5 TUBING MATERIAL CODE: HDPE/S FIELD -FILTERED: 0 N FILTER SIZE: Filtration Equipment Type: 1 pm FIELD DECONTAMINATION: PUMP Y ® TUBING Y ® (replaced) DUPLICATE: Y E SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 3 CG 40 mL HCL - < 2 VOC APP 100 1 AG 250 mL - - - PAH APP 500 2 AG 100 mL H2SO4 - < 2 TPH APP 500 1 AG 1 L - - - Pest. 8141 APP 500 1 AG 1 L - - - Herb. 8151 APP 500 1 PE 250 mL H2SO4 - < 2 Ammonia APP 500 1 AG 1 L - - < 2 OC Pest. 8081 APP 500 1 PE 250 mL HNO3 - < 2 As, Ba, Pb, Fe APP 500 1 PE 250 mL HNO3 - < 2 Diss. As, Ba, Pe, Fe APP 500 REMARKS: T.O.C. -0.27' YS/556 MPM#7 TBM#2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) : 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 2. STABIUZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212. SECTION 3) 3. BLS = Below Land Surface pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200- 2); optionally, ± 0.2 mg/L or ± 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally ± 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 E E , ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course 2018-3057 WELL NO: MW-44 SITE LOCATION: 1802 NW 37t Ave, Miami, FL 33125 SAMPLE ID: PACE /3 DATE: 3/27/2019 WELL ( PVC) DIAMETER (inches): 2.0 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 1.88 feet to 11.88 feet STATIC DEPTH TO WATER (feet BLS): 4.0 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 11.88 feet - 4.0 feet) X 0.16 gallons/foot = 1.26 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X 20 feet) + gallons = gallons INITIAL PUMP OR TUB NG DEPTH IN WELL (feet): 8 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 8 PURGING INITIATED AT: 07:27 PURGING ENDED AT: 07:51 TOTAL VOLUME PURGED (gallons): 3.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (9pm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 07:43 2.0 2.0 0.125 4 6.82 0.967 10.5 8.4 24.20 Clear None 07:47 0.5 2.5 0.125 4 6.84 0.961 7.9 5.8 24.63 Clear None 07:51 0.5 3.0 0.125 4 6.82 0.958 8.3 4.7 24.54 Clear None 07:55 0.5 3.5 0.125 4 6.82 0.957 7.4 4.1 24.58 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25' = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 518" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLED BY (PRINT) / AFFILIATION: Russell Fernandez / EE&G SAMPLER(S) SIGNATURE(S): « '_� - SAMPLING INITIATED AT: 07:55 SAMPLING ENDED AT: 08:00 PUMP OR TUBING DEPTH IN WELL (feet): 8.0 TUBING MATERIAL CODE: HDPE/S FIELD -FILTERED: 0 N FILTER SIZE: 1 µm Filtration Equipment Type: FIELD DECONTAMINATION: PUMP Y ® TUBING Y ® (replaced) DUPLICATE: Y E SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total Fe APP 500 1 PE 250 mL HNO3 - < 2 Diss. Fe APP 500 1 AG 1 L - - - Dieldrin 8081 APP 500 REMARKS: T.O.C. -02' YS1556 MPM # 7 TBM# 2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) S-B I I dS rf NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BL - e ow an u ace 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, ± 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally ± 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 E Ei -G ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: SCS-MW-1 SITE LOCATION: 1802 NW 37th Avenue Miami, FL 33125 SAMPLE ID: PACE DATE: 3 / 27 / 2019 PURGING DATA (2/2B/3 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 2.1 feet to 12.1 feet STATIC DEPTH TO WATER (feet BLS): 4.0 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 12.1 feet- 4.0 feet) X 0.09 gallons/foot = 0.73 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 8 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 8 PURGING INITIATED AT: 08:45 PURGING ENDED AT: 09:01 TOTAL VOLUME PURGED (gallons): 2.0 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND_ (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 08:53 1.0 1.0 0.125 4.0 6.89 0.711 48.9 0.5 22.85 Murky / Orange None 08:57 0.5 1.5 0.125 4.0 6.90 0.650 27.6 2.7 22.87 Murky' Orange None 09:01 0.5 2.0 0.125 4.0 6.92 0.702 25.2 3.3 22.92 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0 65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft ): 1/8" = 0.0006; 3/16' = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer, BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; O = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Russell Femandez / EE&G SAMPLER(S) SIGNATURE(S): SAMPLING INITIATED AT: 09:01 SAMPLING ENDED AT: 09:10 PUMP OR TUBING DEPTH IN WELL (feet): 8 TUBING MATERIAL CODE: HDPE/S FIELD -FILTERED: M N FILTER SIZE: Filtration Equipment Type: 1 pm FIELD DECONTAMINATION: PUMP Y 0 TUBING Y ® (replaced) DUPLICATE: Y QN SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total Fe APP 500 1 PE 250 mL HNO3 - < 2 Diss. Fe APP 500 1 AG 1 L - - - Dieldrin 8081 APP 500 REMARKS: T.O.C. -O4' YS/556 MPM#7 TBM#2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) : 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 31 pH: ± 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200- 2); optionally, ± 0.2 mg/L or ± 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally ± 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 EE&G SERVICES, LLC ENVIRONMENTAL 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-8 SITE LOCATION: 1802 NW 37th Avenue Miami, FL 33125 SAMPLE ID: PACE DATE: 3 / 27 / 2019 PURGING DATA (2/2B/3 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 2.89 feet to 12.89 feet STATIC DEPTH TO WATER (feet BLS): 4.3 PURGE PUMP TYPE OR BAILER: PP#4 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 12.89 feet - 4.3 feet) X 0.09 gallons/foot = 0.77 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 8 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 8 PURGING INITIATED AT: 09:28 PURGING ENDED AT: 09:48 TOTAL VOLUME PURGED (gallons): 2.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gPm) DEPTH TO WATER (feet) PH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 09:36 1.0 1.0 0.125 4.3 7.09 0.614 102 5.7 24.98 Cloudy None 09:40 0.5 1.5 0.125 4.3 7.08 0.611 67.3 4.8 24.95 Cloudy None 09:44 0.5 2.0 0.125 4.3 7.07 0.605 29.5 4.4 24.92 Cloudy None 09:48 0.5 2.5 0.125 4.3 7.09 0.607 17.6 3.0 25.17 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1 25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0 65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft ): 118" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Kelsey Cortina / EE&G SAMPLER(S) SIGNATURE(S): Ccrt.SAMPLING r\o INITIATED AT: 09:48 SAMPLING ENDED AT: 09:55 PUMP OR TUBING DEPTH IN WELL (feet): 8 TUBING FIELD -FILTERED: d N FILTER SIZE: MATERIAL CODE: HDPEJS Filtration Equipment Type: 1 iim FIELD DECONTAMINATION: PUMP Y ® TUBING Y ® (replaced) DUPLICATE: Y SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total As , Ba. Pb, Fe APP 500 1 PE 250 mL HNO3 - < 2 Diss. As, Ba. Pb, Fe APP 500 1 AG 1 L - - - OC Pest. 8081 APP 500 REMARKS: T.O. C. -0./7' YS1556 MPM # 7 TBM# 1 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.G. 3. BLS =Below Land Surrac 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212. SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200- 2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally ± 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 E E -G ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-7 SITE LOCATION: 1802 NW 37°i Avenue Miami, FL 33125 SAMPLE ID: PACE DATE: 3/27/2019 PURGING DATA (2/2B/3 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 1.92 feet to 11.92 feet STATIC DEPTH TO WATER (feet BLS): 3.64 PURGE PUMP TYPE OR BAILER: PP#4 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 11.92 feet- 3.64 feet) X 0.09 gallons/foot = 0.75 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING FINAL PUMP OR TUBING DEPTH IN WELL (feet): 7 DEPTH IN WELL (feet): 7 PURGING INITIATED AT: 10:28 PURGING ENDED AT: 10:56 TOTAL VOLUME PURGED (gallons): 3.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 10:36 1.0 1.0 0.125 7.64 7.32 0.991 213 14.3 25.23 Cloudy None 10:40 0.5 1.5 0.125 7.64 7.20 0.890 124 5.7 25.42 Cloudy None 10:44 0.5 2.0 0.125 7.64 7.20 0.890 72.4 5.5 25.45 Cloudy None 10:48 0.5 2.5 0.125 7.64 7.17 0.880 56.9 3.8 25.35 Cloudy None 10:52 0.5 3.0 0.125 7.64 7.15 0.794 42.1 3.5 25.33 Clear None 10:56 0.5 3.5 0.125 7.64 7.14 0.786 23.6 3.4 25.35 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1 25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0 65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft ): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0 004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Kelsey Cortina / EE&G SAMPLER(S) SIGNATURE(S) ra SAMPLING INITIATED AT: 10:56 SAMPLING ENDED AT: 10:59 PUMP OR TUBING DEPTH IN WELL (feet): 7 TUBING MATERIAL CODE: HDPE/S FIELD -FILTERED: 0 N FILTER SIZE: Filtration Equipment Type: 1 pm FIELD DECONTAMINATION: PUMP Y ® TUBING Y © (replaced) DUPLICATE: Y E SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL 1-1NO3 - < 2 Total As, Ba, Pb, Fe APP 500 1 PE 250 mL HNO3 - < 2 Diss. As, Ba, Pb, Fe APP 500 1 AG 1 L - - - OC Pest. 8081 APP 500 REMARKS: T.O.C. -02' YS/ 556 MPM # 7 TBM# I MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene: S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) : 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200- 2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 E E t ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-6 SITE LOCATION: 1802 NW 37'" Avenue Miami, FL 33125 SAMPLE ID: PACE DATE: 3 / 27 / 2019 2/2B/3 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 3.0 feet to 13.0 feet STATIC DEPTH TO WATER (feet BLS): 5.1 PURGE PUMP TYPE OR BAILER: PP#4 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 13.0 feet- 5.1 feet) X 0.09 gallons/foot = 0.69 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 9 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 9 PURGING INITIATED AT: 11:33 PURGING ENDED AT: 11:57 TOTAL VOLUME PURGED (gallons): 3.0 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 11:41 1.0 1.0 0.125 5.1 7.13 0.416 68.8 6.6 25.74 Cloudy None 11:45 0.5 1.5 0.125 5.1 7.13 0.411 66.7 5.8 25.77 Cloudy None 11:49 0.5 2.0 0.125 5.1 7.14 0.406 76.2 5.0 25.78 Cloudy None 11:53 0.5 2.5 0.125 5.1 7.14 0.400 80.0 4.7 25.76 Cloudy None 11:57 0.5 3.0 0.125 5.1 7.15 0.396 105 4.3 25.75 Cloudy None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1 25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0 65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft ): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; O = Other (Specify) SAMPLED BY (PRINT) / AFFILIATION: Kelsey Cortina / EE&G SAMPLER(S) SIGNATURE(S): SAMPLING INITIATED AT: 11:57 SAMPLINGDA ENDED AT: 12:00 PUMP OR TUBING DEPTH IN WELL (feet): 9 TUBING FIELD -FILTERED: M N FILTER SIZE: MATERIAL CODE: HDPE/S Filtration Equipment Type: 1 pm FIELD DECONTAMINATION: PUMP Y ® TUBING Y ® (replaced) DUPLICATE: Y E SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total As, Ba, Pb, Fe APP 500 PE 250 mL HNO3 - < 2 Diss. As, Ba, Pb, Fe APP 500 1 AG 1 L - - - OC Pest. 8081 APP 500 REMARKS: T.O.0 -02' YS/556 MPM#7 TBM# 1 MATERIAL CODES: AG = Amber S = Silicone; Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; 0 = Other (Specify) T = Teflon; SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS -Below Land Surfac 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200- 2); optionally, ± 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally ± 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 E E -G ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course 2018-3057 WELL NO: MW-31 SITE LOCATION: 1802 NW 37t Ave, Miami, FL 33125 SAMPLE ID: PACE PURGING DATA (2 / 2B / 3 DATE: 3 / 27 / 2019 WELL ( PVC) DIAMETER (inches): 2.0 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 2.6 feet to 12.6 feet STATIC DEPTH TO WATER (feet BLS): 3.85 PURGE PUMP TYPE OR BAILER: PP#4 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 12.6 feet - 3.85 feet) X 0.16 gallons/foot = 1.4 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 8.5 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 8.5 PURGING INITIATED AT: 12:20 PURGING ENDED AT: 12:48 TOTAL VOLUME PURGED (gallons): 3.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet)units) pH (standard COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (%Saturation) TEMP. c (C) COLOR (describe) ODOR (describe) 12:36 2.0 2.0 0.125 3.85 7.07 0.540 33.1 4.9 28.14 Clear None 12:40 0.5 2.5 0.125 3.85 7.07 0.548 14.3 2.7 28.11 Clear None 12:44 0.5 3.0 0.125 3.85 7.07 0.547 14.5 2.6 27.09 Clear None 12:48 0.5 3.5 0.125 3.85 7.07 0.545 12.7 2.1 28.02 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Kelsey Cortina / EE&G SAMPLER(S) SIGNATURE(S): *...,.... SAMPLING INITIATED AT: 12:48 SAMPLING ENDED AT: 12:51 PUMP OR TUBING DEPTH IN WELL (feet): 8.5 TUBING MATERIAL CODE: HDPE/S FIELD -FILTERED: 0 N FILTER SIZE: Filtration Equipment Type: 1 um FIELD DECONTAMINATION: PUMP Y ® TUBING Y ® (replaced) DUPLICATE: Y E SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE i mn per mnute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total As, Fe APP 500 1 PE 250 mL HNO3 - < 2 Diss. As, Fe APP 500 1 AG 1 L - - - Dieldrin 8081 APP 500 REMARKS_ T O. C. 0.5' VS1556 MPM # 7 TBM# 1 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; S = Silicone; T = Teflon; 0 = Other (Specify) LDPE = Low Density Polyethylene; PP = Polypropylene; SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailee BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) : 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 E E t ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-2 SITE LOCATION: 1802 NW 37th Avenue Miami, FL 33125 SAMPLE ID: PACE DATE: 4 / 8 / 2019 PURGING DATA (2/2B/3 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 4.69 feet to 14.69 feet STATIC DEPTH TO WATER (feet BLS): 6.4 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 14.69 feet - 6.4 feet) X 0.06 gallons/foot = 0.48 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 10.5 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 10.5 PURGING INITIATED AT: 10:15 PURGING ENDED AT: 10:35 TOTAL VOLUME PURGED (gallons): 2.5 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. ( mS/cm) TURBIDITY (NTUs)(% DISSOLVED OXYGEN Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 10:23 1.0 1.0 0.125 6.44 6.90 0.724 OR 5.8 25.31 Cloudy None 10:27 0.5 1.5 0.125 6.44 6.91 0.719 OR 5.2 25.39 Cloudy None 10:31 0.5 2.0 0.125 6.44 6.92 0.709 OR 4.4 25.47 Cloudy None 10:35 0.5 2.5 0.125 6.44 6.92 0.711 OR 3.9 25.42 Cloudy None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1 25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0 65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft ): 1/8" = 0.0006; 3/16" = 0.0014; 1 /4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Russell Femandez / EE&G SAMPLER(S) SIGNATURE(S): - SAMPLING INITIATED AT: 10:35 SAMPLING ENDED AT: 10:40 PUMP OR TUBING DEPTH IN WELL (feet): 10.5 TUBING MATERIAL CODE: HDPE/S FIELD -FILTERED: 0 N FILTER SIZE: Filtration Equipment Type: Disposable 1 um FIELD DECONTAMINATION: PUMP Y QN TUBING Y ® (replaced) DUPLICATE: Y 0 SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total As, Fe APP 500 1 PE 250 mL HNO3 - < 2 Dissolved As, Fe APP 500 REMARKS: T.O.C. -028' YS/556 MPM#7 TBM#2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: ± 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200- 2); optionally, ± 0.2 mg/L or ± 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 E Ei -G ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) SITE LOCATION: 1802 NW 37fh Ave. Miami, FL 33125 WELL NO: MW-38 SAMPLE ID: PACE DATE: 4 / 8 / 2019 PURGING DATA (2/2B/3 WELL ( PVC) DIAMETER (inches): 2.0 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 4.3 feet to 14.3 feet STATIC DEPTH TO WATER (feet BLS): 3.71 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 14.3 feet - 3.71 feet) X 0.16 gallons/foot = 1.69 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 9 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 9 PURGING INITIATED AT: 11:29 PURGING ENDED AT: 11:53 TOTAL VOLUME PURGED (gallons): 3.0 TIME VOLUME PURGED (gallons)units) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (� Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 11:45 2.0 2.0 0.125 3.74 7.08 0.577 7.22 4.6 25.77 Clear None 11:49 0.5 2.5 0.125 3.74 7.09 0.554 6.43 3.0 25.76 Clear None 11:53 0.5 3.0 0.125 3.74 7.10 0.549 3.18 2.8 25.75 Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006, 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Russell Fernandez / EE&G SAMPLER(S) SIGNATURE(S): 1G------- SAMPLING INITIATED AT: 11:54 SAMPLING ENDED AT: 12:00 PUMP OR TUBING DEPTH IN WELL (feet): 9 TUBING MATERIAL CODE: HDPE/S FIELD -FILTERED: 0 N FILTER SIZE: Filtration Equipment Type: 1 pm FIELD DECONTAMINATION: PUMP Y QN TUBING Y QN (replaced) DUPLICATE: Y �N SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total Fe APP 500 1 PE 250 mL HNO3 - < 2 Dissolved Fe APP 500 REMARKS TO C. -037' YS1556 MPM # 7 TBM# 2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 EEG ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-9 SITE LOCATION: 1802 NW 37th Ave, Miami, FL 33125 SAMPLE ID: PACE DATE: 4 / 8 / 2019 PURGING DATA (2 / 2B / 3 WELL ( PVC) DIAMETER (inches): 2.0 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 2.97 feet to 12.97 feet STATIC DEPTH TO WATER (feet BLS): 3.73 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) _ ( 12.97 feet - 3.73 feet) X 0.16 gallons/foot = 1.48 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 8.5 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 8.5 PURGING INITIATED AT: 12:40 PURGING ENDED AT: 13:04 TOTAL VOLUME PURGED (gallons): 3.0 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (% Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 12:56 2.0 2.0 0.125 4.23 6.89 1.250 6.3 3.9 26.93 Clear w/ organic debris Norte 13:00 0.5 2.5 0.125 4.23 6.92 1.187 7.13 3.4 26.90 Clear w/ organic debris None 13:04 0.5 3.0 0.125 4.23 6.94 1.168 7.08 3.8 26.89 Clear w/ organic debris None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Russell Femandez / EE&G SAMPLER(S) SIGNATURE(S): SAMPLING INITIATED AT: 13:05 SAMPLING ENDED AT: 13:10 PUMP OR TUBING DEPTH IN WELL (feet): 8.5 TUBING MATERIAL CODE: HDPE/S FIELD -FILTERED: 6 N FILTER SIZE: Filtration Equipment Type: 1 µm FIELD DECONTAMINATION: PUMP Y ® TUBING Y ® (replaced) DUPLICATE: Y �N SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE min per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total Fe APP 500 1 PE 250 mL HNO3 - < 2 Dissolved Fe APP 500 REMARKS T.O.C. -0.27' YS/ 556 MPM # 7 TBM# 2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene: S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 E E G ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-5 SAMPLE ID: PACE SITE LOCATION: 1802 NW 37th Avenue Miami, FL 33125 DATE: 4 / 8 / 2019 PURGING DATA (2 / 2B / 3 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 025 WELL SCREEN INTERVAL DEPTH: 3.05 feet to 13.05 feet STATIC DEPTH TO WATER (feet BLS): 4.24 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 13.05 feet- 4.24 feet) X 0.09 gallons/foot = 0.79 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 8 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 8 PURGING INITIATED AT: 13:48 PURGING ENDED AT: 14:12 TOTAL VOLUME PURGED (gallons): 3.0 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (qpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (%Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 13:56 1.0 1.0 0.125 4.26 7.29 0.843 OR 5.0 25.40 Cloudy None 14'00 0.5 1.5 0.125 4.26 7.22 0.792 OR 2.9 25.38 Cloudy None 14:04 0.5 2.0 0.125 4.26 7.22 0.785 OR 2.7 25.38 Cloudy None 14:08 0.5 2.5 0.125 4.26 7.21 0.772 OR 2.3 25.33 Cloudy None 14:12 0.5 3.0 0.125 4.26 7.22 0.769 OR 2.5 25.32 Cloudy None WELL CAPACITY (Gallons Per Foot): 0.75" = 0 02; 1" = 0.04; 1.25" = 0.06 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12 = 5.88 TUBING INSIDE DIA CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/18" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 318" = 0.006; 1/2" = 0.010 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer, BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Spedfy) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Russell Femandez / EE&G SAMPLER(S) SIGNATURE(S): - ' "-`. SAMPLING INITIATED AT: 14:12 SAMPLING ENDED AT: 14:20 PUMP OR TUBING DEPTH IN WELL (feet): 8 TUBING FIELD -FILTERED: 0 N FILTER MATERIAL CODE: HDPE/S Filtration Equipment Type: SIZE: 1 pm FIELD DECONTAMINATION: PUMP Y © TUBING Y ® (replaced) DUPLICATE: Y H SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE ((CONTAINERS MATERIAL VOLUMEVOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total Fe APP 500 1 PE 250 mL HNO3 - < 2 Diss. Fe APP 500 REMARKS: T.O.C. -0.35' YS/556 MPM#7 TBM#2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 31 pH: + 0.2 units Temperature: ± 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, ± 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 EE6G ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-10 SITE LOCATION: 1802 NW 37"' Ave, Miami, FL 33125 SAMPLE ID: PACE DATE: 4 / 9 / 2019 3 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 3.6 feet to 13.6 feet STATIC DEPTH TO WATER (feet BLS): 5.75 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH (only fill out if applicable) = ( 13.6 feet - 5.75 feet) X TO WATER) X WELL CAPACITY 0.09 gallons/foot = 0.71 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 9 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 9 PURGING INITIATED AT: 09:36 PURGING ENDED AT: 10:00 TOTAL VOLUME PURGED (gallons): 3.0 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED °OXYGEN (/ Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 09:44 1.0 1.0 0.125 5.77 6.98 0.728 OR 17.8 24.73 Cloudy None 09:48 0.5 1.5 0.125 5.77 7.00 0.722 OR 17.0 24.72 Cloudy None 09:52 0.5 2.0 0.125 5.77 7.03 0.715 OR 16.4 24.72 Cloudy None 09:56 0.5 2.5 0.125 5.77 7.04 0.707 OR 16.0 24.71 Cloudy None 10:00 0.5 3.0 0.125 5.77 7.02 0.710 OR 15.7 24.70 Cloudy None WELL CAPACITY TUBING INSIDE (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026, 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLED BY (PRINT) / AFFILIATION: Russell Fernandez / EE&G SAMPLER(S) SIGNATURE(S): SAMPLING INITIATED AT: 10:00 SAMPLING ENDED AT: 10:05 PUMP OR TUBING DEPTH IN WELL (feet): 9 TUBING MATERIAL CODE: HDPE/S FIELD -FILTERED: N FILTER SIZE: 1 pm Filtration Equipment Type: FIELD DECONTAMINATION: PUMP Y ❑N TUBING Y NQ (replaced) DUPLICATE: Y E SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total As, Pb, Fe APP 500 1 PE 250 mL HNO3 - < 2 Diss. As, Pb, Fe APP 500 REMARKS: TO. C. -0.32' YS1556 MPM # 7 TBM# 2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone: T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) 3 BLS = Below Land Surface NOTES: 1. The above do not constitute all of the Information required by Chapter 62-160, F.A.C. 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 EEG ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) WELL NO: MW-11 SITE LOCATION: 1802 NW 37th Ave, Miami, FL 33125 SAMPLE ID: PACE DATE: 4 / 9 / 2019 PURGING DATA (2/2B/3 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 1.5 feet to 11.5 feet STATIC DEPTH TO WATER (feet BLS): 3.49 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 11.5 feet - 3.49 feet) X 0.09 gallons/foot = 0.72 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 7.5 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 7.5 PURGING INITIATED AT: 10:33 PURGING ENDED AT: 10:57 TOTAL VOLUME PURGED (gallons): 3.0 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED allons (g ) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN (% Saturation) TEMP. c (C) COLOR (describe) ODOR (describe) 10:41 1.0 1.0 0.125 3.5 7.62 0.483 OR 19.8 25.59 Dark Grey / Cloudy None 10:45 0.5 1.5 0.125 3.5 7.61 0.482 OR 16.1 25.59 Dark Grey / Cloudy None 10:49 0.5 2.0 0.125 3.5 7.56 0.482 OR 13.9 25.61 Dark Grey / Cloudy None 10:53 0.5 2.5 0.125 3.5 7.55 0.481 OR 11.8 25.59 Dark Grey / Cloudy None 10:57 0.5 3.0 0.125 3.5 7.54 0.481 OR 11.2 25.58 Dark Grey / Cloudy None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3116" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004: 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Russell Fernandez / EE&G SAMPLER(S) SIGNATURE(S): SAMPLING INITIATED AT: 10:58 SAMPLING ENDED AT: 11:04 PUMP OR TUBING DEPTH IN WELL (feet): 7.5 TUBING MATERIAL CODE: HDPE/S FIELD -FILTERED: 0 N FILTER SIZE: Filtration Equipment Type: 1 fim FIELD DECONTAMINATION: PUMP Y ON TUBING Y QN (replaced) DUPLICATE: Y QN SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE (mL per minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total As. Pb, Fe APP 500 1 PE 250 mL HNO3 - < 2 Diss. As, Pb, Fe APP 500 REMARKS: TO.0 -0I9' YS/556 MPM#7 TBM#2 MATERIAL CODES. AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) : 1. The above do not constitute all of the Information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 E Ei -G ENVIRONMENTAL SERVICES, LLC 5751 Miami Lakes Dr. Miami Lakes, FL 33014 Phone: (305) 374-8300 Fax: (305) 374-9004 GROUNDWATER SAMPLING LOG SITE NAME: Melreese Golf Course (2018-3057) SITE LOCATION: 1802 NW 37"' Ave, Miami, FL 33125 WELL NO: MW-12 SAMPLE ID: PACE DATE: 4 / 9 / 2019 PURGINGDATA(2/2B/3 WELL ( PVC) DIAMETER (inches): 1.5 TUBING DIAMETER (inches): 0.25 WELL SCREEN INTERVAL DEPTH: 2.35 feet to 12.35 feet STATIC DEPTH TO WATER (feet BLS): 3.3 PURGE PUMP TYPE OR BAILER: PP#2 WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 12.35 feet - 3.3 feet) X 0.09 gallons/foot = 0.81 gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons INITIAL PUMP OR TUBING DEPTH IN WELL (feet): 8.0 FINAL PUMP OR TUBING DEPTH IN WELL (feet): 8.0 PURGING INITIATED AT: 11:26 PURGING ENDED AT: 11:50 TOTAL VOLUME PURGED (gallons): 3.0 TIME VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) DEPTH TO WATER (feet) pH (standard units) COND. (mS/cm) TURBIDITY (NTUs) DISSOLVED OXYGEN , (h Saturation) TEMP. (°C) COLOR (describe) ODOR (describe) 11:34 1.0 1.0 0.125 3.87 7.47 0.807 OR 28.3 25.20 Dark Grey / Cloudy None 11:38 0.5 1.5 0.125 3.87 7.41 0.781 OR 23.5 25.19 Dark Grey / Cloudy None 11:42 0.5 2.0 0.125 3.87 7.37 0.754 OR 19.3 25.18 Dark Grey / Cloudy None 11:46 0.5 2.5 0.125 3.87 7.35 0.748 OR 17.4 25.17 Dark Grey / Cloudy None 11:50 0.5 3.0 0.125 3.87 7.32 0.736 OR 16.0 25.16 Dark Grey / Cloudy None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 1.5" = 0.09; 2" = TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" 0.16; 3" = 0.37, 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer, BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: Russell Fernandez / EE&G SAMPLER(S) SIGNATURE(S): -- - SAMPLING INITIATED AT: 11:50 SAMPLING ENDED AT: 11:56 PUMP OR TUBING DEPTH IN WELL (feet): 8.0 TUBING MATERIAL CODE: HDPE/S FIELD -FILTERED: 0 N FILTER SIZE: Filtration Equipment Type: 1 µm FIELD DECONTAMINATION: PUMP Y © TUBING Y ® (replaced) DUPLICATE: Y E SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED ANALYSIS AND/OR METHOD SAMPLING EQUIPMENT CODE SAMPLE PUMP FLOW RATE in mper minute) SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME PRESERVATIVE USED TOTAL VOL ADDED IN FIELD (mL) FINAL pH 1 PE 250 mL HNO3 - < 2 Total As, Pb, Fe APP 500 1 PE 250 mL HNO3 - < 2 Diss. As, Pb, Fe APP 500 REMARKS: TO.C. -0.28' YS/556 MPM#7 TBM#2 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; HDPE = High Density Polyethylene; LDPE = Low Density Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; 0 = Other (Specify) SAMPLING EQUIPMENT CODES: APP = After (Through) Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 3. BLS = Below Land Surface 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE FS 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 °C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 13, 2017 EE&G: Site Rehabilitation Plan August 2019 APPENDIX E PRELIMINARY DESIGN DOCUMENTS NW 37TH AVE NW 42ND AVE NW 19TH TER • NW 19TH ST NW 18TH TER • NW 1811H Si NW 17TH ST Kimley>>> Horn 0200.MLEv NIXiN MO ASSOCIATES. NC EXIST. GROUND AVERAGE MAX. WATER LEVEL 3.0' NGVO EXISTING CONDITION EXIST. GROUND FILL LAKES WITH CLEAN FILL 1 FOOT ABOVE AVERAGE MAX. WATER LEVEL 3.tl• 1.0'• 4.0'NOVD MIAMI FREEDOM PARK LAKE FILL VOLUMES July 22, 2019 PROPOSED CONDITION NW 18TH ST NW 17TH ST PARKING AND //// ELEVATED %//// FIELDS Kimley>>>Horn 0 2010 quLEV.HORN AND ASSOCIATES. INC BUILDING 1 BUILDING 3 BUILDING 5 STADIUM RC)nD B�7 BUILDING A BUILDINGS II-11 II=II-11=F= 11-11..1-11=11 -11=1t� 11=11 11=11=11=11 11 I =11-1111=11 1=11=11=11=11-, II=1 11=1 11=11=11=11 _ 11=11=11=11=1= 11=11=11=11=11=11= 11=111 11=11=11= _ _ 11=11=11=1 11=11 .11=-11=11=11 _=11=11 11=11=11=11. 11: I11:II:11.II:II:� II:11:11:11 III .11:1i=11=11=11 1=11.11—!a —11� 1 r` II=11=11=11 1111: IL11=1 11- 1-11=11 I= . II=11=1 - 11=11= —11=11 —11=11 I1=11=11 _I`d -11=11=11 —11=11=11=11 11=11=11=.11=.1 1=11=11=11=11 1=11=11=11=11=1 =1=11=11011= 1=11=11=11=11=11 11_1111=11=11- 11= 11-11-11=11.-11-111 1=11=11 .11- =11=1 .11=I1-1--1=117911. 11=11-1=1=1=11=A 1= 11=11 11=11=11-11 Z1=11'.- II= =II=11=I ,— ..11=11=11=11= -1 1111=11=11-14 i 1=11=11=11=11:'j A I II=II=11=1—I I 11=11=11=11 11=11=11=11= �,�` 11=11=11=11= I ?I 11=11=11=11=11=1r 11=-11=a=-11=11-11=n-11=11- —,I =11=,i- 11=11=11=1111=11=11=I11 1=1i=ii=11 .11=11=11=11=11=11=11=11=n 11=11=1I. II-11=11=11=11=11=11=11, 11=11==1111-11=11=11=11=11=11=j 11=11=1 11-11=11=11=11=11=11=11=I4 1.I11 1=11=11=11=11=11=11I lr 11= 11=11=11=11=11=1=1=11git;11=11-11-11-1=11=11=11-- 111=11=11=11=11=11=11=11=11— , n—a=11=1l=n-a=:u=u=ii=1t 11-11=11=11=11=11=11=11=11=11. 11.=11-11=11=11=11=11=I1=IL..1P 11=1111=11=11=11=11=11-11= 1=11=1_I=11=11=11=11=11=11— 11=11=11=11=11=J1.=u;--11= 11=11-11-11_ :_ —: 1-11 11=...11%1E. 1I ATH ST NW 19TH TER NW 19TH ST NW 18TH TER NW 18TH ST NW 17TH ST E MIAMI FREEDOM PARK UNSUITABLE MATERIAL EXCAVATION July 22, 2019 LAKES FILLED WITH CLEAN FILL FROM PHASE 1 EXCAVATE UNSUITABLE MATERIAL FROM UNDER STRUCTURES AND SLABS ON GRADE CUT EXISTING GRADE TO SUBGRADE ELEVATION, FILL WITH EXCAVATED MATERIAL, STABILIZE AND REINFORCE WITH GEO-TEXTILE FILL WITH EXCAVATED MATERIAL ONE FOOT BELOW FINISHED GRADE 1 PARKING AND ELEVATED FIELDS Kimley>» Horn BUILDING I STADIUM ROAD STADIUM AND BUILDING ELEVATED PLAZA BUILDING 2 BUILD I ,4 BUILDING 6 PARK AND ANDSCAPF BUILDING 8 SOUTH PARKING LOT HOTEL AND OFFICES 14TH ST NW 19TH NW 19TH NW 18TH LEGEND: PARK AND LANDSCAPE 20 10 !\\\\ 0 ` CLEAN FILL -5 MIAMI FREEDOM PARK GENERAL GRADING July 22, 2019 EXISTING J GROUND FINISHED GRADE SECTION VERTICAL SCALE EXAGGERATION 1:5 FINISHED GRADE SECTION NO VERTICAL SCALE EXAGGERATION 1 ( SEE DETAIL "A" —J - ---\.ITS Kimley>» Horn 0201E gMLET.DRN AND ASSOCIATES. iNL raw .440111 INFERRED EXTENT OF `• AMMONIA -AFFECTED GROUNDWATER f INFERRED EXTENT OF IRON -AFFECTED GROUNDWATER JL INFERRED EXTENT OF ARSENIC -AFFECTED GROUNDWATER DETAIL "A" MIAMI FREEDOM PARK PROPOSED DRAINAGE INFRASTRUCTURE July 22, 2019 LEGEND: AMMONIA IRON ARSENIC PROPOSED EXFILTRATION TRENCH PROPOSED SOLID PIPE EXISTING 16" WATER MAIN WITH 30" CASING Kimley>» Horn 02019 bMIETHOHH MO ASSOCIATES. PC i EXISTING 24" WATER MAIN PROPOSED 12" WATER MAIN sis--—:rfi06/s�r� NN/ 1ATI-1 CT NW 37TH AVE 9TH TER EXISTING 12" WATER MAIN NW 19TH ST NW 18TH TER NW 18TH ST NW 17TH ST EXISTING 8" WATER MAIN MIAMI FREEDOM PARK PROPOSED WATER INFRASTRUCTURE July 22, 2019 1 w NW 18tH ST 1 1 • I PROPOSED SANITARY SEWER GRAVITY MAIN II NW 17tH ST �I• • \ i• w I PROPOSED SANITARY SEWER GRAVITY MAIN Kimley>» Horn 9D01S MMIEY• 2000 SpO ASSOCIATES. INC. 1 1 PROPOSED PRIVATE SANITARY SEWER - �� r- LIFT STATION PROPOSED PRIVATE SANITARY SEWER LIFT STATION PROPOSED 6" SANITARY SEWER FORCE MAIN IL ifl (NW19THST t PROPOSED 8" SANITARY SEWER FORCE MAIN 4TH ST NW 37TH AVE VW 18TH TER NW 18TH ST IqI NW17TH ST MIAMI FREEDOM PARK PROPOSED SEWER INFRASTRUCTURE July 22, 2019 EXISTING 36" SANITARY SEWER FORCE MAIN Y Kimley>» Horn 02010 A1.1IEY.NO0N AND ASSOCIATES, INC ti I w I I z I NW 181H ST NW 17H ST PROPOSED DUCT BANK --\ zs —s,•r= PROPOSED DUCT BANK II II I II 14TH ST II II 11 II I I MIAMI FREEDOM PARK PROPOSED DRY UTILITIES INFRASTRUCTURE July 22, 2019 w a z II NW 19TH TER NW 19TH ST NW 18TH TER NW 18TH ST f NW 17TH ST Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 April 12, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 27, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry, EE&G Environmental Services. LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 54 ceAnalytical® wwwpacelabs.com CERTIFICATIONS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alaska DEC- CS/UST/LUST Alabama Certification #: 41320 Arizona Certification# AZ0819 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 54 aceAnalytical wwwpacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35456829001 SB-1 (0-0.5) Solid 03/25/19 08:45 03/27/19 17:35 35456829002 SB-1 (5-2') Solid 03/25/19 08:47 03/27/19 17:35 35456829003 SB-1 (2-4') Solid 03/25/19 08:49 03/27/19 17:35 35456829004 SB-1 (3.5-4.5') Solid 03/25/19 08:51 03/27/19 17:35 35456829005 SB-2 (0-0.5') Solid 03/25/19 09:45 03/27/19 17:35 35456829006 SB-2 (0.5-2') Solid 03/25/19 09:47 03/27/19 17:35 35456829007 SB-2 (2-4') Solid 03/25/19 09:49 03/27/19 17:35 35456829008 SB-2 (4-6') Solid 03/25/19 09:51 03/27/19 17:35 35456829009 SB-3 (0-0.5') Solid 03/25/19 10:45 03/27/19 17:35 35456829010 SB-3 (0.5-2') Solid 03/25/19 10:47 03/27/19 17:35 35456829011 SB-3 (2-4') Solid 03/25/19 10:49 03/27/19 17:35 35456829012 SB-4 (0-0.5') Solid 03/25/19 12:00 03/27/19 17:35 35456829013 SB-4 (0.5-2') Solid 03/25/19 12:02 03/27/19 17:35 35456829014 SB-4 (2-4') Solid 03/25/19 12:04 03/27/19 17:35 35456829015 SB-5 (0-0.5") Solid 03/25/19 13:00 03/27/19 17:35 35456829016 SB-5 (0.5-2") Solid 03/25/19 13:02 03/27/19 17:35 5456829017 SB-5 (2-4") Solid 03/25/19 13:04 03/27/19 17:35 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 54 aceAnalytical® wwwpacelabs.com SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Analytes Method Analysts Reported Laboratory 35456829001 SB-1 (0-0.5) EPA6010 SC1 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35456829002 SB-1 (5-2') EPA 6010 JWP 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35456829003 SB-1 (2-4') EPA 6010 SC1 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35456829004 SB-1 (3.5-4.5') EPA 8270 MMG 21 PASI-O ASTM D2974-87 CLT 1 PASI-O 35456829005 SB-2 (0-0.5') EPA 6010 SC1 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35456829006 SB-2 (0.5-2') EPA 6010 SC1 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35456829007 SB-2 (2-4') EPA 6010 JWP 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35456829008 SB-2 (4-6') EPA6010 SC1 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35456829009 SB-3 (0-0.5') EPA 6010 JWP 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35456829010 SB-3 (0.5-2') EPA 6010 SC1 3 PASI-O EPA 8270 MMG 21 PASI-O ASTM D2974-87 CLT 1 PASI-O 35456829011 SB-3 (2-4') EPA 6010 JWP 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35456829012 SB-4 (0-0.5') EPA 6010 JWP 3 PASI-O EPA 6010 JWP 2 PASI-O ASTM D2974-87 CLT 1 PASI-O 35456829013 SB-4 (0.5-2') EPA 6010 SC1 3 PASI-O EPA 8270 MMG 21 PASI-O ASTM D2974-87 CLT 1 PASI-O 35456829014 SB-4 (2-4') EPA 6010 SC1 3 PASI-O EPA 6010 JWP 1 PASI-O ASTM D2974-87 CLT 1 PASI-O 35456829015 SB-5 (0-0.5") EPA 6010 SC1 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35456829016 SB-5 (0.5-2") EPA 6010 SC1 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35456829017 SB-5 (2-4") EPA 6010 SC1 3 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 54 aceAnalytical www.pacelabs.com SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course Pace Project No.. 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory ASTM D2974-87 REPORT OF LABORATORY ANALYSIS CLT 1 PASI-O This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 54 aceAnalytical® www.pacelabs.com SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35456829001 SB-1 (0-0.5) EPA6010 Arsenic 16.9 mg/kg 0.65 04/01/1916:23 EPA6010 Barium 10.8 mg/kg 0.65 04/01/19 16:23 EPA6010 Lead 10.1 mg/kg 0.65 04/01/19 16:23 ASTM D2974-87 Percent Moisture 28.9 % 0.10 04/02/19 14:46 35456829002 SB-1 (5-2') EPA 6010 Arsenic 15.5 mg/kg 0.70 04/02/19 14:46 EPA 6010 Barium 11.4 mg/kg 0.70 04/02/19 14:46 EPA 6010 Lead 27.2 mg/kg 0.70 04/02/19 14:46 ASTM D2974-87 Percent Moisture 15.7 % 0.10 04/02/19 15:30 35456829003 SB-1 (2-4') EPA 6010 Arsenic 6.2 mg/kg 0.67 04/01/19 16:26 EPA6010 Barium 41.5 mg/kg 0.67 04/01/19 16:26 EPA6010 Lead 98.0 mg/kg 0.67 04/01/19 16:26 ASTM D2974-87 Percent Moisture 17.1 % 0.10 04/02/19 15:30 35456829004 SB-1 (3.5-4.5') ASTM D2974-87 Percent Moisture 15.1 % 0.10 04/02/19 15:30 35456829005 SB-2 (0-0.5') EPA6010 Arsenic 17.3 mg/kg 0.61 04/01/1916:29 EPA6010 Barium 9.3 mg/kg 0.61 04/01/19 16:29 EPA6010 Lead 5.8 mg/kg 0.61 04/01/19 16:29 ASTM D2974-87 Percent Moisture 11.5 % 0.10 04/02/19 15:30 35456829006 SB-2 (0.5-2') EPA6010 Arsenic 2.3 mg/kg 0.65 04/01/19 16:32 EPA6010 Barium 5.0 mg/kg 0.65 04/01/1916:32 EPA6010 Lead 3.3 mg/kg 0.65 04/01/19 16:32 ASTM D2974-87 Percent Moisture 9.7 % 0.10 04/02/19 15:30 35456829007 SB-2 (2-4') EPA 6010 Arsenic 0.97 mg/kg 0.51 04/02/19 14:55 EPA 6010 Barium 3.5 mg/kg 0.51 04/02/19 14:55 EPA 6010 Lead 6.5 mg/kg 0.51 04/02/19 14:55 ASTM D2974-87 Percent Moisture 8.5 % 0.10 04/02/19 15:30 35456829008 SB-2 (4-6') EPA6010 Arsenic 4.2 mg/kg 0.62 04/01/19 16:34 EPA6010 Barium 9.6 mg/kg 0.62 04/01/19 16:34 EPA6010 Lead 47.6 mg/kg 0.62 04/01/19 16:34 ASTM D2974-87 Percent Moisture 11.1 % 0.10 04/02/19 15:30 35456829009 SB-3 (0-0.5') EPA 6010 Arsenic 23.0 mg/kg 0.58 04/02/19 14:58 EPA 6010 Barium 6.5 mg/kg 0.58 04/02/19 14:58 EPA 6010 Lead 7.0 mg/kg 0.58 04/02/19 14:58 ASTM D2974-87 Percent Moisture 13.5 % 0.10 04/02/19 15:31 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 54 aceAnalytical® www.pacelabs.com SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35456829010 SB-3 (0.5-2') EPA 6010 Arsenic 6.7 mg/kg 0.69 04/01/19 16:37 EPA6010 Barium 7.8 mg/kg 0.69 04/01/19 16:37 EPA6010 Lead 19.6 mg/kg 0.69 04/01/19 16:37 ASTM D2974-87 Percent Moisture 14.8 % 0.10 04/02/19 15:31 35456829011 SB-3 (2-4') EPA 6010 Arsenic 0.43 I mg/kg 0.62 04/02/19 15:00 EPA 6010 Barium 4.4 mg/kg 0.62 04/02/19 15:00 EPA 6010 Lead 0.66 mg/kg 0.62 04/02/19 15:00 ASTM D2974-87 Percent Moisture 11.1 % 0.10 04/02/19 15:31 35456829012 SB-4 (0-0.5') EPA 6010 Arsenic 156 mg/kg 3.3 04/02/19 15:03 EPA6010 Barium 41.9 mg/kg 3.3 04/02/19 15:03 EPA 6010 Lead 212 mg/kg 3.3 04/02/19 15:03 ASTM D2974-87 Percent Moisture 9.7 % 0.10 04/02/19 15:31 35456829013 SB-4 (0.5-2') EPA6010 Arsenic 12.0 mg/kg 0.62 04/01/19 16:40 EPA6010 Barium 48.9 mg/kg 0.62 04/01/19 16:40 -PA 6010 Lead 145 mg/kg 3.1 04/02/19 11:19 . PA 8270 Benzo(a)anthracene 0.014 1 mg/kg 0.038 03/30/19 06:17 EPA 8270 Benzo(a)pyrene 0.012 1 mg/kg 0.038 03/30/19 06:17 EPA 8270 Benzo(b)fluoranthene 0.020 1 mg/kg 0.038 03/30/19 06:17 EPA 8270 Chrysene 0.013 1 mg/kg 0.038 03/30/19 06:17 EPA 8270 Fluoranthene 0.017 1 mg/kg 0.038 03/30/19 06:17 EPA 8270 Pyrene 0.016 1 mg/kg 0.038 03/30/19 06:17 ASTM D2974-87 Percent Moisture 10.5 % 0.10 04/02/19 15:31 35456829014 SB-4 (2-4') EPA6010 Arsenic 89.4 mg/kg 4.1 04/01/19 16:49 EPA 6010 Barium 527 mg/kg 4.1 04/01/19 16:49 EPA 6010 Lead 2410 mg/kg 82.5 04/02/19 15:09 EPA 6010 Lead 0.29 mg/L 0.10 04/10/19 15:32 ASTM D2974-87 Percent Moisture 28.1 % 0.10 04/02/19 15:31 35456829015 SB-5 (0-0.5") EPA6010 Arsenic 47.8 mg/kg 0.64 04/01/19 16:52 EPA6010 Barium 17.5 mg/kg 0.64 04/01/19 16:52 EPA6010 Lead 62.3 mg/kg 0.64 04/01/19 16:52 ASTM D2974-87 Percent Moisture 8.3 % 0.10 04/02/19 15:32 35456829016 SB-5 (0.5-2") EPA6010 Arsenic 7.0 mg/kg 0.61 04/01/19 16:54 EPA6010 Barium 16.3 mg/kg 0.61 04/01/19 16:54 EPA6010 Lead 29.7 mg/kg 0.61 04/01/19 16:54 ASTM D2974-87 Percent Moisture 7.6 % 0.10 04/02/19 15:32 35456829017 SB-5 (2-4") EPA 6010 Arsenic 24.3 mg/kg 2.9 04/01/19 16:57 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 54 SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35456829017 SB-5(2-4") EPA6010 Barium 59.6 mg/kg 2.9 04/01/19 16:57 EPA6010 Lead 430 mg/kg 2.9 04/01/19 16:57 ASTM D2974-87 Percent Moisture 17.8 % 0.10 04/02/19 15:32 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 54 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-1 (0-0.5) Lab ID: 35456829001 Collected: 03/25/19 08:45 Received: 03/27/19 17:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 16.9 mg/kg 0.65 0.33 1 04/01/19 09:10 04/01/19 16:23 7440-38-2 Barium 10.8 mg/kg 0.65 0.33 1 04/01/19 09:10 04/01/19 16:23 7440-39-3 Lead 10.1 mg/kg 0.65 0.33 1 04/01/19 09:10 04/01/19 16:23 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 28.9 % 0.10 0.10 1 04/02/19 14:46 Date: 04/12/2019 10:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 54 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-1 (5-2') Lab ID: 35456829002 Collected: 03/25/19 08:47 Received: 03/27/19 17:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 15.5 mg/kg 0.70 0.35 1 04/01/19 11:36 04/02/19 14:46 7440-38-2 Barium 11.4 mg/kg 0.70 0.35 1 04/01/19 11:36 04/02/19 14:46 7440-39-3 Lead 27.2 mg/kg 0.70 0.35 1 04/01/1911:36 04/02/19 14:46 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 04/12/2019 10:25 PM 15.7 0.10 0.10 1 04/02/1915:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 54 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-1 (2-4') Lab ID: 35456829003 Collected: 03/25/19 08:49 Received: 03/27/19 17:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 6.2 mg/kg 0.67 0.33 1 04/01/19 09:10 04/01/19 16:26 7440-38-2 Barium 41.5 mg/kg 0.67 0.33 1 04/01/19 09:10 04/01/19 16:26 7440-39-3 Lead 98.0 mg/kg 0.67 0.33 1 04/01/19 09:10 04/01/19 16:26 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 17.1 % 0.10 0.10 1 04/02/19 15:30 Date: 04/12/2019 10:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 54 aceAnayical® wwwpacelabscom ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-1 (3.5-4.5') Lab ID: 35456829004 Collected: 03/25/19 08:51 Received: 03/27/19 17:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8270 MSSV Short List Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546 Acenaphthene Acenaphthylene Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene Chrysene Dibenz(a,h)anthracene Fluoranthene Fluorene Indeno(1,2,3-cd)pyrene 1-Methylnaphthalene 2-Methylnaphthalene Naphthalene Phenanthrene Pyrene Surrogates Nitrobenzene-d5 (S) 2-Fluorobiphenyl (S) p-Terphenyl-d14 (S) Percent Moisture Percent Moisture Date: 04/12/2019 10:25 PM 0.014 0.012 0.014 0.011 0.0098 0.011 0.010 0.011 0.013 0.0091 0.013 0.014 0.0091 0.016 0.015 0.014 0.013 0.013 u u u u u u u u u u u u u u u u u u 55 62 76 mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg 0.042 0.040 0.042 0.040 0.040 0.040 0.040 0.040 0.040 0.040 0.040 0.043 0.040 0.047 0.046 0.041 0.040 0.040 24-98 29-101 29-112 Analytical Method: ASTM D2974-87 0.014 0.012 0.014 0.011 0.0098 0.011 0.010 0.011 0.013 0.0091 0.013 0.014 0.0091 0.016 0.015 0.014 0.013 0.013 15.1 % 0.10 0.10 1 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 03/30/19 02:11 03/30/19 02:11 03/30/19 02:11 03/30/19 02:11 03/30/19 02:11 03/30/19 02:11 03/30/19 02:11 03/30/19 02:11 03/30/19 02:11 03/30/19 02:11 03/30/19 02:11 03/30/19 02:11 03/30/19 02:11 03/30/19 02:11 03/30/19 02:11 03/30/19 02:11 03/30/19 02:11 03/30/19 02:11 83-32-9 208-96-8 120-12-7 56-55-3 50-32-8 205-99-2 191-24-2 207-08-9 218-01-9 53-70-3 206-44-0 86-73-7 193-39-5 90-12-0 91-57-6 91-20-3 85-01-8 129-00-0 03/29/19 07:15 03/30/19 02:11 4165-60-0 03/29/19 07:15 03/30/19 02:11 321-60-8 03/29/19 07:15 03/30/19 02:11 1718-51-0 REPORT OF LABORATORY ANALYSIS 04/02/19 15:30 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 54 ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-2 (0-0.5') Lab ID: 35456829005 Collected: 03/25/19 09:45 Received: 03/27/19 17:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 17.3 mg/kg 0.61 0.31 1 04/01/19 09:10 04/01/19 16:29 7440-38-2 Barium 9.3 mg/kg 0.61 0.31 1 04/01/19 09:10 04/01/19 16:29 7440-39-3 Lead 5.8 mg/kg 0.61 0.31 1 04/01/19 09:10 04/01/19 16:29 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 04/12/2019 10:25 PM 11.5 % 0.10 0.10 1 04/02/1915:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 54 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-2 (0.5-2') Lab ID: 35456829006 Collected: 03/25/19 09:47 Received: 03/27/19 17:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3050 Arsenic 2.3 mg/kg 0.65 0.33 1 04/01/19 09:10 04/01/19 16:32 7440-38-2 Barium 5.0 mg/kg 0.65 0.33 1 04/01/19 09:10 04/01/19 16:32 7440-39-3 Lead 3.3 mg/kg 0.65 0.33 1 04/01/19 09:10 04/01/19 16:32 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 04/12/2019 10:25 PM 9.7 % 0.10 0.10 1 04/02/19 15:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 54 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-2 (2-4') Lab ID: 35456829007 Collected: 03/25/19 09:49 Received 03/27/19 17:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 0.97 mg/kg 0.51 0.26 1 04/01/19 11:36 04/02/19 14:55 7440-38-2 Barium 3.5 mg/kg 0.51 0.26 1 04/01/19 11:36 04/02/19 14:55 7440-39-3 Lead 6.5 mg/kg 0.51 0.26 1 04/01/19 11:36 04/02/19 14:55 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 8.5 % 0.10 0.10 1 04/02/19 15:30 Date: 04/12/2019 10:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 54 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-2 (4-6') Lab ID: 35456829008 Collected: 03/25/19 09:51 Received: 03/27/19 17:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 4.2 mg/kg 0.62 0.31 1 04/01/19 09:10 04/01/19 16:34 7440-38-2 Barium 9.6 mg/kg 0.62 0.31 1 04/01/19 09:10 04/01/19 16:34 7440-39-3 Lead 47.6 mg/kg 0.62 0.31 1 04/01/19 09:10 04/01/19 16:34 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 11.1 % 0.10 0.10 1 04/02/19 15:30 Date: 04/12/2019 10:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 54 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-3 (0-0.5') Lab ID: 35456829009 Collected: 03/25/19 10:45 Received: 03/27/19 17:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 23.0 mg/kg 0.58 0.29 1 04/01/19 11:36 04/02/19 14:58 7440-38-2 Barium 6.5 mg/kg 0.58 0.29 1 04/01/19 11:36 04/02/19 14:58 7440-39-3 Lead 7.0 mg/kg 0.58 0.29 1 04/01/19 11:36 04/02/19 14:58 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 13.5 % 0.10 0.10 1 04/02/19 15:31 Date: 04/12/2019 10:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 54 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-3 (0.5-2') Lab ID: 35456829010 Collected: 03/25/19 10:47 Received: 03/27/19 17:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 6.7 mg/kg 0.69 0.34 1 04/01/19 09:10 04/01/19 16:37 7440-38-2 Barium 7.8 mg/kg 0.69 0.34 1 04/01/19 09:10 04/01/19 16:37 7440-39-3 Lead 19.6 mg/kg 0.69 0.34 1 04/01/19 09:10 04/01/19 16:37 7439-92-1 8270 MSSV Short List Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546 Acenaphthene 0.014 U mg/kg 0.042 0.014 1 03/29/19 07:15 03/30/19 05:52 83-32-9 Acenaphthylene 0.012 U mg/kg 0.039 0.012 1 03/29/19 07:15 03/30/19 05:52 208-96-8 Anthracene 0.014 U mg/kg 0.042 0.014 1 03/29/19 07:15 03/30/19 05:52 120-12-7 Benzo(a)anthracene 0.011 U mg/kg 0.039 0.011 1 03/29/19 07:15 03/30/19 05:52 56-55-3 Benzo(a)pyrene 0.0097 U mg/kg 0.039 0.0097 1 03/29/19 07:15 03/30/19 05:52 50-32-8 Benzo(b)fluoranthene 0.010 U mg/kg 0.039 0.010 1 03/29/19 07:15 03/30/19 05:52 205-99-2 Benzo(g,h,i)perylene 0.0098 U mg/kg 0.039 0.0098 1 03/29/19 07:15 03/30/19 05:52 191-24-2 Benzo(k)fluoranthene 0.010 U mg/kg 0.039 0.010 1 03/29/19 07:15 03/30/19 05:52 207-08-9 Chrysene 0.012 U mg/kg 0.039 0.012 1 03/29/19 07:15 03/30/19 05:52 218-01-9 Dibenz(a.h)anthracene 0.0090 U mg/kg 0.039 0.0090 1 03/29/19 07:15 03/30/19 05:52 53-70-3 Fluoranthene 0.013 U mg/kg 0.039 0.013 1 03/29/19 07:15 03/30/19 05:52 206-44-0 Fluorene 0.014 U mg/kg 0.043 0.014 1 03/29/19 07:15 03/30/19 05:52 86-73-7 Indeno(1,2.3-cd)pyrene 0.0090 U mg/kg 0.039 0.0090 1 03/29/19 07:15 03/30/19 05:52 193-39-5 1-Methylnaphthalene 0.015 U mg/kg 0.046 0.015 1 03/29/19 07:15 03/30/19 05:52 90-12-0 2-Methylnaphthalene 0.015 U mg/kg 0.045 0.015 1 03/29/19 07:15 03/30/19 05:52 91-57-6 Naphthalene 0.013 U mg/kg 0.041 0.013 1 03/29/19 07:15 03/30/19 05:52 91-20-3 Phenanthrene 0.013 U mg/kg 0.039 0.013 1 03/29/19 07:15 03/30/19 05:52 85-01-8 Pyrene 0.012 U mg/kg 0.039 0.012 1 03/29/19 07:15 03/30/19 05:52 129-00-0 Surrogates Nitrobenzene-d5 (S) 69 % 24-98 1 03/29/19 07:15 03/30/19 05:52 4165-60-0 2-Fluorobiphenyl (S) 82 % 29-101 1 03/29/19 07:15 03/30/19 05:52 321-60-8 p-Terphenyl-d14 (S) 88 % 29-112 1 03/29/19 07:15 03/30/19 05:52 1718-51-0 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 14.8 % 0.10 0.10 1 04/02/19 15:31 Date: 04/12/2019 10:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 54 aceAnalytical wwwpacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-3 (2-4') Lab ID: 35456829011 Collected: 03/25/19 10:49 Received: 03/27/19 17:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 0.43 I mg/kg 0.62 0.31 1 04/01/19 11:36 04/02/19 15:00 7440-38-2 Barium 4.4 mg/kg 0.62 0.31 1 04/01/19 11:36 04/02/19 15:00 7440-39-3 Lead 0.66 mg/kg 0.62 0.31 1 04/01/19 11:36 04/02/19 15:00 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 04/12/2019 10:25 PM 11.1 % 0.10 0.10 1 04/02/19 15:31 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 54 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-4 (0-0.5') Lab ID: 35456829012 Collected: 03/25/19 12:00 Received: 03/27/19 17:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 156 mg/kg 3.3 1.6 5 04/01/19 11:36 04/02/19 15:03 7440-38-2 Barium 41.9 mg/kg 3.3 1.6 5 04/01/19 11:36 04/02/19 15:03 7440-39-3 Lead 212 mg/kg 3.3 1.6 5 04/01/19 11:36 04/02/19 15:03 7439-92-1 6010 MET ICP, TCLP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Leachate Method/Date: EPA 1311; 04/08/19 15:46 Initial pH: 5; Final pH: 6 Arsenic 0.071 U mg/L 0.10 0.071 1 04/10/19 07:56 04/10/19 15:20 7440-38-2 Lead 0.046 U mg/L 0.10 0.046 1 04/10/19 07:56 04/10/19 15:20 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 9.7 % 0.10 0.10 1 04/02/19 15:31 Date: 04/12/2019 10:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 54 ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-4 (0.5-2') Lab ID: 35456829013 Collected: 03/25/19 12:02 Received: 03/27/19 17:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic Barium Lead 12.0 48.9 145 mg/kg mg/kg mg/kg 0.62 0.62 3.1 0.31 0.31 1.5 1 04/01/19 09:10 1 04/01/19 09:10 5 04/01/19 09:10 8270 MSSV Short List Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546 Acenaphthene Acenaphthylene Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene Chrysene Dibenz(a, h)anthracene Fluoranthene 'luorene deno(1,2,3-cd)pyrene 1-Methylnaphthalene 2-Methylnaphthalene Naphthalene Phenanthrene Pyrene Surrogates Nitrobenzene-d5 (S) 2-Fluorobiphenyl (S) p-Terphenyl-d14 (S) Percent Moisture Percent Moisture Date: 04/12/2019 10:25 PM 0.013 U 0.012 U 0.013 U 0.014 I 0.012 I 0.020 I 0.0094 U 0.010 U 0.013 I 0.0086 U 0.017 I 0.013 U 0.0086 U 0.015 U 0.014 U 0.013 U 0.012 U 0.016 I 63 73 82 mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg % To To 0.040 0.038 0.040 0.038 0.038 0.038 0.038 0.038 0.038 0.038 0.038 0.041 0.038 0.044 0.043 0.039 0.038 0.038 0.013 0.012 0.013 0.011 0.0093 0.010 0.0094 0.010 0.012 0.0086 0.012 0.013 0.0086 0.015 0.014 0.013 0.012 0.012 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 03/29/19 07:15 04/01/19 16:40 04/01/19 16:40 04/02/19 11:19 03/30/19 06:17 03/30/19 06:17 03/30/19 06:17 03/30/19 06:17 03/30/19 06:17 03/30/19 06:17 03/30/19 06:17 03/30/19 06:17 03/30/19 06:17 03/30/19 06:17 03/30/19 06:17 03/30/19 06:17 03/30/19 06:17 03/30/19 06:17 03/30/19 06:17 03/30/19 06:17 03/30/19 06:17 03/30/19 06:17 7440-38-2 7440-39-3 7439-92-1 83-32-9 208-96-8 120-12-7 56-55-3 50-32-8 205-99-2 191-24-2 207-08-9 218-01-9 53-70-3 206-44-0 86-73-7 193-39-5 90-12-0 91-57-6 91-20-3 85-01-8 129-00-0 24-98 1 03/29/19 07:15 03/30/19 06:17 4165-60-0 29-101 1 03/29/19 07:15 03/30/19 06:17 321-60-8 29-112 1 03/29/19 07:15 03/30/19 06:17 1718-51-0 Analytical Method: ASTM D2974-87 10.5 % 0.10 0.10 1 04/02/19 15:31 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 21 of 54 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-4 (2-4') Lab ID: 35456829014 Collected: 03/25/19 12:04 Received: 03/27/19 17:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3050 Arsenic 89.4 mg/kg 4.1 2.1 5 04/01/19 09:10 04/01/19 16:49 7440-38-2 Barium 527 mg/kg 4.1 2.1 5 04/01/19 09:10 04/01/19 16:49 7440-39-3 Lead 2410 mg/kg 82.5 41.2 100 04/01/19 09:10 04/02/19 15:09 7439-92-1 6010 MET ICP, TCLP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Leachate Method/Date: EPA 1311; 04/08/19 15:46 Initial pH: 5; Final pH: 6 Lead 0.29 mg/L 0.10 0.046 1 04/10/19 07:56 04/10/19 15:32 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 28.1 % 0.10 0.10 1 04/02/19 15:31 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/12/2019 10:25 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 54 ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-5 (0-0.5") Lab ID: 35456829015 Collected: 03/25/19 13:00 Received: 03/27/19 17:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 47.8 mg/kg 0.64 0.32 1 04/01/19 09:10 04/01/19 16:52 7440-38-2 Barium 17.5 mg/kg 0.64 0.32 1 04/01/19 09:10 04/01/19 16:52 7440-39-3 Lead 62.3 mg/kg 0.64 0.32 1 04/01/19 09:10 04/01/19 16:52 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 04/12/2019 10:25 PM 8.3 % 0.10 0.10 1 04/02/19 15:32 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 54 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-5 (0.5-2") Lab ID: 35456829016 Collected: 03/25/19 13:02 Received: 03/27/19 17:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3050 Arsenic 7.0 mg/kg 0.61 0.30 1 04/01/19 09:10 04/01/19 16:54 7440-38-2 Barium 16.3 mg/kg 0.61 0.30 1 04/01/19 09:10 04/01/19 16:54 7440-39-3 Lead 29.7 mg/kg 0.61 0.30 1 04/01/19 09:10 04/01/19 16:54 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 7.6 % 0.10 0.10 1 04/02/19 15:32 Date: 04/12/2019 10:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 24 of 54 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-5 (2-4") Lab ID: 35456829017 Collected: 03/25/19 13:04 Received: 03/27/19 17:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 24.3 mg/kg 2.9 1.5 5 04/01/19 09:10 04/01/19 16:57 7440-38-2 Barium 59.6 mg/kg 2.9 1.5 5 04/01/19 09:10 04/01/19 16:57 7440-39-3 Lead 430 mg/kg 2.9 1.5 5 04/01/19 09:10 04/01/19 16:57 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 17.8 % 0.10 0.10 1 04/02/19 15:32 Date: 04/12/2019 10:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 25 of 54 aceAnalytical® wwwpacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 527410 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 35456829001, 35456829003, 35456829005, 35456829006, 35456829008, 35456829010, 35456829013, 35456829014, 35456829015, 35456829016, 35456829017 METHOD BLANK: 2854349 Matrix: Solid Associated Lab Samples: 35456829001, 35456829003, 35456829005, 35456829006, 35456829008, 35456829010, 35456829013, 35456829014, 35456829015, 35456829016, 35456829017 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic mg/kg 0.29 U 0.59 0.29 04/01/19 16:00 Barium mg/kg 0.29 U 0.59 0.29 04/01/19 16:00 Lead mg/kg 0.29 U 0.59 0.29 04/01/19 16:00 LABORATORY CONTROL SAMPLE: 2854350 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic mg/kg 15.1 14.2 94 80-120 Barium mg/kg 15.1 14.9 99 80-120 Lead mg/kg 15.1 15.1 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2854351 2854352 MS MSD 35456756001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic mg/kg 0.62 11.8 15.7 11.7 14.8 94 90 75-125 24 20 J(R1) Barium mg/kg 7.3 11.8 15.7 18.5 26.2 95 121 75-125 34 20 J(R1) Lead mg/kg 6.0 11.8 15.7 16.2 20.1 87 90 75-125 21 20 J(R1) Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date. 04/12/2019 10:25 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 54 QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 527427 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 35456829002, 35456829007, 35456829009, 35456829011, 35456829012 METHOD BLANK: 2854380 Matrix: Solid Associated Lab Samples: 35456829002, 35456829007, 35456829009, 35456829011, 35456829012 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic mg/kg 0.28 U 0.56 0.28 04/02/19 14:14 Barium mg/kg 0.28 U 0.56 0.28 04/02/19 14:14 Lead mg/kg 0.28 U 0.56 0.28 04/02/19 14:14 LABORATORY CONTROL SAMPLE: 2854381 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic mg/kg 13 11.8 91 80-120 Barium mg/kg 13 12.1 93 80-120 Lead mg/kg 13 12.6 97 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2854382 2854383 MS MSD 35455442001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic mg/kg 51.2 U 2680 2710 2200 2270 81 83 75-125 3 20 Barium mg/kg 110 2680 2710 2550 2610 91 92 75-125 2 20 Lead mg/kg 51.2 U 2680 2710 2450 2510 91 92 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/12/2019 10:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 27 of 54 aceAnalytical www pacefabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 529740 Analysis Method: EPA 6010 QC Batch Method: EPA 3010 Analysis Description: 6010 MET TCLP Associated Lab Samples: 35456829012, 35456829014 METHOD BLANK: 2864758 Matrix: Water Associated Lab Samples: 35456829012, 35456829014 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic mg/L 0.0071 U 0.010 0.0071 04/10/19 15:09 Lead mg/L 0.0046 U 0.010 0.0046 04/10/19 15:09 LABORATORY CONTROL SAMPLE: 2868291 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic mg/L 0.25 0.25 100 80-120 Lead mg/L 0.25 0.25 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2868292 2868293 MS MSD 35456829012 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic mg/L 0.071 U 2.5 2.5 2.5 2.5 97 100 75-125 3 20 Lead mg/L 0.046 U 2.5 2.5 2.5 2.5 99 100 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/12/2019 10:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 28 of 54 (lceAnaI}icaI www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 526933 Analysis Method: EPA 8270 QC Batch Method: EPA 3546 Analysis Description: 8270 Solid MSSV Microwave Short Spike Associated Lab Samples: 35456829004, 35456829010, 35456829013 METHOD BLANK: 2850730 Matrix: Solid Associated Lab Samples: Parameter 35456829004, 35456829010, 35456829013 Blank Reporting Units Result Limit MDL Analyzed Qualifiers 1-Methylnaphthalene mg/kg 0.013 U 0.040 0.013 03/29/19 22:04 2-Methylnaphthalene mg/kg 0.013 U 0.039 0.013 03/29/19 22:04 Acenaphthene mg/kg 0.012 U 0.036 0.012 03/29/19 22:04 Acenaphthylene mg/kg 0.011 U 0.034 0.011 03/29/19 22:04 Anthracene mg/kg 0.012 U 0.036 0.012 03/29/19 22:04 Benzo(a)anthracene mg/kg 0.0098 U 0.034 0.0098 03/29/19 22:04 Benzo(a)pyrene mg/kg 0.0085 U 0.034 0.0085 03/29/19 22:04 Benzo(b)fluoranthene mg/kg 0.0091 U 0.034 0.0091 03/29/19 22:04 Benzo(g,h,i)perylene mg/kg 0.0086 U 0.034 0.0086 03/29/19 22:04 Benzo(k)fluoranthene mg/kg 0.0091 U 0.034 0.0091 03/29/19 22:04 Chrysene mg/kg 0.011 U 0.034 0.011 03/29/19 22:04 Dibenz(a,h)anthracene mg/kg 0.0079 U 0.034 0.0079 03/29/19 22:04 Fluoranthene mg/kg 0.011 U 0.034 0.011 03/29/19 22:04 Fluorene mg/kg 0.012 U 0.037 0.012 03/29/19 22:04 ideno(1,2,3-cd)pyrene mg/kg 0.0078 U 0.034 0.0078 03/29/19 22:04 .'Japhthalene mg/kg 0.012 U 0.035 0.012 03/29/19 22:04 Phenanthrene mg/kg 0.011 U 0.034 0.011 03/29/19 22:04 Pyrene mg/kg 0.011 U 0.034 0.011 03/29/19 22:04 2-Fluorobiphenyl (S) % 57 29-101 03/29/19 22:04 Nitrobenzene-d5 (S) % 57 24-98 03/29/19 22:04 p-Terphenyl-d14 (S) % 72 29-112 03/29/19 22:04 LABORATORY CONTROL SAMPLE: 2850731 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1-Methylnaphthalene mg/kg 1.7 1.0 62 38-115 2-Methylnaphthalene mg/kg 1.7 0.98 59 37-115 Acenaphthene mg/kg 1.7 0.95 57 30-127 Acenaphthylene mg/kg 1.7 1.0 62 29-129 Anthracene mg/kg 1.7 1.1 65 37-126 Benzo(a)anthracene mg/kg 1.7 1.2 74 37-130 Benzo(a)pyrene mg/kg 1.7 1.1 67 39-128 Benzo(b)fluoranthene mg/kg 1.7 1.1 65 38-128 Benzo(g,h,i)perylene mg/kg 1.7 1.1 69 34-136 Benzo(k)fluoranthene mg/kg 1.7 1.0 62 39-133 Chrysene mg/kg 1.7 1.2 75 39-125 Dibenz(a,h)anthracene mg/kg 1.7 1.2 72 37-127 Fluoranthene mg/kg 1.7 1.1 66 39-130 Fluorene mg/kg 1.7 1.0 61 35-125 Indeno(1,2,3-cd)pyrene mg/kg 1.7 1.2 72 35-133 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/12/2019 10:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 29 of 54 aceAnalytical w w..pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE 2850731 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Naphthalene mg/kg 1.7 0.98 59 36-115 Phenanthrene mg/kg 1.7 1.1 65 35-128 Pyrene mg/kg 1.7 1.2 75 37-132 2-Fluorobiphenyl (S) % 57 29-101 Nitrobenzene-d5 (S) % 54 24-98 p-Terphenyl-d14 (S) % 71 29-112 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2850732 2850733 MS MSD 35456828002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1-Methylnaphthalene mg/kg 0.013 U 1.7 1.6 1.0 1.3 59 76 38-115 25 40 2-Methylnaphthalene mg/kg 0.013 U 1.7 1.6 0.95 1.2 56 74 37-115 27 40 Acenaphthene mg/kg 0.012 U 1.7 1.6 0.95 1.2 55 73 30-127 27 40 Acenaphthylene mg/kg 0.011 U 1.7 1.6 1.0 1.3 60 80 29-129 27 40 Anthracene mg/kg 0.012 U 1.7 1.6 1.1 1.4 62 82 37-126 27 40 Benzo(a)anthracene mg/kg 0.034 I 1.7 1.6 1.2 1.6 71 95 37-130 27 40 Benzo(a)pyrene mg/kg 0.039 1.7 1.6 1.1 1.5 63 85 39-128 28 40 Benzo(b)fluoranthene mg/kg 0.071 1.7 1.6 1.1 1.4 61 81 38-128 25 40 Benzo(g,h,i)perylene mg/kg 0.029 I 1.7 1.6 1.1 1.5 65 85 34-136 25 40 Benzo(k)fluoranthene mg/kg 0.024 I 1.7 1.6 1.0 1.4 60 81 39-133 29 40 Chrysene mg/kg 0.049 1.7 1.6 1.3 1.7 73 97 39-125 26 40 Dibenz(a,h)anthracene mg/kg 0.0082 I 1.7 1.6 1.2 1.6 68 93 37-127 30 40 Fluoranthene mg/kg 0.075 1.7 1.6 1.2 1.5 64 82 39-130 22 40 Fluorene mg/kg 0.012 U 1.7 1.6 1.0 1.3 59 79 35-125 28 40 Indeno(1,2,3-cd)pyrene mg/kg 0.025 I 1.7 1.6 1.2 1.6 69 92 35-133 26 40 Naphthalene mg/kg 0.012 U 1.7 1.6 0.96 1.2 56 73 36-115 25 40 Phenanthrene mg/kg 0.026 I 1.7 1.6 1.1 1.4 63 84 35-128 27 40 Pyrene mg/kg 0.072 1.7 1.6 1.3 1.7 72 96 37-132 26 40 2-Fluorobiphenyl (S) % 55 75 29-101 Nitrobenzene-d5 (S) % 51 66 24-98 p-Terphenyl-d14 (S) % 69 91 29-112 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/12/2019 10:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 30 of 54 aceAnalytical ® wwwpacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 527841 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 35456829001 SAMPLE DUPLICATE: 2856657 35455415157 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture 5.2 4.5 14 10 J(D6) SAMPLE DUPLICATE: 2856658 35455415167 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture 7.4 7.0 6 10 SAMPLE DUPLICATE: 2856659 35456781003 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture 2.9 2.4 21 10 J(D6) SAMPLE DUPLICATE: 2856660 35456781012 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture 5.9 4.8 22 10 J(D6) Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/12/2019 10:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 31 of 54 www pacelabs. com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 527872 QC Batch Method: ASTM D2974-87 Associated Lab Samples: Analysis Method: Analysis Description: 35456829002, 35456829003, 35456829004, 35456829005, 35456829009,35456829010,35456829011,35456829012, 35456829016,35456829017 ASTM D2974-87 Dry Weight/Percent Moisture 35456829006, 35456829007, 35456829008, 35456829013, 35456829014, 35456829015, SAMPLE DUPLICATE: 2856876 Parameter Units 35456829002 Result Dup Result RPD Max RPD Qualifiers Percent Moisture % 15.7 14.6 7 10 SAMPLE DUPLICATE: 2856877 Parameter Units 35456829012 Result Dup Result RPD Max RPD Qualifiers Percent Moisture 9.7 8.9 9 10 SAMPLE DUPLICATE: 2856878 Parameter Units 35456829017 Result Dup Result RPD Max RPD Qualifiers Percent Moisture % 17.8 19.4 9 10 SAMPLE DUPLICATE: 2856879 Parameter Units 35457022004 Result Dup Result RPD Max RPD Qualifiers Percent Moisture % 7.1 7.0 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/12/2019 10:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 32 of 54 ceAnalytical® www.pacelaabs.com QUALIFIERS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL- Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. U Compound was analyzed for but not detected. J(D6) Estimated Value. The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. J(R1) Estimated Value. RPD value was outside control limits. Date: 04/12/2019 10:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 33 of 54 aceAnalytical® www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456829 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach. FL 33064 954-582-4300 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 35456829001 SB-1 (0-0.5) EPA 3050 527410 EPA 6010 527516 35456829002 SB-1 (5-2') EPA 3050 527427 EPA 6010 527590 35456829003 SB-1 (2-4') EPA 3050 527410 EPA 6010 527516 35456829005 SB-2 (0-0.5') EPA 3050 527410 EPA 6010 527516 35456829006 SB-2 (0.5-2') EPA 3050 527410 EPA 6010 527516 35456829007 SB-2 (2-4') EPA 3050 527427 EPA 6010 527590 35456829008 SB-2 (4-6') EPA 3050 527410 EPA 6010 527516 35456829009 SB-3 (0-0.5') EPA 3050 527427 EPA 6010 527590 35456829010 SB-3 (0.5-2') EPA 3050 527410 EPA 6010 527516 35456829011 SB-3 (2-4') EPA 3050 527427 EPA 6010 527590 35456829012 SB-4 (0-0.5') EPA 3050 527427 EPA 6010 527590 35456829013 SB-4 (0.5-2') EPA 3050 527410 EPA 6010 527516 35456829014 SB-4 (2-4') EPA 3050 527410 EPA 6010 527516 35456829015 SB-5 (0-0.5") EPA 3050 527410 EPA 6010 527516 35456829016 SB-5 (0.5-2") EPA 3050 527410 EPA 6010 527516 35456829017 SB-5 (2-4") EPA 3050 527410 EPA 6010 527516 35456829012 SB-4 (0-0.5') EPA 3010 529740 EPA 6010 529907 35456829014 SB-4 (2-4') EPA 3010 529740 EPA 6010 529907 35456829004 SB-1 (3.5-4.5') EPA 3546 526933 EPA 8270 527121 35456829010 SB-3 (0.5-2') EPA 3546 526933 EPA 8270 527121 35456829013 SB-4 (0.5-2') EPA 3546 526933 EPA 8270 527121 35456829001 SB-1 (0-0.5) ASTM D2974-87 527841 35456829002 SB-1 (5-2') ASTM D2974-87 527872 35456829003 SB-1 (2-4') ASTM D2974-87 527872 35456829004 SB-1 (3.5-4.5') ASTM D2974-87 527872 35456829005 SB-2 (0-0.5') ASTM D2974-87 527872 35456829006 SB-2 (0.5-2') ASTM D2974-87 527872 35456829007 SB-2 (2-4') ASTM D2974-87 527872 35456829008 SB-2 (4-6') ASTM D2974-87 527872 35456829009 SB-3 (0-0.5') ASTM D2974-87 527872 35456829010 SB-3 (0.5-2') ASTM D2974-87 527872 35456829011 SB-3 (2-4') ASTM 02974-87 527872 35456829012 SB-4 (0-0.5') ASTM D2974-87 527872 35456829013 SB-4 (0.5-2') ASTM D2974-87 527872 35456829014 SB-4 (2-4') ASTM D2974-87 527872 35456829015 SB-5 (0-0.5") ASTM D2974-87 527872 35456829016 SB-5 (0.5-2") ASTM D2974-87 527872 35456829017 SB-5 (2-4") ASTM D2974-87 527872 Date: 04/12/2019 10:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 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Lead 6010 Sampler .// - / Signaturg>� Circle One Event: Daily Weekly Monthly Quartely Semi -Annual Annual N/A Cr) t- -�� 6;C..- Preservative Type Codes i�{� A. None E. HCL I. Ice D. HNO3 F. McOH J. MCAA C. H2SO4 G. Na2S203 K znAcetate D. NaOH H. NaHSOa O. Other Sample # Sample ID Collect Date Collect Time Matrix Code d n (L il -2-' >_ _ p xor I o $ O 1 .J t� k"' 1�� t X 1 Vo �( ` ' # of Containers Size/Typo 1 Its IzP REMARKS iSn_j(°_c5) 3j,.�%6 f 5L; i 1 I I I 1 I 11 LI 1 1 1 1 1 1 2S-1(&. 5- t. 05117 qEir 1 1 1 1 Li 1 1 11 1 1 1 1 ❑ 3 5 3 ( -`!'r) eka4Y 1 I I 1 1 Li ❑ I I 1 I I-1 ❑ 4S -i 3'5-4-5) 035k 1 ❑ 1 1 1 1 1 1 1-1 1 1 1 1 5 5S -,2 (c - O 5) 0945 R RI 1L1 ❑ 11 11 LJ 1 I 1.---1 ❑ 6SE .5-.> eici 7 1 154❑ 7 1 I 1 1 1 1 ❑ 11 1 1 7 -I 614/ li 0 I I IN ❑ I I 1 1 I I 11 1 1 8 SB -2 (4 -5"' 6`1 ( 1K 11 L 1 1 1 I-1 I I ❑ Li 1 9 S8 3 (G— 0. 5) Jbl5 \,.( I I' 1 1 ❑ 1 1 11 1 1 1 1 1 1 Li10 5- 3 �� 5 `` /t 3 W n 1 1 El 1 7 11 cIM• TAT. REQUEST,Ru. f •e• Approval/I) Rears Short Hold Circle QA/QC Report Level EDD (Fees May Apply) COC Condition Required State Codificationy Coolers #'s - Temp °C N Toil. iy Su 2D 3D 10 - V__ N 1 2 3 4 CLP AFCEE OAPP Other ADuPT SEDD ERPIMS TSV CSV Other OK Incumrit'I° FL GA SC NC NJ PA LA TX IL 1 2 3 4 5 Item Rel' ishe by () Affiliation Date Time Received b ' tion Date _ Time wkt� , a� off 5� [ q ;Le,i6 �~ i� -\ / , - / I N n Cwda I:i,i L. r J7 Saenphta INTACT upon roam'? Proper Pro::urv.n vu: Indicated? -_ _ _ __ Retuned within hoWln811n u? Custody seals Intact? _ Volumes rued without hondrpnce? _ _ _ _ _ Proper Container; Used/ -- — ---- i. _ : --/ // \ �J /2-0 1 �%'-- c -js\?;7 . - / ; / ' " //� / 7�,- / -1 4 /�i�j-/��rI .Z .' Pmmnann 1 ah Qc.4_451.3_A f1A Revision: I- ALL•C•007- Kev.OU C.O.C. Serial# 145260 � WU# a J541;16829ContalnerType...odes �+ 1 AV Amboy Vial ES 6,cum Sampler o, O CV Clear Vial PPV Prepresurvetl vLnl Plastic PLC Plastic container M AL AIOOILIler PLJ PlanikJor CL Clear Liter Z 21ploc bag a) AP Amber Plastic re 'Indira hag CD AG Amber Glass WP Whirl pak C SJ Soil Jar G Gallen Jug Other TC Terra -core /411v�l'"QcL 11L(Jtical'' �u'� Date: 03/29/19 PM : CTRP www.pacelabs.com L CLIENT: 36—EEG _ Page!r off PPV Prupr000rvod vial Songs). 2oz.4os. Las, thus, 32us or 11_ ulhur e0ml s .4 25om1 12Sm1 -- Example: bzP.b:Plastic, 6ozsJ=eozSoil Jar CompanyName: E- Po# LAB ANALYSIS Address: ') 751 6: .,. (_a;S..e'S Y-. Sample I ` / _' ^ r City: ^'l.t e. , t—di. F� State: � Zip: 3 63I LA; TRC Matrix Codes Attn: 1 u, � IFI,... ,.. FI ` h( D�.� es— r pH Sokol Waste OL Oil GW Ground Wafer SL see,e EFF Effluent SO Soil Sediment AFW Analylo Frets H2U AO Aqueous W W Waste Water NA Nonnquonus OW Onnkmg Wain, PE Petroleum SW Surface Water 0 Othor /^/ l email: J'I'1t�Lys r zie t, c •cc P one: .> 3� --3CCi 11i...JJJ . Pros Codes Projec/rr^^/111 �l (( cam- Name J„'' ( Parameters _ EXAMPLE Diss. Lead 6010 ML Misc. Liquid a,.w ww'M) Samp er /% Signatuurr�/ „�_„ Circle One Event: Daily Weekly Monthly Quaartely Semi -Annual Annual N/A �C5 t7 1, �, =�6X� to Preservative Type Codes A. None E. HCL I. Ice B. HNO3 F. McOH J. MCAA C. H2SO4 G. Na2S2O3 K. Zn Acetate D. NaOH H. NaHSO4 O. Other st CU n Sample ID Collect Date Collect Time Matrix Code' v - 2 L a az `0,)2 2 p 1 a c i-. 3 t r ,.,_Jy� (' `i ` ii, E co of Containers IIII # szelType18ozP REMARKS 1 ---3 (,t-4) 43510/ 9 ) 7 11 a I l I I 11 I I l I n z 5,—I/0-0 -6 1,2e j ,, cg' 1 I I I 11 a I I 1 1 I I ❑ ❑ 3 58-4 o .5 ; \ A23' 1 J>a ■ 1 1 ■ 1 I ■ n 4 t,—z! z—/() 1 f n I I I I 1 I u• n■ 5 Z-5(0-6.5) jzo + I I❑ I I n I I ❑ ❑ u u 6 air-5 o .5-`) e.3c � I I u I I l 1 l l n 7 5. -.5 ...2.-) 4 lr;q 4 (, F7 n u 1 1 I I 1 I n❑ I I I I I I u u u ul NII I Li8 9 11 11 n II ❑ ❑ n MI❑ 11 10 II II II II ❑ II n ❑ 11 C RR TAT. RRgy60T{RMR.R. AAtWW ,d NFPw.di Rues Short Hold Circle QA/QC Report Level EDD (Fees May Apply) COC Condition Required Slate Certlrication Coolers #'s - Temp "C N Today ID 20 3D 4D 60 - Y N_ 1 2 3 4 CLP AFCEE QAPP Other_- ADOPT SEDO ERPIMS TSV CSV Other D" "'n°""''""' FL GA SC NC NJ PA LA TX IL 1 2 3 4 5 Item Reit ish d w Affiliation Time Received by A iation Pate , Time /Da) Received on Wet Ice? _ Proper Proaurvmwus Indicated? Received within holdingamo7 __, Custody seals Intact? Proper Co aalnorablos Ned ls Used hout ndsPnco7 -- _. ' .-I { r `[ ') 1 ).;, K % - ` / ` /�y 1 _ 3 � '7 �—'� /'?( / % r ? / / 4 / 171--._..__ I _L see ctn." a.-enet evision: F•ALL•C•007- Rev.00 C.O.C. Serial # 14 5 2 61 Project # Project Manager: Client: PM: CTR CLIENT: 36-EEG Cooler #1 Temp.'C7 ' (Visual) O# : 35456329 Owe Date: 03/29/19 (BUR) Time 12j.I" '. (Correction Factor) (Actual) Cooler #2 Ternp.`C 2 (5 (Visual) D- -a Cooler#3 Temp..0 Cooler #4 Temp..0 Cooler #5 Temp.`C Cooler #6 Temp.'C (Visual) (Visual) (Visual) (Visual) (Correction Factor) Z/r (Actual) (Correction Factor) (Actual) (Correction Factor) (Actual) (Correction Factor) (Actual) (Correction Factor) (Actual) Courier: -- Fed Ex — UPS USPS — Chem Shipping Method: ght Prtnnty Overnight Other Billing: Rec.p ent Tracking # Sender — Commercial L Pace Standar 7 0,te itt ;'ound Th.,d Cre r.. Date and Initials of person: Examining contents: Label: Deliver: pH: _ Otner Intemationa1Prionly Unknown Custody Seal on Cooler/Box Present: 'yes lido Packing Material: __Buoble'.'+rap _ Bubble Bags ,_None Samples shorted to lab (If Yes. complete) Shorted Date Seals intact: — Yes _ c Ice'ej/' Blue Dry ‘J6ne __Other Comments: Oty Chain of Custody Present -4es No N A Chain of Custody Fitted Out /Yes No N N Relinquished Signature & Sampler Name COC es - No N Samples Arrived within Hold Time -' s _ No N 1 Rush TAT requested on COC Yes -.4 o -N A Sufficient Volume --Yes No N A Correct Containers Used / es No N 1. Containers Intact ,Yes No N A -..._,. _ r - e e-e ... n c ce • _c . ._ ... _ r,.. za! _ Yes Yes No ..A e / No /N :A = ... ... . mow._ Headspace in VOA Vials'? i >Smini Yes No ,K.A Trip Blank Preset,:// : Yes No ..�f� A Client Notification/ Resolution: Comments/ Resolution (use back for additional comments): Date Tiote otec: t.ianager Rev!e:•. Page 37 of 54 ace Analytical i www.pacelabs.com www.pacelabs.com Report Prepared for: Christina Raschke PASI Florida 8 East Tower Circle Ormond Beach FL 32174 REPORT OF LABORATORY ANALYSIS FOR PCDD/PCDF Report Prepared Date: April 12, 2019 Report No 10468837_8290FC_DFR Pace Analytical Services, LLC. 1700 Elm Street Minneapolis, MN 55414 Phone: 612.607.1700 Fax: 612.607.6444 Report Information: Pace Project #: 10468837 Sample Receipt Date: 03/29/2019 Client Project #: 35456829 Client Sub PO #: N/A State Cert #: E87605 Invoicing & Reporting Options: The report provided has been invoiced as a Level 2 PCDD/PCDF Report. If an upgrade of this report package is requested, an additional charge may be applied. Please review the attached invoice for accuracy and forward any questions to Nathan Boberg, your Pace Project Manager. This report has been reviewed by: April 12, 2019 Nathan Boberg, Project Manager 612-360-0728 (612) 607-6444 (fax) nathan.boberg@pacelabs.com Report of Laboratory Analysis Thisreportshouldnotbereproduced,exceptinfull, withoutthewrittenconsentofPaceAnalyticalServices,Inc. Theresultsrelateonlytothesamplesincludedinthisreport. Page 38 of 54 Page 1 of 17 aceAnalytical DISCUSSION Pace Analytical Services, LLC. 1700 Elm Street Minneapolis, MN 55414 Phone: 612.607.1700 Fax: 612.607.6444 This report presents the results from the analyses performed on three samples submitted by a representative of Pace Analytical Services, LLC. The samples were analyzed for the presence or absence of polychlorodibenzo-p-dioxins (PCDDs) and polychlorodibenzofurans (PCDFs) using a modified version of USEPA Method 8290. The reporting limits were based on signal-to-noise measurements. Estimated Maximum Possible Concentration (EMPC) values were treated as positives in the toxic equivalence calculations. Per request, estimated detection limit (EDL) values were provided and flagged "U" where the target analytes were not detected. Second column confirmation analyses of 2,3,7,8-TCDF values obtained from the primary (DB5-MS) column are performed only when specifically requested for a project and only when the values are above the concentration of the lowest calibration standard. Typical resolution for this isomer using the DB5-MS column ranges from 25-30%. The recoveries of the isotopically -labeled PCDD/PCDF internal standards in the sample extracts ranged from 45-88%. All of the labeled internal standard recoveries obtained for this project were within the 40-135% target range specified in Method 8290. Also, since the quantification of the native 2,3,7,8-substituted congeners was based on isotope dilution, the data were automatically corrected for recovery and accurate values were obtained. Values were flagged "I" where incorrect isotope ratios were obtained. Concentrations below the calibration range were flagged "J" and should be regarded as estimates. Concentrations above the calibration range were flagged "E" and should also be regarded as estimates. A laboratory method blank was prepared and analyzed with the sample batch as part of our routine quality control procedures. The results show the blank to contain trace levels of selected congeners. These levels were below the calibration range of the method. Sample levels similar to the corresponding blank level were flagged "B" on the results tables and may be, at least partially, attributed to the background. It should be noted that levels less than ten times the background are not generally considered to be statistically different from the background. A laboratory spike sample was also prepared with the sample batch using reference material that had been fortified with native standards. The recoveries of the spiked native compounds ranged from 99-123%. These results were within the target ranges for the method. Matrix spikes were prepared with the sample batch using sample material from a separate project; results from these analyses will be provided upon request. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10468837_8290FC_DFR Page 39 of 54 Page 2 of 17 Authority TM Minnesota Laboratory Certifications Certificate # Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax:612-607-6444 Authority Certificate # A2LA 2926.01 Alabama 40770 Alaska - DW MN00064 Alaska - UST 17-009 Arizona AZ0014 Arkansas - DW MN00064 Arkansas - WW 88-0680 CNMI Saipan MP0003 California 2929 Colorado MN00064 Connecticut PH-0256 EPA Region 8+ via MN 027-053 Florida (NELAP E87605 Georgia 959 Guam 17-001r Hawaii MN00064 Idaho MN00064 Illinois 200011 Indiana C-MN-01 Iowa 368 Kansas E-10167 Kentucky - DW 90062 Kentucky - WW 90062 Louisiana - DE 03086 Louisiana - DW MN00064 Maine MN00064 Maryland 322 Massachusetts M-MN064 Michigan 9909 Minnesota 027-053-137 Minnesota - De via MN 027-053 Minnesota - Pet 1240 Mississippi MN00064 Missouri - DW 10100 Montana CERT0092 Nebraska NE-OS-18-06 Nevada MN00064 New Hampshire 2081 New Jersey (NE MN002 New York 11647 North Carolina 27700 North Carolina - 27700 North Carolina - 530 North Dakota R-036 Ohio - DW 41244 Ohio - VAP CL101 Oklahoma 9507 Oregon - Primar MN300001 Oregon - Secon MN200001 Pennsylvania 68-00563 Puerto Rico MN00064 South Carolina 74003 South Dakota NA Tennessee TN02818 Texas T104704192 Utah (NELAP) MN00064 Virginia 460163 Washington C486 West Virginia - 382 West Virginia - 9952C Wisconsin 999407970 Wyoming - UST 2926.01 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10468837_8290FC_DFR Report No 10468837 Page 40 of 54 Page 3 of 17 Appendix A Sample Management Report No 10468837_8290FC_e Analytical Services, Inc. Page 41 of 54 Page 4 of 17 2lda OdO6Z8 LC889170 L oN lode i v (0 (D —h Chain of Custody {I Samples were sent directly to the Subcontracting Laboratory. Workorder: 35456829 Workorder Name: Melreese Golf Course 2018-3057 State Of Origin: FL Cert. Needed: I I Yes r1 No ceAnalyt ca/ =aace�a4� Owner Received Date: 3/25/2019 Results Requested By: 3/29/2019 Christina Raschke Pace Analytical South Florida 3610 Park Central Blvd N Pompano Beach, FL 33064 Phone (954)582-4300 Pace Analytical Minnesota 1700 Elm Street SE Suite 200 Minneapolis, MN 55414 Phone (612)607-1700 SB-1 (3.5-4.5) S15-3 (0.5-2') SB-4 (0.5-2') PS PS 3/25/2019 08:51 3/25/2019 10:47 3/25/2019 12:02 35456829010 35456829013 Solid Solid :.y WO#:10468837 8290 Dioxin & Furans ■■©.■■■■■■■■■■ ■■■■■■■■■■■■■■ . 1 a;aftc �'h'�tW�1'M1t'ev�~+�4�4 h.. 7V.%:9.R.W hY M1 ...„i?_... LAB USE ONLY UJ( Transfers Released By Date/Time 'eceived By Date/Time 2 3 _ Cooler Tem.erature on Recei .t mem Custod Seal Y or 003 MMITEMIEL Y ,or N —*In order to maintain client confidentiality, location/name of the sampling site, ampler's name and signature may not be provided on this COC document. cra This chain of custody is considered complete as is since this information is available in the owner laboratory. ^' Wednesday, March 27, 2019 6:56:55 PM 0 CP FMT-ALL-C-002rev.00 24March2009 Page 1 of 1 «; 3 `i =PaceAnaIj4iCai Document Name: Sample Condition Upon Receipt Form Document Revised: O6Feb2019 Page 1 of 1 Document No.: F-MN-L-213-rev.25 Issuing Authority: Pace Minnesota Quality Office Sample Condition Upon Receipt Courier: Client Name: /, , ptL 6 I Project #: [Fed Ex ❑UPS ❑LISPS ❑Client ['Pace // ❑SpeeDee gci_mynercial see Exception Tracking Number: (.4 G 1 7( 3L Gl 6 WO#:10468837 PM. NB3 Due Date' 04/12/19 CLIENT: PRSI-FL Custody Seal on Cooler/Box Present? Aces ❑No Seals Intact? fires ❑No Packing Material: ❑Bubble Wrap elaubble Bags ❑None ZQther: ! [7 Thermometer: 0 G87A9155100842 2-487A9170600254 Type dice: Wet ❑Blue Note: Each West Virginia Sample must have temp taken (no temp blanks) Biological Tissue Frozen? ❑Yes ZI1Vo ❑N/A Temp Blank? EYes ENO ENone ❑Dry ❑Melted Temp should be above freezing to 6°C Cooler Temp Read w/temp blank: Correction Factor: Cooler Temp Corrected w/temp blank oc oC USDA Regulated So ❑ Did samples originate ID, LA. MS, NC, NM, Average Corrected Temp See crone (no tempbl3 k only): Soil: ( N/A, water sample/Other: ) Date/Initials of Person Examining Contents: / 3%Z� +✓l( in a quarantine zone within the United States: L, AR, CA, FL, GA, Did samples originate from a foreign source (Internationally, Including NY, OK, OR, SC, TN, TX or VA (check maps)? Yes ❑No Hawaii and Puerto Rico)? ❑Yes EffNo If Yes to either question, fill out a Regulated Soil Checklist (F-MN-Q-338) and include with SCUR/COC paperwork. COMMENTS: Chain of Custody Present and Filled Out? i; s No 1. Chain of Custody Relinquished? te -s ❑No 2. Sampler Name and/or Signature on COC? ❑Yes ❑No [ej1C/A 3. Samples Arrived within Hold Time? ,i .Yes ❑No 4. Short Hold Time Analysis (<72 hr)? :yes 48.No 5. ❑FecalColiform ❑HPC ❑Total Coliform/E coli ❑BOD/cBOD ❑Hex Chrome ❑Turbidity ❑Nitrate [Nitrite ❑Orthophos pother Rush Turn Around Time Requested? $tes ❑No 6. Sufficient Volume? Ives DNo 7. Correct Containers Used? -Pace Containers Used? fAres iYes ❑No ❑No 8. Containers intact? inYes ❑No 9. Field Filtered Volume Received for Dissolved Tests? DYes ❑No ON/A 10. Is sediment visible in the dissolved container? ❑Yes 11No Is sufficient information available to reconcile the samples to the COC? Matrix: ❑Water 23Soil DOH ❑Other &as ❑No 11. If no, write ID/ Date/Time On Container Below: See Exception ❑ All -containers needing acid/base preservation have been checked? Ali containers needing preservation are found to be in compliance with EPA recommendation? (HNO3, H2SO4, <2pH, NaOH>9 Sulfide, NaO11>12 Cyanide) Exceptions: VOA, Coliform, TOC/DOC Oil and Grease, DRO/8015 (water) and Dioxin/PFAS Des Dyes ❑Yes ❑No ❑No ❑No (N/A :A.N/A ZI/A 12. Sample # II NaOH ❑ HNO3 0H25O4 IN Zinc Acetate Positive for Res. Des See Exception Chlorine? Ohio 0 Headspace in VOA Vials (greater than 6mm)? ❑Yes ❑No EN/A 13. See Exception Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes ❑yes QNo ❑No &/A tgIN/A 14. Pace Trip Blank Lot if (if purchased): CLIENT NOTIFICATION/RESOLUTION Person Contacted: Comments/Resolution: Date/Time: Field Data Required? ❑Yes ❑No Project Manager Review: Date: 4/1/19 Note: Whenever there is a discrepancy affecting North Carolina compiiance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( i.e out of noia, incorrect preservative, out of temp, incorrect containers). Labeled by: Report No 104688378290FC_DFR Page 43 of 54 Page 6 of 17 Document Name: j Document Revised: 04Fe h2019 . ".CeAria/yica/ l SCUR Exception Form — Coolers Above 6°C i Page 1 of 1 Document No.: issuing Authority: F-MN-C-298-Rev.01 I Pace Minnesota Quality Office SUM Exceptions: During sample Triage, this form is to be placid in each cooler that arrives above 6.0 degrees Celsius Workorder#e Other Issues %ssue Type: -, SaMple. fD j Gf afro. v of i Type, Contaiiriers. J If yes, indicate who was contacted/date/time. if no, indicate reason why. Read Temp 03 3 Average Temp V-S. O.Z. G- i Trading, ibi tall' /el Gl tment Lag • kr Preserved ec Samoie5 pH I ! Amount , ct Upon • mate Time Added - . r-eserti.eceip �.t;;u i c s'cec ..aec t .iie n•:e a'ftei addition? ..::dais L. Yes •_ i‘lc Report No 104688378290FCDFR Page 44 of 54 Page 7 of 17 NSF PaceAnalytica Document Name: Regulated Soil Checklist Document Revised: 13Feb2018 Page 1 of 2 Document No.: F-MN-Q-338-Rev.06 Issuing Authority: Pace Minnesota Quality Office USDA REGULATED SOIL CHECKLIST To Be Completed by SR Staff: WO: I tLI G V1( 17 Sample Origin (circle one): DOMESTIC Date: Initials: CM QUARANTINED FOREIGN (Note: soil samples from Hawaii, Guam, Puerto Rico and the US Virgin Islands are considered to be of a Foreign Source) If Domestic, circle State of Origin: AL AR CA FL GA LA MS NC NM NY OK OR SC TN TX VA (Includes: IFA, SOD, Golden Nematode, Karnal Bunt and Witchweed) List County: (USDA Permit/Compliance Agreement authorizes movement of samples from these domestic regulated zones) If Quarantined, circle State of Origin: t ID TX CA List County: ✓\ ' Da (Includes Fruit Fly, Giant African Snail and Pale Cyst Nematode) (Movement is not authorized for Pale Cyst Nematode (iD or Giant African Snail (FLJ, remaining quarantines require additional paperwork) if Foreign, list Country of Origin: (Movement from some Canadian Providences is not allowed. Refer to CS-232 Regulated Soil Flow Chart) REQUIREMENT PPQ-530 Paperwork must be included for any samples from counties with a Fruit Fly Quarantine in TX. Refer to MN-S063 through MN-S065 Samples from ID may not be moved from the quarantined region. Refer to MN-S055 Samples from Giant African Snail Quarantine in FL may not be moved from the quarantined region. Refer to MN-5068 ACTION Scan PPQ 530 to the corresponding Project folder on the x drive. If PPQ-530 is not present, contact the Waste Coordinator and do not continue processing samples. COMPLETED YES NO N/A If samples originated in a quarantined zone, contact the Waste Coordinator and do not continue processing samples. If samples originated in a quarantined zone, contact the Waste Coordinator and do not continue processing samples. YES NO /A YES NO N/A REQUIREMENT "Special Handling" stickers are to be placed on all samples. Samples must be segregated and stored in designated bins, shelves and coolers, ACTION Did "special handling" stickers get placed on all sample containers? COMPLETED YE5 NO Were samples placed in a designated cooler, containers and shelves? YES NO Samples must be double contained to prevent accidental release. Equipment and supplies that have come into contact samples must be decontaminated. Were there any signs of breakage or leakage (check for broken glass and/or loose soil in the cooler)? If NO, ice and melt water can be disposed of by normal process (dow if YES, were ice and melt water separated from the cooler and disposed of properly? YES NO the drain). YES NO N/A Any broken glass and/or loose soil are to be bagged and placed in a USDA Regulated satellite container or active drum (see Waste Coordinator). ice and melt water should be baked at a temperature range of 121-154'F for 2 hours and then cooled before going down the drain. Was the cooler(s) and/or countertop(s) decontaminated using either a fresh 10% bleach solution or 70% ethanol? (Gloves and other lob supplies will be bagged and placed in the USDA Regulated satellite container or active drum). NO Comments: Report No 10468837_8290FCDFR Page 45 of 54 Page 8 of 17 .- aceAnalyticai Document Name: Regulated Soil Checklist Document Revised: 13Feb2O18 Page 2 of 2 Document No.: F-MN-Q-338-Rev.06 Issuing Authority: Pace Minnesota Quality Office To Re Completed by PM and/or PC: Sample Analysis to be conducted (circle all that apply): Name of Subcontract Lab (s): MN Subcontract Lab REQUIREMENT ACTION COMPLETED Permission to ship untreated soil must be on file prior to shipping to any subcontract lab, including IR Pace Labs. Go to: J:\SHARE\PRJ_MGR\10_Client Services Department Documents\Regulated Soils Permits— if permission to ship letter is not there, contact the Waste Coordinator. YES NO N/A Shipment must include a valid copy of the receiving lab's permit as well as permission to ship letter. is a copy of all needed paperwork included with the COC? Do NOT ship samples until all necessary paperwork is compiled, YES NO NJA Comments: 1400 nw 19th st miami fl 33125 Project Manager Signature: Report No 10468837_8290FC_DFR Date: 4/1/19 Page 46 of 54 Page 9 of 17 SI 2 3 S G an 44 I I I • Giant African Land Snail (GALS) Miami -Dade and Broward Counties, July, 2018 Quarantine Zones 4! vyBRON4R9 '• •• ,c% ;V, ' • ; f,,t- • -1••• • r, G • i""5"5• "r7L Cove- city , 61y" cb•.•.', • , .--< 33 r 1=40 VD: P6a10,0k6 ippgi 4u4 • ' • .c , imytaMAR PKY Wie c F 9,217114.1-w-•• • : :rts tZVz ••Fl •":"I • 'Ai!. • , 1..AvOnt • • ;4r. •", - "7.1 drr -•• okE FifY• • - t d • ; "-iu es - "OM OxT • - Chr ; 1,14- i5.4,11,141 . '. • _ - 4-tuiltrs • i . • • - '1°j-r.- • - , i 1 ...,?..:4,..-; ,•,....4:-_4.,..e-,4-:-74r --:- 3,11---‘, , -.lg.! ; . Taradj,--7:' .' ,-4.• r t., sak411-.14--ST-er - .• • 2,,,,t-I#4f.;'' 5- . ',Tr.- 1Yrs . • ;.7 - i • : ' : - . :.1. '.7_;;; :_ s. \ t....,.,---li,Te.5_ , ; • .:' 40",NA J -': r ' etaig-t----1,?•i• .-:\:$314,GrItrer. ',,70.:..; — .f•-•, u- ,,kti • .••• ..--.J .. ,.! • -1. ,....1,--,0-•,77.- r ..:1,1:'• - .4-- r ;-• — • ; ... , , . , - - -- .• i KorgoMEt i _ . 1 , k. • ...- . _ - 1 • ''.' ,. - ,• 1 - s' :;. 4,104.1an'-',1W7,4'... q6 _1.....-V • - 1- . • ','"1% .. _ • 31. 444-1•41:41,4,0,,g--i:-..4r-.t-T-EIF-r A "trio - i• - k ' heflefrilMaSa' i -14,----. -. !,:‘,Tr.i i ; - • .., -.--=-.%..' ' '! V.' • T --T '11,..- - 3 - ...-'-ri-75 '4. -.F. • =Al ,. ze.-..„.-;, ,,•.4....,-, .1 .44,--ps,4:41.44L4,A ....................................... - ,Kentitii,. 14,tiv.,..._4•L:_=--7-.1, • •'•`4V • . -oir,-, •,.. :T3W40- 74, - .1 • i L. -,-.-A-J.,:,!. ..r4;,,L . , . 3:-: :-.•-•••Pr''''' i "r'• 4 ,..e. ' Ef v-. :-,. -; Pid,144:1-1-1A-. • ---,471...f!'; • - . q • di • '-'4' : • 1; z" c:•..PROI.il, .t rti • titighttelfkddiVW,S • ' , 4.1 gRliall nor • "t • • E • = lauritEitn*,, _ Waif Wig • me 3 ern 7 ti lb Report No 10468837 8290FC_DFR • GALS Quarantine Zones USDA Page 47 of 54 Page 10 of 17 Analytical TM Reporting Flags Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 A = Reporting Limit based on signal to noise B = Less than 10x higher than method blank level C = Result obtained from confirmation analysis D = Result obtained from analysis of diluted sample E = Exceeds calibration range I = Interferencepresent J = Estimated value L = Suppressive interference, analyte may be biased low Nn = Value obtained from additional analysis P = PCDEInterference R = Recovery outside target range S = Peak saturated U = Analyte not detected V = Result verified by confirmation analysis X = %D Exceeds limits Y = Calculated using average of daily RFs * = SeeDiscussion REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10468837_8290FC_DFR Page 11 of 17 Tel: 612-607-1700 Fax: 612-607-6444 Report No 10468837 Page 48 of 54 Appendix B Sample Analysis Summary Report No 10468837_8290FC_de Analytical Services, Inc. Page 49 of 54 Page 12 of 17 Analytical Client's Sample ID Lab Sample ID Filename Injected By Total Amount Extracted Moisture Dry Weight Extracted ICAL ID CCaI Filename(s) Method Blank ID Native Isomers TM Metho d 8290 Sample Analysis Results Client - PASI Florida SB-1 (3.5-4.5') 35456829004 F190411B_08 SMT 11.9 g 15.1 10.1 g F190112 F190411B_01 & BLANK-69658 Conc EMPC ng/Kg ng/Kg 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 4.2 65 3.5 130 3.0 9.5 91 12 150 19 5.9 7.9 2.7 90 5.5 250 120 1700 110 15 410 1,2,3,4,6,7,8-HpCDD 1200 Total HpCDD 2500 OCDF OCDD 210 6800 Matrix Dilution Collected Received F190411 B_17 Extracted Analyzed EDL Internal ng/Kg Standards 0.93 2,3,7,8-TCDF-13C 0.93 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 0.47 2,3,4,7,8-PeCDF-13C 0.47 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 0.65 J 1,2,3,6,7,8-HxCDF-13C 0.32 2,3,4,6,7,8-HxCDF-13C 0.49 1,2, 3, 7, 8, 9-HxC D F-13C 1,2,3,4,7,8-HxCDD-13C 0.31 1,2,3,6,7,8-HxCDD-13C 0.31 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612- 607-6444 Solid NA 03/25/2019 08:51 03/29/2019 09:45 04/05/2019 18:30 04/11/2019 18:17 0.28 0.32 0.32 0.20 J 0.28 1.5 1.7 1.3 1.5 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 ng's Percent Added Recovery 2.00 69 2.00 71 2.00 76 2.00 78 2.00 88 2.00 67 2.00 67 2.00 67 2.00 63 2.00 67 2.00 62 2.00 58 2.00 63 2.00 68 4.00 75 2.00 NA 2.00 NA 0.20 73 0.74 Total 2,3,7,8-TCDD 1.2 Equivalence: 77 ng/Kg 1.00 (Lower -bound - Using ITE Factors) 0.34 0.34 0.55 0.51 E Conc = Concentration (Totals include 2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit ND = Not Detected NA = Not Applicable NC = Not Calculated Results reported on a dry weight basis and are valid to no more than 2 significant figures. J = Estimated value E= Exceeds calibration range REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10468837_8290FC_DFR Page 13 of 17 Page 50 of 54 Analytical Client's Sample ID Lab Sample ID Filename Injected By Total Amount Extracted % Moisture Dry Weight Extracted ICAL ID CCal Filename(s) Method Blank ID Native Isomers TM Method 8290 Sample Analysis Results Client - PASI Florida SB-3 (0.5-2') 35456829010 F190411B_09 SMT 11.8 g 14.8 10.1 g F190112 F 190411 B_01 & BLANK-69658 Conc EMPC ng/Kg ng/Kg Matrix Dilution Collected Received F190411 B_17 Extracted Analyzed EDL Internal ng/Kg Standards Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis. MN 55414 Tel: 612-607-1700 Fax: 612- 607-6444 Solid NA 03/25/2019 10:47 03/29/2019 09:45 04/05/2019 18:30 04/11/2019 19:00 ng's Percent Added Recovery 2,3,7,8-TCDF 0.34 U 0.34 Total TCDF 0.42 0.34 J 2,3,7,8-TCDD 0.50 U 0.50 Total TCDD 0.51 0.50 BJ 1,2,3,7,8-PeCDF 0.33 U 2,3,4,7,8-PeCDF 0.17 U Total PeCDF 0.68 1,2,3,7,8-PeCDD Total PeCDD 0.33 0.17 0.25 J 0.41 U 0.41 0.41 U 0.41 1,2,3,4,7,8-HxCDF 0.35 U 1,2,3,6,7,8-HxCDF 0.33 U 2,3,4,6,7,8-HxCDF 0.23 U 1,2,3,7,8,9-HxCDF 0.26 U Total HxCDF 0.36 1,2,3,4,7,8-HxCDD 0.49 U 1,2,3,6,7,8-HxCDD 0.50 U 1,2,3,7,8,9-HxCDD Total HxCDD 1.8 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD 0.80 0.32 U 0.80 3.8 0.38 0.35 0.33 0.23 0.26 0.29 0.49 0.50 0.36 IJ 0.45 BJ 0.35 J 0.32 0.33 J 0.52 J 6.9 0.52 0.66 U 0.66 20 0.66 2,3,7,8-TCDF-13C 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 2,3,4,7,8-PeCDF-13C 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 1,2,3,6,7,8-HxCDF-13C 2,3,4,6,7,8-HxCDF-13C 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 1,2,3,6,7,8-HxCDD-13C 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 1,2,3,4-TCDD-13C J 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 4.00 2.00 2.00 0.20 Total 2, 3, 7, 8-TC D D Equivalence: 0.10 ng/Kg (Lower -bound - Using ITE Factors) 50 52 56 58 65 53 56 57 49 51 45 50 49 55 55 NA NA 64 Conc = Concentration (Totals include 2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit ND = Not Detected NA = Not Applicable NC = Not Calculated Results reported on a dry weight basis and are valid to no more than 2 significant figures. J = Estimated value B = Less than 10x higher than method blank level I = Interference present REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services. Inc. Report No 10468837_8290FC_DFR Page 14 of 17 Page 51 of 54 Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Analytical Client's Sample ID Lab Sample ID Filename Injected By Total Amount Extracted % Moisture Dry Weight Extracted ICAL ID CCaI Filename(s) Method Blank ID Native Isomers 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD TM Metho d 8290 Sample Analysis Results Client - PASI Florida SB-4 (0.5-2') 35456829013 F190411B_10 SMT 11.5 g 10.5 10.3 g F190112 F190411B_01 & BLANK-69658 Conc EMPC ng/Kg ng/Kg 2.2 34 1.4 59 0.94 1.6 12 3.1 32 1.4 0.89 1.1 17 2.8 11 7.8 120 1,2,3,4,6,7,8-HpCDF 11 1,2,3,4,7,8,9-HpCDF 0.98 Total HpCDF 34 1,2,3,4,6,7,8-HpCDD 280 Total HpCDD 540 OCDF OCDD 28 1900 0.31 F190411B_17 EDL ng/Kg 0.51 0.51 0.27 0.27 0.48 J 0.28 J 0.38 0.51 J 0.51 0.15 J 0.14 J 0.14 J 0.062 IJ 0.12 0.35 J 0.51 0.41 0.42 0.31 0.20 J 0.25 0.88 0.88 0.47 0.81 Matrix Dilution Collected Received Extracted Analyzed Internal Standards Tel: 612-607-1700 Fax: 612- 607-6444 Solid NA 03/25/2019 12:02 03/29/2019 09:45 04/05/2019 18:30 04/11/2019 19:43 2,3,7,8-TCDF-13C 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 2,3,4,7,8-PeCDF-13C 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 1,2,3,6,7,8-HxCDF-13C 2,3,4,6,7,8-HxCDF-13C 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 1,2,3,6,7,8-HxCDD-13C 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C ng's Percent Added Recovery 2.00 67 2.00 69 2.00 74 2.00 75 2.00 85 2.00 61 2.00 65 2.00 69 2.00 65 2.00 67 2.00 64 2.00 61 2.00 66 2.00 69 4.00 77 1,2,3,4-TCDD-13C 2.00 NA 1,2,3,7,8,9-HxCDD-13C 2.00 NA 2,3,7,8-TCDD-37CI4 0.20 68 Total 2,3,7,8-TCDD Equivalence: 11 ng/Kg (Lower -bound - Using ITE Factors) Conc = Concentration (Totals include 2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit ND = Not Detected NA = Not Applicable NC = Not Calculated Results reported on a dry weight basis and are valid to no more than 2 significant figures. J = Estimated value I = Interference present REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10468837_8290FC_DFR Page 52 of 54 Page 15 of 17 Analytical Lab Sample Name Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) Native Isomers TM Method 8290 Blank Analysis Results DFBLKLP BLANK-69658 F190411B_06 10.7 g F190112 F190411B_01 & F190411B_17 Conc EMPC EDL ng/Kg ng/Kg ng/Kg Matrix Dilution Extracted Analyzed Injected By Internal Standards Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis. MN 55414 Tel: 612-607-1700 Fax: 612-607-6444 Solid NA 04/05/2019 18:30 04/11/2019 16:51 SMT ng's Percent Added Recovery 2,3,7,8-TCDF Total TCDF 0.13 U 0.13 U 2,3,7,8-TCDD 0.22 U Total TCDD 0.32 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 0.23 U 0.14 U 0.18 U 0.14 U 0.28 0.076 U 0.086 U 0.076 U 0.083 U 0.080 U 0.10 U 0.11 U 0.078 U 0.43 0.096 U 0.088 U 0.092 U 0.076 0.086 0.076 0.083 0.080 0.10 0.11 0.078 0.097 J 0.13 2,3,7,8-TCDF-13C 0.13 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 0.22 2,3,4,7,8-PeCDF-13C 0.22 J 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 0.23 1, 2, 3, 6, 7, 8-HxC DF-13C 0.14 2,3,4,6,7,8-HxCDF-13C 0.18 1,2, 3, 7, 8, 9-HxC DF-13C 1,2,3,4,7,8-HxCDD-13C 0.14 1,2,3,6,7,8-HxCDD-13C 0.14 J 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 1,2,3,4-TCDD-13C 1 ,2,3,7,8,9-HxCDD-1 3C 2,3,7,8-TCDD-37CI4 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 4.00 2.00 2.00 0.20 0.096 Total 2,3,7,8-TCDD 0.088 Equivalence: 0.0020 ng/Kg 0.092 (Lower -bound - Using ITE Factors) 1,2,3,4,6,7,8-HpCDD 0.20 0.13 J Total HpCDD 0.50 0.13 J OCDF 0.32 U 0.32 OCDD 0.40 U 0.40 55 54 60 61 69 52 56 57 52 53 51 55 57 57 61 NA NA 113 Conc= Concentration (Totals include2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit Results reported on a total weight basis and are valid to no more than 2 significant figures. J = Estimated value REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full. without the written consent of Pace Analytical Services, Inc. Report No 10468837_8290FC_DFR Page 16 of 17 Page 53 of 54 7/e Analytic Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) Method Blank ID Native Isomers 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD TM Method Method 8290 Laboratory Control Spike Results Qs (ng) 0.20 0.20 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 LCS-69659 F190411B_04 10.7 g F190112 F190411B_01 & F190411B_17 BLANK-69658 Qm (ng) 0.22 0.23 1.1 1.1 0.99 1.2 1.1 1.1 1.1 1.1 1.2 1.0 Rec. 110 2,3,7,8-TCDF-13C 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 115 2,3,4,7,8-PeCDF-13C 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 112 1,2,3,6,7,8-HxCDF-13C 115 2,3,4,6,7,8-HxCDF-13C 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 99 1,2,3,6,7,8-HxCDD-13C 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C Matrix Dilution Extracted Analyzed Injected By 119 109 108 106 113 123 104 1.0 1.2 119 1.0 1.1 105 1.0 1.0 104 2.0 2.3 114 2.0 2.3 114 Internal Standards 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37C14 Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612-607-6444 Solid NA 04/05/2019 18:30 04/11/2019 15:25 SMT ng's Percent Added Recovery 2.0 64 2.0 63 2.0 70 2.0 74 2.0 81 2.0 70 2.0 72 2.0 71 2.0 62 2.0 71 2.0 69 2.0 62 2.0 65 2.0 70 4.0 58 2.0 NA 2.0 NA 0.20 134 Qs = Quantity Spiked Qm = Quantity Measured Rec. = Recovery (Expressed as Percent) R = Recovery outside of target range Y = RF averaging used in calculations Nn = Value obtained from additional analysis NA = Not Applicable = See Discussion REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10468837_8290FC_DFR Page 17 of 17 Page 54 of 54 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 April 16, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 27, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Some analyses have been subcontracted outside of the Pace Network. The subcontracted laboratory report has been attached. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry, EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 97 Pa eAnalytical www.pacelabs.com CERTIFICATIONS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Bivd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alaska DEC- CS/UST/LUST Alabama Certification #: 41320 Arizona Certification#AZ0819 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 97 aceAnalytical www.pacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35457287001 SB-6 (0-0.5') Solid 03/26/19 08:40 03/27/19 17:40 35457287002 SB-6 (0.5-2") Solid 03/26/19 08:42 03/27/19 17:40 35457287003 SB-6 (2-4') Solid 03/26/19 08:44 03/27/19 17:40 35457287004 SB-9 (0-0.5') Solid 03/26/19 10:10 03/27/19 17:40 35457287005 SB-9 (0.5-2') Solid 03/26/19 10:12 03/27/19 17:40 35457287006 SB-9 (2-4') Solid 03/26/19 10:14 03/27/19 17:40 35457287007 SB-7 (0-0.5') Solid 03/26/19 10:40 03/27/19 17:40 35457287008 SB-7 (0.5-2') Solid 03/26/19 10:42 03/27/19 17:40 35457287009 SB-7 (2-4') Solid 03/26/19 10:44 03/27/19 17:40 35457287010 SB-8 (0-0.5') Solid 03/26/19 11:30 03/27/19 17:40 35457287011 SB-8 (0.5-2') Solid 03/26/19 11:32 03/27/19 17:40 35457287012 SB-8 (2-4') Solid 03/26/19 11:34 03/27/19 17:40 35457287013 SB-12 (0-0.5') Solid 03/26/19 12:00 03/27/19 17:40 35457287014 SB-12 (0.5-2') Solid 03/26/19 12:02 03/27/19 17:40 35457287015 SB-12 (2-4') Solid 03/26/19 12:04 03/27/19 17:40 35457287016 SB-12 (4-6') Solid 03/26/19 12:06 03/27/19 17:40 5457287017 SB-12 (6-7') Solid 03/26/19 12:08 03/27/19 17:40 35457287018 SB-11 (0-0.5') Solid 03/26/19 12:25 03/27/19 17:40 35457287019 SB-11 (0.5-2') Solid 03/26/19 12:27 03/27/19 17:40 35457287020 SB-11 (2-4') Solid 03/26/19 12:29 03/27/19 17:40 35457287021 SB-11 (4-6') Solid 03/26/19 12:31 03/27/19 17:40 35457287022 SB-11 (6-8') Solid 03/26/19 12:33 03/27/19 17:40 35457287023 SB-10 (0-0.5') Solid 03/26/19 13:10 03/27/19 17:40 35457287024 SB-10 (0.5-2') Solid 03/26/19 13:12 03/27/19 17:40 35457287025 SB-10 (2-4') Solid 03/26/19 13:14 03/27/19 17:40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 97 aceAnalytical wwwpacelabs.com SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Analytes Method Analysts Reported Laboratory 35457287001 SB-6 (0-0.5') 35457287002 SB-6 (0.5-2") 35457287003 SB-6 (2-4') 35457287004 SB-9 (0-0.5') 35457287005 SB-9 (0.5-2') 35457287006 SB-9 (2-4') EPA6010 SC1 3 PASI-O ASTM D2974-87 CLT 1 PASI-O EPA6010 SC1 3 PASI-O ASTM D2974-87 CLT 1 PASI-O EPA6010 SC1 3 PASI-O ASTM D2974-87 CLT 1 PASI-O EPA 6010 SC1 3 PASI-O ASTM D2974-87 CLT 1 PASI-O EPA 6010 SC1 3 PASI-O ASTM D2974-87 CLT 1 PASI-O EPA 8081 AER, TCB 22 PASI-O FL -PRO RJR 3 PASI-O EPA 6010 JWP 7 PASI-O EPA 7471 CS2 1 PASI-O EPA 8270 TWB 21 PASI-O EPA 8260 BCH 70 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457287007 SB-7 (0-0.5') EPA 6010 SC1 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457287008 SB-7 (0.5-2') EPA 6010 SC1 3 PASI-O EPA 6010 JWP 2 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457287009 SB-7 (2-4') EPA 6010 SC1 3 PASI-O EPA 6010 JWP 1 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457287010 SB-8 (0-0.5') EPA 6010 SC1 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457287011 SB-8 (0.5-2') EPA 6010 SC1 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457287012 SB-8 (2-4') EPA 6010 SC1 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457287013 SB-12 (0-0.5') EPA 6010 SC1 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457287014 SB-12 (0.5-2') EPA 6010 SC1 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457287015 SB-12 (2-4') EPA 6010 SC1 3 PASI-O ASTM D2974-87 CLT 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 97 aceAnalytical www.pacelabs.com SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 35457287016 SB-12 (4-6') 35457287017 SB-12 (6-7') EPA6010 SC1 3 PASI-O ASTM D2974-87 CLT 1 PASI-O FL -PRO BP2 3 PASI-O EPA6010 JWP, SC1 7 PASI-O EPA6010 JWP 2 PASI-O EPA 7471 AMS 1 PASI-O EPA 8270 TWB 21 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457287018 SB-11 (0-0.5') EPA6010 SC1 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457287019 SB-11 (0.5-2') EPA6010 SC1 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457287020 SB-11 (2-4') EPA6010 JWP, SC1 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457287021 SB-11 (4-6') EPA6010 SC1 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457287022 SB-11 (6-8') EPA 6010 JWP, SC1 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457287023 SB-10 (0-0.5') EPA 6010 SC1 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457287024 SB-10 (0.5-2') EPA 6010 JWP. SC1 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457287025 SB-10 (2-4') EPA 6010 SC1 3 PASI-O ASTM D2974-87 CLT 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 97 aceAnalytical® www.pacelabs.com SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35457287001 SB-6 (0-0.5') EPA 6010 Arsenic 13.3 mg/kg 0.56 04/02/19 11:30 EPA 6010 Barium 20.5 mg/kg 0.56 04/02/19 11:30 EPA 6010 Lead 16.2 mg/kg 0.56 04/02/19 11:30 ASTM D2974-87 Percent Moisture 15.7 % 0.10 04/03/19 09:20 35457287002 SB-6 (0.5-2") EPA 6010 Barium 6.2 mg/kg 0.59 04/02/19 11:33 EPA 6010 Lead 8.7 mg/kg 0.59 04/02/19 11:33 ASTM D2974-87 Percent Moisture 7.6 % 0.10 04/03/19 09:20 35457287003 SB-6 (2-4') EPA 6010 Arsenic 0.52 I mg/kg 0.64 04/02/19 11:36 EPA 6010 Barium 3.3 mg/kg 0.64 04/02/19 11:36 EPA 6010 Lead 5.3 mg/kg 0.64 04/02/19 11:36 ASTM D2974-87 Percent Moisture 3.1 % 0.10 04/03/19 09:20 35457287004 SB-9 (0-0.5') EPA 6010 Arsenic 2.3 mg/kg 0.65 04/02/19 11:39 EPA 6010 Barium 36.3 mg/kg 0.65 04/02/19 11:39 EPA 6010 Lead 69.9 mg/kg 0.65 04/02/19 11:39 ASTM D2974-87 Percent Moisture 7.8 % 0.10 04/03/19 09:21 35457287005 SB-9 (0.5-2') EPA 6010 Arsenic 14.9 mg/kg 0.62 04/02/19 11:42 EPA 6010 Barium 225 mg/kg 6.2 04/02/19 14:58 EPA 6010 Lead 636 mg/kg 6.2 04/02/19 14:58 ASTM D2974-87 Percent Moisture 12.5 % 0.10 04/03/19 09:21 35457287006 SB-9 (2-4') EPA 8081 Chlordane (Technical) 0.28 mg/kg 0.22 04/02/19 23:50 EPA 8081 4,4'-DDE 0.012 I mg/kg 0.022 04/02/19 03:52 EPA 8081 Dieldrin 0.0050 I mg/kg 0.022 04/02/19 03:52 FL -PRO Petroleum Range Organics 222 mg/kg 25.1 04/02/19 21:33 D4 EPA 6010 Arsenic 7.8 mg/kg 2.7 04/02/19 15:35 EPA 6010 Barium 129 mg/kg 2.7 04/02/19 15:35 EPA 6010 Cadmium 2.2 mg/kg 0.27 04/02/19 15:35 EPA 6010 Chromium 23.1 mg/kg 1.4 04/02/19 15:35 EPA 6010 Lead 409 mg/kg 2.7 04/02/19 15:35 EPA 6010 Silver 1.6 mg/kg 1.4 04/02/19 15:35 EPA 7471 Mercury 0.34 mg/kg 0.0090 04/01/19 14:25 EPA 8260 Acetone 0.083 mg/kg 0.024 04/02/19 03:06 EPA 8260 Tetrachloroethene 0.011 mg/kg 0.0059 04/02/19 03:06 ASTM D2974-87 Percent Moisture 21.7 % 0.10 04/02/19 11:56 35457287007 SB-7 (0-0.5') EPA 6010 Arsenic 18.8 mg/kg 0.61 04/02/19 11:51 EPA 6010 Barium 29.2 mg/kg 0.61 04/02/19 11:51 EPA 6010 Lead 174 mg/kg 6.1 04/02/19 15:01 ASTM D2974-87 Percent Moisture 19.3 % 0.10 04/03/19 09:21 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 97 /2eAnaIyticaI wwwpacelabscom SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35457287008 SB-7 (0.5-2') EPA 6010 Arsenic 275 mg/kg 7.9 04/02/19 11:53 EPA 6010 Barium 278 mg/kg 7.9 04/02/19 11:53 EPA 6010 Lead 1560 mg/kg 7.9 04/02/19 11:53 EPA 6010 Arsenic 0.15 mg/L 0.10 04/10/19 15:34 EPA 6010 Lead 0.12 mg/L 0.10 04/10/19 15:34 ASTM D2974-87 Percent Moisture 27.9 % 0.10 04/03/19 09:21 35457287009 SB-7 (2-4') EPA 6010 Arsenic 32.0 mg/kg 9.9 04/02/19 15:04 EPA 6010 Barium 698 mg/kg 9.9 04/02/19 15:04 EPA 6010 Lead 3090 mg/kg 98.8 04/02/19 16:06 EPA 6010 Lead 0.13 mg/L 0.10 04/10/19 15:37 ASTM D2974-87 Percent Moisture 38.2 % 0.10 04/03/19 09:21 J(D6) 35457287010 SB-8 (0-0.5') EPA 6010 Arsenic 29.8 mg/kg 0.56 04/02/19 11:59 EPA6010 Barium 11.8 mg/kg 0.56 04/02/19 11:59 EPA 6010 Lead 7.3 mg/kg 0.56 04/02/19 11:59 ASTM D2974-87 Percent Moisture 15.9 % 0.10 04/03/19 09:22 '5457287011 SB-8 (0.5-2') _.:PA 6010 Arsenic 17.9 mg/kg 0.66 04/02/19 12:02 EPA 6010 Barium 49.9 mg/kg 0.66 04/02/19 12:02 EPA 6010 Lead 152 mg/kg 6.6 04/02/19 15:07 ASTM D2974-87 Percent Moisture 22.2 % 0.10 04/03/19 09:22 35457287012 SB-8 (2-4') EPA 6010 Arsenic 26.9 mg/kg 8.9 04/02/19 12:05 EPA 6010 Barium 182 mg/kg 8.9 04/02/19 12:05 EPA 6010 Lead 525 mg/kg 8.9 04/02/19 12:05 ASTM D2974-87 Percent Moisture 41.7 % 0.10 04/03/19 09:22 35457287013 SB-12 (0-0.5') EPA 6010 Arsenic 11.3 mg/kg 0.67 04/03/19 11:15 EPA 6010 Barium 10.3 mg/kg 0.67 04/03/19 11:15 EPA 6010 Lead 10.8 mg/kg 0.67 04/03/19 11:15 ASTM D2974-87 Percent Moisture 14.1 % 0.10 04/03/19 09:22 35457287014 SB-12 (0.5-2') EPA 6010 Arsenic 5.0 mg/kg 0.67 04/03/19 11:27 EPA 6010 Barium 1270 mg/kg 13.3 04/03/19 14:22 EPA 6010 Lead 23.2 mg/kg 0.67 04/03/19 11:27 ASTM D2974-87 Percent Moisture 27.8 % 0.10 04/03/19 09:22 35457287015 SB-12 (2-4') EPA 6010 Arsenic 8.3 mg/kg 0.72 04/03/19 11:30 EPA 6010 Barium 28.2 mg/kg 0.72 04/03/19 11:30 EPA 6010 Lead 62.1 mg/kg 0.72 04/03/19 11:30 ASTM D2974-87 Percent Moisture 19.5 % 0.10 04/03/19 09:22 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 97 aceAnalytical www.pacelabs.com SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35457287016 SB-12 (4-6') EPA 6010 Arsenic 78.1 mg/kg 3.5 04/03/19 11:33 EPA 6010 Barium 254 mg/kg 3.5 04/03/19 11:33 EPA 6010 Lead 1900 mg/kg 34.7 04/03/19 14:25 ASTM D2974-87 Percent Moisture 20.2 % 0.10 04/03/19 09:22 35457287017 SB-12 (6-7') FL -PRO Petroleum Range Organics 436 mg/kg 6.3 04/05/19 10:48 EPA 6010 Arsenic 152 mg/kg 4.2 04/03/19 11:36 EPA 6010 Barium 4020 mg/kg 84.7 04/03/19 14:30 EPA 6010 Cadmium 18.3 mg/kg 0.42 04/03/19 11:36 EPA 6010 Chromium 78.2 mg/kg 2.1 04/03/19 11:36 EPA 6010 Lead 4510 mg/kg 84.7 04/03/19 14:30 EPA 6010 Silver 7.3 mg/kg 2.1 04/03/19 11:36 EPA 6010 Lead 0.34 mg/L 0.10 04/10/19 15:40 EPA7471 Mercury 0.42 mg/kg 0.014 04/03/19 15:10 J(M1),J(R1) ASTM D2974-87 Percent Moisture 37.3 % 0.10 04/03/19 09:22 35457287018 SB-11 (0-0.5') EPA 6010 Arsenic 8.7 mg/kg 0.63 04/03/19 11:44 EPA 6010 Barium 8.5 mg/kg 0.63 04/03/19 11:44 EPA 6010 Lead 10.1 mg/kg 0.63 04/03/19 11:44 ASTM D2974-87 Percent Moisture 6.8 % 0.10 04/03/19 09:22 35457287019 SB-11 (0.5-2') EPA6010 Arsenic 8.2 mg/kg 0.52 04/03/19 11:47 EPA6010 Barium 30.0 mg/kg 0.52 04/03/19 11:47 EPA 6010 Lead 92.9 mg/kg 0.52 04/03/19 11:47 ASTM D2974-87 Percent Moisture 12.7 % 0.10 04/03/19 09:23 35457287020 SB-11 (2-4') EPA 6010 Arsenic 10.0 mg/kg 0.53 04/03/19 11:50 EPA 6010 Barium 41.0 mg/kg 0.53 04/03/19 11:50 EPA 6010 Lead 160 mg/kg 5.3 04/03/19 14:33 ASTM D2974-87 Percent Moisture 16.5 % 0.10 04/03/19 09:23 35457287021 SB-11 (4-6') EPA 6010 Arsenic 8.2 mg/kg 0.79 04/03/19 11:53 EPA 6010 Barium 50.7 mg/kg 0.79 04/03/19 11:53 EPA 6010 Lead 64.3 mg/kg 0.79 04/03/19 11:53 ASTM D2974-87 Percent Moisture 21.5 % 0.10 04/03/19 09:23 35457287022 SB-11 (6-8') EPA 6010 Arsenic 36.1 mg/kg 3.7 04/03/19 11:56 EPA 6010 Barium 292 mg/kg 3.7 04/03/19 11:56 EPA 6010 Lead 1850 mg/kg 74.7 04/03/19 14:44 ASTM D2974-87 Percent Moisture 29.8 % 0.10 04/03/19 09:23 35457287023 SB-10 (0-0.5') EPA 6010 Arsenic 12.6 mg/kg 0.50 04/03/19 11:59 EPA 6010 Barium 7.4 mg/kg 0.50 04/03/19 11:59 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 97 SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.. 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35457287023 SB-10 (0-0.5') EPA 6010 Lead 7.9 mg/kg 0.50 04/03/19 11:59 ASTM D2974-87 Percent Moisture 5.9 % 0.10 04/03/19 09:23 35457287024 SB-10 (0.5-2') EPA 6010 Arsenic 13.7 mg/kg 0.65 04/03/19 12:01 EPA 6010 Barium 31.5 mg/kg 0.65 04/03/19 12:01 EPA 6010 Lead 259 mg/kg 6.5 04/03/19 14:39 ASTM D2974-87 Percent Moisture 10.9 % 0.10 04/03/19 09:23 35457287025 SB-10 (2-4') EPA 6010 Arsenic 0.53 I mg/kg 0.69 04/03/19 12:04 EPA 6010 Barium 12.9 mg/kg 0.69 04/03/19 12:04 EPA 6010 Lead 5.2 mg/kg 0.69 04/03/19 12:04 ASTM D2974-87 Percent Moisture 15.2 % 0.10 04/03/19 09:23 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 97 aceAnapical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-6 (0-0.5') Lab ID: 35457287001 Collected: 03/26/19 08:40 Received: 03/27/19 17:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 13.3 mg/kg 0.56 0.28 1 04/01/1916:21 04/02/1911:30 7440-38-2 Barium 20.5 mg/kg 0.56 0.28 1 04/01/19 16:21 04/02/19 11:30 7440-39-3 Lead 16.2 mg/kg 0.56 0.28 1 04/01/19 16:21 04/02/19 11:30 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 15.7 % 0.10 0.10 1 04/03/19 09:20 Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 97 www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-6 (0.5-2") Lab ID: 35457287002 Collected: 03/26/19 08:42 Received: 03/27/19 17:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 0.30 U mg/kg 0.59 0.30 1 04/01/19 16:21 04/02/19 11:33 7440-38-2 Barium 6.2 mg/kg 0.59 0.30 1 04/01/19 16:21 04/02/19 11:33 7440-39-3 Lead 8.7 mg/kg 0.59 0.30 1 04/01/19 16:21 04/02/19 11:33 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 7.6 % 0.10 0.10 1 04/03/19 09:20 Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 97 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-6 (2-4') Lab ID: 35457287003 Collected: 03/26/19 08:44 Received: 03/27/19 17:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 0.52 I mg/kg 0.64 0.32 1 04/01/19 16:21 04/02/1911:36 7440-38-2 Barium 3.3 mg/kg 0.64 0.32 1 04/01/19 16:21 04/02/19 11:36 7440-39-3 Lead 5.3 mg/kg 0.64 0.32 1 04/01/19 16:21 04/02/19 11:36 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 3.1 % 0.10 0.10 1 04/03/19 09:20 Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 97 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project. 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-9 (0-0.5') Lab ID: 35457287004 Collected: 03/26/19 10:10 Received: 03/27/19 17:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 2.3 mg/kg 0.65 0.33 1 04/01/19 16:21 04/02/19 11:39 7440-38-2 Barium 36.3 mg/kg 0.65 0.33 1 04/01/19 16:21 04/02/19 11:39 7440-39-3 Lead 69.9 mg/kg 0.65 0.33 1 04/01/19 16:21 04/02/19 11:39 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 7.8 % 0.10 0.10 1 04/03/19 09:21 Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-9 (0.5-2') Lab ID: 35457287005 Collected: 03/26/19 10:12 Received: 03/27/19 17:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3050 Arsenic 14.9 mg/kg 0.62 0.31 1 04/01/19 16:21 04/02/19 11:42 7440-38-2 Barium 225 mg/kg 6.2 3.1 10 04/01/19 16:21 04/02/19 14:58 7440-39-3 Lead 636 mg/kg 6.2 3.1 10 04/01/19 16:21 04/02/19 14:58 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 04/16/2019 12:00 AM 12.5 % 0.10 0.10 1 04/03/19 09:21 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-9 (2-4') Lab ID: 35457287006 Collected: 03/26/19 10:14 Received: 03/27/19 17:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8081 GCS Pesticides Aldrin alpha-BHC beta-BHC delta-BHC gamma-BHC (Lindane) Chlordane (Technical) 4,4'-DDD 4,4'-DDE 4,4'-DDT Dieldrin Endosulfan I Endosulfan II Endosulfan sulfate Endrin Endrin aldehyde Endrin ketone Heptachlor eptachlor epoxide wlethoxychlor Toxaphene Surrogates Tetrachloro-m-xylene (S) Decachlorobiphenyl (S) FL -PRO Soil Microwave Petroleum Range Organics Surrogates o-Terphenyl (S) N-Pentatriacontane (S) 6010 MET ICP Arsenic Barium Cadmium Chromium Lead Selenium Silver 7471 Mercury Mercury 8270 MSSV Short List Microwave Acenaphthene Acenaphthylene Date: 04/16/2019 12:00 AM Analytical Method: EPA 8081 Preparation Method: EPA 3546 0.00075 U 0.00089 U 0.00099 U 0.0011 U 0.0019 U 0.28 0.0017 U 0.012 I 0.0012 U 0.0050 I 0.00032 0.00073 0.00055 0.00067 0.00085 0.0010 0.00050 0.0014 0.013 0.094 mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg 0.022 0.00075 10 03/30/19 10:41 0.022 0.00089 10 03/30/19 10:41 0.022 0.00099 10 03/30/19 10:41 0.022 0.0011 10 03/30/19 10:41 0.022 0.0019 10 03/30/19 10:41 0.22 0.20 10 03/30/19 10:41 0.022 0.0017 10 03/30/19 10:41 0.022 0.00078 10 03/30/19 10:41 0.022 0.0012 10 03/30/19 10:41 0.022 0.00051 10 03/30/19 10:41 0.022 0.00032 10 03/30/19 10:41 0.022 0.00073 10 03/30/19 10:41 0.022 0.00055 10 03/30/19 10:41 0.022 0.00067 10 03/30/19 10:41 0.042 0.00085 10 03/30/19 10:41 0.022 0.0010 10 03/30/19 10:41 0.022 0.00050 10 03/30/19 10:41 0.022 0.0014 10 03/30/19 10:41 0.022 0.013 10 03/30/19 10:41 0.22 0.094 10 03/30/19 10:41 87 % 53-140 74 % 43-157 Analytical Method: FL -PRO Preparati 222 mg/kg 25.1 102 % 66-136 92 % 42-159 04/02/19 03:52 04/02/19 03:52 04/02/19 03:52 04/02/19 03:52 04/02/19 03:52 04/02/19 23:50 04/02/19 03:52 04/02/19 03:52 04/02/19 03:52 04/02/19 03:52 04/02/19 03:52 04/02/19 03:52 04/02/19 03:52 04/02/19 03:52 04/02/19 03:52 04/02/19 03:52 04/02/19 03:52 04/02/19 03:52 04/02/19 03:52 04/02/19 03:52 309-00-2 319-84-6 319-85-7 319-86-8 58-89-9 57-74-9 72-54-8 72-55-9 50-29-3 60-57-1 959-98-8 33213-65-9 1031-07-8 72-20-8 7421-93-4 53494-70-5 76-44-8 1024-57-3 72-43-5 8001-35-2 10 03/30/19 10:41 04/02/19 03:52 877-09-8 10 03/30/19 10:41 04/02/19 03:52 2051-24-3 on Method: EPA 3546 16.0 5 04/02/19 02:06 04/02/19 21:33 5 04/02/19 02:06 04/02/19 21:33 84-15-1 5 04/02/19 02:06 04/02/19 21:33 630-07-09 Analytical Method: EPA 6010 Preparation Method: EPA 3050 7.8 129 2.2 23.1 409 2.1 U 1.6 mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg 2.7 2.7 0.27 1.4 2.7 4.1 1.4 1.4 1.4 0.14 0.68 1.4 2.1 0.68 5 04/01/1911:36 5 04/01/19 11:36 5 04/01/19 11:36 5 04/01/19 11:36 5 04/01/1911:36 5 04/01/19 11:36 5 04/01/1911:36 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.34 mg/kg 0.0090 0.0045 04/02/19 15:35 04/02/19 15:35 04/02/19 15:35 04/02/19 15:35 04/02/19 15:35 04/02/19 15:35 04/02/19 15:35 D4 7440-38-2 7440-39-3 7440-43-9 7440-47-3 7439-92-1 7782-49-2 D3 7440-22-4 1 03/31/19 16:43 04/01/19 14:25 7439-97-6 Analytical Method: EPA 8270 Preparation Method: EPA 3546 0.044 U mg/kg 0.040 U mg/kg 0.14 0.044 1 03/30/19 09:58 0.13 0.040 1 03/30/19 09:58 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 04/01/19 20:02 83-32-9 P1 04/01/19 20:02 208-96-8 P1 Page 15 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-9 (2-4') Results reported on a "dry weight' Parameters Lab ID: 35457287006 Collected: 03/26/19 10:14 Received: 03/27/19 17:40 Matrix: Solid ' basis and are adjusted for percent moisture, sample size and any dilutions. Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8270 MSSV Short List Microwave Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene Chrysene Dibenz(a.h)anthracene Fluoranthene Fluorene Indeno(1,2,3-cd)pyrene 1-Methylnaphthalene 2-Methylnaphthalene Naphthalene Phenanthrene Pyrene Surrogates Nitrobenzene-d5 (S) 2-Fluorobiphenyl (S) p-Terphenyl-d14 (S) 8260 MSV 5035 1.1,1,2-Tetrachloroethane 1,1.1-Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,1-Dichloropropene 1,2,3-Trichlorobenzene 1,13-Trichloropropane 1,2,3-Trimethylbenzene 1,2,4-Trichlorobenzene 1,2,4-Trimethylbenzene 1,2-Dichlorobenzene 1,2-Dichloroethane 1.2-Dichloropropane 1, 3,5-Trimethylbenzene 1,3-Dichlorobenzene 1,3-Dichloropropane 1,4-Dichlorobenzene 2,2-Dichloropropane 2-Butanone (MEK) 2-Chloroethylvinyl ether 2-Chlorotoluene Date: 04/16/2019 12:00 AM Analytical Method: EPA 8270 Preparation Method: EPA 3546 0.045 U mg/kg 0.14 0.045 1 03/30/19 09:58 04/01/19 20:02 120-12-7 P1 0.037 U mg/kg 0.13 0.037 1 03/30/19 09:58 04/01/19 20:02 56-55-3 P1 0.032 U mg/kg 0.13 0.032 1 03/30/19 09:58 04/01/19 20:02 50-32-8 P1 0.034 U mg/kg 0.13 0.034 1 03/30/19 09:58 04/01/19 20:02 205-99-2 P1 0.032 U mg/kg 0.13 0.032 1 03/30/19 09:58 04/01/19 20:02 191-24-2 P1 0.034 U mg/kg 0.13 0.034 1 03/30/19 09:58 04/01/19 20:02 207-08-9 P1 0.041 U mg/kg 0.13 0.041 1 03/30/19 09:58 04/01/19 20:02 218-01-9 P1 0.029 U mg/kg 0.13 0.029 1 03/30/19 09:58 04/01/19 20:02 53-70-3 P1 0.042 U mg/kg 0.13 0.042 1 03/30/19 09:58 04/01/19 20:02 206-44-0 P1 0.046 U mg/kg 0.14 0.046 1 03/30/19 09:58 04/01/19 20:02 86-73-7 P1 0.029 U mg/kg 0.13 0.029 1 03/30/19 09:58 04/01/19 20:02 193-39-5 P1 0.050 U mg/kg 0.15 0.050 1 03/30/19 09:58 04/01/19 20:02 90-12-0 P1 0.049 U mg/kg 0.15 0.049 1 03/30/19 09:58 04/01/19 20:02 91-57-6 P1 0.044 U mg/kg 0.13 0.044 1 03/30/19 09:58 04/01/19 20:02 91-20-3 P1 0.042 U mg/kg 0.13 0.042 1 03/30/19 09:58 04/01/19 20:02 85-01-8 P1 0.040 U mg/kg 0.13 0.040 1 03/30/19 09:58 04/01/19 20:02 129-00-0 P1 78 % 24-98 1 03/30/19 09:58 04/01/19 20:02 4165-60-0 79 % 29-101 1 03/30/19 09:58 04/01/19 20:02 321-60-8 92 % 29-112 1 03/30/19 09:58 04/01/19 20:02 1718-51-0 Analytical Method: EPA 8260 Preparation Method: EPA 5035 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 630-20-6 0.0032 U mg/kg 0.0059 0.0032 1 04/01/19 15:12 04/02/19 03:06 71-55-6 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 79-34-5 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 79-00-5 0.0032 U mg/kg 0.0059 0.0032 1 04/01/19 15:12 04/02/19 03:06 75-34-3 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 75-35-4 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 563-58-6 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 87-61-6 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 96-18-4 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 526-73-8 N2 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 120-82-1 0.0033 U mg/kg 0.0059 0.0033 1 04/01/19 15:12 04/02/19 03:06 95-63-6 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 95-50-1 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 107-06-2 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 78-87-5 0.0034 U mg/kg 0.0059 0.0034 1 04/01/19 15:12 04/02/19 03:06 108-67-8 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 541-73-1 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 142-28-9 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 106-46-7 0.0031 U mg/kg 0.0059 0.0031 1 04/01/19 15:12 04/02/19 03:06 594-20-7 0.0059 U mg/kg 0.012 0.0059 1 04/01/19 15:12 04/02/19 03:06 78-93-3 0.012 U mg/kg 0.024 0.012 1 04/01/19 15:12 04/02/19 03:06 110-75-8 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 95-49-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-9 (2-4') Lab ID: 35457287006 Collected: 03/26/19 10:14 Received: 03/27/19 17:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8260 MSV 5035 Analytical Method: EPA 8260 Preparation Method: EPA 5035 2-Hexanone 0.0059 U mg/kg 0.012 0.0059 1 04/01/19 15:12 04/02/19 03:06 591-78-6 4-Chlorotoluene 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 106-43-4 4-Methyl-2-pentanone (MIBK) 0.0059 U mg/kg 0.012 0.0059 1 04/01/19 15:12 04/02/19 03:06 108-10-1 Acetone 0.083 mg/kg 0.024 0.012 1 04/01/19 15:12 04/02/19 03:06 67-64-1 Acetonitrile 0.030 U mg/kg 0.059 0.030 1 04/01/19 15:12 04/02/19 03:06 75-05-8 Benzene 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 71-43-2 Bromobenzene 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 108-86-1 Bromochloromethane 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 74-97-5 Bromodichloromethane 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 75-27-4 Bromoform 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 75-25-2 Bromomethane 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 74-83-9 Carbon disulfide 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 75-15-0 Carbon tetrachloride 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 56-23-5 Chlorobenzene 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 108-90-7 Chloroethane 0.0042 U mg/kg 0.0059 0.0042 1 04/01/19 15:12 04/02/19 03:06 75-00-3 Chloroform 0.0035 U mg/kg 0.0059 0.0035 1 04/01/19 15:12 04/02/19 03:06 67-66-3 Chloromethane 0.0033 U mg/kg 0.0059 0.0033 1 04/01/19 15:12 04/02/19 03:06 74-87-3 iromochloromethane 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 124-48-1 i)ibromomethane 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 74-95-3 Dichlorodifluoromethane 0.0031 U mg/kg 0.0059 0.0031 1 04/01/19 15:12 04/02/19 03:06 75-71-8 Ethylbenzene 0.0033 U mg/kg 0.0059 0.0033 1 04/01/19 15:12 04/02/19 03:06 100-41-4 lodomethane 0.0059 U mg/kg 0.012 0.0059 1 04/01/19 15:12 04/02/19 03:06 74-88-4 Isopropylbenzene (Cumene) 0.0034 U mg/kg 0.0059 0.0034 1 04/01/19 15:12 04/02/19 03:06 98-82-8 Methyl-tert-butyl ether 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 1634-04-4 Methylene Chloride 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 75-09-2 Styrene 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 100-42-5 Tetrachloroethene 0.011 mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 127-18-4 Toluene 0.0032 U mg/kg 0.0059 0.0032 1 04/01/19 15:12 04/02/19 03:06 108-88-3 Trichloroethene 0.0033 U mg/kg 0.0059 0.0033 1 04/01/19 15:12 04/02/19 03:06 79-01-6 Trichlorofluoromethane 0.0032 U mg/kg 0.0059 0.0032 1 04/01/19 15:12 04/02/19 03:06 75-69-4 Vinyl acetate 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 108-05-4 Vinyl chloride 0.0032 U mg/kg 0.0059 0.0032 1 04/01/19 15:12 04/02/19 03:06 75-01-4 Xylene (Total) 0.0061 U mg/kg 0.018 0.0061 1 04/01/19 15:12 04/02/19 03:06 1330-20-7 cis-1,2-Dichloroethene 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 156-59-2 cis-1,3-Dichloropropene 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 10061-01-5 m&p-Xylene 0.0061 U mg/kg 0.012 0.0061 1 04/01/19 15:12 04/02/19 03:06 179601-23-1 n-Butylbenzene 0.0036 U mg/kg 0.0059 0.0036 1 04/01/19 15:12 04/02/19 03:06 104-51-8 n-Propylbenzene 0.0031 U mg/kg 0.0059 0.0031 1 04/01/19 15:12 04/02/19 03:06 103-65-1 o-Xylene 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 95-47-6 p-Isopropyltoluene 0.0036 U mg/kg 0.0059 0.0036 1 04/01/19 15:12 04/02/19 03:06 99-87-6 sec-Butylbenzene 0.0034 U mg/kg 0.0059 0.0034 1 04/01/19 15:12 04/02/19 03:06 135-98-8 tert-Butylbenzene 0.0034 U mg/kg 0.0059 0.0034 1 04/01/19 15:12 04/02/19 03:06 98-06-6 trans-1,2-Dichloroethene 0.0036 U mg/kg 0.0059 0.0036 1 04/01/19 15:12 04/02/19 03:06 156-60-5 trans-1,3-Dichloropropene 0.0030 U mg/kg 0.0059 0.0030 1 04/01/19 15:12 04/02/19 03:06 10061-02-6 Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-9 (2-4') Lab ID: 35457287006 Collected: 03/26/19 10:14 Received: 03/27/19 17:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8260 MSV 5035 Analytical Method: EPA 8260 Preparation Method: EPA 5035 Surrogates 4-Bromofluorobenzene (S) 85 % 68-125 1 04/01/19 15:12 04/02/19 03:06 460-00-4 1,2-Dichloroethane-d4 (S) 111 % 71-132 1 04/01/19 15:12 04/02/19 03:06 17060-07-0 Toluene-d8 (S) 97 % 70-130 1 04/01/19 15:12 04/02/19 03:06 2037-26-5 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 21.7 % 0.10 0.10 1 04/02/19 11:56 Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-7 (0-0.5') Lab ID: 35457287007 Collected: 03/26/19 10:40 Received: 03/27/19 17:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3050 Arsenic 18.8 mg/kg 0.61 0.30 1 04/01/19 16:21 04/02/19 11:51 7440-38-2 Barium 29.2 mg/kg 0.61 0.30 1 04/01/19 16:21 04/02/19 11:51 7440-39-3 Lead 174 mg/kg 6.1 3.0 10 04/01/19 16:21 04/02/19 15:01 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 19.3 % 0.10 0.10 1 04/03/19 09:21 Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 97 /eAnaIyticaI wwwpacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-7 (0.5-2') Lab ID: 35457287008 Collected: 03/26/19 10:42 Received: 03/27/19 17:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 275 mg/kg 7.9 3.9 10 04/01/19 16:21 04/02/19 11:53 7440-38-2 Barium 278 mg/kg 7.9 3.9 10 04/01/19 16:21 04/02/19 11:53 7440-39-3 Lead 1560 mg/kg 7.9 3.9 10 04/01/19 16:21 04/02/19 11:53 7439-92-1 6010 MET ICP, TCLP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Leachate Method/Date: EPA 1311; 04/08/19 15:46 Initial pH: 5; Final pH: 5 Arsenic 0.15 mg/L 0.10 0.071 1 04/10/19 07:56 04/10/19 15:34 7440-38-2 Lead 0.12 mg/L 0.10 0.046 1 04/10/19 07:56 04/10/19 15:34 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 04/16/2019 12:00 AM 27.9 % 0.10 0.10 1 04/03/19 09:21 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-7 (2-4') Lab ID: 35457287009 Collected: 03/26/19 10:44 Received: 03/27/19 17:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 32.0 mg/kg 9.9 4.9 10 04/01/19 16:21 04/02/19 15:04 7440-38-2 Barium 698 mg/kg 9.9 4.9 10 04/01/19 16:21 04/02/19 15:04 7440-39-3 Lead 3090 mg/kg 98.8 49.4 100 04/01/19 16:21 04/02/19 16:06 7439-92-1 6010 MET ICP, TCLP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Leachate Method/Date: EPA 1311: 04/08/19 15:46 Initial pH: 5; Final pH: 6 Lead 0.13 mg/L 0.10 0.046 1 04/10/19 07:56 04/10/19 15:37 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 38.2 % 0.10 0.10 1 04/03/19 09:21 J(D6) Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 21 of 97 aceAnalytical wwwpacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-8 (0-0.5') Lab ID: 35457287010 Collected: 03/26/19 11:30 Received: 03/27/19 17:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 29.8 mg/kg 0.56 0.28 1 04/01/19 16:21 04/02/19 11:59 7440-38-2 Barium 11.8 mg/kg 0.56 0.28 1 04/01/19 16:21 04/02/19 11:59 7440-39-3 Lead 7.3 mg/kg 0.56 0.28 1 04/01/19 16:21 04/02/19 11:59 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 15.9 % 0.10 0.10 1 04/03/19 09:22 Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 22 of 97 aceAnalytical www.pace/abs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-8 (0.5-2') Lab ID: 35457287011 Collected: 03/26/19 11:32 Received: 03/27/19 17:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 17.9 mg/kg 0.66 0.33 1 04/01/19 16:21 04/02/19 12:02 7440-38-2 Barium 49.9 mg/kg 0.66 0.33 1 04/01/19 16:21 04/02/19 12:02 7440-39-3 Lead 152 mg/kg 6.6 3.3 10 04/01/19 16:21 04/02/1915:07 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 22.2 % 0.10 0.10 1 04/03/19 09:22 Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach. FL 33064 954-582-4300 Sample: SB-8 (2-4') Lab ID: 35457287012 Collected: 03/26/19 11:34 Received: 03/27/19 17:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 26.9 mg/kg 8.9 4.5 10 04/01/19 16:21 04/02/1912:05 7440-38-2 Barium 182 mg/kg 8.9 4.5 10 04/01/19 16:21 04/02/19 12:05 7440-39-3 Lead 525 mg/kg 8.9 4.5 10 04/01/19 16:21 04/02/19 12:05 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 41.7 % 0.10 0.10 1 04/03/19 09:22 Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 24 of 97 www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-12 (0-0.5') Lab ID: 35457287013 Collected: 03/26/19 12:00 Received: 03/27/19 17:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 11.3 mg/kg 0.67 0.34 1 04/02/19 14:58 04/03/19 11:15 7440-38-2 Barium 10.3 mg/kg 0.67 0.34 1 04/02/19 14:58 04/03/19 11:15 7440-39-3 Lead 10.8 mg/kg 0.67 0.34 1 04/02/19 14:58 04/03/19 11:15 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 14.1 % 0.10 0.10 1 04/03/19 09:22 Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 25 of 97 ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-12 (0.5-2') Lab ID: 35457287014 Collected: 03/26/19 12:02 Received: 03/27/19 17:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 5.0 mg/kg 0.67 0.33 1 04/02/19 14:58 04/03/19 11:27 7440-38-2 Barium 1270 mg/kg 13.3 6.7 20 04/02/19 14:58 04/03/19 14:22 7440-39-3 Lead 23.2 mg/kg 0.67 0.33 1 04/02/19 14:58 04/03/19 11:27 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 27.8 % 0.10 0.10 1 04/03/19 09:22 Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 26 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-12 (2-4') Lab ID: 35457287015 Collected: 03/26/19 12:04 Received: 03/27/19 17:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 8.3 mg/kg 0.72 0.36 1 04/02/19 14:58 04/03/19 11:30 7440-38-2 Barium 28.2 mg/kg 0.72 0.36 1 04/02/19 14:58 04/03/1911:30 7440-39-3 Lead 62.1 mg/kg 0.72 0.36 1 04/02/19 14:58 04/03/19 11:30 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 04/16/2019 12:00 AM 19.5 % 0.10 0.10 1 04/03/19 09:22 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 27 of 97 aceAnaVical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-12 (4-6') Lab ID: 35457287016 Collected: 03/26/19 12:06 Received: 03/27/19 17:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3050 Arsenic 78.1 mg/kg 3.5 1.7 5 04/02/19 14:58 04/03/19 11:33 7440-38-2 Barium 254 mg/kg 3.5 1.7 5 04/02/19 14:58 04/03/19 11:33 7440-39-3 Lead 1900 mg/kg 34.7 17.4 50 04/02/19 14:58 04/03/1914:25 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 04/16/2019 12:00 AM 20.2 % 0.10 0.10 1 04/03/19 09:22 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 28 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project. 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-12 (6-7') Lab ID: 35457287017 Collected: 03/26/19 12:08 Received: 03/27/19 17:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual FL -PRO Soil Microwave Petroleum Range Organics Surrogates o-Terphenyl (S) N-Pentatriacontane (S) 6010 MET ICP Arsenic Barium Cadmium Chromium Lead Selenium Silver 6010 MET ICP, TCLP -senic mead 7471 Mercury Mercury 8270 MSSV Short List Microwave Acenaphthene Acenaphthylene Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene Chrysene Dibenz(a.. h)anthracene Fluoranthene Fluorene Indeno(1,2,3-cd)pyrene 1-Methylnaphthalene 2-Methylnaphthalene Naphthalene Phenanthrene Pyrene Surrogates Nitrobenzene-d5 (S) Date: 04/16/2019 12:00 AM Analytical Method: FL -PRO Preparation Method: EPA 3546 436 mg/kg 6.3 4.0 1 04/04/19 14:20 04/05/19 10:48 56 59 66-136 1 04/04/19 14:20 04/05/19 10:48 84-15-1 J(S0), S8 42-159 1 04/04/19 14:20 04/05/19 10:48 630-07-09 Analytical Method: EPA6010 152 4020 18.3 78.2 4510 63.5 U 7.3 mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg Analytical Method: EPA 6010 Leachate Method/Date: EPA 0.071 U mg/L 0.34 mg/L Analytical Method: EPA 7471 Preparation Method: EPA 3050 4.2 84.7 0.42 2.1 84.7 127 2.1 2.1 42.3 0.21 1.1 42.3 63.5 1.1 5 100 5 5 100 100 5 04/02/19 14:58 04/02/19 14:58 04/02/19 14:58 04/02/19 14:58 04/02/19 14:58 04/02/19 14:58 04/02/19 14:58 04/03/19 11:36 7440-38-2 04/03/19 14:30 7440-39-3 04/03/19 11:36 7440-43-9 04/03/19 11:36 7440-47-3 04/03/19 14:30 7439-92-1 04/03/19 14:30 7782-49-2 D3 04/03/19 11:36 7440-22-4 Preparation Method: EPA 3010 1311: 04/08/19 15:46 Initial pH: 5: Final pH: 5 0.10 0.071 1 04/10/19 07:56 04/10/19 15:40 7440-38-2 0.10 0.046 1 04/10/19 07:56 04/10/19 15:40 7439-92-1 Preparation Method: EPA 7471 0.42 mg/kg 0.014 0.0068 1 04/03/19 11:41 04/03/1915:10 7439-97-6 J(M1). J(R1) Analytical Method: EPA 8270 Preparation Method: EPA 3546 0.053 0.048 0.054 0.044 0.038 0.041 0.039 0.041 0.049 0.035 0.050 0.055 0.035 0.060 0.058 0.053 0.050 0.048 69 mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg 0.16 0.15 0.16 0.15 0.15 0.15 0.15 0.15 0.15 0.15 0.15 0.17 0.15 0.18 0.18 0.16 0.15 0.15 0.053 0.048 0.054 0.044 0.038 0.041 0.039 0.041 0.049 0.035 0.050 0.055 0.035 0.060 0.058 0.053 0.050 0.048 03/30/19 09:58 03/30/19 09:58 03/30/19 09:58 03/30/19 09:58 03/30/19 09:58 03/30/19 09:58 03/30/19 09:58 03/30/19 09:58 03/30/19 09:58 03/30/19 09:58 03/30/19 09:58 03/30/19 09:58 03/30/19 09:58 03/30/19 09:58 03/30/19 09:58 03/30/19 09:58 03/30/19 09:58 03/30/19 09:58 04/01/19 20:27 04/01/19 20:27 04/01/19 20:27 04/01/19 20:27 04/01/19 20:27 04/01/19 20:27 04/01/19 20:27 04/01/19 20:27 04/01/19 20:27 04/01/19 20:27 04/01/19 20:27 04/01/19 20:27 04/01/19 20:27 04/01/19 20:27 04/01/19 20:27 04/01/19 20:27 04/01/19 20:27 04/01/19 20:27 83-32-9 208-96-8 120-12-7 56-55-3 50-32-8 205-99-2 191-24-2 207-08-9 218-01-9 53-70-3 206-44-0 86-73-7 193-39-5 90-12-0 91-57-6 91-20-3 85-01-8 129-00-0 24-98 1 03/30/19 09:58 04/01/19 20:27 4165-60-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. P1 P1 P1 P1 P1 P1 P1 P1 P1 P1 P1 P1 P1 P1 P1 P1 P1 P1 Page 29 of 97 ANALYTICAL RESULTS Project 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-12 (6-7') Lab ID: 35457287017 Collected: 03/26/19 12:08 Received: 03/27/19 17:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8270 MSSV Short List Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546 Surrogates 2-Fluorobiphenyl (S) 71 % 29-101 1 03/30/19 09:58 04/01/19 20:27 321-60-8 p-Terphenyl-d14 (S) 88 % 29-112 1 03/30/19 09:58 04/01/19 20:27 1718-51-0 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 37.3 % 0.10 0.10 1 04/03/19 09.22 Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 30 of 97 aceAnalytical wwwpacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-11 (0-0.5') Lab ID: 35457287018 Collected: 03/26/19 12:25 Received: 03/27/19 17:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 8.7 mg/kg 0.63 0.31 1 04/02/19 14:58 04/03/19 11:44 7440-38-2 Barium 8.5 mg/kg 0.63 0.31 1 04/02/19 14:58 04/03/19 11:44 7440-39-3 Lead 10.1 mg/kg 0.63 0.31 1 04/02/19 14:58 04/03/19 11:44 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 6.8 % 0.10 0.10 1 04/03/19 09:22 Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 31 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-11 (0.5-2') Lab ID: 35457287019 Collected: 03/26/19 12:27 Received: 03/27/19 17:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 8.2 mg/kg 0.52 0.26 1 04/02/19 14:58 04/03/19 11:47 7440-38-2 Barium 30.0 mg/kg 0.52 0.26 1 04/02/19 14:58 04/03/19 11:47 7440-39-3 Lead 92.9 mg/kg 0.52 0.26 1 04/02/19 14:58 04/03/19 11:47 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 12.7 % 0.10 0.10 1 04/03/19 09:23 Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 32 of 97 aceAnalytical www.pace/abs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-11 (2-4') Lab ID: 35457287020 Collected: 03/26/19 12:29 Received: 03/27/19 17:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 10.0 mg/kg 0.53 0.26 1 04/02/19 14:58 04/03/19 11:50 7440-38-2 Barium 41.0 mg/kg 0.53 0.26 1 04/02/19 14:58 04/03/19 11:50 7440-39-3 Lead 160 mg/kg 5.3 2.6 10 04/02/19 14:58 04/03/19 14:33 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 16.5 % 0.10 0.10 1 04/03/19 09:23 Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 33 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-11 (4-6') Lab ID: 35457287021 Collected: 03/26/19 12:31 Received: 03/27/19 17:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 8.2 mg/kg 0.79 0.40 1 04/02/19 14:58 04/03/19 11:53 7440-38-2 Barium 50.7 mg/kg 0.79 0.40 1 04/02/19 14:58 04/03/19 11:53 7440-39-3 Lead 64.3 mg/kg 0.79 0.40 1 04/02/19 14:58 04/03/19 11:53 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 21.5 % 0.10 0.10 1 04/03/19 09:23 Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 34 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-11 (6-8') Lab ID: 35457287022 Collected: 03/26/19 12:33 Received: 03/27/19 17:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3050 Arsenic 36.1 mg/kg 3.7 1.9 5 04/02/19 14:58 04/03/19 11:56 7440-38-2 Barium 292 mg/kg 3.7 1.9 5 04/02/19 14:58 04/03/19 11:56 7440-39-3 Lead 1850 mg/kg 74.7 37.4 100 04/02/19 14:58 04/03/19 14:44 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 04/16/2019 12:00 AM 29.8 0.10 0.10 1 04/03/19 09:23 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 35 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-10 (0-0.5') Lab ID: 35457287023 Collected: 03/26/19 13:10 Received: 03/27/19 17:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units POL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 12.6 mg/kg 0.50 0.25 1 04/02/19 14:58 04/03/19 11:59 7440-38-2 Barium 7.4 mg/kg 0.50 0.25 1 04/02/19 14:58 04/03/19 11:59 7440-39-3 Lead 7.9 mg/kg 0.50 0.25 1 04/02/19 14:58 04/03/19 11:59 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 5.9 % 0.10 0.10 1 04/03/19 09:23 Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 36 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.. 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-10 (0.5-2') Lab ID: 35457287024 Collected: 03/26/19 13:12 Received: 03/27/19 17:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 13.7 mg/kg 0.65 0.32 1 04/02/19 14:58 04/03/1912:01 7440-38-2 Barium 31.5 mg/kg 0.65 0.32 1 04/02/19 14:58 04/03/19 12:01 7440-39-3 Lead 259 mg/kg 6.5 3.2 10 04/02/19 14:58 04/03/19 14:39 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 04/16/2019 12:00 AM 10.9 0.10 0.10 1 04/03/19 09:23 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 37 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-10 (2-4') Lab ID: 35457287025 Collected: 03/26/19 13:14 Received: 03/27/19 17:40 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 0.53 I mg/kg 0.69 0.34 1 04/02/19 14:58 04/03/19 12:04 7440-38-2 Barium 12.9 mg/kg 0.69 0.34 1 04/02/19 14:58 04/03/19 12:04 7440-39-3 Lead 5.2 mg/kg 0.69 0.34 1 04/02/19 14:58 04/03/19 12:04 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 04/16/2019 12:00 AM 15.2 ok 0.10 0.10 1 04/03/19 09:23 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 38 of 97 aceAnalytical® wwwpacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 527333 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 35457287006 METHOD BLANK: 2854104 Matrix: Solid Associated Lab Samples: 35457287006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury mg/kg 0.0040 U 0.0081 0.0040 04/01/19 13:33 LABORATORY CONTROL SAMPLE: 2854105 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg 0.084 0.069 82 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2854106 2854107 MS MSD 35456180001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual lercury mg/kg 0.030 0.1 0.1 0.12 0.14 87 112 80-120 19 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 39 of 97 .a) aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 528009 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 35457287017 METHOD BLANK: 2857750 Matrix: Solid Associated Lab Samples: 35457287017 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury mg/kg 0.0045 U 0.0090 0.0045 04/03/19 15:06 LABORATORY CONTROL SAMPLE: 2857751 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg 0.079 0.081 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2857752 2857753 MS MSD 35457287017 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 0.42 0.15 0.14 0.29 0.47 -83 40 80-120 48 20 J(M1), i J(R1) Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 40 of 97 aceAnalybcal www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 527427 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 35457287006 METHOD BLANK: 2854380 Matrix: Solid Associated Lab Samples: 35457287006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic mg/kg 0.28 U 0.56 0.28 04/02/19 14:14 Barium mg/kg 0.28 U 0.56 0.28 04/02/19 14:14 Cadmium mg/kg 0.028 U 0.056 0.028 04/02/19 14:14 Chromium mg/kg 0.14 U 0.28 0.14 04/02/19 14:14 Lead mg/kg 0.28 U 0.56 0.28 04/02/19 14:14 Selenium mg/kg 0.42 U 0.84 0.42 04/02/19 14:14 Silver mg/kg 0.14 U 0.28 0.14 04/02/19 14:14 LABORATORY CONTROL SAMPLE: 2854381 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers Arsenic mg/kg 13 11.8 91 80-120 Barium mg/kg 13 12.1 93 80-120 ;admium mg/kg 1.3 1.2 95 80-120 Chromium mg/kg 13 12.8 99 80-120 Lead mg/kg 13 12.6 97 80-120 Selenium mg/kg 13 11.2 86 80-120 Silver mg/kg 1.3 1.1 82 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2854382 2854383 MS MSD 35455442001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic mg/kg 51.2 U 2680 2710 2200 2270 81 83 75-125 3 20 Barium mg/kg 110 2680 2710 2550 2610 91 92 75-125 2 20 Cadmium mg/kg 5.1 U 259 259 243 248 90 91 75-125 2 20 Chromium mg/kg 51.6 2680 2710 2530 2600 92 94 75-125 3 20 Lead mg/kg 51.2 U 2680 2710 2450 2510 91 92 75-125 2 20 Selenium mg/kg 76.8 U 2680 2710 1970 2020 73 74 75-125 2 20 J(M1) Silver mg/kg 25.6 U 259 259 210 215 78 79 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 41 of 97 P'ceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 527508 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 35457287001, 35457287002, 35457287003, 35457287004, 35457287005, 35457287007, 35457287008, 35457287009, 35457287010, 35457287011, 35457287012 METHOD BLANK: 2854912 Matrix: Solid Associated Lab Samples: 35457287001, 35457287002, 35457287003, 35457287004, 35457287005, 35457287007, 35457287008, 35457287009, 35457287010, 35457287011, 35457287012 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic mg/kg 0.28 U 0.57 0.28 04/02/19 14:52 Barium mg/kg 0.28 U 0.57 0.28 04/02/19 14:52 Lead mg/kg 0.28 U 0.57 0.28 04/02/19 14:52 LABORATORY CONTROL SAMPLE: 2854913 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic mg/kg 14.2 13.3 94 80-120 Barium mg/kg 14.2 14.2 100 80-120 Lead mg/kg 14.2 14.2 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2854914 2854915 MS MSD 35456781018 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic mg/kg 1.2 14.3 13.8 15.3 15.3 99 102 75-125 0 20 Barium mg/kg 8.9 14.3 13.8 21.3 22.3 87 97 75-125 5 20 Lead mg/kg 34.5 14.3 13.8 41.0 42.4 45 57 75-125 3 20 J(M1) Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 42 of 97 (eAnaIYllcaI www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 527795 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 35457287013, 35457287014, 35457287015, 35457287016, 35457287017, 35457287018, 35457287019, 35457287020, 35457287021, 35457287022, 35457287023, 35457287024, 35457287025 METHOD BLANK: 2856473 Matrix: Solid Associated Lab Samples: Parameter 35457287013, 35457287014, 35457287015, 35457287016, 35457287017, 35457287018, 35457287019, 35457287020, 35457287021, 35457287022, 35457287023, 35457287024, 35457287025 Blank Reporting Units Result Limit MDL Analyzed Qualifiers Arsenic mg/kg 0.24 U 0.49 0.24 04/03/19 14:10 Barium mg/kg 0.24 U 0.49 0.24 04/03/19 14:10 Cadmium mg/kg 0.024 U 0.049 0.024 04/03/19 14:10 Chromium mg/kg 0.12 U 0.24 0.12 04/03/19 14:10 Lead mg/kg 0.24 U 0.49 0.24 04/03/19 14:10 Selenium mg/kg 0.36 U 0.73 0.36 04/03/19 14:10 Silver mg/kg 0.12 U 0.24 0.12 04/03/19 14:10 LABORATORY CONTROL SAMPLE: 2856474 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers ',rsenic mg/kg 22.7 20.2 89 80-120 sarium mg/kg 22.7 20.7 91 80-120 Cadmium mg/kg 2.3 2.1 93 80-120 Chromium mg/kg 11.3 10.8 95 80-120 Lead mg/kg 22.7 21.4 94 80-120 Selenium mg/kg 34 28.8 85 80-120 Silver mg/kg 11.3 10.2 90 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2856475 2856476 MS MSD 35457287013 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic mg/kg 11.3 31.9 31.3 41.9 41.5 96 97 75-125 1 20 Barium mg/kg 10.3 31.9 31.3 39.4 37.8 91 88 75-125 4 20 Cadmium mg/kg 0.18 3.1 3.1 2.8 2.7 84 81 75-125 4 20 Chromium mg/kg 8.2 15.9 15.7 23.5 22.6 96 92 75-125 4 20 Lead mg/kg 10.8 31.9 31.3 38.1 37.0 86 84 75-125 3 20 Selenium mg/kg 0.50 U 47.7 47 41.9 40.5 87 85 75-125 4 20 Silver mg/kg 0.63 15.9 15.7 16.2 15.4 98 94 75-125 5 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 43 of 97 aceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 529740 Analysis Method: EPA 6010 QC Batch Method: EPA 3010 Analysis Description: 6010 MET TCLP Associated Lab Samples: 35457287008, 35457287009, 35457287017 METHOD BLANK: 2864758 Matrix: Water Associated Lab Samples: 35457287008, 35457287009, 35457287017 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic mg/L 0.0071 U 0.010 0.0071 04/10/19 15:09 Lead mg/L 0.0046 U 0.010 0.0046 04/10/19 15:09 LABORATORY CONTROL SAMPLE: 2868291 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic mg/L 0.25 0.25 100 80-120 Lead mg/L 0.25 0.25 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2868292 2868293 MS MSD 35456829012 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic mg/L 0.071 U 2.5 2.5 2.5 2.5 97 100 75-125 3 20 Lead mg/L 0.046 U 2.5 2.5 2.5 2.5 99 100 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 44 of 97 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 527554 Analysis Method: EPA 8260 QC Batch Method: EPA 5035 Analysis Description: 8260 MSV 5035 Associated Lab Samples: 35457287006 METHOD BLANK: 2855084 Matrix: Solid Associated Lab Samples: 35457287006 Parameter Blank Reporting Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 1,1,1-Trichloroethane mg/kg 0.0027 U 0.0050 0.0027 04/01/19 19:44 1,1,2,2-Tetrachloroethane mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 1,1,2-Trichloroethane mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 1,1-Dichloroethane mg/kg 0.0027 U 0.0050 0.0027 04/01/19 19:44 1,1-Dichloroethene mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 1,1-Dichloropropene mg/kg 0.0026 U 0.0050 0.0026 04/01/19 19:44 1,2,3-Trichlorobenzene mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 1,2,3-Trichloropropane mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 1,2,3-Trimethylbenzene mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 N2 1,2,4-Trichlorobenzene mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 1,2,4-Trimethylbenzene mg/kg 0.0028 U 0.0050 0.0028 04/01/19 19:44 1,2-Dichlorobenzene mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 1,2-Dichloroethane mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 ',2-Dichloropropane mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 1,3,5-Trimethylbenzene mg/kg 0.0029 U 0.0050 0.0029 04/01/19 19:44 1,3-Dichlorobenzene mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 1,3-Dichloropropane mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 1,4-Dichlorobenzene mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 2,2-Dichloropropane mg/kg 0.0026 U 0.0050 0.0026 04/01/19 19:44 2-Butanone (MEK) mg/kg 0.0050 U 0.010 0.0050 04/01/19 19:44 2-Chloroethylvinyl ether mg/kg 0.010 U 0.020 0.010 04/01/19 19:44 2-Chlorotoluene mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 2-Hexanone mg/kg 0.0050 U 0.010 0.0050 04/01/19 19:44 4-Chlorotoluene mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 4-Methyl-2-pentanone (MIBK) mg/kg 0.0050 U 0.010 0.0050 04/01/19 19:44 Acetone mg/kg 0.010 U 0.020 0.010 04/01/19 19:44 Acetonitrile mg/kg 0.025 U 0.050 0.025 04/01/19 19:44 Benzene mg/kg 0.0026 U 0.0050 0.0026 04/01/19 19:44 Bromobenzene mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 Bromochloromethane mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 Bromodichloromethane mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 Bromoform mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 Bromomethane mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 Carbon disulfide mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 Carbon tetrachloride mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 Chlorobenzene mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 Chloroethane mg/kg 0.0036 U 0.0050 0.0036 04/01/19 19:44 Chloroform mg/kg 0.0030 U 0.0050 0.0030 04/01/19 19:44 Chloromethane mg/kg 0.0028 U 0.0050 0.0028 04/01/19 19:44 cis-1,2-Dichloroethene mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 45 of 97 /aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 METHOD BLANK: 2855084 Matrix: Solid Associated Lab Samples: 35457287006 Parameter Blank Reporting Units Result Limit MDL Analyzed Qualifiers cis-1,3-Dichloropropene mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 Dibromochloromethane mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 Dibromomethane mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 Dichlorodifluoromethane mg/kg 0.0027 U 0.0050 0.0027 04/01/19 19:44 Ethylbenzene mg/kg 0.0028 U 0.0050 0.0028 04/01/19 19:44 lodomethane mg/kg 0.0050 U 0.010 0.0050 04/01/19 19:44 Isopropylbenzene (Cumene) mg/kg 0.0029 U 0.0050 0.0029 04/01/19 19:44 m&p-Xylene mg/kg 0.0051 U 0.010 0.0051 04/01/19 19:44 Methyl-tert-butyl ether mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 Methylene Chloride mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 n-Butylbenzene mg/kg 0.0030 U 0.0050 0.0030 04/01/19 19:44 n-Propylbenzene mg/kg 0.0026 U 0.0050 0.0026 04/01/19 19:44 o-Xylene mg/kg 0.0026 U 0.0050 0.0026 04/01/19 19:44 p-lsopropyltoluene mg/kg 0.0030 U 0.0050 0.0030 04/01/19 19:44 sec-Butylbenzene mg/kg 0.0029 U 0.0050 0.0029 04/01/19 19:44 Styrene mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 tert-Butylbenzene mg/kg 0.0029 U 0.0050 0.0029 04/01/19 19:44 Tetrachloroethene mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 Toluene mg/kg 0.0027 U 0.0050 0.0027 04/01/19 19:44 trans-1,2-Dichloroethene mg/kg 0.0030 U 0.0050 0.0030 04/01/19 19:44 trans-1,3-Dichloropropene mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 Trichloroethene mg/kg 0.0028 U 0.0050 0.0028 04/01/19 19:44 Trichlorofluoromethane mg/kg 0.0027 U 0.0050 0.0027 04/01/19 19:44 Vinyl acetate mg/kg 0.0025 U 0.0050 0.0025 04/01/19 19:44 Vinyl chloride mg/kg 0.0027 U 0.0050 0.0027 04/01/19 19:44 Xylene (Total) mg/kg 0.0051 U 0.015 0.0051 04/01/19 19:44 1,2-Dichloroethane-d4 (S) % 99 71-132 04/01/19 19:44 4-Bromofluorobenzene (S) % 99 68-125 04/01/19 19:44 Toluene-d8 (S) % 100 70-130 04/01/19 19:44 LABORATORY CONTROL SAMPLE: 2855085 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane mg/kg 0.02 0.021 106 70-130 1,1,1-Trichloroethane mg/kg 0.02 0.019 95 70-130 1,1,2,2-Tetrachloroethane mg/kg 0.02 0.021 106 70-130 1,1,2-Trichloroethane mg/kg 0.02 0.020 101 70-130 1,1-Dichloroethane mg/kg 0.02 0.020 97 70-130 1,1-Dichloroethene mg/kg 0.02 0.019 96 62-131 1,1-Dichloropropene mg/kg 0.02 0.020 98 70-130 1,2,3-Trichlorobenzene mg/kg 0.02 0.021 105 70-130 1,2,3-Trichloropropane mg/kg 0.02 0.022 107 72-137 1,2,3-Trimethylbenzene mg/kg 0.02 0.019 93 70-130 N2 1,2,4-Trichlorobenzene mg/kg 0.02 0.020 101 70-130 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 46 of 97 /eAnaIyticaI www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE: 2855085 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,2,4-Trimethylbenzene mg/kg 0.02 0.019 96 70-130 1,2-Dichlorobenzene mg/kg 0.02 0.020 98 70-130 1,2-Dichloroethane mg/kg 0.02 0.020 98 70-130 1,2-Dichloropropane mg/kg 0.02 0.020 99 70-130 1,3,5-Trimethylbenzene mg/kg 0.02 0.020 97 70-130 1,3-Dichlorobenzene mg/kg 0.02 0.019 96 70-130 1,3-Dichloropropane mg/kg 0.02 0.020 101 70-130 1,4-Dichlorobenzene mg/kg 0.02 0.020 98 70-130 2,2-Dichloropropane mg/kg 0.02 0.019 94 70-130 2-Butanone (MEK) mg/kg 0.04 0.045 110 64-121 2-Chloroethylvinyl ether mg/kg 0.02 0.022 107 20-150 2-Chlorotoluene mg/kg 0.02 0.019 95 70-130 2-Hexanone mg/kg 0.04 0.044 109 59-137 4-Chlorotoluene mg/kg 0.02 0.019 95 70-130 4-Methyl-2-pentanone (MIBK) mg/kg 0.04 0.043 107 70-130 Acetone mg/kg 0.04 0.046 114 68-146 Acetonitrile mg/kg 0.2 0.21 105 68-131 Benzene mg/kg 0.02 0.019 95 70-130 Bromobenzene mg/kg 0.02 0.020 99 70-130 Rromochloromethane mg/kg 0.02 0.020 99 70-130 ,romodichloromethane mg/kg 0.02 0.020 99 70-130 Bromoform mg/kg 0.02 0.019 92 54-129 Bromomethane mg/kg 0.02 0.020 99 58-144 Carbon disulfide mg/kg 0.02 0.021 103 57-133 Carbon tetrachloride mg/kg 0.02 0.019 95 63-137 Chlorobenzene mg/kg 0.02 0.019 96 70-130 Chloroethane mg/kg 0.02 0.022 107 40-165 Chloroform mg/kg 0.02 0.019 96 70-130 Chloromethane mg/kg 0.02 0.022 111 64-127 cis-1,2-Dichloroethene mg/kg 0.02 0.020 98 70-130 cis-1,3-Dichloropropene mg/kg 0.02 0.020 100 70-130 Dibromochloromethane mg/kg 0.02 0.020 100 70-130 Dibromomethane mg/kg 0.02 0.021 101 70-130 Dichlorodifluoromethane mg/kg 0.02 0.022 107 51-143 Ethylbenzene mg/kg 0.02 0.019 96 70-130 lodomethane mg/kg 0.04 0.042 103 58-137 Isopropylbenzene (Cumene) mg/kg 0.02 0.020 97 70-130 m&p-Xylene mg/kg 0.04 0.039 97 70-130 Methyl-tert-butyl ether mg/kg 0.02 0.021 103 65-124 Methylene Chloride mg/kg 0.02 0.021 103 51-142 n-Butylbenzene mg/kg 0.02 0.019 96 70-130 n-Propylbenzene mg/kg 0.02 0.019 95 70-130 o-Xylene mg/kg 0.02 0.020 97 70-130 p-Isopropyltoluene mg/kg 0.02 0.019 95 70-130 sec-Butylbenzene mg/kg 0.02 0.020 97 70-130 Styrene mg/kg 0.02 0.019 96 70-130 tert-Butylbenzene mg/kg 0.02 0.020 97 70-130 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 47 of 97 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE: 2855085 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers Tetrachloroethene mg/kg 0.02 0.020 101 70-130 Toluene mg/kg 0.02 0.019 96 70-130 trans-1,2-Dichloroethene mg/kg 0.02 0.019 95 70-130 trans-1,3-Dichloropropene mg/kg 0.02 0.021 103 70-130 Trichloroethene mg/kg 0.02 0.019 94 70-130 Trichlorofluoromethane mg/kg 0.02 0.020 99 60-148 Vinyl acetate mg/kg 0.02 0.023 112 70-130 Vinyl chloride mg/kg 0.02 0.019 94 69-124 Xylene (Total) mg/kg 0.061 0.059 97 70-130 1,2-Dichloroethane-d4 (S) % 102 71-132 4-Bromofluorobenzene (S) % 100 68-125 Toluene-d8 (S) % 100 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2855088 2855089 MS MSD 35457357001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1.1,1,2-Tetrachloroethane mg/kg 2.0 U 0.016 0.014 0.0086 0.0082 55 59 70-130 5 40 J(M1) ug/kg 1,1,1-Trichloroethane mg/kg 2.2 U 0.016 0.014 0.013 0.011 83 82 70-130 14 40 ug/kg 1,1,2,2-Tetrachloroethane mg/kg 2.0 U 0.016 0.014 0.013 0.011 85 82 70-130 16 40 ug/kg 1,1,2-Trichloroethane mg/kg 2.0 U 0.016 0.014 0.013 0.011 83 83 70-130 13 40 ug/kg 1,1-Dichloroethane mg/kg 2.1 U 0.016 0.014 0.014 0.012 92 89 70-130 16 40 ug/kg 1.1-Dichloroethene mg/kg 2.0 U 0.016 0.014 0.015 0.013 96 93 62-131 15 40 ug/kg 1,1-Dichloropropene mg/kg 2.0 U 0.016 0.014 0.0099 0.0091 63 66 70-130 8 40 J(M1) ug/kg 1,2,3-Trichlorobenzene mg/kg 2.0 U 0.016 0.014 0.0037 I 0.0040 24 29 70-130 40 J(M1) ug/kg 1,2,3-Trichloropropane mg/kg 2.0 U 0.016 0.014 0.014 0.011 88 82 72-137 20 40 ug/kg 1,2,3-Trimethylbenzene mg/kg 2.0 U 0.016 0.014 0.0033 I 0.0028 I 21 20 70-130 40 J(M1), ug/kg N2 1.2,4-Trichlorobenzene mg/kg 2.0 U 0.016 0.014 0.0033 I 0.0033 I 21 24 70-130 40 J(M1) ug/kg 1,2,4-Trimethylbenzene mg/kg 2.2 U 0.016 0.014 0.0022 0.0020 I 11 14 70-130 40 J(M1) ug/kg U 1,2-Dichlorobenzene mg/kg 2.0 U 0.016 0.014 0.0040 0.0038 25 28 70-130 3 40 J(M1) ug/kg 1,2-Dichloroethane mg/kg 2.0 U 0.016 0.014 0.014 0.012 89 84 70-130 18 40 ug/kg 1,2-Dichloropropane mg/kg 2.0 U 0.016 0.014 0.012 0.011 79 79 70-130 14 40 ug/kg 1,3,5-Trimethylbenzene mg/kg 2.3 U 0.016 0.014 0.0023 0.0023 I 13 17 70-130 40 J(M1) ug/kg U Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 48 of 97 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2855088 2855089 MS MSD 35457357001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,3-Dichlorobenzene mg/kg 2.0 U 0.016 0.014 0.0038 I 0.0034 I 24 25 70-130 40 J(M1) ug/kg 1,3-Dichloropropane mg/kg 2.0 U 0.016 0.014 0.013 0.011 82 82 70-130 12 40 ug/kg 1.4-Dichlorobenzene mg/kg 2.0 U 0.016 0.014 0.0039 0.0036 25 26 70-130 11 40 J(M1) ug/kg 2,2-Dichloropropane mg/kg 2.0 U 0.016 0.014 0.014 0.011 88 83 70-130 19 40 ug/kg 2-Butanone (MEK) mg/kg 3.9 U 0.031 0.028 0.028 0.023 88 82 64-121 20 40 ug/kg 2-Chloroethylvinyl ether mg/kg 7.8 U 0.016 0.014 0.012 I 0.013 I 74 93 20-150 40 ug/kg 2-Chlorotoluene mg/kg 2.0 U 0.016 0.014 0.0029 I 0.0030 I 19 22 70-130 40 J(M1) ug/kg 2-Hexanone mg/kg 3.9 U 0.031 0.028 0.017 0.021 54 77 59-137 22 40 J(M1) ug/kg 4-Chlorotoluene mg/kg 2.0 U 0.016 0.014 0.0027 I 0.0028 I 17 20 70-130 40 J(M1) ug/kg 4-Methyl-2-pentanone mg/kg 3.9 U 0.031 0.028 0.024 0.025 77 90 70-130 3 40 (MIBK) ug/kg Acetone mg/kg 9.5 I 0.031 0.028 0.036 0.031 84 77 68-146 15 40 ug/kg cetonitrile mg/kg 19.6 U 0.16 0.14 0.12 0.12 74 87 68-131 3 40 ug/kg Benzene mg/kg 0.0020 U 0.016 0.014 0.011 0.0098 69 71 70-130 9 40 J(M1) Bromobenzene mg/kg 2.0 U 0.016 0.014 0.0052 0.0049 33 36 70-130 5 40 J(M1) ug/kg Bromochloromethane mg/kg 2.0 U 0.016 0.014 0.014 0.012 91 88 70-130 16 40 ug/kg Bromodichloromethane mg/kg 2.0 U 0.016 0.014 0.012 0.010 75 76 70-130 12 40 ug/kg Bromoform mg/kg 2.0 U 0.016 0.014 0.0086 0.0081 55 58 54-129 6 40 ug/kg Bromomethane mg/kg 2.0 U 0.016 0.014 0.014 0.013 88 92 58-144 9 40 ug/kg Carbon disulfide mg/kg 2.0 U 0.016 0.014 0.013 0.012 80 84 57-133 8 40 ug/kg Carbon tetrachloride mg/kg 2.0 U 0.016 0.014 0.011 0.010 72 73 63-137 11 40 ug/kg Chlorobenzene mg/kg 2.0 U 0.016 0.014 0.0057 0.0054 36 39 70-130 5 40 J(M1) ug/kg Chloroethane mg/kg 2.8 U 0.016 0.014 0.018 0.015 117 105 40-165 23 40 ug/kg Chloroform mg/kg 2.3 U 0.016 0.014 0.013 0.011 83 83 70-130 13 40 ug/kg Chloromethane mg/kg 2.2 U 0.016 0.014 0.017 0.015 108 106 64-127 14 40 ug/kg cis-1,2-Dichloroethene mg/kg 2.0 U 0.016 0.014 0.013 0.011 81 81 70-130 13 40 ug/kg cis-1,3-Dichloropropene mg/kg 2.0 U 0.016 0.014 0.0093 0.0090 59 65 70-130 4 40 J(M1) ug/kg Dibromochloromethane mg/kg 2.0 U 0.016 0.014 0.011 0.010 68 73 70-130 6 40 J(M1) ug/kg Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 49 of 97 aceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2855088 2855089 MS MSD 35457357001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Dibromomethane mg/kg 2.0 U 0.016 0.014 0.014 0.012 89 87 70-130 15 40 ug/kg Dichlorodifluoromethane mg/kg 2.1 U 0.016 0.014 0.017 0.015 112 112 51-143 12 40 ug/kg Ethylbenzene mg/kg 0.0022 U 0.016 0.014 0.0037 I 0.0042 24 30 70-130 40 J(M1) lodomethane mg/kg 3.9 U 0.031 0.028 0.030 0.028 95 102 58-137 5 40 ug/kg Isopropylbenzene (Cumene) mg/kg 2.3 U 0.016 0.014 0.0027 I 0.0031 I 17 22 70-130 40 J(M1) ug/kg m&p-Xylene mg/kg 4.0 U 0.031 0.028 0.0058 I 0.0067 I 19 24 70-130 40 J(M1) ug/kg Methyl-tert-butyl ether mg/kg 0.0020 U 0.016 0.014 0.017 0.014 106 100 65-124 19 40 Methylene Chloride mg/kg 2.0 U 0.016 0.014 0.015 0.012 94 84 51-142 24 40 ug/kg n-Butylbenzene mg/kg 2.4 U 0.016 0.014 0.0024 0.0021 7 9 70-130 40 J(M1) ug/kg U U n-Propylbenzene mg/kg 2.1 U 0.016 0.014 0.0021 0.0023 I 13 17 70-130 40 J(M1) ug/kg U o-Xylene mg/kg 2.0 U 0.016 0.014 0.0039 I 0.0041 25 30 70-130 40 J(M1) ug/kg p-Isopropyltoluene mg/kg 2.4 U 0.016 0.014 0.0024 0.0021 10 12 70-130 40 J(M1) ug/kg U U sec-Butylbenzene mg/kg 2.3 U 0.016 0.014 0.0023 0.0020 I 11 15 70-130 40 J(M1) ug/kg U Styrene mg/kg 2.0 U 0.016 0.014 0.0036 I 0.0037 23 27 70-130 40 J(M1) ug/kg tert-Butylbenzene mg/kg 2.3 U 0.016 0.014 0.0027 I 0.0026 I 17 19 70-130 40 J(M1) ug/kg Tetrachloroethene mg/kg 2.0 U 0.016 0.014 0.0063 0.0081 40 59 70-130 24 40 J(M1) ug/kg Toluene mg/kg 0.0021 U 0.016 0.014 0.0068 0.0067 43 48 70-130 2 40 J(M1) trans-1,2-Dichloroethene mg/kg 2.4 U 0.016 0.014 0.012 0.010 77 74 70-130 17 40 ug/kg trans-1,3-Dichloropropene mg/kg 2.0 U 0.016 0.014 0.0095 0.0093 61 67 70-130 2 40 J(M1) ug/kg Trichloroethene mg/kg 2.2 U 0.016 0.014 0.0086 0.0085 55 61 70-130 2 40 J(M1) ug/kg Trichlorofluoromethane mg/kg 2.1 U 0.016 0.014 0.016 0.014 101 101 60-148 13 40 ug/kg Vinyl acetate mg/kg 2.0 U 0.016 0.014 0.0055 0.0046 35 33 70-130 17 40 J(M1) ug/kg Vinyl chloride mg/kg 2.1 U 0.016 0.014 0.015 0.013 93 91 69-124 14 40 ug/kg Xylene (Total) mg/kg 0.0040 U 0.047 0.042 0.0040 0.0041 I 0 10 70-130 40 MS U 1,2-Dichloroethane-d4 (S) % 101 100 71-132 40 4-Bromofluorobenzene (S) % 95 99 68-125 40 Toluene-d8 (S) % 99 100 70-130 40 Results presented on this page are in the units indicated by the "Units' column except where an altemate unit is presented to the right of the result. Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 50 of 97 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 527236 Analysis Method: EPA 8081 QC Batch Method: EPA 3546 Analysis Description: 8081 GCS Pesticides Associated Lab Samples: 35457287006 METHOD BLANK: 2853478 Matrix: Solid Associated Lab Samples: 35457287006 Parameter Blank Reporting Units Result Limit MDL Analyzed Qualifiers 4,4'-DDD mg/kg 0.00013 U 0.0017 0.00013 04/01/19 23:16 4,4'-DDE mg/kg 0.000061 U 0.0017 0.000061 04/01/19 23:16 4,4'-DDT mg/kg 0.000095 U 0.0017 0.000095 04/01/19 23:16 Aldrin mg/kg 0.000058 U 0.0017 0.000058 04/01/19 23:16 alpha-BHC mg/kg 0.000069 U 0.0017 0.000069 04/01/19 23:16 beta-BHC mg/kg 0.000077 U 0.0017 0.000077 04/01/19 23:16 Chlordane (Technical) mg/kg 0.016 U 0.017 0.016 04/01/19 23:16 delta-BHC mg/kg 0.000087 U 0.0017 0.000087 04/01/19 23:16 Dieldrin mg/kg 0.000040 U 0.0017 0.000040 04/01/19 23:16 Endosulfan I mg/kg 0.000025 U 0.0017 0.000025 04/01/19 23:16 Endosulfan II mg/kg 0.000057 U 0.0017 0.000057 04/01/19 23:16 Endosulfan sulfate mg/kg 0.000043 U 0.0017 0.000043 04/01/19 23:16 Endrin mg/kg 0.000052 U 0.0017 0.000052 04/01/19 23:16 Endrin aldehyde mg/kg 0.000066 U 0.0033 0.000066 04/01/19 23:16 -ndrin ketone mg/kg 0.000080 U 0.0017 0.000080 04/01/19 23:16 jamma-BHC (Lindane) mg/kg 0.00015 U 0.0017 0.00015 04/01/19 23:16 Heptachlor mg/kg 0.000039 U 0.0017 0.000039 04/01/19 23:16 Heptachlor epoxide mg/kg 0.00011 U 0.0017 0.00011 04/01/19 23:16 Methoxychlor mg/kg 0.0010 U 0.0017 0.0010 04/01/19 23:16 Toxaphene mg/kg 0.0073 U 0.017 0.0073 04/01/1923:16 Decachlorobiphenyl (S) % 108 43-157 04/01/19 23:16 Tetrachloro-m-xylene (S) % 90 53-140 04/01/19 23:16 LABORATORY CONTROL SAMPLE: 2853479 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 4,4'-DDD mg/kg 0.017 0.017 100 71-137 4,4'-DDE mg/kg 0.017 0.018 108 71-136 4,4'-DDT mg/kg 0.017 0.020 118 62-140 Aldrin mg/kg 0.017 0.018 107 67-128 alpha-BHC mg/kg 0.017 0.018 109 68-130 beta-BHC mg/kg 0.017 0.017 104 70-130 delta-BHC mg/kg 0.017 0.012 72 45-123 Dieldrin mg/kg 0.017 0.018 107 72-132 Endosulfan I mg/kg 0.017 0.018 108 72-130 Endosulfan II mg/kg 0.017 0.016 97 72-132 Endosulfan sulfate mg/kg 0.017 0.017 100 68-130 Endrin mg/kg 0.017 0.018 107 70-135 Endrin aldehyde mg/kg 0.017 0.013 77 59-131 Endrin ketone mg/kg 0.017 0.017 101 69-135 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 51 of 97 Pace Analytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE: 2853479 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers gamma-BHC (Lindane) mg/kg 0.017 0.018 110 69-132 Heptachlor mg/kg 0.017 0.019 113 68-131 Heptachlor epoxide mg/kg 0.017 0.018 109 69-130 Methoxychlor mg/kg 0.017 0.018 108 64-139 Decachlorobiphenyl (S) % 90 43-157 Tetrachloro-m-xylene (S) % 90 53-140 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2853480 2853481 MS MSD 35456275001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 4,4'-DDD mg/kg 0.00015 0.019 0.12 0.025 0.14 133 112 71-137 140 40 J(R1) U 4,4'-DDE mg/kg 0.0023 0.019 0.12 0.023 0.14 108 112 71-136 146 40 J(R1) 4,4'-DDT mg/kg 0.0024 0.019 0.12 0.025 0.17 120 132 62-140 149 40 J(R1) Aldrin mg/kg 0.0069 0.019 0.12 0.026 0.15 103 116 67-128 142 40 J(R1) alpha-BHC mg/kg 0.000078 0.019 0.12 0.018 0.14 95 108 68-130 154 40 J(R1) U beta-BHC mg/kg 0.000087 0.019 0.12 0.017 0.13 91 104 70-130 154 40 J(R1) U delta-BHC mg/kg 0.000098 0.019 0.12 0.012 0.097 65 76 45-123 155 40 J(R1) U Dieldrin mg/kg 0.052 0.019 0.12 0.081 0.20 155 115 72-132 84 40 J(M1), J(R1) Endosulfan I mg/kg 0.000028 0.019 0.12 0.018 0.14 98 109 72-130 153 40 J(R1) U Endosulfan II mg/kg 0.000064 0.019 0.12 0.017 0.13 91 103 72-132 154 40 J(R1) U Endosulfan sulfate mg/kg 0.000048 0.019 0.12 0.018 0.14 96 112 68-130 155 40 J(R1) U Endrin mg/kg 0.000059 0.019 0.12 0.025 0.14 136 114 70-135 140 40 J(M1), U J(R1) Endrin aldehyde mg/kg 0.000074 0.019 0.12 0.012 0.12 65 95 59-131 164 40 J(R1) U Endrin ketone mg/kg 0.00092 I 0.019 0.12 0.019 0.14 96 107 69-135 151 40 J(R1) gamma-BHC (Lindane) mg/kg 0.00017 0.019 0.12 0.019 0.14 99 108 69-132 152 40 J(R1) U Heptachlor mg/kg 0.000044 0.019 0.12 0.018 0.14 97 110 68-131 154 40 J(R1) U Heptachlor epoxide mg/kg 0.0025 0.019 0.12 0.020 0.14 95 110 69-130 150 40 J(R1) Methoxychlor mg/kg 0.0012 U 0.019 0.12 0.023 0.16 122 127 64-139 150 40 J(R1) Decachlorobiphenyl (S) % 92 99 43-157 Tetrachloro-m-xylene (S) % 75 84 53-140 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 52 of 97 aceAnalytical® www.pacelabscom QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 527237 Analysis Method: EPA 8270 QC Batch Method: EPA 3546 Analysis Description: 8270 Solid MSSV Microwave Short Spike Associated Lab Samples: 35457287006, 35457287017 METHOD BLANK: 2853482 Matrix: Solid Associated Lab Samples: 35457287006, 35457287017 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1-Methylnaphthalene mg/kg 0.013 U 0.039 0.013 04/01/19 17:58 2-Methylnaphthalene mg/kg 0.013 U 0.038 0.013 04/01/19 17:58 Acenaphthene mg/kg 0.012 U 0.035 0.012 04/01/19 17:58 Acenaphthylene mg/kg 0.010 U 0.034 0.010 04/01/19 17:58 Anthracene mg/kg 0.012 U 0.035 0.012 04/01/19 17:58 Benzo(a)anthracene mg/kg 0.0095 U 0.034 0.0095 04/01/19 17:58 Benzo(a)pyrene mg/kg 0.0083 U 0.034 0.0083 04/01/19 17:58 Benzo(b)fluoranthene mg/kg 0.0089 U 0.034 0.0089 04/01/19 17:58 Benzo(g,h,i)perylene mg/kg 0.0084 U 0.034 0.0084 04/01/19 17:58 Benzo(k)fluoranthene mg/kg 0.0089 U 0.034 0.0089 04/01/19 17:58 Chrysene mg/kg 0.011 U 0.034 0.011 04/01/19 17:58 Dibenz(a,h)anthracene mg/kg 0.0077 U 0.034 0.0077 04/01/19 17:58 Fluoranthene mg/kg 0.011 U 0.034 0.011 04/01/19 17:58 Fluorene mg/kg 0.012 U 0.036 0.012 04/01/19 17:58 ideno(1,2,3-cd)pyrene mg/kg 0.0076 U 0.034 0.0076 04/01/19 17:58 ,Japhthalene mg/kg 0.011 U 0.034 0.011 04/01/19 17:58 Phenanthrene mg/kg 0.011 U 0.034 0.011 04/01/19 17:58 Pyrene mg/kg 0.011 U 0.034 0.011 04/01/19 17:58 2-Fluorobiphenyl (S) % 80 29-101 04/01/19 17:58 Nitrobenzene-d5 (S) % 83 24-98 04/01/19 17:58 p-Terphenyl-d14 (S) % 94 29-112 04/01/19 17:58 LABORATORY CONTROL SAMPLE: 2853483 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1-Methylnaphthalene mg/kg 1.7 1.3 77 38-115 2-Methylnaphthalene mg/kg 1.7 1.2 72 37-115 Acenaphthene mg/kg 1.7 1.2 73 30-127 Acenaphthylene mg/kg 1.7 1.3 79 29-129 Anthracene mg/kg 1.7 1.3 81 37-126 Benzo(a)anthracene mg/kg 1.7 1.6 96 37-130 Benzo(a)pyrene mg/kg 1.7 1.4 84 39-128 Benzo(b)fluoranthene mg/kg 1.7 1.4 82 38-128 Benzo(g,h,i)perylene mg/kg 1.7 1.3 80 34-136 Benzo(k)fluoranthene mg/kg 1.7 1.4 83 39-133 Chrysene mg/kg 1.7 1.6 97 39-125 Dibenz(a,h)anthracene mg/kg 1.7 1.3 80 37-127 Fluoranthene mg/kg 1.7 1.5 89 39-130 Fluorene mg/kg 1.7 1.3 78 35-125 Indeno(1,2,3-cd)pyrene mg/kg 1.7 1.4 84 35-133 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 53 of 97 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE: 2853483 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Naphthalene mg/kg 1.7 1.2 75 36-115 Phenanthrene mg/kg 1.7 1.4 82 35-128 Pyrene mg/kg 1.7 1.5 93 37-132 2-Fluorobiphenyl (S) % 71 29-101 Nitrobenzene-d5 (S) % 72 24-98 p-Terphenyl-d14 (S) % 86 29-112 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2853510 2853511 MS MSD 35457602007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1-Methylnaphthalene mg/kg 0.017 U 2.2 2.2 1.5 1.7 70 80 38-115 14 40 2-Methylnaphthalene mg/kg 0.017 U 2.2 2.2 1.4 1.6 66 74 37-115 13 40 Acenaphthene mg/kg 0.021 I 2.2 2.2 1.4 1.8 66 82 30-127 21 40 Acenaphthylene mg/kg 0.017 I 2.2 2.2 1.6 1.8 72 83 29-129 14 40 Anthracene mg/kg 0.066 2.2 2.2 1.6 2.1 73 93 37-126 24 40 Benzo(a)anthracene mg/kg 0.71 2.2 2.2 2.6 5.7 88 229 37-130 74 40 J(M1), J(R1) Benzo(a)pyrene mg/kg 0.76 2.2 2.2 2.5 5.4 80 213 39-128 74 40 J(M1), J(R1) Benzo(b)fluoranthene mg/kg 1.4 2.2 2.2 3.1 7.7 81 294 38-128 85 40 J(M1), J(R1) Benzo(g,h,i)perylene mg/kg 0.47 2.2 2.2 1.9 3.0 66 119 34-136 47 40 J(R1) Benzo(k)fluoranthene mg/kg 0.54 2.2 2.2 2.2 4.5 79 182 39-133 67 40 J(M1), J(R1) Chrysene mg/kg 1.1 2.2 2.2 3.0 7.2 92 286 39-125 82 40 J(M1), J(R1) Dibenz(a,h)anthracene mg/kg 0.14 2.2 2.2 1.5 1.9 64 82 37-127 23 40 Fluoranthene mg/kg 1.6 2.2 2.2 3.6 11.6 96 464 39-130 104 40 J(M1), J(R1) Fluorene mg/kg 0.025 I 2.2 2.2 1.5 1.9 70 86 35-125 21 40 Indeno(1,2,3-cd)pyrene mg/kg 0.45 2.2 2.2 1.9 3.2 70 126 35-133 48 40 J(R1) Naphthalene mg/kg 0.015 U 2.2 2.2 1.4 1.6 65 75 36-115 14 40 Phenanthrene mg/kg 0.61 2.2 2.2 2.4 6.1 83 255 35-128 88 40 J(M1), J(R1) Pyrene mg/kg 1.3 2.2 2.2 3.3 9.2 92 365 37-132 95 40 J(M1), J(R1) 2-Fluorobiphenyl (S) % 65 72 29-101 Nitrobenzene-d5 (S) % 62 70 24-98 p-Terphenyl-d14 (S) % 73 78 29-112 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 54 of 97 2ceAnalytical® wwwpacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 527633 Analysis Method: FL -PRO QC Batch Method: EPA 3546 Analysis Description: FL -PRO Soil Associated Lab Samples: 35457287006 METHOD BLANK: 2855552 Matrix: Solid Associated Lab Samples: 35457287006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Petroleum Range Organics N-Pentatriacontane (S) o-Terphenyl (S) ok mg/kg 2.6 U 4.0 2.6 04/02/19 08:47 94 42-159 04/02/19 08:47 98 66-136 04/02/19 08:47 LABORATORY CONTROL SAMPLE: 2855553 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Petroleum Range Organics mg/kg 200 170 85 65-119 N-Pentatriacontane (S) % 88 42-159 o-Terphenyl (S) % 93 66-136 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2855582 2855583 MS MSD 35457687003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Petroleum Range Organics mg/kg 5.8 241 239 225 209 91 85 39-181 7 25 N-Pentatriacontane (S) % 92 96 42-159 o-Terphenyl (S) % 101 97 66-136 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 55 of 97 /1eAnaIy1icaI www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 528316 Analysis Method: FL -PRO QC Batch Method: EPA 3546 Analysis Description: FL -PRO Soil Associated Lab Samples: 35457287017 METHOD BLANK: 2859584 Matrix: Solid Associated Lab Samples: 35457287017 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Petroleum Range Organics N-Pentatriacontane (S) o-Terphenyl (S) 0/0 mg/kg 2.6 U 4.0 2.6 04/04/19 21:44 89 42-159 04/04/19 21:44 92 66-136 04/04/19 21:44 LABORATORY CONTROL SAMPLE: 2859585 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Petroleum Range Organics mg/kg 201 177 88 65-119 N-Pentatriacontane (S) % 94 42-159 o-Terphenyl (S) % 87 66-136 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2859624 2859625 MS MSD 35458751003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Petroleum Range Organics mg/kg 273 219 212 542 497 113 95 39-181 9 25 D4 N-Pentatriacontane (S) % 89 85 42-159 o-Terphenyl (S) % 87 86 66-136 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 56 of 97 /1%eAnalytical® www.pacefabscom QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 527713 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 35457287006 SAMPLE DUPLICATE: 2855916 35457506001 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture % 11.3 10.1 11 10 J(D6) SAMPLE DUPLICATE: 2855924 35457295010 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture Ok 12.6 11.2 12 10 J(D6) SAMPLE DUPLICATE: 2855925 35457958004 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture % 8.8 5.3 49 10 J(D6) ,AMPLE DUPLICATE: 2855926 35458020004 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture % 18.9 17.4 8 10 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 57 of 97 (_/ aceAnalytical wwwpacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 528020 QC Batch Method: ASTM D2974-87 Associated Lab Samples: 35457287001,35457287002, 35457287009,35457287010, 35457287016,35457287017, 35457287023,35457287024, Analysis Method: Analysis Description: 35457287003,35457287004, 35457287011,35457287012, 35457287018,35457287019, 35457287025 ASTM D2974-87 Dry Weight/Percent Moisture 35457287005, 35457287007, 35457287008, 35457287013, 35457287014, 35457287015, 35457287020, 35457287021, 35457287022, SAMPLE DUPLICATE: 2857796 Parameter Units 35457029001 Result Dup Result RPD Max RPD Qualifiers Percent Moisture Ok 11.3 11.4 1 10 SAMPLE DUPLICATE: 2857797 Parameter Units 35457029014 Result Dup Result RPD Max RPD Qualifiers Percent Moisture 1.4 1.6 10 10 SAMPLE DUPLICATE: 2857798 Parameter Units 35457287009 Result Dup Result RPD Max RPD Qualifiers Percent Moisture 38.2 50.8 28 10 J(D6) SAMPLE DUPLICATE: 2857799 Parameter Units 35457287018 Result Dup Result RPD Max RPD Qualifiers Percent Moisture 0/0 6.8 7.2 5 10 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 58 of 97 /1 aceAnalytical www.pacelabs.com QUALIFIERS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach SAMPLE QUALIFIERS Sample: 35457287008 [1] Insufficient sample received from client to perform the analysis per EPA method requirements. Sample: 35457287017 [1] Insufficient sample received from client to perform the analysis per EPA method requirements. ANALYTE QUALIFIERS The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. U Compound was analyzed for but not detected. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D4 Sample was diluted due to the presence of high levels of target analytes. J(D6) Estimated Value. The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. J(M1) Estimated Value. Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. J(R1) Estimated Value. RPD value was outside control limits. J(SO) Estimated Value. Surrogate recovery outside laboratory control limits. MS Analyte recovery in the matrix spike was outside QC limits for one or more of the constituent analytes used in the calculated result. Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 59 of 97 www..pacelabs.com QUALIFIERS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 ANALYTE QUALIFIERS N2 The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A complete list of accreditations/certifications is available upon request. P1 Routine initial sample volume or weight was not used for extraction, resulting in elevated reporting limits. S8 Surrogate recovery outside laboratory control limits due to matrix interferences (confirmed by similar results from sample re -extraction and/or re -analysis) Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 60 of 97 aceAnalytical® www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 35457287006 SB-9 (2-4') EPA 3546 527236 EPA 8081 527486 35457287006 SB-9 (2-4') EPA 3546 527633 FL -PRO 527653 35457287017 SB-12 (6-7') EPA 3546 528316 FL -PRO 528591 35457287001 SB-6 (0-0.5') EPA 3050 527508 EPA 6010 527614 35457287002 SB-6 (0.5-2") EPA 3050 527508 EPA 6010 527614 35457287003 SB-6 (2-4') EPA 3050 527508 EPA 6010 527614 35457287004 SB-9 (0-0.5') EPA 3050 527508 EPA 6010 527614 35457287005 SB-9 (0.5-2') EPA 3050 527508 EPA 6010 527614 35457287006 SB-9 (2-4') EPA 3050 527427 EPA 6010 527590 35457287007 SB-7 (0-0.5') EPA 3050 527508 EPA 6010 527614 35457287008 SB-7 (0.5-2') EPA 3050 527508 EPA 6010 527614 35457287009 SB-7 (2-4') EPA 3050 527508 EPA 6010 527614 35457287010 SB-8 (0-0.5') EPA 3050 527508 EPA 6010 527614 35457287011 SB-8 (0.5-2') EPA 3050 527508 EPA 6010 527614 35457287012 SB-8 (2-4') EPA 3050 527508 EPA 6010 527614 35457287013 SB-12 (0-0.5') EPA 3050 527795 EPA 6010 527911 35457287014 SB-12 (0.5-2') EPA 3050 527795 EPA 6010 527911 35457287015 SB-12 (2-4') EPA 3050 527795 EPA 6010 527911 ,5457287016 SB-12 (4-6') EPA 3050 527795 EPA 6010 527911 35457287017 SB-12 (6-7') EPA 3050 527795 EPA 6010 527911 35457287018 SB-11 (0-0.5') EPA 3050 527795 EPA 6010 527911 35457287019 SB-11 (0.5-2') EPA 3050 527795 EPA 6010 527911 35457287020 SB-11 (2-4') EPA 3050 527795 EPA 6010 527911 35457287021 SB-11 (4-6') EPA 3050 527795 EPA 6010 527911 35457287022 SB-11 (6-8') EPA 3050 527795 EPA 6010 527911 35457287023 SB-10 (0-0.5') EPA 3050 527795 EPA 6010 527911 35457287024 SB-10 (0.5-2') EPA 3050 527795 EPA 6010 527911 35457287025 SB-10 (2-4') EPA 3050 527795 EPA 6010 527911 35457287008 SB-7 (0.5-2') EPA 3010 529740 EPA 6010 529907 35457287009 SB-7 (2-4') EPA 3010 529740 EPA 6010 529907 35457287017 SB-12 (6-7') EPA 3010 529740 EPA 6010 529907 35457287006 SB-9 (2-4') EPA 7471 527333 EPA 7471 527354 35457287017 SB-12 (6-7') EPA 7471 528009 EPA 7471 528144 35457287006 SB-9 (2-4') EPA 3546 527237 EPA 8270 527572 35457287017 SB-12 (6-7') EPA 3546 527237 EPA 8270 527572 35457287006 SB-9 (2-4') EPA 5035 527554 EPA 8260 527582 35457287001 SB-6 (0-0.5') ASTM D2974-87 528020 35457287002 SB-6 (0.5-2") ASTM D2974-87 528020 35457287003 SB-6 (2-4') ASTM D2974-87 528020 35457287004 SB-9 (0-0.5') ASTM D2974-87 528020 35457287005 SB-9 (0.5-2') ASTM D2974-87 528020 35457287006 SB-9 (2-4') ASTM D2974-87 527713 Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 61 of 97 aceAnalytical® www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457287 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID QC Batch Method Analytical QC Batch Analytical Method Batch 35457287007 SB-7 (0-0.5') ASTM D2974-87 528020 35457287008 SB-7 (0.5-2') ASTM D2974-87 528020 35457287009 SB-7 (2-4') ASTM D2974-87 528020 35457287010 SB-8 (0-0.5') ASTM D2974-87 528020 35457287011 SB-8 (0.5-2') ASTM D2974-87 528020 35457287012 SB-8 (2-4') ASTM D2974-87 528020 35457287013 SB-12 (0-0.5') ASTM D2974-87 528020 35457287014 SB-12 (0.5-2') ASTM D2974-87 528020 35457287015 SB-12 (2-4') ASTM D2974-87 528020 35457287016 SB-12 (4-6') ASTM D2974-87 528020 35457287017 SB-12 (6-7') ASTM D2974-87 528020 35457287018 SB-11 (0-0.5') ASTM D2974-87 528020 35457287019 SB-11 (0.5-2') ASTM D2974-87 528020 35457287020 SB-11 (2-4') ASTM D2974-87 528020 35457287021 SB-11 (4-6') ASTM D2974-87 528020 35457287022 SB-11 (6-8') ASTM D2974-87 528020 35457287023 SB-10 (0-0.5') ASTM D2974-87 528020 35457287024 SB-10 (0.5-2') ASTM D2974-87 528020 35457287025 SB-10 (2-4') ASTM D2974-87 528020 Date: 04/16/2019 12:00 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 62 of 97 ^veers ( (pp 9TODY RECORDCe Container Type Code 5 ///��� W (�� . 35457287 pi'h rJ( C ��� �] �jr J ® Analytical Pace UI IGdlytica www.pacelahs.com Page p o4 -� ®II AV Amber Vial ES Enemy Sumnlarw CV Clear c PPV Plastic m :l vile P Plastic PLC Plastic crer.�.,� AL Anther Liter PLJ Plants Jar CL Clear Liter Z Aram bail 0) Amhurlor:licIII'III �. IIIII III Ambar GLISEIIr,■ Soll Jar r L 5457287 P.4oz, 802.1l _ Company Name: PO# 3 IS S Slzntsr. 2oi.4oz, tlot, 1602, 32uz or IL, other_ 4801 500m1 25001 125 ml Example: 4ozP a 4oz Phallic, BozSJ= Box Soil Jor Address: ' j7,'j j 1v{r.c.--7-,.--,-; Li' . Sample City: z_Q--.:. L///�---�c-S State:P-1, Zip: j'74(y TRC Matrix Codes Attn: I jj l I c�'.0 l Bfl l ii Ltr� \i ,. p_,rs7 'Q pH SD Solid Mere OL Oil CV/ Gerund Water so Slather // T email: A) Lam,.,'��1'`. C s r �' ( �11 Phone: 3� 7_,Lr sC)�) Pres Codas mmem :VFW Annlyle Fruo H2O AO Aqueous WW WeideWalm NA Nonaquomm J! 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Serial # 1.4 5 2 6 2 PaceAnalytical www.pacelabs.com Company Name: -4' C ff PO# Address: 5 7 ( i— �:-K.�,S .- . 1 7),.City �, .ti �; �s., State: p-:— Zip: Attn: Ivi.JJ, • !-,e••-d /n , , ',_Z /- emaihnndat.n, tr . '� Phone: 7.j.77 -- ' -7-P-31L'` Project t �('1 Name }... ' \-r e. vr)1T C- 7 ,..Prot # -5. .f - ::. Sampler Signatur Sample ID 7 E m Circle One Event: Daily Weekly Monthly Quartely Semi -Annual Annual N/A 0 Collect Date Collect Time Matnx Code' _q w w= iL iL So WO## : 35457287 )RD PM: CTR CLIENT: 36-EEG c ac g g Sample TRC pH Pres Codes Parameters Due Date: 04/03/19 Page of,, LAB ANALYSIS 1 2 3 4 5 6 7 8 9 10 Cxb TAT REQUEST (Ruh roue M4 ,o) Y , N R)SH Teeny ID 20 3D 4D 5D Re}intluishhhieid by p-) ." Ij2A Short Hold 1/ Affiliation n 01 L. 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Mould limas. Rie:4vl Preservative Type Codes A. None E. HCL I. Ice B. HNO3 F. McOH J. MCAA C. H2SO4 G. Na2S203 K. ZnAcolato D. NaOH H. NaHSO4 O. Other FL GA SC NC NJ PA LA TX IL Time REMARKS Coolers #'s - Temp °C 1 2 3 4 5 Nun.Conlormanc,; Fuu,I,l" Samples INTACT upon .arrival? Received on Wel Ica? Proper Prosnrvallvuo Indicated? Received within holding time? Custody main Intact? Voloblec rued without hoodspacu? Proper Conlalnor.: Usi,d? C.O.C. Serial # - 14363 WO# ' 3JJ 11 2V p PM PaceAnalytical CLINTIE: www.paeelabs.com R© ,x �" y Page"; of, / Container Type Codes rn : CTR Due Date: 04/03/ 19 36-EEG AV : Vial ES Encore Sancti, `D PPv Pwprurmrved vun I' 'ILni PI. (: Plastic cnnbnner10 1, Arun Lam PLJ Plastic Jar (:L Clear Lags Z Zrpluo burl a7 AP Amber Plastic TB ruhl:rr b•el AG Amber Gia5k WP Whirl pak a SJ Snn Jar c, Gmkm Jnp Olhur IC I ernecero PPv PIopru:.urvud vial Sl..l(s) Yea. aux. Buz. 16at, :j1o.: or IL, other anent veernl :'vnntl 125 c.Lrnl Lx:m,ple: 40zP • 4oz Pleallc, oozSJ• oe. sou Jar Company Name: � �- PO# LAB ANALYSIS �`4' Address: 67 ( 1 -_-., . c,„. -,!F, I. /,`. 1 Sample .'.•/ City: .;,:Y-., ,,,;"-S State: lam-, Zip: _550/41/ TRC Matrix Codes Attn: L(i ( �,/4h . • � t»1) {: Cam( (--_,„?.,H ,. Cje,. pH SD Solid Waslo OL Oil GruwN W.rlur SL Silldne EFF Effluent SO Soil Sudlnxrnl AFW Ao llyle /no. Hal AU Aqueous WW Wu+Jr, Wnirn NA Nunuqueuu:. DW Dunking W:rler PI Pt:nmie SW Surlier Wulur 0 Other ... . r. ML Mist: Liquid lu•.�. +• �i (GVJ �, _ t j email: /Q,., , *'r+ lj — a(3v� Phone: L"'� 3 7 Pres Codas �.�G� ` Namt{ 11�,, ,(V� /' r� c,� e Vte�(Y'e,se., (,c),4' C'r5 Prot # 5c.d ( D `3f.1") Parameters l"1 J 2 1 F- EXAMPLE Diss. Lead 6010 Sa�mp er �,z ' Circle One Event: Daily Weekly Monthly Signa ur /flG �/Quartely Semi•Annual Annual N!A Preservative Type Codes A. None E. HCL I. Ice C. HNO3 F. Me01 J. MCAA C. H2SO4 G. Na2S203 K. zOthetate D. NaOH H. NaHSO4 O. Other Sample # <\ ��VI Collect Sample ID Date Collect Time Matrix Code' LL " g Y O r a = o # of Containers 1 Sizeyp it REMARKS 1 S• .--,r 41-L) 3);?„-, )1��! SC' I -I I I I I I I u u I -II 2 5 —f i .: -) > 3'S I 5a' a 1 1 u u u u 1 1 P1 35z-;c,(c -c: ; J;/) I r n it❑ Li l l ❑ I I ■ 4 5-. (-- (c 5-,7i• t /54Z 1 g I I I I a I I LI I-1 u f I 5jn-)0 'V) � I31- :4' ( �I �l (-I 1 1 1 J �I I I 6 n it❑❑❑ u❑ Li u 7 u I I Li I I a 1 1 ❑❑ n 8 u n I I I I n u❑ n it 9 I I ❑ 1 1 n 1 1 ❑ 1 1 n u 10 ❑ 1 1 n I I 7 1 1 ❑ 1 1 ❑ Short Hold Circle CA/QC Report Level EDD (Fees May Apply) COC Condition Required State Certification Coolers #'s - Temp °C iellln N I ro.:r ID zD 3D .ID nu V N 1 2 3 4 CLP AFCEE OAPP Other _ ADaPT SEDO ERPIMS TSV CSV Other _ on m::,:rry nr b, FL GA SC NC NJ PA LA TX IL _ 2 3 4 5 Item i.,....:q4 uished by Affiliation Date Time Received by filiation Dar Dae Time 1,4. i1/? 7 I 'Jv f-1—.„_� --" C --; !Me:t ( Ic , No lunu:nc• rue„,,, S.o11[:. IN I AC I un'n.01,11' n,,.rvera rleW:1t k:r• wenr:r Pre • . valrv,...In,n„rlr.rr ;r:,,r,lvr•r, wrunl1111:11111111 lone„ n:.nxly slials lilts 1, Vul:ane:. rocYl without IttiatI,p•ar: , NOW Cunl:rurer:. Used', '"- t I�Q < ,1 2) lJ .-3J4 .!c /7� / 3 J 1 4 ompano Lat3 y54- Revision: F•ALL•C•007- Rev.00 C.O.C. Serial # 1 2 5 9 7 7 Project # Project Manager: Client: W© o 35457287 PM: CTR CLIENT: 36-EEG Due Date: 04/03/19 Cooler #1 Temp. CO, 7 (Visual) (Correction Factor) e' * 7 (Actual) Cooler #2 Temp. C (Visual) (Correction Factor) (Actual) Cooler #3 Temp. C (Visual) (Correction Factor) (Actual) Cooler #4 Temp. C (Visual) (Correction Factor) (Actual) Cooler #5 Temp.`C (Visual) (Correction Factor) (Actual) Cooler #6 Temp.'C (Visual) (Correction Factor) (Actual) Courier: -- Fa; Ex — UPS — USPS — C ie t — Co ^'erc:al�Pece Shipping Method: Billing: Tracking # Date and Initials of person: Examining contents: Label: Deliver: pH: Custody Seal on Cooler/Box Present: �c.s^ Seals intact: — Yes Ice Packing Material: _- Elu:i': .. ::. Samples shorted to lab (If Yes. complete) S•,cr:ee Date Si';!,.c ' -- s: Una:- c -... • . .. I "s Nc . banlcles A.rrive:1 .Ii!ri r'. r fir, .. e5 . •.. , -. R..sr T- eq,,esi-n :. -„ _ Yes Sufficient vciume �/'S'es Nc Cc!:,... ,maulers Ls.: es :\7 es/ je N - r-ieri:: t_I -c.. . ,. ,:ials? ( >emm, :. ._ . T rp ci: ank Prase"' v -s .• Client Notification/ Resolution: Person Coniactec Comments/ Resolution (use back for additional comments): Da:e Page 66 of 97 aeAnalytical® National Center for Testing & Innovation A\ALYT CAL RH3ORT April 10, 2019 Pace Analytical - Pompano Beach, FL Sample Delivery Group: L1085002 Samples Received: 04/03/2019 Project Number: 35457287 Description: melrose Golf Course 2018-3057 Site: 001 Report To: Christina Raschke 3610 Park Central Blvd N Pompano Beach, FL 33064 Entire Report Reviewed By: Nancy McLain Project Manager Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be repr oduced. except in full, without written approval of the laboratory. Where applicable. sampling conducted by Pace National is performed per guidance provided in laboratory standard operating procedures: 060302.060303, and 060304. Mount Juliet, TN 37122 615-758-5858 TABLE OF CONTENTS ONE LAB. NATIONWIDE. Cp: Cover Page 1 Tc: Table of Contents 2 Ss: Sample Summary 3 Cn: Case Narrative 4 Sr: Sample Results 5 SB-9 (2-4) L1085002-01 5 Qc: Quality Control Summary 6 Total Solids by Method 2540 G-2011 6 Chlorinated Acid Herbicides (GC) by Method 8151 7 OP Pesticides by Method 8141 9 GI: Glossary of Terms 12 Al: Accreditations & Locations 13 Sc: Sample Chain of Custody 14 ACCOUNT: Pace Analytical - Pompano Beach, FL Co Cn Qc GI Al Sc Page 68 of 97 PROJECT: SDG: DATE/TIME: PAGE: 35457287 L1085002 04/10/1915:34 2 of 15 SAMPLE SUMMARY ONE LAB. NATIONWIDE. SB-9 (2-4) L1085002-01 Solid Collected oi Collected date:tin e Feceived datei0me _3 26-i910:14 04:0!19 08:45 • cod Batch Dilution Preparation Analysis Analyst Location date/time date/time Total Solids by Method 2540 G-2011 WG1261799 1 04/09/19 11:35 04/09/1911:44 JD Mt. Juliet, TN Chlorinated Acid Herbicides (GC) by Method 8151 WG1262151 1 04/07/19 07:43 04/08/1912:35 KLM Mt. Juliet, TN OP Pesticides by Method 8141 WG1260293 10 04/04/19 18:43 04/05/19 21:10 HMH Mt. Juliet, TN ACCOUNT: Pace Analytical - Pompano Beach, FL Cp Tc 4 Cn cSr E QC GI Al Page 69 of 97 PROJECT: SDG: DATE/TIME: PAGE: 35457287 L1085002 04/10/1915.34 3 of 15 CASE NARRATIVE ONE LAB. NATIONWIDE. Alk All sample aliquots were received at the correct temperature, in the proper containers, with the appropriate preservatives, and within method specified holding times, unless qualified or notated within the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data. OLAN Nancy McLain Project Manager ACCOUNT: Pace Analytical - Pompano Beach, FL l Cp] 4 Cn Sr 0c GI Al Cr Page 70 of 97 PROJECT: SDG: DATE/TIME: RAGE: 35457287 L1085002 04/10/1915:34 4 of 15 SB-9 (2-4) SAMPLE RESULTS - 01 Collected date/time: 03/26/19 10:14 L1085002 ONE LAB. NATIONWIDE. a Total Solids by Method 2540 G-2011 to -.el Solids Result Qualifier Dilution Analysis Batch date / time 85.1 1 04/09/201911:44 WG1261799 Chlorinated Acid Herbicides (GC) by Method 8151 Result (dry) Qualifier MDL (dry) RDL (dry) Dilution Analysis Batch Analyte mg/kg mg/kg mg/kg date/time 2,4-D 0.00825 U 0.00825 0.0823 1 04/08/201912:35 WG1262151 Dalapon 0.0133 U 0.0133 0.0823 1 04/08/201912:35 WG1262151 2,4-DB 0.0349 U 0.0349 0.0823 1 04/08/201912:35 WG1262151 Dicamba 0.0184 U 0.0184 0.0823 1 04/08/201912:35 WG1262151 Dichloroprop 0.0288 U 0.0288 0.0823 1 04/08/201912:35 WG1262151 Dinoseb 0.00819 J U 0.00819 0.0823 1 04/08/2019 12:35 WG1262151 MCPA 0.521 J U 0.521 7.64 1 04/08/2019 12:35 WG1262151 MCPP 0.431 U 0.431 7.64 1 04/08/2019 12:35 WG1262151 2,4,5-1 0.0100 U 0.0100 0.0823 1 04/08/2019 12:35 WG1262151 2,4,5-TP (Silvex) 0.0126 U 0.0126 0.0823 1 04/08/201912:35 WG1262151 (S) 2,4-Dichlorophenyl Acetic Acid 76.0 22.0-132 04/08/2019 12:35 WG1262151 OP Pesticides by Method 8141 Result (dry) Qualifier MDL (dry) RDL (dry) Dilution Analysis Batch Analyte mg/kg mg/kg mg/kg date/time Azinphos-Methyl 0.0444 Q U 0.0444 1.18 10 04/05/2019 21:10 WG1260293 Bolstar (Sulprofos) 0.0651 Q U 0.0651 1.18 10 04/05/2019 21:10 WG1260293 Chlorpyrifos 0.108 Q U 0.108 1.18 10 04/05/2019 21:10 WG1260293 Coumaphos 0.0799 Q U 0.0799 1.18 10 04/05/2019 21:10 WG1260293 ^:.meton,-0 and -S 0.0398 Q U 0.0398 0.823 10 04/05/2019 21:10 WG1260293 non 0.0525 Q U 0.0525 1.18 10 04/05/2019 21:10 WG1260293 uichlorvos 0.114 Q U 0.114 1.18 10 04/05/2019 21:10 WG1260293 Dimethoate 0.233 Q U 0.233 1.18 10 04/05/2019 21:10 WG1260293 Disulfoton 0.0585 Q U 0.0585 1.18 10 04/05/2019 21:10 WG1260293 EPN 0.0602 Q U 0.0602 1.18 10 04/05/2019 21:10 WG1260293 Ethoprop 0.0546 Q U 0.0546 1.18 10 04/05/2019 21:10 WG1260293 Ethyl Parathion 0.0671 Q U 0.0671 1.18 10 04/05/2019 21:10 WG1260293 Fensulfothion 0.199 Q U 0.199 1.18 10 04/05/2019 21:10 WG1260293 Fenthion 0.0714 Q U 0.0714 1.18 10 04/05/2019 21:10 WG1260293 Malathion 0.0823 Q U 0.0823 1.18 10 04/05/2019 21:10 WG1260293 Merphos 0.0633 Q U 0.0633 1.18 10 04/05/2019 21:10 WG1260293 Methyl parathion 0.0786 Q U 0.0786 1.18 10 04/05/2019 21:10 WG1260293 Mevinphos 0.120 Q U 0.120 1.18 10 04/05/2019 21:10 WG1260293 Naled 0.0491 Q U 0.0491 1.18 10 04/05/2019 21:10 WG1260293 Phorate 0.0553 Q U 0.0553 1.18 10 04/05/2019 21:10 WG1260293 Ronne) 0.0514 Q U 0.0514 1.18 10 04/05/2019 21:10 WG1260293 Stirophos 0.0631 Q U 0.0631 1.18 10 04/05/2019 21:10 WG1260293 Sulfotep 0.0454 Q U 0.0454 1.18 10 04/05/2019 21:10 WG1260293 TEPP 1.84 Q U 1.84 11.8 10 04/05/2019 21:10 WG1260293 Tokuthion (Prothothiofos) 0.0710 Q U 0.0710 1.18 10 04/05/2019 21:10 WG1260293 Trichloronate 0.0780 Q U 0.0780 1-18 10 04/05/2019 21:10 WG1260293 (S) Triphenyl Phosphate 872 36.0-121 04/05/2019 21:10 WG1260293 Sample Narrative: L1085002-01 WG1260293: Dilution due to viscosity ACCOUNT: Pace Analytical - Pompano Beach, FL Cp Ss a Cn 5 Sr 6 Qc GI Al Page 71 of 97 PROJECT: SDG: DATE/TIME: PAGE: 35457287 L1085002 04/10/1915:34 5 of 15 WG1261799 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. Ilk Total Solids by Method 2540 G-2011 L1085002-01 Method Blank (MB) (MB) R3400130-1 04/09/19 11:44 MB Result Analyte % Total Solids 0.00100 MB Qualifier MB MDL MB RDL L1085058-01 Original Sample (OS) • Duplicate (DUP) (OS) L1085058-01 04/09/19 11:44 • (DUP) R3400130-3 04/09/1911:44 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte % % % % Total Solids 80.8 81.0 1 0.347 10 Laboratory Control Sample (LCS) (LCS) R3400130-2 04/09/19 11:44 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte % % Total Solids 50.0 50.0 100 85.0-115 ACCOUNT: Face Analytical - Pompano Beach, FL Cp 3 SS Sr 6 Qc 7GI Al -,ge72of97 PROJECT: SDG: DATE/TIME: 'AGE: 35457287 L1085002 04/10/19 15:34 6 of 15 WG12 151 QUALITY COr R0L SUMMARY ONE LAB. " �NWIDE. Chlorinate, yid Herbicides (GC) by Method 8151 L1t . J2-01 Method Blank (MB) (MB) R3399764-1 04/08/19 11:53 MB Result MB Qualifier MB MDL MB RDL Analyte mg/kg mg/kg mg/kg 2,4-0 0.00702 U 0.00702 0.0700 Dalapon 0.0113 U 0.0113 0.0700 2,4-DB 0.0297 U 0.0297 0.0700 Dicamba 0.0157 U 0.0157 0.0700 Dichloroprop 0.0245 U 0.0245 0.0700 Dinoseb 0.00697 U 0.00697 0.0700 MCPA 0.443 U 0.443 6.50 MCPP 0.367 U 0.367 6.50 2,4,5-T 0.00852 U 0.00852 0.0700 2,4,5-TP (Silvex) 0.0107 U 0.0107 0.0700 (S) 2,4-Dich/orophenyl Acetic 78.4 22.0 132 Acid Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3399764-2 04/08/19 12:07 • (LCSD) R3399764-3 04/08/19 12:21 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte mg/kg mg/kg mg/kg % % % % % 2,4-0 0.167 0.132 0.134 79.0 80.2 40.0-120 1.50 20 Dalapon 0.167 0.125 0.129 74.9 77.2 15.0-120 3.15 27 2,4-DB 0.167 0.113 0.118 67.7 70.7 25.0-143 4.33 20 Dicamba 0.167 0.154 0.158 92.2 94.6 43.0-120 2.56 20 Dichloroprop 0.167 0.147 0.149 88.0 89.2 32.0-129 1.35 20 Dinoseb 0.167 0.0168 0.0127 10.1 7.60 10.0-120 J 27.8 40 MCPA 1.67 2.77 3.00 166 180 31.0-121 J J 7.97 33 MCPP 1.67 1.83 1.80 110 108 28.0-133 1.65 33 2,4,5-T 0.167 0.126 0.128 75.4 76.6 41.0-120 1.57 20 2,4,5-TP (Silvex) 0.167 0.149 0.152 89.2 91.0 42.0-120 1.99 20 (S) 2,4-Dichlorophenyl Acetic 82.0 82.0 22.0-132 Acid L1085872-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) Cp 3 SS 4 Cn Sr GI Al (OS) L1085872-01 04/08/19 15:48 • (MS) R3399764-4 04/08/19 16:02 • (MSD) R3399764-5 04/08/19 16:16 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte mg/kg mg/kg mg/kg mg/kg % % % % % 2,4-0 0.167 0.00702 0.123 0.133 73.7 79.6 1 10.0-160 7,81 24 Dalapon 0.167 0.0113 0.121 0.133 72.5 79.6 1 10.0-121 9.45 27 2,4-09 0.167 0.0297 0.114 0.125 68.3 74.9 1 10.0-160 9.21 22 Dicamba 0.167 0.0164 0.153 0.165 91.6 98.8 1 10.0-154 7.55 21 Page 73 of 97 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Pompano Beach, FL 35457287 L1085002 04/10/19 15:34 7 of 15 WG1262151 QUALITY CONTROL SUMMARY Chlorinated Acid Herbicides (GC) by Method 8151 L1085002-01 ONE LAB. NATIONWIDE. L1085872-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1085872-01 04/08/19 15:48 • (MS) R3399764-4 04/08/19 16:02 • (MSD) R3399764-5 04/08/1916:16 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte mg/kg mg/kg mg/kg mg/kg % % % % % Dichloroprop 0.167 0.0245 0.131 0.139 78.4 83.2 1 10.0-158 5.93 20 Dinoseb 0.167 0.00697 0.0261 0.0305 15.6 18.3 1 10.0-120 15.5 40 MCPA 1.67 0.443 5.54 6.12 332 366 1 10.0-160 J L J L 9.95 40 MCPP 1.67 0.367 0.849 0.827 50.8 49.5 1 10.0-160 2.63 40 2,4,5-T 0.167 0.00852 0.130 0.139 77.8 83.2 1 10.0-157 6.69 20 2,4,5-TP (Silvex) 0.167 0.0107 0.134 0.144 80.2 86.2 1 10.0-156 7.19 20 (S) 2,4-Dichloropheny/Acetic Acid 83.8 85.0 22.0-132 ACCOUNT: Pace Analytical - Pompano Beach, FL Cp 2 Tc 3Ss Sr 6 Qc GI Al -Tge 74 of 97 PROJECT: SDG: DATE/TIME: AGE: 35457287 L1085002 04/10/19 15:34 8 of 15 WG12 293 QUALITY CO' 2OL SUMMARY OP Pestle', . by Method 8141 L1, 02-01 ONE LAB. ^ - RNWIDE. Method Blank (MB) (MB) R3399442-1 04/05/19 12:12 MB Result MB Qualifier MB MDL MB RDL Analyte mg/kg mg/kg mg/kg Azinphos-Methyl 0.00378 U 0.00378 0.100 Bolstar (Sulprofos) 0.00554 U 0.00554 0.100 Chlorpyrifos 0.00923 U 0.00923 0.100 Coumaphos 0.00680 U 0.00680 0.100 Demeton,-0 and -S 0.00339 U 0.00339 0.0700 Diazinon 0.00447 U 0.00447 0.100 Dichlorvos 0.00969 U 0.00969 0.100 Dimethoate 0.0198 U 0.0198 0.100 Disulfoton 0.00498 U 0.00498 0.100 EPN 0.00512 U 0.00512 0.100 Ethoprop 0.00465 U 0.00465 0.100 Ethyl Parathion 0.00571 U 0.00571 0.100 Fensulfothion 0.0169 U 0.0169 0.100 Fenthion 0.00608 U 0.00608 0.100 Malathion 0.00700 U 0.00700 0.100 Merphos 0.00539 U 0.00539 0.100 Methyl parathion 0.00669 U 0.00669 0.100 Mevinphos 0.0102 U 0.0102 0.100 Naled 0.00418 U 0.00418 0.100 Phorate 0.00471 U 0.00471 0.100 Ronnel 0.00437 U 0.00437 0.100 Stirophos 0.00537 U 0.00537 0.100 Sulfotep 0.00386 U 0.00386 0.100 TEPP 0.157 U 0.157 1.00 Tokuthion (Prothothiofos) 0.00604 U 0.00604 0.100 Trichloronate 0.00664 U 0.00664 0.100 (S) Triphenyl Phosphate 114 36.0-121 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3399442-2 04/05/19 12:44 • (LCSD) R3399442-3 04/05/19 13:15 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte mg/kg mg/kg mg/kg % % % % Azinphos-Methyl 0.333 0.348 0.349 105 105 58,0-125 0.287 20 Bolstar (Sulprofos) 0.333 0.350 0.349 105 105 64.0-120 0.286 20 Chlorpyrifos 0.333 0.339 0.332 102 99.7 62.0-120 2.09 20 Coumaphos 0.333 0.373 0.371 112 111 60.0-120 0.538 20 Demeton,-0 and -S 0.167 0.166 0.161 99.4 96.4 59.0-120 P P 3.06 20 Diazinon 0.333 0.238 0.252 71.5 75.7 49.0-120 5.71 20 ACCOUNT: Pace Analytical - Pompano Beach, FL Page 75 of 97 PROJECT: SDG: DATE/TIME: PAGE: 35457287 L1085002 04/10/19 15:34 9 of 15 Cp Ss 4Cn 5 Sr 7 GI VAI WG1260293 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. 10 OP Pesticides by Method 8141 L1085002-01 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3399442-2 04/05/19 12:44 • (LCSD) R3399442-3 04/05/19 13:15 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte mg/kg mg/kg mg/kg % % % % % Dichlorvos 0.333 0.325 0.327 97.6 98.2 37.0-120 0.613 22 Dimethoate 0.333 0.240 0.251 72.1 75.4 46.0-127 4.48 20 Disulfoton 0.333 0.333 0.326 100 97.9 60.0-121 2.12 20 EPN 0.333 0.397 0.398 119 120 60.0-121 0.252 20 Ethoprop 0.333 0.322 0.319 96.7 95.8 59.0-120 0.936 20 Ethyl Parathion 0.333 0.349 0.344 105 103 62.0-120 1.44 20 Fensulfothion 0.333 0.350 0.366 105 110 58.0-123 4.47 20 Fenthion 0.333 0.314 0.308 94.3 92.5 61.0-121 1.93 20 Malathion 0.333 0.305 0.323 91.6 97.0 59.0-120 5.73 20 Merphos 0.333 0.427 0.415 128 125 59.0-120 J J 2.85 20 Methyl parathion 0.333 0.353 0.335 106 101 63.0-120 5.23 20 Mevinphos 0.333 0.283 0.291 85.0 87.4 50.0-120 2.79 20 Naled 0.333 0.266 0.269 79.9 80.8 10.0-125 1.12 26 Phorate 0.333 0.319 0.322 95.8 96.7 60.0-120 0.936 20 Ronnel 0.333 0.326 0.320 97.9 96.1 62.0-120 1.86 20 Stirophos 0.333 0.334 0.334 100 100 62.0-120 0.000 20 Sulfotep 0.333 0.349 0.343 105 103 62.0-122 1.73 20 TEPP 3.33 0.462 0.569 13.9 17.1 1.00-135 20.8 40 Tokuthion (Prothothiofos) 0.333 0.345 0.344 104 103 63.0-120 0.290 20 Trichloronate 0.333 0.330 0.322 99.1 96.7 62.0-120 2.45 20 (S) Triphenyl Phosphate 109 111 36.0-121 L1084635-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) Cp 3 SS Cn 6 Qc GI !;I (OS) L1084635-01 04/05/19 21:42 • (MS) R3399442-4 04/05/19 22:14 • (MSD) R3399442-5 04/05/19 22:45 Spike Amount Original Result MS Result (dry) MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits (dry) (dry) (dry) Analyte mg/kg mg/kg mg/kg mg/kg % % % % % Azinphos-Methyl 0.415 0.0471 0.345 0.349 83.2 84.1 10 10.0-160 1.08 22 Bolster (Sulprofos) 0.415 0.0690 0.313 0.314 75.4 75.7 10 10.0-151 0.398 20 Chlorpyrifos 0.415 0.115 0.312 0.295 75.1 71.2 10 12.0-149 5.34 20 Coumaphos 0.415 0.0847 0.432 0.456 104 110 10 10.0-160 5.33 22 Demeton,-0 and -S 0.208 0.0422 0.181 0.163 86.8 78.4 10 10.0-160 10.1 23 Diazinon 0.415 0.0557 0.334 0.324 80.5 78.1 10 11.0-157 3.03 20 Dichlorvos 0.415 0.121 0.464 0.425 112 102 10 10.0-160 8.70 24 Dimethoate 0.415 0.247 0.290 0.000 70.0 0.000 10 10.0-150 U J U 200 27 Disulfoton 0.415 0.0621 0.316 0.320 76.3 77.2 10 12.0-155 1.17 20 EPN 0.415 0.0638 0.396 0.410 95.5 98.8 10 10.0-159 3.40 20 Ethoprop 0.415 0.0579 0.334 0.331 80.5 79.9 10 11.0-156 0.749 20 Ethyl Parathion 0.415 0.0711 0.351 0.320 84.7 77.2 10 10.0-147 9.28 20 -"go 76 of 97 ACCOUNT: PROJECT: SDG: DATE/TIME: 'AGE: Pace Analytical - Pompano Beach, FL 35457287 L1085002 04/10/19 15:34 10 of 15 WG12 293 QUALITY COP ROL SUMMARY ONE LAB. t‘" -nNWIDE. OP Pestick. , by Method 8141 L1i, J2-01 L1084635-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1084635-01 04/05/19 21:42 • (MS) R3399442-4 04/05/19 22:14 • (MSD) R3399442-5 04/05/19 22:45 Spike Amount Original Result MS Result (dry) (dry) MSD Result (dry) (dry) MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte mg/kg mg/kg mg/kg mg/kg % % % % Fensulfothion 0.415 0.211 0.386 0.380 93.1 91.6 10 10.0-157 1.63 27 Fenthion 0.415 0.0758 0.288 0.259 69.4 62.5 10 13.0-155 10.5 20 Malathion 0.415 0.0872 0.297 0.280 71.5 67.6 10 13.0-137 5.62 21 Merphos 0.415 0,0672 0.178 0.164 42.9 39.6 10 10.0-147 8.00 26 Methyl parathion 0.415 0.0834 0.307 0.280 73.9 67.6 10 10.0-150 8.92 21 Mevinphos 0.415 0.127 0.326 0.285 78.7 68.8 10 10.0-158 13.4 24 Naled 0.415 0.0521 0.000 0.000 0.000 0.000 10 10.0-137 J U .1 U 0.000 40 Phorate 0.415 0.0587 0.308 0.294 74.2 70.9 10 13.0-154 4.55 20 Ronnel 0.415 0.0545 0.287 0.273 69.1 65.8 10 14.0-149 4.90 20 Stirophos 0.415 0.0669 0.293 0.277 70.6 66.7 10 10.0-150 5.69 20 Sulfotep 0.415 0.0481 0.326 0.335 78.7 80.8 10 10.0-160 2.64 20 TEPP 4.15 1.96 0.000 0.000 0.000 0.000 10 1.00-142 J U J U 0.000 28 Tokuthion (Prothothiofos) 0.415 0.0753 0.335 0.308 80.8 74.2 10 12.0-153 8.53 20 Trichloronate 0.415 0.0827 0.289 0.252 69.7 60.7 10 12.0-152 13.8 20 (S) Triphenyl Phosphate 83.2 88.9 36.0-121 Sample Narrative: OS: Dilution due to viscosity ACCOUNT: Pace Analytical - Pompano Beach, FL Cp Tc 3 SS Cn Sr 6 Qc 7 GI AI Page 77 of 97 PROJECT: SDG: DATE/TIME: PAGE: 35457287 L1085002 04/10/19 15:34 11 of 15 GLOSSARY OF TERMS ONE LAB. NATIONWIDE. SI Guide to Reading and Understanding Your Laboratory Report The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and if you have additional questions please contact your project representative. Abbreviations and Definitions (dry) MDL MDL (dry) RDL RDL (dry) Rec. RPD SDG (S) Analyte Dilution Limits Original Sample Qualifier Result Uncertainty (Radiochemistry) Case Narrative (Cn) Quality Control Summary (Qc) Sample Chain of Custody (Sc) Sample Results (Sr) Sample Summary (Ss) Qualifier Results are reported based on the dry weight of the sample. [this will only be present on a dry report basis for soils]. Method Detection Limit. Method Detection Limit. Reported Detection Limit. Reported Detection Limit. Recovery. Relative Percent Difference. Sample Delivery Group. Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be detected in all environmental media. The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes reported. If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor. These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or duplicated within these ranges. The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control sample. The Original Sample may not be included within the reported SDG. This column provides a letter and/or number designation that corresponds to additional information concerning the result reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable. The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL" (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte. Confidence level of 2 sigma. A brief discussion about the included sample results, including a discussion of any non -conformances to protocol observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report. This section of the report includes the results of the laboratory quality control analyses required by procedure or analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material. This is the document created in the field when your samples were initially collected. This is used to verify the time and date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the samples from the time of collection until delivery to the laboratory for analysis. This section of your report will provide the results of all testing performed on your samples. These results are provided by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for each sample will provide the name and method number for the analysis reported. This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and times of preparation and/or analysis. Description J L P Q u The value is outside laboratory established criteria. Off -scale high. Actual value is known to be greater than value given. RPD between the primary and confirmatory analysis exceeded 40%. Sample held beyond the accepted holding time. Indicates the compound was analyzed for but not detected above the method detection limit. ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Pompano Beach, FL 35457287 L1085002 04/10/1915:34 Ss GI Al Page 78 of 97 PAGE: 12 of 15 ACCREDITATIONS & LOCATIONS ONE LAB. NATIONWIDE. Pace National is the only environmental laboratory accredited/certified to support your work nationwide from one location. One phone call, one point of contact, one laboratory. No other lab is as accessible or prepared to handle your needs throughout the country. Our capacity and capability from our single location laboratory is comparable to the collective totals of the network laboratories in our industry. The most significant benefit to our one location design is the design of our laboratory campus. The model is conducive to accelerated productivity, decreasing turn -around time, and preventing cross contamination, thus protecting sample integrity. Our focus on premium quality and prompt service allows us to be YOUR LAB OF CHOICE. ` Not all certifications held by the laboratory are applicable to the results reported in the attached report. Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace National. State Accreditations Alabama 40660 Nebraska NE-OS-15-05 Alaska 17-026 Nevada TN-03-2002-34 Arizona A70612 New Hampshire 2975 Arkansas 88-0469 New Jersey—NELAP TN002 California 2932 New Mexico' n/a Colorado TN00003 New York 11742 Connecticut PH-0197 North Carolina Env375 Florida E87487 North Carolina' DW21704 Georgia NELAP North Carolina 3 41 Georgia' 923 North Dakota R-140 Idaho TN00003 Ohio—VAP CL0069 Illinois 200008 Oklahoma 9915 Indiana C-TN-01 Oregon TN200002 Iowa 364 Pennsylvania 68-02979 Kansas E-10277 Rhode Island LA000356 Kentucky 16 90010 South Carolina 84004 Kentucky 2 16 South Dakota n/a Louisiana A130792 Tennessee' 2006 Louisiana' LA180010 Texas T104704245-18-15 Maine TN0002 Texas5 LAB0152 Maryland 324 Utah TN00003 Massachusetts M-TN003 Vermont VT2006 Michigan 9958 Virginia 460132 Minnesota 047-999-395 Washington C847 Mississippi TN00003 West Virginia 233 Missouri 340 Wisconsin 9980939910 Montana CERT0086 Wyoming A2LA Third Party Federal Accreditations A2LA — ISO 17025 1461.01 A2LA — ISO 170255 1461.02 Canada 1461.01 EPA—Crypto TN00003 AIHA-LAP,LLC EMLAP 100789 DOD 1461.01 USDA P330-15-00234 Drinking Water 2 Underground Storage Tanks ' Aquatic Toxicity " Chemical/Microbiological 5 Mold 6 Wastewater n/a Accreditation not applicable Our Locations Pace National has sixty-four client support centers that provide sample pickup and/or the delivery of sampling supplies. If you would like assistance from one of our support offices, please contact our main office. Pace National performs all testing at our central laboratory. ACCOUNT: Pace Analytical - Pompano Beach, FL PROJECT: 35457287 SDG: L1085002 DATE/TIME: 04/10/19 15:34 Cp Tc Ss 4 Cn 5 Sr 6 Qc GI Page 79 of 97 PAGE: 13 of 15 Al Chain of Custody Workorder: 35457287 Workorder Name: melrose Goff Course 2018-3057 Results Requested By: 4/3/2019 ace Analytical wrwp^ce1!t3 resrn Report / Invoice To j Subcbntratt To ti Requested Analysis Christina Raschke Pace Analytical South Florida P. . 1 1 g 8141 OP Pesticides — 1 d V) LAB USE ONLY 3610 Park Central Blvd N Pompano Beach, FL 33064 e'"^-',�10 h Phone (954)582-4300 fill ���� Email. christina.raschke©pacelabs.com State of Sample Origin: FL Preserved Containers Item + Sam*Ic Colleci Dat9fThCte Lab ID , _ Matrix • 1 SB-9 (2-4') 3/2812019 10:14 35457287006 Solid X n (bi a.) 2 ,.1 f 2 3 4 ,_ Comments Transfers Reiss B DatefTims Received By Detain 1 R-2 (pq • to lid ,e-Jfu l PIG 2 3 Cooler Temperature on Receipt , •) 'C Custody Seal Y or /11\, T Received on Ice rr,, l� or N 1 Samples Intact Of) or N Z 3081 Friday, March 29. 2019 6 10 28 PM FMT-ALL-C-002rev.00 24March2009 f'ag1 of le 80 of 97 Pace Analytical National Center for Testing & Innovation Cooler Receipt Form Client:-? SDGtt: ��41 i✓ Iowan,� Cooler Received/Opened On: -3: 6 / 19 Temperature: 1A Received IUv: Kristin Willis Signature: Kt/01 1 i c Receipt Check List NP Yes No COC Seal Present / Intact? ,----- COC Signed / Accurate? Bottles arrive intact? / Correct bottles used? / Sufficient volume sent? / If Applicable VOA Zero headspace? Preservation Correct / Checked? Page 81 of 97 ace Analytical www pacelabs com Report Prepared for: Christina Raschke PASI Florida 3610 Park Central Blvd N Pompano Beach FL 33064 REPORT OF LABORATORY ANALYSIS FOR PCDD/PCDF Report Prepared Date: April 15, 2019 Report No 104689228290FC_DFR Pace Analytical Services, LLC. 1700 Elm Street Minneapolis, MN 55414 Phone: 612.607.1700 Fax: 612.607.6444 Report Information: Pace Project #: 10468922 Sample Receipt Date: 03/30/2019 Client Project #: 35457287 Client Sub PO #: N/A State Cert #: E87605 Invoicing & Reporting Options: The report provided has been invoiced as a Level 2 PCDD/PCDF Report. If an upgrade of this report package is requested, an additional charge may be applied. Please review the attached invoice for accuracy and forward any questions to Nathan Boberg, your Pace Project Manager. This report has been reviewed by: April 15, 2019 Nathan Boberg, Project Manager 612-360-0728 (612) 607-6444 (fax) nathan.boberg@pacelabs.com Report of Laboratory Analysis Thisreportshouldnotbereproduced,exceptinfull, withoutthewrittenconsentofPaceAnalyticalServices,Inc. Theresultsrelateonlyt othesamplesincludedinthisreport. Page 82 of 97 Page 1 of 16 aceAnalytical DISCUSSION Pace Analytical Services, LLC. 1700 Elm Street Minneapolis, MN 55414 Phone: 612.607.1700 Fax: 612.607.6444 This report presents the results from the analyses performed on two samples submitted by a representative of Pace Analytical Services, LLC. The samples were analyzed for the presence or absence of polychlorodibenzo-p-dioxins (PCDDs) and polychlorodibenzofurans (PCDFs) using a modified version of USEPA Method 8290. The reporting limits were based on signal-to-noise measurements. Estimated Maximum Possible Concentration (EMPC) values were treated as positives in the toxic equivalence calculations. Per request, estimated detection limit (EDL) values were provided and flagged "U" where the target analytes were not detected. Second column confirmation analyses of 2,3,7,8-TCDF values obtained from the primary (DB5-MS) column are performed only when specifically requested for a project and only when the values are above the concentration of the lowest calibration standard. Typical resolution for this isomer using the DB5-MS column ranges from 25-30%. The recoveries of the isotopically -labeled PCDD/PCDF internal standards in the sample extracts ranged from 20-80%. Except for four low values, which were flagged "R" on the results table, the labeled internal standard recoveries obtained for this project were within the 40-135% target range specified in Method 8290. Also, since the quantification of the native 2,3,7,8-substituted congeners was based on isotope dilution, the data were automatically corrected for recovery and accurate values were obtained. In some cases, interfering substances impacted the determinations of PCDD or PCDF congeners; the affected values were flagged "I" where incorrect isotope ratios were obtained or "P" where polychlorinated diphenyl ethers were present. Concentrations below the calibration range were flagged "J" and should be regarded as estimates. A laboratory method blank was prepared and analyzed with the sample batch as part of our routine quality control procedures. The results show that PCDDs and PCDFs were not detected. These results indicate that the sample preparation procedures did not significantly impact the results of the field sample determinations. A laboratory spike sample was also prepared with the sample batch using reference material that had been fortified with native standards. The recoveries of the spiked native compounds ranged from 98-123%. These results were within the target ranges for the method. Matrix spikes were prepared with the sample batch using sample material from a separate project; results from these analyses will be provided upon request. REPORT OF LABORATORYANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10468922_8290FC_DFR Page 83 of 97 Page 2 of 16 Authority Minnesota Laboratory Certifications Certificate # Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612-607-6444 Authority Certificate # A2LA 2926.01 Alabama 40770 Alaska - DW MN00064 Alaska - UST 17-009 Arizona AZ0014 Arkansas - DW MN00064 Arkansas - WW 88-0680 CNMI Saipan MP0003 California 2929 Colorado MN00064 Connecticut PH-0256 EPA Region 8+ via MN 027-053 Florida (NELAP E87605 Georgia 959 Guam 17-001r Hawaii MN00064 Idaho MN00064 Illinois 200011 Indiana C-MN-01 Iowa 368 Kansas E-10167 Kentucky - DW 90062 Kentucky - WW 90062 Louisiana - DE 03086 Louisiana - DW MN00064 Maine MN00064 Maryland 322 Massachusetts M-MN064 Michigan 9909 Minnesota 027-053-137 Minnesota - De via MN 027-053 Minnesota - Pet 1240 Mississippi MN00064 Missouri - DW 10100 Montana CERT0092 Nebraska NE-OS-18-06 Nevada MN00064 New Hampshire 2081 New Jersey (NE MN002 New York 11647 North Carolina 27700 North Carolina - 27700 North Carolina - 530 North Dakota R-036 Ohio - DW 41244 Ohio - VAP CL101 Oklahoma 9507 Oregon - Primar MN300001 Oregon - Secon MN200001 Pennsylvania 68-00563 Puerto Rico MN00064 South Carolina 74003 South Dakota NA Tennessee TN02818 Texas T104704192 Utah (NELAP) MN00064 Virginia 460163 Washington C486 West Virginia - 382 West Virginia - 9952C Wisconsin 999407970 Wyoming - UST 2926.01 REPORT OF LABORATORYANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, Inc. Report No 10468922_8290FC_DFR Page 84 of 97 Page 3 of 16 Appendix A Sample Management Report No 10468922_8290FC_e Analytical Services, Inc. Page 85 of 97 Page 4 of 16 70 cD 0 Z 0 2JdO Od06Z8 ZZ689.170 a n :ody 0 Samples were sent directly to the Subcontracting Laboratory. Workorder: 35457287 Workorder Name: melrose Golf Course 2018-3057 State Of Origin: FL Cert. Needed: Yes Li No ace Analytical www. oaceiebs.com Owner Received Date: 3/27/2019 Results Requested By: 4/3/2019 Report To J Subcontract To ;!' . ` Roque. t;d Analysis Christina Raschke Pace Analytical Minnesota Pace Analytical South Florida 1700 Elm Street.SE 3610 Park Central Blvd N Suite 200 Pompano Beach, FL 33064 Minneapolis, MN 55414 Phone (954)582-4300 Phone (612)607-1700 "c W O CN 07 ;� i F J` _ ��S 'fll Tu , ,Y - v. r "' / �,Fj �1 in d �4}• ' '• , 1•� 84.e; ` ) l '1�,.F 1" 1 T r �1 ;DIY 3 i ,qcb. 6 51 LAS u, YlY USE ONLY .P,seTlJBtt;'011Xa1�1erS- t item Sample ID Sample Type Collect Date/'time Lab ID Matrix 1 8-9 (2-4') PS � 3/26/2019 10:14 35457287006 Solid 1 X cp\ 2 8-12 (6-71 PS 3/26/2019 12:08 35457287017 Solid 1 X t 111 3 4 s i § Comn ents Transfers Released By i Date!Time Received By Date/Time 2 3 Cooler Temperature on Receipt 44••- °C Custody Seal -62 or N EReceived on Ice or N 1 Samples Intact () or N —in order to maintain client confidentiality, location/name of the sampling site, sampler's name and signature may not be provided on this COC document. This chain of custody is considered complete as is since this information is available in the owner laboratory. 0) rn Friday. Maria 29, 211141 7 1 47 PM 0 CD FMT ALL-C-002rev.00 24March2009 BGEAl1r?I�/17Ca� Document Name: Sample Condition Upon Receipt Form Document Revised: 06Feb2o14 Page 1 of 1 Document No.: F-MN-L-213-rev.25 Issuing Authority: Pace Minnesota Quality Office Sample Condition Upon Receipt Courier: Tracking Number: Client Name: 'PAT f,75CacM., !o_--‘ Vic-, ®Fed Ex CUPS CUSPS ❑Client 1 ❑Pace ❑SpeeDee ❑Commercial see Exception /Ill(,1 6l3' (11)i Project Custody Seal on Cooler/Box Present? 0Yes ❑No Seals Intact? 5§Yes ONO Biological Tissue Frozen? ❑Yes ❑No ®N/A Packing Material: l]Bubble Wrap MBubble Bags ❑None ❑Other: Temp Blank? [Yes kJNo Thermometer: ❑ G87A9155100842 X G87A9170600254 Type of ice: Wet ❑Blue ❑None ❑Dry ❑Melted Note: Each West Virginia Sample must have temp taken (no temp blanks) Temp should be above freezing to 6`c Cooler Temp Read w/temp blank: °C Correction Factor: �r �/t Cooler Temp Corrected w/temp blank : °C Average Corrected Temp See Exceptions (no tempblank only): J 3 °c USDA Regulated Soil: (❑ N/A, water sample/Other: ) Date/Initials of Person Examining Contents: Did samples originate in a quarantine zone within the United States: AL, AR, CA, FL, GA, Did samples originate from a foreign source (internationally, including ID, LA. MS, NC, NM, NY, OK, OR, SC, TN, TX or VA (check maps)? MYes ❑No Hawaii and Puerto Rico)? ❑Yes JNo If Yes to either question, fill out a Regulated Soil Checklist (F-MN-Q-338) and include with SCUR/COC paperwork. COMMENTS: Chain of Custody Present and Filled Out? ijtgYes ❑No 1. Chain of Custody Relinquished? JKlYes ❑No 2. Sampler Name and/or Signature on COC? Oyes ❑N° ©N/A 3. Samples Arrived within Hold Time? Yes No 4. Short Hold Time Analysis (<72 hr)? ❑Yes .®No 5. ❑Fecal Coliform ❑HPC ❑Total Coliform/E coli ❑BOD/cBOD ['Hex Chrome ['Turbidity ❑Nitrate ❑Nitrite ❑Orthophos Dother lush Turn Around Time Requested? j JYes ❑No 6. efficient Volume? ($jYes ❑_No 7. Correct Containers Used? -Pace Containers Used? JYes ®Yes ❑No CND 8. Containers Intact? NYes ONO 9. Field Filtered Volume Received for Dissolved Tests? Dyes ❑No ®N/A 10. Is sediment visible in the dissolved container? • Yes • No Is sufficient information available to reconcile the samples to the COC? Matrix: ❑Water 1XISoil ❑Oil ❑Other }]Yes ❑No 11. If no, write ID/ Date/Time on Container Below: See Exception ❑ All containers needing acid/base preservation have been checked? All containers needing preservation are found to be in compliance with EPA recommendation? (HNO3, H2SO4, <2pH, NaOH >9 Sulfide, NaOH>12 Cyanide) Exceptions: VOA, Coliform, TOC/DOC Oil and Grease, DRO/8015 (water) and Dioxin/PFAS Oyes ❑Yes ❑Yes ❑No DNo ❑No AjN/A (LN/A ®N/A 12. Sample # • NaOH IN HNO3 ■ H2SO4 ■Zinc Acetate Positive for Res. ['Yes See Exception Chlorine? ❑No Headspace in VOA Vials (greater than 6mm)? ❑Yes ❑No s[jt NJA 13. See Exception ❑ Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes ❑Yes ❑No ❑No IDN/A tON/A 14. t 4y �)) Pace Trip Blank Lot # (if purchased): F�.J �f-� CLIENT NOTIFICATION/RESOLUTION Person Contacted: Comments/Resolution: Project Manager Review: Note: Whenever there is a discrepancy affecting North Carolina compliance moles, a copy of this form will be sent to the North Carolina DEH NiR Certification Office (i.e out of hold, incorrect preservative, out of temp, incorrect containers). Date/Time: Field Data Required? ❑Yes ❑No Date: 4/1/19 Labeled by: Report No 104689228290FCDFR Page 87 of 97 Page 6 of 16 ei f P'iceAnaIyt/Ca1 Documen: Name: SCUR Exception Form —Coolers Above 6°C Document Revised: 04feb2019 Page 1 of 1 Document No.: F-M N-C-298-Rev.01 Issuing Authority: Pace Minnesota Quality Office SCUR Exceptions: During sample triage, this form is to be placed in each cooler that arrives above 6.0 degrees Celsius Workorder #: Container Out of Temp Sample IDs Type Other Issues # of Containers PM Notified? Elves No If yes, indicate who was contacted/date/time. If no, indicate reason why. Multiple Cooler Project? ❑Yes ❑No if you answered yes, fill out Information to the left. Issue Type: Sample ID Container Type # of Containers No Temp Blank Read Corrected Temp Temp Average Temp Tracking Number H Adjustment Log for Preserved Samples Sample ID Type of Preserv. pH Upon Receipt Date Adjusted Time Adjusted Amount Added (mL) Lot #t Added pH After In Compliance after addition? Ini:ials ❑Yes No ❑Yes No Yes ❑No Yes III No Report No 10468922_8290FC_DFR Page 88 of 97 Page 7 of 16 / „PaceAnalytical Document Name: Regulated Soil Checklist Document Revised: 13Feb2018 Page 1 of 2 Document No.: F-MN-Q-338-Rev.06 Issuing Authority: Pace Minnesota Quality Office USDA REGULATED SOIL CHECKLIST To Be Completed by SR Staff: WO: 10468922 Sample Origin (circle one): DOMESTIC Date: (\ QUARANTINED Initials: FOREIGN (Note: soil samples from Hawaii, Guam, Puerto Rico and the US Virgin Islands are considered to be of a Foreign Source) If Domestic, circle State of Origin: AL AR CA L} GA LA MS NC NM NY OK OR SC TN TX VA (Includes: !FA, SOD, Golden Nematode, Kama! Bunt and Witchweed)List County: ; ( (�.� r..., - i fir (USDA Permit/Compliance Agreement authorizes movement of samples from these domestic regulated zones) If Quarantined, circle State of Origin: FL ID TX CA List County: (Includes Fruit Fly, Giant African Snail and Pale Cyst Nematode) (Movement is not authorized for Pale Cyst Nematode (ID or Giant African Snail (FLJ, remaining quarantines require additional paperwork) If Foreign, list Country of Origin: (Movement from some Canadian Providences is not allowed. Refer to CS-232 Regulated Soil Flow Chart) REQUIREMENT ACTION COMPLETED PPQ-530 Paperwork must be included for any samples from counties with a Fruit Fly Quarantine in TX. Refer to MN-S063 through MN-S065 Scan PPQ-530 to the corresponding Project folder on the x drive. If PPQ-530 is not present, contact the Waste Coordinator and do not continue processing samples. YES NO N/A Samples from ID may not be moved from the quarantined region. Refer to MN-SOSS If samples originated in a quarantined zone, contact the Waste Coordinator and do not continue processing samples. YES NO /A� Samples from Giant African Snail Quarantine in FL may not be moved from the quarantined region. Refer to MN-S068 If samples originated in a quarantined zone, contact the Waste Coordinator and do not continue processing samples. YES NO P. ! REQUIREMENT ACTION - COMPLETED "Special Handling" stickers are to be placed on all samples. Did "special handling" stickers get placed on all sample containers? ,YE NO Samples must be segregated and stored in designated bins, shelves and coolers. Were samples placed in a designated cooler, containers and shelves? ,^ t> NO Samples must be double contained to prevent accidental release. Were there any signs of breakage or leakage (check for broken glass and/or loose soil in the cooler)? If NO, ice and melt water can be disposed of by normal process (down YES 6.1 the drain). If YES, were ice and melt water separated from the cooler and disposed of properly? Any broken glass and/or loose soil are to be bagged and placed in a container or active drum (see Waste Coordinator). Ice and melt water should be baked at a temperature range of 121-154°F cooled before going down the drain. YES NOA USDA Regulated satellite for 2 hours and then Equipment and supplies that have come into contact samples must be decontaminated. Was the cooler(s) and/or countertop(s) decontaminated using either a fresh 10% bleach solution or 70% ethanol? (Gloves and other lab supplies will be bagged and placed in the USDA Regulated satellite container or active drum). `` "> /YES,) NO Comments: Report No 104689228290FCDFR Page 89 of 97 Page 8 of 16 v=i f �f ,.-PaceAnalytical Document Name: Regulated Soil Checklist Document Revised; 13Feb2018 Page 2 of 2 Document No.: F-MN-Q-338-Rev.06 issuing Authority: Pace Minnesota Quality Office To Be Completed by PM and/or PC: Sample Analysis to be conducted (circle all that apply): Name of Subcontract Lab (s): MN Subcontract Lab REQUIREMENT ACTION COMPLETED Permission to ship untreated soil must be on file prior to shipping to any subcontract lab, including IR Pace Labs. Go to: J:\SHARE\PRJ_MGR\10_Client Services Department Documents\Regulated Soils Permits— if permission to ship letter is not there, contact the Waste Coordinator. YES NO N/A Shipment must include a valid copy of the receiving lab's permit as well as permission to ship letter. Is a copy of all needed paperwork included with the COC? Do NOT ship samples until all necessary paperwork is compiled. 1 YES NO N/A Comments: Project Manager Signature: Vrivd34y-f-,\ Report No 104689228290FC_DFR Date: 4/1/19 Page 90 of 97 Page 9 of 16 --681.41LEZEIVIMMiSLWA101=1122.47.,14., Giant African Land Snail (GALS) Miami -Dade and Broward Counties, July, 2018 . „ TI7X225Za. IliMIPAPIATAPTEEMPall, Quarantine Zones , , . , •-,,,,„...., „, . - "7-7------.--77----77- t FiErlatior- , •,. _ i__ 1:1 c56, : F:59540'5,!tp BI)/5) ,, _ ..5, ,.: ,-...5 . , cii t hi.• •I''•:---5 ilPTERS{l' 4,5\n.E51Va : -!•A • .. =,' a :...., :), i , 6 ;.,- ...! :-. , .. .!.. ::: „ : :: : -,,, .=,=',' .., ,,-,:•-,,-- --E:i ',.8 m /2, : iP • i-- 1,5§5 i i :, 2C:,A 7' ;Z nu ,c ..1 5F- rrn ' , ; ,„ •_•,'"..—: 1 VI ig • 4t,.):.:1:,1,.,iE = ,,r.,-5,, !. rnb 5, :a ,..„i • 515.f5, . . ''..'••' •• ',, (,, ts;11' '5, 41'8!'r r, cfilrFIN RE.*-f tg •,- • , ,.L:.'_ '... ' • !! g co ' -on,' '1•51,3 AD ' . - - ', 'i--.'z z " • 7,-.' , 0(1459- City i'm.. Filip-oPNIsT •-u, . 1 --Vs'. -, lAtf..6-1.....;'.. •_• ; - : ' ''' : !,7-, .. - . -,•-:M . nrifiStIWS1",‘ trip.3.', ,)4' wif„ '. -- • ' bi' ;FT... P‘ in;-- -4-8 • - •• Fmpz$Rty.1.?_1—'. • • -- '-.1.. ' ' ik'' : i • , 4 k Penl?r6(4 iPP:6.0.%)1Ft, - i , , . • , ,•- .r. r- t . i • • ...!...--,''');:......"'..--4;.r--'' •—;.. ,-;%415:"-- „--.....--i.. . f .. J• 4 4 . 44( . , , , VW CI : - 5 5"c.i 5 -90 . , . 5-:7, Par P.go q14114q 4,1.3:111 4 V42104:31&17,4,3 . . .." . IL e4h • j ny.vi rirCtilit4a1A.,14,' 14. Tani '! 131, WO-Tti'gre;"— , _ ;#12—• • 7d5-' pithrtioixitri t a ' ' . •*. • 4 Rid g- .65,54 . • 'Hfightd4. .0.41 5 \P,T!• D: 1 14i..)4E =in=zionm= 0 El GALS Quarantine Zones 3 75 7 5 16 Wes Report No 10468922_8290FC DFR 1,44P Wt/AA-1004 USDA r.5--411-5Tfi Page 91 of 97 Page 10 of 16 Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 AnalyticalTM +� Reporting Flags A = Reporting Limit based on signal to noise B = Less than 10x higher than method blank level C = Result obtained from confirmation analysis D = Result obtained from analysis of diluted sample E = Exceeds calibration range I = Interferencepresent J = Estimated value L = Suppressive interference, analyte may be biased low Nn = Value obtained from additional analysis P = PCDElnterference R = Recovery outside target range S = Peak saturated U = Analyte not detected V = Result verified by confirmation analysis X = %D Exceeds limits Y = Calculated using average of daily RFs * = SeeDiscussion REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10468922_8290FC_DFR Page 11 of 16 Tel: 612-607-1700 Fax: 612-607-6444 Page 92 of 97 Appendix B Sample Analysis Summary Report No 10468922_8290FC_dNck'e Analytical Services, Inc. Page 93 of 97 Page 12 of 16 7/e Analytic Client's Sample ID Lab Sample ID Filename Injected By Total Amount Extracted Moisture Dry Weight Extracted ICAL ID CCaI Filename(s) Method Blank ID Native Isomers SB-9 (2-4') 35457287006 Y190412B_14 JRH 12.8 g 21.7 10.1 g Y190110 Y190412B_02 BLANK-69708 Conc EMPC ng/Kg ng/Kg TM Metho d 8290 Sample Analysis Results Client - PASI Florida Matrix Dilution Collected Received & Y190412B_16 Extracted Analyzed Internal Standards 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD 1.5 14 0.91 52 0.64 U 1.9 32 0.65 U 8.4 0.81 1.3 0.33 U 22 1.9 9.1 5.8 100 10 0.34 U 34 240 510 23 1800 1.5 EDL ng/Kg 0.39 0.39 0.26 J 0.26 0.64 0.48 J 0.56 0.65 0.65 0.39 J 0.56 PJ 0.21 J 0.33 0.37 0.92 J 0.45 0.29 0.55 0.34 0.34 0.34 1.4 1.4 0.62 1.3 Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis. MN 55414 Tel: 612-607-1700 Fax: 612- 607-6444 Solid NA 03/26/2019 10:14 03/30/2019 09:20 04/08/2019 15:30 04/13/2019 02:47 2,3,7,8-TCDF-13C 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 2,3,4,7,8-PeCDF-13C 1,2,3,7,8-PeCDD-13C 1 ,2,3,4,7,8-HxCDF-1 3C 1,2,3,6,7,8-HxCDF-13C 2,3,4,6,7,8-HxCDF-13C 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 1,2,3,6,7,8-HxCDD-13C 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37C14 ng's Percent Added Recovery 2.00 65 2.00 70 2.00 65 2.00 63 2.00 77 2.00 65 2.00 56 2.00 58 2.00 52 2.00 64 2.00 50 2.00 35 R 2.00 29 R 2.00 37 R 4.00 20 R 2.00 NA 2.00 NA 0.20 63 Total 2, 3, 7, 8-TC D D Equivalence: 8.5 ng/Kg (Lower -bound - Using ITE Factors) Conc = Concentration (Totals include 2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit ND = Not Detected NA = Not Applicable NC = Not Calculated Results reported on a dry weight basis and are valid to no more than 2 significant figures. J = Estimated value R = Recovery outside target range P = PCDE Interference REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services. Inc. Report No 10468922_8290FC_DFR Page 13 of 16 Page 94 of 97 ace Analytical TM Clients Sample ID Lab Sample ID Filename Injected By Total Amount Extracted % Moisture Dry Weight Extracted ICAL ID CCal Filename(s) Method Blank ID Native Isomers Method 8290 Sample Analysis Results Client - PASI Florida SB-12 (6-7') 35457287017 Y190412B_15 JRH 16.2 g 37.3 10.2 g Y190110 Y190412B_02 BLANK-69708 Conc ng/Kg 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD EMPC ng/Kg 2.5 Matrix Dilution Collected Received & Y190412B_16 Extracted Analyzed EDL Internal ng/Kg Standards Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612- 607-6444 Solid NA 03/26/2019 12:08 03/30/2019 09:20 04/08/2019 15:30 04/13/2019 03:34 1.2 P 19 1.2 37 0.44 U 1.9 33 0.98 0.31 IJ - - 0.31 0.44 0.48 J 0.46 2.7 0.42 J 42 0.42 0.82 2.0 0.19 U 11 3.0 11 8.1 140 8.0 0.94 30 1.1 0.32 J 0.24 J 0.15 IJ 0.19 0.23 0.25 J 0.72 0.28 0.42 0.35 0.28 J 0.31 260 0.33 540 0.33 16 0.63 2100 0.47 2,3,7,8-TCDF-13C 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 2,3,4,7,8-PeCDF-1 3C 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 1,2,3,6,7,8-HxCDF-13C 2,3,4,6,7,8-HxCDF-13C 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 1,2,3,6,7,8-HxCDD-13C 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C ng's Percent Added Recovery 2.00 65 2.00 70 2.00 66 2.00 67 2.00 80 2.00 68 2.00 59 2.00 60 2.00 51 2.00 68 2.00 52 2.00 44 2.00 42 2.00 53 4.00 40 1,2,3,4-TCDD-13C 2.00 NA 1,2,3,7,8,9-HxCDD-13C 2.00 NA 2,3,7,8-TCDD-37CI4 0.20 69 Total 2, 3, 7, 8-TC D D Equivalence: 11 ng/Kg (Lower -bound - Using ITE Factors) Conc = Concentration (Totals include 2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit ND = Not Detected NA = Not Applicable NC = Not Calculated Results reported on a dry weight basis and are valid to no more than 2 significant figures. J = Estimated value P = PCDE Interference I= Interference present REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10468922_8290FC_DFR Page 14 of 16 Page 95 of 97 Pace Analytical Services. LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 AnalyticalTM Lab Sample Name Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) Metho d 8290 Blank Analysis Results DFBLKMC BLANK-69708 F190412B_05 10.2 g F190112 F190412A_16 & F190412B_16 Native Conc Isomers ng/Kg 2,3,7,8-TCDF 0.20 U Total TCDF 0.20 U 2,3,7,8-TCDD 0.28 U Total TCDD 0.28 U 1,2,3,7,8-PeCDF 0.26 U 2,3,4,7,8-PeCDF 0.14 U Total PeCDF 0.20 U 1,2,3,7,8-PeCDD 0.25 U Total PeCDD 0.25 U 1,2,3,4,7,8-HxCDF 0.21 U 1,2,3,6,7,8-HxCDF 0.19 U 2,3,4,6,7,8-HxCDF 0.21 U 1,2,3,7,8,9-HxCDF 0.31 U Total HxCDF 0.23 U 1,2,3,4,7,8-HxCDD 0.25 U 1,2,3,6,7,8-HxCDD 0.27 U 1,2,3,7,8,9-HxCDD 0.25 U Total HxCDD 0.26 U 1,2,3,4,6,7,8-HpCDF 0.27 U 1,2,3,4,7,8,9-HpCDF 0.38 U Total HpCDF 0.32 U 1,2,3,4,6,7,8-HpCDD 0.38 U Total HpCDD 0.38 U OCDF 1.6 U OCDD 1.4 U EMPC EDL ng/Kg ng/Kg Matrix Dilution Extracted Analyzed Injected By Internal Standards Tel: 612-607-1700 Fax: 612-607-6444 Solid NA 04/08/2019 15:30 04/12/2019 15:59 JRH 0.20 2,3,7,8-TCDF-13C 0.20 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 0.28 2,3,4,7,8-PeCDF-13C 0.28 1 ,2,3,7,8-PeCDD-1 3C 1 ,2,3,4,7,8-HxCDF-1 3C 0.26 1,2,3,6,7,8-HxCDF-13C 0.14 2,3,4,6,7,8-HxCDF-13C 0.20 1,2,3,7,8,9-HxCDF-13C 1,2, 3,4,7, 8-HxCDD-13C 0.25 1,2,3,6,7,8-HxCDD-13C 0.25 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1 ,2,3,4,6,7,8-HpCDD-1 3C OCDD-13C 0.21 0.19 0.21 0.31 0.23 0.25 0.27 0.25 0.26 ng's Percent Added Recovery 2.00 57 2.00 58 2.00 67 2.00 68 2.00 77 2.00 59 2.00 65 2.00 62 2.00 53 2.00 60 2.00 58 2.00 51 2.00 48 2.00 52 4.00 42 1,2,3,4-TCDD-13C 2.00 NA 1,2,3,7,8,9-HxCDD-13C 2.00 NA 2,3,7,8-TCDD-37014 0.20 57 0.27 Total 2,3,7,8-TCDD 0.38 Equivalence: 0.00 ng/Kg 0.32 (Lower -bound - Using ITE Factors) 0.38 0.38 1.6 1.4 Conc= Concentration (Totals include2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit Results reported on a total weight basis and are valid to no more than 2 significant figures. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10468922_8290FC_DFR Page 15 of 16 Page 96 of 97 Pace Analytical Services. LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Analytical Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) Method Blank ID Native Isomers 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD TM Method 8290 Laboratory Control Spike Results Qs (ng) 0.20 LCS-69709 F190412B_15 10.2 g F190112 F190412A16 & F190412B16 BLANK-69708 Qm (ng) 0.23 0.20 0.23 1.0 1.0 1.1 1.2 1.0 0.98 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 2.0 2.0 1.2 1.1 1.1 1.1 1.1 1.2 1.1 1.2 1.1 1.0 2.1 2.2 Rec. Matrix Dilution Extracted Analyzed Injected By Internal Standards 113 2,3,7,8-TCDF-13C 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 115 2,3,4,7,8-PeCDF-13C 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 113 1,2,3,6,7,8-HxCDF-13C 117 2,3,4,6,7,8-HxCDF-13C 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 98 1,2,3,6,7,8-HxCDD-13C 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 121 1,2,3,4,6,7,8-HpCDD-13C 110 OCDD-13C 107 107 113 123 109 118 107 104 104 112 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37C14 Tel: 612-607-1700 Fax: 612-607-6444 Solid NA 04/08/2019 15:30 04/12/2019 23:10 JRH ng's Percent Added Recovery 2.0 64 2.0 65 2.0 74 2.0 75 2.0 86 2.0 63 2.0 69 2.0 71 2.0 61 2.0 66 2.0 66 2.0 62 2.0 55 2.0 61 4.0 46 2.0 NA 2.0 NA 0.20 69 Qs = Quantity Spiked Qm = Quantity Measured Rec. = Recovery (Expressed as Percent) R = Recovery outside of target range Y = RF averaging used in calculations Nn = Value obtained from additional analysis NA = Not Applicable * = See Discussion REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10468922_8290FCDFR Page 97 of 97 Page 16 of 16 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 April 04, 2019 Thuysi Ho EE&G Environmental Services, LLC 5751 Miami Lakes Dr. Hialeah, FL 33014 RE: Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Dear Thuysi Ho: Enclosed are the analytical results for sample(s) received by the laboratory on March 28, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Craig Clevenger. EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 97 ceAnalytical® www.pacelabs.com CERTIFICATIONS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 97 aceAnalytical www.pacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35457430001 SB-13 (0-0.5') Solid 03/27/19 08:45 03/28/19 17:45 35457430002 SB-13 (0.5-2') Solid 03/27/19 08:47 03/28/19 17:45 35457430003 SB-13 (2-4') Solid 03/27/19 08:49 03/28/19 17:45 35457430004 SB-13 (4-6') Solid 03/27/19 08:51 03/28/19 17:45 35457430005 SB-14 (0-0.5') Solid 03/27/19 09:10 03/28/19 17:45 35457430006 SB-14 (0.5-2') Solid 03/27/19 09:12 03/28/19 17:45 35457430007 SB-14 (2-4') Solid 03/27/19 09:14 03/28/19 17:45 35457430008 SB-15 (0-0.5') Solid 03/27/19 09:25 03/28/19 17:45 35457430009 SB-15 (0.5-2') Solid 03/27/19 09:27 03/28/19 17:45 35457430010 SB-15 (2-4') Solid 03/27/19 09:29 03/28/19 17:45 35457430011 SB-15 (4-6') Solid 03/27/19 09:31 03/28/19 17:45 35457430012 SB-15 (6-8') Solid 03/27/19 09:33 03/28/19 17:45 35457430013 SB-16 (0-0.5') Solid 03/27/19 09:50 03/28/19 17:45 35457430014 SB-16 (0.5-2') Solid 03/27/19 09:52 03/28/19 17:45 35457430015 SB-16 (2-4') Solid 03/27/19 09:54 03/28/19 17:45 35457430016 SB-16 (4-6') Solid 03/27/19 09:56 03/28/19 17:45 5457430017 SB-16 (6-8') Solid 03/27/19 09:58 03/28/19 17:45 35457430018 SB-17 (0-0.5') Solid 03/27/19 10:30 03/28/19 17:45 35457430019 SB-17 (0.5-2') Solid 03/27/19 10:32 03/28/19 17:45 35457430020 SB-17 (2-4') Solid 03/27/19 10:34 03/28/19 17:45 35457430021 SB-17 (4-6') Solid 03/27/19 10:36 03/28/19 17:45 35457430022 SB-18 (0-0.5') Solid 03/27/19 10:50 03/28/19 17:45 35457430023 SB-18 (0.5-2') Solid 03/27/19 10:52 03/28/19 17:45 35457430024 SB-18 (2-4') Solid 03/27/19 10:54 03/28/19 17:45 35457430025 SB-18 (4-6') Solid 03/27/19 10:56 03/28/19 17:45 35457430026 SB-18 (6-8') Solid 03/27/19 10:58 03/28/19 17:45 35457430027 SB-19 (0-0.5') Solid 03/27/19 11:20 03/28/19 17:45 35457430028 SB-19 (0.5-2') Solid 03/27/19 11:22 03/28/19 17:45 35457430029 SB-19 (2-4') Solid 03/27/19 11:24 03/28/19 17:45 35457430030 SB-20 (0-0.5') Solid 03/27/19 11:40 03/28/19 17:45 35457430031 SB-20 (0.5-2') Solid 03/27/19 11:42 03/28/19 17:45 35457430032 SB-20 (2-4') Solid 03/27/19 11:44 03/28/19 17:45 35457430033 SB-21 (0-0.5') Solid 03/27/19 12:10 03/28/19 17:45 35457430034 SB-21 (0.5-2') Solid 03/27/19 12:12 03/28/19 17:45 35457430035 SB-21 (2-4') Solid 03/27/19 12:14 03/28/19 17:45 35457430036 SB-21 (4-6') Solid 03/27/19 12:16 03/28/19 17:45 35457430037 SB-21 (6-8') Solid 03/27/19 12:18 03/28/19 17:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 97 aceAnalytical www.pacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35457430038 SB-22 (0-0.5') Solid 03/27/19 12:30 03/28/19 17:45 35457430039 SB-22 (0.5-2') Solid 03/27/19 12:32 03/28/19 17:45 35457430040 SB-22 (2-4') Solid 03/27/19 12:34 03/28/19 17:45 35457430041 SB-22 (4-6') Solid 03/27/19 12:36 03/28/19 17:45 35457430042 SB-23 (0-0.5') Solid 03/27/19 12:50 03/28/19 17:45 35457430043 SB-23 (0.5-2') Solid 03/27/19 12:52 03/28/19 17:45 35457430044 SB-23 (2-4') Solid 03/27/19 12:54 03/28/19 17:45 35457430045 SB-23 (4-6') Solid 03/27/19 12:56 03/28/19 17:45 35457430046 SB-24 (0-0.5') Solid 03/27/19 13:05 03/28/19 17:45 35457430047 SB-24 (0.5-2') Solid 03/27/19 13:07 03/28/19 17:45 35457430048 SB-24 (2-4') Solid 03/27/19 13:09 03/28/19 17:45 35457430049 SB-24 (4-6') Solid 03/27/19 13:11 03/28/19 17:45 35457430050 SB-25 (0-0.5') Solid 03/27/19 13:30 03/28/19 17:45 35457430051 SB-25 (0.5-2') Solid 03/27/19 13:32 03/28/19 17:45 35457430052 SB-25 (2-4') Solid 03/27/19 13:34 03/28/19 17:45 35457430053 SB-25 (4-6') Solid 03/27/19 13:36 03/28/19 17:45 35457430054 SB-26 (0-0.5') Solid 03/27/19 13:46 03/28/19 17:45 35457430055 SB-26 (0.5-2') Solid 03/27/19 13:48 03/28/19 17:45 35457430056 SB-26 (2-4') Solid 03/27/19 13:50 03/28/19 17:45 35457430057 SB-27 (0-0.5') Solid 03/27/19 14:00 03/28/19 17:45 35457430058 SB-27 (0.5-2') Solid 03/27/19 14:02 03/28/19 17:45 35457430059 SB-27 (2-4') Solid 03/27/19 14:04 03/28/19 17:45 35457430060 SB-28 (0-0.5') Solid 03/27/19 14:24 03/28/19 17:45 35457430061 SB-28 (0.5-2') Solid 03/27/19 14:26 03/28/19 17:45 35457430062 SB-28 (2-4') Solid 03/27/19 14:28 03/28/19 17:45 35457430063 SB-28 (4-6') Solid 03/27/19 14:30 03/28/19 17:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 97 SAMPLE ANALYTE COUNT Project: 2018-3057/Melrese Golf Course Pace Project No.. 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Analytes Method Analysts Reported Laboratory 35457430001 SB-13 (0-0.5') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430002 SB-13 (0.5-2') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430003 SB-13 (2-4') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430004 SB-13 (4-6') EPA 6010 JWP, LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430005 SB-14 (0-0.5') EPA 6010 JWP. LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430006 SB-14 (0.5-2') EPA 6010 JWP, LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430007 SB-14 (2-4') EPA 6010 JWP, LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430008 SB-15 (0-0.5') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430009 SB-15 (0.5-2') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430010 SB-15 (2-4') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430011 SB-15 (4-6') EPA 6010 JWP, LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430012 SB-15 (6-8') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430013 SB-16 (0-0.5') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430014 SB-16 (0.5-2') EPA 6010 JWP 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430015 SB-16 (2-4') EPA 6010 JWP 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430016 SB-16 (4-6') EPA 6010 JWP 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430017 SB-16 (6-8') EPA 6010 JWP 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430018 SB-17 (0-0.5') EPA6010 JWP 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430019 SB-17 (0.5-2') EPA 6010 JWP 3 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 97 SAMPLE ANALYTE COUNT Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Analytes Method Analysts Reported Laboratory ASTM D2974-87 CLT 1 PASI-0 35457430020 SB-17 (2-4') EPA6010 JWP 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430021 SB-17 (4-6') EPA 6010 JWP 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430022 SB-18 (0-0.5') EPA 6010 JWP 3 PASI-O ASTM D2974-87 CLT 1 PASI-0 35457430023 SB-18 (0.5-2') EPA 6010 JWP 3 PASI-0 ASTM D2974-87 CLT 1 PASI-O 35457430024 SB-18 (2-4') EPA 6010 JWP 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430025 SB-18 (4-6') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430026 SB-18 (6-8') EPA 6010 JWP 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430027 SB-19 (0-0.5') EPA 6010 JWP 3 PASI-0 ASTM D2974-87 CLT 1 PASI-0 35457430028 SB-19 (0.5-2') EPA6010 JWP 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430029 SB-19 (2-4') EPA 6010 JWP 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430030 SB-20 (0-0.5') EPA 6010 JWP 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430031 SB-20 (0.5-2') EPA 6010 JWP 3 PASI-0 ASTM D2974-87 CLT 1 PASI-0 35457430032 SB-20 (2-4') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430033 SB-21 (0-0.5') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430034 SB-21 (0.5-2') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430035 SB-21 (2-4') EPA 6010 LEC 3 PASI-0 ASTM D2974-87 CLT 1 PASI-0 35457430036 SB-21 (4-6') EPA 6010 LEC 3 PASI-0 ASTM D2974-87 CLT 1 PASI-0 35457430037 SB-21 (6-8') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 97 SAMPLE ANALYTE COUNT Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Analytes Method Analysts Reported Laboratory 35457430038 SB-22 (0-0.5') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430039 SB-22 (0.5-2') EPA6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430040 SB-22 (2-4') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430041 SB-22 (4-6') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430042 SB-23 (0-0.5') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430043 SB-23 (0.5-2') EPA6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430044 SB-23 (2-4') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430045 SB-23 (4-6') EPA 6010 JWP 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430046 SB-24 (0-0.5') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430047 SB-24 (0.5-2') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430048 SB-24 (2-4') EPA6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430049 SB-24 (4-6') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430050 SB-25 (0-0.5') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430051 SB-25 (0.5-2') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430052 SB-25 (2-4') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430053 SB-25 (4-6') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430054 SB-26 (0-0.5') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430055 SB-26 (0.5-2') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430056 SB-26 (2-4') EPA 6010 LEC 3 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 97 aceAnalytical www.pacelabs.com SAMPLE ANALYTE COUNT Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory ASTM D2974-87 CLT 1 PASI-O 35457430057 SB-27 (0-0.5') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430058 SB-27 (0.5-2') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430059 SB-27 (2-4') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430060 SB-28 (0-0.5') EPA6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430061 SB-28 (0.5-2') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430062 SB-28 (2-4') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O 35457430063 SB-28 (4-6') EPA 6010 LEC 3 PASI-O ASTM D2974-87 CLT 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 97 aceAnalytical® www.pacelabs.com SUMMARY OF DETECTION Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35457430001 SB-13 (0-0.5') EPA 6010 Arsenic 2.5 mg/kg 0.63 04/04/19 14:10 EPA 6010 Barium 7.8 mg/kg 0.63 04/04/19 14:10 EPA 6010 Lead 13.7 mg/kg 0.63 04/04/19 14:10 ASTM D2974-87 Percent Moisture 11.9 % 0.10 04/04/19 10:55 35457430002 SB-13 (0.5-2') EPA 6010 Arsenic 1.7 mg/kg 0.61 04/04/19 14:13 EPA 6010 Barium 88.8 mg/kg 0.61 04/04/19 14:13 EPA 6010 Lead 11.0 mg/kg 0.61 04/04/19 14:13 ASTM D2974-87 Percent Moisture 10.6 % 0.10 04/04/19 10:55 35457430003 SB-13 (2-4') EPA 6010 Arsenic 47.0 mg/kg 1.2 04/04/19 14:16 EPA 6010 Barium 19.4 mg/kg 1.2 04/04/19 14:16 EPA 6010 Lead 16.6 mg/kg 1.2 04/04/19 14:16 ASTM D2974-87 Percent Moisture 50.7 % 0.10 04/04/19 10:55 35457430004 SB-13 (4-6') EPA 6010 Arsenic 3.6 mg/kg 0.49 04/04/19 14:19 EPA 6010 Barium 22.3 mg/kg 0.49 04/04/19 14:19 -PA 6010 Lead 395 mg/kg 48.5 04/04/19 16:14 ASTM D2974-87 Percent Moisture 11.8 % 0.10 04/04/19 10:56 35457430005 SB-14 (0-0.5') EPA6010 Arsenic 31.0 mg/kg 0.53 04/04/19 14:21 EPA 6010 Barium 25.5 mg/kg 0.53 04/04/19 14:21 EPA 6010 Lead 165 mg/kg 5.3 04/04/19 16:17 ASTM D2974-87 Percent Moisture 9.9 % 0.10 04/04/19 10:56 35457430006 SB-14 (0.5-2') EPA 6010 Arsenic 15.8 mg/kg 3.3 04/04/19 14:24 EPA 6010 Barium 145 mg/kg 3.3 04/04/19 14:24 EPA 6010 Lead 1110 mg/kg 65.7 04/04/19 16:20 ASTM D2974-87 Percent Moisture 13.7 ok 0.10 04/04/19 10:56 35457430007 SB-14 (2-4') EPA 6010 Arsenic 63.0 mg/kg 3.4 04/04/19 14:27 EPA 6010 Barium 523 mg/kg 3.4 04/04/19 14:27 EPA 6010 Lead 1210 mg/kg 6.8 04/04/19 16:23 ASTM D2974-87 Percent Moisture 23.5 % 0.10 04/04/19 10:56 35457430008 SB-15 (0-0.5') EPA 6010 Arsenic 2.8 mg/kg 0.54 04/04/19 14:30 EPA 6010 Barium 7.7 mg/kg 0.54 04/04/19 14:30 EPA 6010 Lead 8.8 mg/kg 0.54 04/04/19 14:30 ASTM D2974-87 Percent Moisture 11.5 % 0.10 04/04/19 10:56 35457430009 SB-15 (0.5-2') EPA 6010 Arsenic 12.0 mg/kg 0.56 04/04/19 14:41 EPA6010 Barium 15.3 mg/kg 0.56 04/04/19 14:41 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 97 aceAnalytical wwwpacelabs.com SUMMARY OF DETECTION Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35457430009 SB-15 (0.5-2') EPA 6010 Lead 85.7 mg/kg 0.56 04/04/19 14:41 ASTM D2974-87 Percent Moisture 12.5 % 0.10 04/04/19 10:56 35457430010 SB-15 (2-4') EPA 6010 Arsenic 14.4 mg/kg 3.8 04/04/19 14:44 EPA 6010 Barium 124 mg/kg 3.8 04/04/19 14:44 EPA 6010 Lead 168 mg/kg 3.8 04/04/19 14:44 ASTM D2974-87 Percent Moisture 35.1 % 0.10 04/04/19 10:56 35457430011 SB-15 (4-6') EPA 6010 Arsenic 40.0 mg/kg 4.0 04/04/19 14:47 EPA 6010 Barium 714 mg/kg 4.0 04/04/19 14:47 EPA 6010 Lead 1870 mg/kg 79.4 04/04/19 16:25 ASTM D2974-87 Percent Moisture 32.2 % 0.10 04/04/19 10:56 35457430012 SB-15 (6-8') EPA 6010 Arsenic 25.0 mg/kg 8.9 04/04/19 14:50 EPA 6010 Barium 39.3 mg/kg 8.9 04/04/19 14:50 EPA 6010 Lead 61.8 mg/kg 8.9 04/04/19 14:50 ASTM D2974-87 Percent Moisture 70.9 % 0.10 04/04/19 10:56 35457430013 SB-16 (0-0.5') EPA 6010 Arsenic 0.94 mg/kg 0.65 04/04/19 14:52 EPA 6010 Barium 5.3 mg/kg 0.65 04/04/19 14:52 EPA 6010 Lead 5.7 mg/kg 0.65 04/04/19 14:52 ASTM D2974-87 Percent Moisture 10.1 % 0.10 04/04/19 10:56 35457430014 SB-16 (0.5-2') EPA 6010 Arsenic 10.4 mg/kg 0.64 04/04/19 13:17 EPA 6010 Barium 10.3 mg/kg 0.64 04/04/19 13:17 EPA 6010 Lead 3.4 mg/kg 0.64 04/04/19 13:17 ASTM D2974-87 Percent Moisture 30.1 % 0.10 04/04/19 10:56 35457430015 SB-16 (2-4') EPA 6010 Arsenic 3.0 mg/kg 0.68 04/04/19 13:20 EPA 6010 Barium 33.4 mg/kg 0.68 04/04/19 13:20 EPA 6010 Lead 113 mg/kg 0.68 04/04/19 13:20 ASTM D2974-87 Percent Moisture 13.1 % 0.10 04/04/19 10:56 35457430016 SB-16 (4-6') EPA 6010 Arsenic 3.4 mg/kg 0.59 04/04/19 13:22 EPA 6010 Barium 20.4 mg/kg 0.59 04/04/19 13:22 EPA 6010 Lead 26.5 mg/kg 0.59 04/04/19 13:22 ASTM D2974-87 Percent Moisture 16.6 % 0.10 04/04/19 10:56 35457430017 SB-16 (6-8') EPA 6010 Arsenic 25.3 mg/kg 3.3 04/04/19 13:31 EPA 6010 Barium 207 mg/kg 3.3 04/04/19 13:31 EPA 6010 Lead 4980 mg/kg 66.5 04/04/19 15:33 ASTM D2974-87 Percent Moisture 20.2 % 0.10 04/04/19 10:56 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 97 aceAnalytical® www.pacelabs.com SUMMARY OF DETECTION Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35457430018 SB-17 (0-0.5') EPA 6010 Arsenic 14.3 mg/kg 0.69 04/04/19 13:34 EPA 6010 Barium 9.2 mg/kg 0.69 04/04/19 13:34 EPA 6010 Lead 5.2 mg/kg 0.69 04/04/19 13:34 ASTM D2974-87 Percent Moisture 10.3 % 0.10 04/04/19 10:57 J(D6) 35457430019 SB-17 (0.5-2') EPA 6010 Arsenic 9.8 mg/kg 2.5 04/04/19 13:37 EPA 6010 Barium 51.2 mg/kg 2.5 04/04/19 13:37 EPA 6010 Lead 142 mg/kg 2.5 04/04/19 13:37 ASTM D2974-87 Percent Moisture 14.5 % 0.10 04/04/19 10:57 35457430020 SB-17 (2-4') EPA 6010 Arsenic 9.9 mg/kg 1.2 04/04/19 13:39 EPA 6010 Barium 131 mg/kg 1.2 04/04/19 13:39 EPA 6010 Lead 699 mg/kg 12.0 04/04/19 15:36 ASTM D2974-87 Percent Moisture 10.1 % 0.10 04/04/19 10:57 35457430021 SB-17 (4-6') EPA 6010 Arsenic 18.2 mg/kg 3.3 04/04/19 13:42 EPA 6010 Barium 216 mg/kg 3.3 04/04/19 13:42 -PA 6010 Lead 1090 mg/kg 32.8 04/04/19 15:39 ,ASTM D2974-87 Percent Moisture 18.0 % 0.10 04/04/19 10:57 35457430022 SB-18 (0-0.5') EPA 6010 Arsenic 13.6 mg/kg 0.64 04/04/19 13:45 EPA 6010 Barium 13.2 mg/kg 0.64 04/04/19 13:45 EPA 6010 Lead 8.6 mg/kg 0.64 04/04/19 13:45 ASTM D2974-87 Percent Moisture 13.6 % 0.10 04/04/19 10:57 35457430023 SB-18 (0.5-2') EPA 6010 Arsenic 13.3 mg/kg 0.64 04/04/19 13:48 EPA 6010 Barium 13.7 mg/kg 0.64 04/04/19 13:48 EPA 6010 Lead 29.3 mg/kg 0.64 04/04/19 13:48 ASTM D2974-87 Percent Moisture 20.5 % 0.10 04/04/19 10:57 35457430024 SB-18 (2-4') EPA 6010 Arsenic 4.0 mg/kg 0.66 04/04/19 13:51 EPA 6010 Barium 20.9 mg/kg 0.66 04/04/19 13:51 EPA 6010 Lead 46.0 mg/kg 0.66 04/04/19 13:51 ASTM D2974-87 Percent Moisture 22.4 % 0.10 04/04/19 10:57 35457430025 SB-18 (4-6') EPA 6010 Arsenic 6.4 mg/kg 0.67 04/04/19 10:20 EPA 6010 Barium 29.1 mg/kg 0.67 04/04/19 10:20 EPA 6010 Lead 167 mg/kg 6.7 04/04/19 15:04 ASTM D2974-87 Percent Moisture 10.7 % 0.10 04/04/19 10:57 35457430026 SB-18 (6-8') EPA 6010 Arsenic 29.7 mg/kg 3.4 04/04/19 13:57 EPA6010 Barium 278 mg/kg 3.4 04/04/19 13:57 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 97 aceAnalytical® www.pacelabs.com SUMMARY OF DETECTION Project: 2018-3057/Melrese Golf Course Pace Project No. 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35457430026 SB-18 (6-8') EPA 6010 Lead 624 mg/kg 3.4 04/04/19 13:57 ASTM D2974-87 Percent Moisture 25.6 % 0.10 04/04/19 09:23 35457430027 SB-19 (0-0.5') EPA 6010 Arsenic 22.9 mg/kg 3.5 04/04/19 14:05 EPA 6010 Barium 31.9 mg/kg 3.5 04/04/19 14:05 EPA 6010 Lead 195 mg/kg 3.5 04/04/19 14:05 ASTM D2974-87 Percent Moisture 12.0 % 0.10 04/04/19 09:23 35457430028 SB-19 (0.5-2') EPA 6010 Arsenic 8.2 mg/kg 3.2 04/04/19 14:08 EPA 6010 Barium 54.1 mg/kg 3.2 04/04/19 14:08 EPA 6010 Lead 176 mg/kg 3.2 04/04/19 14:08 ASTM D2974-87 Percent Moisture 16.6 % 0.10 04/04/19 09:23 35457430029 SB-19 (2-4') EPA 6010 Arsenic 12.8 mg/kg 3.3 04/04/19 14:11 EPA 6010 Barium 208 mg/kg 3.3 04/04/19 14:11 EPA 6010 Lead 524 mg/kg 3.3 04/04/19 14:11 ASTM D2974-87 Percent Moisture 29.8 % 0.10 04/04/19 09:23 35457430030 SB-20 (0-0.5') EPA 6010 Arsenic 27.8 mg/kg 0.70 04/04/19 14:14 EPA 6010 Barium 18.1 mg/kg 0.70 04/04/19 14:14 EPA 6010 Lead 42.1 mg/kg 0.70 04/04/19 14:14 ASTM D2974-87 Percent Moisture 17.4 % 0.10 04/04/19 09:23 35457430031 SB-20 (0.5-2') EPA 6010 Arsenic 1.2 mg/kg 0.54 04/04/19 14:17 EPA 6010 Barium 11.7 mg/kg 0.54 04/04/19 14:17 EPA 6010 Lead 8.3 mg/kg 0.54 04/04/19 14:17 ASTM D2974-87 Percent Moisture 10.6 % 0.10 04/04/19 09:23 35457430032 SB-20 (2-4') EPA 6010 Arsenic 29.5 mg/kg 3.7 04/04/19 11:09 EPA6010 Barium 212 mg/kg 3.7 04/04/19 11:09 J(M1) EPA6010 Lead 500 mg/kg 3.7 04/04/19 11:09 J(M1),J(R1) ASTM D2974-87 Percent Moisture 24.1 % 0.10 04/04/19 09:23 35457430033 SB-21 (0-0.5') EPA 6010 Arsenic 19.5 mg/kg 0.69 04/04/19 11:26 EPA 6010 Barium 10.5 mg/kg 0.69 04/04/19 11:26 EPA 6010 Lead 12.0 mg/kg 0.69 04/04/19 11:26 ASTM D2974-87 Percent Moisture 20.4 % 0.10 04/04/19 09:23 35457430034 SB-21 (0.5-2') EPA 6010 Arsenic 16.1 mg/kg 0.69 04/04/19 11:29 EPA 6010 Barium 24.2 mg/kg 0.69 04/04/19 11:29 EPA 6010 Lead 91.2 mg/kg 0.69 04/04/19 11:29 ASTM D2974-87 Percent Moisture 12.6 % 0.10 04/04/19 09:23 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 97 www.pacelabs.com SUMMARY OF DETECTION Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed 35457430035 SB-21 (2-4') EPA 6010 Arsenic 49.7 mg/kg 2.9 04/04/19 11:32 EPA 6010 Barium 85.5 mg/kg 2.9 04/04/19 11:32 EPA 6010 Lead 661 mg/kg 57.6 04/04/19 14:55 ASTM D2974-87 Percent Moisture 18.7 % 0.10 04/04/19 09:23 35457430036 SB-21 (4-6') EPA 6010 Arsenic 12.4 mg/kg 3.2 04/04/19 11:35 EPA 6010 Barium 148 mg/kg 3.2 04/04/19 11:35 EPA 6010 Lead 298 mg/kg 3.2 04/04/19 11:35 ASTM D2974-87 Percent Moisture 21.4 % 0.10 04/04/19 09:23 35457430037 SB-21 (6-8') EPA 6010 Arsenic 85.0 mg/kg 3.6 04/04/19 11:38 EPA 6010 Barium 507 mg/kg 3.6 04/04/19 11:38 EPA 6010 Lead 393 mg/kg 3.6 04/04/19 11:38 ASTM D2974-87 Percent Moisture 25.8 % 0.10 04/04/19 09:24 35457430038 SB-22 (0-0.5') EPA 6010 Arsenic 12.8 mg/kg 0.51 04/04/19 11:40 EPA 6010 Barium 7.5 mg/kg 0.51 04/04/19 11:40 -PA 6010 Lead 9.2 mg/kg 0.51 04/04/19 11:40 ASTM D2974-87 Percent Moisture 7.4 % 0.10 04/04/19 09:24 35457430039 SB-22 (0.5-2') EPA 6010 Arsenic 0.73 mg/kg 0.58 04/04/19 11:43 EPA 6010 Barium 5.8 mg/kg 0.58 04/04/19 11:43 EPA 6010 Lead 9.3 mg/kg 0.58 04/04/19 11:43 ASTM D2974-87 Percent Moisture 6.7 % 0.10 04/04/19 09:24 35457430040 SB-22 (2-4') EPA 6010 Barium 4.0 mg/kg 0.54 04/04/19 11:46 EPA 6010 Lead 3.0 mg/kg 0.54 04/04/19 11:46 ASTM D2974-87 Percent Moisture 7.4 % 0.10 04/04/19 09:24 35457430041 SB-22 (4-6') EPA 6010 Arsenic 47.7 mg/kg 3.1 04/04/19 11:49 EPA 6010 Barium 215 mg/kg 3.1 04/04/19 11:49 EPA 6010 Lead 3180 mg/kg 62.2 04/04/19 14:58 ASTM D2974-87 Percent Moisture 20.9 % 0.10 04/04/19 09:24 35457430042 SB-23 (0-0.5') EPA 6010 Arsenic 30.2 mg/kg 0.66 04/04/19 11:52 EPA 6010 Barium 7.5 mg/kg 0.66 04/04/19 11:52 EPA 6010 Lead 16.8 mg/kg 0.66 04/04/19 11:52 ASTM D2974-87 Percent Moisture 11.3 % 0.10 04/04/19 09:24 35457430043 SB-23 (0.5-2') EPA 6010 Arsenic 30.4 mg/kg 0.62 04/04/19 12:00 EPA 6010 Barium 14.0 mg/kg 0.62 04/04/19 12:00 EPA 6010 Lead 70.7 mg/kg 0.62 04/04/19 12:00 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 97 aceAnalytical www.pacelabs.com SUMMARY OF DETECTION Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35457430043 SB-23 (0.5-2') ASTM D2974-87 Percent Moisture 9.8 % 0.10 04/04/19 09:24 35457430044 SB-23 (2-4') EPA 6010 Arsenic 12.8 mg/kg 0.82 04/04/19 12:03 EPA 6010 Barium 22.1 mg/kg 0.82 04/04/19 12:03 EPA 6010 Lead 53.3 mg/kg 0.82 04/04/19 12:03 ASTM D2974-87 Percent Moisture 27.2 % 0.10 04/04/19 09:24 35457430045 SB-23 (4-6') EPA 6010 Arsenic 0.56 mg/kg 0.54 04/04/19 13:54 EPA 6010 Barium 4.1 mg/kg 0.54 04/04/19 13:54 EPA 6010 Lead 3.3 mg/kg 0.54 04/04/19 13:54 ASTM D2974-87 Percent Moisture 12.3 % 0.10 04/04/19 09:24 35457430046 SB-24 (0-0.5') EPA 6010 Arsenic 29.3 mg/kg 0.63 04/04/19 12:06 EPA 6010 Barium 6.6 mg/kg 0.63 04/04/19 12:06 EPA 6010 Lead 7.7 mg/kg 0.63 04/04/19 12:06 ASTM D2974-87 Percent Moisture 10.4 % 0.10 04/04/19 09:24 35457430047 SB-24 (0.5-2') EPA 6010 Arsenic 36.4 mg/kg 2.5 04/04/19 12:09 EPA 6010 Barium 20.1 mg/kg 2.5 04/04/19 12:09 EPA 6010 Lead 3140 mg/kg 49.1 04/04/19 15:01 ASTM D2974-87 Percent Moisture 8.8 % 0.10 04/04/19 09:24 35457430048 SB-24 (2-4') EPA 6010 Arsenic 26.4 mg/kg 3.4 04/04/19 12:12 EPA 6010 Barium 82.4 mg/kg 3.4 04/04/19 12:12 EPA 6010 Lead 255 mg/kg 3.4 04/04/19 12:12 ASTM D2974-87 Percent Moisture 13.4 % 0.10 04/04/19 09:24 35457430049 SB-24 (4-6') EPA 6010 Arsenic 22.5 mg/kg 3.2 04/04/19 12:18 EPA 6010 Barium 150 mg/kg 3.2 04/04/19 12:18 EPA 6010 Lead 299 mg/kg 3.2 04/04/19 12:18 ASTM D2974-87 Percent Moisture 17.9 % 0.10 04/04/19 09:24 35457430050 SB-25 (0-0.5') EPA 6010 Arsenic 19.4 mg/kg 0.57 04/04/19 12:21 EPA 6010 Barium 9.2 mg/kg 0.57 04/04/19 12:21 EPA 6010 Lead 23.9 mg/kg 0.57 04/04/19 12:21 ASTM D2974-87 Percent Moisture 13.2 % 0.10 04/04/19 09:25 35457430051 SB-25 (0.5-2') EPA 6010 Arsenic 2.7 mg/kg 0.68 04/04/19 12:24 EPA 6010 Barium 22.9 mg/kg 0.68 04/04/19 12:24 EPA 6010 Lead 69.8 mg/kg 0.68 04/04/19 12:24 ASTM D2974-87 Percent Moisture 12.6 % 0.10 04/04/19 09:25 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 97 723ceAnalytical® www.pacelabs.com SUMMARY OF DETECTION Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35457430052 SB-25 (2-4') EPA 6010 Arsenic 7.1 mg/kg 0.71 04/04/19 10:23 EPA 6010 Barium 26.2 mg/kg 0.71 04/04/19 10:23 EPA 6010 Lead 41.6 mg/kg 0.71 04/04/19 10:23 ASTM D2974-87 Percent Moisture 28.0 % 0.10 04/04/19 09:25 35457430053 SB-25 (4-6') EPA 6010 Arsenic 6.8 mg/kg 0.67 04/04/19 10:26 EPA 6010 Barium 20.4 mg/kg 0.67 04/04/19 10:26 EPA 6010 Lead 56.5 mg/kg 0.67 04/04/19 10:26 ASTM D2974-87 Percent Moisture 23.4 % 0.10 04/04/19 09:25 35457430054 SB-26 (0-0.5') EPA 6010 Arsenic 19.5 mg/kg 0.66 04/04/19 10:29 EPA 6010 Barium 14.3 mg/kg 0.66 04/04/19 10:29 EPA 6010 Lead 29.8 mg/kg 0.66 04/04/19 10:29 ASTM D2974-87 Percent Moisture 12.9 % 0.10 04/04/19 09:25 35457430055 SB-26 (0.5-2') EPA 6010 Arsenic 9.6 mg/kg 0.67 04/04/19 10:31 EPA 6010 Barium 12.6 mg/kg 0.67 04/04/19 10:31 -PA 6010 Lead 15.3 mg/kg 0.67 04/04/19 10:31 .iSTM D2974-87 Percent Moisture 22.8 % 0.10 04/04/19 09:25 35457430056 SB-26 (2-4') EPA 6010 Arsenic 1.6 mg/kg 0.58 04/04/19 10:34 EPA 6010 Barium 3.5 mg/kg 0.58 04/04/19 10:34 EPA 6010 Lead 3.4 mg/kg 0.58 04/04/19 10:34 ASTM D2974-87 Percent Moisture 12.2 % 0.10 04/04/19 09:25 35457430057 SB-27 (0-0.5') EPA 6010 Arsenic 5.5 mg/kg 0.56 04/04/19 10:37 EPA 6010 Barium 7.2 mg/kg 0.56 04/04/19 10:37 EPA 6010 Lead 5.1 mg/kg 0.56 04/04/19 10:37 ASTM D2974-87 Percent Moisture 5.7 % 0.10 04/04/19 09:25 35457430058 SB-27 (0.5-2') EPA 6010 Arsenic 2.0 mg/kg 0.60 04/04/19 10:40 EPA 6010 Barium 7.3 mg/kg 0.60 04/04/19 10:40 EPA 6010 Lead 4.1 mg/kg 0.60 04/04/19 10:40 ASTM D2974-87 Percent Moisture 6.0 % 0.10 04/04/19 09:25 35457430059 SB-27 (2-4') EPA 6010 Arsenic 2.3 mg/kg 0.72 04/04/19 10:43 EPA 6010 Barium 7.7 mg/kg 0.72 04/04/19 10:43 EPA 6010 Lead 14.4 mg/kg 0.72 04/04/19 10:43 ASTM D2974-87 Percent Moisture 13.9 % 0.10 04/04/19 09:25 35457430060 SB-28 (0-0.5') EPA 6010 Arsenic 3.6 mg/kg 0.68 04/04/19 10:52 EPA 6010 Barium 22.9 mg/kg 0.68 04/04/19 10:52 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 97 aceAnalytical www pace/abs. com SUMMARY OF DETECTION Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35457430060 SB-28 (0-0.5') EPA 6010 Lead 18.0 mg/kg 0.68 04/04/19 10:52 ASTM D2974-87 Percent Moisture 15.0 % 0.10 04/04/19 09:25 35457430061 SB-28 (0.5-2') EPA6010 Barium 6.9 mg/kg 0.58 04/04/19 10:54 EPA 6010 Lead 13.7 mg/kg 0.58 04/04/19 10:54 ASTM D2974-87 Percent Moisture 7.8 % 0.10 04/04/19 09:25 35457430062 SB-28 (2-4') EPA 6010 Arsenic 0.71 mg/kg 0.66 04/04/19 10:57 EPA 6010 Barium 4.7 mg/kg 0.66 04/04/19 10:57 EPA 6010 Lead 5.0 mg/kg 0.66 04/04/19 10:57 ASTM D2974-87 Percent Moisture 9.9 % 0.10 04/04/19 12:32 35457430063 SB-28 (4-6') EPA 6010 Arsenic 4.8 mg/kg 0.77 04/04/19 11:00 EPA 6010 Barium 24.1 mg/kg 0.77 04/04/19 11:00 EPA 6010 Lead 85.4 mg/kg 0.77 04/04/19 11:00 ASTM D2974-87 Percent Moisture 20.9 % 0.10 04/04/19 12:32 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC, Page 16 of 97 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-13 (0-0.5') Lab ID: 35457430001 Collected: 03/27/19 08:45 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 2.5 mg/kg 0.63 0.31 1 04/03/19 15:23 04/04/19 14:10 7440-38-2 Barium 7.8 mg/kg 0.63 0.31 1 04/03/19 15:23 04/04/19 14:10 7440-39-3 Lead 13.7 mg/kg 0.63 0.31 1 04/03/19 15:23 04/04/19 14:10 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 11.9 % 0.10 0.10 1 04/04/19 10:55 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-13 (0.5-2') Lab ID: 35457430002 Collected: 03/27/19 08:47 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3050 Arsenic 1.7 mg/kg 0.61 0.30 1 04/03/19 15:23 04/04/1914:13 7440-38-2 Barium 88.8 mg/kg 0.61 0.30 1 04/03/19 15:23 04/04/19 14:13 7440-39-3 Lead 11.0 mg/kg 0.61 0.30 1 04/03/19 15:23 04/04/19 14:13 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 10.6 % 0.10 0.10 1 04/04/19 10:55 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 97 aceAnalytical wwwpacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-13 (2-4') Lab ID: 35457430003 Collected: 03/27/19 08:49 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 47.0 mg/kg 1.2 0.61 1 04/03/19 15:23 04/04/19 14:16 7440-38-2 Barium 19.4 mg/kg 1.2 0.61 1 04/03/19 15:23 04/04/19 14:16 7440-39-3 Lead 16.6 mg/kg 1.2 0.61 1 04/03/19 15:23 04/04/1914:16 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 50.7 % 0.10 0.10 1 04/04/19 10:55 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 97 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-13 (4-6') Lab ID: 35457430004 Collected: 03/27/19 08:51 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA 3050 Arsenic 3.6 mg/kg 0.49 0.24 1 04/03/19 15:23 04/04/19 14:19 7440-38-2 Barium 22.3 mg/kg 0.49 0.24 1 04/03/19 15:23 04/04/19 14:19 7440-39-3 Lead 395 mg/kg 48.5 24.3 100 04/03/19 15:23 04/04/19 16:14 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 11.8 % 0.10 0.10 1 04/04/19 10:56 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 97 ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-14 (0-0.5') Lab ID: 35457430005 Collected: 03/27/19 09:10 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 31.0 mg/kg 0.53 0.26 1 04/03/19 15:23 04/04/19 14:21 7440-38-2 Barium 25.5 mg/kg 0.53 0.26 1 04/03/19 15:23 04/04/19 14:21 7440-39-3 Lead 165 mg/kg 5.3 2.6 10 04/03/19 15:23 04/04/19 16:17 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 04/04/2019 05:44 PM 9.9 % 0.10 0.10 1 04/04/19 10:56 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 21 of 97 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.. 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-14 (0.5-2') Lab ID: 35457430006 Collected: 03/27/19 09:12 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 15.8 mg/kg 3.3 1.6 5 04/03/19 15:23 04/04/19 14:24 7440-38-2 Barium 145 mg/kg 3.3 1.6 5 04/03/19 15:23 04/04/19 14:24 7440-39-3 Lead 1110 mg/kg 65.7 32.8 100 04/03/19 15:23 04/04/19 16:20 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 04/04/2019 05:44 PM 13.7 % 0.10 0.10 1 04/04/19 10:56 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 22 of 97 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-14 (2-4') Lab ID: 35457430007 Collected: 03/27/19 09:14 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 63.0 mg/kg 3.4 1.7 5 04/03/19 15:23 04/04/1914:27 7440-38-2 Barium 523 mg/kg 3.4 1.7 5 04/03/19 15:23 04/04/19 14:27 7440-39-3 Lead 1210 mg/kg 6.8 3.4 10 04/03/19 15:23 04/04/19 16:23 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 23.5 % 0.10 0.10 1 04/04/19 10:56 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 97 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-15 (0-0.5') Lab ID: 35457430008 Collected: 03/27/19 09:25 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 2.8 mg/kg 0.54 0.27 1 04/03/19 15:23 04/04/19 14:30 7440-38-2 Barium 7.7 mg/kg 0.54 0.27 1 04/03/19 15:23 04/04/19 14:30 7440-39-3 Lead 8.8 mg/kg 0.54 0.27 1 04/03/19 15:23 04/04/19 14:30 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 11.5 % 0.10 0.10 1 04/04/19 10:56 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 24 of 97 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.. 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-15 (0.5-2') Lab ID: 35457430009 Collected: 03/27/19 09:27 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 12.0 mg/kg 0.56 0.28 1 04/03/19 15:23 04/04/19 14:41 7440-38-2 Barium 15.3 mg/kg 0.56 0.28 1 04/03/19 15:23 04/04/19 14:41 7440-39-3 Lead 85.7 mg/kg 0.56 0.28 1 04/03/19 15:23 04/04/19 14:41 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 12.5 % 0.10 0.10 1 04/04/19 10:56 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 25 of 97 aceAnalytical ® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-15 (2-4') Lab ID: 35457430010 Collected: 03/27/19 09:29 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 14.4 mg/kg 3.8 1.9 5 04/03/19 15:23 04/04/19 14:44 7440-38-2 Barium 124 mg/kg 3.8 1.9 5 04/03/19 15:23 04/04/19 14:44 7440-39-3 Lead 168 mg/kg 3.8 1.9 5 04/03/19 15:23 04/04/19 14:44 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 35.1 % 0.10 0.10 1 04/04/19 10:56 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 26 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-15 (4-6') Lab ID: 35457430011 Collected: 03/27/19 09:31 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 40.0 mg/kg 4.0 2.0 5 04/03/19 15:23 04/04/19 14:47 7440-38-2 Barium 714 mg/kg 4.0 2.0 5 04/03/19 15:23 04/04/19 14:47 7440-39-3 Lead 1870 mg/kg 79.4 39.7 100 04/03/19 15:23 04/04/19 16:25 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 04/04/2019 05:44 PM 32.2 % 0.10 0.10 1 04/04/1910:56 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 27 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-15 (6-8') Lab ID: 35457430012 Collected: 03/27/19 09:33 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 25.0 mg/kg 8.9 4.5 5 04/03/19 15:23 04/04/19 14:50 7440-38-2 Barium 39.3 mg/kg 8.9 4.5 5 04/03/19 15:23 04/04/19 14:50 7440-39-3 Lead 61.8 mg/kg 8.9 4.5 5 04/03/19 15:23 04/04/19 14:50 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 70.9 % 0.10 0.10 1 04/04/19 10:56 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 28 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-16 (0-0.5') Lab ID: 35457430013 Collected: 03/27/19 09:50 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 0.94 mg/kg 0.65 0.33 1 04/03/19 15:23 04/04/19 14:52 7440-38-2 Barium 5.3 mg/kg 0.65 0.33 1 04/03/19 15:23 04/04/1914:52 7440-39-3 Lead 5.7 mg/kg 0.65 0.33 1 04/03/19 15:23 04/04/19 14:52 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 04/04/2019 05:44 PM 10.1 % 0.10 0.10 1 04/04/19 10:56 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 29 of 97 aceAnalytical® wwwpacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-16 (0.5-2') Lab ID: 35457430014 Collected: 03/27/19 09:52 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 10.4 mg/kg 0.64 0.32 1 04/03/19 16:39 04/04/19 13:17 7440-38-2 Barium 10.3 mg/kg 0.64 0.32 1 04/03/19 16:39 04/04/19 13:17 7440-39-3 Lead 3.4 mg/kg 0.64 0.32 1 04/03/1916:39 04/04/19 13:17 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 30.1 % 0.10 0.10 1 04/04/19 10:56 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 30 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-16 (2-4') Lab ID: 35457430015 Collected: 03/27/19 09:54 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 3.0 mg/kg 0.68 0.34 1 04/03/19 16:39 04/04/19 13:20 7440-38-2 Barium 33.4 mg/kg 0.68 0.34 1 04/03/19 16:39 04/04/19 13:20 7440-39-3 Lead 113 mg/kg 0.68 0.34 1 04/03/19 16:39 04/04/19 13:20 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 13.1 % 0.10 0.10 1 04/04/19 10:56 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 31 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-16 (4-6') Lab ID: 35457430016 Collected: 03/27/19 09:56 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 3.4 mg/kg 0.59 0.30 1 04/03/19 16:39 04/04/19 13:22 7440-38-2 Barium 20.4 mg/kg 0.59 0.30 1 04/03/19 16:39 04/04/19 13:22 7440-39-3 Lead 26.5 mg/kg 0.59 0.30 1 04/03/19 16:39 04/04/1913:22 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 16.6 % 0.10 0.10 1 04/04/19 10:56 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 32 of 97 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-16 (6-8') Lab ID: 35457430017 Collected: 03/27/19 09:58 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 25.3 mg/kg 3.3 1.7 5 04/03/19 16:39 04/04/19 13:31 7440-38-2 Barium 207 mg/kg 3.3 1.7 5 04/03/19 16:39 04/04/19 13:31 7440-39-3 Lead 4980 mg/kg 66.5 33.2 100 04/03/19 16:39 04/04/19 15:33 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 20.2 % 0.10 0.10 1 04/04/19 10:56 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 33 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-17 (0-0.5') Lab ID: 35457430018 Collected: 03/27/19 10:30 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 14.3 mg/kg 0.69 0.34 1 04/03/1916:39 04/04/19 13:34 7440-38-2 Barium 9.2 mg/kg 0.69 0.34 1 04/03/19 16:39 04/04/19 13:34 7440-39-3 Lead 5.2 mg/kg 0.69 0.34 1 04/03/19 16:39 04/04/19 13:34 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 10.3 % 0.10 0.10 1 04/04/19 10:57 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/04/2019 05:44 PM without the written consent of Pace Analytical Services, LLC. J(D6) Page 34 of 97 ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-17 (0.5-2') Lab ID: 35457430019 Collected: 03/27/19 10:32 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 9.8 mg/kg 2.5 1.3 5 04/03/19 16:39 04/04/19 13:37 7440-38-2 Barium 51.2 mg/kg 2.5 1.3 5 04/03/19 16:39 04/04/19 13:37 7440-39-3 Lead 142 mg/kg 2.5 1.3 5 04/03/19 16:39 04/04/19 13:37 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 14.5 % 0.10 0.10 1 04/04/19 10:57 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 35 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-17 (2-4') Lab ID: 35457430020 Collected: 03/27/19 10:34 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3050 Arsenic 9.9 mg/kg 1.2 0.60 2 04/03/19 16:39 04/04/19 13:39 7440-38-2 Barium 131 mg/kg 1.2 0.60 2 04/03/19 16:39 04/04/19 13:39 7440-39-3 Lead 699 mg/kg 12.0 6.0 20 04/03/19 16:39 04/04/19 15:36 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 10.1 % 0.10 0.10 1 04/04/19 10:57 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 36 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-17 (4-6') Lab ID: 35457430021 Collected: 03/27/19 10:36 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 18.2 mg/kg 3.3 1.6 5 04/03/19 16:39 04/04/19 13:42 7440-38-2 Barium 216 mg/kg 3.3 1.6 5 04/03/19 16:39 04/04/19 13:42 7440-39-3 Lead 1090 mg/kg 32.8 16.4 50 04/03/19 16:39 04/04/19 15:39 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 18.0 % 0.10 0.10 1 04/04/19 10:57 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 37 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-18 (0-0.5') Lab ID: 35457430022 Collected: 03/27/19 10:50 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 13.6 mg/kg 0.64 0.32 1 04/03/19 16:39 04/04/19 13:45 7440-38-2 Barium 13.2 mg/kg 0.64 0.32 1 04/03/19 16:39 04/04/19 13:45 7440-39-3 Lead 8.6 mg/kg 0.64 0.32 1 04/03/19 16:39 04/04/19 13:45 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 13.6 % 0.10 0.10 1 04/04/19 10:57 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 38 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-18 (0.5-2') Lab ID: 35457430023 Collected: 03/27/19 10:52 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3050 Arsenic 13.3 mg/kg 0.64 0.32 1 04/03/19 16:39 04/04/19 13:48 7440-38-2 Barium 13.7 mg/kg 0.64 0.32 1 04/03/19 16:39 04/04/19 13:48 7440-39-3 Lead 29.3 mg/kg 0.64 0.32 1 04/03/19 16:39 04/04/19 13:48 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 04/04/2019 05:44 PM 20.5 % 0.10 0.10 1 04/04/19 10:57 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 39 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-18 (2-4') Lab ID: 35457430024 Collected: 03/27/19 10:54 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 4.0 mg/kg 0.66 0.33 1 04/03/19 16:39 04/04/19 13:51 7440-38-2 Barium 20.9 mg/kg 0.66 0.33 1 04/03/19 16:39 04/04/19 13:51 7440-39-3 Lead 46.0 mg/kg 0.66 0.33 1 04/03/19 16:39 04/04/19 13:51 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 22.4 % 0.10 0.10 1 04/04/19 10:57 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 40 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-18 (4-6') Lab ID: 35457430025 Collected: 03/27/19 10:56 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3050 Arsenic 6.4 mg/kg 0.67 0.33 1 04/04/19 02:22 04/04/19 10:20 7440-38-2 Barium 29.1 mg/kg 0.67 0.33 1 04/04/19 02:22 04/04/19 10:20 7440-39-3 Lead 167 mg/kg 6.7 3.3 10 04/04/19 02:22 04/04/19 15:04 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 10.7 % 0.10 0.10 1 04/04/19 10:57 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 41 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No : 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-18 (6-8') Lab ID: 35457430026 Collected: 03/27/19 10:58 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 29.7 mg/kg 3.4 1.7 5 04/03/19 16:39 04/04/19 13:57 7440-38-2 Barium 278 mg/kg 3.4 1.7 5 04/03/19 16:39 04/04/19 13:57 7440-39-3 Lead 624 mg/kg 3.4 1.7 5 04/03/19 16:39 04/04/19 13:57 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 25.6 % 0.10 0.10 1 04/04/19 09:23 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/04/2019 05:44 PM without the written consent of Pace Analytical Services, LLC. Page 42 of 97 www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-19 (0-0.5') Lab ID: 35457430027 Collected: 03/27/19 11:20 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3050 Arsenic 22.9 mg/kg 3.5 1.8 5 04/03/19 16:39 04/04/19 14:05 7440-38-2 Barium 31.9 mg/kg 3.5 1.8 5 04/03/19 16:39 04/04/19 14:05 7440-39-3 Lead 195 mg/kg 3.5 1.8 5 04/03/19 16:39 04/04/19 14:05 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 12.0 % 0.10 0.10 1 04/04/19 09:23 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 43 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-19 (0.5-2') Lab ID: 35457430028 Collected: 03/27/19 11:22 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3050 Arsenic 8.2 mg/kg 3.2 1.6 5 04/03/19 16:39 04/04/19 14:08 7440-38-2 Barium 54.1 mg/kg 3.2 1.6 5 04/03/19 16:39 04/04/19 14:08 7440-39-3 Lead 176 mg/kg 3.2 1.6 5 04/03/19 16:39 04/04/19 14:08 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 16.6 % 0.10 0.10 1 04/04/19 09:23 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 44 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach. FL 33064 954-582-4300 Sample: SB-19 (2-4') Lab ID: 35457430029 Collected: 03/27/19 11:24 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 12.8 mg/kg 3.3 1.6 5 04/03/19 16:39 04/04/19 14:11 7440-38-2 Barium 208 mg/kg 3.3 1.6 5 04/03/19 16:39 04/04/19 14:11 7440-39-3 Lead 524 mg/kg 3.3 1.6 5 04/03/19 16:39 04/04/19 14:11 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 29.8 % 0.10 0.10 1 04/04/19 09:23 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 45 of 97 aceAnalytical® wwwpace/abs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-20 (0-0.5') Lab ID: 35457430030 Collected: 03/27/19 11 40 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 27.8 mg/kg 0.70 0.35 1 04/03/19 16:39 04/04/19 14:14 7440-38-2 Barium 18.1 mg/kg 0.70 0.35 1 04/03/19 16:39 04/04/19 14:14 7440-39-3 Lead 42.1 mg/kg 0.70 0.35 1 04/03/19 16:39 04/04/19 14:14 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 17.4 % 0.10 0.10 1 04/04/19 09:23 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 46 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-20 (0.5-2') Lab ID: 35457430031 Collected: 03/27/19 11:42 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 1.2 mg/kg 0.54 0.27 1 04/03/19 16:39 04/04/19 14:17 7440-38-2 Barium 11.7 mg/kg 0.54 0.27 1 04/03/19 16:39 04/04/19 14:17 7440-39-3 Lead 8.3 mg/kg 0.54 0.27 1 04/03/19 16:39 04/04/19 14:17 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 10.6 % 0.10 0.10 1 04/04/19 09:23 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 47 of 97 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-20 (2-4') Lab ID: 35457430032 Collected: 03/27/19 11:44 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 29.5 mg/kg 3.7 1.8 5 04/03/19 16:39 04/04/19 11:09 7440-38-2 Barium 212 mg/kg 3.7 1.8 5 04/03/19 16:39 04/04/19 11:09 7440-39-3 J(M1) Lead 500 mg/kg 3.7 1.8 5 04/03/19 16:39 04/04/19 11:09 7439-92-1 J(M1), J(R1) Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 24.1 % 0.10 0.10 1 04/04/19 09:23 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 48 of 97 aceAnalytical wwwpacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-21 (0-0.5') Lab ID: 35457430033 Collected: 03/27/19 12:10 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3050 Arsenic 19.5 mg/kg 0.69 0.35 1 04/03/19 16:39 04/04/19 11:26 7440-38-2 Barium 10.5 mg/kg 0.69 0.35 1 04/03/19 16:39 04/04/19 11:26 7440-39-3 Lead 12.0 mg/kg 0.69 0.35 1 04/03/19 16:39 04/04/19 11:26 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 04/04/2019 05:44 PM 20.4 % 0.10 0.10 1 04/04/19 09:23 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 49 of 97 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.. 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-21 (0.5-2') Lab ID: 35457430034 Collected: 03/27/19 12:12 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 16.1 mg/kg 0.69 0.34 1 04/03/19 16:39 04/04/19 11:29 7440-38-2 Barium 24.2 mg/kg 0.69 0.34 1 04/03/19 16:39 04/04/19 11:29 7440-39-3 Lead 91.2 mg/kg 0.69 0.34 1 04/03/19 16:39 04/04/19 11:29 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 04/04/2019 05:44 PM 12.6 % 0.10 0.10 1 04/04/19 09:23 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 50 of 97 ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-21 (2-4') Lab ID: 35457430035 Collected: 03/27/19 12:14 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 49.7 mg/kg 2.9 1.4 5 04/03/19 16:39 04/04/1911:32 7440-38-2 Barium 85.5 mg/kg 2.9 1.4 5 04/03/19 16:39 04/04/19 11:32 7440-39-3 Lead 661 mg/kg 57.6 28.8 100 04/03/19 16:39 04/04/19 14:55 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 18.7 % 0.10 0.10 1 04/04/19 09:23 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/04/2019 05:44 PM without the written consent of Pace Analytical Services, LLC. Page 51 of 97 www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-21 (4-6') Lab ID: 35457430036 Collected: 03/27/19 12:16 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 12.4 mg/kg 3.2 1.6 5 04/03/19 16:39 04/04/1911:35 7440-38-2 Barium 148 mg/kg 3.2 1.6 5 04/03/19 16:39 04/04/19 11:35 7440-39-3 Lead 298 mg/kg 3.2 1.6 5 04/03/19 16:39 04/04/19 11:35 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 21.4 % 0.10 0.10 1 04/04/19 09:23 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 52 of 97 www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.. 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-21 (6-8') Lab ID: 35457430037 Collected: 03/27/19 12:18 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 85.0 mg/kg 3.6 1.8 5 04/03/19 16:39 04/04/19 11:38 7440-38-2 Barium 507 mg/kg 3.6 1.8 5 04/03/19 16:39 04/04/19 11:38 7440-39-3 Lead 393 mg/kg 3.6 1.8 5 04/03/19 16:39 04/04/19 11:38 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 04/04/2019 05:44 PM 25.8 % 0.10 0.10 1 04/04/19 09:24 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 53 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-22 (0-0.5') Lab ID: 35457430038 Collected: 03/27/19 12:30 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 12.8 mg/kg 0.51 0.25 1 04/03/19 16:39 04/04/19 11:40 7440-38-2 Barium 7.5 mg/kg 0.51 0.25 1 04/03/19 16:39 04/04/19 11:40 7440-39-3 Lead 9.2 mg/kg 0.51 0.25 1 04/03/19 16:39 04/04/19 11:40 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 7.4 % 0.10 0.10 1 04/04/19 09:24 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 54 of 97 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-22 (0.5-2') Lab ID: 35457430039 Collected: 03/27/19 12:32 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 0.73 mg/kg 0.58 0.29 1 04/03/19 16:39 04/04/19 11:43 7440-38-2 Barium 5.8 mg/kg 0.58 0.29 1 04/03/19 16:39 04/04/19 11:43 7440-39-3 Lead 9.3 mg/kg 0.58 0.29 1 04/03/1916:39 04/04/1911:43 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 6.7 % 0.10 0.10 1 04/04/19 09:24 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 55 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-22 (2-4') Lab ID: 35457430040 Collected: 03/27/19 12:34 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 0.27 U mg/kg 0.54 0.27 1 04/03/19 16:39 04/04/19 11:46 7440-38-2 Barium 4.0 mg/kg 0.54 0.27 1 04/03/19 16:39 04/04/19 11:46 7440-39-3 Lead 3.0 mg/kg 0.54 0.27 1 04/03/19 16:39 04/04/19 11:46 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 7.4 % 0.10 0.10 1 04/04/19 09:24 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 56 of 97 /eAnaIyticaI www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-22 (4-6') Lab ID: 35457430041 Collected: 03/27/19 12:36 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3050 Arsenic 47.7 mg/kg 3.1 1.6 5 04/03/19 16:39 04/04/19 11:49 7440-38-2 Barium 215 mg/kg 3.1 1.6 5 04/03/19 16:39 04/04/19 11:49 7440-39-3 Lead 3180 mg/kg 62.2 31.1 100 04/03/19 16:39 04/04/19 14:58 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 20.9 % 0.10 0.10 1 04/04/19 09:24 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 57 of 97 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-23 (0-0.5') Lab ID: 35457430042 Collected: 03/27/19 12:50 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 30.2 mg/kg 0.66 0.33 1 04/03/19 16:39 04/04/19 11:52 7440-38-2 Barium 7.5 mg/kg 0.66 0.33 1 04/03/19 16:39 04/04/19 11:52 7440-39-3 Lead 16.8 mg/kg 0.66 0.33 1 04/03/19 16:39 04/04/1911:52 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 04/04/2019 05:44 PM 11.3 % 0.10 0.10 1 04/04/19 09:24 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 58 of 97 aceAnalytkal® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-23 (0.5-2') Lab ID: 35457430043 Collected: 03/27/19 12:52 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3050 Arsenic 30.4 mg/kg 0.62 0.31 1 04/03/19 16:39 04/04/19 12:00 7440-38-2 Barium 14.0 mg/kg 0.62 0.31 1 04/03/19 16:39 04/04/19 12:00 7440-39-3 Lead 70.7 mg/kg 0.62 0.31 1 04/03/19 16:39 04/04/19 12:00 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 04/04/2019 05:44 PM 9.8 % 0.10 0.10 1 04/04/19 09:24 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 59 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-23 (2-4') Lab ID: 35457430044 Collected: 03/27/19 12:54 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 12.8 mg/kg 0.82 0.41 1 04/03/19 16:39 04/04/19 12:03 7440-38-2 Barium 22.1 mg/kg 0.82 0.41 1 04/03/19 16:39 04/04/19 12:03 7440-39-3 Lead 53.3 mg/kg 0.82 0.41 1 04/03/19 16:39 04/04/19 12:03 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 27.2 % 0.10 0.10 1 04/04/19 09:24 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 60 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-23 (4-6') Lab ID: 35457430045 Collected: 03/27/19 12:56 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 0.56 mg/kg 0.54 0.27 1 04/03/19 16:39 04/04/19 13:54 7440-38-2 Barium 4.1 mg/kg 0.54 0.27 1 04/03/19 16:39 04/04/19 13:54 7440-39-3 Lead 3.3 mg/kg 0.54 0.27 1 04/03/19 16:39 04/04/19 13:54 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 04/04/2019 05:44 PM 12.3 % 0.10 0.10 1 04/04/19 09:24 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 61 of 97 /'eAnaIYticaI www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-24 (0-0.5') Lab ID: 35457430046 Collected: 03/27/19 13:05 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 29.3 mg/kg 0.63 0.32 1 04/03/19 16:39 04/04/19 12:06 7440-38-2 Barium 6.6 mg/kg 0.63 0.32 1 04/03/19 16:39 04/04/19 12:06 7440-39-3 Lead 7.7 mg/kg 0.63 0.32 1 04/03/19 16:39 04/04/19 12:06 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 10.4 % 0.10 0.10 1 04/04/19 09:24 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 62 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-24 (0.5-2') Lab ID: 35457430047 Collected: 03/27/19 13:07 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3050 Arsenic 36.4 mg/kg 2.5 1.2 5 04/03/19 16:39 04/04/19 12:09 7440-38-2 Barium 20.1 mg/kg 2.5 1.2 5 04/03/19 16:39 04/04/19 12:09 7440-39-3 Lead 3140 mg/kg 49.1 24.6 100 04/03/1916:39 04/04/1915:01 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 8.8 % 0.10 0.10 1 04/04/19 09:24 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 63 of 97 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-24 (2-4') Lab ID: 35457430048 Collected: 03/27/19 13:09 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 26.4 mg/kg 3.4 1.7 5 04/03/19 16:39 04/04/19 12:12 7440-38-2 Barium 82.4 mg/kg 3.4 1.7 5 04/03/19 16:39 04/04/19 12:12 7440-39-3 Lead 255 mg/kg 3.4 1.7 5 04/03/19 16:39 04/04/19 12:12 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 13.4 % 0.10 0.10 1 04/04/19 09:24 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 64 of 97 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-24 (4-6') Lab ID: 35457430049 Collected: 03/27/19 13:11 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 22.5 mg/kg 3.2 1.6 5 04/03/19 16:39 04/04/19 12:18 7440-38-2 Barium 150 mg/kg 3.2 1.6 5 04/03/19 16:39 04/04/19 12:18 7440-39-3 Lead 299 mg/kg 3.2 1.6 5 04/03/19 16:39 04/04/19 12:18 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 17.9 % 0.10 0.10 1 04/04/19 09:24 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 65 of 97 ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-25 (0-0.5') Lab ID: 35457430050 Collected: 03/27/19 13:30 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 19.4 mg/kg 0.57 0.29 1 04/03/19 16:39 04/04/19 12:21 7440-38-2 Barium 9.2 mg/kg 0.57 0.29 1 04/03/19 16:39 04/04/19 12:21 7440-39-3 Lead 23.9 mg/kg 0.57 0.29 1 04/03/19 16:39 04/04/19 12:21 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 13.2 % 0.10 0.10 1 04/04/19 09:25 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 66 of 97 www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-25 (0.5-2') Lab ID: 35457430051 Collected: 03/27/19 13:32 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 2.7 mg/kg 0.68 0.34 1 04/03/19 16:39 04/04/19 12:24 7440-38-2 Barium 22.9 mg/kg 0.68 0.34 1 04/03/19 16:39 04/04/19 12:24 7440-39-3 Lead 69.8 mg/kg 0.68 0.34 1 04/03/19 16:39 04/04/19 12:24 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 12.6 % 0.10 0.10 1 04/04/19 09:25 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 67 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-25 (2-4') Lab ID: 35457430052 Collected: 03/27/19 13:34 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 7.1 mg/kg 0.71 0.36 1 04/04/19 02:22 04/04/19 10:23 7440-38-2 Barium 26.2 mg/kg 0.71 0.36 1 04/04/19 02:22 04/04/19 10:23 7440-39-3 Lead 41.6 mg/kg 0.71 0.36 1 04/04/19 02:22 04/04/19 10:23 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 28.0 % 0.10 0.10 1 04/04/19 09:25 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 68 of 97 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-25 (4-6') Lab ID: 35457430053 Collected: 03/27/19 13:36 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 6.8 mg/kg 0.67 0.33 1 04/04/19 02:22 04/04/19 10:26 7440-38-2 Barium 20.4 mg/kg 0.67 0.33 1 04/04/19 02:22 04/04/19 10:26 7440-39-3 Lead 56.5 mg/kg 0.67 0.33 1 04/04/19 02:22 04/04/19 10:26 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 23.4 %a 0.10 0.10 1 04/04/19 09:25 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 69 of 97 aceAnalytical® wwwpace/abs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-26 (0-0.5') Lab ID: 35457430054 Collected: 03/27/19 13:46 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3050 Arsenic 19.5 mg/kg 0.66 0.33 1 04/04/19 02:22 04/04/19 10:29 7440-38-2 Barium 14.3 mg/kg 0.66 0.33 1 04/04/19 02:22 04/04/19 10:29 7440-39-3 Lead 29.8 mg/kg 0.66 0.33 1 04/04/19 02:22 04/04/19 10:29 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 12.9 % 0.10 0.10 1 04/04/19 09:25 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 70 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-26 (0.5-2') Lab ID: 35457430055 Collected: 03/27/19 13:48 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3050 Arsenic 9.6 mg/kg 0.67 0.34 1 04/04/19 02:22 04/04/19 10:31 7440-38-2 Barium 12.6 mg/kg 0.67 0.34 1 04/04/19 02:22 04/04/19 10:31 7440-39-3 Lead 15.3 mg/kg 0.67 0.34 1 04/04/19 02:22 04/04/19 10:31 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 22.8 % 0.10 0.10 1 04/04/19 09:25 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 71 of 97 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-26 (2-4') Lab ID: 35457430056 Collected: 03/27/19 13:50 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 1.6 mg/kg 0.58 0.29 1 04/04/19 02:22 04/04/19 10:34 7440-38-2 Barium 3.5 mg/kg 0.58 0.29 1 04/04/19 02:22 04/04/19 10:34 7440-39-3 Lead 3.4 mg/kg 0.58 0.29 1 04/04/19 02:22 04/04/19 10:34 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 04/04/2019 05:44 PM 12.2 % 0.10 0.10 1 04/04/19 09:25 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 72 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-27 (0-0.5') Lab ID: 35457430057 Collected: 03/27/19 14:00 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method. EPA 3050 Arsenic 5.5 mg/kg 0.56 0.28 1 04/04/19 02:22 04/04/19 10:37 7440-38-2 Barium 7.2 mg/kg 0.56 0.28 1 04/04/19 02:22 04/04/19 10:37 7440-39-3 Lead 5.1 mg/kg 0.56 0.28 1 04/04/19 02:22 04/04/19 10:37 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 04/04/2019 05:44 PM 5.7 ok 0.10 0.10 1 04/04/19 09:25 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 73 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-27 (0.5-2') Lab ID: 35457430058 Collected: 03/27/19 14:02 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 2.0 mg/kg 0.60 0.30 1 04/04/19 02:22 04/04/19 10:40 7440-38-2 Barium 7.3 mg/kg 0.60 0.30 1 04/04/19 02:22 04/04/19 10:40 7440-39-3 Lead 4.1 mg/kg 0.60 0.30 1 04/04/19 02:22 04/04/19 10:40 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 6.0 % 0.10 0.10 1 04/04/19 09:25 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 74 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-27 (2-4') Lab ID: 35457430059 Collected: 03/27/19 14:04 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 2.3 mg/kg 0.72 0.36 1 04/04/19 02:22 04/04/19 10:43 7440-38-2 Barium 7.7 mg/kg 0.72 0.36 1 04/04/19 02:22 04/04/19 10:43 7440-39-3 Lead 14.4 mg/kg 0.72 0.36 1 04/04/19 02:22 04/04/19 10:43 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 04/04/2019 05:44 PM 13.9 % 0.10 0.10 1 04/04/19 09:25 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 75 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-28 (0-0.5') Lab ID: 35457430060 Collected: 03/27/19 14:24 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 3.6 mg/kg 0.68 0.34 1 04/04/19 02:22 04/04/19 10:52 7440-38-2 Barium 22.9 mg/kg 0.68 0.34 1 04/04/19 02:22 04/04/19 10:52 7440-39-3 Lead 18.0 mg/kg 0.68 0.34 1 04/04/19 02:22 04/04/19 10:52 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 04/04/2019 05:44 PM 15.0 % 0.10 0.10 1 04/04/19 09:25 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 76 of 97 aceAnalytkal® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-28 (0.5-2') Lab ID: 35457430061 Collected: 03/27/19 14:26 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA 3050 Arsenic 0.29 U mg/kg 0.58 0.29 1 04/04/19 02:22 04/04/19 10:54 7440-38-2 Barium 6.9 mg/kg 0.58 0.29 1 04/04/19 02:22 04/04/19 10:54 7440-39-3 Lead 13.7 mg/kg 0.58 0.29 1 04/04/19 02:22 04/04/19 10:54 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 04/04/2019 05:44 PM 7.8 0.10 0.10 1 04/04/19 09:25 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 77 of 97 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-28 (2-4') Lab ID: 35457430062 Collected: 03/27/19 14:28 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 0.71 mg/kg 0.66 0.33 1 04/04/19 02:22 04/04/19 10:57 7440-38-2 Barium 4.7 mg/kg 0.66 0.33 1 04/04/19 02:22 04/04/19 10:57 7440-39-3 Lead 5.0 mg/kg 0.66 0.33 1 04/04/19 02:22 04/04/19 10:57 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 9.9 % 0.10 0.10 1 04/04/19 12:32 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 78 of 97 aceAnalytkal® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-28 (4-6') Lab ID: 35457430063 Collected: 03/27/19 14:30 Received: 03/28/19 17:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 4.8 mg/kg 0.77 0.38 1 04/04/19 02:22 04/04/19 11:00 7440-38-2 Barium 24.1 mg/kg 0.77 0.38 1 04/04/19 02:22 04/04/19 11:00 7440-39-3 Lead 85.4 mg/kg 0.77 0.38 1 04/04/19 02:22 04/04/19 11:00 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 20.9 % 0.10 0.10 1 04/04/19 12:32 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 79 of 97 aceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 528159 QC Batch Method: EPA 3050 Associated Lab Samples: 35457430001, 35457430002, 35457430008,35457430009, Analysis Method: EPA 6010 Analysis Description: 6010 MET Solid 35457430003, 35457430004, 35457430005, 35457430006, 35457430007, 35457430010, 35457430011, 35457430012, 35457430013 METHOD BLANK: 2858463 Associated Lab Samples: 35457430001, 35457430002, 35457430008,35457430009, Parameter Units Matrix: Solid 35457430003, 35457430004, 35457430005, 35457430006, 35457430007, 35457430010, 35457430011, 35457430012, 35457430013 Blank Reporting Result Limit MDL Analyzed Qualifiers Arsenic Barium Lead mg/kg mg/kg mg/kg 0.29 U 0.58 0.29 04/04/19 13:30 0.29 U 0.58 0.29 04/04/19 13:30 0.29 U 0.58 0.29 04/04/19 13:30 LABORATORY CONTROL SAMPLE: 2858464 Parameter Units Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers Arsenic Barium Lead mg/kg mg/kg mg/kg 30.3 28.1 93 80-120 30.3 29.1 96 80-120 30.3 29.4 97 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2858465 MS 35457327002 Spike Parameter Units Result Conc. 2858466 MSD Spike MS MSD MS MSD % Rec Max Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic mg/kg Barium Lead mg/kg mg/kg 5.4 44.3 50.8 48.1 36.3 96 61 75-125 28 20 J(M1), J(R1) 71.9 44.3 50.8 57.4 59.5 -33 -25 75-125 3 20 J(M1) 107 44.3 50.8 173 106 148 -1 75-125 48 20 J(M1), J(R1) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 80 of 97 ceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 528160 QC Batch Method: EPA 3050 Associated Lab Samples: 35457430014,35457430015, 35457430021,35457430022, 35457430029,35457430030, Analysis Method: Analysis Description: 35457430016,35457430017, 35457430023,35457430024, 35457430031, 35457430045 EPA 6010 6010 MET Solid 35457430018, 35457430019, 35457430020, 35457430026, 35457430027, 35457430028, METHOD BLANK: 2858471 Associated Lab Samples: Parameter Matrix: Solid 35457430014,35457430015,35457430016,35457430017,35457430018,35457430019,35457430020, 35457430021,35457430022,35457430023,35457430024,35457430026,35457430027,35457430028, 35457430029,35457430030,35457430031,35457430045 Blank Reporting Units Result Limit MDL Analyzed Qualifiers Arsenic Barium Lead mg/kg mg/kg mg/kg 0.26 U 0.52 0.26 04/04/19 12:57 0.26 U 0.52 0.26 04/04/19 12:57 0.26 U 0.52 0.26 04/04/19 12:57 LABORATORY CONTROL SAMPLE: 2858472 Parameter Units Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers Arsenic Barium ' .ead mg/kg mg/kg mg/kg 21.6 19.7 91 80-120 21.6 21.5 99 80-120 21.6 21.1 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2858473 MS 35457423001 Spike Parameter Units Result Conc. 2858474 MSD Spike MS Conc. Result MSD Result MS MSD % Rec Max % Rec % Rec Limits RPD RPD Qual Arsenic Barium Lead mg/kg mg/kg mg/kg 2.8 36.2 29.4 36.6 30.3 93 94 75-125 19 20 10.1 36.2 29.4 45.1 38.2 97 95 75-125 17 20 12.9 36.2 29.4 44.7 38.0 88 85 75-125 16 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 81 of 97 aceAnalytical® wwwpacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 528162 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 35457430032,35457430033,35457430034,35457430035,35457430036,35457430037,35457430038, 35457430039,35457430040,35457430041,35457430042,35457430043,35457430044,35457430046, 35457430047,35457430048,35457430049,35457430050,35457430051 METHOD BLANK: 2858477 Matrix: Solid Associated Lab Samples: 35457430032, 35457430033, 35457430034, 35457430035, 35457430036, 35457430037, 35457430038, 35457430039, 35457430040, 35457430041, 35457430042, 35457430043, 35457430044, 35457430046, 35457430047, 35457430048, 35457430049, 35457430050, 35457430051 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic mg/kg 0.23 U 0.47 0.23 04/04/19 11:03 Barium mg/kg 0.23 U 0.47 0.23 04/04/19 11:03 Lead mg/kg 0.23 U 0.47 0.23 04/04/19 11:03 LABORATORY CONTROL SAMPLE: 2858478 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic mg/kg 30.8 28.6 93 80-120 Barium mg/kg 30.8 29.1 94 80-120 Lead mg/kg 30.8 29.8 97 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2858479 2858480 MS MSD 35457430032 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic mg/kg 29.5 40.4 37 67.9 68.1 95 104 75-125 0 20 Barium mg/kg 212 40.4 37 278 290 163 210 75-125 4 20 J(M1) Lead mg/kg 500 40.4 37 2120 793 4010 792 75-125 91 20 J(M1), J(R1), L Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 82 of 97 (/eAnaIYticaI www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 528295 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 35457430025, 35457430052, 35457430053, 35457430054, 35457430055, 35457430056, 35457430057, 35457430058, 35457430059, 35457430060, 35457430061, 35457430062, 35457430063 METHOD BLANK: 2859507 Matrix: Solid Associated Lab Samples: 35457430025, 35457430052, 35457430053, 35457430054, 35457430055, 35457430056, 35457430057, 35457430058, 35457430059, 35457430060, 35457430061, 35457430062, 35457430063 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic mg/kg 0.31 U 0.61 0.31 04/04/19 09:43 Barium mg/kg 0.31 U 0.61 0.31 04/04/19 09:43 Lead mg/kg 0.31 U 0.61 0.31 04/04/19 09:43 LABORATORY CONTROL SAMPLE: 2859508 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic mg/kg 29.9 28.3 95 80-120 Barium mg/kg 29.9 28.8 96 80-120 Lead mg/kg 29.9 29.5 99 80-120 .MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2859509 2859510 MS MSD 2616728001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic mg/kg 18.2 41.9 37.8 66.7 61.1 116 114 75-125 9 20 Barium mg/kg 44.3 41.9 37.8 100 89.5 134 120 75-125 11 20 J(M1) Lead mg/kg 14.0 41.9 37.8 62.9 55.2 117 109 75-125 13 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 83 of 97 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 528365 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 35457430001,35457430002,35457430003,35457430004,35457430005,35457430006,35457430007, 35457430008,35457430009,35457430010,35457430011,35457430012,35457430013,35457430014, 35457430015,35457430016,35457430017,35457430018,35457430019,35457430020,35457430021, 35457430022,35457430023,35457430024,35457430025 SAMPLE DUPLICATE: 2859772 35457409031 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture 15.7 19.9 24 10 J(D6) SAMPLE DUPLICATE: 2859773 35457429005 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture °Jo 76.5 77.7 2 10 SAMPLE DUPLICATE: 2859774 35457430009 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture % 12.5 13.1 4 10 SAMPLE DUPLICATE: 2859775 35457430018 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture % 10.3 9.0 13 10 J(D6) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 84 of 97 aceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: QC Batch Method: 528390 ASTM D2974-87 Associated Lab Samples: 35457430026,35457430027,3 35457430033, 35457430034, 3 35457430040,35457430041,3 35457430047, 35457430048, 3 Analysis Method: Analysis Description: ASTM D2974-87 Dry Weight/Percent Moisture 5457430028,35457430029,35457430030,35457430031,35457430032, 5457430035,35457430036,35457430037,35457430038,35457430039, 5457430042,35457430043,35457430044,35457430045,35457430046, 5457430049,35457430050 SAMPLE DUPLICATE: 2859830 Parameter Units 35457430026 Result Dup Result Max RPD RPD Qualifiers Percent Moisture % 25.6 24.7 3 10 SAMPLE DUPLICATE: 2859831 Parameter Units 35457430036 Result Dup Result RPD Max RPD Qualifiers Percent Moisture Ok 21.4 20.1 6 10 SAMPLE DUPLICATE: 2859832 Parameter Units 35457430045 Result Dup Result RPD Max RPD Qualifiers 'ercent Moisture % 12.3 12.0 2 10 SAMPLE DUPLICATE: 2859833 Parameter Units 35457430054 Result Dup Result RPD Max RPD Qualifiers Percent Moisture 12.9 12.2 6 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 85 of 97 aceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 528455 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 35457430062, 35457430063 SAMPLE DUPLICATE: 2860322 35457430062 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture % 9.9 10.2 3 10 SAMPLE DUPLICATE: 2860323 35457605008 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture % 10.2 9.1 11 10 J(D6) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 86 of 97 (/eAnaI}icaI www.pacelabs.com QUALIFIERS Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS U Compound was analyzed for but not detected. J(D6) Estimated Value. The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. J(M 1) Estimated Value. Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. J(R1) Estimated Value. RPD value was outside control limits. L Off -scale high. Actual value is known to be greater than value given. Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 87 of 97 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Analytical QC Batch Method QC Batch Analytical Method Batch 35457430001 SB-13 (0-0.5') EPA 3050 528159 EPA 6010 528262 35457430002 SB-13 (0.5-2') EPA 3050 528159 EPA 6010 528262 35457430003 SB-13 (2-4') EPA 3050 528159 EPA 6010 528262 35457430004 SB-13 (4-6') EPA 3050 528159 EPA 6010 528262 35457430005 SB-14 (0-0.5') EPA 3050 528159 EPA 6010 528262 35457430006 SB-14 (0.5-2') EPA 3050 528159 EPA 6010 528262 35457430007 SB-14 (2-4') EPA 3050 528159 EPA 6010 528262 35457430008 SB-15 (0-0.5') EPA 3050 528159 EPA 6010 528262 35457430009 SB-15 (0.5-2') EPA 3050 528159 EPA 6010 528262 35457430010 SB-15 (2-4') EPA 3050 528159 EPA 6010 528262 35457430011 SB-15 (4-6') EPA 3050 528159 EPA 6010 528262 35457430012 SB-15 (6-8') EPA 3050 528159 EPA 6010 528262 35457430013 SB-16 (0-0.5') EPA 3050 528159 EPA 6010 528262 35457430014 SB-16 (0.5-2') EPA 3050 528160 EPA 6010 528263 35457430015 SB-16 (2-4') EPA 3050 528160 EPA 6010 528263 35457430016 SB-16 (4-6') EPA 3050 528160 EPA 6010 528263 35457430017 SB-16 (6-8') EPA 3050 528160 EPA 6010 528263 35457430018 SB-17 (0-0.5') EPA 3050 528160 EPA 6010 528263 35457430019 SB-17 (0.5-2') EPA 3050 528160 EPA 6010 528263 35457430020 SB-17 (2-4') EPA 3050 528160 EPA 6010 528263 35457430021 SB-17 (4-6') EPA 3050 528160 EPA 6010 528263 35457430022 SB-18 (0-0.5') EPA 3050 528160 EPA 6010 528263 35457430023 SB-18 (0.5-2') EPA 3050 528160 EPA 6010 528263 35457430024 SB-18 (2-4') EPA 3050 528160 EPA 6010 528263 35457430025 SB-18 (4-6') EPA 3050 528295 EPA 6010 528314 35457430026 SB-18 (6-8') EPA 3050 528160 EPA 6010 528263 35457430027 SB-19 (0-0.5') EPA 3050 528160 EPA 6010 528263 35457430028 SB-19 (0.5-2') EPA 3050 528160 EPA 6010 528263 35457430029 SB-19 (2-4') EPA 3050 528160 EPA 6010 528263 35457430030 SB-20 (0-0.5') EPA 3050 528160 EPA 6010 528263 35457430031 SB-20 (0.5-2') EPA 3050 528160 EPA 6010 528263 35457430032 SB-20 (2-4') EPA 3050 528162 EPA 6010 528264 35457430033 SB-21 (0-0.5') EPA 3050 528162 EPA 6010 528264 35457430034 SB-21 (0.5-2') EPA 3050 528162 EPA 6010 528264 35457430035 SB-21 (2-4') EPA 3050 528162 EPA 6010 528264 35457430036 SB-21 (4-6') EPA 3050 528162 EPA 6010 528264 35457430037 SB-21 (6-8') EPA 3050 528162 EPA 6010 528264 35457430038 SB-22 (0-0.5') EPA 3050 528162 EPA 6010 528264 35457430039 SB-22 (0.5-2') EPA 3050 528162 EPA 6010 528264 35457430040 SB-22 (2-4') EPA 3050 528162 EPA 6010 528264 35457430041 SB-22 (4-6') EPA 3050 528162 EPA 6010 528264 35457430042 SB-23 (0-0.5') EPA 3050 528162 EPA 6010 528264 35457430043 SB-23 (0.5-2') EPA 3050 528162 EPA 6010 528264 35457430044 SB-23 (2-4') EPA 3050 528162 EPA 6010 528264 35457430045 SB-23 (4-6') EPA 3050 528160 EPA 6010 528263 35457430046 SB-24 (0-0.5') EPA 3050 528162 EPA 6010 528264 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 88 of 97 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Lab ID Sample ID Analytical QC Batch Method QC Batch Analytical Method Batch 35457430047 SB-24 (0.5-2') EPA 3050 528162 EPA 6010 528264 35457430048 SB-24 (2-4') EPA 3050 528162 EPA 6010 528264 35457430049 SB-24 (4-6') EPA 3050 528162 EPA 6010 528264 35457430050 SB-25 (0-0.5') EPA 3050 528162 EPA 6010 528264 35457430051 SB-25 (0.5-2') EPA 3050 528162 EPA 6010 528264 35457430052 SB-25 (2-4') EPA 3050 528295 EPA 6010 528314 35457430053 SB-25 (4-6') EPA 3050 528295 EPA 6010 528314 35457430054 SB-26 (0-0.5') EPA 3050 528295 EPA 6010 528314 35457430055 SB-26 (0.5-2') EPA 3050 528295 EPA 6010 528314 35457430056 SB-26 (2-4') EPA 3050 528295 EPA 6010 528314 35457430057 SB-27 (0-0.5') EPA 3050 528295 EPA 6010 528314 35457430058 SB-27 (0.5-2') EPA 3050 528295 EPA 6010 528314 35457430059 SB-27 (2-4') EPA 3050 528295 EPA 6010 528314 35457430060 SB-28 (0-0.5') EPA 3050 528295 EPA 6010 528314 35457430061 SB-28 (0.5-2') EPA 3050 528295 EPA 6010 528314 35457430062 SB-28 (2-4') EPA 3050 528295 EPA 6010 528314 35457430063 SB-28 (4-6') EPA 3050 528295 EPA 6010 528314 35457430001 SB-13 (0-0.5') ASTM D2974-87 528365 35457430002 SB-13 (0.5-2') ASTM D2974-87 528365 15457430003 SB-13 (2-4') ASTM D2974-87 528365 5457430004 SB-13 (4-6') ASTM D2974-87 528365 35457430005 SB-14 (0-0.5') ASTM D2974-87 528365 35457430006 SB-14 (0.5-2') ASTM D2974-87 528365 35457430007 SB-14 (2-4') ASTM D2974-87 528365 35457430008 SB-15 (0-0.5') ASTM D2974-87 528365 35457430009 SB-15 (0.5-2') ASTM D2974-87 528365 35457430010 SB-15 (2-4') ASTM D2974-87 528365 35457430011 SB-15 (4-6') ASTM D2974-87 528365 35457430012 SB-15 (6-8') ASTM D2974-87 528365 35457430013 SB-16 (0-0.5') ASTM D2974-87 528365 35457430014 SB-16 (0.5-2') ASTM D2974-87 528365 35457430015 SB-16 (2-4') ASTM D2974-87 528365 35457430016 SB-16 (4-6') ASTM D2974-87 528365 35457430017 SB-16 (6-8') ASTM D2974-87 528365 35457430018 SB-17 (0-0.5') ASTM D2974-87 528365 35457430019 SB-17 (0.5-2') ASTM D2974-87 528365 35457430020 SB-17 (2-4') ASTM D2974-87 528365 35457430021 SB-17 (4-6') ASTM D2974-87 528365 35457430022 SB-18 (0-0.5') ASTM D2974-87 528365 35457430023 58-18 (0.5-2') ASTM D2974-87 528365 35457430024 SB-18 (2-4') ASTM D2974-87 528365 35457430025 SB-18 (4-6') ASTM D2974-87 528365 35457430026 SB-18 (6-8') ASTM D2974-87 528390 35457430027 SB-19 (0-0.5') ASTM D2974-87 528390 35457430028 SB-19 (0.5-2') ASTM D2974-87 528390 35457430029 SB-19 (2-4') ASTM D2974-87 528390 35457430030 SB-20 (0-0.5') ASTM D2974-87 528390 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 89 of 97 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melrese Golf Course Pace Project No.: 35457430 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Analytical QC Batch Method QC Batch Analytical Method Batch 35457430031 SB-20 (0.5-2') ASTM D2974-87 528390 35457430032 SB-20 (2-4') ASTM D2974-87 528390 35457430033 SB-21 (0-0.5') ASTM D2974-87 528390 35457430034 SB-21 (0.5-2') ASTM 02974-87 528390 35457430035 SB-21 (2-4') ASTM D2974-87 528390 35457430036 SB-21 (4-6') ASTM D2974-87 528390 35457430037 SB-21 (6-8') ASTM 02974-87 528390 35457430038 SB-22 (0-0.5') ASTM D2974-87 528390 35457430039 SB-22 (0.5-2') ASTM D2974-87 528390 35457430040 SB-22 (2-4') ASTM D2974-87 528390 35457430041 SB-22 (4-6') ASTM D2974-87 528390 35457430042 SB-23 (0-0.5') ASTM D2974-87 528390 35457430043 SB-23 (0.5-2') ASTM D2974-87 528390 35457430044 SB-23 (2-4') ASTM D2974-87 528390 35457430045 SB-23 (4-6') ASTM 02974-87 528390 35457430046 SB-24 (0-0.5') ASTM D2974-87 528390 35457430047 SB-24 (0.5-2') ASTM 02974-87 528390 35457430048 SB-24 (2-4') ASTM 02974-87 528390 35457430049 SB-24 (4-6') ASTM D2974-87 528390 35457430050 SB-25 (0-0.5') ASTM D2974-87 528390 35457430051 SB-25 (0.5-2') ASTM D2974-87 528390 35457430052 SB-25 (2-4') ASTM D2974-87 528390 35457430053 SB-25 (4-6') ASTM D2974-87 528390 35457430054 SB-26 (0-0.5') ASTM D2974-87 528390 35457430055 SB-26 (0.5-2') ASTM D2974-87 528390 35457430056 SB-26 (2-4') ASTM D2974-87 528390 35457430057 SB-27 (0-0.5') ASTM D2974-87 528390 35457430058 SB-27 (0.5-2') ASTM D2974-87 528390 35457430059 SB-27 (2-4') ASTM D2974-87 528390 35457430060 SB-28 (0-0.5') ASTM D2974-87 528390 35457430061 SB-28 (0.5-2') ASTM 02974-87 528390 35457430062 SB-28 (2-4') ASTM 02974-87 528455 35457430063 SB-28 (4-6') ASTM D2974-87 528455 Date: 04/04/2019 05:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 90 of 97 WO#:35457430 it Mil ill Section A Required Client Information: Cel;i o:Jrty Address FFBG 5751 Miami Lakes Drive, Mann Lakes. FL Required Project Information: Report To. Craig Clevenger Copy To IAIN-OF-CUSTODY / Analytical Request Document Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section C Invoice Information: Attention Company Name IPage : Of Email I,ci,:,ty Phone (305) 374-8300 !Fax Requested Due Date Purchase Order # Project Name Address Pace Quote Melrose Golf Course Project # 2018-3057 Pace Project Manager Pace Profile # Regulatory Agency Xs lL H SAMPLE ID One Character per box. Sample Ids must be unique MAr'I0 cote. W.r,r'r wr I ���� `:I ,, u: wa• w✓ of 'ATRIX CODE (see vat d codes to left) I COLLECTED SAMPLE TEMP AT COLLECTION u/ rw o O u Preservatives Z_ >- Requested Analysis Fil crcd (Y/N) START END a 2-'2O 2 O = 2 HCI = o Z Na2S2O3 c m c O Analyses Test 1 DATE TIME DATE TIME 1 2 - 3 4 - 5 6 7 8 9 10 11 12 I ADDITIONAL COMMENTS ~ RELINQU SHED BY AFFILIATION DATE TIME ACCEPTED BY / A 1 TION DATE TIME /7 / -1 I ).f"\-1 f I< ��/„ / , /:, , �� - _ SAMPLER NAME AND SIGNATURE PRINT Name of SAMPLER: SIGNATURE of SAMPLER: DATE Signed: -3 State / Location FL 0) SAMPLE CONDITIONS 8- N d N a o- sz C U >- O Page 91 of 97 °2x4ral.fica! Section A Required Client Information: Company Fr_EG Address Email 5751 Miami Lakes Drive. Miami Lakes. FL crlevencar c t: nrlc.1 cm Phone (305) 374-8300 R quc sl .d Due Date Fa Section 8 Required Project Information: Report To Copy To Purchase CHAIN -OF -CUSTODY / Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT All relevant fields must be completed accurately. Section C Craig Clevenger Order Protect Name Melrese Golf Course Project tt 2018-3057 Invoice Information: Attenl on Company Name Address Pace Quote Pace Project Manager Pace Profile I Page : Of Regulatory Agency State 1 Location SAMPLE ID One Character per box. (A-Z, 0-9 / , -) Sarnple Ids must be unique ADDITIONAL COMMENTS NIA i RI% I riinuri, W.rt•�: Veil• r Proclurl Oil w4;,r• nn omrrr 0 U 0 n C a O COLLECTED START DATE TIME • Requested Analysis Filtered (YIN) END DATE RELINOU SHED BY AFFILIATION TIME Preservatives O x 0 O Z 0 N Z fNCu a C O ileelIlIlil ilIlIlIlIli ilIlIlIlIli 1111 ......NN ,......IN RURUI....., ...I, ............ ACCEPTED BY / AFFILIATION DATE FL SAMPLER NAME AND SIGNATURE PRINT Name of SAMPLER: SIGNATURE of SAMPLER TIME ' L3 7 1 DATE Signed: 1 a. i SAMPLE CONDITIONS • a `m _ m 0 Z co j Y Page 92 of 97 �-i CHAIN -OF -CUSTODY / Analytical Request Document Section A Required Client Information: ELSG Report To Craig Clevenger Address 5751 Miami Lakes Drive. Miami Lakes, FL Copy To: Email CCII?vericer?'riL'ar)dr 00m I Purchase Order 1r- Phone (305) 374-8300 Ilia, Project Name Melrose Golf Course Requested Due Date Project# 2018-3057 company The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section B Section C Required Project Information: Invoice Information: Atlenhon Company Name Address Pace Quote Pace Project Manager Pace Profile 8 rowuIX I)rIntmq w.m' SAMPLE ID One Character per box. (A-Z 0-9 / , -) Sample Ids rnust be unique Coos uw w1 w 161 0 0 i E. 0 0 0 LLI COLLECTED START DATE TIME END DATE TIME TEMP AT COLLECTION c z 0 u 0 Preservatives Z >- Requested Analysis Filtered (YIN) Page : Of Regulatory Agency State / Location 2 N O 0/ 2 O 2 U 20 z 0 co z 0 6 8 9 10 11 12 ADDITIONAL COMMENTS RELINQU SHED BY AFFILIATION ic� SAMPLER NAME AN DATE D SIGNATUR PRINT Name of SAMPLER: E TIME SIGNATURE of SAMPLER: - Analyses Test ACCEPTED BY / AFFILIATION DATE Signed: DATE TIME > •3 7 yL ) a. FL U T= SAMPLE CONDITIONS cc 8 D 01 O N N Q m V Page 93 of 97 Company Address Email Phone arvi,l 1 CHAIN -OF -CUSTODY / Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section B Request .d Due Date Section A Section C Required Client Information; Required Project Information: Invoice Information: EEE.G Report To Craig Clevenger 5751 Miami Lakes Drive. Miami Lakes, FL Copy To cClevenatjr.c.•:e�lrrlc.ronl (305)374-8300 'Fax Purchase Order k Project Name Melrose Golf Course Project S, 2018-3057 Attention Company Marne Address Pace Quote Pace Project Manager Pace Profile 1/ I Page : Of Regulatory Agency 1 2 3 4 5 6 7 8 9 SAMPLE ID One Character per box. (A-Z,0-9/,-) Sample Ids must be unique Mr, r;<ix coot. 1ri111,19 W.,l-, UW W0,.t W1 W., W.,,1 WW Product 1' Soil/5old 51. 01 01 wn1,: We nrr Au Otlw•1 01 n.m TS COLLECTED START m DATE TIME END DATE TIME O 1 PLE TEMP AT COLLE CC U 0 m U Preservatives O S O z 0 2 >- Analyses Test Requested Analysis Filtered (Y/N) State / Location FL 10 11 12 ADDITIONAL COMMENTS RELINQU SHED BY AFFILIATION DATE Residual Chlor r e (YIN) TIME 4,141.3 /;7;L-� SAMPLER NAME AND SIGNATURE ACCEPTED BY / AFFILIATION PRINT Name of SAMPLER: ]] 4) )(%' SIGNATURE of SAMPLER: DATE TIME (I DATE Signed:^7/27//� SAMPLE CONDITIONS 3 3- 13, o_ m o Z 4iU52 Page 94 of 97 Section A Required Client Information: Company EEBG Address 5751 Mraml Lakes Dave, Miami Lakes, FL _mall l:ClevE-fl0Br:5?.c-:nnf(❑ Ct rti none (305) 374-8300 IFax toquested Due Date Section 8 Required Project Inforration: Report To Craig Clevenger Copy To Purchase Order # Project Name Melrose Golf Course Project if 2018-3057 CHAIN -OF -CUSTODY / Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section C Invoice Information: Attention Company Name Address Pace Quote Pace Project Manager Pace Profile # Page : Of Regulatory Agency SAMPLE ID One Character per box. (AZ 0-9 / • -) Sample Ids must be unique Maiwix _e(,I. Inulloinw,b, OW Want VJI NAV C)il ill Vein• wry 2 3 4 5 6 7 8 0 0 Ul a yr COLLECTED START DATE 'TIME END DATE TIME Requested Analysis Filtered (Y/N) State / Location FL Preservatives Z } Uncresened 0 N 0 O z O N z 0 9 10 11 Analyses Test 12 ADDITIONAL COMMENTS RELINQU SHED BY AFFILIATION DATE 312,41 SAMPLER NAME AND SIGNATURE PRINT Na me TIME ACCEPTED:. /AFFILIATION DATE 1/ TIME of SAMPLER: SIGNATURE of SAMPLER: ll DATE Signed: SAMPLE CONDITIONS o 0 `m _ 7 O 8 CNU r!, Page 95 of 97 Section A Required Client Information: Company Address EE&G CHAIN -OF -CUSTODY / Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section B Required Project Information: 5751 Miami Lakes Drive, Miami Lakes, FL Email 1CIt'.VL'nc1 Jrr-: Cu.111CiC.Crl171 Ph one (305) 374-8300 IFax Requested Due Date Lu 1 5 Report To Craig Clevenger Copy To Purchase Order # Project Name. Melrese Golf Course Project 11 2018-3057 SAMPLE ID One Character per box. (A-Z, O-9 / , -) Sample Ids must be unique MATRIX COOL Or,n,nq Wale/ eW W.Iter WT WJI, WW Piuouct SoNScin SI. 01 Ot. W.w• WP AR Oltu, or 7 i:.su�• I:i COLLECTED START DATE TIME END DATE TIME SAMPLE FLE TEMP AT COLLECTION Section C Invoice Information: Attention Company Name Address Pace Quote Pace Project Manager Pace Profile 8. OF CONTAINERS 0 C D O Preservatives 0 z z z 0 co Z O Analyses Test Requested Analysis Fil ercd (YIN Regulatory Agency State / Location FL U 6 7 8 9 10 11 12 ADDITIONAL COMMENTS REUNQU SHED BY AFFILIATION DATE ;. SAMPLER NAME AND SIGNATURE PRINT N TIME 6, J( i4 ACCEPTED BY / AFFILIATION ameofSAMPLER: ��/(.j/ j ((4 SIGNATURE of SAMPLER:/ 7 DATE .r TIME T (✓ (I l DATE Signed: —7i y O a. SAMPLE CONDITIONS 0 D d `m Page 96 of 97 Cr .... Project # Project Manager: Client: ei Foam '(SCUR WO# 3645 PM: CTR � � CLIENT; Due Date: 04/04/19 9 Da-e J�1�' //q T i ftD: t�ft� 7T i Cooler #1 Temp.'C Ill. O (Visual) ,L") (Correction Factor) `4/‘ Ci (Actual) Cooler #2 Temp.'C (Visual) (Correction Factor) (Actual) Cooler#3 Temp.'C (Visual) (Correction Factor) (Actual) Cooler #4 Temp.'C (Visual) (Correction Factor) (Actual) Cooler #5 Temp.'C (Visual) (Correction Factor) (Actual) Cooler #6Ternp.'C (Visual) (Correction Factor) (Actual) Courier: — Fed Ex — UPS USPS — C..enn: — Cc irnerc a �- P Shipping Method: ri .. D, Other Billing: Recp., e.. Sender .. ;ret;:Caro Tracking # Examining contents: Label: Deliver: pH: Date and Initials of person: -.5. l 7/1} Ss : :• .,- __: . _ . Custody Seal on Cooler/Box Present: _Yes ' Seals intact: _ Yes Ice: '.Vet Blue Dry Nene=2) Packing Material:—Buoh:!e rac 7 Bubble Zags —None Oiner Samples shorted to lab (If Yes. complete) Shored Date S,loried T me Chain of Custody P-€sent ' yes N Chain of Custody Filled Out -es No : A Relinquished Sranature & Sampler Name CO ,es No N :A Samples Arrived •nthin Hold Time iYes - Ny N A Rush TAT requested on COC f jfs G o N A Sufficient Volume /es No N A. Correct Containers Used /Yes No N A Containers lntec: / es No VA.. - c -e... Xs No N A _ --_ Yes No /�A - ......:.._ ...- ., Headspace in VOA Vials? , ,-q,,.•n Ye` No X; Trip Bunn Present Yes No N Client Notification/ Resolution: ^ersen Contact_ Comments/ Resolution (use back for additional comments): Project %tairaoer Revie':: Date Page 97 of 97 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 May 01, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on April 09, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. This is a revised report. TCLP Lead has been added for SB-32 (0.5-2') and SB-34 (2-4'). If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry, EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 49 ace Analytical www.pacelabs.com CERTIFICATIONS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alaska DEC- CS/UST/LUST Alabama Certification #: 41320 Arizona Certification# AZ0819 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 49 aceAnalytical® www.pacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35460150001 SB-29 (0-0.5) Solid 04/08/19 09:00 04/09/19 18:10 35460150002 SB-29 (0.5-2) Solid 04/08/19 09:02 04/09/19 18:10 35460150003 SB-29 (2-4) Solid 04/08/19 09:04 04/09/19 18:10 35460150004 SB-30 (0-0.5) Solid 04/08/19 10:00 04/09/19 18:10 35460150005 SB-30 (0.5-2) Solid 04/08/19 10:02 04/09/19 18:10 35460150006 SB-30 (2-4) Solid 04/08/19 10:04 04/09/19 18:10 35460150007 SB-31 (0-0.5) Solid 04/08/19 11:00 04/09/19 18:10 35460150008 SB-31 (0.5-2) Solid 04/08/19 11:02 04/09/19 18:10 35460150009 SB-31 (2-4) Solid 04/08/19 11:04 04/09/19 18:10 35460150010 SB-31 (4-6) Solid 04/08/19 11:06 04/09/19 18:10 35460150011 SB-32 (0-0.5) Solid 04/08/19 12:00 04/09/19 18:10 35460150012 SB-32 (0.5-2) Solid 04/08/19 12:02 04/09/19 18:10 35460150013 SB-32 (2-4) Solid 04/08/19 12:04 04/09/19 18:10 35460150014 SB-33 (0-0.5) Solid 04/08/19 12:45 04/09/19 18:10 35460150015 SB-33 (0.5-2) Solid 04/08/19 12:47 04/09/19 18:10 35460150016 SB-33 (2-4) Solid 04/08/19 12:49 04/09/19 18:10 5460150017 SB-34 (0-0.5) Solid 04/08/19 13:05 04/09/19 18:10 35460150018 SB-34 (0.5-2) Solid 04/08/19 13:07 04/09/19 18:10 35460150019 SB-34 (2-4) Solid 04/08/19 13:09 04/09/19 18:10 35460150020 SB-35 (0-0.5) Solid 04/08/19 13:20 04/09/19 18:10 35460150021 SB-35 (0.5-2) Solid 04/08/19 13:22 04/09/19 18:10 35460150022 SB-35 (2-4) Solid 04/08/19 13:24 04/09/19 18:10 35460150023 SB-36 (0-0.5) Solid 04/08/19 13:35 04/09/19 18:10 35460150024 SB-36 (0.5-2) Solid 04/08/19 13:37 04/09/19 18:10 35460150025 SB-36 (2-4) Solid 04/08/19 13:39 04/09/19 18:10 35460150026 SB-37 (0-0.5) Solid 04/08/19 13:50 04/09/19 18:10 35460150027 SB-37 (0.5-2) Solid 04/08/19 13:52 04/09/19 18:10 35460150028 SB-37 (2-4) Solid 04/08/19 13:54 04/09/19 18:10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 49 aceAnalytical® www.pacelabs.com SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 35460150001 SB-29 (0-0.5) EPA 6010 JWP 2 PASI-O ASTM D2974-87 CLT 1 PASI-O 35460150002 SB-29 (0.5-2) EPA 6010 JWP 2 PASI-O ASTM D2974-87 CLT 1 PASI-O 35460150003 SB-29 (2-4) EPA6010 JWP 2 PASI-O ASTM D2974-87 CLT 1 PASI-O 35460150004 SB-30 (0-0.5) EPA 6010 JWP 2 PASI-O ASTM D2974-87 CLT 1 PASI-O 35460150005 SB-30 (0.5-2) EPA 6010 JWP 2 PASI-O ASTM D2974-87 CLT 1 PASI-O 35460150006 SB-30 (2-4) EPA6010 JWP 2 PASI-O ASTM D2974-87 CLT 1 PASI-O 35460150007 SB-31 (0-0.5) EPA 6010 JWP 2 PASI-O ASTM D2974-87 CLT 1 PASI-O 35460150008 SB-31 (0.5-2) EPA 6010 JWP 2 PASI-O ASTM D2974-87 CLT 1 PASI-O 35460150009 SB-31 (2-4) EPA 6010 JWP 2 PASI-O ASTM D2974-87 CLT 1 PASI-O 35460150010 SB-31 (4-6) EPA 6010 JWP 2 PASI-O ASTM D2974-87 CLT 1 PASI-O 35460150011 SB-32 (0-0.5) EPA 6010 JWP 2 PASI-O ASTM D2974-87 CLT 1 PASI-O 35460150012 SB-32 (0.5-2) EPA 6010 JWP 2 PASI-O EPA6010 SC1 1 PASI-O ASTM D2974-87 CLT 1 PASI-O 35460150013 SB-32 (2-4) EPA 6010 JWP 2 PASI-O ASTM D2974-87 CLT 1 PASI-O 35460150014 SB-33 (0-0.5) EPA 6010 JWP 2 PASI-O ASTM D2974-87 CLT 1 PASI-O 35460150015 SB-33 (0.5-2) EPA6010 JWP 2 PASI-O ASTM D2974-87 CLT 1 PASI-O 35460150016 SB-33 (2-4) EPA 6010 JWP 2 PASI-O ASTM D2974-87 CLT 1 PASI-O 35460150017 SB-34 (0-0.5) EPA 6010 JWP 2 PASI-O ASTM D2974-87 CLT 1 PASI-O 35460150018 SB-34 (0.5-2) EPA 6010 JWP 2 PASI-O ASTM D2974-87 CLT 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 49 Pace Analytical Services, LLC 2ceAnal ical3610Park Central Blvd N Pompano Beach, FL 33064 www.pacelabs.com 954-582-4300 SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 35460150019 SB-34 (2-4) EPA 6010 JWP 2 PASI-O EPA 6010 SC1 1 PASI-O ASTM D2974-87 CLT 1 PASI-O 35460150020 SB-35 (0-0.5) EPA 6010 JWP 2 PASI-O ASTM D2974-87 CLT 1 PASI-O 35460150021 SB-35 (0.5-2) EPA 6010 SC1 2 PASI-O ASTM D2974-87 CLT 1 PASI-O 35460150022 SB-35 (2-4) EPA 6010 SC1 2 PASI-O ASTM D2974-87 CLT 1 PASI-O 35460150023 SB-36 (0-0.5) EPA 6010 JWP 2 PASI-O ASTM D2974-87 CLT 1 PASI-O 35460150024 SB-36 (0.5-2) EPA6010 JWP, SC1 2 PASI-O ASTM D2974-87 CLT 1 PASI-O 35460150025 SB-36 (2-4) EPA 6010 SC1 2 PASI-O ASTM D2974-87 CLT 1 PASI-O '5460150026 SB-37 (0-0.5) EPA6010 SC1 2 PASI-O ASTM D2974-87 CLT 1 PASI-O 35460150027 SB-37 (0.5-2) EPA 6010 JWP. SC1 2 PASI-O ASTM D2974-87 CLT 1 PASI-O 35460150028 SB-37 (2-4) EPA6010 JWP, SC1 2 PASI-O ASTM D2974-87 CLT 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 49 aceAnalytical® www.pacelabs.com SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35460150001 SB-29 (0-0.5) EPA 6010 Arsenic 27.5 mg/kg 0.61 04/17/19 05:50 EPA 6010 Lead 5.8 mg/kg 0.61 04/17/19 05:50 ASTM D2974-87 Percent Moisture 14.1 % 0.10 04/11/19 09:46 35460150002 SB-29 (0.5-2) EPA 6010 Arsenic 12.5 mg/kg 0.64 04/17/19 06:07 EPA 6010 Lead 116 mg/kg 0.64 04/17/19 06:07 ASTM D2974-87 Percent Moisture 12.4 % 0.10 04/11/19 09:46 35460150003 SB-29 (2-4) EPA 6010 Arsenic 2.4 mg/kg 0.66 04/17/19 06:11 EPA 6010 Lead 381 mg/kg 6.6 04/17/19 20:55 ASTM D2974-87 Percent Moisture 15.3 % 0.10 04/11/19 09:46 35460150004 SB-30 (0-0.5) EPA 6010 Arsenic 27.7 mg/kg 0.66 04/17/19 06:15 EPA 6010 Lead 5.9 mg/kg 0.66 04/17/19 06:15 ASTM D2974-87 Percent Moisture 14.7 % 0.10 04/11/19 09:46 35460150005 SB-30 (0.5-2) EPA 6010 Arsenic 5.1 mg/kg 0.71 04/17/19 06:19 EPA 6010 Lead 78.6 mg/kg 0.71 04/17/19 06:19 ASTM D2974-87 Percent Moisture 15.5 % 0.10 04/11/19 09:46 35460150006 SB-30 (2-4) EPA 6010 Arsenic 4.1 mg/kg 0.64 04/17/19 06:23 EPA 6010 Lead 26.3 mg/kg 0.64 04/17/19 06:23 ASTM D2974-87 Percent Moisture 26.0 % 0.10 04/11/19 09:47 35460150007 SB-31 (0-0.5) EPA 6010 Arsenic 6.0 mg/kg 0.49 04/17/19 06:27 EPA 6010 Lead 7.4 mg/kg 0.49 04/17/19 06:27 ASTM D2974-87 Percent Moisture 6.6 % 0.10 04/11/19 09:47 35460150008 SB-31 (0.5-2) EPA 6010 Arsenic 5.1 mg/kg 0.56 04/17/19 06:39 EPA 6010 Lead 10.1 mg/kg 0.56 04/17/19 06:39 ASTM D2974-87 Percent Moisture 7.7 % 0.10 04/11/19 09:47 35460150009 SB-31 (2-4) EPA 6010 Arsenic 3.5 mg/kg 0.69 04/17/19 06:43 EPA 6010 Lead 25.5 mg/kg 0.69 04/17/19 06:43 ASTM D2974-87 Percent Moisture 11.9 % 0.10 04/11/19 09:47 35460150010 SB-31 (4-6) EPA 6010 Arsenic 2.2 mg/kg 0.69 04/17/19 20:59 EPA 6010 Lead 96.7 mg/kg 0.69 04/17/19 20:59 ASTM D2974-87 Percent Moisture 11.1 % 0.10 04/11/19 09:47 J(D6) 35460150011 SB-32 (0-0.5) EPA 6010 Arsenic 7.7 mg/kg 0.63 04/17/19 06:51 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 49 faceAnalytical www pacelabs.com SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35460150011 SB-32 (0-0.5) EPA 6010 Lead 28.2 mg/kg ASTM D2974-87 Percent Moisture 5.7 % 0.63 04/17/19 06:51 0.10 04/11/19 09:47 35460150012 SB-32 (0.5-2) EPA 6010 Arsenic 22.7 mg/kg 0.57 04/17/19 06:56 EPA 6010 Lead 5820 mg/kg 56.9 04/17/19 21:03 EPA 6010 Lead 0.17 mg/L 0.10 04/24/19 11:26 ASTM D2974-87 Percent Moisture 10.4 % 0.10 04/11/19 09:47 35460150013 SB-32 (2-4) EPA 6010 Arsenic 10 mg/kg 0.80 04/17/19 07:00 EPA 6010 Lead 1020 mg/kg 16.1 04/17/19 21:15 ASTM D2974-87 Percent Moisture 25.7 % 0.10 04/11/19 09:47 35460150014 SB-33 (0-0.5) EPA 6010 Arsenic 0.56 I mg/kg 0.60 04/17/19 07:04 EPA 6010 Lead 3.9 mg/kg 0.60 04/17/19 07:04 ASTM D2974-87 Percent Moisture 6.4 % 0.10 04/11/19 09:48 35460150015 SB-33 (0.5-2) 'EPA 6010 Arsenic 1.4 mg/kg 0.53 04/17/19 07:08 _PA 6010 Lead 3.3 mg/kg 0.53 04/17/19 07:08 ASTM D2974-87 Percent Moisture 7.5 % 0.10 04/11/19 09:48 35460150016 SB-33 (2-4) EPA 6010 Arsenic 16.6 mg/kg 0.65 04/17/19 07:12 EPA 6010 Lead 42.0 mg/kg 0.65 04/17/19 07:12 ASTM D2974-87 Percent Moisture 13.4 % 0.10 04/11/19 09:48 35460150017 SB-34 (0-0.5) EPA 6010 Arsenic 9.2 mg/kg 0.52 04/17/19 07:16 EPA 6010 Lead 49.8 mg/kg 0.52 04/17/19 07:16 ASTM D2974-87 Percent Moisture 11.5 % 0.10 04/11/19 09:48 35460150018 SB-34 (0.5-2) EPA 6010 Arsenic 52.8 mg/kg 0.66 04/17/19 07:28 EPA 6010 Lead 216 mg/kg 6.6 04/17/19 21:19 ASTM D2974-87 Percent Moisture 16.8 % 0.10 04/11/19 09:48 35460150019 SB-34 (2-4) EPA 6010 Arsenic 49.3 mg/kg 0.98 04/17/19 07:32 EPA 6010 Lead 7650 mg/kg 98.3 04/17/19 21:23 EPA 6010 Lead 0.50 mg/L 0.10 05/01/19 13:34 ASTM D2974-87 Percent Moisture 38.6 % 0.10 04/11/19 09:48 J(D6) 35460150020 SB-35 (0-0.5) EPA 6010 Arsenic 3.4 mg/kg 0.63 04/17/19 07:37 EPA 6010 Lead 6.3 mg/kg 0.63 04/17/19 07:37 ASTM D2974-87 Percent Moisture 6.1 % 0.10 04/11/19 09:48 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 49 aceAnalytical® www.pacelabs.com SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35460150021 SB-35 (0.5-2) EPA 6010 Arsenic 7.4 mg/kg 0.61 04/15/19 22:23 EPA 6010 Lead 97.7 mg/kg 0.61 04/15/19 22:23 ASTM D2974-87 Percent Moisture 15.7 % 0.10 04/11/19 09:48 35460150022 SB-35 (2-4) EPA 6010 Arsenic 10.4 mg/kg 0.80 04/15/19 22:32 EPA 6010 Lead 1720 mg/kg 16.1 04/16/19 13:58 ASTM D2974-87 Percent Moisture 36.0 % 0.10 04/11/19 09:49 35460150023 SB-36 (0-0.5) EPA 6010 Arsenic 20.4 mg/kg 0.59 04/16/19 22:00 EPA 6010 Lead 21.1 mg/kg 0.59 04/16/19 22:00 ASTM D2974-87 Percent Moisture 18.9 % 0.10 04/11/19 09:49 35460150024 SB-36 (0.5-2) EPA 6010 Arsenic 12.0 mg/kg 0.69 04/15/19 20:00 EPA 6010 Lead 462 mg/kg 6.9 04/16/19 22:04 ASTM D2974-87 Percent Moisture 13.6 % 0.10 04/11/19 09:49 35460150025 SB-36 (2-4) EPA 6010 Arsenic 19.1 mg/kg 0.73 04/15/19 20:03 EPA 6010 Lead 106 mg/kg 0.73 04/15/19 20:03 ASTM D2974-87 Percent Moisture 19.8 % 0.10 04/11/19 09:49 35460150026 SB-37 (0-0.5) EPA 6010 Arsenic 12.0 mg/kg 0.73 04/15/19 20:06 EPA 6010 Lead 10.0 mg/kg 0.73 04/15/19 20:06 ASTM D2974-87 Percent Moisture 15.4 % 0.10 04/11/19 09:49 35460150027 SB-37 (0.5-2) EPA 6010 Arsenic 12.7 mg/kg 0.61 04/15/19 20:09 EPA 6010 Lead 224 mg/kg 6.1 04/16/19 22:08 ASTM D2974-87 Percent Moisture 15.0 % 0.10 04/11/19 09:49 35460150028 SB-37 (2-4) EPA 6010 Arsenic 75.9 mg/kg 1.1 04/15/19 20:12 EPA 6010 Lead 1920 mg/kg 22.3 04/16/19 22:12 ASTM D2974-87 Percent Moisture 45.3 % 0.10 04/11/19 09:49 J(D6) REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 49 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-29 (0-0.5) Lab ID: 35460150001 Collected: 04/08/19 09:00 Received: 04/09/19 18:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 27.5 mg/kg 0.61 0.31 1 04/11/19 15:19 04/17/19 05:50 7440-38-2 Lead 5.8 mg/kg 0.61 0.31 1 04/11/19 15:19 04/17/19 05:50 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 14.1 % 0.10 0.10 1 04/11/19 09:46 Date: 05/01/2019 03:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 49 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 36- 0 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-29 (0.5-2) Lab ID: 35460150002 Collected: 04/08/19 09:02 Received: 04/09/19 18:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 12.5 mg/kg 0.64 0.32 1 04/11/19 15:19 04/17/19 06:07 7440-38-2 Lead 116 mg/kg 0.64 0.32 1 04/11/19 15:19 04/17/19 06:07 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 05/01/2019 03:11 PM 12.4 % 0.10 0.10 1 04/11/19 09:46 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 49 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-29 (2-4) Lab ID: 35460150003 Collected: 04/08/19 09:04 Received: 04/09/19 18:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 2.4 mg/kg 0.66 0.33 1 04/11/19 15:19 04/17/19 06:11 7440-38-2 Lead 381 mg/kg 6.6 3.3 10 04/11/19 15:19 04/17/19 20:55 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 15.3 % 0.10 0.10 1 04/11/19 09:46 Date: 05/01/2019 03:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 49 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-30 (0-0.5) Lab ID: 35460150004 Collected: 04/08/19 10:00 Received: 04/09/19 18:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 27.7 mg/kg 0.66 0.33 1 04/11/19 15:19 04/17/19 06:15 7440-38-2 Lead 5.9 mg/kg 0.66 0.33 1 04/11/19 15:19 04/17/19 06:15 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 14.7 % 0.10 0.10 1 04/11/19 09:46 Date: 05/01/2019 03:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 49 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach. FL 33064 954-582-4300 Sample: SB-30 (0.5-2) Lab ID: 35460150005 Collected: 04/08/19 10:02 Received: 04/09/19 18:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 5.1 mg/kg 0.71 0.36 1 04/11/19 15:19 04/17/19 06:19 7440-38-2 Lead 78.6 mg/kg 0.71 0.36 1 04/11/19 15:19 04/17/19 06:19 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 05/01/2019 03:11 PM 15.5 % 0.10 0.10 1 04/11/19 09:46 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 49 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-562-4300 Sample: SB-30 (2-4) Lab ID: 35460150006 Collected: 04/08/19 10:04 Received: 04/09/19 18:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 4.1 mg/kg 0.64 0.32 1 04/11/19 15:19 04/17/19 06:23 7440-38-2 Lead 26.3 mg/kg 0.64 0.32 1 04/11/19 15:19 04/17/19 06:23 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 26.0 °Ao 0.10 0.10 1 04/11/19 09:47 Date: 05/01/2019 03:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 49 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Sample: SB-31 (0-0.5) Lab ID: 35460150007 Collected: 04/08/19 11:00 Received: 04/09/19 18:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 6.0 mg/kg 0.49 0.24 1 04/11/19 15:19 04/17/19 06:27 7440-38-2 Lead 7.4 mg/kg 0.49 0.24 1 04/11/19 15:19 04/17/19 06:27 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 6.6 % 0.10 0.10 1 04/11/19 09:47 Date: 05/01/2019 03:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 49 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-31 (0.5-2) Lab ID: 35460150008 Collected: 04/08/19 11:02 Received: 04/09/19 18:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 5.1 mg/kg 0.56 0.28 1 04/11/19 15:19 04/17/19 06:39 7440-38-2 Lead 10.1 mg/kg 0.56 0.28 1 04/11/19 15:19 04/17/19 06:39 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 05/01/2019 03:11 PM 7.7 % 0.10 0.10 1 04/11/19 09:47 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 49 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-31 (2-4) Lab ID: 35460150009 Collected: 04/08/19 11:04 Received: 04/09/19 18:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3050 Arsenic 3.5 mg/kg 0.69 0.35 1 04/11/19 15:19 04/17/19 06:43 7440-38-2 Lead 25.5 mg/kg 0.69 0.35 1 04/11/19 15:19 04/17/19 06:43 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 11.9 % 0.10 0.10 1 04/11/19 09:47 Date: 05/01/2019 03:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 49 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-31 (4-6) Lab ID: 35460150010 Collected: 04/08/19 11:06 Received: 04/09/19 18:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 2.2 mg/kg 0.69 0.35 1 04/11/19 15:19 04/17/19 20:59 7440-38-2 Lead 96.7 mg/kg 0.69 0.35 1 04/11/19 15:19 04/17/19 20:59 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 11.1 % 0.10 0.10 1 04/11/19 09:47 Date: 05/01/2019 03:11 PM REPORT OF LABORATORY ANALYSIS J(D6) This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 49 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Sample: SB-32 (0-0.5) Lab ID: 35460150011 Collected: 04/08/19 12:00 Received: 04/09/19 18:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 7.7 mg/kg 0.63 0.31 1 04/11/19 15:19 04/17/19 06:51 7440-38-2 Lead 28.2 mg/kg 0.63 0.31 1 04/11/19 15:19 04/17/19 06:51 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 5.7 % 0.10 0.10 1 04/11/19 09:47 Date: 05/01/2019 03:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 49 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-32 (0.5-2) Lab ID: 35460150012 Collected: 04/08/19 12:02 Received: 04/09/19 18:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3050 Arsenic 22.7 mg/kg 0.57 0.28 1 04/11/19 15:19 04/17/19 06:56 7440-38-2 Lead 5820 mg/kg 56.9 28.4 100 04/11/19 15:19 04/17/19 21:03 7439-92-1 6010 MET ICP, TCLP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Leachate Method/Date: EPA 1311; 04/22/19 15:43 Initial pH: 5; Final pH: 5 Lead 0.17 mg/L 0.10 0.046 1 04/23/19 20:33 04/24/19 11:26 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 10.4 % 0.10 0.10 1 04/11/19 09:47 Date: 05/01/2019 03:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 49 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Sample: SB-32 (2-4) Lab ID: 35460150013 Collected: 04/08/19 12:04 Received: 04/09/19 18:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 10 mg/kg 0.80 0.40 1 04/11/19 15:19 04/17/19 07:00 7440-38-2 Lead 1020 mg/kg 16.1 8.0 20 04/11/19 15:19 04/17/19 21:15 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 05/01/2019 03:11 PM 25.7 % 0.10 0.10 1 04/11/19 09:47 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 21 of 49 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No. 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-33 (0-0.5) Lab ID: 35460150014 Collected: 04/08/19 12:45 Received: 04/09/19 18:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 0.56 I mg/kg Lead 3.9 mg/kg 0.60 0.30 1 04/11/19 15:19 04/17/19 07:04 7440-38-2 0.60 0.30 1 04/11/19 15:19 04/17/19 07:04 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 05/01/2019 03:11 PM 6.4 % 0.10 0.10 1 04/11/19 09:48 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 22 of 49 aceAnalytical wwwpacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-33 (0.5-2) Lab ID: 35460150015 Collected: 04/08/19 12:47 Received: 04/09/19 18:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 1.4 mg/kg 0.53 0.27 1 04/11/19 15:19 04/17/19 07:08 7440-38-2 Lead 3.3 mg/kg 0.53 0.27 1 04/11/19 15:19 04/17/19 07:08 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 7.5 % 0.10 0.10 1 04/11/19 09:48 Date: 05/01/2019 03:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 49 aceAnalytical www pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-33 (2-4) Lab ID: 35460150016 Collected: 04/08/19 12:49 Received: 04/09/19 18:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 16.6 mg/kg 0.65 0.32 1 04/11/19 15:19 04/17/19 07:12 7440-38-2 Lead 42.0 mg/kg 0.65 0.32 1 04/11/19 15:19 04/17/19 07:12 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 05/01/2019 03:11 PM 13.4 0.10 0.10 1 04/11/19 09:48 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 24 of 49 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-34 (0-0.5) Lab ID: 35460150017 Collected: 04/08/19 13:05 Received: 04/09/19 18:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 9.2 mg/kg 0.52 0.26 1 04/11/19 15:19 04/17/19 07:16 7440-38-2 Lead 49.8 mg/kg 0.52 0.26 1 04/11/19 15:19 04/17/19 07:16 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 11.5 % 0.10 0.10 1 04/11/19 09:48 Date: 05/01/2019 03:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 25 of 49 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-34 (0.5-2) Lab ID: 35460150018 Collected: 04/08/19 13:07 Received: 04/09/19 18:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3050 Arsenic 52.8 mg/kg 0.66 0.33 1 04/11/19 15:19 04/17/19 07:28 7440-38-2 Lead 216 mg/kg 6.6 3.3 10 04/11/19 15:19 04/17/19 21:19 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 05/01/2019 03:11 PM 16.8 0.10 0.10 1 04/11/19 09:48 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 26 of 49 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Sample: SB-34 (2-4) Lab ID: 35460150019 Collected: 04/08/19 13:09 Received: 04/09/19 18:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 49.3 mg/kg 0.98 0.49 1 04/11/19 15:19 04/17/19 07:32 7440-38-2 Lead 7650 mg/kg 98.3 49.2 100 04/11/19 15:19 04/17/19 21:23 7439-92-1 6010 MET ICP, TCLP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Leachate Method/Date: EPA 1311; 04/29/19 15:30 Initial pH: 5; Final pH: 5 Lead 0.50 mg/L 0.10 0.046 1 04/30/19 17:34 05/01/19 13:34 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 38.6 % 0.10 0.10 1 04/11/19 09:48 Date: 05/01/2019 03:11 PM REPORT OF LABORATORY ANALYSIS J(D6) This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 27 of 49 aceAnalytical wwwpacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-35 (0-0.5) Lab ID: 35460150020 Collected: 04/08/19 13:20 Received: 04/09/19 18:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 3.4 mg/kg Lead 6.3 mg/kg 0.63 0.32 1 04/11/19 15:19 04/17/19 07:37 7440-38-2 0.63 0.32 1 04/11/19 15:19 04/17/19 07:37 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 05/01/2019 03:11 PM 6.1 % 0.10 0.10 1 04/11/19 09:48 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC, Page 28 of 49 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-35 (0.5-2) Lab ID: 35460150021 Collected: 04/08/19 13:22 Received: 04/09/19 18:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 7.4 mg/kg Lead 97.7 mg/kg 0.61 0.30 1 04/13/19 04:52 04/15/19 22:23 7440-38-2 0.61 0.30 1 04/13/19 04:52 04/15/19 22:23 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 05/01/2019 03:11 PM 15.7 ok 0.10 0.10 1 04/11/19 09:48 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 29 of 49 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-35 (2-4) Lab ID: 35460150022 Collected: 04/08/19 13:24 Received: 04/09/19 18:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 10.4 mg/kg 0.80 0.40 1 04/13/19 04:52 04/15/19 22:32 7440-38-2 Lead 1720 mg/kg 16.1 8.0 20 04/13/19 04:52 04/16/19 13:58 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 05/01/2019 03:11 PM 36.0 0.10 0.10 1 04/11/19 09:49 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 30 of 49 aceAnalytical wwwpacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-36 (0-0.5) Lab ID: 35460150023 Collected: 04/08/19 13:35 Received: 04/09/19 18:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 20.4 mg/kg 0.59 0.30 1 04/12/19 11:09 04/16/19 22:00 7440-38-2 Lead 21.1 mg/kg 0.59 0.30 1 04/12/19 11:09 04/16/19 22:00 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 18.9 % 0.10 0.10 1 04/11/19 09:49 Date: 05/01/2019 03:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 31 of 49 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-36 (0.5-2) Lab ID: 35460150024 Collected: 04/08/19 13:37 Received: 04/09/19 18.10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 12.0 mg/kg 0.69 0.35 1 04/12/19 11:09 04/15/19 20:00 7440-38-2 Lead 462 mg/kg 6.9 3.5 10 04/12/19 11:09 04/16/19 22:04 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 05/01/2019 03:11 PM 13.6 ok 0.10 0.10 1 04/11/19 09:49 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 32 of 49 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Sample: SB-36 (2-4) Lab ID: 35460150025 Collected: 04/08/19 13:39 Received: 04/09/19 18:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3050 Arsenic 19.1 mg/kg 0.73 0.37 1 04/12/19 11:09 04/15/19 20:03 7440-38-2 Lead 106 mg/kg 0.73 0.37 1 04/12/19 11:09 04/15/19 20:03 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 05/01/2019 03:11 PM 19.8 % 0.10 0.10 1 04/11/19 09:49 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 33 of 49 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-37 (0-0.5) Lab ID: 35460150026 Collected: 04/08/19 13:50 Received: 04/09/19 18:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 12.0 mg/kg 0.73 0.37 1 04/12/19 11:09 04/15/19 20:06 7440-38-2 Lead 10.0 mg/kg 0.73 0.37 1 04/12/19 11:09 04/15/19 20:06 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 15.4 % 0.10 0.10 1 04/11/19 09:49 Date: 05/01/2019 03:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 34 of 49 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-37 (0.5-2) Lab ID: 35460150027 Collected: 04/08/19 13:52 Received: 04/09/19 18:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3050 Arsenic 12.7 mg/kg Lead 224 mg/kg 0.61 0.30 1 04/12/19 11:09 04/15/19 20:09 7440-38-2 6.1 3.0 10 04/12/19 11:09 04/16/19 22:08 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 05/01/2019 03:11 PM 15.0 0.10 0.10 1 04/11/19 09:49 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 35 of 49 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: SB-37 (2-4) Lab ID: 35460150028 Collected: 04/08/19 13:54 Received: 04/09/19 18:10 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 75.9 mg/kg 1.1 0.56 1 04/12/19 11:09 04/15/19 20:12 7440-38-2 Lead 1920 mg/kg 22.3 11.1 20 04/12/19 11:09 04/16/19 22:12 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 05/01/2019 03:11 PM 45.3 0.10 0.10 1 REPORT OF LABORATORY ANALYSIS 04/11/19 09:49 J(D6) This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 36 of 49 PaceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 530316 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 35460150001,35460150002,35460150003,35460150004,35460150005,35460150006,35460150007, 35460150008,35460150009,35460150010,35460150011,35460150012,35460150013,35460150014, 35460150015,35460150016,35460150017,35460150018,35460150019,35460150020 METHOD BLANK: 2871248 Matrix: Solid Associated Lab Samples: 35460150001, 35460150002, 35460150003, 35460150004, 35460150005, 35460150006, 35460150007, 35460150008, 35460150009, 35460150010, 35460150011, 35460150012, 35460150013, 35460150014, 35460150015, 35460150016, 35460150017, 35460150018, 35460150019, 35460150020 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic mg/kg 0.24 U 0.48 0.24 04/17/19 05:35 Lead mg/kg 0.24 U 0.48 0.24 04/17/19 05:35 LABORATORY CONTROL SAMPLE: 2871249 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic mg/kg 15.1 13.8 91 80-120 Lead mg/kg 15.1 15.2 101 80-120 AATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2871250 2871251 MS MSD 35460150001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic mg/kg 27.5 17.6 16.9 43.3 40.9 90 79 75-125 6 20 Lead mg/kg 5.8 17.6 16.9 21.4 20.7 88 88 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 05/01/2019 03:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 37 of 49 2eAnalytical° www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 530540 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 35460150023, 35460150024, 35460150025, 35460150026, 35460150027, 35460150028 METHOD BLANK: 2872954 Matrix: Solid Associated Lab Samples: 35460150023, 35460150024, 35460150025, 35460150026, 35460150027, 35460150028 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic mg/kg 0.30 U 0.61 0.30 04/16/19 21:32 Lead mg/kg 0.30 U 0.61 0.30 04/16/19 21:32 LABORATORY CONTROL SAMPLE: 2872955 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic mg/kg 15.2 13.9 91 80-120 Lead mg/kg 15.2 15.5 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2872956 2872957 MS MSD 35460150023 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic mg/kg 20.4 17 17.4 38.4 39.2 106 109 75-125 2 20 Lead mg/kg 21.1 17 17.4 37.9 40.6 98 112 75-125 7 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 05/01/2019 03:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 38 of 49 aceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 530774 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 35460150021, 35460150022 METHOD BLANK: 2874754 Matrix: Solid Associated Lab Samples: 35460150021, 35460150022 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic mg/kg 0.29 U 0.58 Lead mg/kg 0.29 U 0.58 0.29 04/16/19 13:39 0.29 04/16/19 13:39 LABORATORY CONTROL SAMPLE: 2874755 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic mg/kg 14.9 12.7 85 80-120 Lead mg/kg 14.9 13.4 90 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2874756 2874757 MS MSD 35460005028 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic mg/kg 5.1 16.3 15.8 18.7 20.4 83 97 75-125 9 20 Lead mg/kg 1.8 16.3 15.8 16.4 16.3 90 92 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 05/01/2019 03:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 39 of 49 2ceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 533260 Analysis Method: EPA 6010 QC Batch Method: EPA 3010 Analysis Description: 6010 MET TCLP Associated Lab Samples: 35460150012 METHOD BLANK: 2886124 Matrix: Water Associated Lab Samples: 35460150012 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Lead mg/L 0.0046 U 0.010 0.0046 04/24/19 11:21 LABORATORY CONTROL SAMPLE: 2888756 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead mg/L 0.25 0.27 106 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2888757 2888758 MS MSD 35460150012 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Lead mg/L 0.17 2.5 2.5 2.8 2.8 104 104 75-125 0 20 Results presented on this page are in the units indicated by the "Units.' column except where an alternate unit is presented to the right of the result. Date: 05/01/2019 03:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 40 of 49 aceAnalytical® www.paceiabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 535143 Analysis Method: EPA 6010 QC Batch Method: EPA 3010 Analysis Description: 6010 MET TCLP Associated Lab Samples: 35460150019 METHOD BLANK: 2896335 Matrix Water Associated Lab Samples: 35460150019 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Lead mg/L 0.0046 U 0.010 0.0046 05/01/19 13:28 LABORATORY CONTROL SAMPLE: 2899056 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead mg/L 0.25 0.22 90 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2899059 2899060 MS MSD 35460150019 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual ead mg/L 0.50 2.5 2.5 2.8 2.9 94 94 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 05/01/2019 03:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 41 of 49 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 530247 QC Batch Method: ASTM D2974-87 Associated Lab Samples: 35460150001, 35460150008, 35460150015, 35460150022, Analysis Method: Analysis Description: ASTM D2974-87 Dry Weight/Percent Moisture 35460150002,35460150003,35460150004,35460150005,35460150006, 35460150009,35460150010,35460150011,35460150012,35460150013, 35460150016,35460150017,35460150018,35460150019,35460150020, 35460150023,35460150024,35460150025 35460150007, 35460150014, 35460150021, SAMPLE DUPLICATE: 2870820 Parameter Units 35460472004 Result Dup Result RPD Max RPD Qualifiers Percent Moisture Ok 26.6 30.8 15 10 J(D6) SAMPLE DUPLICATE: 2870821 Parameter Units 35460150010 Result Dup Result RPD Max RPD Qualifiers Percent Moisture 12.9 15 10 J(D6) SAMPLE DUPLICATE: 2870822 Parameter Units 35460150019 Result Dup Result RPD Max RPD Qualifiers Percent Moisture % 38.6 34.0 13 10 J(D6) SAMPLE DUPLICATE: 2870823 Parameter Units 35460150028 Result Dup Result RPD Max RPD Qualifiers Percent Moisture % 45.3 36.9 20 10 J(D6) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 05/01/2019 03:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 42 of 49 aceAnalytical www.pacelabs.com QUALIFIERS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. U Compound was analyzed for but not detected. J(D6) Estimated Value. The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. Date: 05/01/2019 03:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 43 of 49 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Lab ID Sample ID Analytical QC Batch Method QC Batch Analytical Method Batch 35460150001 SB-29 (0-0.5) EPA 3050 530316 EPA 6010 530435 35460150002 SB-29 (0.5-2) EPA 3050 530316 EPA 6010 530435 35460150003 SB-29 (2-4) EPA 3050 530316 EPA 6010 530435 35460150004 SB-30 (0-0.5) EPA 3050 530316 EPA 6010 530435 35460150005 SB-30 (0.5-2) EPA 3050 530316 EPA 6010 530435 35460150006 SB-30 (2-4) EPA 3050 530316 EPA 6010 530435 35460150007 SB-31 (0-0.5) EPA 3050 530316 EPA 6010 530435 35460150008 SB-31 (0.5-2) EPA 3050 530316 EPA 6010 530435 35460150009 SB-31 (2-4) EPA 3050 530316 EPA 6010 530435 35460150010 SB-31 (4-6) EPA 3050 530316 EPA 6010 530435 35460150011 SB-32 (0-0.5) EPA 3050 530316 EPA 6010 530435 35460150012 SB-32 (0.5-2) EPA 3050 530316 EPA 6010 530435 35460150013 SB-32 (2-4) EPA 3050 530316 EPA 6010 530435 35460150014 SB-33 (0-0.5) EPA 3050 530316 EPA 6010 530435 35460150015 SB-33 (0.5-2) EPA 3050 530316 EPA 6010 530435 35460150016 SB-33 (2-4) EPA 3050 530316 EPA 6010 530435 35460150017 SB-34 (0-0.5) EPA 3050 530316 EPA 6010 530435 35460150018 SB-34 (0.5-2) EPA 3050 530316 EPA 6010 530435 35460150019 SB-34 (2-4) EPA 3050 530316 EPA 6010 530435 35460150020 SB-35 (0-0.5) EPA 3050 530316 EPA 6010 530435 35460150021 SB-35 (0.5-2) EPA 3050 530774 EPA 6010 530802 35460150022 SB-35 (2-4) EPA 3050 530774 EPA 6010 530802 35460150023 SB-36 (0-0.5) EPA 3050 530540 EPA 6010 530701 35460150024 SB-36 (0.5-2) EPA 3050 530540 EPA 6010 530701 35460150025 SB-36 (2-4) EPA 3050 530540 EPA 6010 530701 35460150026 SB-37 (0-0.5) EPA 3050 530540 EPA 6010 530701 35460150027 SB-37 (0.5-2) EPA 3050 530540 EPA 6010 530701 35460150028 SB-37 (2-4) EPA 3050 530540 EPA 6010 530701 35460150012 SB-32 (0.5-2) EPA 3010 533260 EPA 6010 533292 35460150019 SB-34 (2-4) EPA 3010 535143 EPA 6010 35460150001 SB-29 (0-0.5) ASTM D2974-87 530247 35460150002 SB-29 (0.5-2) ASTM D2974-87 530247 35460150003 SB-29 (2-4) ASTM D2974-87 530247 35460150004 SB-30 (0-0.5) ASTM D2974-87 530247 35460150005 SB-30 (0.5-2) ASTM D2974-87 530247 35460150006 SB-30 (2-4) ASTM D2974-87 530247 35460150007 SB-31 (0-0.5) ASTM D2974-87 530247 35460150008 SB-31 (0.5-2) ASTM D2974-87 530247 35460150009 SB-31 (2-4) ASTM D2974-87 530247 35460150010 SB-31 (4-6) ASTM D2974-87 530247 35460150011 SB-32 (0-0.5) ASTM D2974-87 530247 35460150012 SB-32 (0.5-2) ASTM D2974-87 530247 35460150013 SB-32 (2-4) ASTM D2974-87 530247 35460150014 SB-33 (0-0.5) ASTM D2974-87 530247 35460150015 SB-33 (0.5-2) ASTM D2974-87 530247 35460150016 SB-33 (2-4) ASTM D2974-87 530247 Date: 05/01/2019 03:11 PM REPORT OF LABORATORY ANALYSIS 535160 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 44 of 49 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35460150 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Analytical Sample ID QC Batch Method QC Batch Analytical Method Batch 35460150017 SB-34 (0-0.5) ASTM D2974-87 530247 35460150018 SB-34 (0.5-2) ASTM D2974-87 530247 35460150019 SB-34 (2-4) ASTM D2974-87 530247 35460150020 SB-35 (0-0.5) ASTM D2974-87 530247 35460150021 SB-35 (0.5-2) ASTM D2974-87 530247 35460150022 SB-35 (2-4) ASTM D2974-87 530247 35460150023 SB-36 (0-0.5) ASTM D2974-87 530247 35460150024 SB-36 (0.5-2) ASTM D2974-87 530247 35460150025 SB-36 (2-4) ASTM D2974-87 530247 35460150026 SB-37 (0-0.5) ASTM D2974-87 530247 35460150027 SB-37 (0.5-2) ASTM D2974-87 530247 35460150028 SB-37 (2-4) ASTM D2974-87 530247 Date: 05/01/2019 03:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 45 of 49 rsB4E0N11 OF CUSTODY RECORDContainer Type Codes �� jj `�% • �D Analytical y# ' 35460150 Pace Pace / YI alyt ical www.pacelabs.comAG ote: Page 11 of 3 AV nether Vial Es Encore s:nnd v1 CV Mastic nl PPV Plnprn rvtienc,l P Plastic PLC Plastic rAnbnnw � AL Amber Ulm PL J Plastic JarCD CL poor Ulm Z Zlplac bog (d AP Amber Plastic Todlar d 1111 I II' 11111 I'll1l'll 35460150 W Whirlbng AmburGlnan WP pok SJ Soil Jar G Cullen Jug Other TC Tenav:oru PPV z,4ozo odvu �% 1 Company Name: (i "� r PQ# ( ,ALYSIS S Size(s) 2oz, 4oz. Enc. tgoz. 32oz or 11. other 40m1 500,nl 25(Iml 125 05 Example: 400P=4oz Plastic, flo0SJ= floc Soil Jar Address: 5/ kit 1�. ..,5 ��, ,.II u rI City: , ,--...: -,�;--S State: C.- zip: 3?Od� -I RC Matrix Codes `(I /� Attn: NtI.Gh,,..� Va-.... / �(kc3 J(G,l ey,q��" pH w eo�urwwmm OL stodge ( J J email: ,Ia ,� {�J�j C -o . 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Liquid OL Oil SL Sludge SO Soil Sediment AO Aqueous NA Nonuquoou:: PE Petroleum o Other Irene n{ _,IYI Preservative Type Codes A. None E. HCL I. Ice B. HNO3 F. McOH J. MCAA C. H2SO4 G. Na2S2O3 K. zn Acetala D. NaOH H. NaHSO4 O. Other Coolers #'s - Temp •C NorhConlorrnance Found? Samples INTACT up0r1 :naval? Rucmvud un Wul Ice? Proper Prosurvalwes Indicated? Hummed within holding lime? Custody sores Intact? Volatiies reed w,lhoul headepace? Proper Containers Used'r lU 0) to EL C.O.C. Serial # 1 PaceAnalytical www.pacelabs.com CHAN OF CUSTODY RECORD LAB W.O # Quote: Page, of,' j Company Name: EE--G-- PO# Address: 75/ /,,4L•a.,,>. L City: Attn: L,G.C. .--1 J email: Project Name Oro Samp er Signa ur 1 2 3 4 5 6 7 8 9 10 33-3 51537i "50141 t C C(e>_,lr Cif Phone: ,10 State: FL. Zip PT C1,)(5c. Proj # ;220p 305 -7 7 _ r ircle One Event: Daily Weekly Monthly • rtely Semi -Annual Annual N/A Sample ID Collect Collect Matrix Se, 5:,2) .,2-41) 57-21 „2--e-/) 5'g-3-76 -mil) Circle AlT. REWIEST (Rush Fen. Appr.,"m st.dw N ROSH Date Time Code' 1335 /337 )557 1y52 135P2 m u- LL LL 58 C 0 Sample TRC pH Pres Codes Parameters A n II u u u n u u II LAB ANALYSIS n n # of Containers SizelType u II n u II u n fI u n ozP Container Type Codes v AV Ambur Vial ES Encore Sampler O CV Clear Val PPV Pruprucarvud wall W P Plastic PL C Plastic container .4- AL Amber Laur PL J Plastic Jar 0) CL Clow. Lilco Z Anon bap tT AP Alnbor PInslic TB Todlnr bug (i AG Amber Glass WP Whirl pak a. SJ Sod Jar G Gallon Jug Other TC Tera•core PPV Propreservud vial Studs). 2oz. 4uz. 8oz. 16oz, 32ez or 1L, other _ 40m1 500m1 2500.1 125 ml Example: 4o.P = 4. Plastic, 8oaSJ= 8. Soil Jar Matrix Codes SD Solid W,:au GW Ground Wittig EFF Ellluom AFW Mobile Free N20 WW Waste Walor DW Dunking Walor SW Surface Water ML Misc. Lewd OL Oil SL Slung(' SO Sod Sediment AO Aqueous NA Nonnqueous PE Petroleum 0 Omer p+lee.e a MI Preservative Type Codes A. None E. HCL B. HNO3 F. McOH C. H2SO4 G. Na2S2O3 D. NaOH H. NaHSO4 1. Ice J. MCAA K. 2n Acetate O. Other REMARKS Today 1D 2D 3D 4D 5D Item z7.7is cJ)by 3 4 Short Hold N Pompano Lab 954-582-4300 Affiliation Circle QA/QC Report Level I 2 3 4 CLP AFCEE OAPP Other Time EDD (Fees May Apply) ADaPT SEDD ERPIMS TSV CSV Other Received by i fi Iation COC Condition OK Incompluer Date Required State Certification FL GA SC NC NJ PA LA TX IL Time /5O7 Revision: F•ALL•C•007- Rev.00 Coolers #'s - Temp eC 2 3 4 5 No Conformance Found? Samples INTACT uponur rv.d'I Received on Wet Ice? Proper Pronontaivos Indicated? Received 0.1150 holding 11ine? Custody seals Intact? VRI.rblus rood milieu! hmdspnco? Pallier Containers Usnd7 C.O.C. Serial # 1 5 9 .411.56,7/Cau e. 7-# : 35460150 19 Project pM: CTR Due Date. 04/16/ Project Manage CLIENT: 36-EE6 Client ,_ 7A/ 'ssmng .utnor y ace 1r,.; e Cooler #1 Temp.'C 9 (Visual) (Correction Factory./ (Actual) Cooler #2 Temp.'C (Visual) (Correction Factor) (Actual) = Date and Initials of person: Examining contents: Label: Deliver: pH: Cooler #3 Temp.'C Cooler p4 Temp.'C Cooler #5 Temp.'C Cooler #6 Temp.'C (Visual) (Correction Factor) (Actual) (Visual) (Correction Factor) (Actual) [Visual) (Correction Factor) (Actual) (Visual) (Correction Factor) (Actual) Courier: — Fe Ex — U S LISPS — Gen: — - r'a;; Shipping Method Billing: _ F_;.,e..,. _ Tracking u Custody Seal on Cooler/Box Present: Packing Material:—B:Dr;e .'- :.- i : iR ,t_;)e =a_s _'done Samples shorted to lab (If Yes. complete) S Date Seals intact: �e. —nt^er rnents: Sn.x.ned -,.,,e C' a!r- .- _ ..s:ody ores. Z'; e•s = Nr,• =i.•, ^" it c '..Sin iE7 ^-: No , RBI. .0 . _ ea S, o,._.. .re & Sampler Name C.es Lv�J'4fJ,y�s 7 No t.- Samples ::ve : ,:nt'-. r . � . me /es 1 No -w.-. R„sh - eo ested ......r._ =ves ^ ,cam _N. Z''es =No IN - ,:. _... .,; . hers Use^ ij"es __ No = . y_. .. ..- • ..--.._- --- yes Client Notification' Resolution' Comments: Resolution (use back for additional comments): Page 49 of 49 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 April 02, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35453908 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 13, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Kelsey Cortina. EE&G Environmental Solutions, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 42 vnmpacelabs.corn Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 CERTIFICATIONS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35453908 Ormond Beach Certification Ds 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 42 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35453908 Lab ID Sample ID Matrix Date Collected Date Received 35453908001 TE-4(2-4') Solid 03/12/19 11:20 03/13/19 18:15 35453908002 TE-1 (1-2') Solid 03/12/19 14:00 03/13/19 18:15 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 42 aceAnalytical Kww..pacelabs.co,m Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course Pace Project No.: 35453908 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35453908001 TE-4(2-4') 35453908002 TE-1 (1-2') FL -PRO RJR 3 PASI-O EPA6010 JWP, SC1 7 PASI-O EPA 6010 LEC 1 PASI-O EPA 7471 AMS 1 PASI-O EPA 8270 TWB 24 PASI-O ASTM D2974-87 CLT 1 PASI-O FL -PRO RJR 3 PASI-O EPA6010 SC1 7 PASI-O EPA6010 LEC 1 PASI-O EPA 7471 AMS 1 PASI-O EPA 8270 TWB 24 PASI-O EPA 8260 BCH 55 PASI-O ASTM D2974-87 CLT 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 42 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35453908 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35453908001 TE-4(2-4') FL -PRO Petroleum Range Organics 128 mg/kg 5.2 03/18/19 14:21 EPA 6010 Arsenic 3.8 mg/kg 0.71 03/18/19 20:55 EPA 6010 Barium 21.4 mg/kg 0.71 03/18/19 20:55 EPA 6010 Cadmium 0.89 mg/kg 0.071 03/18/19 20:55 EPA 6010 Chromium 8.1 mg/kg 0.36 03/18/19 20:55 EPA 6010 Lead 181 mg/kg 7.1 03/19/19 14:48 EPA 6010 Silver 0.73 mg/kg 0.36 03/18/19 20:55 EPA 7471 Mercury 0.31 mg/kg 0.012 03/18/19 21:22 EPA 8270 Benzo(a)anthracene 0.022 1 mg/kg 0.044 03/16/19 22:59 EPA 8270 Benzo(a)pyrene 0.018 1 mg/kg 0.044 03/16/19 22:59 EPA 8270 Benzo(b)fluoranthene 0.026 1 mg/kg 0.044 03/16/19 22:59 EPA 8270 Benzo(g,h,i)perylene 0.016 1 mg/kg 0.044 03/16/19 22:59 EPA 8270 Benzo(k)fluoranthene 0.012 1 mg/kg 0.044 03/16/19 22:59 EPA 8270 Chrysene 0.019 1 mg/kg 0.044 03/16/19 22:59 EPA 8270 Fluoranthene 0.027 I mg/kg 0.044 03/16/19 22:59 EPA 8270 Indeno(1,2,3-cd)pyrene 0.011 1 mg/kg 0.044 03/16/19 22:59 EPA 8270 Pyrene 0.026 1 mg/kg 0.044 03/16/19 22:59 ASTM D2974-87 Percent Moisture 23.1 % 0.10 03/14/19 12:07 35453908002 TE-1 (1-2') L-PRO Petroleum Range Organics 38.1 mg/kg 4.5 03/18/19 14:21 EPA 6010 Arsenic 14.3 mg/kg 0.69 03/18/19 21:04 EPA 6010 Barium 33.6 mg/kg 0.69 03/18/19 21:04 EPA 6010 Cadmium 0.61 mg/kg 0.069 03/18/19 21:04 EPA 6010 Chromium 21.8 mg/kg 0.34 03/18/19 21:04 EPA 6010 Lead 105 mg/kg 0.69 03/18/19 21:04 EPA 6010 Silver 0.89 mg/kg 0.34 03/18/19 21:04 EPA 7471 Mercury 0.093 mg/kg 0.0084 03/18/19 21:24 EPA 8260 Acetone 0.031 mg/kg 0.020 03/18/19 03:48 ASTM D2974-87 Percent Moisture 12.4 % 0.10 03/14/19 12:07 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 42 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No : 35453908 Sample: TE-4(2-4') Lab ID: 35453908001 Collected: 03/12/19 11:20 Received: 03/13/19 18:15 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual FL -PRO Soil Microwave Petroleum Range Organics Surrogates o-Terphenyl (S) N-Pentatriacontane (S) 6010 MET ICP Arsenic Barium Cadmium Chromium Lead Selenium Silver 6010 MET ICP, TCLP Lead 7471 Mercury Mercury 8270 MSSV Full List Microwave Acenaphthene Acenaphthylene Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene Chrysene Dibenz(a,h)anthracene Fluoranthene Fluorene Indeno(1,2,3-cd)pyrene 1-Methylnaphthalene 2-Methylnaphthalene Naphthalene Phenanthrene Pyrene Surrogates Nitrobenzene-d5 (S) 2-Fluorobiphenyl (S) p-Terphenyl-d14 (S) Phenol-d5 (S) Date: 04/02/2019 03:25 PM Analytical Method: FL -PRO Preparation Method: EPA 3546 128 mg/kg 5.2 3.3 1 03/15/19 00:54 03/18/19 14:21 89 90 66-136 1 03/15/19 00:54 03/18/19 14:21 84-15-1 42-159 1 03/15/19 00:54 03/18/19 14:21 630-07-09 Analytical Method: EPA 6010 Preparation Method: EPA 3050 3.8 21.4 0.89 8.1 181 0.53 U 0.73 mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg 0.71 0.71 0.071 0.36 7.1 1.1 0.36 0.36 0.36 0.036 0.18 3.6 0.53 0.18 1 03/14/19 16:59 1 03/14/19 16:59 1 03/14/19 16:59 1 03/14/19 16:59 10 03/14/19 16:59 1 03/14/19 16:59 1 03/14/19 16:59 03/18/19 20:55 7440-38-2 03/18/19 20:55 7440-39-3 03/18/19 20:55 7440-43-9 03/18/19 20:55 7440-47-3 03/19/19 14:48 7439-92-1 03/18/19 20:55 7782-49-2 03/18/19 20:55 7440-22-4 Analytical Method: EPA 6010 Preparation Method: EPA 3010 Leachate Method/Date: EPA 1311; 03/29/19 19:37 Initial pH: 5; Final pH: 6 0.046 U mg/L 0.10 0.046 1 03/30/19 14:43 03/31/1917:23 7439-92-1 Analytical Method: EPA 7471 Preparation Method 0.31 mg/kg 0.012 0.0059 Analytical Method: EPA 8270 Preparation Method 0.015 U 0.014 U 0.016 U 0.022 I 0.018 I 0.026 I 0.016 1 0.012 1 0.019 1 0.010 U 0.027 1 0.016 U 0.011 1 0.017 U 0.017 U 0.015 U 0.015 U 0.026 I 64 78 87 51 mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg Ok Ok ova ova 0.047 0.044 0.047 0.044 0.044 0.044 0.044 0.044 0.044 0.044 0.044 0.048 0.044 0.052 0.051 0.046 0.044 0.044 24-98 29-101 29-112 10-104 0.015 0.014 0.016 0.013 0.011 0.012 0.011 0.012 0.014 0.010 0.014 0.016 0.010 0.017 0.017 0.015 0.015 0.014 EPA 7471 1 03/18/19 18:42 03/18/19 21:22 7439-97-6 EPA 3546 03/15/19 07:33 03/15/19 07:33 03/15/19 07:33 03/15/19 07:33 03/15/19 07:33 03/15/19 07:33 03/15/19 07:33 03/15/19 07:33 03/15/19 07:33 03/15/19 07:33 03/15/19 07:33 03/15/19 07:33 03/15/19 07:33 03/15/19 07:33 03/15/19 07:33 03/15/19 07:33 03/15/19 07:33 03/15/19 07:33 03/16/19 22:59 83-32-9 03/16/19 22:59 208-96-8 03/16/19 22:59 120-12-7 03/16/19 22:59 56-55-3 03/16/19 22:59 50-32-8 03/16/19 22:59 205-99-2 03/16/19 22:59 191-24-2 03/16/19 22:59 207-08-9 03/16/19 22:59 218-01-9 03/16/19 22:59 53-70-3 03/16/19 22:59 206-44-0 03/16/19 22:59 86-73-7 03/16/19 22:59 193-39-5 03/16/19 22:59 90-12-0 03/16/19 22:59 91-57-6 03/16/19 22:59 91-20-3 03/16/19 22:59 85-01-8 03/16/19 22:59 129-00-0 03/15/19 07:33 03/16/19 22:59 4165-60-0 03/15/19 07:33 03/16/19 22:59 321-60-8 03/15/19 07:33 03/16/19 22:59 1718-51-0 03/15/19 07:33 03/16/19 22:59 4165-62-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 42 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35453908 Sample: TE-4(2-4') Lab ID: 35453908001 Collected: 03/12/19 11:20 Received: 03/13/19 18:15 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8270 MSSV Full List Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546 Surrogates 2-Fluorophenol (S) 49 % 19-95 1 03/15/19 07:33 03/16/19 22:59 367-12-4 2,4,6-Tribromophenol (S) 70 % 23-110 1 03/15/19 07:33 03/16/19 22:59 118-79-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 23.1 % 0.10 0.10 1 03/14/19 12:07 Date: 04/02/2019 03:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 42 www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35453908 Sample: TE-1 (1-2') Lab ID: 35453908002 Collected: 03/12/19 14:00 Received: 03/13/19 18:15 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual FL -PRO Soil Microwave Analytical Method: FL -PRO Preparation Method: EPA 3546 Petroleum Range Organics Surrogates o-Terphenyl(S) N-Pentatriacontane (S) 6010 MET ICP Arsenic Barium Cadmium Chromium Lead Selenium Silver 6010 MET ICP, TCLP Lead 7471 Mercury Mercury 8270 MSSV Full List Microwave Acenaphthene Acenaphthylene Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene Chrysene D i be nz(a, h)a nth ra ce ne Fluoranthene Fluorene Indeno(1,2,3-cd)pyrene 1-Methylnaphthalene 2-Methylnaphthalene Naphthalene Phenanthrene Pyrene Surrogates Nitrobenzene-d5 (S) 2-Fluorobiphenyl (S) p-Terphenyl-d14 (S) Phenol-d5 (S) Date: 04/02/2019 03:25 PM 38.1 mg/kg 98 110 Ok 4.5 2.9 1 03/15/19 00:54 03/18/19 14:21 66-136 42-159 1 03/15/19 00:54 1 03/15/19 00:54 Analytical Method: EPA 6010 Preparation Method: EPA 3050 14.3 33.6 0.61 21.8 105 0.51 U 0.89 mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg 0.69 0.69 0.069 0.34 0.69 1.0 0.34 0.34 0.34 0.034 0.17 0.34 0.51 0.17 Analytical Method: EPA 6010 Preparation Method: Leachate Method/Date: EPA 1311; 03/29/19 19:37 0.046 U mg/L 0.10 0.046 Analytical Method: EPA 7471 Preparation Method: 0.093 mg/kg 0.0084 0.0042 03/14/19 16:59 03/14/19 16:59 03/14/19 16:59 03/14/19 16:59 03/14/19 16:59 03/14/19 16:59 03/14/19 16:59 03/18/19 14:21 84-15-1 03/18/19 14:21 630-07-09 03/18/19 21:04 7440-38-2 03/18/19 21:04 7440-39-3 03/18/19 21:04 7440-43-9 03/18/19 21:04 7440-47-3 03/18/19 21:04 7439-92-1 03/18/19 21:04 7782-49-2 03/18/19 21:04 7440-22-4 EPA 3010 Initial pH: 5; Final pH: 6 1 03/30/19 14:43 03/31/19 17:35 7439-92-1 EPA 7471 1 03/18/19 18:42 03/18/19 21:24 7439-97-6 Analytical Method: EPA 8270 Preparation Method: EPA 3546 0.013 U mg/kg 0.042 0.013 1 03/15/19 07:33 03/16/19 23:51 83-32-9 0.012 U mg/kg 0.039 0.012 1 03/15/19 07:33 03/16/19 23:51 208-96-8 0.014 U mg/kg 0.042 0.014 1 03/15/19 07:33 03/16/19 23:51 120-12-7 0.011 U mg/kg 0.039 0.011 1 03/15/19 07:33 03/16/19 23:51 56-55-3 0.0097 U mg/kg 0.039 0.0097 1 03/15/19 07:33 03/16/19 23:51 50-32-8 0.010 U mg/kg 0.039 0.010 1 03/15/19 07:33 03/16/19 23:51 205-99-2 0.0098 U mg/kg 0.039 0.0098 1 03/15/19 07:33 03/16/19 23:51 191-24-2 0.010 U mg/kg 0.039 0.010 1 03/15/19 07:33 03/16/19 23:51 207-08-9 0.012 U mg/kg 0.039 0.012 1 03/15/19 07:33 03/16/19 23:51 218-01-9 0.0090 U mg/kg 0.039 0.0090 1 03/15/19 07:33 03/16/19 23:51 53-70-3 0.013 U mg/kg 0.039 0.013 1 03/15/19 07:33 03/16/19 23:51 206-44-0 0.014 U mg/kg 0.043 0.014 1 03/15/19 07:33 03/16/19 23:51 86-73-7 0.0089 U mg/kg 0.039 0.0089 1 03/15/19 07:33 03/16/19 23:51 193-39-5 0.015 U mg/kg 0.046 0.015 1 03/15/19 07:33 03/16/19 23:51 90-12-0 0.015 U mg/kg 0.045 0.015 1 03/15/19 07:33 03/16/19 23:51 91-57-6 0.013 U mg/kg 0.040 0.013 1 03/15/19 07:33 03/16/19 23:51 91-20-3 0.013 U mg/kg 0.039 0.013 1 03/15/19 07:33 03/16/19 23:51 85-01-8 0.012 U mg/kg 0.039 0.012 1 03/15/19 07:33 03/16/19 23:51 129-00-0 69 % 24-98 1 66 % 29-101 1 84 % 29-112 1 58 % 10-104 1 03/15/19 07:33 03/16/19 23:51 4165-60-0 03/15/19 07:33 03/16/19 23:51 321-60-8 03/15/19 07:33 03/16/19 23:51 1718-51-0 03/15/19 07:33 03/16/19 23:51 4165-62-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 42 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35453908 Sample: TE-1 (1-2') Lab ID: 35453908002 Collected: 03/12/19 14:00 Received: 03/13/19 18:15 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8270 MSSV Full List Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546 Surrogates 2-Fluorophenol (S) 54 % 19-95 1 03/15/19 07:33 03/16/19 23:51 367-12-4 2,4,6-Tribromophenol (S) 71 % 23-110 1 03/15/19 07:33 03/16/19 23:51 118-79-6 8260 MSV 5035 Analytical Method: EPA 8260 Preparation Method: EPA 5035 Acetone 0.031 mg/kg 0.020 0.010 1 03/16/19 20:39 03/18/19 03:48 67-64-1 Acetonitrile 0.026 U mg/kg 0.051 0.026 1 03/16/19 20:39 03/18/19 03:48 75-05-8 Benzene 0.0026 U mg/kg 0.0051 0.0026 1 03/16/19 20:39 03/18/19 03:48 71-43-2 Bromochloromethane 0.0026 U mg/kg 0.0051 0.0026 1 03/16/19 20:39 03/18/19 03:48 74-97-5 Bromodichloromethane 0.0026 U mg/kg 0.0051 0.0026 1 03/16/19 20:39 03/18/19 03:48 75-27-4 Bromoform 0.0026 U mg/kg 0.0051 0.0026 1 03/16/19 20:39 03/18/19 03:48 75-25-2 Bromomethane 0.0026 U mg/kg 0.0051 0.0026 1 03/16/19 20:39 03/18/19 03:48 74-83-9 2-Butanone (MEK) 0.0051 U mg/kg 0.010 0.0051 1 03/16/19 20:39 03/18/19 03:48 78-93-3 Carbon disulfide 0.0026 U mg/kg 0.0051 0.0026 1 03/16/19 20:39 03/18/19 03:48 75-15-0 Carbon tetrachloride 0.0026 U mg/kg 0.0051 0.0026 1 03/16/19 20:39 03/18/19 03:48 56-23-5 Chlorobenzene 0.0026 U mg/kg 0.0051 0.0026 1 03/16/19 20:39 03/18/19 03:48 108-90-7 Chloroethane 0.0037 U mg/kg 0.0051 0.0037 1 03/16/19 20:39 03/18/19 03:48 75-00-3 hloroform 0.0030 U mg/kg 0.0051 0.0030 1 03/16/19 20:39 03/18/19 03:48 67-66-3 Chloromethane 0.0029 U mg/kg 0.0051 0.0029 1 03/16/19 20:39 03/18/19 03:48 74-87-3 1,2-Dibromo-3-chloropropane 0.0026 U mg/kg 0.0051 0.0026 1 03/16/19 20:39 03/18/19 03:48 96-12-8 Dibromochloromethane 0.0026 U mg/kg 0.0051 0.0026 1 03/16/19 20:39 03/18/19 03:48 124-48-1 1,2-Dibromoethane (EDB) 0.0026 U mg/kg 0.0051 0.0026 1 03/16/19 20:39 03/18/19 03:48 106-93-4 Dibromomethane 0.0026 U mg/kg 0.0051 0.0026 1 03/16/19 20:39 03/18/19 03:48 74-95-3 1,2-Dichlorobenzene 0.0026 U mg/kg 0.0051 0.0026 1 03/16/19 20:39 03/18/19 03:48 95-50-1 1,4-Dichlorobenzene 0.0026 U mg/kg 0.0051 0.0026 1 03/16/19 20:39 03/18/19 03:48 106-46-7 trans-1,4-Dichloro-2-butene 0.0026 U mg/kg 0.0051 0.0026 1 03/16/19 20:39 03/18/19 03:48 110-57-6 1,1-Dichloroethane 0.0028 U mg/kg 0.0051 0.0028 1 03/16/19 20:39 03/18/19 03:48 75-34-3 1,2-Dichloroethane 0.0026 U mg/kg 0.0051 0.0026 1 03/16/19 20:39 03/18/19 03:48 107-06-2 1,2-Dichloroethene (Total) 0.0031 U mg/kg 0.0051 0.0031 1 03/16/19 20:39 03/18/19 03:48 540-59-0 1,1-Dichloroethene 0.0026 U mg/kg 0.0051 0.0026 1 03/16/19 20:39 03/18/19 03:48 75-35-4 cis-1,2-Dichloroethene 0.0026 U mg/kg 0.0051 0.0026 1 03/16/19 20:39 03/18/19 03:48 156-59-2 trans-1,2-Dichloroethene 0.0031 U mg/kg 0.0051 0.0031 1 03/16/19 20:39 03/18/19 03:48 156-60-5 1,2-Dichloropropane 0.0026 U mg/kg 0.0051 0.0026 1 03/16/19 20:39 03/18/19 03:48 78-87-5 cis-1,3-Dichloropropene 0.0026 U mg/kg 0.0051 0.0026 1 03/16/19 20:39 03/18/19 03:48 10061-01-5 trans-1,3-Dichloropropene 0.0026 U mg/kg 0.0051 0.0026 1 03/16/19 20:39 03/18/19 03:48 10061-02-6 Ethylbenzene 0.0029 U mg/kg 0.0051 0.0029 1 03/16/19 20:39 03/18/19 03:48 100-41-4 2-Hexanone 0.0051 U mg/kg 0.010 0.0051 1 03/16/19 20:39 03/18/19 03:48 591-78-6 lodomethane 0.0051 U mg/kg 0.010 0.0051 1 03/16/19 20:39 03/18/19 03:48 74-88-4 Isopropylbenzene (Cumene) 0.0030 U mg/kg 0.0051 0.0030 1 03/16/19 20:39 03/18/19 03:48 98-82-8 Methylene Chloride 0.0026 U mg/kg 0.0051 0.0026 1 03/16/19 20:39 03/18/19 03:48 75-09-2 4-Methyl-2-pentanone (MIBK) 0.0051 U mg/kg 0.010 0.0051 1 03/16/19 20:39 03/18/19 03:48 108-10-1 Methyl-tert-butyl ether 0.0026 U mg/kg 0.0051 0.0026 1 03/16/19 20:39 03/18/19 03:48 1634-04-4 Styrene 0.0026 U mg/kg 0.0051 0.0026 1 03/16/19 20:39 03/18/19 03:48 100-42-5 1,1,1,2-Tetrachloroethane 0.0026 U mg/kg 0.0051 0.0026 1 03/16/19 20:39 03/18/19 03:48 630-20-6 1,1,2,2-Tetrachloroethane 0.0026 U mg/kg 0.0051 0.0026 1 03/16/19 20:39 03/18/19 03:48 79-34-5 Date: 04/02/2019 03:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 42 ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35453908 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: TE-1 (1-2') Lab ID: 35453908002 Collected: 03/12/19 14:00 Received: 03/13/19 18:15 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8260 MSV 5035 Analytical Method: EPA 8260 Preparation Method: EPA 5035 Tetrachloroethene 0.0026 U mg/kg 0.0051 0.0026 1 03/16/19 20:39 03/18/19 03:48 127-18-4 Toluene 0.0028 U mg/kg 0.0051 0.0028 1 03/16/19 20:39 03/18/19 03:48 108-88-3 1,1,1-Trichloroethane 0.0028 U mg/kg 0.0051 0.0028 1 03/16/19 20:39 03/18/19 03:48 71-55-6 1,1,2-Trichloroethane 0.0026 U mg/kg 0.0051 0.0026 1 03/16/19 20:39 03/18/19 03:48 79-00-5 Trichloroethene 0.0029 U mg/kg 0.0051 0.0029 1 03/16/19 20:39 03/18/19 03:48 79-01-6 Trichlorofluoromethane 0.0028 U mg/kg 0.0051 0.0028 1 03/16/19 20:39 03/18/19 03:48 75-69-4 1,2,3-Trichloropropane 0.0026 U mg/kg 0.0051 0.0026 1 03/16/19 20:39 03/18/19 03:48 96-18-4 Vinyl acetate 0.0026 U mg/kg 0.0051 0.0026 1 03/16/19 20:39 03/18/19 03:48 108-05-4 Vinyl chloride 0.0028 U mg/kg 0.0051 0.0028 1 03/16/19 20:39 03/18/19 03:48 75-01-4 Xylene (Total) 0.0053 U mg/kg 0.015 0.0053 1 03/16/19 20:39 03/18/19 03:48 1330-20-7 m&p-Xylene 0.0053 U mg/kg 0.010 0.0053 1 03/16/19 20:39 03/18/19 03:48 179601-23-1 o-Xylene 0.0026 U mg/kg 0.0051 0.0026 1 03/16/19 20:39 03/18/19 03:48 95-47-6 Surrogates 4-Bromofluorobenzene (S) 102 % 68-125 1 03/16/19 20:39 03/18/19 03:48 460-00-4 1,2-Dichloroethane-d4 (S) 102 % 71-132 1 03/16/19 20:39 03/18/19 03:48 17060-07-0 Toluene-d8 (S) 97 % 70-130 1 03/16/19 20:39 03/18/19 03:48 2037-26-5 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 04/02/2019 03:25 PM 12.4 % 0.10 0.10 1 03/14/19 12:07 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 42 aceAnalytical wvwpacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35453908 QC Batch: 523899 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 35453908001, 35453908002 METHOD BLANK: 2831595 Matrix: Solid Associated Lab Samples: 35453908001, 35453908002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury mg/kg 0.0037 U 0.0074 0.0037 03/18/19 21:03 LABORATORY CONTROL SAMPLE: 2831596 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg 0.076 0.078 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2831597 2831598 MS MSD 35451691001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual lercury mg/kg 0.013 U 0.25 0.27 0.25 0.25 101 92 80-120 2 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/02/2019 03:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 42 www.pacelabs.corn Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35453908 QC Batch: 523148 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 35453908001, 35453908002 METHOD BLANK: 2826496 Matrix: Solid Associated Lab Samples: 35453908001, 35453908002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic mg/kg 0.28 U 0.57 0.28 03/18/19 20:29 Barium mg/kg 0.28 U 0.57 0.28 03/18/19 20:29 Cadmium mg/kg 0.028 U 0.057 0.028 03/18/19 20:29 Chromium mg/kg 0.14 U 0.28 0.14 03/18/19 20:29 Lead mg/kg 0.28 U 0.57 0.28 03/18/19 20:29 Selenium mg/kg 0.42 U 0.85 0.42 03/18/19 20:29 Silver mg/kg 0.14 U 0.28 0.14 03/18/19 20:29 LABORATORY CONTROL SAMPLE: 2826497 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers Arsenic mg/kg 12.2 12.0 98 80-120 Barium mg/kg 12.2 12.1 99 80-120 Cadmium mg/kg 1.2 1.2 102 80-120 Chromium mg/kg 12.2 12.6 103 80-120 Lead mg/kg 12.2 12.6 103 80-120 Selenium mg/kg 12.2 11.2 92 80-120 Silver mg/kg 1.2 1.1 92 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2826498 2826499 MS MSD 35453525015 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic mg/kg 0.25 U 16.9 14.8 14.5 12.8 85 86 75-125 13 20 Barium mg/kg 5.4 16.9 14.8 21.8 20.3 97 101 75-125 7 20 Cadmium mg/kg 0.025 U 1.7 1.4 1.6 1.5 97 100 75-125 10 20 Chromium mg/kg 1.8 16.9 14.8 19.3 17.7 103 107 75-125 8 20 Lead mg/kg 92.8 16.9 14.8 101 86.5 51 -43 75-125 16 20 J(M1) Selenium mg/kg 0.37 U 16.9 14.8 14.2 12.9 84 87 75-125 10 20 Silver mg/kg 0.12 U 1.7 1.4 1.5 1.3 87 88 75-125 11 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/02/2019 03:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 42 wwwpacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35453908 QC Batch: 527287 Analysis Method: EPA 6010 QC Batch Method: EPA 3010 Analysis Description: 6010 MET TCLP Associated Lab Samples: 35453908001, 35453908002 METHOD BLANK: 2851541 Matrix: Water Associated Lab Samples: 35453908001, 35453908002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Lead mg/L 0.0046 U 0.010 0.0046 03/31/19 17:17 LABORATORY CONTROL SAMPLE: 2853804 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead mg/L 0.25 0.25 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2853805 2853806 MS MSD 35453908001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual ead mg/L 0.046 U 2.5 2.5 2.5 2.6 101 102 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/02/2019 03:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 42 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35453908 QC Batch: 523673 Analysis Method: EPA 8260 QC Batch Method: EPA 5035 Analysis Description: 8260 MSV 5035 Associated Lab Samples: 35453908002 METHOD BLANK: 2830761 Matrix: Solid Associated Lab Samples: 35453908002 Parameter Blank Reporting Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane mg/kg 0.0025 U 0.0050 0.0025 03/17/19 21:11 1,1,1-Trichloroethane mg/kg 0.0028 U 0.0050 0.0028 03/17/19 21:11 1,1,2,2-Tetrachloroethane mg/kg 0.0025 U 0.0050 0.0025 03/17/19 21:11 1,1,2-Trichloroethane mg/kg 0.0025 U 0.0050 0.0025 03/17/19 21:11 1,1-Dichloroethane mg/kg 0.0027 U 0.0050 0.0027 03/17/19 21:11 1,1-Dichloroethene mg/kg 0.0025 U 0.0050 0.0025 03/17/19 21:11 1,2,3-Trichloropropane mg/kg 0.0025 U 0.0050 0.0025 03/17/19 21:11 1,2-Dibromo-3-chloropropane mg/kg 0.0025 U 0.0050 0.0025 03/17/19 21:11 1,2-Dibromoethane (EDB) mg/kg 0.0025 U 0.0050 0.0025 03/17/19 21:11 1,2-Dichlorobenzene mg/kg 0.0025 U 0.0050 0.0025 03/17/19 21:11 1,2-Dichloroethane mg/kg 0.0025 U 0.0050 0.0025 03/17/1921:11 1,2-Dichloroethene (Total) mg/kg 0.0031 U 0.0050 0.0031 03/17/19 21:11 1,2-Dichloropropane mg/kg 0.0025 U 0.0050 0.0025 03/17/1921:11 1,4-Dichlorobenzene mg/kg 0.0025 U 0.0050 0.0025 03/17/1921:11 2-Butanone (MEK) mg/kg 0.0050 U 0.010 0.0050 03/17/19 21:11 2-Hexanone mg/kg 0.0050 U 0.010 0.0050 03/17/19 21:11 4-Methyl-2-pentanone (MIBK) mg/kg 0.0050 U 0.010 0.0050 03/17/19 21:11 Acetone mg/kg 0.010 U 0.020 0.010 03/17/19 21:11 Acetonitrile mg/kg 0.025 U 0.050 0.025 03/17/19 21:11 Benzene mg/kg 0.0026 U 0.0050 0.0026 03/17/19 21:11 Bromochloromethane mg/kg 0.0025 U 0.0050 0.0025 03/17/19 21:11 Bromodichloromethane mg/kg 0.0025 U 0.0050 0.0025 03/17/19 21:11 Bromoform mg/kg 0.0025 U 0.0050 0.0025 03/17/19 21:11 Bromomethane mg/kg 0.0025 U 0.0050 0.0025 03/17/19 21:11 Carbon disulfide mg/kg 0.0025 U 0.0050 0.0025 03/17/19 21:11 Carbon tetrachloride mg/kg 0.0025 U 0.0050 0.0025 03/17/19 21:11 Chlorobenzene mg/kg 0.0025 U 0.0050 0.0025 03/17/19 21:11 Chloroethane mg/kg 0.0036 U 0.0050 0.0036 03/17/19 21:11 Chloroform mg/kg 0.0030 U 0.0050 0.0030 03/17/19 21:11 Chloromethane mg/kg 0.0028 U 0.0050 0.0028 03/17/19 21:11 cis-1,2-Dichloroethene mg/kg 0.0025 U 0.0050 0.0025 03/17/19 21:11 cis-1,3-Dichloropropene mg/kg 0.0025 U 0.0050 0.0025 03/17/19 21:11 Dibromochloromethane mg/kg 0.0025 U 0.0050 0.0025 03/17/19 21:11 Dibromomethane mg/kg 0.0025 U 0.0050 0.0025 03/17/19 21:11 Ethylbenzene mg/kg 0.0028 U 0.0050 0.0028 03/17/19 21:11 lodomethane mg/kg 0.0050 U 0.010 0.0050 03/17/19 21:11 Isopropylbenzene (Cumene) mg/kg 0.0029 U 0.0050 0.0029 03/17/19 21:11 m&p-Xylene mg/kg 0.0052 U 0.010 0.0052 03/17/19 21:11 Methyl-tert-butyl ether mg/kg 0.0025 U 0.0050 0.0025 03/17/19 21:11 Methylene Chloride mg/kg 0.0025 U 0.0050 0.0025 03/17/19 21:11 o-Xylene mg/kg 0.0026 U 0.0050 0.0026 03/17/19 21:11 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/02/2019 03:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 42 wvswpacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35453908 METHOD BLANK: 2830761 Matrix: Solid Associated Lab Samples: 35453908002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Styrene mg/kg 0.0025 U 0.0050 0.0025 03/17/19 21:11 Tetrachloroethene mg/kg 0.0025 U 0.0050 0.0025 03/17/19 21:11 Toluene mg/kg 0.0027 U 0.0050 0.0027 03/17/19 21:11 trans-1,2-Dichloroethene mg/kg 0.0031 U 0.0050 0.0031 03/17/19 21:11 trans-1,3-Dichloropropene mg/kg 0.0025 U 0.0050 0.0025 03/17/19 21:11 trans-1,4-Dichloro-2-butene mg/kg 0.0025 U 0.0050 0.0025 03/17/19 21:11 Trichloroethene mg/kg 0.0028 U 0.0050 0.0028 03/17/19 21:11 Trichlorofluoromethane mg/kg 0.0027 U 0.0050 0.0027 03/17/19 21:11 Vinyl acetate mg/kg 0.0025 U 0.0050 0.0025 03/17/19 21:11 Vinyl chloride mg/kg 0.0027 U 0.0050 0.0027 03/17/19 21:11 Xylene (Total) mg/kg 0.0052 U 0.015 0.0052 03/17/19 21:11 1,2-Dichloroethane-d4 (S) % 92 71-132 03/17/19 21:11 4-Bromofluorobenzene (S) % 96 68-125 03/17/19 21:11 Toluene-d8 (S) % 99 70-130 03/17/19 21:11 LABORATORY CONTROL SAMPLE: 2830762 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane mg/kg 0.02 0.021 104 70-130 1,1,1-Trichloroethane mg/kg 0.02 0.022 110 70-130 1,1,2,2-Tetrachloroethane mg/kg 0.02 0.020 99 70-130 1,1,2-Trichloroethane mg/kg 0.02 0.020 102 70-130 1,1-Dichloroethane mg/kg 0.02 0.022 109 70-130 1,1-Dichloroethene mg/kg 0.02 0.023 116 62-131 1,2,3-Trichloropropane mg/kg 0.02 0.020 100 72-137 1,2-Dibromo-3-chloropropane mg/kg 0.02 0.021 104 65-132 1,2-Dibromoethane (EDB) mg/kg 0.02 0.020 103 70-130 1,2-Dichlorobenzene mg/kg 0.02 0.019 98 70-130 1,2-Dichloroethane mg/kg 0.02 0.021 104 70-130 1,2-Dichloroethene (Total) mg/kg 0.04 0.043 108 70-130 1,2-Dichloropropane mg/kg 0.02 0.020 102 70-130 1,4-Dichlorobenzene mg/kg 0.02 0.019 97 70-130 2-Butanone (MEK) mg/kg 0.04 0.035 88 64-121 2-Hexanone mg/kg 0.04 0.039 97 59-137 4-Methyl-2-pentanone (MIBK) mg/kg 0.04 0.039 98 70-130 Acetone mg/kg 0.04 0.035 87 68-146 Acetonitrile mg/kg 0.2 0.17 88 68-131 Benzene mg/kg 0.02 0.022 109 70-130 Bromochloromethane mg/kg 0.02 0.022 113 70-130 Bromodichloromethane mg/kg 0.02 0.020 102 70-130 Bromoform mg/kg 0.02 0.017 87 54-129 Bromomethane mg/kg 0.02 0.022 112 58-144 Carbon disulfide mg/kg 0.02 0.018 93 57-133 Carbon tetrachloride mg/kg 0.02 0.022 112 63-137 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/02/2019 03:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 42 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35453908 LABORATORY CONTROL SAMPLE: 2830762 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers Chlorobenzene mg/kg 0.02 0.020 100 70-130 Chloroethane mg/kg 0.02 0.018 93 40-165 Chloroform mg/kg 0.02 0.021 107 70-130 Chloromethane mg/kg 0.02 0.017 83 64-127 cis-1,2-Dichloroethene mg/kg 0.02 0.021 106 70-130 cis-1,3-Dichloropropene mg/kg 0.02 0.021 105 70-130 Dibromochloromethane mg/kg 0.02 0.021 107 70-130 Dibromomethane mg/kg 0.02 0.021 108 70-130 Ethylbenzene mg/kg 0.02 0.020 100 70-130 lodomethane mg/kg 0.04 0.035 88 58-137 lsopropylbenzene (Cumene) mg/kg 0.02 0.020 99 70-130 m&p-Xylene mg/kg 0.04 0.039 97 70-130 Methyl-tert-butyl ether mg/kg 0.02 0.019 98 65-124 Methylene Chloride mg/kg 0.02 0.017 88 51-142 o-Xylene mg/kg 0.02 0.019 96 70-130 Styrene mg/kg 0.02 0.020 100 70-130 Tetrachloroethene mg/kg 0.02 0.023 117 70-130 Toluene mg/kg 0.02 0.020 103 70-130 trans-1,2-Dichloroethene mg/kg 0.02 0.022 110 70-130 trans-1,3-Dichloropropene mg/kg 0.02 0.021 106 70-130 trans-1,4-Dichloro-2-butene mg/kg 0.02 0.020 102 65-142 Trichloroethene mg/kg 0.02 0.022 110 70-130 Trichlorofluoromethane mg/kg 0.02 0.019 96 60-148 Vinyl acetate mg/kg 0.02 0.020 102 70-130 Vinyl chloride mg/kg 0.02 0.016 80 69-124 Xylene (Total) mg/kg 0.06 0.058 97 70-130 1,2-Dichloroethane-d4 (S) % 99 71-132 4-Bromofluorobenzene (S) % 100 68-125 Toluene-d8 (S) % 98 70-130 MATRIX SPIKE SAMPLE: 2832269 Parameter 35453517002 Spike MS MS % Rec Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane mg/kg 0.0024 U 0.024 0.025 105 70-130 1,1,1-Trichloroethane mg/kg 0.0026 U 0.024 0.026 111 70-130 1,1,2,2-Tetrachloroethane mg/kg 0.0024 U 0.024 0.026 109 70-130 1,1,2-Trichloroethane mg/kg 0.0024 U 0.024 0.026 109 70-130 1,1-Dichloroethane mg/kg 0.0026 U 0.024 0.027 112 70-130 1,1-Dichloroethene mg/kg 0.0024 U 0.024 0.022 94 62-131 1,2,3-Trichloropropane mg/kg 0.0024 U 0.024 0.025 106 72-137 1,2-Dibromo-3-chloropropane mg/kg 0.0024 U 0.024 0.025 104 65-132 1,2-Dibromoethane (EDB) mg/kg 0.0024 U 0.024 0.025 108 70-130 1,2-Dichlorobenzene mg/kg 0.0024 U 0.024 0.022 94 70-130 1,2-Dichloroethane mg/kg 0.0024 U 0.024 0.023 96 70-130 1,2-Dichloroethene (Total) mg/kg 0.0029 U 0.048 0.052 111 70-130 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/02/2019 03:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 42 n www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35453908 MATRIX SPIKE SAMPLE: Parameter 2832269 35453517002 Spike MS MS % Rec Units Result Conc. Result % Rec Limits Qualifiers 1,2-Dichloropropane mg/kg 0.0024 U 0.024 0.025 106 70-130 1,4-Dichlorobenzene mg/kg 0.0024 U 0.024 0.022 91 70-130 2-Butanone (MEK) mg/kg 0.0048 U 0.048 0.047 93 64-121 J 2-Hexanone mg/kg 0.0048 U 0.048 0.051 108 59-137 J 4-Methyl-2-pentanone (MIBK) mg/kg 0.0048 U 0.048 0.053 113 70-130 Acetone mg/kg 0.021 0.048 0.070 103 68-146 Acetonitrile mg/kg 0.024 U 0.24 0.24 100 68-131 J Benzene mg/kg 0.0025 U 0.024 0.027 114 70-130 Bromochloromethane mg/kg 0.0024 U 0.024 0.028 118 70-130 Bromodichloromethane mg/kg 0.0024 U 0.024 0.024 101 70-130 Bromoform mg/kg 0.0024 U 0.024 0.020 87 54-129 Bromomethane mg/kg 0.0024 U 0.024 0.023 97 58-144 Carbon disulfide mg/kg 0.0024 U 0.024 0.020 85 57-133 Carbon tetrachloride mg/kg 0.0024 U 0.024 0.027 115 63-137 Chlorobenzene mg/kg 0.0024 U 0.024 0.024 100 70-130 J Chloroethane mg/kg 0.0035 U 0.024 0.017 72 40-165 Chloroform mg/kg 0.0029 U 0.024 0.025 105 70-130 Chloromethane mg/kg 0.0027 U 0.024 0.024 103 64-127 cis-1,2-Dichloroethene mg/kg 0.0024 U 0.024 0.026 109 70-130 'is-1,3-Dichloropropene mg/kg 0.0024 U 0.024 0.025 104 70-130 )iromochloromethane mg/kg 0.0024 U 0.024 0.026 110 70-130 Dibromomethane mg/kg 0.0024 U 0.024 0.028 117 70-130 Ethylbenzene mg/kg 0.0027 U 0.024 0.023 96 70-130 lodomethane mg/kg 0.0048 U 0.048 0.041 88 58-137 J Isopropylbenzene (Cumene) mg/kg 0.0028 U 0.024 0.023 97 70-130 m&p-Xylene mg/kg 0.0050 U 0.048 0.046 93 70-130 Methyl-tert-butyl ether mg/kg 0.0024 U 0.024 0.024 103 65-124 Methylene Chloride mg/kg 0.0024 U 0.024 0.023 98 51-142 o-Xylene mg/kg 0.0025 U 0.024 0.023 95 70-130 Styrene mg/kg 0.0024 U 0.024 0.023 97 70-130 Tetrachloroethene mg/kg 0.0024 U 0.024 0.029 124 70-130 Toluene mg/kg 0.0026 U 0.024 0.026 110 70-130 trans-1,2-Dichloroethene mg/kg 0.0029 U 0.024 0.027 113 70-130 trans-1,3-Dichloropropene mg/kg 0.0024 U 0.024 0.025 106 70-130 trans-1,4-Dichloro-2-butene mg/kg 0.0024 U 0.024 0.025 106 65-142 Trichloroethene mg/kg 0.0027 U 0.024 0.027 114 70-130 Trichlorofluoromethane mg/kg 0.0026 U 0.024 0.020 84 60-148 Vinyl acetate mg/kg 0.0024 U 0.024 0.020 84 70-130 Vinyl chloride mg/kg 0.0026 U 0.024 0.019 81 69-124 Xylene (Total) mg/kg 0.0050 U 0.07 0.068 97 70-130 1,2-Dichloroethane-d4 (S) % 88 71-132 4-Bromofluorobenzene (S) % 101 68-125 Toluene-d8 (S) % 98 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/02/2019 03:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 42 aceAnalytical wwwpacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35453908 SAMPLE DUPLICATE: 2832268 35453517001 Dup Max Parameter Units Result Result RPD RPD Qualifiers 1,1,1,2-Tetrachloroethane mg/kg 0.0029 U 0.0032 U 40 1,1,1-Trichloroethane mg/kg 0.0032 U 0.0035 U 40 1,1,2,2-Tetrachloroethane mg/kg 0.0029 U 0.0032 U 40 1,1,2-Trichloroethane mg/kg 0.0029 U 0.0032 U 40 1,1-Dichloroethane mg/kg 0.0032 U 0.0035 U 40 1,1-Dichloroethene mg/kg 0.0029 U 0.0032 U 40 1,2,3-Trichloropropane mg/kg 0.0029 U 0.0032 U 40 1,2-Dibromo-3-chloropropane mg/kg 0.0029 U 0.0032 U 40 1,2-Dibromoethane (EDB) mg/kg 0.0029 U 0.0032 U 40 1,2-Dichlorobenzene mg/kg 0.0029 U 0.0032 U 40 1.2-Dichloroethane mg/kg 0.0029 U 0.0032 U 40 1,2-Dichloroethene (Total) mg/kg 0.0036 U 0.0039 U 40 1,2-Dichloropropane mg/kg 0.0029 U 0.0032 U 40 1,4-Dichlorobenzene mg/kg 0.0029 U 0.0032 U 40 2-Butanone (MEK) mg/kg 0.0059 U 0.0064 U 40 J 2-Hexanone mg/kg 0.0059 U 0.0064 U 40 J 4-Methyl-2-pentanone (MIBK) mg/kg 0.0059 U 0.0064 U 40 Acetone mg/kg 0.049 0.026 60 40 J(D6) Acetonitrile mg/kg 0.029 U 0.032 U 40 J Benzene mg/kg 0.0030 U 0.0033 U 40 Bromochloromethane mg/kg 0.0029 U 0.0032 U 40 Bromodichloromethane mg/kg 0.0029 U 0.0032 U 40 Bromoform mg/kg 0.0029 U 0.0032 U 40 Bromomethane mg/kg 0.0029 U 0.0032 U 40 Carbon disulfide mg/kg 0.0029 U 0.0032 U 40 Carbon tetrachloride mg/kg 0.0029 U 0.0032 U 40 Chlorobenzene mg/kg 0.0029 U 0.0032 U 40 J Chloroethane mg/kg 0.0042 U 0.0046 U 40 Chloroform mg/kg 0.0035 U 0.0038 U 40 Chloromethane mg/kg 0.0033 U 0.0036 U 40 cis-1,2-Dichloroethene mg/kg 0.0029 U 0.0032 U 40 cis-1,3-Dichloropropene mg/kg 0.0029 U 0.0032 U 40 Dibromochloromethane mg/kg 0.0029 U 0.0032 U 40 Dibromomethane mg/kg 0.0029 U 0.0032 U 40 Ethylbenzene mg/kg 0.0033 U 0.0036 U 40 lodomethane mg/kg 0.0059 U 0.0064 U 40 J Isopropylbenzene (Cumene) mg/kg 0.0034 U 0.0037 U 40 m&p-Xylene mg/kg 0.0060 U 0.0065 U 40 Methyl-tert-butyl ether mg/kg 0.0029 U 0.0032 U 40 Methylene Chloride mg/kg 0.0029 U 0.0032 U 40 o-Xylene mg/kg 0.0030 U 0.0033 U 40 Styrene mg/kg 0.0029 U 0.0032 U 40 Tetrachloroethene mg/kg 0.0029 U 0.0032 U 40 Toluene mg/kg 0.0032 U 0.0034 U 40 trans-1,2-Dichloroethene mg/kg 0.0036 U 0.0039 U 40 trans-1,3-Dichloropropene mg/kg 0.0029 U 0.0032 U 40 trans-1,4-Dichloro-2-butene mg/kg 0.0029 U 0.0032 U 40 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/02/2019 03:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 42 wvw ..pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35453908 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 SAMPLE DUPLICATE: 2832268 Parameter 35453517001 Dup Max Units Result Result RPD RPD Qualifiers Trichloroethene mg/kg 0.0033 U 0.0036 U 40 Trichlorofluoromethane mg/kg 0.0032 U 0.0035 U 40 Vinyl acetate mg/kg 0.0030 U 0.0032 U 40 Vinyl chloride mg/kg 0.0031 U 0.0034 U 40 Xylene (Total) mg/kg 0.0060 U 0.0065 U 40 1,2-Dichloroethane-d4 (S) % 97 95 6 40 4-Bromofluorobenzene (S) % 103 100 6 40 Toluene-d8 (S) % 98 99 10 40 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/02/2019 03:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 42 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35453908 QC Batch: 523276 Analysis Method: EPA 8270 QC Batch Method: EPA3546 Analysis Description: 8270 Solid Full List MSSV Microwave Associated Lab Samples: 35453908001, 35453908002 METHOD BLANK: 2827834 Matrix: Solid Associated Lab Samples: 35453908001, 35453908002 Parameter Blank Reporting Units Result Limit MDL Analyzed Qualifiers 1-Methylnaphthalene mg/kg 0.013 U 0.040 0.013 03/16/19 23:25 2-Methylnaphthalene mg/kg 0.013 U 0.039 0.013 03/16/19 23:25 Acenaphthene mg/kg 0.012 U 0.036 0.012 03/16/19 23:25 Acenaphthylene mg/kg 0.011 U 0.034 0.011 03/16/19 23:25 Anthracene mg/kg 0.012 U 0.036 0.012 03/16/19 23:25 Benzo(a)anthracene mg/kg 0.0097 U 0.034 0.0097 03/16/19 23:25 Benzo(a)pyrene mg/kg 0.0084 U 0.034 0.0084 03/16/19 23:25 Benzo(b)fluoranthene mg/kg 0.0090 U 0.034 0.0090 03/16/19 23:25 Benzo(g,h,i)perylene mg/kg 0.0085 U 0.034 0.0085 03/16/19 23:25 Benzo(k)fluoranthene mg/kg 0.0091 U 0.034 0.0091 03/16/19 23:25 Chrysene mg/kg 0.011 U 0.034 0.011 03/16/19 23:25 Dibenz(a,h)anthracene mg/kg 0.0078 U 0.034 0.0078 03/16/19 23:25 Fluoranthene mg/kg 0.011 U 0.034 0.011 03/16/19 23:25 Fluorene mg/kg 0.012 U 0.037 0.012 03/16/19 23:25 Indeno(1,2,3-cd)pyrene mg/kg 0.0078 U 0.034 0.0078 03/16/19 23:25 Naphthalene mg/kg 0.012 U 0.035 0.012 03/16/19 23:25 Phenanthrene mg/kg 0.011 U 0.034 0.011 03/16/19 23:25 Pyrene mg/kg 0.011 U 0.034 0.011 03/16/19 23:25 2,4,6-Tribromophenol (S) % 60 23-110 03/16/19 23:25 2-Fluorobiphenyl (S) % 67 29-101 03/16/19 23:25 2-Fluorophenol (S) % 56 19-95 03/16/19 23:25 Nitrobenzene-d5 (S) % 63 24-98 03/16/19 23:25 p-Terphenyl-d14 (S) % 83 29-112 03/16/19 23:25 Phenol-d5 (S) % 59 10-104 03/16/19 23:25 LABORATORY CONTROL SAMPLE: 2827835 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1-Methylnaphthalene mg/kg 1.6 1.2 73 38-115 2-Methylnaphthalene mg/kg 1.6 1.2 72 37-115 Acenaphthene mg/kg 1.6 1.1 69 30-127 Acenaphthylene mg/kg 1.6 1.2 73 29-129 Anthracene mg/kg 1.6 1.2 72 37-126 Benzo(a)anthracene mg/kg 1.6 1.3 79 37-130 Benzo(a)pyrene mg/kg 1.6 1.2 73 39-128 Benzo(b)fluoranthene mg/kg 1.6 1.2 73 38-128 Benzo(g,h,i)perylene mg/kg 1.6 1.2 74 34-136 Benzo(k)fluoranthene mg/kg 1.6 1.2 71 39-133 Chrysene mg/kg 1.6 1.3 78 39-125 Dibenz(a,h)anthracene mg/kg 1.6 1.2 74 37-127 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/02/2019 03:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 42 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35453908 LABORATORY CONTROL SAMPLE: 2827835 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Fluoranthene mg/kg 1.6 1.3 76 39-130 Fluorene mg/kg 1.6 1.1 66 35-125 Indeno(1,2,3-cd)pyrene mg/kg 1.6 1.2 74 35-133 Naphthalene mg/kg 1.6 1.2 71 36-115 Phenanthrene mg/kg 1.6 1.1 70 35-128 Pyrene mg/kg 1.6 1.3 77 37-132 2,4,6-Tribromophenol (S) % 68 23-110 2-Fluorobiphenyl (S) % 70 29-101 2-Fluorophenol (S) % 60 19-95 Nitrobenzene-d5 (S) % 67 24-98 p-Terphenyl-d14 (S) % 85 29-112 Phenol-d5 (S) % 65 10-104 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2827836 2827837 MS MSD 35453908001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1-Methylnaphthalene mg/kg 0.017 U 2.2 2.2 1.4 1.4 63 66 38-115 6 40 -Methylnaphthalene mg/kg 0.017 U 2.2 2.2 1.3 1.4 62 65 37-115 5 40 .Acenaphthene mg/kg 0.015 U 2.2 2.2 1.3 1.4 62 63 30-127 2 40 Acenaphthylene mg/kg 0.014 U 2.2 2.2 1.5 1.4 71 65 29-129 9 40 Anthracene mg/kg 0.016 U 2.2 2.2 1.4 1.5 64 68 37-126 6 40 Benzo(a)anthracene mg/kg 0.022 I 2.2 2.2 1.5 1.6 70 74 37-130 6 40 Benzo(a)pyrene mg/kg 0.018 I 2.2 2.2 1.4 1.5 65 69 39-128 6 40 Benzo(b)fluoranthene mg/kg 0.026 I 2.2 2.2 1.4 1.5 66 69 38-128 5 40 Benzo(g,h,i)perylene mg/kg 0.016 1 2.2 2.2 1.4 1.5 65 70 34-136 7 40 Benzo(k)fluoranthene mg/kg 0.012 1 2.2 2.2 1.4 1.5 64 67 39-133 6 40 Chrysene mg/kg 0.019 1 2.2 2.2 1.5 1.7 69 75 39-125 9 40 Dibenz(a,h)anthracene mg/kg 0.010 U 2.2 2.2 1.4 1.5 66 71 37-127 7 40 Fluoranthene mg/kg 0.027 1 2.2 2.2 1.5 1.6 67 73 39-130 8 40 Fluorene mg/kg 0.016 U 2.2 2.2 1.4 1.4 65 66 35-125 2 40 Indeno(1,2,3-cd)pyrene mg/kg 0.011 1 2.2 2.2 1.4 1.5 66 70 35-133 6 40 Naphthalene mg/kg 0.015 U 2.2 2.2 1.3 1.4 61 63 36-115 4 40 Phenanthrene mg/kg 0.015 U 2.2 2.2 1.4 1.5 62 68 35-128 9 40 Pyrene mg/kg 0.026 1 2.2 2.2 1.5 1.6 67 71 37-132 6 40 2,4,6-Tribromophenol (S) % 65 69 23-110 2-Fluorobiphenyl (S) % 72 73 29-101 2-Fluorophenol (S) % 45 47 19-95 Nitrobenzene-d5 (S) % 58 59 24-98 p-Terphenyl-d14 (S) % 76 82 29-112 Phenol-d5 (S) % 49 51 10-104 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/02/2019 03:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 21 of 42 aceAnalytical www..pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35453908 QC Batch: 523278 Analysis Method: FL -PRO QC Batch Method: EPA 3546 Analysis Description: FL -PRO Soil Associated Lab Samples: 35453908001, 35453908002 METHOD BLANK: 2827843 Matrix: Solid Associated Lab Samples: 35453908001, 35453908002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Petroleum Range Organics mg/kg 2.6 U 4.0 2.6 03/18/19 13:19 N-Pentatriacontane (S) % 96 42-159 03/18/19 13:19 o-Terphenyl (S) % 97 66-136 03/18/19 13:19 LABORATORY CONTROL SAMPLE: 2827844 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Petroleum Range Organics mg/kg 196 188 96 65-119 N-Pentatriacontane (S) % 103 42-159 o-Terphenyl (S) % 97 66-136 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2827845 2827846 MS MSD 35454014001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Petroleum Range Organics mg/kg 10.4 U 801 779 742 704 92 90 39-181 5 25 N-Pentatriacontane (S) % 111 105 42-159 o-Terphenyl (S) % 106 105 66-136 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/02/2019 03:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 22 of 42 aceAnalytical ww,wpace!abs. corn Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35453908 QC Batch: 523088 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 35453908001, 35453908002 SAMPLE DUPLICATE: 2826275 35453861001 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture Oh 17.9 19.0 6 10 SAMPLE DUPLICATE: 2826276 35453682001 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture 4.7 4.8 2 10 SAMPLE DUPLICATE: 2826277 35453579001 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture % 79.6 80.5 1 10 AMPLE DUPLICATE: 2826278 35453906002 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture Ok 37.6 35.2 7 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/02/2019 03:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 42 -PaceAnalytical wwwpacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALIFIERS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35453908 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. U Compound was analyzed for but not detected. J The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have a low bias. J The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. J(D6) Estimated Value. The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. J(M1) Estimated Value. Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. Date: 04/02/2019 03:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 24 of 42 /eAnaIyticaI www.pacelabs.com Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melreese Golf Course Pace Project No.: 35453908 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 35453908001 TE-4(2-4') EPA 3546 523278 FL -PRO 523753 35453908002 TE-1 (1-2') EPA 3546 523278 FL -PRO 523753 35453908001 TE-4(2-4') EPA 3050 523148 EPA 6010 523268 35453908002 TE-1 (1-2') EPA 3050 523148 EPA 6010 523268 35453908001 TE-4(2-4') EPA 3010 527287 EPA 6010 527323 35453908002 TE-1 (1-2') EPA 3010 527287 EPA 6010 527323 35453908001 TE-4(2-4') EPA 7471 523899 EPA 7471 524028 35453908002 TE-1 (1-2') EPA 7471 523899 EPA 7471 524028 35453908001 TE-4(2-4') EPA 3546 523276 EPA 8270 523663 35453908002 TE-1 (1-2') EPA 3546 523276 EPA 8270 523663 35453908002 TE-1 (1-2') EPA 5035 523673 EPA 8260 523676 35453908001 TE-4(2-4') ASTM D2974-87 523088 35453908002 TE-1 (1-2') ASTM D2974-87 523088 Date: 04/02/2019 03:25 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 25 of 42 CHAIN OF CUSTODY RECORD Container Type Codes fdi !] [(` WO# 1111111111111 • 35453908 _AB W.O # Quote: Page Of I I I II I I III AV Ambnr Vial ES Encore Sampler CV Clnnr Vial PPV Propreserved vial P Pmber PLC Plastic container AL Amber Liter PL J Plastic Jar CL Z Liptac bag Ambnr Plastic TB Todlor bag 3S4Ei3!308 9 r Gl Amber AG AmbnGlnss WP Whirl pak SJ Soil JrG Gallon Jug Other TC Tnne-corn PPV Prepreeervnd vial �..✓ /'� Company Name: CC•'�l"r PO# LAB ANALYSIS Slzo(s): 2oz, 4oz, 8oz, 16oz, 32nz or 1L. other 40m1 500m1 250m1 125 mt Example: 4ozPa4ozPlastic. eozSJe8ozSoil Jar Address: �t5 ( ;tI, 11, 1 � L , ) - jl'- Sample City: /"4 Lem-, L V , State: Zip: fj ' ( TRC Matrix Codes Attn: L C`!‘ vl �iJ, . /' c .{ } ( ,L, q Fa3C �� 1 �• b fj='F+� pH SD Solid Wncin OL Oil Ow Ground weer SL Sludge _ email: m1%2,-) ty tzle.Cr-4-Y? i J\ /( ' 7 yJ—� f� C<'MPhone: ;`5-3,- L V• Pres Codes EFF AnollEffluent SO Soil Sediment AFW Analyle Free H2O AO Aqueous wW Waste Wally NA Nonnqunow r Project (. Name re,e'X� l 'I2 J _ _ Ce^J: k,proj # _.": L' /� �,.3C'J 7 i -4: EXAMPLE Diss. Lead 6010 OW peeking Water PE Petroleum SW Surface Water 0 Other ML MSc. Liquid 1P1aess spaotyl -- Samp er ,, - / 1 ,/ ()Circle Signa ure%,.' Z. '`,;„ /�. One Event: Daily Weekly Monthly 1 Quartely Semi -Annual Annual N/A N E --r ---5- �. \, Preservative Type Codes a Sample ID Collect Date Collect Time Matrix Code" it It rz x c p 13 c 5 $ cis a `y ^ `-- ,,�'1 ` - - f A. None E. HCL I. Ice B. HNO3 F. McOH J. MCAA C. H2SO4 G. Na2S2O3 K. an Acetate D. NaOH H. NaHSO4 O. Other E# of Containers Size/Typo 4-16ozP 1 1 I REMARKS 1-;'c 1/ a --a 51/ i� >j.?c s� n 1❑ 1 I n 217 - I ! — ` ,-li, Ii9 /ic/j c CG P C [ ' g (0-,1 1 P1 1 I LI 3 n ❑ n II II II II II II 4 ❑ n u n I I 1 ❑ 1 1 U I I 5 ❑❑ LJ I I ❑ 1-11 1 L❑ 6 II n II II 11 II II LI LJ 7 n ❑ ❑ LJ II ❑ ❑ 8 n ❑ ❑ l I I I 1 I ❑ n o n 9 n L Li I n 1 1 LI ■ ■ I I 10 LI 11 I I LJ 1 1 LJ I I I I 11 0 cin T.A.T REQUEST Munn Fans App..) EDD (Fees May Apply) COC Condition Required State Certification Coolers #'s - Temp °C "'"(NM Ruen Short Hold Circle QA/QC Report Level �'� N Tably ID 2D 30 4D ID - y N - 1 2 3 4 CLP AFCEE QAPP Other ADaPT SEDD ERPIMS TSV CSV Other OK Incomtxele FL GA SC NC NJ PA LA TX IL '%'2 3_ 4 5 Item R uis ed'by / Affiliation Dat Time Received by Aff i on Date Time 1 %�'. 77 � ��' C •�//Y/y' n /%/` 3/"�' 1 {!,` / `-" : ' 1 { .� ( r / )/�{•�y+��11jt � / �' J Non-ConlINTACT Found'7 Samples INTACT upon arrival? / '� C 1 L _; _- - J�l -7 /( /�6..' 777 Gi,� C i ✓ L� 1 ' J Rnudved nn Wol Im7i Propar Pmsnrvallvn:: Indlunndi RecMVnd wahtn boldin Ile•, Custody elude Intnele -'•/�'� , . ;1713117i ( cod .n7 %�� J—.— •� 7 ,( / I J 1 y ' -- i ( ( ; `` i . - fGj '.+ _ I .1 7 ; / Volnalos rued without huadspncni Proper Containers Used? ab 954-5SZ- 0 N Revision: F•ALL•C•007- Rev.00 C.O.C. Serial # vL_'-r Document Name: Sample Condition Upon Receipt Form e Analytical Document No.: F-FL-C-007 rev. 13 6�10!�_ 3`�453905 Project ti PSI : C TF_ Project Manager CLIENT: 36-EE0 Client: -> „ Thermometer Used: I ') State of Origin: Cooler#1 Temp.°C c i (Visual) 4C) • Cooler#2 Temp.°C (Visual) Cooler#3 Temp.°C (Visual) Cooler #4 Temp.°C (Visual) Cooler #5 Temp.°C (Visual) Cooler #6 Temp.°C (Visual) Date: • cei•t Form(SqUR) Due Date: 03/19/19 111 (Correction Factor) (Correction Factor) (Correction Factor) (Correction Factor) (Correction Factor) (Correction Factor) Document Revised: May 30, 2018 Issuing Authority: Pace Florida Quality Office Date and Initials of person: Examining contents: Label: , Deliver: /:, i'� 1' pH: Time: 0 j 1 (4) Initials For WV` projects, all containers verified to <_6 °C LI r •—S (Actual) (Actual) (Actual) (Actual) (Actual) (Actual) Courier: ❑ Fed Ex ❑ UPS ❑ USPS ❑ Client P Commercial ❑ Pace Shipping Method: ❑ First Overnight ❑ Priority Overnight ❑ Standard Ovemight ❑ Ground ❑ Other Billing: ❑ Recipient Tracking # ❑ Sender ❑ Third Party ❑ Credit Card Custody Seal on Cooler/Box Present: ❑Yes �No Seals intact: ❑ Yes ❑ No Packing Material: ❑Bubble Wrap cBubble Bags ❑None ❑Other Samples shorted to lab (If Yes, complete) Shorted Date: • ❑ Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun ❑ Other El International Priority El Unknown Ice: Shorted Time: Blue Dry None Qty: Chain of Custody Present AfYes ❑ No ❑N/A „� Chain of Custody Filled Out ffYes 0 No ❑N/A Relinquished Signature & Sampler Name COC s6Yes 0 No ❑N/A Samples Arrived within Hold Time ,DYes 0 No ❑N/A Rush TAT requested on COC DYes 0/No ❑N/A Sufficient Volume riYes ❑ No ❑N/A Correct Containers Used /SYes 0 No ❑N/A Containers Intact ,DYes 0 No ❑N/A Sample Labels match COC (sample IDs & date/time of collection) ZfYes 0 No ❑N/A All containers needing acid/base preservation have been checked. DYes All Containers needingpreservation are found to be in compliance with EPA recommendation: ❑Yes Exceptions: VOA, Coliform, TOC, O&G, Carbamates 0 No l❑NiA ❑ No G_fN/A Preservation Information: Preservative: Lot #/Trace #: Date: Time: Initials: Headspace in VOA Vials? (>6mm): ❑Yes / ❑ No tI2N/A Trip Blank Present: ❑Yes 0 No ,CN/A ehent Notification/ Resolution: Person Contacted: Comments/ Resolution (use back for additional comments): Date/Time: Project Manager Review: Date: Pje 27 of 42 TM ace Analytical www.pacelabs.com www.pacelabs.com Report Prepared for: Christina Raschke PASI Florida 8 East Tower Circle Ormond Beach FL 32174 REPORT OF LABORATORY ANALYSIS FOR PCDD/PCDF Report Prepared Date: March 25, 2019 Report No 104672158290FC_DFR Pace Analytical Services, LLC. 1700 Elm Street Minneapolis, MN 55414 Phone: 612.607.1700 Fax: 612.607.6444 Report Information: Pace Project #: 10467215 Sample Receipt Date: 03/15/2019 Client Project #: 35453908 Client Sub PO #: N/A State Cert #: E87605 Invoicing & Reporting Options: The report provided has been invoiced as a Level 2 PCDD/PCDF Report. If an upgrade of this report package is requested, an additional charge may be applied. Please review the attached invoice for accuracy and forward any questions to Kirsten Hogberg, your Pace Project Manager. This report has been reviewed by: March 26, 2019 Nathan Boberg, Project Manager 612-360-0728 (612) 607-6444 (fax) nathan.boberg@pacelabs.com Report of Laboratory Analysis Thisreportshouldnotbereproduced,except infull, withoutthewrittenconsentofPaceAnalyticalServices,l nc. Theresultsrelateonlyt othesamplesincludedinthisreport. Page 28 of 42 Page 1 of 15 ace Analytical Pace Analytical Services, LLC. 1700 Elm Street Minneapolis, MN 55414 Phone: 612.607.1700 Fax: 612.607.6444 DISCUSSION This report presents the results from the analyses performed on two samples submitted by a representative of Pace Analytical Services, LLC. The samples were analyzed for the presence or absence of polychlorodibenzo-p-dioxins (PCDDs) and polychlorodibenzofurans (PCDFs) using a modified version of USEPA Method 8290. The reporting limits were based on signal-to-noise measurements. Estimated Maximum Possible Concentration (EMPC) values were treated as positives in the toxic equivalence calculations. Per request, estimated detection limit (EDL) values were provided and flagged "U" where the target analytes were not detected. Second column confirmation analyses of 2,3,7,8-TCDF values obtained from the primary (DB5-MS) column are performed only when specifically requested for a project and only when the values are above the concentration of the lowest calibration standard. Typical resolution for this isomer using the DB5-MS column ranges from 25-30%. The recoveries of the isotopically -labeled PCDD/PCDF internal standards in the sample extracts ranged from 46-89%. All of the labeled internal standard recoveries obtained for this project were within the 40-135% target range specified in Method 8290. Also, since the quantification of the native 2,3,7,8-substituted congeners was based on isotope dilution, the data were automatically corrected for recovery and accurate values were obtained. Values were flagged "I" where incorrect isotope ratios were obtained. Concentrations below the calibration range were flagged "J" and should be regarded as estimates. A laboratory method blank was prepared and analyzed with the sample batch as part of our routine quality control procedures. The results show that PCDDs and PCDFs were not detected. These results indicate that the sample preparation procedures did not significantly impact the results of the field sample determinations. A laboratory spike sample was also prepared with the sample batch using reference material that had been fortified with native standards. The recoveries of the spiked native compounds ranged from 103-121%. These results were within the target ranges for the method. Matrix spikes were prepared with the sample batch using sample material from a separate project; results from these analyses will be provided upon request. REPORT OF LABORATORYANALYSIS This report shall not be reproduced, except in full, withoutthe written consent of Pace Analytical Services, Inc. Page 29 of 42 Report No 10467215_8290FC_DFR Page 2 of 15 Authority Tl,1 Minnesota Laboratory Certifications Certificate # Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax:612-607-6444 Authority Certificate # A2LA 2926.01 Alabama 40770 Alaska - DW MN00064 Alaska - UST 17-009 Arizona AZ0014 Arkansas - DW MN00064 Arkansas - WW 88-0680 CNMI Saipan MP0003 California 2929 Colorado MN00064 Connecticut PH-0256 EPA Region 8+ via MN 027-053 Florida (NELAP E87605 Georgia 959 Guam 17-001 r Hawaii MN00064 Idaho MN00064 Illinois 200011 Indiana C-MN-01 Iowa 368 Kansas E-10167 Kentucky - DW 90062 Kentucky - WW 90062 Louisiana - DE 03086 Louisiana - DW MN00064 Maine MN00064 Maryland 322 Massachusetts M-MN064 Michigan 9909 Minnesota 027-053-137 Minnesota - De via MN 027-053 Minnesota - Pet 1240 Mississippi MN00064 Missouri - DW 10100 Montana CERT0092 Nebraska NE-OS-18-06 Nevada MN00064 New Hampshire 2081 New Jersey (NE MN002 New York 11647 North Carolina 27700 North Carolina - 27700 North Carolina - 530 North Dakota R-036 Ohio - DW 41244 Ohio - VAP CL101 Oklahoma 9507 Oregon - Primar MN300001 Oregon - Secon MN200001 Pennsylvania 68-00563 Puerto Rico MN00064 South Carolina 74003 South Dakota NA Tennessee TN02818 Texas T104704192 Utah (NELAP) MN00064 Virginia 460163 Washington C486 West Virginia - 382 West Virginia - 9952C Wisconsin 999407970 Wyoming - UST 2926.01 REPORT OF LABORATORYANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10467215_8290FC_DFR Report No 10467215 Page 30 of 42 Page 3 of 15 Appendix A Sample Management Report No 10467215 8290FC de Analytical Services, Inc. Page 31 of 42 Page 4 of 15 Ida Od06Z8 91-Z2.91701- oN pode Chain of Custody Samples were sent directly to the Subcontracting Laboratory. Workorder: 35453908 Christina Raschke Pace Analytical South Florida 3610 Park Central Blvd N Pompano Beach, FL 33064 Phone (954)582-4300 2 3 4 5 TE-4(2- 4') TE-1 (1-21 Transfers 2 Released By Workorder Name: Meireese Gold Course WPace PS PS Pace Analytical Minnesota 1700 Elm Street SE Suite 200 Minneapolis, MN 55414 Phone (612)607-1700 3/12/2019 11:20 35453908001 3/12/2019 14:00 Daterrime 35453908002 .3=i'1'(yta. Received By State Of Origin: FL Cert. Needed: Yes Owner Received Date: Date/Time /is ft� cto-r--) 3 No WO#:10467215 ?IIII III II IIIIIII IIII 3/13/2019 Results Requested By: 3/19/2019 LAB USE ONLY Cooler Temperature on Receipt D • 1 °C I Custody Seal Y or 1N J Received on Ice or N Samples Inta ***In order to maintain client confidentiality, location/name of the sampling site, sampler's name and signature may not be provided on this COC docum�rlt This chain of custody is considered complete as is since this information is available in the owner laboratory. CO m 01 niursday, March 14, 2019 2:54:18 PM c_ N or N FMT-ALL-C-002rev.00 24March2009 Page 1 of 1 Cooler PI T :'C--_(Vis it)ry 'i Cooler S2Temp.'C ( s:Sal) Cooler #3 Temp:'C (Visual) Cooler#4 Temp'C (Visual) Cooler #5 Temp.+C (Visual) Cooler SS Temp,'C (Visual) Courier:: 0 Shipping Method: Billing: Tracking* Documentmune: Sample. Condition Upon Receipt Form DocumentNo.: F-FL-C-007 rev.13 art_ara: -; Project • ' +�► PM C'FFt Project Manager maw, 38.e itt Client: Thermometer Used; _T <1- � I ccel )t Fort i (SCUR) is Date 03/18t19 UoountentRevIseri: May30, 2016 Issuing Aulhott y; PaceFloodsQuality Office Date and initials of person: Examining contents: Label: DeliVerr PH: L' Date: 3' 1 y tc Time: 03 1 (Cr Initials: State at Ortgin C} For tNVprojects, ell containers verified tooe.°C emp. ua[) • (Correction Factor) r (Aolual); (Correction Factor} ._(Actual) (Correction Factor) (Actual) (Cop/ectlon-Factor) (Actual) (Correction Factor) (Actual): (Correctldn Feletor` /Actual); Fed EX ❑ UPS ❑ USPS ° Client.ommerclat 0 Pace 0 First Oyer► ipht. 0 Priority Overnight: 0 Standard Overnight D. Qib ind O flitter' 0 Recipient 0 Sender 0 Third Party 0 Credit:Card Q .Samples O On ice;:ogling process has begun ❑. Samples on:loe; t4otlniiprooitas has begun Q Sarrotes on ice, cooling:process has begun ❑ Samples on ice, cooling process has begun ❑ 3ampiesan ice;,eooling proceae has begun ❑ SanipieaOnIca cooling promo has begun. Daher t 1 intemallenat Prjiriiy t3 Unknown Custody Seal an Coofer/Box Present: Des 021Go Seale ntactt:0 Yea 0 No Packing Material: OBubble Wrap Itratible Bags ONone ❑Other Samples shorted to tab (if Yes, complete) Shorted Date: ice: Shorted Time: Blue Dry None fay _ - - Chain of Custody Present PI (es 0 No ON/A vv,mgat. wp Chain of Custody: Filled Qut ,L0Yes No ON/A Relinquished .Signature &Sampler Name--CoC "151JYesO°No' ON/A Samples Arrived within Hold Time ,tea in No ON/A Rush TAT requested on COC OYes 2610 DN/A Sufficient Volume ci"Y�es 0 No ON/A CorrectContainers Used 4es E No ON/A Containers Intact dYea 0 No ON/A y Sample Labels match COO (aampielOa & date/lime of collection) mee 0 No ON/A: All containers needingsdd/base preservation heve 0een Checked tales CI NoON/A All Containers needing preaervalton are found to be In compliance with EPA recommendation: Dyes 0 No O A F aeptions: VOA, Conform. TOG: Odra; Carbametes Preservation Information: Pres ; i at#!i race fF irece Darn: lima; Initials: // Headspace In VOA Vials? (>8mm): OYes 0 No I,2NA Trip Blank Present: °Yea 0 No. A. Went HotttlCattonl Resolution: Person Contacted: Comments/ Resolution (use back for additional comments): DateITRme: Project Manager Review: Report No 104672158290FC_DFR Date; Page 33 of 42 Page 6 of 15 _,r°""^ `! aeeAnalyical` Document Name: Sample Condition Upon Receipt Form Document Revised: o6Feb2019 Page 1 of 1 Document No.: F-MN-L-213-rev.25 Issuing Authority: Pace Minnesota Quality Office Sample Condition Upon Receipt Courier: Client Name: 4 (c A Project##: WO# :10467215 Fed Ex ❑UPS ❑LISPS [Client ['Pace ❑SpeeDee ['Commercial see Exception Tracking Number: - ; -TZ *30•$l CCcCJ ij ❑ PM: KNH Due Date: 03/22/19 CLIENT: PASI-FL Custody Seal on Cooler/Box Present? ['Yes to Seals Intact? ❑Yes/�Jo Biological Tissue Frozen? ['Yes❑No [i J/A Packing Material: nubble Wrap Bubble Bags None O9ther: 6'V Temp Blank? rNs ❑No Thermometer: 0G87A9155100842 7A917060D254 Type of ice: 1 Wet ❑Blue ❑None EDry ❑Melted Note: Each West Virginia Sample must have temp taken (no temp blanks) Temp should be above freezing to 6"C Cooler Temp Read w/temp blank: 0 • oC Correction Factor:"tl • L Cooler Temp Corrected w/temp blank : 0 , 4;S oC Average Corrected Temp See Exceptions (no temp blank only): ❑ DC USDA Regulated Soil: (❑ N/A, water sample/Other: ) Date/Initials of Person Examining Contents: Q' d 3 5 // Did samples originate in a quarantine zone within the United States: AL, AR, CA, L, A Did samples originate from a foreign source (internationally, including ID, LA. MS, NC, NM, NY, OK, OR, SC, TN, TX or VA (check maps)? 15* to Hawaii and Puerto Rico)? Dyes LLdtslo if Yes to either question, fill out a Regulated Soil Checklist (F-MN-Q-338) and include with SCUR/COC paperwork. COMMENTS: Chain of Custody Present and Filled Out? TaYes ❑No 1. Chain of Custody Relinquished? gives ❑No 2. Sampler Name and/or Signature on COC? ❑Yes ❑No WSJ/A 3. Samples Arrived within Hold Time? 51Yes ❑No 14. Short Hold Time Analysis (<72 hr)? ❑Yes E) No 5. ['Fecal Coliform OHPC ❑Total Coliform/E coli ❑BOD/cBOD ❑Hex Chrome ❑Turbidity ['Nitrate ❑NItrite ❑Orthophos ['other Rush Turn Around Time Requested? tgYes ❑No 6. Sufficient Volume? ?}Yes No 7. Correct Containers Used? -Pace Containers Used? NYes Yes ❑No ❑No 8. Containers Intact? Yes ❑No 9. Field Filtered Volume Received for Dissolved Tests? Elves ❑No EtdN/A 10. Is sediment visible in the dissolved container? I)•Yes II No Is sufficient information available to reconcile the samples to the COC? Matrix: ❑Water [ Gpil Dal [(Other tkes ❑No 11. If no, write ID/ Date/Time on Container Beiow: See Exception • All containers needing acid/base preservation have been checked? All containers needing preservation are found to be in compliance with EPA recommendation? (HNO3, H504, <2pH, NaOH >9 Sulfide, NaOH>12 Cyanide) Exceptions: VOA, Coliform, TOC/DOC Oil and Grease, DRO/8015 (water) and Dioxin/PFAS ['Yes ❑Yes ales ❑No ❑No ❑No [RN/A E /A [) N/A 12. Sample if ❑ NaOH ❑ HNO3 ■ H2SO4 •Zinc Acetate Positive for Res. II Yes See Exception Chlorine? III No • Headspace in VOA Vials (greater than 6mm)? 0Yes ❑No ®N/A 13. see Exception IN Trip Blank Present? Trip Blank Custody Seals Present? DYes ❑Yes ❑No ❑No RN/A EN/A 14. Pace Trip Blank Lot # (if purchased): Ni lQr CLIENT NOTIFICATION/RESOLUTION Person Contacted: Comments/Resolution: Samples require Method 8290. Date/Time: Field Data Required? ❑Yes No Project Manager Review r n //i Note: Whenever there is a discrepancy zffect ng rfYc7 th Carolina cplianc samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( Le out of holo, incorrect preservative, out of temp, incorrect containers). Date: 3/19/2019 R,Port No 10467215_8290FC_DFR Labeledby: Page 34 of 42 Page 7 of 15 ,0 ` .. aceAnaiyticai.. Document Name: Regulated Soil Checklist Document Revised: 13Feb2018 Page 1 of 2 Doc x m e nt No . F-MN-Q-338-Rev.06 Issuing Authority: Pace Minnesota Quality Office To Be Completed by SR Staff: WO: Sample Origin (circle one): USDA REGULATED SOIL CHECKLIST Date: QUARANTINED Initials: 675D\ FOREIGN (Note: soil samples from Hawaii, .. •• - - . Rico and the US Virgin !stands are considered to be of a Foreign Source) If Domestic, circle State of Origin: (includes: IFA, 50D, Golden Nematode, Kornai Bunt and Witchweed) AL AR CA l FL iGA LA MS NC NM NY OK OR SC TN TX VA List County: (USDA Permit/Compliance Agreement authorizes movement of samples from these domestic regulated zones) If Quarantined, circle State of Origin: FL ID TX CA List County: (Includes Fruit Fly, Giant African Snail and Pale Cyst Nematode) (Movement is not authorized for Pale Cyst Nematode (ID or Giant African snail (FL], remaining quarantines require additional paperwork) If Foreign, list Country of Origin: (Movement from some Canadian Providences is not allowed. Refer to CS-232 Regulated Soil Flow Chart) REQUIREMENT ACTION COMPLETED PPQ-530 Paperwork must be included for any samples from counties with a Fruit Fly Quarantine in TX. Refer to MN-S063 through MN-5065 Scan PPQ-530 to the corresponding Protect folder on the x drive. If PPQ-530 is not present, contact the Waste Coordinator and do not continue processing samples. .. YES NO E/Tok-- % Samples from ID may not be moved from the quarantined region. Refer to MN-5055 If samples originated in a quarantined zone, contact the Waste Coordinator and do not continue processing samples. YES NO N/A Samples from Giant African Snail Quarantine in FL maynot be moved from the quarantined region. Refer to MN-S068 If samples originated in a quarantined zone, contact the Waste Coordinator and do not continue processing samples. YES NO N/A REQUIREMENT ACTION PLETED dotNO "Special Handling" stickers are to be placed on all samples. Did "special handling" stickers get placed on all sample containers? Samples must be segregated and stored in designated bins, shelves and coolers. Were samples placed in a designated cooler, containers and shelves? YES NO Samples must be double contained to prevent accidental release. Were there any signs of breakage or leakage (check for broken glass and/or loose soil in the cooler)? 1f NO, ice and melt water can be disposed of by normal process (down YES O the drain). If YES, were ice and melt water separated from the cooler and disposed of properly? Any broken glass and/or loose soil are to be bagged and placed in a container or active drum (see Waste Coordinator). Ice and melt water should be baked at a temperature range of 121-154°F cooled before going down the drain. YES NO USDA Regulated satellite • for 2 hours and then Equipment and supplies that have come into contact samples must be decontaminated. Was the cooler(s) and/or countertop(s) decontaminated using either a fresh 10% bleach solution or 70% ethanol? (Gloves and other lab supplies will be bagged and placed in the USDA Regulated satellite container or active drum). NO 0 Comments: Report No 104672158290FCDFR Page 35 of 42 Page 8 of 15 --PaceRnalytical Document Name: Regulated Soil Checklist Document Revised: 13Feo2018. Page 2 of 2 Document No.: F-MN-Q-338-Rev.06 Issuing Authority: Pace Minnesota Quality Office To Be Completed by PM and/or PC: Sample Analysis to be conducted (circle all that apply): Name of Subcontract Lab (s): MN Subcontract Lab REQUIREMENT ACTION COMPLETED Permission to ship untreated soil must be on file prior to shipping to any subcontract lab, including IR Pace Labs. Go to: J:\SHARE\PRJ_MGR\10_Client Services Department Documents \Regulated Soils Permits — if permission to ship letter is not there, contact the Waste Coordinator. YES NO dp Shipment must include a valid copy of the receiving lab's permit as well as permission toship letter. Is a copy of all needed paperwork included with the COC? Do NOT ship samples until all necessary paperwork is compiled. YES NO N/A Comments: Project Manager Signature: Report No 10467215_8290FC_DFR Date: 3/19/2019 Page 36 of 42 Page 9 of 15 AnIj4!ca( Reporting Flags Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 A = Reporting Limit based on signal to noise B = Less than 10x higher than method blank level C = Result obtained from confirmation analysis D = Result obtained from analysis of diluted sample E = Exceeds calibration range I = Interferencepresent J = Estimated value L = Suppressive interference, analyte may be biased low Nn = Value obtained from additional analysis P = PCDEInterference R = Recovery outside target range S = Peak saturated U = Analyte not detected V = Result verified by confirmation analysis X = %D Exceeds limits Y = Calculated using average of daily RFs * = SeeDiscussion REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10467215_8290FC_DFR Page 10 of 15 Tel, 612-607-1700 Fax:612-607-6444 Report No 10467215 Page 37 of 42 Appendix B Sample Analysis Summary Report No 10467215_8290FC_e Analytical Services, Inc. Page 38 of 42 Page 11 of 15 ND = Not Detected NA = Not Applicable NC = Not Calculated Results reported on a dry weight basis and are valid to no more than 2 significant figures. J = Estimated value ae Analytical Client's Sample ID Lab Sample ID Filename Injected By Total Amount Extracted % Moisture Dry Weight Extracted ICAL ID CCaI Filename(s) Method Blank ID Native Isomers 2,3,7,8-TCDF Total TCDF Method 8290 Sample Analysis Results Client - PASI Florida TE-4(2-4') 35453908001 F190323A_02 ZMS 13.1 g 23.1 10.0 g F190112 F190322B_19 & BLANK-69147 Conc EMPC ng/Kg ng/Kg 2.0 59 2,3,7,8-TCDD 0.54 U Total TCDD 21 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 2.1 11 130 1.7 20 3.0 4.9 7.7 1.2 86 1.9 5.4 3.3 59 19 1.8 37 Matrix Dilution Collected Received F190323A_14 Extracted Analyzed EDL Internal ng/Kg Standards 1.0 2,3,7,8-TCDF-13C 1.0 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 0.54 2,3,4,7,8-PeCDF-13C 0.54 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 0.67 J 1,2,3,6,7,8-HxCDF-13C 0.40 2,3,4,6,7,8-HxCDF-13C 0.54 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 0.30 J 1,2,3,6,7,8-HxCDD-13C 0.30 1,2,3,4,6,7, 8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 0.14 J 1,2,3,4,6,7,8-HpCDD-13C 0.19 J OCDD-13C 0.22 0.16 J 1,2,3,4-TCDD-13C 0.18 1,2,3,7,8,9-HxCDD-13C 0.27 J 2,3,7,8-TCDD-37CI4 0.16 0.24 J 0.22 Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax- 612-607-6444 Solid NA 03/12/2019 11:20 03/15/2019 09:00 03/20/2019 16:10 03/22/2019 23:45 0.22 0.29 J 0.25 1,2,3,4,6,7,8-HpCDD 43 0.35 Total HpCDD 84 0.35 OCDF OCDD 15 0.30 240 0.47 ng's Percent Added Recovery 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 4.00 2.00 2.00 0.20 Total 2, 3, 7, 8-TC D D Equivalence: 10 ng/Kg (Lower -bound - Using ITE Factors) 48 53 58 58 70 47 49 52 47 52 48 46 46 53 47 NA NA 54 Conc = Concentration (Totals include 2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit Page 39 of 42 Report No 10467215_8290FC_DFR Page 12 of 15 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Analytical Client's Sample ID Lab Sample ID Filename Injected By Total Amount Extracted % Moisture Dry Weight Extracted ICAL ID CCal Filename(s) Method Blank ID Native Isomers TM Met hod 8290 Sample Analysis Results Client - PASI Florida TE-1 (1-2') 35453908002 F190323A_03 ZMS 11.4g 12.4 10.0 g F190112 F190322B_19 & F190323A_14 BLANK-69147 Conc EMPC ng/Kg ng/Kg EDL ng/Kg Matrix Dilution Collected Received Extracted Analyzed Internal Standards Tel: 612-607-1700 Fax: 612- 607-6444 Solid NA 03/12/2019 14:00 03/15/2019 09:00 03/20/2019 16:10 03/23/2019 00:29 ng's Percent Added Recovery 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD 0.82 6.1 0.88 U 3.7 0.74 7.4 0.82 7.8 0.49 0.63 0.16 U 8.2 4.1 2.6 41 0.29 U 0.24 U 0.38 0.53 0.66 0.58 J 0.58 0.88 0.88 0.27 IJ 0.23 J 0.25 0.30 J 0.30 0.11 0.11 0.13 0.16 0.13 0.29 0.26 0.25 0.26 J IJ J IJ J J 2,3,7,8-TCDF-13C 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 2,3,4,7,8-PeCDF-1 3C 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 1,2,3,6,7,8-HxCDF-13C 2,3,4,6,7,8-HxCDF-13C 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 1,2,3,6,7,8-HxCDD-13C 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 4.00 2.00 2.00 2,3,7,8-TCDD-37C14 0.20 6.1 0.19 I Total 2,3,7,8-TCDD 0.29 Equivalence: 3.7 ng/Kg 0.24 (Lower -bound - Using ITE Factors) 100 0.69 210 0.69 13 0.51 830 1.3 62 66 71 74 89 56 60 62 57 62 59 56 58 64 60 NA NA 67 Conc = Concentration (Totals include 2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit ND = Not Detected NA = Not Applicable NC = Not Calculated Results reported on a dry weight basis and are valid to no more than 2 significant figures. J = Estimated value I= Interference present REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10467215_8290FC_DFR Page 13 of 15 Page 40 of 42 AnaIyticaIT M Lab Sample Name Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) Native Isomers Method 8290 Blank Analysis Results DFBLKFC BLANK-69147 Y190322A_17 20.3 g Y190110 Y190322A 02 & Y190322A 18 Conc EMPC EDL ng/Kg ng/Kg ng/Kg Matrix Dilution Extracted Analyzed Injected By Internal Standards Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis. MN 55414 Tel: 612-607-1700 Fax: 612- 607-6444 Solid NA 03/20/2019 16:10 03/22/2019 22:32 JRH 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD 0.051 U 0.051 U 0.093 U 0.093 U 0.096 U 0.092 U 0.094 U 0.20 U 0.20 U 0.066 U 0.069 U 0.050 U 0.059 U 0.061 U 0.095 U 0.083 U 0.098 U 0.092 U 0.053 U 0.082 U 0.068 U 0.12 U 0.12 U 0.13 U 0.25 U 0.066 0.069 0.050 0.059 0.061 0.095 0.083 0.098 0.092 0.051 2,3,7,8-TCDF-13C 0.051 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 0.093 2,3,4,7,8-PeCDF-13C 0.093 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 0.096 1,2,3,6,7,8-HxCDF-13C 0.092 2,3,4,6,7,8-HxCDF-13C 0.094 1,2,3,7, 8, 9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 0.20 1,2, 3, 6, 7, 8-HxCD D-13C 0.20 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 ng's Percent Added Recovery 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 4.00 2.00 2.00 0.20 0.053 Total 2,3,7,8-TCDD 0.082 Equivalence: 0.00 ng/Kg 0.068 (Lower -bound - Using ITE Factors) 0.12 0.12 0.13 0.25 68 67 70 64 70 59 54 64 70 65 52 61 59 63 53 NA NA 42 Conc= Concentration (Totals include2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit Results reported on a total weight basis and are valid to no more than 2 significant figures. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10467215 8290FC DFR Page 41 of 42 Page 14 of 15 Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Analytical Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) Method Blank ID Native Isomers 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD TM Method Method 8290 Laboratory Control Spike Results LCS-69148 Y190322A_10 20.8 g Y190110 Y190322A_02 & Y190322A_18 BLANK-69147 Matrix Dilution Extracted Analyzed Injected By Qs Qm % Internal (ng) (ng) Rec. Standards 0.20 0.21 107 2,3,7,8-TCDF-130 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 0.20 0.24 121 2,3,4,7,8-PeCDF-13C 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 1.0 1.1 115 1,2,3,6,7,8-HxC DF-13C 1.0 1.1 115 2,3,4,6,7,8-HxCDF-13C 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 1.0 1.0 103 1,2,3,6,7, 8-HxCDD-13C 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 2.0 2.0 1.2 1.2 1.1 1.2 1.2 1.2 1.2 1.2 1.1 1.1 2.2 2.3 120 116 114 115 118 121 121 117 109 110 110 115 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 Tel: 612-607-1700 Fax: 612-607-6444 Solid NA 03/20/2019 16:10 03/22/2019 17:04 JRH ng's Percent Added Recovery 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 4.0 2.0 2.0 0.20 76 71 75 71 75 61 57 66 70 68 56 60 57 61 53 NA NA 78 Qs = Quantity Spiked Qm = Quantity Measured Rec. = Recovery (Expressed as Percent) R= Recovery outside of target range Y = RF averaging used in calculations Nn = Value obtained from additional analysis NA = Not Applicable * = See Discussion REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10467215_8290FC_DF R Page 42 of 42 Page 15 of 15 aceAnalytical wwwpace/abs.com April 02, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35455234 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 18, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc. Michael Van Ry, EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC, Page 1 of 48 s"7 PceAnalytical www.pacelabs.com CERTIFICATIONS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35455234 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification Ds 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 48 aceAnalytical www.pacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35455234 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35455234001 TE-9 (2-4) Solid 03/18/19 08:10 03/18/19 17:30 35455234002 TE-14 (0-2) Solid 03/18/19 11:30 03/18/19 17:30 35455234003 TE-24 (0-2) Solid 03/18/19 13:40 03/18/19 17:30 35455234004 TE-24 (2-4) Solid 03/18/19 13:50 03/18/19 17:30 35455234005 TE-19 (2-4) Solid 03/18/19 14:50 03/18/19 17:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 48 aceAnalytical l www.pacelabs.com SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course Pace Project No.: 35455234 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach. FL 33064 954-582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35455234001 TE-9 (2-4) 35455234002 TE-14 (0-2) 35455234003 TE-24 (0-2) 35455234004 TE-24 (2-4) 35455234005 TE-19 (2-4) FL -PRO BP2 3 PASI-O EPA6010 SC1 7 PASI-O EPA 6010 LEC 1 PASI-O EPA 7471 AMS 1 PASI-O EPA 8270 CB1 21 PASI-O ASTM D2974-87 CLT 1 PASI-O FL -PRO BP2 3 PASI-O EPA6010 SC1 7 PASI-O EPA 6010 LEC 1 PASI-O EPA 7471 AMS 1 PASI-O EPA8270 CB1 21 PASI-O ASTM D2974-87 CLT 1 PASI-O FL -PRO BP2 3 PASI-O EPA6010 JWP 7 PASI-O EPA 7471 AMS 1 PASI-O EPA8270 CB1 21 PASI-O ASTM D2974-87 CLT 1 PASI-O FL -PRO BP2 3 PASI-O EPA6010 SC1 7 PASI-O EPA 7471 AMS 1 PASI-O EPA8270 CB1 21 PASI-O ASTM D2974-87 CLT 1 PASI-O FL -PRO BP2 3 PASI-O EPA6010 SC1 7 PASI-O EPA 7471 AMS 1 PASI-O EPA8270 CB1 21 PASI-O ASTM D2974-87 CLT 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 48 SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35455234 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35455234001 TE-9 (2-4) FL -PRO Petroleum Range Organics 189 mg/kg 5.4 03/21/19 05:52 EPA6010 Arsenic 56.6 mg/kg 4.0 03/21/19 12:35 EPA 6010 Barium 141 mg/kg 4 0 03/21/19 12:35 EPA6010 Cadmium 1.8 mg/kg 0.40 03/21/19 12:35 EPA6010 Chromium 34.3 mg/kg 2.0 03/21/19 12:35 EPA6010 Lead 361 mg/kg 4.0 03/21/19 12:35 EPA 6010 Silver 4.2 mg/kg 2.0 03/21/19 12:35 EPA 7471 Mercury 0.080 mg/kg 0.012 03/22/19 17:29 EPA 8270 Acenaphthene 0.024 1 mg/kg 0.049 03/22/19 18:38 EPA 8270 Acenaphthylene 0.023 1 mg/kg 0.046 03/22/19 18:38 EPA 8270 Fluoranthene 0.020 1 mg/kg 0.046 03/22/19 18:38 EPA 8270 Fluorene 0.037 1 mg/kg 0.050 03/22/19 18:38 EPA 8270 1-Methylnaphthalene 0.039 1 mg/kg 0.055 03/22/19 18:38 EPA 8270 2-Methylnaphthalene 0.049 1 mg/kg 0.053 03/22/19 18:38 EPA 8270 Naphthalene 0.14 mg/kg 0.048 03/22/19 18:38 EPA 8270 Phenanthrene 0.063 mg/kg 0.046 03/22/19 18:38 EPA 8270 Pyrene 0.024 I mg/kg 0.046 03/22/19 18:38 ASTM D2974-87 Percent Moisture 27.2 % 0.10 03/22/19 12:14 35455234002 TE-14 (0-2) 'L-PRO Petroleum Range Organics 9.7 mg/kg 4.8 03/21/19 05:52 EPA6010 Arsenic 10 mg/kg 0.71 03/21/19 12:38 EPA6010 Barium 38.8 mg/kg 0.71 03/21/19 12:38 EPA6010 Cadmium 0.73 mg/kg 0.071 03/21/19 12:38 EPA6010 Chromium 13.5 mg/kg 0.35 03/21/19 12:38 EPA 6010 Lead 120 mg/kg 0.71 03/21119 12:38 EPA6010 Silver 1.6 mg/kg 0.35 03/21/19 12:38 EPA7471 Mercury 0.085 mg/kg 0.011 03/22/19 17:31 EPA 8270 Benzo(a)anthracene 0.020 1 mg/kg 0.042 03/22/19 19:03 EPA 8270 Benzo(a)pyrene 0.014 1 mg/kg 0.042 03/22/19 19:03 EPA 8270 Benzo(b)fluoranthene 0.020 1 mg/kg 0.042 03/22/19 19:03 EPA8270 Benzo(g,h,i)perylene 0.013 1 mg/kg 0.042 03/22/19 19:03 EPA 8270 Chrysene 0.015 1 mg/kg 0.042 03/22/19 19:03 EPA8270 Fluoranthene 0.014 1 mg/kg 0.042 03/22119 19:03 EPA 8270 Pyrene 0.014 1 mg/kg 0.042 03/22/19 19:03 ASTM D2974-87 Percent Moisture 17.7 % 0.10 03/22/19 14:19 35455234003 TE-24 (0-2) FL -PRO Petroleum Range Organics 4.5 mg/kg 4.2 03/21/19 22:05 EPA 6010 Arsenic 10.9 mg/kg 0.53 03/23/19 14:39 EPA6010 Barium 26.4 mg/kg 0.53 03/23/19 14:39 CPA6010 Cadmium 0.60 mg/kg 0.053 03/23/19 14:39 EPA6010 Chromium 17.2 mg/kg 0.27 03/23/19 14:39 EPA6010 Lead 99.7 mg/kg 0.53 03/23/19 14:39 EPA6010 Silver 0.56 mg/kg 0.27 03/23/19 14:39 EPA7471 Mercury 0.096 mg/kg 0.0079 03/22/19 18:09 J(M1),J(R1) EPA 8270 Benzo(a)anthracene 0.011 I mg/kg 0.036 03/22/19 19:27 EPA 8270 Benzo(b)fluoranthene 0-011 I mg/kg 0-036 03/22/19 19:27 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 48 SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35455234 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35455234003 TE-24 (0-2) ASTM D2974-87 Percent Moisture 5.6 % 0.10 03/22/19 14:19 35455234004 TE-24 (2-4) EPA6010 Arsenic 7.1 mg/kg 0.56 03/21/19 12:41 EPA6010 Barium 35.3 mg/kg 0.56 03/21/19 12:41 EPA6010 Cadmium 0.38 mg/kg 0.056 03/21/19 12:41 EPA 6010 Chromium 29.3 mg/kg 0.28 03/21/19 12:41 EPA6010 Lead 49.4 mg/kg 0.56 03/21/19 12:41 EPA6010 Silver 0.67 mg/kg 0.28 03/21/19 12:41 EPA 7471 Mercury 0.075 mg/kg 0.010 03/22/19 17:33 EPA 8270 Benzo(a)anthracene 0.012 I mg/kg 0.040 03/22/19 19:52 ASTM D2974-87 Percent Moisture 15.1 % 0.10 03/22/19 14:20 35455234005 TE-19 (2-4) FL -PRO Petroleum Range Organics 238 mg/kg 4.4 03/22/19 12:37 EPA 6010 Arsenic 6.1 mg/kg 0.58 03/21/19 12:44 EPA 6010 Barium 56.7 mg/kg 0.58 03/21/19 12:44 EPA6010 Cadmium 0.32 mg/kg 0.058 03/21/19 12:44 EPA6010 Chromium 9.9 mg/kg 0.29 03/21/19 12:44 EPA 6010 Lead 69.7 mg/kg 0.58 03/21/19 12:44 EPA6010 Silver 0.65 mg/kg 0.29 03/21/19 12:44 EPA 7471 Mercury 0.061 mg/kg 0.0077 03/22/19 17:35 EPA8270 Acenaphthene 0.024 1 mg/kg 0.039 03/22/19 11:49 J(M1),J(R1) EPA8270 Acenaphthylene 0.024 1 mg/kg 0.037 03/22/19 11:49 J(M1),J(R1) EPA8270 Anthracene 0.025 1 mg/kg 0.039 03/22/19 11:49 J(M1),J(R1) EPA 8270 Benzo(a)anthracene 0.012 1 mg/kg 0.037 03/22/19 11:49 EPA 8270 Benzo(b)fluoranthene 0.011 1 mg/kg 0.037 03/22/19 11:49 EPA 8270 Chrysene 0.013 1 mg/kg 0.037 03/22/19 11:49 EPA 8270 Fluoranthene 0.039 mg/kg 0.037 03/22/19 11:49 EPA8270 Fluorene 0.043 mg/kg 0.040 03/22/19 11:49 J(M1),J(R1) EPA8270 1-Methylnaphthalene 0.062 mg/kg 0.043 03/22/19 11:49 J(M1),J(R1) EPA8270 2-Methylnaphthalene 0.077 mg/kg 0.042 03/22/19 11:49 J(M1),J(R1) EPA8270 Naphthalene 0.17 mg/kg 0.038 03/22/19 11:49 J(M1),J(R1) EPA 8270 Phenanthrene 0.099 mg/kg 0.037 03/22/19 11:49 J(M1),J(R1) EPA 8270 Pyrene 0.044 mg/kg 0.037 03/22/19 11:49 ASTM D2974-87 Percent Moisture 7.4 % 0.10 03/22/19 14:20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 48 ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35455234 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: TE-9 (2-4) Lab ID: 35455234001 Collected: 03/18/19 08:10 Received: 03/18/19 17:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No uual FL -PRO Soil Microwave Petroleum Range Organics Surrogates o-Terphenyl (S) N-Pentatriacontane (S) 6010 MET ICP Arsenic Barium Cadmium Chromium Lead Selenium Silver Analytical Method: FL -PRO Preparation Method: EPA 3546 189 mg/kg 5.4 3.4 1 03/20/19 04:12 03/21/19 05:52 88 % 66-136 91 % 42-159 1 03/20/19 04:12 03/21/19 05:52 84-15-1 1 03/20/19 04:12 03/21/19 05:52 630-07-09 Analytical Method: EPA 6010 Preparation Method: EPA 3050 56.6 141 1.8 34.3 361 3.0 U 4.2 mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg 4.0 4.0 0.40 2.0 4.0 6.0 2.0 2.0 2.0 0.20 0.99 2.0 3.0 0.99 6010 MET ICP, TCLP Analytical Method: EPA6010 Preparation Method: Leachate Method/Date: EPA 1311; 03/29/19 19:37 ' ead 0.046 U mg/L 0.10 0.046 471 Mercury Analytical Method: EPA 7471 Preparation Method: Mercury 0.080 mg/kg 0.012 0.0062 8270 MSSV Short List Microwave Analytical Method: EPA8270 Preparation Method: Acenaphthene Acenaphthylene Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fl uoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene Chrysene Dibenz(a,h)anthracene Fluoranthene Fluorene Indeno(1,2,3-cd)pyrene 1-Methylnaphthalene 2-Methylnaphthalene Naphthalene Phenanthrene Pyrene Surrogates Nitrobenzene-d5 (S) 2-Fluorobiphenyl (S) p-Terphenyl-d14 (S) Date: 04/02/2019 03:42 PM 0.024 I 0.023 I 0.016 U 0.013 U 0.011 U 0.012 U 0.012 U 0.012 U 0.015 U 0.011 U 0.020 I 0.037 I 0.011 U 0.039 I 0.049 I 0.14 0.063 0.024 I 68 66 76 mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg Ok 0.049 0.046 0.049 0.046 0.046 0.046 0.046 0.046 0.046 0.046 0.046 0.050 0.046 0.055 0.053 0.048 0.046 0.046 24-98 29-101 29-112 0.016 0.014 0.016 0.013 0.011 0.012 0.012 0.012 0.015 0.011 0.015 0.016 0.011 0.018 0.018 0.016 0.015 0.015 5 03/20/19 16:32 5 03/20/19 16:32 5 03/20/1916:32 5 03/20/1916:32 5 03/20/19 16:32 5 03/20/1916:32 5 03/20/1916:32 03/21/19 12:35 03/21/19 12:35 03/21/19 12:35 03/21/19 12:35 03/21/19 12:35 03/21/19 12:35 03/21/19 12:35 EPA 3010 Initial pH: 5; Final pH: 5 7440-38-2 7440-39-3 7440-43-9 7440-47-3 7439-92-1 7782-49-2 7440-22-4 1 03/30/19 14:43 03/31 / 19 17:40 7439-92-1 EPA 7471 1 03/21/19 13:13 03/22/19 17:29 7439-97-6 EPA 3546 03/20/19 04:54 03/20/19 04:54 03/20/19 04:54 03/20/19 04:54 03/20/19 04:54 03/20/19 04:54 03/20/19 04:54 03/20/19 04:54 03/20/19 04:54 03/20/19 04:54 03/20/19 04:54 03/20/19 04:54 03/20/19 04:54 03/20/19 04:54 03/20/19 04:54 03/20/19 04:54 03/20/19 04:54 03/20/19 04:54 03/22/19 18:38 03/22/19 18:38 03/22/19 18:38 03/22/19 18:38 03/22/19 18:38 03/22/19 18:38 03/22/19 18:38 03/22/19 18:38 03/22/19 18:38 03/22/19 18:38 03/22/19 18:38 03/22/19 18:38 03/22/19 18:38 03/22/19 18:38 03/22/19 18:38 03/22/19 18:38 03/22/19 18:38 03/22/19 18:38 83-32-9 208-96-8 120-12-7 56-55-3 50-32-8 205-99-2 191-24-2 207-08-9 218-01-9 53-70-3 206-44-0 86-73-7 193-39-5 90-12-0 91-57-6 91-20-3 85-01-8 129-00-0 03/20/19 D4:54 03/22/19 18:38 4165-60-0 03/20/19 04:54 03/22/19 18:38 321-60-8 03/20/19 04:54 03/22/19 18:38 1718-51-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 48 /182ceAnalytical wwwpacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35455234 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: TE-9 (2-4) Lab ID: 35455234001 Collected: 03/18/19 08:10 Received: 03/18/19 17:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analysed CAS No. Qual Percent Moisture Percent Moisture Date: 04/02/2019 03:42 PM Analytical Method: ASTM D2974-87 27.2 % 0.10 0.10 1 03/22/19 12:14 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 48 ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35455234 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-562-4300 Sample: TE-14 (0-2) Lab ID: 35455234002 Collected: 03/18/19 11:30 Received: 03/18/19 17:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual FL -PRO Soil Microwave Analytical Method: FL -PRO Preparation Method: EPA3546 Petroleum Range Organics 9.7 mg/kg 4.8 3.0 1 03/20/19 04:12 03/21/19 05:52 Surrogates o-Terphenyl (S) 92 % 66-136 1 03/20/19 04:12 03/21/19 05:52 84-15-1 N-Pentatriacontane (S) 92 % 42-159 1 03/20/19 04:12 03/21/19 05:52 630-07-09 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA 3050 Arsenic 10 mg/kg 0.71 0.35 1 03/20/19 16:32 03/21/19 12:38 7440-38-2 Barium 38.8 mg/kg 0.71 0.35 1 03/20/19 16:32 03/21/19 12:38 7440-39-3 Cadmium 0.73 mg/kg 0.071 0.035 1 03/20/19 16:32 03/21/19 12:38 7440-43-9 Chromium 13.5 mg/kg 0.35 0.18 1 03/20/19 16:32 03/21/19 12:38 7440-47-3 Lead 120 mg/kg 0.71 0.35 1 03/20/19 16:32 03/21/19 12:38 7439-92-1 Selenium 0.53 U mg/kg 1.1 0.53 1 03/20/19 16:32 03/21/19 12:38 7782-49-2 Silver 1.6 mg/kg 0.35 0.18 1 03/20/19 16:32 03/21/19 12:38 7440-22-4 6010 MET ICP, TCLP Analytical Method: EPA6010 Preparation Method: EPA3010 Leachate Method/Date: EPA 1311; 03/29/19 19:37 Initial pH: 5; Final pH: 5 ' ead 0.046 U mg/L 0.10 0.046 1 03/30/19 14:43 03/31/19 17:43 7439-92-1 /471 Mercury Analytical Method: EPA7471 Preparation Method: EPA7471 Mercury 0.085 mg/kg 0.011 0.0057 1 03/21/19 13:13 03/22/19 17:31 7439-97-6 8270 MSSV Short List Microwave Analytical Method: EPA8270 Preparation Method: EPA3546 Acenaphthene 0.014 U mg/kg 0.044 0.014 1 03/20/19 04:54 03/22/19 19:03 83-32-9 Acenaphthylene 0.013 U mg/kg 0.042 0.013 1 03/20/19 04:54 03/22/19 19:03 208-96-8 Anthracene 0.015 U mg/kg 0.044 0.015 1 03/20/19 04:54 03/22/19 19:03 120-12-7 Benzo(a)anthracene 0.020 I mg/kg 0.042 0.012 1 03/20/19 04:54 03/22/19 19:03 56-55-3 Benzo(a)pyrene 0.014 I mg/kg 0.042 0.010 1 03/20/19 04:54 03/22/19 19:03 50-32-8 Benzo(b)fluoranthene 0.020 I mg/kg 0.042 0.011 1 03/20/19 04:54 03/22/19 19:03 205-99-2 Benzo(g,h,i)perylene 0.013 I mg/kg 0.042 0.010 1 03/20/19 04:54 03/22/19 19:03 191-24-2 Benzo(k)fluoranthene 0.011 U mg/kg 0.042 0.011 1 03/20/19 04:54 03/22/19 19:03 207-08-9 Chrysene 0.015 I mg/kg 0.042 0.013 1 03/20/19 04:54 03/22/19 19:03 218-01-9 Dibenz(a,h)anthracene 0.0095 U mg/kg 0.042 0.0095 1 03/20/19 04:54 03/22/19 19:03 53-70-3 Fluoranthene 0.014 I mg/kg 0.042 0.014 1 03/20/19 04:54 03/22/19 19:03 206-44-0 Fluorene 0.015 U mg/kg 0.045 0.015 1 03/20/19 04:54 03/22/19 19:03 86-73-7 Indeno(1,2,3-cd)pyrene 0.0095 U mg/kg 0.042 0.0095 1 03/20/19 04:54 03/22/19 19:03 193-39-5 1-Methylnaphthalene 0.016 U mg/kg 0.049 0.016 1 03/20/19 04:54 03/22/19 19:03 90-12-0 2-Methylnaphthalene 0.016 U mg/kg 0.048 0.016 1 03/20/19 04:54 03/22/19 19:03 91-57-6 Naphthalene 0.014 U mg/kg 0.043 0.014 1 03/20/19 04:54 03/22/19 19:03 91-20-3 Phenanthrene 0.014 U mg/kg 0.042 0.014 1 03/20/19 04:54 03/22/19 19:03 85-01-8 Pyrene 0.014 I mg/kg 0.042 0.013 1 03/20/19 04:54 03/22/19 19:03 129-00-0 Surrogates Nitrobenzene-d5 (S) 77 % 24-98 1 03/20/19 04:54 03/22/19 19:03 4165-60-0 2-Fluorobiphenyl (S) 71 % 29-101 1 03/20/19 04:54 03/22/19 19:03 321-60-8 p-Terphenyl-d14 (S) 81 % 29-112 1 03/20/19 04:54 03/22/19 19:03 1718-51-0 Date: 04/02/2019 03:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 48 ace Analytical wwwpacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35455234 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: TE-14 (0-2) Lab ID: 35455234002 Collected: 03/18/19 11:30 Received 03/18/19 17:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL Dr Prepared Analyzed CAS No. Qual Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 17.7 % 0.10 0.10 1 03/22/19 14:19 Date: 04/02/2019 03:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 48 ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35455234 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: TE-24 (0-2) Lab ID: 35455234003 Collected: 03/18/19 13:40 Received: 03/18/19 17:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual FL -PRO Soil Microwave Petroleum Range Organics Surrogates o-Terphenyl (S) N-Pentatriacontane (S) 6010 MET ICP Arsenic Barium Cadmium Chromium Lead Selenium Silver 7471 Mercury Mercury ,270 MSSV Short List Microwave Acenaphthene Acenaphthylene Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene Chrysene Dibenz(a, h)a nthracene Fluoranthene Fluorene Indeno(1,2,3-cd)pyrene 1-Methylnaphthalene 2-Methylnaphthalene Naphthalene Phenanthrene Pyrene Surrogates Nitrobenzene-d5 (S) 2-Fluorobiphenyl (S) p-Terphenyl-d14 (S) Percent Moisture Percent Moisture Date: 04/02/2019 03:42 PM Analytical Method: FL -PRO Preparation Method: EPA 3546 4.5 mg/kg 4.2 2.7 1 03/20/19 06.15 03/21/19 22:05 88 % 66-136 1 03/20/19 06:15 03/21/19 22:05 84-15-1 88 % 42-159 1 03/20/19 06:15 03/21/19 22:05 630-07-09 Analytical Method: EPA 6010 Preparation Method: EPA 3050 10.9 mg/kg 0.53 0.27 1 03/22/19 11:24 03/23/19 14:39 7440-38-2 26.4 mg/kg 0.53 0.27 1 03/22/19 11:24 03/23/19 14:39 7440-39-3 0.60 mg/kg 0.053 0.027 1 03/22/19 11:24 03/23/19 14:39 7440-43-9 17.2 mg/kg 0.27 0.13 1 03/22/19 11:24 03/23/19 14:39 7440-47-3 99.7 mg/kg 0.53 0.27 1 03/22/19 11:24 03/23/19 14:39 7439-92-1 0.40 U mg/kg 0.80 0.40 1 03/22/19 11:24 03/23/19 14:39 7782-49-2 0.56 mg/kg 0.27 0.13 1 03/22/19 11:24 03/23/19 14:39 7440-22-4 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.096 mg/kg 0.0079 0.0040 1 03/22/19 11:35 03/22/19 18:09 7439-97-6 J(M1), J(R1) Analytical Method: EPA 8270 Preparation Method: EPA 3546 0.012 U mglkg 0.038 0.012 1 03/20/19 04:54 03/22/19 19:27 83-32-9 0.011 U mg/kg 0.036 0.011 1 03/20/19 04:54 03/22/19 19:27 208-96-8 0.013 U mg/kg 0.038 0.013 1 03/20/19 04:54 03/22/19 19:27 120-12-7 0.011 1 mg/kg 0.036 0.010 1 03/20/19 04:54 03/22/19 19:27 56-55-3 0.0089 U mglkg 0.036 0.0089 1 03/20/19 04:54 03/22/19 19:27 50-32-8 0.011 I mg/kg 0.036 0.0096 1 03/20/19 04:54 03/22/19 19:27 205-99-2 0.0090 U mg/kg 0.036 0.0090 1 03/20/19 04:54 03/22/19 19:27 191-24-2 0.0096 U mg/kg 0.036 0.0096 1 03/20/19 04:54 03/22/19 19:27 207-08-9 0.011 U mg/kg 0.036 0.011 1 03/20/19 04:54 03/22/19 19:27 218-01-9 0.0082 U mg/kg 0.036 0.0082 1 03/20/19 04:54 03/22/19 19:27 53-70-3 0.012 U mg/kg 0.036 0.012 1 03/20/19 04:54 03/22/19 19:27 206-44-0 0.013 U mg/kg 0.039 0.013 1 03/20/19 04:54 03/22/19 19:27 86-73-7 0.0082 U mg/kg 0.036 0.0082 1 03/20/19 04:54 03/22/19 19:27 193-39-5 0.014 U mg/kg 0.042 0.014 1 03/20/19 04:54 03/22/19 19:27 90-12-0 0.014 U mg/kg 0.041 0.014 1 03/20/19 04:54 03/22/19 19:27 91-57-6 0.012 U mg/kg 0.037 0.012 1 03/20/19 04:54 03/22/19 19:27 91-20-3 0.012 U mg/kg 0.036 0.012 1 03/20/19 04:54 03/22/19 19:27 85-01-8 0.011 U mg/kg 0.036 0.011 1 03/20/19 04:54 03/22/19 19:27 129-00-0 80 % 24-98 1 03/20/19 04:54 03/22/19 19:27 4165-60-0 74 % 29-101 1 03/20/19 04:54 03/22/19 19:27 321-60-8 81 % 29-112 1 03/20/19 04:54 03/22/19 19:27 1718-51-0 Analytical Method: ASTM D2974-87 5.6 % 0.10 0.10 1 03/22/1914:19 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 48 aceAnalytical www pacelabs. com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35455234 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: TE-24 (2-4) Lab ID: 35455234004 Collected: 03/18/19 13:50 Received: 03/18/19 17:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual FL -PRO Soil Microwave Analytical Method: FL -PRO Preparation Method: EPA3546 Petroleum Range Organics 3.0 U mg/kg 4.7 3.0 1 03/20/19 06:15 03/21/19 22:05 Surrogates o-Terphenyl (S) 96 % 66-136 1 03/20/19 06:15 03/21/19 22:05 84-15-1 N-Pentatriacontane (S) 98 % 42-159 1 03/20/19 06:15 03/21/19 22:05 630-07-09 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 7.1 mg/kg 0.56 0.28 1 03/20/19 16:32 03/21/19 12:41 7440-38-2 Barium 35.3 mg/kg 0.56 0.28 1 03/20/10 16:32 03/21/19 12:41 7440-39-3 Cadmium 0.38 mg/kg 0.056 0.028 1 03/20/19 16:32 03/21/19 12:41 7440-43-9 Chromium 29.3 mg/kg 0.28 0.14 1 03/20/19 16:32 03/21/19 12:41 7440-47-3 Lead 49.4 mg/kg 0.56 0.28 1 03/20/19 16:32 03/21/19 12:41 7439-92-1 Selenium 0.42 U mg/kg 0.84 0.42 1 03/20/19 16:32 03/21/19 12:41 7782-49-2 Silver 0.67 mg/kg 0.28 0.14 1 03/20/19 16:32 03/21/19 12:41 7440-22-4 7471 Mercury Analytical Method: EPA7471 Preparation Method: EPA7471 Mercury 0.075 mg/kg 0.010 0.0052 1 03/21/19 13:13 03/22/19 17:33 7439-97-6 8270 MSSV Short List Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546 Acenaphthene 0.014 U mg/kg 0.042 0.014 1 03/20/19 04:54 03/22/19 19:52 83-32-9 Acenaphthylene 0.012 U mg/kg 0.040 0.012 1 03/20/19 04:54 03/22/19 19:52 208-96-8 Anthracene 0.014 U mg/kg 0.042 0.014 1 03/20/19 04:54 03/22/19 19:52 120-12-7 Benzo(a)anthracene 0.012 I mg/kg 0.040 0.011 1 03/20/19 04:54 03/22/19 19:52 56-55-3 Benzo(a)pyrene 0.0098 U mg/kg 0.040 0.0098 1 03/20/19 04:54 03/22/19 19:52 50-32-8 Benzo(b)fluoranthene 0.010 U mg/kg 0.040 0.010 1 03/20/19 04:54 03/22/19 19:52 205-99-2 Benzo(g,h,i)perylene 0.0099 U mg/kg 0.040 0.0099 1 03/20/19 04:54 03/22/19 19:52 191-24-2 Benzo(k)fluoranthene 0.011 U mg/kg 0.040 0.011 1 03/20/19 04:54 03/22/19 19:52 207-08-9 Chrysene 0.012 U mg/kg 0.040 0.012 1 03/20/19 04:54 03/22/19 19:52 218-01-9 Dibenz(a,h)anthraccnc 0.0091 U mg/kg 0.040 0.0091 1 03/20/19 04:54 03/22/19 19:52 53-70-3 Fluoranthene 0.013 U mg/kg 0.040 0.013 1 03/20/19 04:54 03/22/19 19:52 206-44-0 Fluorene 0.014 U mg/kg 0.043 0.014 1 03/20/19 04:54 03/22/19 19:52 86-73-7 Indeno(1,2,3-cd)pyrene 0.0090 U mg/kg 0.040 0.0090 1 03/20/19 04:54 03/22/19 19:52 193-39-5 1-Methylnaphthalene 0.015 U mg/kg 0.046 0.015 1 03/20/19 04:54 03/22/19 19:52 90-12-0 2-Methylnaphthalene 0.015 U mg/kg 0.045 0.015 1 03/20/19 04:54 03/22/19 19:52 91-57-6 Naphthalene 0.014 U mg/kg 0.041 0.014 1 03/20/19 04:54 03/22/19 19:52 91-20-3 Phenanthrene 0.013 U mg/kg 0.040 0.013 1 03/20/19 04:54 03/22/19 19:52 85-01-8 Pyrene 0.012 U mg/kg 0.040 0.012 1 03/20/19 04:54 03/22/19 19:52 129-00-0 Surrogates Nitrobenzene-d5 (S) 76 % 24-98 1 03/20/19 04:54 03/22/19 19:52 4165-60-0 2-Fluorobiphenyl (S) 70 % 29-101 1 03/20/19 04:54 03/22/19 19:52 321-60-8 p-Terphenyl-d14 (S) 80 % 29-112 1 03/20/19 04:54 03/22/19 19:52 1718-51-0 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 15.1 % 0.10 0.10 1 03/22/19 14:20 Date: 04/02/2019 03:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 48 aceAnalytical wwwpacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35455234 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: TE-19 (2-4) Lab ID: 35455234005 Collected: 03/18/19 14:50 Received: 03/18/19 17:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual FL -PRO Soil Microwave Petroleum Range Organics Surrogates o-Terphenyl (S) N-Pentatriacontane (S) 6010 MET ICP Arsenic Barium Cadmium Chromium Lead Selenium Silver 7471 Mercury Mercury 270 MSSV Short List Microwave Acenaphthene Acenaphthylene Anthracene Benzo(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene Chrysene Dibenz(a,h)anthracene Fluoranthene Fluorene Indeno(1,2,3-cd)pyrene 1-Methylnaphthalene 2-Methylnaphthalene Naphthalene Phenanthrene Pyrene Surrogates Nitrobenzene-d5 (S) 2-Fluorobiphenyl (S) Date: 04/02/2019 03:42 PM Analytical Method: FL -PRO Preparation Method: EPA 3546 238 mg/kg 4.4 92 % 66-136 99 % 42-159 2.8 1 03/20/19 06:15 03/22/19 12:37 1 03/20/19 06:15 03/22/19 12:37 84-15-1 1 03/20/19 06:15 03/22/19 12:37 630-07-09 Analytical Method: EPA 6010 Preparation Method: EPA 3050 6.1 56.7 0.32 9.9 69.7 0.44 U 0.65 mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg 0.58 0.29 1 03/20/19 16:32 0.58 0.29 1 03/20/19 16:32 0.058 0.029 1 03/20/19 16:32 0.29 0.15 1 03/20/19 16:32 0.58 0.29 1 03/20/19 16:32 0.88 0.44 1 03/20/19 16:32 0.29 0.15 1 03/20/19 16:32 03/21/19 12:44 03/21/19 12:44 03/21/19 12:44 03/21/19 12:44 03/21/19 12:44 03/21/19 12:44 03/21/19 12:44 7440-38-2 7440-39-3 7440-43-9 7440-47-3 7439-92-1 7782-49-2 7440-22-4 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.061 mg/kg 0.0077 0.0039 1 03/21/19 13:13 03/22/19 17:35 7439-97-6 Analytical Method: EPA8270 Preparation Method: EPA3546 0.024 0.024 0.025 0.012 1 0.0091 U 0.011 1 0.0092 U 0.0098 U 0.013 1 0.0084 U 0.039 0.043 mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg 0.039 0.037 0.039 0.037 0.037 0.037 0.037 0.037 0.037 0.037 0.037 0.040 0.0083 U mg/kg 0.037 0.062 mg/kg 0.043 0.077 mg/kg 0.042 0.17 mg/kg 0.038 0.099 mg/kg 0.037 0.044 mg/kg 0.037 43 % 24-98 52 % 29-101 0.013 0.011 0.013 0.010 0.0091 0.0097 0.0092 0.0098 0.012 0.0084 0.012 0.013 1 03/20/19 06:45 1 03/20/19 06:45 1 03/20/19 06:45 1 03/20/19 06:45 1 03/20/19 06:45 1 03/20/19 06:45 1 03/20/19 06:45 1 03/20/19 06:45 1 03/20/19 06:45 1 03/20/19 06:45 1 03/20/19 06:45 1 03/20/19 06:45 03/22/19 11:49 03/22/19 11:49 03/22/19 11:49 03/22/19 11:49 03/22/19 11:49 03/22/19 11:49 03/22/19 11:49 03/22/19 11:49 03/22/19 11:49 03/22/19 11:49 03/22/19 11:49 03/22/19 11:49 83-32-9 208-96-8 120-12-7 56-55-3 50-32-8 205-99-2 191-24-2 207-08-9 218-01-9 53-70-3 206-44-0 86-73-7 0.0083 1 03/20/19 06:45 03/22/19 11:49 193-39-5 0.014 1 03/20/19 0645 03/22/19 11.49 90-12-0 0.014 1 03/20/19 06:45 03/22/19 11:49 91-57-6 0.013 1 03/20/19 06:45 03/22/19 11:49 91-20-3 0.012 1 03/20/19 06:45 03/22/19 11:49 85-01-8 0.012 1 03/20/19 06:45 03/22/19 11:49 129-00-0 1 03/20/19 06:45 03/22/19 11:49 4165-60-0 1 03/20/19 06:45 03/22/19 11:49 321-60-8 REPORT OF LABORATORY ANALYSIS J(M1), J(R1) J(M1), J(R1) J(M1), J(R1) J(M1) J(M1) J(M1), J(R1) J(M1), J(R1) J(M1), J(R1) J(M1), J(R1) J(M1), J(R1) This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 48 aceAnalytical wwwpacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35455234 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: TE-19 (2-4) Lab ID: 35455234005 Collected: 03/18/19 14:50 Received: 03/18/19 17:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8270 MSSV Short List Microwave Surrogates p-Terphenyl-d14 (S) Percent Moisture Percent Moisture Date: 04/02/2019 03:42 PM Analytical Method: EPA 8270 Preparation Method: EPA 3546 56 070 29-112 1 03/20/1906:45 03/22/1911.49 1718-51-0 Analytical Method: ASTM D2974-87 7.4 % 0.10 0.10 1 03/22/19 14:20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 48 �aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35455234 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 524787 Analysis Method: EPA 7471 QC Batch Method: EPA7471 Analysis Description: 7471 Mercury Associated Lab Samples: 35455234001, 35455234002, 35455234004, 35455234005 METHOD BLANK: 2837406 Matrix: Solid Associated Lab Samples: 35455234001, 35455234002, 35455234004, 35455234005 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury mg/kg 0.0043 U 0.0086 0.0043 03/22/19 12:10 LABORATORY CONTROL SAMPLE: 2837407 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg 0.078 0.079 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2837408 2837409 MS MSD 35453946001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual lercury mg/kg 0.23 0.26 0.27 0.29 0.30 25 26 80-120 2 20 J(M1) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/02/2019 03:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 48 www.pacolabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35455234 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 525260 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 35455234003 METHOD BLANK: 2840498 Matrix: Solid Associated Lab Samples: 35455234003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury mg/kg 0.0049 U 0.0098 0.0049 03/22/19 18:05 LABORATORY CONTROL SAMPLE: 2840499 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg 0.094 0.096 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2840500 2840501 MS MSD 35455234003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 0.096 0.089 0.079 0.13 0.10 39 9 80-120 23 20 J(M1), J(R1) Results presented on this page are in the units indicated by the "Units' column except where an alternate unit is presented to the right of the result. Date: 04/02/2019 03:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 48 (/2'Yte www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35455234 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 524676 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 35455234001, 35455234002, 35455234004, 35455234005 METHOD BLANK: 2836206 Matrix: Solid Associated Lab Samples: 35455234001. 35455234002, 35455234004, 35455234005 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic mg/kg 0.28 U 0.57 0.28 03/21/19 11:23 Barium mg/kg 0.28 U 0.57 0.28 03/21/19 11:23 Cadmium mg/kg 0.028 U 0.057 0.028 03/21/19 11:23 Chromium mg/kg 0.14 U 0.28 0.14 03/21/19 11:23 Lead mg/kg 0.28 U 0.57 0.28 03/21/19 11:23 Selenium mg/kg 0.42 U 0.85 0.42 03/21/19 11:23 Silver mg/kg 0.14 U 0.28 0.14 03/21/19 11:23 LABORATORY CONTROL SAMPLE: 2836207 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers Arsenic mg/kg 15.3 14.4 94 80-120 Barium mg/kg 15-3 15.1 98 80-120 ;admium mg/kg 1.5 1.5 99 80-120 Chromium mg/kg 15.3 15.6 102 80-120 Lead mg/kg 15.3 15.2 99 80-120 Selenium mg/kg 15.3 13.6 88 80-120 Silver mg/kg 1.5 1.5 97 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2836208 2836209 MS MSD 35453946001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic mg/kg 4.9 32.3 30 33.7 33.3 89 94 75-125 1 20 Barium mg/kg 90.1 32.3 30 110 115 61 82 75-125 4 20 J(M1) Cadmium mg/kg 0.61 3.3 3.1 3.6 3.4 92 92 75-125 6 20 Chromium mg/kg 12.8 32.3 30 44.8 44.3 99 105 75-125 1 20 Lead mg/kg 11.5 32.3 30 40.8 39.9 91 94 75-125 2 20 Selenium mg/kg 1.1 U 32.3 30 30.5 28.9 91 92 75-125 5 20 Silver mg/kg 1.2 3.3 3.1 4.3 4.2 96 99 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/02/2019 03:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 48 tL QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35455234 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 525212 Analysis Method: EPA6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 35455234003 METHOD BLANK: 2840253 Matrix: Solid Associated Lab Samples: 35455234003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic mg/kg 0.31 U 0.62 0.31 03/22/19 15:30 Barium mg/kg 0.31 U 0.62 0.31 03/22/19 15:30 Cadmium mg/kg 0.031 U 0.062 0.031 03/22/19 15:30 Chromium mg/kg 0.16 U 0.31 0.16 03/22/19 15:30 Lead mg/kg 0.31 U 0.62 0.31 03/22/19 15:30 Selenium mg/kg 0.47 U 0.94 0.47 03/22/19 15:30 Silver mg/kg 0.16 U 0.31 0.16 03/22/19 15:30 LABORATORY CONTROL SAMPLE: 2840254 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers Arsenic mg/kg 14.9 14.5 97 80-120 Barium mg/kg 14.9 15.0 101 80-120 Cadmium mg/kg 1.5 1.5 101 80-120 Chromium mg/kg 14.9 15.5 104 80-120 Lead mg/kg 14.9 15.2 102 80-120 Selenium mg/kg 14.9 13.6 91 80-120 Silver mg/kg 1.5 1.5 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2840255 2840256 MS MSD 35454978007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic mg/kg 0.29 U 14.8 12.9 11.8 10.3 79 80 75-125 14 20 Barium mg/kg 0.75 14.8 12.9 15.5 15.7 99 116 75-125 2 20 Cadmium mg/kg 0.029 U 1.5 1.2 1.4 1.2 95 92 75-125 17 20 Chromium mg/kg 2.2 14.8 12.9 17.8 15.6 105 104 75-125 13 20 Lead mg/kg 1.2 14.8 12.9 15.5 14.3 96 101 75-125 8 20 Selenium mg/kg 0.44 U 14.8 12.9 11.6 9.9 78 77 75-125 16 20 Silver mg/kg 0.15 U 1.5 1.2 1.3 1.1 91 88 75-125 18 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/02/2019 03:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 48 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35455234 QC Batch: 527287 Analysis Method: EPA 6010 QC Batch Method: EPA 3010 Analysis Description: 6010 MET TCLP Associated Lab Samples: 35455234001, 35455234002 METHOD BLANK: 2851541 Matrix: Water Associated Lab Samples: 35455234001, 35455234002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Lead mg/L 0.0046 U 0.010 0.0046 03/31/19 17:17 LABORATORY CONTROL SAMPLE: 2853804 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead mglL 0.25 0.25 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2853805 2853806 MS MSD 35453908001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual ead mg/L 0.046 U 2.5 2.5 2.5 2.6 101 102 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/02/2019 03:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 48 Face Analytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35455234 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 524361 Analysis Method: EPA 8270 QC Batch Method: EPA 3546 Analysis Description: 8270 Solid MSSV Microwave Short Spike Associated Lab Samples: 35455234001, 35455234002, 35455234003, 35455234004 METHOD BLANK: 2834748 Matrix: Solid Associated Lab Samples: Parameter 35455234001, 35455234002, 35455234003, 35455234004 Blank Reporting Units Result Limit MDL Analyzed Qualifiers 1-Methylnaphthalene mg/kg 0.013 U 0.040 0.013 03/21/19 18:46 2-Methylnaphthalene mg/kg 0.013 U 0.039 0.013 03/21/19 18:46 Acenaphthene mg/kg 0.012 U 0.036 0.012 03/21/19 18:46 Acenaphthylene mg/kg 0.010 U 0.034 0.010 03/21/19 18:46 Anthracene mg/kg 0.012 U 0.036 0.012 03/21/19 18:46 Benzo(a)anthracene mg/kg 0.0096 U 0.034 0.0096 03/21/19 18:46 Benzo(a)pyrene mg/kg 0.0083 U 0.034 0.0083 03/21/19 18:46 Benzo(b)fluoranthene mg/kg 0.0090 U 0.034 0.0090 03/21/19 18:46 Benzo(g,h,i)perylene mg/kg 0.0084 U 0.034 0.0084 03/21/19 18:46 Benzo(k)fluoranthene mg/kg 0.0090 U 0.034 0.0090 03/21/19 18:46 Chrysene mg/kg 0.011 U 0.034 0.011 03/21/19 18:46 Dibenz(a,h)anthracene mg/kg 0.0077 U 0.034 0.0077 03/21/19 18:46 Fluoranthene mg/kg 0.011 U 0.034 0.011 03/21/19 18:46 Fluorene mg/kg 0.012 U 0.037 0.012 03/21/19 18:46 Indeno(1,2,3-cd)pyrene mg/kg 0.0077 U 0.034 0.0077 03/21/19 18:46 Naphthalene mg/kg 0.012 U 0.035 0.012 03/21/19 18:46 Phenanthrene mg/kg 0.011 U 0.034 0.011 03/21/19 18:46 Pyrene mg/kg 0.011 U 0.034 0.011 03/21/19 18:46 2-Fluorobiphenyl (S) % 80 29-101 03/21/19 18:46 Nitrobenzene-d5 (S) % 88 24-98 03/21/19 18:46 p-Terphenyl-d14 (S) % 96 29-112 03/21/19 18:46 LABORATORY CONTROL SAMPLE: 2834749 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1-Methylnaphthalene mg/kg 1.7 1.2 74 38-115 2-Methylnaphthalene mg/kg 1.7 1.2 71 37-115 Acenaphthene mg/kg 1.7 1.2 72 30-127 Acenaphthylene mg/kg 1.7 1.3 78 29-129 Anthracene mg/kg 1.7 1.3 80 37-126 Benzo(a)anthracene mg/kg 1.7 1.6 93 37-130 Benzo(a)pyrene mg/kg 1.7 1.3 81 39-128 Benzo(b)fluoranthene mg/kg 1.7 1.3 78 38-128 Benzo(g,h,i)perylene mg/kg 1.7 1.5 92 34-136 Benzo(k)fluoranthene mg/kg 1.7 1.3 79 39-133 Chrysene mg/kg 1.7 1.5 92 39-125 Dibenz(a,h)anthracene mg/kg 1.7 1.5 92 37-127 Fluoranthene mg/kg 1-7 1.4 85 39-130 Fluorene mg/kg 1.7 1.3 77 35-125 Indeno(1,2,3-cd)pyrene mg/kg 1.7 1.6 93 35-133 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/02/2019 03:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 48 *.c."/ tPaceAna1vticaI wwwpacelabs.com I QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35455234 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE: 2834749 Spike LCS LCS % Rec Parameter Units Conc Result % Rec Limits Qualifiers Naphthalene mg/kg 1.7 1.2 74 36-115 Phenanthrene mg/kg 1.7 1.4 83 35-128 Pyrene mg/kg 1.7 1.5 90 37-132 2-Fluorobiphenyl (S) % 69 29-101 Nitrobenzene-d5 (S) % 75 24-98 p-Terphenyl-d14 (S) % 83 29-112 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2834750 2834751 MS MSD 35455113003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1-Methylnaphthalene mg/kg 0.014 U 1.8 1.8 1.2 1.4 69 78 38-115 12 40 2-Methylnaphthalene mg/kg 0.014 U 1.8 1.8 1.2 1.3 68 75 37-115 10 40 Acenaphthene mg/kg 0.012 U 1.8 1.8 1.2 1.4 70 78 30-127 11 40 Acenaphthylene mg/kg 0.011 U 1.8 1.8 1.3 1.5 76 85 29-129 12 40 Anthracene mglkg 0.013 U 1.8 1.8 1.4 1.5 80 82 37-126 3 40 Benzo(a)anthracene mg/kg 0.010 U 1.8 1.8 1.7 1.7 97 94 37-130 3 40 Benzo(a)pyrene mg/kg 0.0088 U 1.8 1.8 1.5 1.4 84 80 39-128 5 40 lenzo(b)fluoranthene mg/kg 0.0095 U 1.8 1.8 1.4 1.3 81 76 38-128 6 40 3enzo(g,h,i)perylene mg/kg 0.0089 U 1.8 1.8 1.7 1.6 96 91 34-136 5 40 Benzo(k)fluoranthene mg/kg 0.0095 U 1.8 1.8 1.4 1.4 82 77 39-133 6 40 Chrysene mg/kg 0.011 U 1.8 1.8 1.7 1.6 97 91 39-125 6 40 Dibenz(a,h)anthracene mglkg 0.0082 U 1.8 1.8 1.7 1.6 96 90 37-127 6 40 Fluoranthene mg/kg 0.012 U 1.8 1.8 1.5 1.5 88 87 39-130 0 40 Fluorene mg/kg 0.013 U 1.8 1.8 1.3 1.5 76 82 35-125 9 40 Indeno(1,2,3-cd)pyrene mg/kg 0.0081 U 1.8 1.8 1.7 1.6 98 91 35-133 6 40 Naphthalene mg/kg 0.012 U 1.8 1.8 1.2 1.4 68 78 36-115 13 40 Phenanthrene mg/kg 0.012 U 1.8 1.8 1.5 1.5 82 85 35-128 4 40 Pyrene mg/kg 0.011 U 1.8 1.8 1.6 1.6 93 90 37-132 2 40 2-Fluorobiphenyl (S) % 66 76 29-101 Nitrobenzene-d5 (S) % 72 79 24-98 p-Terphenyl-d14 (S) % 87 83 29-112 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/02/2019 03:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 21 of 48 QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35455234 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 524363 Analysis Method: EPA 8270 QC Batch Method: EPA 3546 Analysis Description: 8270 Solid MSSV Microwave Short Spike Associated Lab Samples: 35455234005 METHOD BLANK: 2834756 Matrix: Solid Associated Lab Samples: 35455234005 Parameter Blank Reporting Units Result Limit MDL Analyzed Qualifiers 1-Methylnaphthalene mg/kg 0.013 U 0.040 0.013 03/22/19 09:32 2-Methylnaphthalene mg/kg 0.013 U 0.039 0.013 03/22/19 09:32 Acenaphthene mg/kg 0.012 U 0.036 0.012 03/22/19 09:32 Acenaphthylene mg/kg 0.011 U 0.034 0.011 03/22/19 09:32 Anthracene mg/kg 0.012 U 0.036 0.012 03/22/19 09:32 Benzo(a)anthracene mg/kg 0.0098 U 0.034 0.0098 03/22/19 09:32 Benzo(a)pyrene mg/kg 0.0085 U 0.034 0.0085 03/22/19 09:32 Benzo(b)fluoranthene mg/kg 0.0091 U 0.034 0.0091 03/22/19 09:32 Benzo(g,h,i)perylene mg/kg 0.0086 U 0.034 0.0086 03/22/19 09:32 Benzo(k)fluoranthene mg/kg 0.0091 U 0.034 0.0091 03/22/19 09:32 Chrysene mg/kg 0.011 U 0.034 0.011 03/22/19 09:32 Dibenz(a,h)anthraccne mg/kg 0.0079 U 0.034 0.0079 03/22/19 09:32 Fluoranthene mg/kg 0.011 U 0.034 0.011 03/22/19 09:32 Fluorene mg/kg 0.012 U 0.037 0.012 03/22/19 09:32 Indeno(1,2,3-cd)pyrene mg/kg 0.0078 U 0.034 0.0078 03/22/19 09:32 Naphthalene mg/kg 0.012 U 0.035 0.012 03/22/19 09:32 Phenanthrene mg/kg 0.011 U 0.034 0.011 03/22/19 09:32 Pyrene mg/kg 0.011 U 0.034 0.011 03/22/19 09:32 2-Fluorobiphenyl (S) % 61 29-101 03/22/19 09:32 Nitrobenzene-d5 (S) % 55 24-98 03/22/19 09:32 p-Terphenyl-d14 (S) % 75 29-112 03/22/19 09:32 LABORATORY CONTROL SAMPLE: 2834757 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1-Methylnaphthalene mg/kg 1.7 1.1 66 38-115 2-Methylnaphthalene mg/kg 1.7 1.0 62 37-115 Acenaphthene mg/kg 1.7 1.0 62 30-127 Acenaphthylene mg/kg 1.7 1.1 66 29-129 Anthracene mg/kg 1.7 1.1 67 37-126 Benzo(a)anthracene mg/kg 1.7 1.3 76 37-130 Benzo(a)pyrene mg/kg 1.7 1.1 67 39-128 Benzo(b)fluoranthene mg/kg 1.7 1.1 64 38-128 Benzo(g,h,i)perylene mg/kg 1.7 1.1 69 34-136 Benzo(k)fluoranthene mg/kg 1.7 1.1 68 39-133 Chrysene mg/kg 1.7 1.3 78 39-125 Dibenz(a,h)anthracene mg/kg 1.7 1.1 69 37-127 Fluoranthene mg/kg 1.7 1.2 74 39-130 Fluorene mg/kg 1.7 1.1 68 35-125 Indeno(1,2,3-cd)pyrene mg/kg 1.7 1.2 70 35-133 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/02/2019 03:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 22 of 48 j PaceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35455234 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE: 2834757 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Naphthalene mg/kg 1.7 1.0 60 36-115 Phenanthrene mg/kg 1.7 1.1 67 35-128 Pyrene mg/kg 1.7 1.2 74 37-132 2-Fluorobiphenyl (S) % 61 29-101 Nitrobenzene-d5(S) % 55 24-98 p-Terphenyl-d14 (S) % 71 29-112 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2834758 2834759 MS MSD 35455234005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1-Methylnaphthalene mg/kg 0.062 1.8 1.8 0.18 0.99 6 51 38-115 139 40 J(M1), J(R1) 2-Methylnaphthalene mg/kg 0.077 1.8 1.8 0.19 0.95 6 48 37-115 133 40 J(M1), J(R1) Acenaphthene mg/kg 0.024 1 1.8 1.8 0.30 0.93 15 50 30-127 102 40 J(M1), J(R1) Acenaphthylene mg/kg 0.024 1 1.8 1.8 0.23 0.92 11 49 29-129 120 40 J(M1), J(R1) Nnthracene mg/kg 0.025 1 1.8 1.8 0.47 0.88 25 47 37-126 61 40 J(M1). J(R1) Benzo(a)anthracene mg/kg 0.012 1 1.8 1.8 0.75 0.92 41 50 37-130 20 40 Benzo(a)pyrene mg/kg 0.0091 U 1.8 1.8 0.65 0.71 36 39 39-128 8 40 J(M1) Benzo(b)fluoranthene mg/kg 0.011 1 1.8 1.8 0.74 0.80 40 43 38-128 7 40 Benzo(g,h,i)perylene mg/kg 0.0092 U 1.8 1.8 0.70 0.70 38 39 34-136 1 40 Benzo(k)fluoranthene mg/kg 0.0098 U 1.8 1.8 0.72 0.74 39 41 39-133 3 40 Chrysene mg/kg 0.013 1 1.8 1.8 0.76 0.91 41 50 39-125 19 40 Dibenz(a,h)anthracene mg/kg 0.0084 U 1.8 1.8 0.65 0.68 36 38 37-127 5 40 J(M1) Fluoranthene mg/kg 0.039 1.8 1.8 0.81 1.0 43 54 39-130 23 40 Fluorene mg/kg 0.043 1.8 1.8 0.46 1.0 23 53 35-125 74 40 J(M1), J(R1) Indeno(1,2,3-cd)pyrene mg/kg 0.0083 U 1.8 1.8 0.65 0.69 36 38 35-133 6 40 Naphthalene mg/kg 0.17 1.8 1.8 0.15 1.0 -1 46 36-115 147 40 J(M1), J(R1) Phenanthrene mg/kg 0.099 1.8 1.8 0.59 1.0 27 51 35-128 54 40 J(M1), J(R1) Pyrene mg/kg 0.044 1.8 1.8 0.84 1.0 44 53 37-132 17 40 2-Fluorobiphenyl (S) % 11 49 29-101 J(S0) Nitrobenzene-d5 (S) % 5 29 24-98 J(S0) p-Terphenyl-d14 (S) % 43 53 29-112 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/02/2019 03:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 48 QUALITY CONTROL DATA Project: 2018-30571Melreese Golf Course Pace Project No.: 35455234 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 524362 Analysis Method: FL -PRO QC Batch Method: EPA 3546 Analysis Description: FL -PRO Soil Associated Lab Samples: 35455234001, 35455234002 METHOD BLANK: 2834752 Matrix: Solid Associated Lab Samples: 35455234001, 35455234002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Petroleum Range Organics mg/kg 2.6 U 4.0 2.6 03/21/19 02:46 N-Pentatriacontane (S) % 102 42-159 03/21/19 02:46 o-Terphenyl (S) % 107 66-136 03/21/19 02:46 LABORATORY CONTROL SAMPLE: 2834753 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Petroleum Range Organics N-Pentatriacontane (S) o-Terphenyl (S) mg/kg 203 187 92 65-119 106 42-159 105 66-136 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2834801 2834802 MS MSD 35455025001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Petroleum Range Organics mg/kg 2.9 U 228 228 177 183 78 81 39-181 4 25 N-Pentatriacontane (S) % 101 92 42-159 o-Terphenyl (S) % 105 94 66-136 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/02/2019 03:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 24 of 48 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35455234 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 524375 Analysis Method. FL -PRO QC Batch Method: EPA 3546 Analysis Description: FL -PRO Soil Associated Lab Samples: 35455234003, 35455234004, 35455234005 METHOD BLANK: 2834812 Matrix: Solid Associated Lab Samples: 35455234003, 35455234004, 35455234005 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Petroleum Range Organics mg/kg 2.5 U 3.9 2.5 03/21/19 21:34 N-Pentatriacontane (S) % 92 42-159 03/21/19 21:34 o-Terphenyl (S) % 90 66-136 03/21/1921:34 LABORATORY CONTROL SAMPLE: 2834813 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Petroleum Range Organics mg/kg 201 172 86 65-119 N-Pentatriacontane (S) % 102 42-159 o-Terphenyl (S) % 99 66-136 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2834816 2834817 MS MSD 35455024001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Petroleum Range Organics mg/kg 2.6 U 202 201 166 156 82 77 39-181 7 25 N-Pentatriacontane (S) % 95 89 42-159 o-Terphenyl(S) % 94 90 66-136 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/02/2019 03:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 25 of 48 77 Face Analytical wwwpacelabs.com QUALITY CONTROL DATA Project: 2018-30571Melreese Golf Course Pace Project No.: 35455234 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 525283 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 35455234001 SAMPLE DUPLICATE: 2840595 35455118001 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture % 8.6 9.9 14 10 J(D6) SAMPLE DUPLICATE: 2840596 35455131003 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 9.1 9.8 7 10 SAMPLE DUPLICATE: 2840597 35455131014 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 13.0 14.3 9 10 SAMPLE DUPLICATE: 2840598 35455831009 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture % 8.0 7.9 2 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/02/2019 03:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 26 of 48 �Jf ice Analytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35455234 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 525312 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 35455234002, 35455234003, 35455234004, 35455234005 SAMPLE DUPLICATE: 2840802 35454978035 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture % 5.4 2.5 74 10 J(D6) SAMPLE DUPLICATE: 2840803 35455113002 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture % 13.1 13.7 4 10 SAMPLE DUPLICATE: 2840804 35455494003 Dup Parameter Units Result Result Percent Moisture RPD Max RPD Qualifiers 7.3 7.4 2 10 ;AMPLE DUPLICATE: 2840805 35455494012 Dup Parameter Units Result Result RPD Percent Moisture Max RPD Qualifiers 9.9 10.3 4 10 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/02/2019 03:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 27 of 48 vnvw.pacelabs.com QUALIFIERS Project: 2018-30571Melreese Golf Course Pace Project No.: 35455234 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PAST-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. U Compound was analyzed for but not detected. J(D6) Estimated Value. The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. J(M1) Estimated Value. Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. J(R1) Estimated Value. RPD value was outside control limits. J(S0) Estimated Value. Surrogate recovery outside laboratory control limits. Date 04/02/2019 03 42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 28 of 48 aceAnalytical www.pacetabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melreese Golf Course Pace Project No.: 35455234 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Analytical QC Batch Method QC Batch Analytical Method Batch 35455234001 TE-9 (2-4) EPA 3546 524362 FL -PRO 35455234002 TE-14 (0-2) EPA 3546 524362 FL -PRO 524497 524497 35455234003 TE-24 (0-2) EPA 3546 524375 FL -PRO 524511 35455234004 TE-24 (2-4) EPA 3546 524375 FL -PRO 524511 35455234005 TE-19 (2-4) EPA 3546 524375 FL -PRO 524511 35455234001 TE-9 (2-4) EPA 3050 524676 EPA 6010 524729 35455234002 TE-14 (0-2) EPA 3050 524676 EPA 6010 524729 35455234003 TE-24 (0-2) EPA 3050 525212 EPA 6010 525359 35455234004 TE-24 (2-4) EPA 3050 524676 EPA 6010 524729 35455234005 TE-19 (2-4) EPA 3050 524676 EPA 6010 524729 35455234001 TE-9 (2-4) EPA 3010 527287 EPA 6010 527323 35455234002 TE-14 (0-2) EPA 3010 527287 EPA 6010 527323 35455234001 TE-9 (2-4) EPA 7471 524787 EPA 7471 525054 35455234002 TE-14 (0-2) EPA 7471 524787 EPA 7471 525054 35455234003 TE-24 (0-2) EPA 7471 525260 EPA 7471 525294 35455234004 TE-24 (2-4) EPA 7471 524787 EPA 7471 525054 15455234005 TE-19 (2-4) EPA 7471 524787 EPA 7471 525054 35455234001 TE-9 (2-4) EPA 3546 524361 EPA 8270 525010 35455234002 TE-14 (0-2) EPA 3546 524361 EPA 8270 525010 35455234003 TE-24 (0-2) EPA 3546 524361 EPA 8270 525010 35455234004 TE-24 (2-4) EPA 3546 524361 EPA 8270 525010 35455234005 TE-19 (2-4) EPA 3546 524363 EPA 8270 525199 35455234001 TE-9 (2-4) ASTM D2974-87 525283 35455234002 TE-14 (0-2) ASTM D2974-87 525312 35455234003 TE-24 (0-2) ASTM D2974-87 525312 35455234004 TE-24 (2-4) ASTM D2974-87 525312 35455234005 TE-19 (2-4) ASTM D2974-87 525312 Date: 04/02/2019 03:42 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 29 of 48 -FaceAnalytical WLVW.p3Cel'dhS.CDITI L WO# 111111111 35455234 : A 35 11 11 /� ��r 55 I ((���//III��� ,/ 34 "v Page Of - , g Container Type ...odes AV Mrnnr Vine ES Encoru S:.nnylcr p CV Clear Vint PPV Prepromovotl vial O P Amber PLC Plastic k.r our Ch AL Amber Ulm PL J Pluabc Jar CL Clear Liter Z Z'Plac iwp N AP Ambrrr Plastic TB Tedlar bug co CIS AG i nt Glasa WP Whirl pak CI - SJ Sall Jar G Gallon Jug °"'"` Tc Tenn -core PPV Prepravatv"d •nnl s /' C 1 11l1 Address: S YJ I/ All ,um; L c-1A, , Dr sample 1 J City: �l i aAl , I.0 5 State: FL- Zip: 33C) f TRC Matrix Codes �� 1 Q /' Attn: All I � � Y1n i V:L+t i 1 � l.y'Qt �l F.�dF '.t/P.v�rz i pH SD Solid Wa:I 0- 011 GW Ground Water SL Sludge EFF Effluent SO Sail Sediment AFW Anoka., Free H2e AO AQueoua WW Waste Water NANonnauuouc OW Drinking Water PE Petroleum SW Sonata Wobr G Oho( ML Misc. Llqultl n • ••^ r J email: yu, / nn 1 7 -L /�11 I''lJc-,..r, �+% e...-- kl. c Gr"Phone: J0J - )41- 1-'5Vv Pras Codes Project /y� / ,. c Name 1 +`�11�G�+ie GC:it Ca,,rse Proj # -- 1 U - 30.5 T Parameters EXAMPLE Dias. Lead 6010 Samp er Circle One Event: Daily Weekly Monthly Signatur / Ouartely Semi -Annual Annual N/A - Preservative T ype Codes A. None E. HCL I. Ice B. NNW F. McOH J. MCAA C. H2SO4 G. Na2S203 K. za Acetate D. NaOH H. NaHSO4 O. Other (Sample Sample ID Collect Date Collect Time Matrix Code' 32 is tom',. it et. . o `o c x a .8 •- 0 I- 8 `,; -T- co- J ..c.,_.) �' , -" # of Containers — Stzofrypo .4-- rrr--��� M 180zP REMARKS 1 _ T L--9 (2-i) 3/I`-f,; -. c) 5Q 6 i:1 Q ®. 29 ■ ■ ■ IN Arch., U C . (Cr 2 Tr i ) `j f t) -_ �iq/►� li ;o SO ( �� ■ �+ ■ ■ U ■ j ; �ese sa,w�le› 3Try �,«�>;//)c(i3'-iOso ( IA r. 0 ®, ® ■ n ❑ ■ 4 - "t(2-9) 77631j9 13;50 5Gl ( A ■ Z ■ X ■ ■ ■ ■ 5 Tr- 19t (`2--`1) 3)jg/,t It 50 So C fzi7 ill LSI I XI ❑ ■ ■ ■ 6 ■ II MI II III NI ■ IN■ 7 IN ■ ■ ■ ■ ❑ . IN IN 8 ■ ■ ■ ■ ■ ■ U ■ ❑ I g ■ ■ E ■ n ■ ■ ■ ❑ 10 GYCNTAT. ■ n ■ ■ ■ ❑ ■ ■ ❑ nEWEat ate, mum r®neunnal ease Short Hold Circle QA/QC Report Level PCoolers EDD (Fees May Apply) COC Condition Required so�te #'s - Temp °C C lJ N Today ID° 2D 3D 40 Y__ N 1 2 3 4 CLP AFCEE QAPP Ober ADaPT SEDD ERPIMS TSV CSV Other OK Inmmnl"lu FL GA SC NC NJ PA LA TX IL 2 3 4 5 Item Relinquished by Affiliation Date Time Received by1 riiation Dal __ Time N (, kit rn.l I d, 11 IN IACI upon .rr v:il-vet.-- Received on W"t Ice"? � ,...., Proper Pruwrvabvos Indicated? ._r_ — Received within holding umuT �/ —� We? CIISIWY:+IalG Intact? _ Vokroars roil without MmnuVacu7 Proper Cmtwlnur:: UsudT -5 r T G I:J �V �' , -sw � /( /!'1 1(, D /� 2 F l"�-�.I / 1 .3 I ! D� . �'!���./ e `' / /�� /f�// / j/f ( P �'I"l �, i i 1r : `3,/\(2 ` ' / 1 1, f / t. Li 1 1yJ ( 1('�•� j�y..., �j/ _ i�% 1 _ —1--) fT/ r �I Q Pmmnann 1 ah 9Sd_5R9.a3nn Lj o .. :_ . -err - .nn, m_.. f j�� 11 1 / J /' --t- l C.O.C. Serial # 1 y r 2 St 10,1,c a6Pd • kiE,_, t1111111111111 . '7iTwArff-WirfWfWMIZA74:1?1, Project KW:35455234 Project Manage! PM: CTR CLIENT: 36-EEG Client: Cooler #1 Temp.'C (Visual) Cooler #2 Temp.'C (Visual) Cooler #3 Temp.'C (Visual) Cooler #4 Temp.-C (Visual) Cooler #5 Teinp."C (Visual) Cooler #6 Temp.'C (Visual) Due Date: 03/25/19 D,— T z Correction Factor) . (Actual) (Correction Factor) (Actual) (Correction Factor) (Actual) (Correction Factor) (Actual) (Correction Factor) (Actual) (Correction Factor) (Actual) Courier: — Eel Ex — LIPS LISPS — — Shipping Method: x:.': :Y-:•• •H.,:•••••";'•• Billing: Tracking # Pac Date and Initials of person: Examining coin Label: Deliver: , pH: i•- 01,e• Custody Seal on Cooler/Box Present: Packing Material: jrr .* Samples shorted to lab (If Yes. complete) Sncrt.Fro D2'.2 Seals intact: Comments: ••••••"...Ces ' • ' 'x Nc N..: `.1.nLs", • '-••••-ir- Client Notification/ Resolution: Comments' Resolution (use back for additional comments): Da:e ace Analytical www.pacelabs.com Report Prepared for: Christina Raschke PASI Florida 8 East Tower Circle Ormond Beach FL 32174 REPORT OF LABORATORY ANALYSIS FOR PCDD/PCDF Report Prepared Date: April 1, 2019 Report No 10467622_8290FC_DFR Pace Analytical Services, LLC. 1700 Elm Street Minneapolis, MN 55414 Phone: 612.607.1700 Fax: 612.607.6444 Report Information: Pace Project #: 10467622 Sample Receipt Date: 03/21/2019 Client Project #: 35455234 Client Sub PO #: N/A State Cert #: E87605 Invoicing & Reporting Options: The report provided has been invoiced as a Level 2 PCDD/PCDF Report. [fan upgrade of this report package is requested, an additional charge may be applied. Please review the attached invoice for accuracy and forward any questions to Kirstcn Hogberg, your Pace Project Manager. This report has been reviewed by: Imo, April 02, 2019 Kirsten Hogberg, Project Manager (612) 607-6407 (612) 607-6444 (fax) kirsten.hogberg@pacelabs.com Report of Laboratory Analysis Th i sreportshouldno tbereproduced,except inful I, withoutt hewrittenconsento fPaceA nalyticalServices, inc Theresultsrelateonlyt othesamplesmcludedinthisreport. Page 32 of 48 Page 1 of 17 /72ce Analytical Pace Analytical Services, LLC. 1700 Elm Street Minneapolis, MN 55414 Phone: 612.607.1700 Fax: 612.607.6444 DISCUSSION This report presents the results from the analyses performed on five samples submitted by a representative of Pace Analytical Services, LLC. The samples were analyzed for the presence or absence of polychlorodibenzo-p-dioxins (PCDDs) and polychlorodibenzofurans (PCDFs) using a modified version of USEPA Method 8290. The reporting limits were based on signal-to-noise measurements. Estimated Maximum Possible Concentration (EMPC) values were treated as positives in the toxic equivalence calculations. Per request, estimated detection limit (EDL) values were provided and flagged "U" where the target analytes were not detected. Second column confirmation analyses of 2,3,7,8-TCDF values obtained from the primary (DB5-MS) column are performed only when specifically requested for a project and only when the values are above the concentration of the lowest calibration standard. Typical resolution for this isomer using the DB5-MS column ranges from 25-30%. The recoveries of the isotopically -labeled PCDD/PCDF internal standards in the sample extracts ranged from 44-94%. All of the labeled internal standard recoveries obtained for this project were within the 40-135% target range specified in Method 8290. Also, since the quantification of the native 2,3,7,8-substituted congeners was based on isotope dilution, the data were automatically corrected for recovery and accurate values were obtained. Values were flagged "I" where incorrect isotope ratios were obtained. Concentrations below the calibration range were flagged "J" and should be regarded as estimates. A laboratory method blank was prepared and analyzed with the sample batch as part of our routine quality control procedures. The results show that PCDDs and PCDFs were not detected. These results indicate that the sample preparation procedures did not significantly impact the results of the field sample determinations. A laboratory spike sample was also prepared with the sample batch using reference material that had been fortified with native standards. The recoveries of the spiked native compounds ranged from 88-113%. These results were within the target ranges for the method. Matrix spikes were prepared with the sample batch using sample material from a separate project; results from these analyses will be provided upon request. REPORT OF LABORATORYANALYSIS This report shall not be reproduced, except in full, withoutthewritten consent of Pace Analytical Services, Inc. Report No 10467622_8290FC_DFR Page 33 of 48 Page 2 of 17 Authority Minnesota Laboratory Certifications Certificate # Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612-607-6444 Authority Certificate # A2LA 2926.01 Alabama 40770 Alaska - DW MN00064 Alaska - UST 17-009 Arizona AZ0014 Arkansas - DW MN00064 Arkansas - WW 88-0680 CNMI Saipan MP0003 California 2929 Colorado MN00064 Connecticut PH-0256 EPA Region 8+ via MN 027-053 Florida (NELAP E87605 Georgia 959 Guam 17-001r Hawaii MN00064 Idaho MN00064 Illinois 200011 Indiana C-MN-01 Iowa 368 Kansas E-10167 Kentucky - DW 90062 Kentucky - WW 90062 Louisiana - DE 03086 Louisiana - DW MN00064 Maine MN00064 Maryland 322 Massachusetts M-MN064 Michigan 9909 Minnesota 027-053-137 Minnesota - De via MN 027-053 Minnesota - Pet 1240 Mississippi MN00064 Missouri - DW 10100 Montana CERT0092 Nebraska NE-OS-18-06 Nevada MN00064 New Hampshire 2081 New Jersey (NE MN002 New York 11647 North Carolina 27700 North Carolina - 27700 North Carolina - 530 North Dakota R-036 Ohio - DW 41244 Ohio - VAP CL101 Oklahoma 9507 Oregon - Primar MN300001 Oregon - Secon MN200001 Pennsylvania 68-00563 Puerto Rico MN00064 South Carolina 74003 South Dakota NA Tennessee TN02818 Texas T104704192 Utah (NELAP) MN00064 Virginia 460163 Washington C486 West Virginia - 382 West Virginia - 9952C Wisconsin 999407970 Wyoming - UST 2926.01 REPORT OF LABORATORYANALYSIS This report shall not be reproduced, except in full. without the written consent of Pace Analytical Services, Inc. Report No 10467622_8290FC_DFR Report No 10467622 Page 34 of 48 Page 3 of 17 Appendix A Sample Management Report No 10467622_8290FC_de Analytical Services, Inc. Page 35 of 48 Page 4 of 17 Ja OdO6Z8 ZZ9/9170L- oN pod Chain of Custody i Samples were sent directly to the Subcontracting Laboratory. Workorder: 35455234 Workorder Narne: Melreese Golf Course 2018-3057 State Of Origin: FL Cert. Needed: Yes Owner Received Date: No 3/18/2019 ceArtalyt .a! wu+rneearaua-zom Results Requested By: 3/25/2019 Christina Raschke Pace Analytical South Florida 3610 Park Central Blvd N Pompano Beach, FL 33064 Phone (954)582-4300 Pace Analytical Minnesota 1700 Elm Street SE Suite 200 Minneapolis, MN 55414 Phone (612)607-1700 ■ Ell E-9 (2-4) E-14 (0-2) PS E-24 (0-2) E-24 (2-4) E-19 (2-4) Ps PS PS PS 3/18/2019 08:10 3/18/2019 11:30 3/18/2019 13:40 3/18/2019 13:50 3/18/2019 14:50 35455234001 35455234002 35455234003 35455234004 Solid Solid Solid 35455234005 Solid Solid woa:smaeisn 11111111 II II 101111111 E11■■■■©IEEE■■■MINE ■■■��■ON■■■■NNE■■■ IIIMIIIMM112111111111111111111MNIMMIIIIMMIll iimmommummunnummErnami Transfers Released By Date/Time eceived By Date/Time 1 2 3 Cooler Tern • erature on Recei • t Z. 'C Custod Seal or N Received on Ice or N order to maintain client confidentiality, location/name of the sampling site, sampler's name and signature may not be provided on this COC docume r' This chain of custody is considered complete as is since this information is available in the owner laboratory. o Wednesday, March 20, 2019 3:58:58 PM A CO FMT-ALL-C-002rev.00 24March2009 Page 1 of 1 l en aCeAnalytical Document Name: Sample Condition Upon Receipt Form Document Revised: O6Feb2O19 Page 1 of 1 Document No.: F-MN-L-213-rev.25 Issuing Authority: Pace Minnesota Quality Office Sample Condition Upon Receipt Courier: Tracking Number: Client Name: Fed Ex ❑UPS ❑LISPS ❑Client Pace ❑SpeeDee ['Commercial See Exception c., • jl1.i/i �9 ' l i (�I ? l it (156i1 ❑ Project #: Custody Seal on Cooler/Box Present? ®Yes ❑No Seals Intact? Packing Material: ['Bubble Wrap ®Bubble Bags ❑None ❑Other: Thermometer: ❑ G87A9155100842 G87A9170600254 Type of ice: DINvet Note: Each West Virginia Sample must have temp taken (no temp blanks) Won :10467622 PM: KNH Due Date: @ /@4/19 CLIENT: PRSI—FL s UNo Biological Tissue Frozen? ❑Yes No I23N/A Temp Blank? ©Yes ❑No ['Blue ❑None Dry ❑Melted I Temp should be above freezing to 6°C Cooler Temp Read w/temp blank: •2 • °C Correction Factor: -O. 1 Cooler Temp Corrected w/temp blank : °C Average Corrected Temp See Exceptions (no temp blank only): ❑ oC t USDA Regulated Soil: (u3 N/A, water sample/Other: ) Date/Initials of Person Examining Contents: (If, J Did samples originate in a quarantine zone within the United States: AL, AR, CAA GA, Did samples originate from a foreign source (internationally, including ID; LA. MS, NC, NM, NY, OK, OR, SC, TN, TX or VA (check maps)? 2)Yes ❑No Hawaii and Puerto Rico)? ['Yes J1No If Yes to either question, fill out a Regulated Soil Checklist (F-MN-Q-338) and include with SCUR/COC paperwork. COMMENTS: Chain of Custody Present and Filled Out? Rives DM) 1. Chain of Custody Relinquished? Rives ❑No 2. Sampler Name and/or Signature on COC? ❑Yes ❑No ®N/A 3. Samples Arrived within Hold Time? [Yes ❑No 4. Short Hold Time Analysis (<72 hr)? ['Yes JANo 5. ❑Fecal Coliform ❑HPC ❑Total Coliform/E coli ❑ BOD/cBOD ❑Hex Chrome ['Turbidity ❑Nitrate ['Nitrite ❑Orthophos ❑Other Rush Turn Around Time Requested? (5]Yes ONO b. ,ufficient Volume? (Ives ❑No 7. Correct Containers Used? -Pace Containers Used? ( 1Yes Yes ❑No ❑No 8 Containers Intact? ®Yes ❑No 9. Field Filtered Volume Received for Dissolved Tests? ❑ves DNo .❑N/A 10. Is sediment visible in the dissolved container? • Yes ❑No Is sufficient information available to reconcile the samples to the COC? Matrix: ❑Water, )Soil ❑Oil ['Other j$JYes ❑No 11. If no, write ID/ Date/Time on Container Below: See Exception ■ All containers needing acid/base preservation have been checked? All containers needing preservation are found to be in compliance with EPA recommendation? (HNO3, H2SO4, 2pH, NaOH>9 Sulfide, NaO1-1>12 Cyanide) Exceptions: VOA, Coliform, TOC/DOC Oil and Grease, DRO/8015 (water) and Dioxin/PEAS ❑Yes Dyes ❑Yes ❑No Ono ❑No (y]N/A ®N/A ®N/A 12. Sample # • NaOH ❑ HNO3 ■ HzSOa ❑Zinc Acetate Positive for Res. • Yes See Exception Chlorine? • No ❑ Headspace in VOA Vials (greater than 6mm)? ['Yes ❑No ®N/A 13. See Exception M Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes Des ❑No ❑No IZIN/A J❑C N/A 14. /%t1 Pace Trip Blank Lot # (If purchased): is )/J-\ CLIENT NOTIFICATION/RESOLUTION Person Contacted: Comments/Resolution: Method 8290 required. Date/Time: Field Data Required? ❑Yes No Project Manager Review: Note: Whenever there is a discrepancy off ting Carolina com hold, Incorrect preservative, out of temp, incorrect containers). Date: 3/99/201 C) nce spies, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( i.e out of Labeled by: Report No 10467622_8290FC_DFR Page 37 of 48 Page 6 of 17 § ,, PaceAnalyticai Document Name: Regulated Soil Checklist Document Revised; 13Feb201a Page 1 of 2 Document No.: F-MN-Q-338-Rev.06 Issuing Authority: Pace Minnesota Quality Office USDA REGULATED SOIL CHECKLIST To Be Completed by SR Staff: WO: 10467622 Date: 3/ Sample Origin (circle one): DOMESTIC % QUARANTINED (Note: soil samples from Howaii, Guam, Puerto Rico and the US Virgin islands are considered to be of a Foreign Source) If Domestic, circle State of Origin: AL AR CA FI_ )GA LA MS NC NM NY OK OR SC TN TX VA Initials: (Includes: 1FA, SOD, Golden Nematode, Karnal Bunt and Witchweed) List County: FOREIGN (USDA Permit/Compliance Agreement authorizes movement of samples from these domestic regulated zones) If Quarantined, circle State of Origin: FL ID TX CA List County: (includes Fruit Fly, Giant African Snail and Pale Cyst Nematode) (Movement is not authorized for Pale Cyst Nematode (ID or Giant African Snail ]FL], remaining quarantines require additional paperwork) If Foreign, list Country of Origin: (Movement from some Canadian Providences is not allowed. Refer to CS-232 Regulated Soil Flow Chart) REQUIREMENT ACTION COMPLETED PPQ-530 Paperwork must be included for any samples from counties with a Fruit Fly Quarantine in TX. Refer to MN-5063 through MN-S065 Scan PPQ-530 to the corresponding Project folder on the x drive. If PPQ-530 is not present, contact the Waste Coordinator and do not continue processing samples. "— YES NO N/AJ �1e,A Samples from ID may not be moved from the quarantined region. Refer to MN-S055 If samples originated in a quarantined zone, contact the Waste Coordinator and do not continue processing samples. YES NO N/A ) Samples from Giant African Snail Quarantine in FL may not be moved from the quarantined region. Refer to MN-5068 if samples originated in a quarantined zone, contact the Waste Coordinator and do not continue processing samples. YES NO N/A REQUIREMENT ACTION PLETED "Special Handling" stickers are to be placed on all samples. Did "special handling" stickers get placed on all sample containers? YES NO Samples must be segregated and stored in designated bins, shelves and coolers. Were samples placed in a designated cooler, containers and shelves? YES ? NO Samples must be double contained to prevent accidental release. Were there any signs of breakage or leakage (check for broken glass and/or loose soil in the cooler)? If NO, ice and melt water can be disposed of by normal process (down YES NO j the drain). _ p� If YES, were ice and melt water separated from the cooler and disposed of properly? Any broken glass and/or loose soil are to be bagged and placed in a container or active drum isee Waste Coordinator). Ice and melt water should be baked at a temperature range of 121-154°F cooled before going down the drain. / YES NO ( N/A 111 USDA Regulated satellite for 2 hours and then Equipment and supplies that have come into contact samples must be decontaminated. Was the cooler(s) and/or countertop(s) decontaminated using either a fresh 10% bleach solution or 70% ethanol? (Gloves and other lab supplies will be bagged and placed in the USDA Regulated satellite container or active drum). ' a YES I NO a Comments: Report No 10467622_8290FC_DFR Page 38 of 48 Page 7 of 17 4''Fri. FaceAnalytical n Document Name: Regulated Soil Checklist Document No.: F-M N-Q-338-Rev.05 Document Revised: 20Jan2017 Page 2 of 2 Issuing Authority: Pace Minnesota Quality Office To Be Completed by PM and/or PC: Sample Analysis to be conducted (circle all that apply): Name of Subcontract Lab (s): MN Subcontract Lab REQUIREMENT ACTION COMPLETED Permission to ship untreated soil must be .. on file prior to shipping to any subcontract lab, including IR Pace Labs. Go to: J:\SHARE\PR1_MGR\10_Client Services Department Documents\ Regulated Soils Permits — if permission to ship letter is not there, contact the Waste Coordinator. YES NO N/A Shipment must include a valid copy of the receiving lab's permit as well as permission to ship letter. Is a copy of all needed paperwork included with the COC? Do NOT ship samples until all necessary paperwork is compiled. YES NO N/A Comments: Project Manager Signature: Gw- Report No 104676228290FC_DFR Date: 3/22/2019 Page 39 of 48 Page8of17 TM ace Analytical Reporting Flags Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 A = Reporting Limit based on signal to noise B = Less than 10x higher than method blank level C = Result obtained from confirmation analysis D = Result obtained from analysis of diluted sample E = Exceeds calibration range I = Interferencepresent J = Estimated value L = Suppressive interference, analyte may be biased low Nn = Value obtained from additional analysis P = PCDElnterference R = Recovery outside target range S = Peak saturated U = Analyte not detected V = Result verified by confirmation analysis X = %D Exceeds limits Y = Calculated using average of daily RFs * = SeeDiscussion REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services. Inc. Report No 10467622_8290FC_DFR Page 9 of 17 Tel: 612-607-1700 Fax: 612-607-6444 Report No 10467622 Page 40 of 48 Appendix B Sample Analysis Summary Report No 10467622_8290FC_e Analytical Services, Inc. Page 41 of 48 Page 10 of 17 TM aceAnalytical Metho d 8290 Sample Analysis Results Client - PASI Florida Client's Sample ID TE-9 (2-4) Lab Sample ID 35455234001 Filename F190331A_11 Injected By JRH Total Amount Extracted 14.1 g % Moisture 27.2 Dry Weight Extracted 10.3 g ICAL ID F190112 CCaI Filename(s) F190330A_18 & Method Blank ID BLANK-69386 Native Isomers 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD Conc EMPC ng/Kg ng/Kg 4.3 41 1.5 91 0.79 1.2 15 4.6 46 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 4.5 2,3,4,6,7,8-HxCDF 1.4 1,2,3,7,8,9-HxCDF 0.24 U Total HxCDF 39 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 3.7 14 11 160 71 0.75 U 71 1,2,3,4,6,7,8-HpCDD 370 Total HpCDD 780 OCDF OCDD 39 3400 0.91 Matrix Dilution Collected Received F190331A_17 Extracted Analyzed Internal Standards EDL ng/Kg Pace Analytical Services, LLC 1 /00 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 512- 607-6444 Solid NA 03/18/2019 08:10 03/21/2019 09:25 03/27/2019 16:05 03/31/2019 07:03 0.71 2,3,7,8-TCDF-13C 0.71 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 0.44 2,3,4,7,8-PeCDF-13C 0.44 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 0.45 J 1,2,3,6,7,8-HxCDF-13C 0.22 J 2,3,4,6,7,8-HxCDF-13C 0.33 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 0.44 J 1,2,3,6,7,8-HxCDD-13C 0.44 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 0.28 IJ 0.26 J 0.24 J 0.24 0.25 0.29 J 0.30 0.24 0.28 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 ng's Percent Added Recovery 2.00 65 2.00 71 2.00 64 2.00 64 2.00 75 2.00 64 2.00 69 2.00 68 2.00 60 2.00 67 2.00 64 2.00 51 2.00 48 2.00 56 4.00 44 2.00 NA 2.00 NA 0.20 75 0.47 Total 2,3,7,8-TCDD 0.75 Equivalence: 16 ng/Kg 0.61 (Lower -bound - Using ITE Factors) 0.82 0.82 0.36 0.90 Conc = Concentration (Totals include 2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit ND = Not Detected NA = Not Applicable NC = Not Calculated Results reported on a dry weight basis and are valid to no more than 2 significant figures. J = Estimated value I = Interference present REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full.. without the written consent of Pace Analytical Services. Inc. Report No 10467622_8290FC_DFR Page 11 of 17 Page 42 of 48 ace Analytical Client's Sample ID Lab Sample ID Filename Injected By Total Amount Extracted % Moisture Dry Weight Extracted ICAL ID CCal Filename(s) Method Blank ID Native Isomers 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD TM Method 8290 Sample Analysis Results Client - PASI Florida TE-14 (0-2) 35455234002 F190331A_12 JRH 12.3 g 17.7 10.1 g F190112 F190330A_18 & BLANK-69386 Conc EMPC ng/Kg ng/Kg 0.90 U 0.90 U 0.70 U 6.8 0.32 U 0.36 4.0 0.50 U 2.5 0.45 0.14 U 8.3 1.5 7.2 4.9 63 0.46 0.46 Matrix Dilution Collected Received F190331A_17 Extracted Analyzed EDL Internal ng/Kg Standards 0.90 2,3,7,8-TCDF-13C 0.90 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 0.70 2,3,4,7,8-PeCDF-13C 0.70 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 0.32 1,2,3,6,7,8-HxCDF-13C 0.27 J 2,3,4,6,7,8-HxCDF-13C 0.30 J 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 0.50 1,2,3,6,7, 8-HxCDD-13C 0.50 J 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 0.25 J 0.26 IJ 0.13 IJ 0.14 0.20 0.26 J 0.29 0.29 J 0.28 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax:612-607-6444 Solid NA 03/18/2019 11:30 03/21/2019 09:25 03/27/2019 16:05 03/31/2019 07:47 ng's Percent Added Recovery 2.00 64 2.00 70 2.00 68 2.00 69 2.00 85 2.00 65 2.00 68 2.00 69 2.00 67 2.00 70 2.00 69 2.00 62 2.00 64 2.00 71 4.00 66 2.00 NA 2.00 NA 0.20 72 8.6 0.21 Total 2,3,7,8-TCDD 0.30 U 0.30 Equivalence: 4.7 ng/Kg 12 0.25 (Lower -bound - Using ITE Factors) 190 0.83 350 0.83 18 0.55 960 0.73 Conc = Concentration (Totals include 2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit ND = Not Detected NA = Not Applicable NC = Not Calculated Results reported on a dry weight basis and are valid to no more than 2 significant figures. J = Estimated value 1= Interference present REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of PaceAnalytical Services, Inc. Report No 10467622_8290FC_DFR Page 43 of 48 Page 12 of 17 ace Analytical Client's Sample ID Lab Sample ID Filename Injected By Total Amount Extracted % Moisture Dry Weight Extracted ICAL ID CCaI Filename(s) Method Blank ID Native Isomers TM Metho d 8290 Sample Analysis Results Client - PASI Florida TE-24 (0-2) 35455234003 F190331A_13 JRH 10.6g 5.6 10.0 g F190112 F190330A_18 & BLANK-69386 Conc EMPC EDL ng/Kg ng/Kg ng/Kg Matrix Dilution Collected Received F190331A_17 Extracted Analyzed Internal Standards Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612- 607-6444 Solid NA 03/18/2019 13:40 03/21/2019 09:25 03/27/2019 16:05 03/31/2019 08:30 2,3,7,8-TCDF 0.97 Total TCDF 14 2,3,7,8-TCDD 0.36 U Total TCDD 12 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 0.62 U 1.6 16 1.5 9.4 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 1.4 2,3,4,6,7,8-HxCDF 1.5 1,2,3,7,8,9-HxCDF 0.22 U Total HxCDF 19 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD 1.5 5.7 4.3 68 14 1.1 33 1.5 0.57 J 2,3,7,8-TCDF-13C 0.57 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 0.36 2,3,4,7,8-PeCDF-13C 0.36 1, 2, 3, 7, 8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 0.62 1,2,3,6,7,8-HxCDF-13C 0.13 J 2,3,4,6,7,8-HxCDF-13C 0.37 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 0.48 J 1,2,3,6,7,8-HxCDD-13C 0.48 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 0.21 IJ 0.20 J 0.11 J 0.22 0.19 0.20 J 0.23 0.10 J 0.18 0.095 0.16 J 0.13 150 0.63 280 0.63 24 0.53 1200 0.70 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 ng's Percent Added Recovery 2.00 66 2.00 72 2.00 72 2.00 70 2.00 87 2.00 66 2.00 71 2.00 74 2.00 67 2.00 73 2.00 72 2.00 65 2.00 64 2.00 74 4.00 64 2.00 NA 2.00 NA 0.20 71 Total 2, 3, 7, 8-TC D D Equivalence: 6.1 ng/Kg (Lower -bound - Using ITE Factors) Conc = Concentration (Totals include 2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit ND = Not Detected NA = Not Applicable NC = Not Calculated Results reported on a dry weight basis and are valid to no more than 2 significant figures. J = Estimated value I = Interference present REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10467622_8290FC_DFR Page 44 of 48 Page 13 of 17 ace Analytical Client's Sample ID Lab Sample ID Filename Injected By Total Amount Extracted % Moisture Dry Weight Extracted ICAL ID CCaI Filename(s) Method Blank ID Native Isomers Tra Method 8290 Sample Analysis Results Client - PASI Flonda TE-24 (2-4) 35455234004 F190331A_14 JRH 11.8 g 15.1 10.0 g F190112 F190330A_18 & BLANK-69386 Conc EMPC EDL ng/Kg ng/Kg ng/Kg Matrix Dilution Collected Received F190331A_17 Extracted Analyzed Internal Standards Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612- 607-6444 Solid NA 03/18/2019 13:50 03/21/2019 09:25 03/27/2019 16:05 03/31/2019 09:13 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD 0.81 U 0.81 2,3,7,8-TCDF-13C 0.81 U 0.81 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 0.76 U 0.76 2,3,4,7,8-PeCDF-13C 4.5 0.76 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 0.49 U 0.49 1,2,3,6,7,8-HxCDF-13C 0.61 0.35 J 2,3,4,6,7,8-HxCDF-13C 2.2 0.42 J 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 0.45 U 0.45 1,2,3,6,7,8-HxCDD-13C 0.45 U 0.45 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 0.48 0.45 0.65 0.17 U 6.7 0.38 1.5 1.1 16 0.23 J 0.33 J 0.16 J 0.17 0.22 0.17 IJ 0.24 IJ 0.15 J 0.18 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 ng's Percent Added Recovery 2.00 69 2.00 76 2.00 77 2.00 76 2.00 94 2.00 68 2.00 73 2.00 77 2.00 70 2.00 78 2.00 73 2.00 73 2.00 71 2.00 83 4.00 73 2.00 NA 2.00 NA 0.20 71 5.5 0.13 Total 2,3,7,8-TCDD 0.46 U 0.46 Equivalence: 1.7 ng/Kg 14 0.30 (Lower -bound - Using ITE Factors) 44 0.12 87 0.12 11 0.59 430 1.1 Conc = Concentration (Totals include 2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL= Estimated Detection Limit ND = Not Detected NA = Not Applicable NC = Not Calculated Results reported on a dry weight basis and are valid to no more than 2 significant figures. J = Estimated value I = Interference present REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without thewritten consentof Pace Analytical Services, Inc. Report No 10467622_8290FC_DFR Page 45 of 48 Page 14 of 17 ace Analytical Client's Sample ID Lab Sample ID Filename Injected By Total Amount Extracted % Moisture Dry Weight Extracted ICAL ID CCal Filename(s) Method Blank ID Native Isomers TM Metho d 8290 Sample Analysis Results Client - PASI Florida TE-19 (2-4) 35455234005 F190331A_15 JRH 11.2g 7.4 10.4 g F190112 F190330A_18 & BLANK-69386 Conc ng/Kg EMPC EDL ng/Kg ng/Kg Matrix Dilution Collected Received F190331A_17 Extracted Analyzed Internal Standards Pace Analytical Services, LLC 1700 Flm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612- 607-6444 Solid NA 03/18/2019 14:50 03/21/2019 09:25 03/27/2019 16:05 03/31/2019 09:56 2,3,7,8-TCDF 1.2 Total TCDF 11 2,3,7,8-TCDD Total TCDD 0.79 U 45 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF 1.0 Total PeCDF 14 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD 2.0 19 0.55 1.2 11 1.8 7.3 5.0 84 5.2 19 190 370 13 1200 0.69 0.95 0.32 0.81 0.80 0.80 0.79 0.79 0.32 IJ 0.23 J 0.27 0.49 J 0.49 0.36 0.23 0.19 0.096 0.22 J J IJ IJ 0.25 J 0.24 0.31 0.27 0.19 0.17 IJ 0.18 0.79 0.79 0.33 0.26 2,3,7,8-TCDF-13C 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 2,3,4,7,8-PeCDF-13C 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 1,2,3,6,7,8-HxCDF-13C 2,3,4,6, 7,8-HxCDF-13C 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 1,2,3,6,7,8-HxCDD-13C 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 Total 2,3,7,8-TCDD Equivalence: 6.5 ng/Kg (Lower -bound - Using ITE ng's Percent Added Recovery 2.00 67 2.00 73 2.00 74 2.00 76 2.00 92 2.00 67 2.00 69 2.00 71 2.00 67 2.00 71 2.00 70 2.00 65 2.00 66 2.00 74 4.00 68 2.00 NA 2.00 NA 0.20 69 Factors) Conc = Concentration (Totals include 2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit ND = Not Detected NA = Not Applicable NC = Not Calculated Results reported on a dry weight basis and are valid to no more than 2 significant figures. J = Estimated value I= Interference present REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10467622_8290FC_DFR Page 15 of 17 Page 46 of 48 aceAnalytical r Lab Sample Name Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) Native Isomers 2,3,7,8-TCDF Total TCDF Method 8290 Blank Analysis Results DFBLKIL BLANK-69386 F190330A_13 10.9 g F190112 F190330A_01 & F190330A_18 Conc EMPC EDL ng/Kg ng/Kg ng/Kg 0.26 U 0.26 0.26 U 0.26 2,3,7,8-TCDD 0.36 U 0.36 Total TCDD 0.36 U 0.36 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 0.22 U 0.14 U 0.18 U 0.22 0.14 0.18 1,2,3,7,8-PeCDD 0.27 U 0.27 Total PeCDD 0.27 U 0.27 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 0.16 U 0.18 U 0.15 U 0.22 U 0.18 U 0.31 U 0.24 U 0.27 U 0.27 U 0.16 0.18 0.15 0.22 0.18 0.31 0.24 0.27 0.27 Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax:612-607-6444 Matrix Solid Dilution NA Extracted 03/27/2019 16:05 Analyzed 03/30/2019 19:35 Injected By BAL Internal Standards 2,3,7,8-TCDF-13C 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 2,3,4,7,8-PeCDF-13C 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 1,2,3,6,7,8-HxCDF-13C 2,3,4,6,7,8-HxCDF-13C 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 1,2,3,6,7,8-HxCDD-13C 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 ng's Percent Added Recovery 2.00 57 2.00 64 2.00 70 2.00 70 2.00 85 2.00 65 2.00 69 2.00 69 2.00 59 200 69 2.00 66 2.00 65 2.00 59 2.00 68 4.00 60 2.00 NA 2.00 NA 0.20 62 0.11 U 0.11 Total 2,3,7,8-TCDD 0.20 U 0.20 Equivalence: 0.00 ng/Kg 0.15 U 0.15 (Lower -bound - Using ITE Factors) 1,2,3,4,6,7,8-HpCDD 0.26 U 0.26 Total HpCDD 0.26 U 0.26 OCDF 0.56 U 0.56 OCDD 0.69 U 0.69 Conc= Concentration (Totalsinclude2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit Results reported on a total weight basis and are valid to no more than 2 significant figures. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10467622_8290FC_DFR Page 47 of 48 Page 16 of 17 TM ace Analytical Method Method 8290 Laboratory Control Spike Results Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612- 607-6444 Lab Sample ID LCS-69387 Filename F190330A_06 Matrix Solid Total Amount Extracted 10.0 g Dilution NA ICAL ID F190112 Extracted 03/27/2019 16:05 CCaI Filename(s) F190330A_01 & F190330A_18 Analyzed 03/30/2019 14:33 Method Blank ID BLANK-69386 Injected By BAL Native Qs Qm % Internal ng's Percent Isomers (ng) (ng) Rec. Standards Added Recovery 2,3,7,8-TCDF 0.20 0.21 106 2,3,7,8-TCDF-13C 2.0 68 Total TCDF 2,3,7,8-TCDD-13C 2.0 72 1,2,3,7,8-PeCDF-13C 2.0 83 2,3,7,8-TCDD 0.20 0.21 104 2,3,4,7,8-PeCDF-13C 2.0 84 Total TCDD 1,2,3,7,8-PeCDD-13C 2.0 107 1,2,3,4,7,8-HxCDF-13C 2.0 71 1,2,3,7,8-PeCDF 1.0 1.0 102 1,2,3,6,7,8-HxCDF-13C 2.0 76 2,3,4,7,8-PeCDF 1.0 1.0 104 2,3,4,6,7,8-HxCDF-13C 2.0 78 Total PeCDF 1,2,3,7,8,9-HxCDF-13C 2.0 70 1,2,3,4,7,8-HxCDD-13C 2.0 75 1,2,3,7,8-PeCDD 1.0 0.88 88 1,2,3,6,7,8-HxCDD-13C 2.0 74 Total PeCDD 1,2,3,4,6,7,8-HpCDF-13C 2.0 78 1,2,3,4,7,8,9-HpCDF-13C 2.0 74 1,2,3,4,7,8-HxCDF 1.0 1.1 107 1,2,3,4,6,7,8-HpCDD-13C 2.0 85 1,2,3,6,7,8-HxCDF 1.0 1.0 102 OCDD-13C 4.0 76 2,3,4,6,7,8-HxCDF 1.0 0.98 98 1,2,3,7,8,9-HxCDF 1.0 0.98 98 1,2,3,4-TCDD-13C 2.0 NA Total HxCDF 1,2,3,7,8,9-HxCDD-13C 2.0 NA 1,2,3,4,7,8-HxCDD 1.0 1.0 105 2,3,7,8-TCDD-37CI4 0.20 68 1,2,3,6,7,8-HxCDD 1.0 1.1 113 1,2,3,7,8,9-HxCDD 1.0 1.0 104 Total HxCDD 1,2,3,4,6,7,8-HpCDF 1.0 1.0 105 1,2,3,4,7,8,9-HpCDF 1.0 0.97 97 Total HpCDF 1,2,3,4,6,7,8-HpCDD 1.0 0.94 94 Total HpCDD OCDF 2.0 1.8 91 OCDD 2.0 2.0 101 Qs = Quantity Spiked Qm = Quantity Measured Rec. = Recovery (Expressed as Percent) R = Recovery outside of target range Y = RF averaging used in calculations Nn = Value obtained from additional analysis NA = Not Applicable = See Discussion REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services. Inc. Report No 10467622_8290FC_DFR Page 17 of 17 Page 48 of 48 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 April 10, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35454205 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 14, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Kelsey Cortina, EE&G Environmental Solutions, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 44 /2ceAnalytical® wwwpacelabs.com CERTIFICATIONS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35454205 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL33064 954-582-4300 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alaska DEC- CS/UST/LUST Alabama Certification #: 41320 Arizona Certification# AZ0819 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 44 aceAnalytical wwwpace/abs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35454205 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35454205001 TE-29 (0-1') Solid 03/13/19 08:40 03/14/19 16:00 35454205002 TE-13 Debris (2-4') Solid 03/13/19 13:00 03/14/19 16:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 44 aceAnalytical www.pacelabs.com SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course Pace Project No.: 35454205 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35454205001 TE-29 (0-1') 35454205002 TE-13 Debris (2-4') FL -PRO RJR 3 PASI-O EPA6010 SC1 7 PASI-O EPA 7471 AMS 1 PASI-O EPA 8270 TWB 21 PASI-O ASTM D2974-87 CLT 1 PASI-O FL -PRO RJR 3 PASI-O EPA6010 LEC, SC1 7 PASI-O EPA 6010 LEC 1 PASI-0 EPA 7471 AMS 1 PASI-O EPA 8270 TWB 21 PASI-O ASTM D2974-87 CLT 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 44 aceAnalytical www pacelabs.com SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35454205 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35454205001 TE-29 (0-1') FL -PRO Petroleum Range Organics 52.3 mg/kg 5.7 03/18/19 22:18 EPA 6010 Arsenic 47.6 mg/kg 0.64 03/22/19 17:57 EPA 6010 Barium 14.4 mg/kg 0.64 03/22/19 17:57 EPA 6010 Cadmium 0.44 mg/kg 0.064 03/22/19 17:57 EPA 6010 Chromium 13.6 mg/kg 0.32 03/22/19 17:57 EPA 6010 Lead 28.7 mg/kg 0.64 03/22/19 17:57 EPA 6010 Selenium 0.56 I mg/kg 0.97 03/22/19 17:57 EPA 6010 Silver 0.35 mg/kg 0.32 03/22/19 17:57 EPA 7471 Mercury 0.024 mg/kg 0.0094 03/20/19 13:46 EPA8270 Benzo(a)anthracene 0.015 I mg/kg 0.047 03/21/19 16:19 EPA 8270 Benzo(b)fluoranthene 0.017 I mg/kg 0.047 03/21/19 16:19 ASTM D2974-87 Percent Moisture 28.0 % 0.10 03/19/19 10:43 35454205002 TE-13 Debris (2-4') EPA 6010 Arsenic 9.7 mg/kg 0.85 03/22/19 18:00 EPA 6010 Barium 65.6 mg/kg 0.85 03/22/19 18:00 EPA 6010 Cadmium 1.2 mg/kg 0.085 03/22/19 18:00 EPA 6010 Chromium 33.9 mg/kg 0.42 03/22/19 18:00 EPA 6010 Lead 202 mg/kg 4.2 03/25/19 14:46 EPA 6010 Silver 0.98 mg/kg 0.42 03/22/19 18:00 _PA 7471 Mercury 0.14 mg/kg 0.014 03/20/19 16:39 EPA 8270 Benzo(a)anthracene 0.020 1 mg/kg 0.047 03/20/19 09:05 EPA 8270 Benzo(a)pyrene 0.014 1 mg/kg 0.047 03/20/19 09:05 EPA 8270 Benzo(b)fluoranthene 0.021 1 mg/kg 0.047 03/20/19 09:05 EPA 8270 Fluoranthene 0.019 1 mg/kg 0.047 03/20/19 09:05 EPA 8270 Naphthalene 0.021 1 mg/kg 0.049 03/20/19 09:05 EPA 8270 Pyrene 0.019 1 mg/kg 0.047 03/20/19 09:05 ASTM D2974-87 Percent Moisture 27.1 % 0.10 03/19/19 10:43 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 44 ceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35454205 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: TE-29 (0-1') Lab ID: 35454205001 Collected: 03/13/19 08:40 Received: 03/14/19 16:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual FL -PRO Soil Microwave Analytical Method: FL -PRO Preparation Method: EPA 3546 Petroleum Range Organics 52.3 mg/kg 5.7 3.6 1 03/16/19 01:11 03/18/19 22:18 Surrogates o-Terphenyl (S) 94 % 66-136 1 03/16/19 01:11 03/18/19 22:18 84-15-1 N-Pentatriacontane (S) 93 % 42-159 1 03/16/19 01:11 03/18/19 22:18 630-07-09 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Arsenic 47.6 mg/kg 0.64 0.32 1 03/20/19 11:56 03/22/19 17:57 7440-38-2 Barium 14.4 mg/kg 0.64 0.32 1 03/20/19 11:56 03/22/19 17:57 7440-39-3 Cadmium 0.44 mg/kg 0.064 0.032 1 03/20/19 11:56 03/22/19 17:57 7440-43-9 Chromium 13.6 mg/kg 0.32 0.16 1 03/20/19 11:56 03/22/19 17:57 7440-47-3 Lead 28.7 mg/kg 0.64 0.32 1 03/20/19 11:56 03/22/19 17:57 7439-92-1 Selenium 0.56 I mg/kg 0.97 0.48 1 03/20/19 11:56 03/22/19 17:57 7782-49-2 Silver 0.35 mg/kg 0.32 0.16 1 03/20/19 11:56 03/22/19 17:57 7440-22-4 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.024 mg/kg 0.0094 0.0047 1 03/19/19 17:50 03/20/19 13:46 7439-97-6 8270 MSSV Short List Microwave Analytical Method: EPA 8270 Preparation Method: EPA 3546 Acenaphthene 0.016 U mg/kg 0.050 0.016 1 03/20/19 21:22 03/21/19 16:19 83-32-9 Acenaphthylene 0.015 U mg/kg 0.047 0.015 1 03/20/19 21:22 03/21/19 16:19 208-96-8 Anthracene 0.016 U mg/kg 0.050 0.016 1 03/20/19 21:22 03/21/19 16:19 120-12-7 Benzo(a)anthracene 0.015 I mg/kg 0.047 0.013 1 03/20/19 21:22 03/21/19 16:19 56-55-3 Benzo(a)pyrene 0.012 U mg/kg 0.047 0.012 1 03/20/19 21:22 03/21/19 16:19 50-32-8 Benzo(b)fluoranthene 0.017 I mg/kg 0.047 0.012 1 03/20/19 21:22 03/21/19 16:19 205-99-2 Benzo(g,h,i)perylene 0.012 U mg/kg 0.047 0.012 1 03/20/19 21:22 03/21/19 16:19 191-24-2 Benzo(k)fluoranthene 0.012 U mg/kg 0.047 0.012 1 03/20/19 21:22 03/21/19 16:19 207-08-9 Chrysene 0.015 U mg/kg 0.047 0.015 1 03/20/19 21:22 03/21/19 16:19 218-01-9 Dibenz(a,h)anthracene 0.011 U mg/kg 0.047 0.011 1 03/20/19 21:22 03/21/19 16:19 53-70-3 Fluoranthene 0.015 U mg/kg 0.047 0.015 1 03/20/19 21:22 03/21/19 16:19 206-44-0 Fluorene 0.017 U mg/kg 0.051 0.017 1 03/20/19 21:22 03/21/19 16:19 86-73-7 Indeno(1,2,3-cd)pyrene 0.011 U mg/kg 0.047 0.011 1 03/20/19 21:22 03/21/19 16:19 193-39-5 1-Methylnaphthalene 0.018 U mg/kg 0.055 0.018 1 03/20/19 21:22 03/21/19 16:19 90-12-0 2-Methylnaphthalene 0.018 U mg/kg 0.054 0.018 1 03/20/19 21:22 03/21/19 16:19 91-57-6 Naphthalene 0.016 U mg/kg 0.048 0.016 1 03/20/19 21:22 03/21/19 16:19 91-20-3 Phenanthrene 0.015 U mg/kg 0.047 0.015 1 03/20/19 21:22 03/21/19 16:19 85-01-8 Pyrene 0.015 U mg/kg 0.047 0.015 1 03/20/19 21:22 03/21/19 16:19 129-00-0 Surrogates Nitrobenzene-d5 (S) 57 % 24-98 1 03/20/19 21:22 03/21/19 16:19 4165-60-0 2-Fluorobiphenyl (S) 75 % 29-101 1 03/20/19 21:22 03/21/19 16:19 321-60-8 p-Terphenyl-d14 (S) 96 % 29-112 1 03/20/19 21:22 03/21/19 16:19 1718-51-0 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 04/10/2019 07:02 PM 28.0 % 0.10 0.10 1 03/19/1910:43 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 44 2ceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35454205 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: TE-13 Debris (2-4') Lab ID: 35454205002 Collected: 03/13/19 13:00 Received: 03/14/19 16:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual FL -PRO Soil Microwave Analytical Method: FL -PRO Preparation Method: EPA 3546 Petroleum Range Organics 3.6 U mg/kg Surrogates o-Terphenyl (S) 90 N-Pentatriacontane (S) 100 6010 MET ICP Ok Ok 5.6 3.6 1 03/16/19 01:11 03/18/19 22:18 66-136 42-159 Analytical Method: EPA 6010 Arsenic 9.7 Barium 65.6 Cadmium 1.2 Chromium 33.9 Lead 202 Selenium 0.63 U Silver 0.98 mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg 1 03/16/19 01:11 1 03/16/19 01:11 Preparation Method: EPA 3050 0.85 0.85 0.085 0.42 4.2 1.3 0.42 0.42 0.42 0.042 0.21 2.1 0.63 0.21 6010 MET ICP, TCLP Analytical Method: EPA6010 Preparation Method: Leachate Method/Date: EPA 1311; 03/29/19 19:37 ead 0.046 U mg/L 0.10 0.046 i471 Mercury Analytical Method: EPA 7471 Preparation Method: Mercury 0.14 mg/kg 0.014 0.0068 8270 MSSV Short List Microwave Analytical Method: EPA 8270 Preparation Method: Acenaphthene 0.016 U Acenaphthylene 0.015 U Anthracene 0.017 U Benzo(a)anthracene 0.020 Benzo(a)pyrene 0.014 I Benzo(b)fluoranthene 0.021 I Benzo(g,h,i)perylene 0.012 U Benzo(k)fluoranthene 0.013 U Chrysene 0.015 U Dibenz(a,h)anthracene 0.011 U Fluoranthene 0.019 Fluorene 0.017 U Indeno(1,2,3-cd)pyrene 0.011 U 1-Methylnaphthalene 0.018 U 2-Methylnaphthalene 0.018 U Naphthalene 0.021 Phenanthrene 0.015 U Pyrene 0.019 I Surrogates Nitrobenzene-d5 (S) 60 2-Fluorobiphenyl (S) 59 p-Terphenyl-d14 (S) 59 Date: 04/10/2019 07:02 PM mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg Ok 0.050 0.047 0.050 0.047 0.047 0.047 0.047 0.047 0.047 0.047 0.047 0.051 0.047 0.056 0.054 0.049 0.047 0.047 0.016 0.015 0.017 0.013 0.012 0.013 0.012 0.013 0.015 0.011 0.015 0.017 0.011 0.018 0.018 0.016 0.015 0.015 1 03/20/19 11:56 1 03/20/19 11:56 1 03/20/19 11:56 1 03/20/19 11:56 5 03/20/1911:56 1 03/20/19 11:56 1 03/20/19 11:56 03/18/19 22:18 84-15-1 03/18/19 22:18 630-07-09 03/22/19 18:00 7440-38-2 03/22/19 18:00 7440-39-3 03/22/19 18:00 7440-43-9 03/22/19 18:00 7440-47-3 03/25/19 14:46 7439-92-1 03/22/19 18:00 7782-49-2 03/22/19 18:00 7440-22-4 EPA 3010 Initial pH: 5; Final pH: 6 1 03/30/19 14:43 03/31/19 17:37 7439-92-1 EPA 7471 1 03/19/19 17:50 03/20/19 16:39 7439-97-6 EPA 3546 03/15/19 13:03 03/20/19 09:05 83-32-9 03/15/19 13:03 03/20/19 09:05 208-96-8 03/15/19 13:03 03/20/19 09:05 120-12-7 03/15/19 13:03 03/20/19 09:05 56-55-3 03/15/19 13:03 03/20/19 09:05 50-32-8 03/15/19 13:03 03/20/19 09:05 205-99-2 03/15/19 13:03 03/20/19 09:05 191-24-2 03/15/19 13:03 03/20/19 09:05 207-08-9 03/15/19 13:03 03/20/19 09:05 218-01-9 03/15/19 13:03 03/20/19 09:05 53-70-3 03/15/19 13:03 03/20/19 09:05 206-44-0 03/15/19 13:03 03/20/19 09:05 86-73-7 03/15/19 13:03 03/20/19 09:05 193-39-5 03/15/19 13:03 03/20/19 09:05 90-12-0 03/15/19 13:03 03/20/19 09:05 91-57-6 03/15/19 13:03 03/20/19 09:05 91-20-3 03/15/19 13:03 03/20/19 09:05 85-01-8 03/15/19 13:03 03/20/19 09:05 129-00-0 24-98 1 03/15/19 13:03 03/20/19 09:05 4165-60-0 29-101 1 03/15/19 13:03 03/20/19 09:05 321-60-8 29-112 1 03/15/19 13:03 03/20/19 09:05 1718-51-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 44 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35454205 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: TE-13 Debris (2-4') Lab ID: 35454205002 Collected: 03/13/19 13:00 Received: 03/14/19 16:00 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture Date: 04/10/2019 07:02 PM 27.1 % 0.10 0.10 1 03/19/1910:43 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 44 aceAnalytical® www pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35454205 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 524124 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 35454205001, 35454205002 METHOD BLANK: 2833127 Matrix: Solid Associated Lab Samples: 35454205001, 35454205002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury mg/kg 0.0043 U 0.0086 0.0043 03/20/19 13:27 LABORATORY CONTROL SAMPLE: 2833128 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg 0.085 0.090 105 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2833129 2833130 MS MSD 35453136001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual lercury mg/kg 0.40 0.82 0.82 0.75 0.69 42 36 80-120 8 20 J(M1) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/10/2019 07:02 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 44 PaceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35454205 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 524529 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 35454205001, 35454205002 METHOD BLANK: 2835305 Matrix: Solid Associated Lab Samples: 35454205001, 35454205002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic mg/kg 0.31 U 0.62 0.31 03/22/19 12:53 Barium mg/kg 0.31 U 0.62 0.31 03/22/19 12:53 Cadmium mg/kg 0.031 U 0.062 0.031 03/22/19 12:53 Chromium mg/kg 0.16 U 0.31 0.16 03/22/19 12:53 Lead mg/kg 0.31 U 0.62 0.31 03/22/19 12:53 Selenium mg/kg 0.47 U 0.93 0.47 03/22/19 12:53 Silver mg/kg 0.16 U 0.31 0.16 03/22/19 12:53 LABORATORY CONTROL SAMPLE: 2835306 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers Arsenic mg/kg 15.1 13.7 90 80-120 Barium mg/kg 15.1 15.2 100 80-120 Cadmium mg/kg 1.5 1.5 99 80-120 Chromium mg/kg 15.1 15.6 103 80-120 Lead mg/kg 15.1 15.1 100 80-120 Selenium mg/kg 15.1 12.6 83 80-120 Silver mg/kg 1.5 1.5 97 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2835307 2835308 MS MSD 35454484002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic mg/kg 4.1 33.5 39.4 36.2 43.1 96 99 75-125 17 20 Barium mg/kg 11.7 33.5 39.4 45.4 53.5 101 106 75-125 16 20 Cadmium mg/kg 0.33 3.4 4.1 3.4 4.0 91 94 75-125 17 20 Chromium mg/kg 6.9 33.5 39.4 39.9 46.4 99 100 75-125 15 20 Lead mg/kg 6.1 33.5 39.4 37.7 43.4 95 95 75-125 14 20 Selenium mg/kg 1.2 I 33.5 39.4 29.1 33.9 84 83 75-125 15 20 Silver mg/kg 0.37 U 3.4 4.1 3.5 4.2 106 108 75-125 18 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/10/2019 07:02 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 44 ceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35454205 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 527287 Analysis Method: EPA 6010 QC Batch Method: EPA 3010 Analysis Description: 6010 MET TCLP Associated Lab Samples: 35454205002 METHOD BLANK: 2851541 Matrix: Water Associated Lab Samples: 35454205002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Lead mg/L 0.0046 U 0.010 0.0046 03/31/19 17:17 LABORATORY CONTROL SAMPLE: 2853804 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead mg/L 0.25 0.25 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2853805 2853806 MS MSD 35453908001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual ead mg/L 0.046 U 2.5 2.5 2.5 2.6 101 102 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/10/2019 07:02 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 44 (/2eAnaIYticaI www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35454205 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 523395 Analysis Method: EPA 8270 QC Batch Method: EPA 3546 Analysis Description: 8270 Solid MSSV Microwave Short Spike Associated Lab Samples: 35454205002 METHOD BLANK: 2828608 Matrix: Solid Associated Lab Samples: 35454205002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1-Methylnaphthalene mg/kg 0.013 U 0.040 0.013 03/18/19 11:12 2-Methylnaphthalene mg/kg 0.013 U 0.039 0.013 03/18/19 11:12 Acenaphthene mg/kg 0.012 U 0.036 0.012 03/18/19 11:12 Acenaphthylene mg/kg 0.011 U 0.034 0.011 03/18/19 11:12 Anthracene mg/kg 0.012 U 0.036 0.012 03/18/19 11:12 Benzo(a)anthracene mg/kg 0.0098 U 0.034 0.0098 03/18/19 11:12 Benzo(a)pyrene mg/kg 0.0085 U 0.034 0.0085 03/18/19 11:12 Benzo(b)fluoranthene mg/kg 0.0091 U 0.034 0.0091 03/18/19 11:12 Benzo(g,h,i)perylene mg/kg 0.0086 U 0.034 0.0086 03/18/19 11:12 Benzo(k)fluoranthene mg/kg 0.0091 U 0.034 0.0091 03/18/19 11:12 Chrysene mg/kg 0.011 U 0.034 0.011 03/18/19 11:12 Dibenz(a,h)anthracene mg/kg 0.0078 U 0.034 0.0078 03/18/19 11:12 Fluoranthene mg/kg 0.011 U 0.034 0.011 03/18/19 11:12 Fluorene mg/kg 0.012 U 0.037 0.012 03/18/19 11:12 Indeno(1,2,3-cd)pyrene mg/kg 0.0078 U 0.034 0.0078 03/18/19 11:12 Naphthalene mg/kg 0.012 U 0.035 0.012 03/18/19 11:12 Phenanthrene mg/kg 0.011 U 0.034 0.011 03/18/19 11:12 Pyrene mg/kg 0.011 U 0.034 0.011 03/18/19 11:12 2-Fluorobiphenyl (S) % 57 29-101 03/18/19 11:12 Nitrobenzene-d5 (S) % 58 24-98 03/18/19 11:12 p-Terphenyl-d14 (S) % 81 29-112 03/18/19 11:12 LABORATORY CONTROL SAMPLE: 2828609 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1-Methylnaphthalene mg/kg 1.6 0.97 59 38-115 2-Methylnaphthalene mg/kg 1.6 0.95 58 37-115 Acenaphthene mg/kg 1.6 1.0 61 30-127 Acenaphthylene mg/kg 1.6 1.1 66 29-129 Anthracene mg/kg 1.6 1.1 67 37-126 Benzo(a)anthracene mg/kg 1.6 1.3 81 37-130 Benzo(a)pyrene mg/kg 1.6 1.1 69 39-128 Benzo(b)fluoranthene mg/kg 1.6 1.1 66 38-128 Benzo(g,h,i)perylene mg/kg 1.6 1.3 78 34-136 Benzo(k)fluoranthene mg/kg 1.6 1.1 68 39-133 Chrysene mg/kg 1.6 1.3 80 39-125 Dibenz(a,h)anthracene mg/kg 1.6 1.2 72 37-127 Fluoranthene mg/kg 1.6 1.2 72 39-130 Fluorene mg/kg 1.6 1.1 64 35-125 Indeno(1,2,3-cd)pyrene mg/kg 1.6 1.2 75 35-133 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/10/2019 07:02 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 44 aceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35454205 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE: 2828609 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Naphthalene mg/kg 1.6 0.97 59 36-115 Phenanthrene mg/kg 1.6 1.2 70 35-128 Pyrene mg/kg 1.6 1.3 80 37-132 2-Fluorobiphenyl (S) % 59 29-101 Nitrobenzene-d5 (S) % 58 24-98 p-Terphenyl-d14 (S) % 75 29-112 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2828610 2828611 MS MSD 35452338001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1-Methylnaphthalene mg/kg 0.015 U 1.9 1.9 0.90 0.81 47 43 38-115 11 40 2-Methylnaphthalene mg/kg 0.015 U 1.9 1.9 0.87 0.80 45 42 37-115 9 40 Acenaphthene mg/kg 0.013 U 1.9 1.9 0.90 0.77 47 41 30-127 15 40 Acenaphthylene mg/kg 0.012 U 1.9 1.9 0.97 0.84 50 45 29-129 14 40 Anthracene mg/kg 0.014 U 1.9 1.9 0.90 0.76 47 40 37-126 17 40 Benzo(a)anthracene mg/kg 0.011 U 1.9 1.9 0.97 0.83 50 44 37-130 15 40 Benzo(a)pyrene mg/kg 0.0097 U 1.9 1.9 0.81 0.69 42 37 39-128 16 40 J(M1) 3enzo(b)fluoranthene mg/kg 0.010 U 1.9 1.9 0.77 0.63 40 33 38-128 20 40 J(M1) -ienzo(g,h,i)perylene mg/kg 0.0098 U 1.9 1.9 0.87 0.74 45 39 34-136 16 40 Benzo(k)fluoranthene mg/kg 0.010 U 1.9 1.9 0.81 0.70 42 37 39-133 14 40 J(M1) Chrysene mg/kg 0.012 U 1.9 1.9 1.0 0.86 53 45 39-125 18 40 Dibenz(a,h)anthracene mg/kg 0.0090 U 1.9 1.9 0.86 0.73 44 39 37-127 16 40 Fluoranthene mg/kg 0.013 U 1.9 1.9 0.90 0.76 46 40 39-130 16 40 Fluorene mg/kg 0.014 U 1.9 1.9 0.91 0.78 47 41 35-125 16 40 Indeno(1,2,3-cd)pyrene mg/kg 0.0089 U 1.9 1.9 0.85 0.71 44 38 35-133 17 40 Naphthalene mg/kg 0.013 U 1.9 1.9 0.93 0.86 48 46 36-115 8 40 Phenanthrene mg/kg 0.013 U 1.9 1.9 0.95 0.79 49 42 35-128 18 40 Pyrene mg/kg 0.012 U 1.9 1.9 1.0 0.88 53 47 37-132 14 40 2-Fluorobiphenyl (S) % 47 42 29-101 Nitrobenzene-d5 (S) % 48 46 24-98 p-Terphenyl-d14 (S) % 57 44 29-112 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/10/2019 07:02 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 44 www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35454205 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 524659 Analysis Method: EPA 8270 QC Batch Method: EPA 3546 Analysis Description: 8270 Solid MSSV Microwave Short Spike Associated Lab Samples: 35454205001 METHOD BLANK: 2836116 Matrix: Solid Associated Lab Samples: 35454205001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1-Methylnaphthalene mg/kg 0.013 U 0.040 0.013 03/21/19 11:57 2-Methylnaphthalene mg/kg 0.013 U 0.039 0.013 03/21/19 11:57 Acenaphthene mg/kg 0.012 U 0.036 0.012 03/21/19 11:57 Acenaphthylene mg/kg 0.011 U 0.034 0.011 03/21/19 11:57 Anthracene mg/kg 0.012 U 0.036 0.012 03/21/19 11:57 Benzo(a)anthracene mg/kg 0.0096 U 0.034 0.0096 03/21/19 11:57 Benzo(a)pyrene mg/kg 0.0083 U 0.034 0.0083 03/21/19 11:57 Benzo(b)fluoranthene mg/kg 0.0090 U 0.034 0.0090 03/21/19 11:57 Benzo(g,h,i)perylene mg/kg 0.0084 U 0.034 0.0084 03/21/19 11:57 Benzo(k)fluoranthene mg/kg 0.0090 U 0.034 0.0090 03/21/19 11:57 Chrysene mg/kg 0.011 U 0.034 0.011 03/21/19 11:57 Dibenz(a,h)anthracene mg/kg 0.0077 U 0.034 0.0077 03/21/19 11:57 Fluoranthene mg/kg 0.011 U 0.034 0.011 03/21/19 11:57 Fluorene mg/kg 0.012 U 0.037 0.012 03/21/19 11:57 Indeno(1,2,3-cd)pyrene mg/kg 0.0077 U 0.034 0.0077 03/21/19 11:57 Naphthalene mg/kg 0.012 U 0.035 0.012 03/21/19 11:57 Phenanthrene mg/kg 0.011 U 0.034 0.011 03/21/19 11:57 Pyrene mg/kg 0.011 U 0.034 0.011 03/21/19 11:57 2-Fluorobiphenyl (S) % 87 29-101 03/21/19 11:57 Nitrobenzene-d5 (S) % 79 24-98 03/21/19 11:57 p-Terphenyl-d14 (S) % 100 29-112 03/21/19 11:57 LABORATORY CONTROL SAMPLE: 2836117 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1-Methylnaphthalene mg/kg 1.7 1.4 84 38-115 2-Methylnaphthalene mg/kg 1.7 1.3 80 37-115 Acenaphthene mg/kg 1.7 1.4 87 30-127 Acenaphthylene mg/kg 1.7 1.5 93 29-129 Anthracene mg/kg 1.7 1.5 92 37-126 Benzo(a)anthracene mg/kg 1.7 1.7 103 37-130 Benzo(a)pyrene mg/kg 1.7 1.5 91 39-128 Benzo(b)fluoranthene mg/kg 1.7 1.5 92 38-128 Benzo(g,h,i)perylene mg/kg 1.7 1.5 94 34-136 Benzo(k)fluoranthene mg/kg 1.7 1.4 87 39-133 Chrysene mg/kg 1.7 1.7 104 39-125 Dibenz(a,h)anthracene mg/kg 1.7 1.5 93 37-127 Fluoranthene mg/kg 1.7 1.7 101 39-130 Fluorene mg/kg 1.7 1.5 94 35-125 Indeno(1,2,3-cd)pyrene mg/kg 1.7 1.6 95 35-133 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/10/2019 07:02 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 44 aceAnalytical www pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35454205 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE: 2836117 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Naphthalene mg/kg 1.7 1.3 80 36-115 Phenanthrene mg/kg 1.7 1.5 93 35-128 Pyrene mg/kg 1.7 1.6 96 37-132 2-Fluorobiphenyl (S) % 86 29-101 Nitrobenzene-d5 (S) % 73 24-98 p-Terphenyl-d14 (S) % 95 29-112 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2836805 2836806 MS MSD 35455268004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1-Methylnaphthalene mg/kg 0.13 1.8 1.8 1.7 1.7 90 88 38-115 3 40 2-Methylnaphthalene mg/kg 0.26 1.8 1.8 1.8 1.8 89 85 37-115 4 40 Acenaphthene mg/kg 0.012 U 1.8 1.8 1.5 1.5 86 83 30-127 4 40 Acenaphthylene mg/kg 0.011 U 1.8 1.8 1.7 1.7 92 93 29-129 0 40 Anthracene mg/kg 0.013 U 1.8 1.8 1.6 1.7 90 94 37-126 3 40 Benzo(a)anthracene mg/kg 0.010 U 1.8 1.8 1.8 1.9 103 105 37-130 2 40 Benzo(a)pyrene mg/kg 0.0089 U 1.8 1.8 1.6 1.7 90 93 39-128 3 40 'enzo(b)fluoranthene mg/kg 0.0096 U 1.8 1.8 1.5 1.7 86 93 38-128 8 40 senzo(g,h,i)perylene mg/kg 0.0090 U 1.8 1.8 1.7 1.7 93 94 34-136 0 40 Benzo(k)fluoranthene mg/kg 0.0096 U 1.8 1.8 1.6 1.6 90 89 39-133 2 40 Chrysene mg/kg 0.011 U 1.8 1.8 1.8 1.8 101 104 39-125 2 40 Dibenz(a,h)anthracene mg/kg 0.0083 U 1.8 1.8 1.6 1.7 91 95 37-127 3 40 Fluoranthene mg/kg 0.012 U 1.8 1.8 1.8 1.9 99 106 39-130 7 40 Fluorene mg/kg 0.013 U 1.8 1.8 1.6 1.6 92 92 35-125 1 40 Indeno(1,2,3-cd)pyrene mg/kg 0.0082 U 1.8 1.8 1.7 1.8 93 99 35-133 5 40 Naphthalene mg/kg 0.60 1.8 1.8 2.1 2.0 84 79 36-115 5 40 Phenanthrene mg/kg 0.012 U 1.8 1.8 1.6 1.7 92 96 35-128 3 40 Pyrene mg/kg 0.011 U 1.8 1.8 1.8 1.8 98 99 37-132 0 40 2-Fluorobiphenyl (S) % 84 84 29-101 Nitrobenzene-d5 (S) % 70 77 24-98 p-Terphenyl-d14 (S) % 97 98 29-112 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/10/2019 07:02 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 44 www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35454205 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 523593 Analysis Method: FL -PRO QC Batch Method: EPA 3546 Analysis Description: FL -PRO Soil Associated Lab Samples: 35454205001, 35454205002 METHOD BLANK: 2830289 Matrix: Solid Associated Lab Samples: 35454205001, 35454205002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Petroleum Range Organics mg/kg 2.5 U 4.0 2.5 03/18/19 14:36 N-Pentatriacontane (S) % 96 42-159 03/18/19 14:36 o-Terphenyl (S) % 96 66-136 03/18/19 14:36 LABORATORY CONTROL SAMPLE: 2830290 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Petroleum Range Organics N-Pentatriacontane (S) o-Terphenyl (S) mg/kg %o %o 202 186 92 65-119 104 42-159 99 66-136 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2830291 2830292 MS MSD 35453967015 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Petroleum Range Organics mg/kg 21.9 217 218 256 230 108 96 39-181 11 25 N-Pentatriacontane (S) % 107 94 42-159 o-Terphenyl (S) % 102 90 66-136 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/10/2019 07:02 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 44 , aceAnalytical wwrw.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35454205 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 524137 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 35454205001, 35454205002 SAMPLE DUPLICATE: 2833230 35454202004 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture OA 29.5 28.6 3 10 SAMPLE DUPLICATE: 2833231 35454734015 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture 9.5 14.5 41 10 J(D6) SAMPLE DUPLICATE: 2833232 35454734006 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture %0 10.6 10.7 2 10 AMPLE DUPLICATE: 2833233 35454585011 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 32.9 32.5 1 10 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/10/2019 07:02 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 44 aceAnalytical® www.pacelabs.com QUALIFIERS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35454205 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS U J(D6) J(M1) The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. Compound was analyzed for but not detected. Estimated Value. The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. Estimated Value. Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. Date: 04/10/2019 07:02 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 44 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melreese Golf Course Pace Project No.: 35454205 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 35454205001 TE-29 (0-1') EPA 3546 523593 FL -PRO 523759 35454205002 TE-13 Debris (2-4') EPA 3546 523593 FL -PRO 523759 35454205001 TE-29 (0-1') EPA 3050 524529 EPA 6010 524669 35454205002 TE-13 Debris (2-4') EPA 3050 524529 EPA 6010 524669 35454205002 TE-13 Debris (2-4') EPA 3010 527287 EPA 6010 527323 35454205001 TE-29 (0-1') EPA 7471 524124 EPA 7471 524351 35454205002 TE-13 Debris (2-4') EPA 7471 524124 EPA 7471 524351 35454205001 TE-29 (0-1') EPA 3546 524659 EPA 8270 524863 35454205002 TE-13 Debris (2-4') EPA 3546 523395 EPA 8270 523885 35454205001 TE-29 (0-1') ASTM D2974-87 524137 35454205002 TE-13 Debris (2-4') ASTM D2974-87 524137 Date: 04/10/2019 07:02 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 44 WO# :35454205 J OF CUSTODY RECORD Container Type Codes • 1111 www.pacelabs.l 35454205 IIIIIIIII III III III 1 Quote: Page 9 of f AV Amber Vial ES Encore Sampler leseeAnalyticP Plastic PLC Plante: container AL Amber Liter PL J Plmdic Jar ter AP Amber(Plastic TB TMhir hag — — AG Amber Glans WP Whirl pak SJ Soil Jar G Gallon Jug Other _ TC Torrn-corn PPV Pmproservod Het Sizo(s): 2oz. doz. Soz, l6oz. 32oz or 1L, other f r CompanyName: G 4- l,- Po# LAB ANALYSIS e, 4 Pee00m1 cPlasIc. m1 Example, an:P = fie: Plastic, eozSJm ep: sou Jar / Address: '`7 75( / , i42-jro. o , 4L. - �.. , . Sample City: i-'f ,: ci, . (.--4.4 ti5 State: ram- Zip: Ci TRC Matrix Codes rT.:� Attn: f � t•U �/%Lsti Cr iz < i -A C• j .z Qe-r- pH SD Solid Waste OL Oil GW Ground Wider SL Sludge _ `} ,, 'n (� email: Ml% i ytO? 7•C�lPhone: 7 '�)`'�/ PreS iacSes EFF Effluent SO Soil Sediment AFW Annlyla Free H2O AO Agoouo., WW Waste Water NA Nonaqueoun. I J Parameters EXAMPLE Diss. Lead 6010 DW Dnnking Water PE PetroleumSW Surface Water O Other Projec , " 5,Name e (Zy-h, i{( LC1('Z.Pro] # J t jC'7 X} ML Misc. Liquid lol,”,nmnly1 Sampler i1 ) Ircle One Event: Dail WeeklyMonthly P/ Y Signatur• _ i <rr r Quartely Semi -Annual Annual N/A - r C Preservative Type Codes Sample # \ ' Sample ID v p Collect Date Collect Time Matrix Code' it it = z Q a c o $ - fT lllll.� {� }— �i•)� �'� 21 A. None E. HCl I. Ice B. HNO3 F. McOH J. MCAA C. H2SO4 G. Na2S203 K. zn Acetate D. NaOH H. NaHSO4 O. Other # of Containers 11 Sete/Type 1 REMARKS 6- c-i.r 3I3i/ C'C SU ❑ i n ❑ ❑ I 1 ❑ I A (�hi1c i -)3 -)31��,. -1:-.5elm i j > �I Q aI �I I Li ', ,� r JcX-..› 3 n u n �u Li u 11 4 INl �I 1 L Li 1 I-1 5 ---����❑ I I �U n 1 1 1 n u 6 ---■■■.� I l 1 1 ■ Li 1 n n u 7 ���■���❑ u u 11 n r I I I 8 ---����❑ I I I I I 1 u Li 1 1 9 ---■.■.❑ u I I I I I 1 u ■ �o a 1 1 11 ❑ 1 1 a 1 1 ❑ u CYMTA.T HEOUESTIRmeFoes Approved) EDD (Fees May Apply) COC Condition Required Stale Certification Coolers It's - Tem C p e X, dint RUSH Short Hold Circle QA/QC Report Level (r N Today 100 — 20 30 40 __ _ N 1 2 3 4 CLP ArCr:E CAPP Other _ ADaPT SEDD ERPIMS TSV CSV Other OK mcn�nna,l�, FL GA SC NC NJ PA LA TX IL _ 2 3 45 5 Item Iln 4is ed by Affiliation Dat Time Received by Affiliation Date Time 1 `• 1 - i )/, 'F (�� �'✓ �-' (I / }J 1.7 / 7 / (�J \� I i L s, J / /am ��y-,11 r'^� — �:---• j/✓ (/ ?-,I)-31 F- r4- 6 l k-i /^ - 1 L V ✓ Nnn-Cenlnm,ane„ Finger' Sample;: INTACT' uprn, nrnval"I h -'i` ~ 111 :+/• 1 i / �'r <? ( / .� j { 3 I t �t 1 nn nrvod on Wol Ice? Proper Presarvnlrvon Indicated? -'- j, fP,lnarivnd j- ,3 qGr 3' �I(� r� Lc `'y within holding tenon Custody nett C ��. - _ --- Volatile,: rent withut rne hn;tdsp:icr9_ without Prulvu Cnnl't nor• ll•nrlT -_ — mpano Lab'954-582-4300 0 Revision: F-ALL-C-007- Rev.00 , C.O.C. Serial # -; 5 2 5 2 ace Analytical" Document Name: Sample Condition Upon Receipt Form Document -Revised: May 30, 2018 Document No.: F-FL-C-007 rev. 13 Issuing Authority: Pace Florida Quality Office Pi±35442O5 Project CTR Project Manage LIEN7: 36-EEG Client. Thermometer Used: T� State of Origin: Samples shorted to lab (If Yes, complete) Due Date: 03/25/19 Date: m.(SCUR), Date and Initials of person: Examining contents: Label: Deliver: pH: - Time: J S Initials: ❑ For WV projects, all containers verified to 5.6 °C Cooler #1 Temp.°C _• 5 (Visual) ' (Correction Factor) ' . S" (Actual) Cooler #2 Temp.°C (Visual) (Correction Factor) (Actual) Cooler #3 Temp.°C (Visual) (Correction Factor) (Actual) Cooler #4 Temp.°C (Visual) (Correction Factor) (Actual) Cooler #5 Temp.°C (Visual) (Correction Factor) (Actual) Cooler #6 Temp.°C (Visual) (Correction Factor) (Actual) Courier: ❑ Fed Ex ❑ UPS ❑ USPS ❑ Client XeCOmmercial D Pace Shipping Method: ❑ First Overnight ❑ Priority Overnight ❑ Standard Ovemight ❑ Ground 0 Other Billing: ❑ Recipient ❑ Sender ❑ Third Party Tracking # Ae8 ❑ Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun Other 0 International Priority ❑ Credit Card 0 Unknown Custody Seal on Cooler/Box Present: ❑Yes o Seals intact: ❑ Yes ❑ No Packing Material: ❑Bubble Wrap /❑ Bubble Bags ❑None ❑Other a l C oF=t Shorted Date Comments: Ice: j Blue Dry None Shorted Time: CTJU Ce,Qty: y C Chain of Custody Present Yes 0 No ❑N/A Chain of Custody Filled Out byes 0 No ❑N/A Relinquished Signature & Sampler Name COC pYes 0 No O N/A Samples Arrived within Hold Time !Yes 0 No ❑N/A Rush TAT requested an COC ❑Yes 0 No/ON/A Sufficient Volume ❑Yes 0 No ❑N/A Correct Containers Used ❑Yes ❑ No ❑N/A Containers Intact Ayes 0 No ❑N/A Sample Labels match COC (samp'e IDs & date/time of collection) I I Yes ❑ No ❑N/A All containers needing acid/base preservation have been I checked. ❑Yes 0 No N/A All Containers needing preservation are found to be in compliance with EPA recommendation: ❑Yes ❑ No N/A Exceptions: VOA, Coliform, TOC, O&G, Carbamates Preservation Information: Preservative: Lot #/Trace #: Date: Time: Initials: Headspace in VOA Vials? ( >6mm): ❑Yes 0 No N/A Trip Blank Present: ❑Yes 0 No N/A Client Notification/ Resolution: Person Contacted: Comments/ Resolution (use back for additional comments): Date/Time: Project Manager Review: Date: Page 21 of 44 TM ace Analytical www.pacelabs.com Report Prepared for: Christina Raschke PASI Florida 3610 Park Central Blvd N Pompano Beach FL 33064 REPORT OF LABORATORY ANALYSIS FOR PCDD/PCDF Report Prepared Date: April 10, 2019 Report No 104670838290FC_DFR Pace Analytical Services, LLC. 1700 Elm Street Minneapolis, MN 55414 Phone: 612.607.1700 Fax: 612.607.6444 Report Information: Pace Project #: 10467083 Sample Receipt Date: 04/03/2019 Client Project #: 35454205 Client Sub PO #: N/A State Cert #: E87605 Invoicing & Reporting Options: The report provided has been invoiced as a Level 2 PCDD/PCDF Report. If an upgrade of this report package is requested, an additional charge may be applied. Please review the attached invoice for accuracy and forward any questions to Kirsten Hogberg, your Pace Project Manager. This report has been reviewed by: April 10, 2019 Kirsten Hogberg, Project Manager (612) 607-6407 (612) 607-6444 (fax) kirsten.hogberg@pacelabs.com Report of Laboratory Analysis Th isreportshouldnotbereproduced,except infull, withoutthewrittenconsentofPaceAnalyticalServices,Inc. Theresultsrelateonlyt othesamplesincludedinthisreport. Page 22 of 44 Page 1 of 23 aceAnalytical Pace Analytical Services, LLC. 1700 Elm Street Minneapolis, MN 55414 Phone: 612.607.1700 Fax: 612.607.6444 DISCUSSION This report presents the results from the analyses performed on two samples submitted by a representative of Pace Analytical Services, LLC. The samples were analyzed for the presence or absence of polychlorodibenzo-p-dioxins (PCDDs) and polychlorodibenzofurans (PCDFs) using a modified version of USEPA Method 8290. The reporting limits were based on signal-to-noise measurements. Estimated Maximum Possible Concentration (EMPC) values were treated as positives in the toxic equivalence calculations. Per request, estimated detection limit (EDL) values were provided and flagged "U" where the target analytes were not detected. The recoveries of the isotopically -labeled PCDD/PCDF internal standards in the sample extracts ranged from 25-46%. Twenty-six labeled internal standard recoveries obtained for this project were below the 40-135% target range specified in Method 8290 and flagged "R" on othe results tables. Since the quantification of the native 2,3,7,8-substituted congeners was based on isotope dilution, the data were automatically corrected for recovery and accurate values were obtained. Values were flagged "I" where incorrect isotope ratios were obtained. Concentrations below the calibration range were flagged "J" and should be regarded as estimates. A laboratory method blank was prepared and analyzed with the sample batch as part of our routine quality control procedures. The results show that PCDDs and PCDFs were not detected. These results indicate that the sample preparation procedures did not significantly impact the results of the field sample determinations. Laboratory and matrix spike samples were also prepared using clean reference matrix or sample matrix that had been fortified with native standard materials. The recoveries of the spiked native compounds generally ranged from 85-125% with relative percent differences (RPDs) of 0.4-52.7%. The background -subtracted recovery values obtained for 1,2,3,7,8,9-HxCDD, HpCDD, and OCDD in the matrix spike and/or matrix spike duplicate were outside the 70-130% target range. Also, the RPD values obtained for these three congeners in the matrix spike analyses were above the 20% target upper limit. These deviations may indicate analytical biases and/or elevated variability for the affected congeners in these determinations. REPORT OF LABORATORYANALYSIS This report shall not be reproduced, except in full.. without the written consent of Pace Analytical Services, Inc. Report No 10467083_8290FC_DFR Page 23 of 44 Page 2 of 23 Authority Minnesota Laboratory Certifications Certificate # Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612-607-6444 Authority Certificate # A2LA 2926.01 Alabama 40770 Alaska - DW MN00064 Alaska - UST 17-009 Arizona AZ0014 Arkansas - DW MN00064 Arkansas - WW 88-0680 CNMI Saipan MP0003 California 2929 Colorado MN00064 Connecticut PH-0256 EPA Region 8+ via MN 027-053 Florida (NELAP E87605 Georgia 959 Guam 17-001r Hawaii MN00064 Idaho MN00064 Illinois 200011 Indiana C-MN-01 Iowa 368 Kansas E-10167 Kentucky - DW 90062 Kentucky - WW 90062 Louisiana - DE 03086 Louisiana - DW MN00064 Maine MN00064 Maryland 322 Massachusetts M-MN064 Michigan 9909 Minnesota 027-053-137 Minnesota - De via MN 027-053 Minnesota - Pet 1240 Mississippi MN00064 Missouri - DW 10100 Montana CERT0092 Nebraska NE-OS-18-06 Nevada MN00064 New Hampshire 2081 New Jersey (NE MN002 New York 11647 North Carolina 27700 North Carolina - 27700 North Carolina - 530 North Dakota R-036 Ohio - DW 41244 Ohio - VAP CL101 Oklahoma 9507 Oregon - Primar MN300001 Oregon - Secon MN200001 Pennsylvania 68-00563 Puerto Rico MN00064 South Carolina 74003 South Dakota NA Tennessee TN02818 Texas T104704192 Utah (NELAP) MN00064 Virginia 460163 Washington C486 West Virginia - 382 West Virginia - 9952C Wisconsin 999407970 Wyoming - UST 2926.01 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10467083_8290FC_DFR Page 24 of 44 Page 3 of 23 Appendix A Sample Management Report No 10467083_8290FC_e Analytical Services, Inc. Page 25 of 44 Page 4 of 23 (D 0 Z 0 • • 0 O CO W CO O m n I 0 m �C7 v CO (D U1 0 N W Chain of Custody Samples were sent directly to the Subcontracting Laboratory. Workorder: 35454205 Workorder Name: Melrose Golf Course State Of Origin: FL Cert. Needed: I I Yes Owner Received Date: WO#:10467083 1(111(11 1(1 I1(!U "II I I No 3/14/2 19 Results Requested By: 3/25/2019 Christina Raschke Pace Analytical South Florida 3610 Park Central Blvd N Pompano Beach, FL 33064 Phone (954)582-4300 TE-29 (0-1') TE-13 Debris (2-4') Transfers Released By Pace Analytical Minnesota 1700 Elm Street SE Suite 200 Minneapolis, MN 55414 Phone (612)607-1700 3/1312019 08:40 3/1312019.13:00 Date/Time 35454205001 35454205002 Received By ,a Date/Time 1 1s rYr7oa 2 Tit.) 3 LAB USE ONLY trot Cooler Temperature on Receipt A / 1 Custody Seal Y or 1 Received on Ice (P) or N Samples Intact or N —"In order to maintain client confidentiality, location/name of the sampling site, sampler's name and signature may not be provided on this COC document. This chain of custody is considered complete as is since this information is available in the owner laboratory. riday, March 15, 2019 8:04134 AM FMT-ALL-C-002rev.00 24March2009 Page 1 of 1 ace Analytical' Flonua C°G°rt,fory Document Name: Sample Condition Upon Receipt Form Document -No.: F-FL-C-007 rev. 13 wommiN40# : 35454205 ,. Project IN: CTR Due Date: 03/25/19 date and Initials of person: Document Revised: May 30, 2018 Issuing Authority: Pace Florida Quality Office, Project Manage :LIENT: 36-EEG Client. Thermometer Used: �-3 State of Origin: Cooler#1 Temp.°C-3 3 (Visual) Cooler #2 Temp.°C ,(Visual) Cooler #3 Temp.°C (Visual) Cooler #4 Temp.°C (Visual) Cooler #5 Temp.°C (Visual) Cooler #6 Temp.°C (Visual) Courier: ❑ Fed Ex Billing: Tracking # Date: 2 ' ! • I 0 (Correction Factor) (Correction Factor) (Correction Factor) (Correction Factor) (Correction Factor) (Correction Factor) Examining contents: Label: Deliver: pH: Time: C13 cl Initials: FFor WV projects, all containers verified to 56 °C • .a (Actual) (Actual) (Actual) (Actual) (Actual) (Actual) ❑ UPS ❑ USPS ❑ Client ®"' commercial ❑ Pace Shipping Method: ❑ First Overnight ❑ Priority Overnight ❑ Standard Overnight ❑ Ground ❑ Other 0 Recipient 0 Sender ❑ Third Party 0 Credit Card Custody Seal on Cooler/Box Present: '❑Yes Seals intact: ❑ Yes ❑ No Packing Material: ❑Bubble Wrap (ErBubble Bags ❑None ❑Other Samples shorted to lab (If Yes, complete) Shorted Date: • O Samples on Ice, cooling process has begun ❑ Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun ❑ Samples on ice, cooling process has begun 0 Samples on ice, cooling process has begun Cl Other 0 International Priority 0 Unknown ice: Blue Dry None Shorted Time: `� Qty: GP'3 Chain of Custody Present Yes 0 No ❑N/A Chain of Custody Filled Out Yes 0 No ❑N/A Relinquished Signature &Sampler Name COC - Yes 0 No ❑N/A Samples Arrived within Hold Time rTYes ❑ No ON/A Rush TAT requested on COC ❑Yes 0 No N/A Sufficient Volume Yes ❑ No ❑N/A Correct Containers Used Yes 0 No EN/A Containers Intact Yes ❑ No ❑N/A Sample Labels match COC (sample IDs & date/time of collection) es 0 No ❑N/A All containers needing acid/base preservation have been checked. ❑Yes 0 No N/A Ali Containers needing preservation are found to be in compliance with EPA recommendation: ❑Yes ❑ No N/A Exceptions: VOA, Coliform, TOC, O&G, Carbamates Preservation Information: Preservative: Lot it/Trace #: Date: Time: Initials: Headspace in VOA Vials? (>8mm): ❑Yes 0 No N/A Trip Blank Present: ❑Yes ❑ No N/A Client Notification/ Resolution: Person Contacted: Comments/ Resolution (use back for additional comments): Date/Time: Project Manager Review: Date: Page 27 of 44 Report No 10467083_8290FC_DFR Page 6 of 23 aceeAnalytical Sample Condition Upon Receipt Courier: Document Name: Sample Condition Upon Receipt Form Document No.: F-MN-L-213-rev.25 Client Name: Project #: MFed Ex ❑UPS ❑uses ❑Client ['Pace ❑SpeeDee ❑Commercial See Exception Tracking Number: gi72 307d1 (03co ❑ Document Revised: 06Feb2019 Page 1 of 1 Issuing Authority: Pace Minnesota Quality Office WO :10467083 PM: KW Due Date: 03/25/19 CLIENT: PASI—FL Custody Seal on Cooler/Box Present? 'Des [d No Seals Intact? ❑Yes QNo Biological Tissue Frozen? ❑Yes ❑No EN/A Packing Material: EBubble Wrap rg Bubble Bags ❑None DOther: Temp Blank? Yes ❑No Thermometer: 0 G87A9155100842 [)(] G87A9170600254 Type of Ice: nWet ❑Blue 0None ❑Dry ❑Melted Note: Each West Virginia Sample must have temp taken (no temp blanks) Temp should be above freezing to 6`C Cooler Temp Read w/temp blank: 02.6 oC Correction Factor: iei,t Cooler Temp Corrected w/temp blank : Average Corrected Temp See Exceptions (no temp blank only): ❑ oC Date/Initials of Person Examining Contents: r% 141;5 AR, CA GA, Did samples originate from a foreign source (internationa' y, including i • . , �HLaiwaii and Puerto Rico)? ❑Yes llo Checklist (r-40 t� 38) and include with SCUR/COC paperwork. USDA Regulated Soil: (® NJA, water sample/Other: Did samples originate in a quarantine zone within the United State _AL, ID, LA. MS, NC, NM, NY, OK, OR, SC, TN, TX or VA (check maps)? " f• If Yes to either question, fill out a Regulate (. COMMENTS: Chain of Custody Present and Filled Out? ®yes ❑No 1. .Chain of Custody Relinquished? ❑X' Yes ❑No 2. Sampler Name and/or Signature an COC? Des ❑No ©N/A 3. Samples Arrived within Hold Time? ®Yes ❑No 4. Short Hold Time Analysis (<72 hr)? Yes No 5. ['Fecal Coliform ❑HPC ❑Total Coliform/E coli ❑BOD/cB0D ❑Hex Chrome ❑Turbidity ❑Nitrate :Nitrite ❑0rthophos Dother Rush Turn Around Time Requested? ❑Yes ®No 6. Sufficient Volume? MYes ❑No 7. Correct Containers Used? -Pace Containers Used? ®Yes ©Yes ❑No ❑No 8. Containers Intact? ®Yes ❑No 9. Field Filtered Volume Received for Dissolved Tests? ❑Yes ❑No ©N/A 10. Is sediment visible in the dissolved container? • Yes • No Is sufficient information available to reconcile the samples to the COC? Matrix: :water VI.S Il ❑011 ❑Other ©Yes ❑No 11. If no, write ID/ Date/Time on Container Below: See Exception 0 All containers needing acid/base preservation have been checked? All containers needing preservation are found to be in compliance with EPA recommendation? (HNO3, H2SO4, <2pH, NaOH >9 Sulfide, NaOH>12 Cyanide) Exceptions: VOA, Coliform, TOC/DOC Oil and Grease, DR0/8015 (water) and Dioxin/PFAS Des :Yes ❑Yes ❑No ❑No ❑No ®N/A ptjN/A 1LN/A 12. 5ample # ❑Zinc Acetate See Exception • NaOH • HNO3 ■ H2SO4 Positive for Res. • Yes Chlorine? INo ■ Headspace in VOA Vials (greater than 6mm)? Dyes ❑No ®N/A 13. See Exception 0 Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes ❑Yes ❑No ❑No (N/A ZN/A 14. Pace Trip Blank Lot II (if purchased): CLIENT NOTIFICATION/RESOLUTION Person Contacted: Comments/Resolution: Date/Time: Field Data Required? ❑Yes ❑No Project Manager Review:J, Note: Whenever there is a discrepancy affecting Nort Carolina compnce says pies, a copy of this form wdii be sent so the North Carolina DEHNR Certification Office 4 i.e out of no!o, incorrect preservative, out of temp, incorrect containers). Date: 3/19/2019 Labe ed by: Report No 10467083_8290FC_DFR Page 28 of 44 Page 7 of 23 (Includes: IFA, SOD, Golden Nematode, Karnol Bunt and Witchweed) ..PaceAnalytica1 Document Name: Regulated Soil Checklist Document Revised: 13Feb2018 Page 1 of 2 Document No.: F-MN-Q-338-Rev.06 Issuing Authority: Pace Minnesota Quality Office To Be Completed by SR Staff: WO: USDA REGULATED SOIL CHECKLIST Date: s) i 1l 5 /11 Initials: (_- .� Sample Origin (circle one): DOMESTIC QUARANTINED FOREIGN (Note: soil samples from Hawaii, Guam, Puerto Rico and the US Virgin Islands are considered to be of a Foreign Source) If Domestic, circle State of Origin: AL AR CA( L) GA LA MS NC NM NY OK OR SC TN TX VA List County: (y) (USDA Permit/Compliance Agreement authorizes movement of samples from these domestic regulated zones) If Quarantined, circle State of Origin: FL ID TX CA List County: (Includes Fruit Fly, Giant African Snail and Pale Cyst Nematode) (Movement is not authorized for Pale Cyst Nematode (la or Giant African Snail PFLJ, remaining quarantines require additional paperwork) If Foreign, list Country of Origin: (Movement from some Canadian Providences is not allowed. Refer to CS-232 Regulated Soil Flow Chart) REQUIREMENT ACTION COMPLETED PPQ-530 Paperwork must be included for any samples from counties with a Fruit Fly Quarantine in TX. Refer to MN-S063 through MN-S065 Scan PPQ-530 to the corresponding Project folder on the x drive. If PPQ-530 is not present, contact the Waste Coordinator and do not continue processing samples. YES NO N/A, Samples from ID may not be moved from the quarantined region. Refer to MN-S055 If samples originated in a quarantined zone, contact the Waste Coordinator and do not continue processing samples. YES NO N/ Samples from Giant African Snail Quarantine in FL may not be moved from the quarantined region. Refer to MN-S068 If samples originated in a quarantined zone, contact the Waste Coordinator and do not continue processing samples. YES NO ' (N/A REQUIREMENT • ACTION 941PLETED "Special Handling" stickers are to be placed on all samples. Did "special handling" stickers get placed on all sample containers? YES' NO Samples must be segregated and stored in designated bins, shelves and coolers. Were samples placed in a designated cooler, containers and shelves? YES NO f;1 Samples must be double contained to prevent accidental release. Were there any signs of breakage or leakage (check for broken glass and/or loose soil in the cooler)? if NO, ice and melt water can be disposed of by normal process (down YES / NO the drain). if YES, were ice and melt water separated from the cooler and disposed of properly? Any broken glass and/or loose soil are to be bagged and placed in a container or active drum (see Waste Coordinator). ice and melt water should be baked at a temperature range of 121-154°F cooled before going down the drain. YES NO (N/A USDA Regulated satellite for 2 hours and then .), Equipment and supplies that have come into contact samples must be decontaminated. Was the cooler(s) and/or countertop(s) decontaminated using either a fresh 10% bleach solution or 70% ethanol? (Gloves and other lab supplies will be bagged and placed in the USDA Regulated satellite container or active drum). /YES f NO 'i, i _.1 Comments: Report No 10467083_8290FCDFR Page 29 of 44 Page 8 of 23 -rceAnalytical Document Name: Regulated Soil Checklist Document Revised: 13Feb2018 Page 2 of 2 Document No.: F-MN-Q-338-Rev.06 Issuing Authority: Pace Minnesota Quality Office To Be Completed by PM andjor PC: Sample Analysis to be conducted (circle all that apply): Name of Subcontract Lab (s): MN Subcontract Lab REQUIREMENT ACTION COMPLETED Permission to ship untreated soil must be on file prior to shipping to any subcontract lab, including IR Pace Labs. Go to: J:\SHARE\PRJ_MGR\10_Client Services Department Documents\Regulated Soils Permits— if permission to ship letter is not there, contact the Waste Coordinator. YES NO . N/A Shipment must include a valid copy of the receiving lab's permit as well as permission to ship letter. Is a copy of all needed paperwork included with the COC? Do NOT ship samples until all necessary paperwork is compiled. YES NO N/A Comments: Project Manager Signature: Date: 3/19/2019 Page 30 of 44 Report No 10467083_8290FC_DFR Page 9 of 23 Report No 10467083_8290FCDFR 2 3 4 Chain of Custody Samples were sent directly to the Subcontracting Laboratory. Workorder: 35454205 Workorder Christina Raschke Pace Analytical South Florida 3610 Park Central Blvd N Pompano Beach, FL 33064 Phone (954)582-4300 TE-29 (0-1') TE-13 Debns (2-4') Transfers 1 2 3 Relea e By Name: 2018-3057/Melreese Golf Course Pace Analytical Minnesota 1700 Elm Street SE Suite 200 Minneapolis, MN 55414 Phone (612)607-1700 3/13/2019 08:40 35454205001 Solid 3/13/2019 13:00 , Cooler temperature on Receipt °C DatefTime 35454205002 Received By 2A9 \1C`o Solid J State Of Origin: FL Cert. Needed: 1 1 Yes Owner Received Date: xin and Furans Daterrime ti`/3/l5 (rr ace No Analytical www.veoerabseom-. 3/14/2019 Results Requested By: 4/1/2019 WOp:10467083 IIIIII14111Illllullll Custody Seal Y or / N j I Received on Ice ,'Y) or N + Samples Intact( Y) or N `"In order to maintain client confidentiality, location/name of the sampling �-� p g siteampler's name and signature may not be provided on this COC document. This chain of custody is considered complete as is since this information is available in the owner laboratory. LAB USE ONLY guesday, April 02, 2019 11:06:06 AM o_ A FMT-ALL-C-002rev 00 24March2009 Page 1 of 1 FaceArnalytical ' Sample Condition Upon. Receipt Courier: Tracking Number: Client Name: aid Ex CUPS CUSPS ❑Client Pace OSpeeDee ❑Commercial See Exception 0--k 2 '3u isf city 1 ❑ Document Name: Sample Condition Upon Receipt Form Document No.: F-MN-L-213-rev.25 Document Revised: 06feb2019 Page 1 of 1 Issuing Authority: Pace Minnesota Quality Office Projecb : WO# :10467083 PM: KNH Due Date: 04/01/19 CLIENT: PASI-FL Custody Seal on Cooler/Box Present? QYes [2(GO" Seals Intact? ❑Yes [ Packing Material: []Bubble Wrap D8ubble Bags ❑None ❑other: Thermometer: ❑ G87A915S100842 ,7A9170600254 Type of Ice: E<fiet ❑Blue Note: Each West Virginia Sample must have temp taken (no temp blanks) Temp should be above freezing to 6°C Cooler Temp Read w/temp blank: i Correction Factor: / i (' Cooler Temp Corrected w/temp blank : Biological Tissue Frozen? CYes DNo L]N/A Temp Blank? ❑Yes ❑None ❑Dry ❑Melted °C -.. USDA Regulated Sod: ( 0 N/A, water sample/Other: • ) l Date/Initials of Person Examining Contents: i u Did samples originate in a quarantine zone within the United States: AL,. AR, FL, GA, Did samples originate from a foreign source (Internationally, including Average Corrected Temp See Exceptions (no tentp blank only): ❑ - °C 1D, LA. MS, NC, NM NY OK OR SC TN , TX or VA (check maps)? QSes o Hawaii and Puerto Rico)? ❑Yeso If Yes to either question, fill out a Regulated Soii Checklist (F-MN-Q338) and inraud th SCUR e wI /COC paperwork. COMMENTS: Chain of Custody Present and Filled Out? ®fes. ❑No 1. Chain of Custody Relinquished? Des ONo 2. Sampler Name and/or Signature on COC? ❑Yes ❑No /A 3. Samples Arrived within Hold Time? ❑W ❑No 4. Short Hold Time Analysis (<72 hrj? ❑yeo EA) 5. ❑Fecal Coliform ❑HPC ❑Total Coliform/E coli ❑BOD/cBOD ❑Hex Chrome ❑Turbidity ❑Nitrate ❑Nitrite ❑Orthophos ❑Other Rush Turn Around Time Requested? 21‹. ❑No 6. Sufficient Volume? Q`ies CI No 7. Correct Containers Used? -Pace Containers Used? Qf'es )]Yes ❑No ❑No 8. Containers Intact? BY -es ❑No 9. Field Filtered Volume Received for Dissolved Tests? ❑Yes ❑No EtgrA 10. Is sediment visible in the dissolved container? 0Yes QNo Is sufficient information available to reconcile the samples to the COC? Matrix: DWateroil 0011 Pother dyes ❑No 11. If no, write ID/ Date/Time on Container Below: See Exception 0 All containers needing acid/base preservation have been checked? All containers needing preservation are found to be in compliance with EPA recommendation? (HNO3, H2SO4, <2pH, NaOH >9 Sulfide, NaOH>12 Cyanide) Exceptions: VOA, Coliform, TOC/DOC Oil and Grease, I DRO/8015 (water) and Dioxin/PFAS Des Dyes ❑Yes ❑No ❑No ❑No ON/A ❑.N/A 210A 12. Sample #i ❑ NaOH 0 HNO3 H2S0s II Zinc Acetate Positive for Res. QYes see Exception Chlorine? []No 0 Headspace in VOA Vials (greater than 6mm)? Trip Yes No 13. See Exception 24 . Blank Present? Trip Blank Custody Seals Present? Dyes r„__ DNo —.._ Cti�l/A 14. , ! i ;, . d Il CLIENT NOTIFICATION/RESOLUTION Person Contacted: Comments/Resolution: Additional volume received 4/3/19. ace i rip an Lot ri (if purchased): Date/Time: Field Data Required? DYes ❑No i;roject Manager Review: Note: Whenever there is a discrepancy of J , arolir.a c 'old, incorrect preservative• out of temp, incorrect containers:-. a.�ce s Report No 104670838290FC_DFR Uate: 4/3/2019 'pies, a copy of this Will be sent to the North Carolina DEHNR Certification Office ( i.e out of Ci Page 32 of 44 Page 11 of 23 - aceAna/ical Document Name: Regulated Soil Checklist Document Revised: 13Feb2018 Page 1 Of 2 Issuing Authority: F-MN-Q-338-Rev.06 Pace Minnesota Quality Office Document No.: USDA REGULATED SOIL CHECKLIST To Be Completed by SR Staff: `NO: 10467083 Date: �i/4/1.1 Initials: L 1 f L Sample Origin (circle one): DOMESTIC) QUARANTINED FOREIGN (Note: soil samples from Hawaii, Guam, Puerto Rico and the US Virgin Islands ore considered to be of a Foreign Source) If Domestic, circle State of Origin: AL AR CA FL GA LA MS NC NM NY OK OR SC TN TX VA (includes: IFA, SOD, Golden Nematode, Kornai Buntand Witchweed) List County: } Jo y f ' 1 1�7 i t01 ti;;CfLO SvJot (USDA Permit/Compliance Agreement authorizes movement of samples from these domestic regulated zones) � If Quarantined, circle State of Origin: FL ID TX CA List County: (includes Fruit Fly, Giant African Snail and Pale Cyst Nematode) (Movement is not authorized for Pale Cyst Nematode (!D or Giant African Snail (FLJ, remaining quarantines require additional paperwork) If Foreign, fist Country of Origin: . (Movement from some Canadian Providences is not allowed. Refer to CS-232 Regulated Soil Flow Chart) REQUIREMENT ACTION COMPLETED PPQ-530 Paperwork must be included for any samples from counties with a Fruit Fly Quarantine in TX. Refer to MN-5063 through MN-5065 Scan PPQ-530 to the corresponding Project folder on the x drive. If PPQ-530 is not present, contact the Waste Coordinator and do not continue processing samples. YES NO c)N/A Samples from ID may not be moved from the quarantined region. Refer to MN-S055 If samples originated in a quarantined zone, contact the Waste Coordinator and do not continue processing samples. YES NO (ILA) Samples from Giant African Snail Quarantine in FL may not be moved from the quarantined region. Refer to MN-5068 If samples originated in a quarantined zone, contact the Waste Coordinator and do not continue processing samples. � YES NO N/R; REQUIREMENT ACTION CO PLETED "Special Handling" stickers are to be placed on all samples. Did "special handling" stickers get placed on all sample containers? TES NO �- Samples must be segregated and stored in designated bins, shelves and coolers. Were samples placed in a designated cooler, containers and shelves? E / YES l NO X. Were there any signs of breakage or leakage (check for broken glass and/or loose soil in the cooler)? !f NO, ice and melt water can be disposed of by normal process (down YES / the drain). Samples must be double contained to prevent accidental release. If YES, were ice and melt water separated from the cooler and disposed of properly? Any broken glass and/or loose soil are to be bagged and placed in a container or active drum (see Waste Coordinator). Ice and melt water should be baked at a temperature range of 121-154°F YES NO N/A ) USDA Regulated satellite for 2 hours and then Equipment and supplies that have come into contact samples must be decontaminated. Was the coolers) and/or countertop(s) decontaminated using either a fresh 10% bleach solution or 70% ethanol? (Gloves and other lab supplies will be bagged and placed in the USDA Regulated satellite container or active drum). ` YES NO ' Comments: Report No 104670838290FCDFR Page 33 of 44 Page 12 of 23 / . PaceAnalytical' Document Name: Regulated Soil Checklist Document Revised: 13Feb2018 Page 2 of 2 Document No.: F-MN-Q-338-Rev.06 issuing Authority: Pace Minnesota Quality Office To Be Completed by PM and/or PC: Sample Analysis to be conducted (circle all that apply): Name of Subcontract Lab (s): MN Subcontract Lab REQUIREMENT ACTION COMPLETED Permission to ship untreated soil must be on file prior to shipping to any subcontract lab, including IR Pace Labs. Shipment must include a valid copy of the receiving lab's permit as well as permission to ship letter. Go to: J:\SHARE\PRJ_MGR\10_Client Services Department Documents\Regulated Soils Permits — if permission to ship letter is not there, contact the Waste Coordinator. YES NO N/A Is a copy of all needed paperwork included with the COC? Do NOT ship samples until all necessary paperwork is compiled. YES NO N/A Comments: Project Manager Signature: Report No 10467083_8290FC_DFR Date: 4/3/2019 Page 34 of 44 Page 13 of 23 ' .�c?Ct?/�fJr7�j/C%fc3i Document Name: SCUR Exception Form — Coolers Above 6"C p Document Revised: 04Feb2019 Page 1 of 1 Document No.: F-MN-C-298-Rev.01 Issuing Authority: Pace Minnesota Quality Office During sample triage, this form is to be placed in each cooler that arrives above 6.0 degrees Celsius SCUR Exceptions: Out of Temp Sample IDs Container Type #of Containers PM Notified? UYes ■No -_ If yes, indicate who was co indicate reason e. no, indicate reason why. why. Multiple Cooler Project? [jres ■No If you answered yes, fill'out information to the left. No Temp Blank —_ Read Temp CorrectedAve TempmpTemp e7 .. �' Other Issues Issue Type: Sample ID Container Type # of Containers H Adjustment L Tracking Number Sample ID Type of Preserv. pH Upon Receipt Date Adjusted Time Adjusted Amount Added (mL) Lot u Added pH After In Compliance after addition? Initials •Yes II No Yes ❑No • Yes III No •Yes •No Report No 104670838290FCDFR Page 35 of 44 Page 14 of 23 Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 ace Analytical TM Reporting Flags A = Reporting Limit based on signal to noise B = Less than 10x higher than method blank level C = Result obtained from confirmation analysis D = Result obtained from analysis of diluted sample E = Exceeds calibration range I = Interferencepresent J = Estimated value L = Suppressive interference, analyte may be biased low Nn = Value obtained from additional analysis P = PCDEInterference R = Recovery outside target range S = Peak saturated U = Analyte not detected V = Result verified by confirmation analysis X = %D Exceeds limits Y = Calculated using average of daily RFs * = SeeDiscussion REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10467083_8290FC_DFR Tel: 612-607-1700 Fax:612-607-6444 Page 36 of 44 Page 15 of 23 Appendix B Sample Analysis Summary Report No 10467083_8290FC_e Analytical Services, Inc. Page 37 of 44 Page 16 of 23 Analytical Client's Sample ID Lab Sample ID Filename Injected By Total Amount Extracted % Moisture Dry Weight Extracted ICAL ID CCaI Filename(s) Method Blank ID Native Isomers TM Metho d 8290 Sample Analysis Results Client - PASI Florida TE-29 (0-1') 35454205001 F190408A_14 SMT 14.1 g 28.0 10.1 g F190112 F190408A_02 & F190408A_16 BLANK-69627 Conc EMPC EDL ng/Kg ng/Kg ng/Kg Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612- 607-6444 Matrix Solid Dilution NA Collected 03/13/2019 08:40 Received 04/03/2019 08:55 Extracted 04/03/2019 15:15 Analyzed 04/08/2019 20:38 Internal Standards 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 0.17 U 0.17 U 0.23 U 0.35 0.18 U 0.14 U 0.16 U 0.13 U 0.13 U 1,2,3,4,7,8-HxCDF 0.18 U 1,2,3,6,7,8-HxCDF 0.13 U 2,3,4,6,7,8-HxCDF 0.14 U 1,2,3,7,8,9-HxCDF 0.16 U Total HxCDF 0.35 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD 0.15 U 0.49 1.8 1.2 0.14 U 1.2 9.4 19 100 0.17 2,3,7,8-TCDF-13C 0.17 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 0.23 2,3,4,7,8-PeCDF-13C 0.23 J 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 0.18 1,2,3,6,7,8-HxCDF-13C 0.14 2,3,4,6,7,8-HxCDF-13C 0.16 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 0.13 1,2,3,6,7,8-HxCDD-13C 0.13 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 0.18 0.13 0.14 0.16 0.15 0.15 0.12 0.31 0.11 0.13 0.17 0.14 0.15 0.14 0.14 1,2,3,4-TCDD-13C J 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 J IJ J J J 2.2 0.80 IJ 1.9 ng's Percent Added Recovery 2.00 40 2.00 42 2.00 41 2.00 33 R 2.00 44 2.00 32 R 2.00 41 2.00 42 2.00 38 R 2.00 37 R 2.00 37 R 2.00 28 R 2.00 32 R 2.00 35 R 4.00 25 R 2.00 NA 2.00 NA 0.20 65 Total 2, 3, 7, 8-TC D D Equivalence: 0.29 ng/Kg (Lower -bound - Using ITE Factors) Conc = Concentration (Totals include 2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit ND = Not Detected NA = Not Applicable NC = Not Calculated Results reported on a dry weight basis and are valid to no more than 2 significant figures. J = Estimated value R = Recovery outside target range I = Interference present REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10467083_8290FC_DFR Page 17 of 23 Page 38 of 44 AnalyticalTM Clients Sample ID Lab Sample ID Filename Injected By Total Amount Extracted Moisture Dry Weight Extracted ICAL ID CCaI Filename(s) Method Blank ID Native Isomers Method 8290 Sample Analysis Results Client - PASI Florida TE-13 Debris (2-4') 35454205002 F190408A_15 SMT 13.8 g 27.1 10.1 g F190112 F190408A_02 & F190408A_16 BLANK-69627 Conc EMPC EDL ng/Kg ng/Kg ng/Kg Matrix Dilution Collected Received Extracted Analyzed Internal Standards Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis. MN 55414 Tel:612-607-1700 Fax: 612- 607-6444 Solid NA 03/13/2019 13:00 04/03/2019 08:55 04/03/2019 15:15 04/08/2019 21:21 ng's Percent Added Recovery 2,3,7,8-TCDF 0.75 0.25 Total TCDF 5.2 0.25 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 0.21 U 0.21 15 0.21 0.37 0.81 7.8 0.23 0.15 0.19 0.75 0.20 6.3 0.20 0.75 5.0 0.80 3.3 31 0.63 0.10 0.12 0.76 0.11 0.18 0.15 0.12 1.9 0.13 0.12 0.17 0.14 1,2,3,4,6,7,8-HpCDF 7.4 0.22 1,2,3,4,7,8,9-HpCDF 0.45 0.22 Total HpCDF 18 0.22 1,2,3,4,6,7,8-HpCDD 90 0.15 Total HpCDD 170 0.15 OCDF OCDD 13 1.1 690 1.1 J 2,3,7,8-TCDF-13C 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 2,3,4,7,8-PeCDF-13C 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C J 1,2,3,6,7,8-HxCDF-13C J 2,3,4,6,7,8-HxCDF-13C 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C IJ 1,2,3,6,7,8-HxCDD-13C 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C IJ 1,2,3,4,6,7,8-HpCDD-13C J OCDD-13C IJ IJ 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C J J IJ 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 4.00 2.00 2.00 2,3,7,8-TCDD-37C14 0.20 Total 2, 3, 7, 8-TC D D IJ Equivalence: 3.4 ng/Kg (Lower -bound - Using ITE Factors) 41 43 42 40 46 43 46 44 41 45 40 37 R 33 R 37 R 26 R NA NA 59 Conc = Concentration (Totals include 2,3.7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit ND = Not Detected NA = Not Applicable NC = Not Calculated Results reported on a dry weight basis and are valid to no more than 2 significant figures. J = Estimated value R = Recovery outside target range 1= Interference present REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without thewritten consent of Pace Analytical Services, Inc. Report No 10467083_8290FC_DFR Page 18 of 23 Page 39 of 44 Analytical Lab Sample Name Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) Native Isomers TM Me thod 8290 Blank Analysis Results DFBLKLF BLANK-69627 F190408A_09 20.4 g F190112 F190408A_02 & F190408A_16 Conc EMPC ng/Kg ng/Kg EDL ng/Kg Matrix Dilution Extracted Analyzed Injected By Internal Standards Pace Analytical Services. LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 TeI:612-607-1700 Fax:612-607-6444 Solid NA 04/03/2019 15:15 04/08/2019 17:02 SMT 2,3,7,8-TCDF 0.056 U Total TCDF 0.056 U 2,3,7,8-TCDD 0.11 U Total TCDD 0.11 U 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD 0.076 U 0.050 U 0.063 U 0.089 U 0.089 U 0.031 U 0.028 U 0.027 U 0.040 U 0.031 U 0.074 U 0.090 U 0.076 U 0.080 U 0.058 U 0.087 U 0.073 U 0.056 2,3,7,8-TCDF-13C 0.056 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 0.11 2,3,4,7,8-PeCDF-13C 0.11 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 0.076 1,2,3,6,7,8-HxCDF-13C 0.050 2,3,4,6,7,8-HxCDF-13C 0.063 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 0.089 1,2,3,6,7,8-HxCDD-13C 0.089 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 0.031 0.028 0.027 0.040 0.031 0.074 0.090 0.076 0.080 ng's Percent Added Recovery 2.00 59 2.00 58 2.00 56 2.00 53 2.00 59 2.00 56 2.00 60 2.00 61 2.00 55 2.00 58 2.00 54 2.00 50 2.00 45 2.00 50 4.00 34 R 1,2,3,4-TCDD-13C 2.00 NA 1,2,3,7,8,9-HxCDD-13C 2.00 NA 2,3,7,8-TCDD-37CI4 0.20 57 0.058 Total 2,3,7,8-TCDD 0.087 Equivalence: 0.00 ng/Kg 0.073 (Lower -bound - Using ITE Factors) 0.084 U 0.084 0.084 U 0.084 OCDF 0.19 U 0.19 OCDD 0.35 U 0.35 Conc=Concentration (Totals include 2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL= Estimated Detection Limit Results reported on a total weight basis and are valid to no more than 2 significant figures. R = Recovery outside target range REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10467083_8290FC_DFR Page 40 of 44 Page 19 of 23 Analytical Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) Method Blank ID Native Isomers 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD TM Method 8290 Laboratory Control Spike Results LCS-69628 F190408A_05 21.0 g F190112 F190408A_02 & F190408A_16 BLANK-69627 Qs Qm (ng) (ng) Rec. 0.20 0.21 105 0.20 0.23 113 1.0 1.1 110 1.0 1.1 113 1.0 0.98 98 1.0 1.2 116 1.0 1.1 112 1.0 1.1 106 1.0 1.1 106 1.0 1.1 112 1.0 1.3 125 1.0 1.1 114 1.0 1.2 119 1.0 1.0 103 1.0 1.0 104 2.0 2.1 103 2.0 2.2 110 Matrix Dilution Extracted Analyzed Injected By Internal Standards 2,3,7,8-TCDF-13C 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 2,3,4,7,8-PeCDF-13C 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 1,2,3,6,7,8-HxCDF-13C 2,3,4,6,7,8-HxCDF-13C 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 1,2,3,6,7,8-HxCDD-13C 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37C14 Pace Analytical Services. LLC 1700 Elm Street - Suite 200 Minneapolis. MN 55414 Tel: 612-607-1700 Fax:612-607-6444 Solid NA 04/03/2019 15:15 04/08/2019 14:10 SMT ng's Percent Added Recovery 2.0 51 2.0 52 2.0 55 2.0 54 2.0 63 2.0 54 2.0 57 2.0 52 2.0 49 2.0 51 2.0 49 2.0 45 2.0 40 2.0 45 4.0 31 R 2.0 NA 2.0 NA 0.20 56 Qs = Quantity Spiked Qm = Quantity Measured Rec. = Recovery (Expressed as Percent) R = Recovery outside of target range Y = RF averaging used in calculations Nn = Value obtained from additional analysis NA = Not Applicable * = See Discussion REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10467083_8290FC_DFR Page 41 of 44 Page 20 of 23 Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Analytical Client's Sample ID Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) Method Blank ID Native Isomers 2,3,7,8-TCDF 2,3,7,8-TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF 1,2,3,7,8-PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF 1,2,3,4,6,7,8-HpCDD OCDF OCDD TM Me thod 8290 Spiked Sample Report Client - PASI Florida TE-13 Debris (2-4')-MS 35454205002-MS F190408A_06 13.8 g F190112 F190408A_02 & F190408A_16 BLANK-69627 Qs Qm % (ng) (ng) Rec. 0.20 0.19 95 0.20 0.20 98 1.00 0.97 97 1.00 1.01 101 1.00 0.86 86 1.00 1.04 104 1.00 0.95 95 1.00 0.95 95 1.00 0.92 92 1.00 0.95 95 1.00 1.08 108 1.00 1.67 167 1.00 1.08 108 1.00 0.93 93 1.00 1.59 159 2.00 2.16 108 2.00 6.94 347 Matrix Dilution Extracted Analyzed Injected By Internal Standards Tel: 612-607-1700 Fax: 612-607-6444 Solid NA 04/03/2019 15:15 04/08/2019 14:53 SMT 2,3,7,8-TCDF-13C 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 2,3,4,7,8-PeCDF-13C 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 1,2,3,6,7,8-HxCDF-13C 2,3,4,6,7,8-HxCDF-13C 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 1,2,3,6,7,8-HxCDD-13C 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C ng's Percent Added Recovery 2.00 54 2.00 56 2.00 54 2.00 26 R 2.00 62 2.00 23 R 2.00 37 R 2.00 39 R 2.00 43 2.00 24 R 2.00 30 R 2.00 17 R 2.00 33 R 2.00 26 R 4.00 17 R 1,2,3,4-TCDD-13C 2.00 NA 1,2,3,7,8,9-HxCDD-13C 2.00 NA 2,3,7,8-TCDD-37CI4 0.20 63 Qs = Quantity Spiked Qm = Quantity Measured Rec. = Recovery (Expressed as Percent) Results reported on a dry weight basis and are valid to no more than 2 significant figures. R = Recovery outside target range REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10467083_8290FC_DFR Page 21 of 23 Page 42 of 44 ace Analytical iM Client's Sample ID Lab Sample ID Filename Total Amount Extracted ICAL ID CCal Filename(s) Method Blank ID Method 8290 Spiked Sample Report Client - PASI Florida TE-13 Debris (2-4')-MSD 35454205002-MSD F190408A_07 13.8 g F190112 F190408A_02 & F190408A16 BLANK-69627 Native Qs Qm % Isomers (ng) (ng) Rec. 2,3,7,8-TCDF 0.20 0.21 103 2,3,7,8-TCDD 0.20 0.20 99 1,2,3,7,8-PeCDF 1.00 0.98 98 2,3,4,7,8-PeCDF 1.00 1.02 102 1,2,3,7,8-PeCDD 1.00 0.90 90 1,2,3,4,7,8-HxCDF 1.00 1.03 103 1,2,3,6,7,8-HxCDF 1.00 0.98 98 2,3,4,6,7,8-HxCDF 1.00 0.98 98 1,2,3,7,8,9-HxCDF 1.00 0.95 95 1,2,3,4,7,8-HxCDD 1.00 1.03 103 1,2,3,6,7,8-HxCDD 1.00 1.14 114 1,2,3,7,8,9-HxCDD 1.00 1.06 106 1,2,3,4,6,7,8-HpCDF 1.00 1.18 118 1,2,3,4,7,8,9-HpCDF 1.00 0.95 95 1,2,3,4,6,7,8-HpCDD 1.00 2.28 228 OCDF 2.00 2.00 100 OCDD 2.00 11.90 595 Matrix Dilution Extracted Analyzed Injected By Internal Standards Pace Analytical Services. LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612-607-6444 Solid NA 04/03/2019 15:15 04/08/2019 15:36 SMT 2,3,7,8-TCDF-13C 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 2,3,4,7,8-PeCDF-13C 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 1,2,3,6,7,8-HxCDF-13C 2, 3,4, 6, 7, 8-HxC DF-13C 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 1,2,3,6,7,8-HxCDD-13C 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C ng's Percent Added Recovery 2.00 57 2.00 62 2.00 59 2.00 58 2.00 67 2.00 50 2.00 55 2.00 56 2.00 49 2.00 52 2.00 50 2.00 41 2.00 40 2.00 43 4.00 31 R 1,2,3,4-TCDD-13C 2.00 NA 1,2,3,7,8,9-HxCDD-13C 2.00 NA 2,3,7,8-TCDD-37CI4 0.20 66 Qs = Quantity Spiked Qm = Quantity Measured Rec. = Recovery (Expressed as Percent) Results reported on a dry weight basis and are valid to no more than 2 significant figures. R = Recovery outside target range REPORT OF LABORATORYANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10467083_8290FC_DFR Page 43 of 44 Page 22 of 23 ace AnalVtical*M Method 8290 Spike Sample Results Client - PASI Florida Pace Analytical Services, Inc. 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612-607-6444 Client Sample ID TE-13 Debris (2-4') Dry Weights Lab Sample ID 35454205002 Sample Filename F190408A_15 Sample Amount 10.1 g MS ID 35454205002-MS MS Filename F190408A_06 MS Amount 10.0 g MSD ID 35454205002-MSD MSD Filename F190408A_07 MSD Amount 10.0 g Analyte Sample Conc. MS/MSD Qs MS Qm MSD Qm ng/Kg (ng) (ng) (ng) RPD Background Subtracted MS % Rec. MSD % Rec. RPD 2,3,7,8-TCDF 0.754 0.20 0.19 0.21 7.6 91 99 7.9 2,3,7,8-TCDD 0.000 0.20 0.20 0.20 0.4 98 99 0.4 1,2,3,7,8-PeCDF 0.371 1.00 0.97 0.98 1.0 97 98 1.1 2,3,4,7,8-PeCDF 0.814 1.00 1.01 1.02 1.1 100 101 1.1 1,2,3,7,8-PeCDD 0.000 1.00 0.86 0.90 4.6 85 89 4.6 1,2,3,4,7,8-HxCDF 0.000 1.00 1.04 1.03 1.8 104 102 1.8 1,2,3,6,7,8-HxCDF 0.748 1.00 0.95 0.98 3.4 94 97 3.4 2,3,4,6,7,8-HxCDF 0.000 1.00 0.95 0.98 2.5 94 97 2.5 1,2,3,7,8,9-HxCDF 0.000 1.00 0.92 0.95 4.2 91 95 4.2 1,2,3,4,7,8-HxCDD 0.797 1.00 0.95 1.03 8.5 94 102 8.5 1,2,3,6,7,8-HxCDD 3.332 1.00 1.08 1.14 5.2 105 111 5.4 1,2,3,7,8,9-HxCDD 0.000 1.00 1.67 1.06 44.5 165 104 45.1 1,2,3,4,6,7,8-HpCDF 7.399 1.00 1.08 1.18 8.4 101 110 9.0 1,2,3,4,7,8,9-HpCDF 0.000 1.00 0.93 0.95 2.0 93 95 2.0 1,2,3,4,6,7,8-HpCDD 89.623 1.00 1.59 2.28 35.6 69 138 66.7 OCDF 13.169 2.00 2.16 2.00 8.0 101 93 8.5 OCDD 685.593 2.00 6.94 11.90 52.7 3 251 195.5 Definitions MS = Matrix Spike MSD = Matrix Spike Duplicate Qm = Quantity Measured Qs = Quantity Spiked % Rec. = Percent Recovery RPD = Relative Percent Difference NA = Not Applicable NC = Not Calculated CDD = Chlorinated dibenzo-p-dioxin CDF = Chlorinated dibenzo-p-furan T = Tetra Pe = Penta Hx = Hexa Hp = Hepta 0 = Octa Thge 44 of 44 F ,rt No 10467083_8290FC_DFR Page 23 of 23 aceAnalytical www.pacelabs.com April 12, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456820 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 27, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry, EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 33 2ceAnalytical® www.pacelabs.com CERTIFICATIONS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456820 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alaska DEC- CS/UST/LUST Alabama Certification #: 41320 Arizona Certification# AZ0819 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 33 aceAnalytical www.pacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456820 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35456820001 TE-31 (2-4) Solid 03/25/19 09:13 03/27/19 17:35 35456820002 TE-27 (0-2) Solid 03/25/19 12:06 03/27/19 17:35 35456820003 TE-25 (0-2) Solid 03/25/19 13:10 03/27/19 17:35 35456820004 TE-33 (0-2) Solid 03/25/19 14:55 03/27/19 17:35 35456820005 TE-33 (2-4) Solid 03/25/19 15:00 03/27/19 17:35 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 33 SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456820 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35456820001 TE-31 (2-4) 35456820002 TE-27 (0-2) 35456820003 TE-25 (0-2) 35456820004 TE-33 (0-2) 35456820005 TE-33 (2-4) EPA 6020 FDV 3 PASI-O ASTM D2974-87 CLT 1 PASI-O EPA6020 FDV 3 PASI-O ASTM D2974-87 CLT 1 PASI-O EPA 6020 FDV 3 PASI-O ASTM D2974-87 CLT 1 PASI-O EPA 6020 FDV 3 PASI-O ASTM D2974-87 CLT 1 PASI-O EPA 6020 FDV 3 PASI-O ASTM D2974-87 CLT 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 33 www.pacelabs.com SUMMARY OF DETECTION Project: 2018-30571Melreese Golf Course Pace Project No.: 35456820 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed 35456820001 TE-31 (2-4) EPA 6020 Arsenic 4.0 mg/kg 1.2 04/04/19 14:06 EPA 6020 Barium 9.3 mg/kg 1.2 04/04/19 14:06 EPA 6020 Lead 14.8 mg/kg 1.2 04/04/19 14:06 ASTM D2974-87 Percent Moisture 15.7 % 0.10 04/04/19 09:02 35456820002 TE-27 (0-2) EPA 6020 Arsenic 13.2 mg/kg 1.3 04/04/19 14:07 EPA 6020 Barium 29.4 mg/kg 1.3 04/04/19 14:07 EPA 6020 Lead 169 mg/kg 1.3 04/04/19 14:07 ASTM D2974-87 Percent Moisture 13.4 % 0.10 04/04/19 09:02 35456820003 TE-25 (0-2) EPA 6020 Arsenic 3.5 mg/kg 1.3 04/04/19 14:08 EPA 6020 Barium 6.9 mg/kg 1.3 04/04/19 14:08 EPA 6020 Lead 15.0 mg/kg 1.3 04/04/19 14:08 ASTM D2974-87 Percent Moisture 16.5 % 0.10 04/04/19 09:02 35456820004 TE-33 (0-2) EPA 6020 Arsenic 36.8 mg/kg 1.2 04/04/19 14:10 EPA 6020 Barium 29.6 mg/kg 1.2 04/04/19 14:10 -PA 6020 Lead 159 mg/kg 1.2 04/04/19 14:10 .ASTM D2974-87 Percent Moisture 12.8 % 0.10 04/04/19 09:02 35456820005 TE-33 (2-4) EPA 6020 Arsenic 58.1 mg/kg 1.7 04/04/19 14:12 EPA 6020 Barium 329 mg/kg 1.7 04/04/19 14:12 EPA 6020 Lead 1890 mg/kg 4.3 04/04/19 14:25 ASTM D2974-87 Percent Moisture 33.0 % 0.10 04/04/19 09:03 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 33 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456820 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: TE-31 (2-4) Lab ID: 35456820001 Collected: 03/25/19 09:13 Received: 03/27/19 17:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Arsenic 4.0 mg/kg 1.2 0.44 20 04/04/19 03:10 04/04/19 14:06 7440-38-2 Barium 9.3 mg/kg 1.2 0.51 20 04/04/19 03:10 04/04/19 14:06 7440-39-3 Lead 14.8 mg/kg 1.2 0.42 20 04/04/19 03:10 04/04/19 14:06 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 15.7 % 0.10 0.10 1 04/04/19 09:02 Date: 04/12/2019 10:22 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 33 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456820 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: TE-27 (0-2) Lab ID: 35456820002 Collected: 03/25/19 12:06 Received: 03/27/19 17:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Arsenic 13.2 mg/kg 1.3 0.49 20 04/04/19 03:10 04/04/19 14:07 7440-38-2 Barium 29.4 mg/kg 1.3 0.56 20 04/04/19 03:10 04/04/19 14:07 7440-39-3 Lead 169 mg/kg 1.3 0.46 20 04/04/19 03:10 04/04/19 14:07 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 13.4 % 0.10 0.10 1 04/04/19 09:02 Date: 04/12/2019 10:22 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 33 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456820 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: TE-25 (0-2) Lab ID: 35456820003 Collected: 03/25/19 13:10 Received: 03/27/19 17:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Arsenic 3.5 mg/kg 1.3 0.49 20 04/04/19 03:10 04/04/19 14:08 7440-38-2 Barium 6.9 mg/kg 1.3 0.56 20 04/04/19 03:10 04/04/19 14:08 7440-39-3 Lead 15.0 mg/kg 1.3 0.46 20 04/04/19 03:10 04/04/19 14:08 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 16.5 % 0.10 0.10 1 04/04/19 09:02 Date: 04/12/2019 10:22 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 33 www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456820 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: TE-33 (0-2) Lab ID: 35456820004 Collected: 03/25/19 14:55 Received: 03/27/19 17:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Arsenic 36.8 mg/kg 1.2 0.44 20 04/04/19 03:10 04/04/19 14:10 7440-38-2 Barium 29.6 mg/kg 1.2 0.51 20 04/04/19 03:10 04/04/19 14:10 7440-39-3 Lead 159 mg/kg 1.2 0.42 20 04/04/19 03:10 04/04/19 14:10 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 12.8 % 0.10 0.10 1 04/04/19 09:02 Date: 04/12/2019 10:22 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 33 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456820 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: TE-33 (2-4) Lab ID: 35456820005 Collected: 03/25/19 15:00 Received: 03/27/19 17:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA6020 Preparation Method: EPA3050 Arsenic 58.1 mg/kg 1.7 0.66 20 04/04/19 03:10 04/04/19 14:12 7440-38-2 Barium 329 mg/kg 1.7 0.76 20 04/04/19 03:10 04/04/19 14:12 7440-39-3 Lead 1890 mg/kg 4.3 1.6 50 04/04/19 03:10 04/04/19 14:25 7439-92-1 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 33.0 % 0.10 0.10 1 04/04/19 09:03 Date: 04/12/2019 10:22 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 33 /2ceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456820 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 528282 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 35456820001, 35456820002, 35456820003, 35456820004, 35456820005 METHOD BLANK: 2859462 Matrix: Solid Associated Lab Samples: Parameter 35456820001, 35456820002, 35456820003, 35456820004, 35456820005 Blank Reporting Units Result Limit MDL Analyzed Qualifiers Arsenic mg/kg 0.45 U 1.2 0.45 04/04/19 13:28 Barium mg/kg 0.51 U 1.2 0.51 04/04/19 13:28 Lead mg/kg 0.42 U 1.2 0.42 04/04/19 13:28 LABORATORY CONTROL SAMPLE: 2859463 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic mg/kg 56.6 51.7 91 80-120 Barium mg/kg 56.6 55.0 97 80-120 Lead mg/kg 56.6 53.9 95 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2859464 2859465 MS MSD 35456168001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic mg/kg 5.2 60.2 55.1 65.2 55.9 100 92 75-125 15 20 Barium mg/kg 4.0 60.2 55.1 65.6 59.4 102 101 75-125 10 20 Lead mg/kg 1.3 60.2 55.1 60.5 53.6 98 95 75-125 12 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/12/2019 10:22 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 33 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456820 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 528363 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 35456820001, 35456820002, 35456820003, 35456820004, 35456820005 SAMPLE DUPLICATE: 2859764 2616432001 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture % 88.4 88.4 0 10 SAMPLE DUPLICATE: 2859765 35457084002 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture 17.5 17.0 3 10 SAMPLE DUPLICATE: 2859766 35457084011 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture 17.2 17.5 2 10 SAMPLE DUPLICATE: 2859767 35458660003 Dup Parameter Units Result Result RPD Max RPD Qualifiers Percent Moisture % 24.4 19.3 23 10 J(D6) Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/12/2019 10:22 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 33 aceAnalytical www.pacelabs.com QUALIFIERS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456820 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: 528359 [1] Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. ANALYTE QUALIFIERS U J(D6) Compound was analyzed for but not detected. Estimated Value. The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. Date: 04/12/2019 10:22 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 33 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456820 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID QC Batch Method Analytical QC Batch Analytical Method Batch 35456820001 TE-31 (2-4) EPA 3050 528282 EPA 6020 528359 35456820002 TE-27 (0-2) EPA 3050 528282 EPA 6020 528359 35456820003 TE-25 (0-2) EPA 3050 528282 EPA 6020 528359 35456820004 TE-33 (0-2) EPA 3050 528282 EPA 6020 528359 35456820005 TE-33 (2-4) EPA 3050 528282 EPA 6020 528359 35456820001 TE-31 (2-4) ASTM D2974-87 528363 35456820002 TE-27 (0-2) ASTM D2974-87 528363 35456820003 TE-25 (0-2) ASTM D2974-87 528363 35456820004 TE-33 (0-2) ASTM D2974-87 528363 35456820005 TE-33 (2-4) ASTM D2974-87 528363 Date: 04/12/2019 10:22 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 33 ,' WIC) 3545 111D�J Container Type Codes M / �7 /'+Q /�,1p /� �] -PaceAnalytical- alyticaI www.pacelahs.com • I I rl I II ■ 1'�III ( I I I I �' I I ECORD I �I ad te: Page Of 1 g AV A,iiei�i Vi.e ES E,,.pr,e S, v..,d'r 5 CV Clear c PPV Plasticconl d or ,_ P Plastic PLC Plastic container AL Amber liter Pl J Plastic Jar CL Clear Liter 2 Ziploc bag tT AP Amber Plastic TB Todlnr hag N 35456820 AG Amber Glare: WP Whldpnk d SJ Soil Jar G Gallon Jug Other TC Term -core PPV Propronerved vial Srzufs): 2oz, 4oz. Boz. 16oz, 32oz or 11. other ,. U - ..__.__.._.__....._ _ 4gnd 500m1 250ne 125 oftcompany Name: = . PO# - -, r , 79-" LAB ANALYSIS Example: 4ozP • aoz Plaetic, aozSJ• aoz Son Jar Address: s-qS it /1,2 , cl o.,, L- ^•Ke5 f Sample y City: ' , 4", Lc ke S State: FL Zip: 3 jU i 4 TRC Matrix Codes Attn: di I . (,Inu {' I .t/a.-t Gif Fax# `-� pH SD Solid W,c.le OL Oil GW Groundl4e SL SludgeEFF //. `J n y `1 i L� _D J �� i 1 - V 'Of- email: %v1 xf9 / i{ T 4 ! c . ✓ Phone: Pres Codes Effluent1N Sediment AFW Anolylu Free H2O AO Aqueous WW Waffle Water NA Non00000. Project Al,SW �/ ((! Name/I r'e.ese. 17U/c- CGJYSCL Proj# .--GP -3OS� Parameters EXAMPLE Dish. Lead 6010 ow Drinking Water PE Pvlrolnum Surface Water 0 Omer ML Kea. Liquid ("1•§e".,,,,,i Sampler � t5-47 / Circle One Event: Daily Weekly Monthly Signatu /) Ouanely Semi -Annual Annual N/A i "i Preservative Type Codes E. Sample ID Collect Date Collect Time Matrix Code" *2 m ; u. tL a- c o w c ro o 3 ,� - 0 S N nej E. HCL I. Ice B 14NO3 F. McOH J. MCAA C. H2SO4 G. Na2S203 K. Zn Acetate D. NaOH H. NaHSOa O. Other E rn # of Containers Size/Typo '— ���------777 , i I 1eozP REMARKS 1 1 E- 1 (� _LA >!'->/iy �' i 3 5 C sv ; I u r i I—i n n u u I I I I T SIrL•� z�� �A T 2 ^D l�"L (U'L) yl_j(i� 1?v� gO N > ci MI I ❑ ❑ 1 I U I I U 3 TE-1j !o--2) -3/251,� i,io so N > Li 1:::] IR I I ❑• I I I I I 4 Te- 3 7 (c-`.. i/zsl/i 0S-5 .SO r\J 5 IA ■ ❑ u ❑ ■ ❑ I I / 5 I C- �) (z— `,1) }/-5/q 1Sov 5r Ci n 3 P2 �] ■ ■ U ❑ ❑ I I ❑ Na 6 u■❑■■ n L Li Li n 7 u u ❑ ■ ❑ n ❑ ❑ ■ 8 ■❑❑ u I I I I ❑ n❑ 9 n❑❑ u I I n U■ LJ ,o ■ MI n I 1 ■ I I I I u cwae T.AT. REuo[:•1 iltu.h I. ems APP...) RueH Short Hold Circle QA/QC Report Level EDD (Fees May Apply) COC Condition Required State Certification Coolers #'s - Temp "C Y N Today ID 20 30 4D 5D Y N 1 2 3 4 CLP AFCEE QAPP Other ADaPT SEDD ERPIMS TSV CSV Other OK Incomplete FL GA SC NC NJ PA LA TX IL _ _ 2 3 4 5 Item Relinquished by Affiliation Date Timfe� Rec�eiijV� b Date Time 1 iiii` - • - C-f- 6 3/_Sll�j 15 .'�`c! /� 4 ' (�AAffilliiation_ C ' �_ )fr [/ �� /1 ( ^J/ )7.5 Ni F nd7 S. pl.,. INTACT loll 2 r.r Y/ `}„/ Y /� ,'Y/raL,f"O J y // J(D/ + - 'l'1 11 -1 I p Ruwrvuo on Wel Ice? Prope, Pmker/Mime'mewled? -�'�—� 1 - _ ,-. ` -J((' 7 1 _ t, I y �i �/�(/r - 7.-., � ` T...2--;) /y / /.v V/ Received within holding 4mu7 Cunludyv+al:: Intact? 4 ID�T ..... ////�/y(•''- .min. 1 ..L. Zre..R aorta V-� �� 1 t��") 47 I \ / /jr_...--- //!!rPv `t'•�•✓_ -'fj J) // /�' �' %•� )1-3 :r Vulalilos leek/ wdhuul liwWspac^ Proper Containers Gaud? ev on: F•ALL•C•007- Rov.00 C.O.C. Serial # 1 4 5 2 5 r. ice / In.;/t 1/cal Project # Project Manager: Client: rernnc,nt le• WWI o 35k 515820 PM: CTR Oue Data?: 04/03/19 CLIENT: 36-E1G /1-33v Date Date and Initials of person: Examining contents: Label:_ Deliver: pH: /7 3J Stale of Origin Cooler #1 Tomp.`C3. g (Visual) Oo (Correction Factor) 3. F (Actual) Cooler #2 Temp.'C2 / 5- (Visual) 9- Z5 (Correction Factor) 2_7) (Actual) Cooler #3 Temp.'C (Visual) (Correction Factor) (Actual) Cooler #4 Temp.'C (Visual) (Correction Factor) (Actual) Cooler #5 Temp.'C (Visual) (Correction Factor) (Actual) Cooler#6 Temp.-C (Visual) (Correction Factor) (Actual) Courier: — Fed Ex — UPS — USPS — Ghent — CornmeTcal L P%ace - Ot er ��st n .„3 t P.,n•., , n.:e•.,�n�,t Stt. ::air.. 2h Memational °nr..'y Shipping Method: � �'e� ;, i - • Other Billing:Recipient Server Ti?ird Pa?y Car Unknown Tracking # Custody Seal on Cooler/Box Present: _Yes Seals intact: — Yes No Ice: e! Blue Dry bra Packing Material: — Bu .bie \'rap 7 Bubble Bags —'gone — Omer Samples shorted to lab (If Yes. complete) Shorted Date Snorted T-me Oty Comments: Chair of CL:stody Present No ___,Yes Chain of Custody Filled Out _/es No N Relinquished Signature & Sampler Name COG- es No N A Samples Arrived within Hold Time Y s . - No N A Rush TAT requested on COG Yes No -NA Sufficient Volume des No VA Correct Containers Useds No NSA Containers Intact ----Yes No N A Sa'-1p e _ace. _ _:_ 20so--._ •_ -.- & ale ! :. _ .,., ev•. Yes No VA eGke� Yes ...7:—:- a... _ .... -=.: rezor,-r_e...a. .- Yes crr:e:... Co -.,C ;i&G ..: -a:es No /N L. No /N A _.,. _.._ ... _ -- -- .. ... ., .,c Headspace in VOA Vials'2 I >6mmi Yes . No /N A Trip Blank Present Yes No JNVA Client Notification/ Resolution: Person Co' tarred Comments/ Resolution (use back for additional comments): Date Time 'roje,.• :..adage: ri;iv ii'.v Date Page 16 of 33 TM ace Analytical www.pacelabs.com Report Prepared for: Christina Raschke PASI Florida 8 East Tower Circle Ormond Beach FL 32174 REPORT OF LABORATORY ANALYSIS FOR PCDD/PCDF Report Prepared Date: April 12, 2019 Report No 10468833_8290FCDFR Pace Analytical Services, LLC. 1700 Elm Street Minneapolis, MN 55414 Phone: 612.607.1700 Fax: 612.607.6444 Report Information: Pace Project #: 10468833 Sample Receipt Date: 03/29/2019 Client Project #: 35456820 Client Sub PO #: N/A State Cert #: E87605 Invoicing & Reporting Options: The report provided has been invoiced as a Level 2 PCDD/PCDF Report. If an upgrade of this report package is requested, an additional charge may be applied. Please review the attached invoice for accuracy and forward any questions to Nathan Boberg, your Pace Project Manager. This report has been reviewed by: April 12, 2019 Nathan Boberg, Project Manager 612-360-0728 (612) 607-6444 (fax) nathan.boberg@pacelabs.com Report of Laboratory Analysis Thisreportshouldn otbereproduced,exceptinfull. withoutthewrittenconsentofPaceAnalyticalServices,Inc. Theresultsrelateonlyt othesamplesincluded i nthisreport. Page 17 of 33 Page 1 of 17 ace Analytical Pace Analytical Services, LLC. 1700 Elm Street Minneapolis, MN 55414 Phone: 612.607.1700 Fax: 612.607.6444 DISCUSSION This report presents the results from the analyses performed on three samples submitted by a representative of Pace Analytical Services, LLC. The samples were analyzed for the presence or absence of polychlorodibenzo-p-dioxins (PCDDs) and polychlorodibenzofurans (PCDFs) using a modified version of USEPA Method 8290. The reporting limits were based on signal-to-noise measurements. Estimated Maximum Possible Concentration (EMPC) values were treated as positives in the toxic equivalence calculations. Per request, estimated detection limit (EDL) values were provided and flagged "U" where the target analytes were not detected. Second column confirmation analyses of 2,3,7,8-TCDF values obtained from the primary (DB5-MS) column are performed only when specifically requested for a project and only when the values are above the concentration of the lowest calibration standard. Typical resolution for this isomer using the DB5-MS column ranges from 25-30%. The recoveries of the isotopically -labeled PCDD/PCDF internal standards in the sample extracts ranged from 30-82%. Except for two low values, which were flagged "R" on the results tables, the labeled internal standard recoveries obtained for this project were within the 40-135% target range specified in Method 8290. Also, since the quantification of the native 2,3,7,8-substituted congeners was based on isotope dilution, the data were automatically corrected for recovery and accurate values were obtained. Values were flagged "I" where incorrect isotope ratios were obtained. Concentrations below the calibration range were flagged "J" and should be regarded as estimates. Concentrations above the calibration range were flagged "E" and should also be regarded as estimates. A laboratory method blank was prepared and analyzed with the sample batch as part of our routine quality control procedures. The results show that PCDDs and PCDFs were not detected. These results indicate that the sample preparation procedures did not significantly impact the results of the field sample determinations. A laboratory spike sample was also prepared with the sample batch using reference material that had been fortified with native standards. The recoveries of the spiked native compounds ranged from 103-119%. These results were within the target range for the method. Matrix spikes were prepared with the sample batch using sample material from a separate project; results from these analyses will be provided upon request. The responses obtained for selected labeled congeners in calibration standard analysis U190411A_17 were outside the target range. As specified in our procedures for this method, the averages of the daily response factors for these compounds were used in the calculations for the samples from this runshift. The affected values were flagged "Y" on the results tables. It should be noted that the accuracy of the native congener determinations was not impacted by these deviations. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Page 18 of 33 Page 2 of 17 Report No 10468833_8290FC_DFR TM Minnesota Laboratory Certifications Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612-607-6444 Authority Certificate # Authority Certificate # A2LA 2926.01 Minnesota - Pet 1240 Alabama 40770 Mississippi MN00064 Alaska - DW MN00064 Missouri - DW 10100 Alaska - UST 17-009 Montana CERT0092 Arizona AZ0014 Nebraska NE-OS-18-06 Arkansas - DW MN00064 Nevada MN00064 Arkansas - WW 88-0680 New Hampshire 2081 CNMI Saipan MP0003 New Jersey (NE MN002 California 2929 New York 11647 Colorado MN00064 North Carolina 27700 Connecticut PH-0256 North Carolina - 27700 EPA Region 8+ via MN 027-053 North Carolina - 530 Florida (NELAP E87605 North Dakota R-036 Georgia 959 Ohio - DW 41244 Guam 17-001r Ohio - VAP CL101 Hawaii MN00064 Oklahoma 9507 Idaho MN00064 Oregon - Primar MN300001 Illinois 200011 Oregon - Secon MN200001 Indiana C-MN-01 Pennsylvania 68-00563 Iowa 368 Puerto Rico MN00064 Kansas E-10167 South Carolina 74003 Kentucky - DW 90062 South Dakota NA Kentucky - WW 90062 Tennessee TN02818 Louisiana - DE 03086 Texas T104704192 Louisiana - DW MN00064 Utah (NELAP) MN00064 Maine MN00064 Virginia 460163 Maryland 322 Washington C486 Massachusetts M-MN064 West Virginia - 382 Michigan 9909 West Virginia - 9952C Minnesota 027-053-137 Wisconsin 999407970 Minnesota - De via MN 027-053 Wyoming - UST 2926.01 REPORT OF LABORATORYANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Page 19 of 33 Report No 10468833_8290FC_DFR Page 3 of 17 Appendix A Sample Management Report No 10468833_8290FC_Ee Analytical Services, Inc. Page 20 of 33 Page 4 of 17 30 CD 0 Z 0 2:1�1:1 Od06Z8 ££2991701. lv u0 c0 01 0 -h Chain of Custody Samples were sent directly to the Subcontracting Laboratory. Workorder: 35456820 Workorder Name: Melreese Golf Course 2018-3057 State Of Origin: FL Cert. Needed: Li Yes Owner Received Date: No 3/25/2019 ceAnialy.Yeal ems: Results Requested By: 4/3/2019 Christina Reschke Pace Analytical South Florida 3610 Park Central Blvd N Pompano Beach, FL 33064 Phone (954)582-4300 Pace Analytical Minnesota 1700 Elm Street SE Suite 200 Minneapolis, MN 55414 Phone (612)607-1700 TE-33 (0-2) TE-33 (2-4) Transfers 2 3 PS PS 3/25/2019 09:13 3/25/2019 14:55 3/25/2019 15:00 35456820001 35456820004 Solid 35456820005 Cooler Tem • erature on Recei • t -7oc Solid Solid 111 11.11M ■■©...•...111.M■ ii.. ■■©■■■■■■■■■■■ ... ..........■■.■ ..■ ...... i....■■.. 8290 Dioxin and Furans jej416efi33 IIIIIII�IIIIIIIIIIIIV LAB USE ONLY Custod Seal Y or Received on Ice c 2 �y k Cr- JIIIIIIMIIIIIITIMEMEIME11111 ££ 4o lZ a6ed '*w/n order to maintain client confidentiality, location/name of the sampling site, sampler's name and signature may not be provided on this COC document. This chain of custody is considered complete as is since this information is available in the owner laboratory. Wednesday, March 27, 2019 6:56:14 PM FMT-ALL-C-002rev.00 24March2009 Page 1 of 1 r1 PaceAnalytical ' Document Name: Sample Condition Upon Receipt Form Document Revised: 06Feb2019 Page 1 of 1 Document No.: F-MN-L-213-rev.25 Issuing Authority: Pace Minnesota Quality Office Sample Condition Upon Receipt Courier: Tracking Number: Client Name:fw_ e, /, 1 Project #: [Fed Ex an ❑LISPS ❑Client El Pace I I 617e A IOttlJTlerClal See Exception WO# • 10468833 PM: NV Due Date: 04/12/19 CLIENT: PRSI-FL Custody Seal on Cooler/Box Present? gtes ❑No Seals Intact? Eyes No Biological Tissue Frozen? Des Z'No ❑N/A Packing Material: [Nubble Wrap fAliubble Bags ['None n9.ther: !' Temp Blank? Oyes ❑No Thermometer: ❑G87A9155100842 (O-G87A9170600254 Typeoflce: trkAit ❑Blue ❑Noce ['Dry ❑r'Leltec Note: Each West Virginia Sample must have temp taken (no temp blanks) Temp should be above freezing to 6°C Cooler Temp Read w/temp blank: Correction Factor: Cooler Temp Corrected w/temp blank : oc aC Average Corrected Temp See Exceptions (no temp Tank only): oc USDA Regulated Soil: (❑ N/A, water sample/Other: ) Date/Initials of Person Examining Contents: ���-- 3/V/i/6( Did samples originate in a quarantine zone within the United States: L, AR, CA, FL GA, Did samples originate from a foreign source (internationally, including ID, LA. MS, NC, NM, NY, OK, OR, SC, TN, TX or VA (check maps)? Yes No Hawaii and Puerto Rico)? Dyes 'No If Yes to either question, fill out a Regulated Soil Checklist (F-MN-Q-338) and include with SCUR/COC paperwork. COMMENTS: Chain of Custody Present and Filled Out? s ❑No 1. Chain of Custody Relinquished? s ❑No 2. Sampler Name and/or Signature on COC? ❑Yes ❑No fjN/A 3. Samples Arrived within Hold Time? 1Xes ❑No 4. Short Hold Time Analysis (<72 hr)? ❑Yes 8No 5. ❑Fecal Coliform ❑HPC ❑Total Coliform/E coli ❑BOD/cBOD ❑Hex Crrome ❑Turbidity ❑Nitrate ❑Nitrite ❑Orthophos ❑Other Rush Turn Around Time Requested? es ❑No 6. Sufficient Volume? `Yes ❑No 7. Correct Containers Used? -Pace Containers Used? (Yes Yes ON() ❑No 8. Containers lntact? EOYes ❑No 9. Field Filtered Volume Received for Dissolved Tests? ❑Yes ❑No 1 N/A 10. Is sediment visible in the dissolved container? Yes IN No Is sufficient information available to reconcile the samples to the COC? Matrix: :water )toil DOH DOther 8Yes ❑No 11. If no, write ID/ Date/Time on Container Below: See Exception ■ All containers needing acid/base preservation have been checked? All containers needing preservation are found to be in compliance with EPA recommendation? (HNO3, H2504, <2pH, NaOH >9 Sulfide, NaOH>12 Cyanide) Exceptions: VOA, Coliform, TOC/DOC Oil and Grease, DRO/8015 (water) and Dioxin/PFAS ❑Yes ❑Yes ❑Yes ❑No ❑No}gi/A ❑No [* N/A Rki/A 12. Sample # • NaOH ❑ HNO3 ■ H250, IN Zinc Acetate Positive for Res. ❑Yes Chlorine? ONo See Exception ❑ Headspace in VOA Vials {greater than 6mm)? [Dyes ❑No EN/A 13. See Exception M Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes ❑Yes ❑No ❑No gt[1/A 42.N/A 14. Pace Trip Blank Lot # (if purchased): CLIENT NOTIFICATION/RESOLUTION Person Contacted: Comments/Resolution: Date/Time: Field Data Required? ❑Yes ❑No Project Manager Review: Note: Whenever there is a discrepancy affecting North Caro Ina c pliance s�mpies, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e out of hold, incorrect preservative, out of temp, incorrect containers), Date: 4/1/19 Labeled by: Report No 10468833_8290FC_DFR Page 22 of 33 Page 6 of 17 / Oace Analytical Document Name: SCUR Exception Form — Coolers Above 6°C Document Revised: Ozife b2019 Page 1 of 1 Document No.: F-MN-C-298-Rev.01 Issuing Authority: Pace Minnesota Quality Office SCUR Exceptions: During sample triage, this form is to be placed in each cooler that arrives above 6.0 degrees Celsius Workorder #: Container # of PM Notified? nYes Out of Tmp.$a(tiple tDs Type Contaimrs If yes, indicate who was contacted/date/time. If no, indicate reason why. ultiple Cooler Project? Eves ENo I= you answered yesrlill out information to the left. Other Issues Issue Type: Sant* II) Container # of Type Containers No Temp Blank Read Temp Corrected Te m p Average Temp O. 6 O. '1 O. 3 O. Z. 0 CII o- 0 LI a•y o / Zq //1 TraCking NornOer. Adnustnient Log for Preserved Samoies Sample IC pH i IArnounc1 I '.-ype of Upon i Daze i Time I Added Lot k , pH In Compliance Preserv, Receipt I Adjusted i Adjusted i (mL) Added I After after addition? initials I i__, Yes EiNo • Yes nwo 1 Yes No Report No 10468833 8290FC DFR Page 23 of 33 Page 7 of 17 i=,, Or 7 . -PceAnalytical Document Name: Regulated Soil Checklist Document Revised: 13Feb2028 Page 1 of 2 Document No.: F-MN-Q-338-Rev.06 Issuing Authority: Pace Minnesota Quality Office USDA REGULATED SOIL CHECKLIST To Be Completed by SR Staff: WO: Sample Origin (circle one): DOMESTIC Date: QUARANTINED Initials: ACM( FOREIGN (Note: soil samples from Hawaii, Guam, Puerto Rico and the US Virgin Islands are considered to be of a Foreign Source) If Domestic, circle State of Origin: AL AR CA FL GA LA MS NC NM NY OK OR SC TN TX VA (includes: iFA, SOD, Golden Nematode, Karnal Bunt and Witchweed) List County: (USDA Permit/Compliance Agreement authorizes movement of samples from these domestic regulated zones) If Quarantined, circle State of Origin: FL ID TX CA List County: (Includes Fruit Fly, 'ant African Snail and Pale Cyst Nematode) (Movement is not authorized for Pale Cyst Nematode (ID or Giant African Snail (FL], remaining quarantines require additional paperwork) If Foreign, list Country of Origin: Miami; ()a&z (Movement from some Canadian Providences 1s not allowed. Refer to CS-232 Regulated Soil Flow Chart) REQUIREMENT ACTION COMPLETED PPQ-530 Paperwork must be included for any samples from counties with a Fruit Fly Quarantine in TX. Refer to MN-5063 through MN-S065 Scan PPQ-530 to the corresponding Project folder on the x drive. If PPQ-530 is not present, contact the Waste Coordinator and do not continue processing samples. YES NO cVt Samples from ID may not be moved from the quarantined region. Refer to MN-5055 If samples originated in a quarantined zone, contact the Waste Coordinator and do not continue processing samples. YES NO N/ Samples from Giant African Snail Quarantine in FL maynot be moved from the quarantined region. Refer to MN-S068 If samples originated in a quarantined zone, contact the Waste Coordinator and do not continue processing samples. YES NO /A REQUIREMENT ACTION COMPLETED "Special Handling" stickers are to be placed on all samples. Did "special handling" stickers get placed on all sample containers? E , NO Samples must be segregated and stored in designated bins, shelves and coolers. Were samples placed it a designated cooler, containers and)NO shelves? Samples must be double contained to prevent accidental release. Were there any signs of breakage or leakage (check for broken glass and/or loose soil in the cooler)? If NO, ice and melt water can be disposed of by normal process (down YES the drain). If YES, were ice and melt water separated from the cooler and disposed of properly? Any broken glass and/or loose soil are to be bagged and placed in a container or active drum (see Waste Coordinator). Ice and melt water should be baked at a temperature range of 121-154°F cooled before going down the dram. YES NO USDA Regulated satellite for 2 hours and then Equipment and supplies that have come into contact samples must be decontaminated. Was the cooler(s) and/or countertop(s) decontaminated using either a fresh 10% bleach solution or 70% ethanol? (Gloves and other lab supplies will be bagged and placed in the USDA Regulated satellite container or active drum). YES NO Comments: Report No 10468833_8290FC_DFR Page 24 of 33 Page 8 of 17 ISii ,� P ceAnaIj iCa/ Document Name: Regulated 5oil Checklist Document Revised: 13Feb2018 Page 2 of 2 Document No.: F-MN-Q-338-Rev.06 Issuing Authority: Pace Minnesota Quality Office To Be Completed by PM and/or PC: Sample Analysis to be conducted (circle all that apply): Name of Subcontract Lab (s): MN Subcontract Lab REQUIREMENT ACTION COMPLETED Permission to ship untreated soil must be on file prior to shipping to any subcontract lab, including IR Pace Labs. Go to: J:\SHARE\PRJ_MGR\10_Client Services Department Documents\Regulated Soils Permits — if permission to ship letter is not there, contact the Waste Coordinator. YES NO N/A Shipment must include a valid copy of the receiving lab's permit as well as permission to ship letter. Is a copy of all needed paperwork included with the COC? Do NOT ship samples until all necessary paperwork is compiled. YES NO N/A Comments: 1400 nw 19th st miami fl 33125 Project Manager Signature: 'qiNsCak-rb\ Report No 10468833_8290FC_DFR Date: 4/1/19 Page 25 of 33 Page 9 of 17 Giant African Land Snail (GALS) Miami -Dade and Broward Counties, July, 2018 3 75 7 5 • hqr,rit, rezik: , Quarantine Zones rt,tif cr tf r., C,i r1.1 ';-,...,,....6,'-:PPTIesg5-1394. 7'D •'' I! E3'1:4-P- 1:11L.1, ' D e „. ,Af., ...,12 = R-1 i P-:Dajiii,f2 1-,91$-'12,16,1-e,„ q.; : ;111111; 7,h-• •q).) . ...t.tz, -i, Gmrr - • .Kii.';' ' - - i , i '• `5 •M' 7 • m:14.•‘;,_A1,G',,,-K -.--' '`-'7•--ei 1--a. ..::?e':-:stp9oTV-15T_• i zsfAF;;70-:.' r4PR.041POIV II' ..,3:1_11,4•P''' :::;'. •:-",1 •t5 ''-' %. i'Z' 1.14,:tfne4 % ' ..A.KR.,, - .1- - : •' ''..4. I ., ' ! • -t-IWy e t •.1 'sgb -,`, - !:- , , a) i P716‘r,?1:r..:11--.k71,11‘i:4/.-;-.-:-.,,,..r1±-2,:,-,.-' • .. 9.5 1 • --- hl IL:t ., -..' 1•.:,-r‘CciTh'n'it'yl6-'-'ifl?..-L'..4.,•41-,44-4:A-r-tia:1:'::-1- r-tri"Ri..-x;•• I* -- I 1: r ' • x --.-.,-, , ----1,8134144%.-t-L1-1.„. path--4-4s; - Mian4_aliiii i;•• --,--4 - • it.: - ,1,1; .; .'....- •-, 4„- •-•. - i - • •-....,(-A:.:T.i-G-T411..Pfc•rir ,.,. 571 • 1.'`!it°•.11 • , • -ntrr ‘Heir• ' ‘+ WOrthiPter • . . - i • ..i4endlitt S , icaldsiel.:Aqs '.- - — '.--.-- ' - Ai;'. . -litL...ir ... 4-- ' • - , 411; ''''' Vid • .0 • 1- .- 1 ,fibeifiaiiiroaliol_ ..,sZ.-- . i'-.,:fit. lfi i• •"'-'-'4*-1-1-` --"' '-7-C:t7. Z1l'!.r! 11.417-.,-4.,7„4-...7 °'''`;1 V,iesio T1. tI,t • 1 , - , t -5. 1... -F4ch":•••• r-r.bc1-:'-'4y' ' el;:..0•'F 4 dt • 15 A, n GALS Quarantine Zones Report No 10468833 8290FC DFR 177 USDA Page 26 of 33 Page 10 of 17 AnalyticalTM Reporting Flags Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 A = Reporting Limit based on signal to noise B = Less than 10x higher than method blank level C = Result obtained from confirmation analysis D = Result obtained from analysis of diluted sample E = Exceeds calibration range I = lnterferencepresent J = Estimated value L = Suppressive interference, analyte may be biased low Nn = Value obtained from additional analysis P = PCDEInterference R = Recovery outside target range S = Peak saturated U = Analyte not detected V = Result verified by confirmation analysis X = %D Exceeds limits Y = Calculated using average of daily RFs * = SeeDiscussion REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10468833_8290FC_DFR Page 11 of 17 Tel: 612-607-1700 Fax:612-607-6444 Page 27 of 33 Appendix B Sample Analysis Summary Report No 10468833_8290FC_CAAnalytical Services, Inc. Page 28 of 33 Page 12 of 17 Analytical Client's Sample ID Lab Sample ID Filename Injected By Total Amount Extracted Moisture Dry Weight Extracted ICAL ID CCal Filename(s) Method Blank ID Native Isomers 2,3,7,8-TCDF Total TCDF TM Method 8290 Sample Analysis Results Client - PASI Florida TE-31 (2-4) 35456820001 U190411A_12 SMT 12.5 g 15.7 10.6 g U190403 U190411A_01 & U190411A_17 BLANK-69640 Conc EMPC ng/Kg ng/Kg 0.59 U 0.59 U 2,3,7,8-TCDD 0.17 U Total TCDD 2.3 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 0.41 U 0.69 12 0.28 1.5 1,2,3,4,7,8-HxCDF 0.77 1,2,3,6,7,8-HxCDF 0.50 2,3,4,6,7,8-HxCDF 0.67 1,2,3,7,8,9-HxCDF 0.24 U Total HxCDF 7.4 1,2,3,4,7,8-HxCDD 0.27 U 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD 0.66 Total HxCDD 10 1,2,3,4,6,7,8-HpCDF 6.2 1,2,3,4,7,8,9-HpCDF 0.40 U Total HpCDF 14 1,2,3,4,6,7,8-HpCDD 31 Total HpCDD 66 OCDF OCDD 1.1 0.38 J 0.32 J 0.24 J 0.24 0.30 0.27 0.30 IJ 0.29 J 0.29 EDL ng/Kg Matrix Dilution Collected Received Extracted Analyzed Internal Standards Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel 612-607-1700 Fax: 612- 607-6444 Solid NA 03/25/2019 09:13 03/29/2019 09:45 04/04/2019 15:00 04/11/2019 19:35 ng's Percent Added Recovery 0.59 2,3,7,8-TCDF-13C 0.59 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 0.17 2,3,4,7,8-PeCDF-13C 0.17 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 0.41 1,2, 3,6,7,8-HxCDF-13C 0.37 J 2,3,4,6,7,8-HxCDF-13C 0.39 1,2, 3, 7, 8, 9-HxC DF-13C 1,2,3,4,7,8-HxCDD-13C 0.25 J 1,2,3,6,7,8-HxCDD-13C 0.25 J 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 4.00 2.00 2.00 0.20 0.23 Total 2,3,7,8-TCDD 0.40 Equivalence: 1.6 ng/Kg 0.32 (Lower -bound - Using ITE Factors) 0.48 0.48 15 0.61 320 1.0 56 59 53 53 62 58 60 56 52 53 51 47 Y 45 Y 48 Y 34 RY NA NA 57 Conc = Concentration (Totals include 2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit ND = Not Detected NA = Not Applicable NC = Not Calculated Results reported on a dry weight basis and are valid to no more than 2 significant figures. J = Estimated value R = Recovery outside target range I = Interference present Y = Calculated using average of daily RFs REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. without the written consent of Pace Analytical Services, Inc. Report No 10468833_8290FC_DFR Page 13 of 17 Page 29 of 33 Analytical Client's Sample ID Lab Sample ID Filename Injected By Total Amount Extracted % Moisture Dry Weight Extracted ICAL ID CCaI Filename(s) Method Blank ID Native Isomers 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD TM Metho d 8290 Sample Analysis Client - PASI Florida TE-33 (0-2) 35456820004 U190411A_13 SMT 12.5 g 12.8 10.9 g U190403 U190411A_01 & U190411A_17 BLANK-69640 Conc EMPC ng/Kg ng/Kg 4.1 89 1.2 91 5.2 11 180 7.1 150 10.0 9.5 13 2.8 140 8.0 19 13 290 52 4.9 90 190 530 52 1100 0.81 0.55 0.67 0.44 J 0.62 0.66 0.62 0.98 0.75 Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612- 607-6444 Results Matrix Solid Dilution NA Collected 03/25/2019 14:55 Received 03/29/2019 09:45 Extracted 04/04/2019 15:00 Analyzed 04/11/2019 20:21 EDL Internal ng's ng/Kg Standards Added Percent Recovery 0.33 2,3,7,8-TCDF-13C 0.33 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 0.40 2,3,4,7,8-PeCDF-13C 0.40 1, 2, 3 , 7, 8-PeCDD-13C 1 ,2,3,4,7,8-HxCDF-1 3C 0.50 1 ,2,3,6,7,8-HxCDF-1 3C 0.58 2,3,4,6,7,8-HxCDF-13C 0.54 1 ,2,3,7,8,9-HxCDF-1 3C 1 ,2,3,4,7,8-HxCDD-1 3C 0.51 1 ,2,3,6,7,8-HxCDD-1 3C 0.51 1,2,3,4,6,7,8-HpC DF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 1 ,2,3,4-TCDD-1 3C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 2.00 64 2.00 67 2.00 60 2.00 56 2.00 66 2.00 66 2.00 69 2.00 64 2.00 55 2.00 62 2.00 57 2.00 44 Y 2.00 42 Y 2.00 45 Y 4.00 30 RY 2.00 NA 2.00 NA 0.20 63 1.5 Total 2,3,7,8-TCDD 0.77 Equivalence: 22 ng/Kg 1.1 (Lower -bound - Using ITE Factors) 1.3 1.3 3.3 3.0 Conc = Concentration (Totals include 2.3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit ND = Not Detected NA = Not Applicable NC = Not Calculated Results reported on a dry weight basis and are valid to no more than 2 significant figures. J = Estimated value R = Recovery outside target range Y = Calculated using average of daily RFs REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10468833_8290FC_DFR Page 14 of 17 Page 30 of 33 Arialytical Client's Sample ID Lab Sample ID Filename Injected By Total Amount Extracted Moisture Dry Weight Extracted ICAL ID CCal Filename(s) Method Blank ID Native Isomers TM Method 8290 Sample Analysis Results Client - PASI Florida TE-33 (2-4) 35456820005 U190411A_14 SMT 13.4 g 33.0 8.96 g U190403 U190411A_01 & BLANK-69640 Conc EMPC ng/Kg ng/Kg 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 3.9 61 17 580 2.9 5.8 75 1,2,3,7,8-PeCDD 43 Total PeCDD 1300 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 4.1 2.8 9.7 1.8 460 Matrix Dilution Collected Received U190411A_17 Extracted Analyzed EDL Internal ng/Kg Standards 0.22 I 2,3,7,8-TCDF-13C 0.22 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 0.29 2,3,4,7,8-PeCDF-13C 0.29 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 0.36 J 1,2,3,6,7,8-HxCDF-13C 0.34 2,3,4,6,7,8-HxCDF-13C 0.35 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 0.74 1,2,3,6,7,8-HxCDD-13C 0.74 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 0.49 J 1,2,3,4,6,7,8-HpCDD-13C 0.35 J OCDD-13C 0.32 0.11 J 1,2,3,4-TCDD-13C 0.32 1,2,3,7,8,9-HxCDD-13C Pace Analytical Services. LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612- 607-6444 Solid NA 03/25/2019 15:00 03/29/2019 09:45 04/04/2019 15:00 04/11/2019 21:06 60 1.1 2,3,7,8-TCDD-37C14 200 1.3 160 1.2 6100 1.2 E 1,2,3,4,6,7,8-HpCDF 300 1,2,3,4,7,8,9-HpCDF 18 Total HpCDF 1700 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD ng's Percent Added Recovery 2.00 77 2.00 80 2.00 72 2.00 71 2.00 82 2.00 75 2.00 79 2.00 73 2.00 65 2.00 50 2.00 63 2.00 60 Y 2.00 55 Y 2.00 64 Y 4.00 45 Y 2.00 NA 2.00 NA 0.20 80 0.99 Total 2,3,7,8-TCDD 0.96 Equivalence: 220 ng/Kg 0.98 (Lower -bound - Using ITE Factors) 6000 1.0 E 13000 1.0 E 1100 1.0 69000 0.73 E Conc = Concentration (Totals include 2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit ND = Not Detected NA = Not Applicable NC = Not Calculated Results reported on a dry weight basis and are valid to no more than 2 significant figures. J = Estimated value E= Exceeds calibration range 1= Interference present Y = Calculated using average of daily RFs REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10468833_8290FC_DFR Page 15 of 17 Page 31 of 33 AnalyticalT h1 Method 8290 Blank Analysis Results i Lab Sample Name Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) DFBLKLJ BLANK-69640 F190410B_06 11.0 g F190112 F190410B_01 & F190410B_18 Native Conc Isomers ng/Kg 2,3,7,8-TCDF 0.33 U Total TCDF 0.33 U 2,3,7,8-TCDD 0.31 U Total TCDD 0.31 U 1,2,3,7,8-PeCDF 0.26 U 2,3,4,7,8-PeCDF 0.20 U Total PeCDF 0.23 U 1,2,3,7,8-PeCDD 0.23 U Total PeCDD 0.23 U 1,2,3,4,7,8-HxCDF 0.11 U 1,2,3,6,7,8-HxCDF 0.10 U 2,3,4,6,7,8-HxCDF 0.10 U 1,2,3,7,8,9-HxCDF 0.14 U Total HxCDF 0.11 U 1,2,3,4,7,8-HxCDD 0.16 U 1,2,3,6,7,8-HxCDD 0.16 U 1,2,3,7,8,9-HxCDD 0.15 U Total HxCDD 0.16 U 1,2,3,4,6,7,8-HpCDF 0.14 U 1,2,3,4,7,8,9-HpCDF 0.20 U Total HpCDF 0.17 U 1,2,3,4,6,7,8-HpCDD 0.21 U Total HpCDD 0.21 U OCDF 0.58 U OCDD 0.59 U EMPC EDL ng/Kg ng/Kg Matrix Dilution Extracted Analyzed Injected By Internal Standards Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612-607-6444 Solid NA 04/04/2019 15:00 04/10/2019 16:23 SMT 0.33 2,3,7,8-TCDF-13C 0.33 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 0.31 2,3,4,7,8-PeCDF-13C 0.31 1,2,3,7,8-PeCDD-13C 1 ,2,3,4,7,8-HxCDF-1 3C 0.26 1,2,3,6,7,8-HxCDF-13C 0.20 2,3,4,6,7,8-HxCDF-13C 0.23 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 0.23 1,2,3,6,7,8-HxCDD-13C 0.23 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 0.11 0.10 0.10 0.14 0.11 0.16 0.16 0.15 0.16 ng's Percent Added Recovery 2.00 68 2.00 72 2.00 72 2.00 74 2.00 85 2.00 67 2.00 72 2.00 75 2.00 65 2.00 74 2.00 70 2.00 71 2.00 72 2.00 76 4.00 72 1,2,3,4-TCDD-13C 2.00 NA 1,2,3,7,8,9-HxCDD-13C 2.00 NA 2,3,7,8-TCDD-37CI4 0.20 78 0.14 Total 2,3,7,8-TCDD 0.20 Equivalence: 0.00 ng/Kg 0.17 (Lower -bound - Using ITE Factors) 0.21 0.21 0.58 0.59 Conc= Concentration (Totals include2,3,7,8-substituted isomers). EMPC= Estimated Maximum Possible Concentration EDL = Estimated Detection Limit Results reported on a total weight basis and are valid to no more than 2 significant figures. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10468833_8290FC_DFR Page 16 of 17 Page 32 of 33 Analytical Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) Method Blank ID TM Method 8290 Laboratory Control Spike Results LCS-69641 F190410B_02 10.2 g F190112 F190410B_01 & F190410B_18 BLANK-69640 Native Qs Qm % Isomers (ng) (ng) Rec. 2,3,7,8-TCDF 0.20 0.22 109 Total TCDF 2,3,7,8-TCDD 0.20 0.23 116 Total TCDD 1,2,3,7,8-PeCDF 1.0 1.1 113 2,3,4,7,8-PeCDF 1.0 1.2 115 Total PeCDF 1,2,3,7,8-PeCDD 1.0 1.0 103 Total PeCDD 1,2,3,4,7,8-HxCDF 1.0 1.2 115 1,2,3,6,7,8-HxCDF 1.0 1.1 109 2,3,4,6,7,8-HxCDF 1.0 1.1 109 1,2,3,7,8,9-HxCDF 1.0 1.1 108 Total HxCDF 1,2,3,4,7,8-HxCDD 1.0 1.1 113 1,2,3,6,7,8-HxCDD 1.0 1.2 119 1,2,3,7,8,9-HxCDD 1.0 1.1 108 Total HxCDD 1,2,3,4,6,7,8-HpCDF 1.0 1.2 116 1,2,3,4,7,8,9-HpCDF 1.0 1.0 103 Total HpCDF 1,2,3,4,6,7,8-HpCDD 1.0 1.1 106 Total HpCDD OCDF 2.0 2.2 109 OCDD 2.0 2.3 115 Matrix Dilution Extracted Analyzed Injected By Internal Standards 2,3,7,8-TCDF-13C 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 2,3,4,7,8-PeCDF-13C 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 1,2,3,6,7,8-HxCDF-13C 2,3,4,6,7,8-HxCDF-13C 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 1,2,3,6,7,8-HxCDD-13C 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 Pace Analytical Services. LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel:612-607-1700 Fax: 612-607-6444 Solid NA 04/04/2019 15:00 04/10/2019 13:32 SMT ng's Percent Added Recovery 2.0 79 2.0 83 2.0 84 2.0 87 2.0 99 2.0 75 2.0 82 2.0 86 2.0 80 2.0 84 2.0 84 2.0 82 2.0 90 2.0 94 4.0 98 2.0 NA 2.0 NA 0.20 85 Qs = Quantity Spiked Qm = Quantity Measured Rec. = Recovery (Expressed as Percent) R = Recovery outside of target range Y = RF averaging used in calculations Nn = Value obtained from additional analysis NA = Not Applicable = See Discussion REPORT OF LABORATORYANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10468833_8290FCDFR Page 17 of 17 Page 33 of 33 aceAnalytical www.pacelabs.com July 23, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35456926 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach. FL 33064 (954)582-4300 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 27, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. This is a revised report. The sample date has been revised. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina. raschke©pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry, EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. without the written consent of Pace Analytical Services, LLC. Page 1 of 19 aceAnalytical vrvnv.pacalabs.com CERTIFICATIONS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35456926 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alaska DEC- CS/UST/LUST Alabama Certification #: 41320 Arizona Certification# AZ0819 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate # 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 19 aceAnalytical www.pacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35456926 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach. FL 33064 (954)582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35456926001 MW-1 Water 03/26/19 10:30 03/27/19 17:15 35456926002 MW-2 Water 03/26/19 11:30 03/27/19 17:15 35456926003 MW-3 Water 03/26/19 12:14 03/27/19 17:15 35456926004 MW-4 Water 03/26/19 13:30 03/27/19 17:15 35456926005 MW-5 Water 03/26/19 13:57 03/27/19 17:15 35456926006 MW-38 Water 03/26/1912:55 03/27/19 17:15 35456926007 MW-9 Water 03/26/19 15:02 03/27/19 17:15 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 19 aceAnalytical www.pacelabs.com SAMPLE ANALYTE COUNT Project 2018-3057/Melreese Golf Course -Revised Report Pace Project No 35456926 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 35456926001 MW-1 EPA 8081 TCB 22 PASI-O EPA 6010 SC1 4 PASI-O 35456926002 MW-2 EPA 8081 TCB 22 PASI-O EPA6010 SC1 4 PASI-O 35456926003 MW-3 EPA 8081 TCB 22 PASI-O EPA6010 SC1 4 PASI-O 35456926004 MW-4 EPA 8081 TCB 22 PASI-O EPA6010 SC1 4 PASI-O 35456926005 MW-5 EPA 8081 TCB 22 PASI-O EPA6010 SC1 4 PASI-O 35456926006 MW-38 EPA 8081 TCB 22 PASI-O EPA6010 SC1 4 PASI-O 35456926007 MW-9 EPA 8081 TCB 22 PASI-O EPA6010 SC1 4 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 19 aceAnalytical www.pacelabs.com SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35456926 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Lab Sample ID Client Sample ID Method Parameters Result 35456926001 MW-1 Units Report Limit Analyzed Qualifiers EPA 8081 Heptachlor epoxide 0.052 ug/L 0.0097 04/09/19 04:39 H7,V EPA 6010 Barium 46.5 ug/L 10.0 04/02/19 16:21 EPA6010 Iron 333 ug/L 40.0 04/02/19 16:21 35456926002 MW-2 EPA 8081 Heptachlor epoxide 0.052 ug/L 0.0096 04/09/19 04:59 H7.V EPA 6010 Arsenic 13.2 ug/L 10.0 04/02/19 16:32 EPA 6010 Barium 21.9 ug/L 10.0 04/02/19 16:32 EPA 6010 Iron 1010 ug/L 40.0 04/02/19 16:32 35456926003 MW-3 EPA 8081 Heptachlor epoxide 0.053 ug/L 0.0097 04/09/19 05:18 H7,V EPA 6010 Arsenic 7.4 I ug/L 10.0 04/02/19 16:35 EPA 6010 Barium 21.8 ug/L 10.0 04/02/19 16:35 EPA6010 Iron 785 ug/L 40.0 04/02/19 16:35 35456926004 MW-4 EPA 8081 Heptachlor epoxide 0.055 ug/L 0.010 04/09/19 05:37 H7.V EPA 6010 Barium 61.7 ug/L 10.0 04/02/19 16:38 EPA6010 Iron 530 ug/L 40.0 04/02/19 16:38 '456926005 MW-5 EPA 8081 Heptachlor epoxide 0.088 ug/L 0.0096 04/09/19 05:56 H7.V EPA 6010 Barium 187 ug/L 10.0 04/02/19 16:41 EPA 6010 Iron 3420 ug/L 40.0 04/02/19 16:41 EPA 6010 Lead 9.0 I ug/L 10.0 04/02/19 16:41 35456926006 MW-38 EPA 8081 Heptachlor epoxide 0.054 ug/L 0.0096 04/09/19 06:16 H7.V EPA 6010 Barium 75.3 ug/L 10.0 04/02/19 16:50 EPA6010 Iron 3830 ug/L 40.0 04/02/19 16:50 35456926007 MW-9 EPA 8081 Heptachlor epoxide 0.063 ug/L 0.0097 04/09/19 06:35 H7.V EPA 6010 Barium 95.1 ug/L 10.0 04/02/19 16:52 EPA 6010 Iron 4030 ug/L 40.0 04/02/19 16:52 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 19 wvw..pacolabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35456926 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Sample: MW-1 Lab ID: 35456926001 Collected: 03/26/19 10:30 Received: 03/27/19 17 15 Matrix Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8081 GCS Pesticides Analytical Method: EPA8081 Preparation Method: EPA3510 Aldrin 0.0015 U ug/L 0.0097 0.0015 1 03/30/19 09:04 04/09/19 04:39 309-00-2 alpha-BHC 0.0020 U ug/L 0.0097 0.0020 1 03/30/19 09:04 04/09/19 04:39 319-84-6 beta-BHC 0.0078 U ug/L 0.0097 0.0078 1 03/30/19 09:04 04/09/19 04:39 319-85-7 delta-BHC 0.0047 U ug/L 0.0097 0.0047 1 03/30/19 09:04 04/09/19 04:39 319-86-8 gamma-BHC (Lindane) 0.0021 U ug/L 0.0097 0.0021 1 03/30/19 09:04 04/09/19 04:39 58-89-9 Chlordane (Technical) 0.17 U ug/L 0.48 0.17 1 03/30/19 09:04 04/09/19 04:39 57-74-9 4,4'-DDD 0.0086 U ug/L 0.0097 0.0086 1 03/30/19 09:04 04/09/19 04:39 72-54-8 CU 4,4'-DDE 0.0048 U ug/L 0.0097 0.0048 1 03/30/19 09:04 04/09/19 04:39 72-55-9 4,4'-DDT 0.0048 U ug/L 0.0097 0.0048 1 03/30/19 09:04 04/09/19 04:39 50-29-3 CU Dieldrin 0.0019 U ug/L 0.0097 0.0019 1 03/30/19 09:04 04/09/19 04:39 60-57-1 Endosulfan I 0.0049 U ug/L 0.0097 0.0049 1 03/30/19 09:04 04/09/19 04:39 959-98-8 Endosulfan II 0.0039 U ug/L 0.0097 0.0039 1 03/30/19 09:04 04/09/19 04:39 33213-65-9 CU Endosulfan sulfate 0.0060 U ug/L 0.097 0.0060 1 03/30/19 09:04 04/09/19 04:39 1031-07-8 CU Endrin 0.0042 U ug/L 0.0097 0.0042 1 03/30/19 09:04 04/09/19 04:39 72-20-8 Endrin aldehyde 0.0035 U ug/L 0.097 0.0035 1 03/30/19 09:04 04/09/19 04:39 7421-93-4 CU Endrin ketone 0.0048 U ug/L 0.0097 0.0048 1 03/30/19 09:04 04/09/19 04:39 53494-70-5 CU Heptachlor 0.0060 U ug/L 0.0097 0.0060 1 03/30/19 09:04 04/09/19 04:39 76-44-8 Heptachlor epoxide 0.052 ug/L 0.0097 0.0050 1 03/30/19 09:04 04/09/19 04:39 1024-57-3 H7,V Methoxychlor 0.0093 U ug/L 0.0097 0.0093 1 03/30/19 09:04 04/09/19 04:39 72-43-5 CU Toxaphene 0.24 U ug/L 0.48 0.24 1 03/30/19 09:04 04/09/19 04:39 8001-35-2 Surrogates Tetrachloro-m-xylene (S) 82 % 27-124 1 03/30/19 09:04 04/09/19 04:39 877-09-8 Decachlorobiphenyl (S) 70 % 10-132 1 03/30/19 09:04 04/09/19 04:39 2051-24-3 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3010 Arsenic 7.1 U ug/L 10.0 7.1 1 04/02/19 08:02 04/02/19 16:21 7440-38-2 Barium 46.5 ug/L 10.0 0.84 1 04/02/19 08:02 04/02/19 16:21 7440-39-3 Iron 333 ug/L 40.0 9.2 1 04/02/19 08:02 04/02/19 16:21 7439-89-6 Lead 4.6 U ug/L 10.0 4.6 1 04/02/19 08:02 04/02/19 16:21 7439-92-1 Date: 07/23/2019 10:44 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 19 www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35456926 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Sample: MW-2 Lab ID: 35456926002 Collected: 03/26/19 11:30 Received: 03/27/19 17:15 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8081 GCS Pesticides Analytical Method: EPA 8081 Preparation Method: EPA 3510 Aldrin 0.0014 U ug/L 0.0096 0.0014 1 03/30/19 09:04 04/09/19 04:59 309-00-2 alpha-BHC 0.0020 U ug/L 0.0096 0.0020 1 03/30/19 09:04 04/09/19 04:59 319-84-6 beta-BHC 0.0077 U ug/L 0.0096 0.0077 1 03/30/19 09:04 04/09/19 04:59 319-85-7 delta-BHC 0.0046 U ug/L 0.0096 0.0046 1 03/30/19 09:04 04/09/19 04:59 319-86-8 gamma-BHC (Lindane) 0.0021 U ug/L 0.0096 0.0021 1 03/30/19 09:04 04/09/19 04:59 58-89-9 Chlordane (Technical) 0.17 U ug/L 0.48 0.17 1 03/30/19 09:04 04/09/19 04:59 57-74-9 4,4'-DDD 0.0086 U ug/L 0.0096 0.0086 1 03/30/19 09:04 04/09/19 04:59 72-54-8 CU 4,4'-DDE 0.0048 U ug/L 0.0096 0.0048 1 03/30/19 09:04 04/09/19 04:59 72-55-9 4,4'-DDT 0.0048 U ug/L 0.0096 0.0048 1 03/30/19 09:04 04/09/19 04:59 50-29-3 CU Dieldrin 0.0019 U ug/L 0.0096 0.0019 1 03/30/19 09:04 04/09/19 04:59 60-57-1 Endosulfan I 0.0049 U ug/L 0.0096 0.0049 1 03/30/19 09:04 04/09/19 04:59 959-98-8 Endosulfan II 0.0039 U ug/L 0.0096 0.0039 1 03/30/19 09:04 04/09/19 04:59 33213-65-9 CU Endosulfan sulfate 0.0060 U ug/L 0.096 0.0060 1 03/30/19 09:04 04/09/19 04:59 1031-07-8 CU Endrin 0.0041 U ug/L 0.0096 0.0041 1 03/30/19 09:04 04/09/19 04:59 72-20-8 Endrin aldehyde 0.0035 U ug/L 0.096 0.0035 1 03/30/19 09:04 04/09/19 04:59 7421-93-4 CU Endrin ketone 0.0048 U ug/L 0.0096 0.0048 1 03/30/19 09:04 04/09/19 04:59 53494-70-5 CU Heptachlor 0.0060 U ug/L 0.0096 0.0060 1 03/30/19 09:04 04/09/19 04:59 76-44-8 sptachlor epoxide 0.052 ug/L 0.0096 0.0050 1 03/30/19 09:04 04/09/19 04:59 1024-57-3 H7,V ethoxychlor 0.0092 U ug/L 0.0096 0.0092 1 03/30/19 09:04 04/09/19 04:59 72-43-5 CU Toxaphene 0.24 U ug/L 0.48 0.24 1 03/30/19 09:04 04/09/19 04:59 8001-35-2 Surrogates Tetrachloro-m-xylene (S) 75 % 27-124 1 03/30/19 09:04 04/09/19 04:59 877-09-8 Decachlorobiphenyl (S) 87 % 10-132 1 03/30/19 09:04 04/09/19 04:59 2051-24-3 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3010 Arsenic 13.2 ug/L 10.0 7.1 1 04/02/19 08:02 04/02/19 16:32 7440-38-2 Barium 21.9 ug/L 10.0 0.84 1 04/02/19 08:02 04/02/19 16:32 7440-39-3 Iron 1010 ug/L 40.0 9.2 1 04/02/19 08:02 04/02/19 16:32 7439-89-6 Lead 4.6 U ug/L 10.0 4.6 1 04/02/19 08:02 04/02/19 16:32 7439-92-1 Date: 07/23/2019 10:44 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 19 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35456926 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Sample: MW-3 Lab ID: 35456926003 Collected: 03/26/19 12:14 Received: 03/27/19 17:15 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8081 GCS Pesticides Analytical Method: EPA 8081 Preparation Method: EPA 3510 Aldrin 0.0015 U ug/L 0.0097 0.0015 1 03/30/19 09:04 04/09/19 05:18 309-00-2 alpha-BHC 0.0020 U ug/L 0.0097 0.0020 1 03/30/19 09:04 04/09/19 05:18 319-84-6 beta-BHC 0.0077 U ug/L 0.0097 0.0077 1 03/30/19 09:04 04/09/19 05:18 319-85-7 delta-BHC 0.0046 U ug/L 0.0097 0.0046 1 03/30/19 09:04 04/09/19 05:18 319-86-8 gamma-BHC (Lindane) 0.0021 U ug/L 0.0097 0.0021 1 03/30/19 09:04 04/09/19 05:18 58-89-9 Chlordane (Technical) 0.17 U ug/L 0.48 0.17 1 03/30/19 09:04 04/09/19 05:18 57-74-9 4,4'-DDD 0.0086 U ug/L 0.0097 0.0086 1 03/30/19 09:04 04/09/19 05:18 72-54-8 CU 4,4'-DDE 0.0048 U ug/L 0.0097 0.0048 1 03/30/19 09:04 04/09/19 05:18 72-55-9 4,4'-DDT 0.0048 U ug/L 0.0097 0.0048 1 03/30/19 09:04 04/09/19 05:18 50-29-3 CU Dieldrin 0.0019 U ug/L 0.0097 0.0019 1 03/30/19 09:04 04/09/19 05:18 60-57-1 Endosulfan I 0.0049 U ug/L 0.0097 0.0049 1 03/30/19 09:04 04/09/19 05:18 959-98-8 Endosulfan II 0.0039 U ug/L 0.0097 0.0039 1 03/30/19 09:04 04/09/19 05:18 33213-65-9 CU Endosulfan sulfate 0.0060 U ug/L 0.097 0.0060 1 03/30/19 09:04 04/09/19 05:18 1031-07-8 CU Endrin 0.0042 U ug/L 0.0097 0.0042 1 03/30/19 09:04 04/09/19 05:18 72-20-8 Endrin aldehyde 0.0035 U ug/L 0.097 0.0035 1 03/30/19 09:04 04/09/19 05:18 7421-93-4 CU Endrin ketone 0.0048 U ug/L 0.0097 0.0048 1 03/30/19 09:04 04/09/19 05:18 53494-70-5 CU Heptachlor 0.0060 U ug/L 0.0097 0.0060 1 03/30/19 09:04 04/09/19 05:18 76-44-8 Heptachlor epoxide 0.053 ug/L 0.0097 0.0050 1 03/30/19 09:04 04/09/19 05:18 1024-57-3 H7.V Methoxychlor 0.0093 U ug/L 0.0097 0.0093 1 03/30/19 09:04 04/09/19 05:18 72-43-5 CU Toxaphene 0.24 U ug/L 0.48 0.24 1 03/30/19 09:04 04/09/19 05:18 8001-35-2 Surrogates Tetrachloro-m-xylene (S) 76 % 27-124 1 03/30/19 09:04 04/09/19 05:18 877-09-8 Decachlorobiphenyl (S) 88 % 10-132 1 03/30/19 09:04 04/09/19 05:18 2051-24-3 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3010 Arsenic 7.4 I ug/L 10.0 7.1 1 04/02/19 08:02 04/02/19 16:35 7440-38-2 Barium 21.8 ug/L 10.0 0.84 1 04/02/19 08:02 04/02/19 16:35 7440-39-3 Iron 785 ug/L 40.0 9.2 1 04/02/19 08:02 04/02/19 16:35 7439-89-6 Lead 4.6 U ug/L 10.0 4.6 1 04/02/19 08:02 04/02/19 16:35 7439-92-1 Date: 07/23/2019 10:44 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 19 www pacelabs. com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35456926 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Sample: MW-4 Lab ID: 35456926004 Collected: 03/26/19 13:30 Received: 03/27/19 17:15 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8081 GCS Pesticides Analytical Method: EPA 8081 Preparation Method: EPA 3510 Aldrin 0.0015 U ug/L 0.010 0.0015 1 03/30/19 09:04 04/09/19 05:37 309-00-2 alpha-BHC 0.0021 U ug/L 0.010 0.0021 1 03/30/19 09:04 04/09/19 05:37 319-84-6 beta-BHC 0.0081 U ug/L 0.010 0.0081 1 03/30/19 09:04 04/09/19 05:37 319-85-7 delta-BHC 0.0049 U ug/L 0.010 0.0049 1 03/30/19 09:04 04/09/19 05:37 319-86-8 gamma-BHC (Lindane) 0.0022 U ug/L 0.010 0.0022 1 03/30/19 09:04 04/09/19 05:37 58-89-9 Chlordane (Technical) 0.18 U ug/L 0.51 0.18 1 03/30/19 09:04 04/09/19 05:37 57-74-9 4,4'-DDD 0.0090 U ug/L 0.010 0.0090 1 03/30/19 09:04 04/09/19 05:37 72-54-8 CU 4,4'-DDE 0.0051 U ug/L 0.010 0.0051 1 03/30/19 09:04 04/09/19 05:37 72-55-9 4,4'-DDT 0.0051 U ug/L 0.010 0.0051 1 03/30/19 09:04 04/09/19 05:37 50-29-3 CU Dieldrin 0.0020 U ug/L 0.010 0.0020 1 03/30/19 09:04 04/09/19 05:37 60-57-1 Endosulfan I 0.0052 U ug/L 0.010 0.0052 1 03/30/19 09:04 04/09/19 05:37 959-98-8 Endosulfan II 0.0041 U ug/L 0.010 0.0041 1 03/30/19 09:04 04/09/19 05:37 33213-65-9 CU Endosulfan sulfate 0.0063 U ug/L 0.10 0.0063 1 03/30/19 09:04 04/09/19 05:37 1031-07-8 CU Endrin 0.0044 U ug/L 0.010 0.0044 1 03/30/19 09:04 04/09/19 05:37 72-20-8 Endrin aldehyde 0.0037 U ug/L 0.10 0.0037 1 03/30/19 09:04 04/09/19 05:37 7421-93-4 CU Endrin ketone 0.0051 U ug/L 0.010 0.0051 1 03/30/19 09:04 04/09/19 05:37 53494-70-5 CU Heptachlor 0.0063 U ug/L 0.010 0.0063 1 03/30/19 09:04 04/09/19 05:37 76-44-8 'eptachlor epoxide 0.055 ug/L 0.010 0.0053 1 03/30/19 09:04 04/09/19 05:37 1024-57-3 H7,V ,ethoxychlor 0.0097 U ug/L 0.010 0.0097 1 03/30/19 09:04 04/09/19 05:37 72-43-5 CU Toxaphene 0.25 U ug/L 0.51 0.25 1 03/30/19 09:04 04/09/19 05:37 8001-35-2 Surrogates Tetrachloro-m-xylene (S) 89 % 27-124 1 03/30/19 09:04 04/09/19 05:37 877-09-8 Decachlorobiphenyl (S) 87 % 10-132 1 03/30/19 09:04 04/09/19 05:37 2051-24-3 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Arsenic 7.1 U ug/L 10.0 7.1 1 04/02/19 08:02 04/02/19 16:38 7440-38-2 Barium 61.7 ug/L 10.0 0.84 1 04/02/19 08:02 04/02/19 16:38 7440-39-3 Iron 530 ug/L 40.0 9.2 1 04/02/19 08:02 04/02/19 16:38 7439-89-6 Lead 4.6 U ug/L 10.0 4.6 1 04/02/19 08:02 04/02/19 16:38 7439-92-1 Date: 07/23/2019 10:44 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 19 wvw ..pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35456926 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Sample: MW-5 Lab ID: 35456926005 Collected: 03/26/19 13:57 Received: 03/27/19 17:15 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8081 GCS Pesticides Analytical Method: EPA 8081 Preparation Method: EPA 3510 Aldrin 0.0014 U ug/L 0.0096 0.0014 1 03/30/19 09:04 04/09/19 05:56 309-00-2 alpha-BHC 0.0020 U ug/L 0.0096 0.0020 1 03/30/19 09:04 04/09/19 05:56 319-84-6 beta-BHC 0.0077 U ug/L 0.0096 0.0077 1 03/30/19 09:04 04/09/19 05:56 319-85-7 delta-BHC 0.0046 U ug/L 0.0096 0.0046 1 03/30/19 09:04 04/09/19 05:56 319-86-8 gamma-BHC (Lindane) 0.0021 U ug/L 0.0096 0.0021 1 03/30/19 09:04 04/09/19 05:56 58-89-9 Chlordane (Technical) 0.17 U ug/L 0.48 0.17 1 03/30/19 09:04 04/09/19 05:56 57-74-9 4,4'-DDD 0.0085 U ug/L 0.0096 0.0085 1 03/30/19 09:04 04/09/19 05:56 72-54-8 CU 4,4'-DDE 0.0048 U ug/L 0.0096 0.0048 1 03/30/19 09:04 04/09/19 05:56 72-55-9 4,4'-DDT 0.0048 U ug/L 0.0096 0.0048 1 03/30/19 09:04 04/09/19 05:56 50-29-3 CU Dieldrin 0.0019 U ug/L 0.0096 0.0019 1 03/30/19 09:04 04/09/19 05:56 60-57-1 Endosulfan I 0.0049 U ug/L 0.0096 0.0049 1 03/30/19 09:04 04/09/19 05:56 959-98-8 Endosulfan II 0.0038 U ug/L 0.0096 0.0038 1 03/30/19 09:04 04/09/19 05:56 33213-65-9 CU Endosulfan sulfate 0.0060 U ug/L 0.096 0.0060 1 03/30/19 09:04 04/09/19 05:56 1031-07-8 CU Endrin 0.0041 U ug/L 0.0096 0.0041 1 03/30/19 09:04 04/09/19 05:56 72-20-8 Endrin aldehyde 0.0035 U ug/L 0.096 0.0035 1 03/30/19 09:04 04/09/19 05:56 7421-93-4 CU Endrin ketone 0.0048 U ug/L 0.0096 0.0048 1 03/30/19 09:04 04/09/19 05:56 53494-70-5 CU Heptachlor 0.0060 U ug/L 0.0096 0.0060 1 03/30/19 09:04 04/09/19 05:56 76-44-8 Heptachlor epoxide 0.088 ug/L 0.0096 0.0050 1 03/30/19 09:04 04/09/19 05:56 1024-57-3 H7,V Methoxychlor 0.0092 U ug/L 0.0096 0.0092 1 03/30/19 09:04 04/09/19 05:56 72-43-5 CU Toxaphene 0.24 U ug/L 0.48 0.24 1 03/30/19 09:04 04/09/19 05:56 8001-35-2 Surrogates Tetrachloro-m-xylene (S) 128 % 27-124 1 03/30/19 09:04 04/09/19 05:56 877-09-8 H7, J(S0) Decachlorobiphenyl (S) 78 ova 10-132 1 03/30/19 09:04 04/09/19 05:56 2051-24-3 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Arsenic 7.1 U ug/L 10.0 7.1 1 04/02/19 08:02 04/02/19 16:41 7440-38-2 Barium 187 ug/L 10.0 0.84 1 04/02/19 08:02 04/02/19 16:41 7440-39-3 Iron 3420 ug/L 40.0 9.2 1 04/02/19 08:02 04/02/19 16:41 7439-89-6 Lead 9.0 I ug/L 10.0 4.6 1 04/02/19 08:02 04/02/19 16:41 7439-92-1 Date: 07/23/2019 10:44 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 19 0 ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35456926 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Sample: MW-38 Parameters Lab ID: 35456926006 Collected: 03/26/19 12:55 Received: 03/27/19 17:15 Matrix: Water Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8081 GCS Pesticides Analytical Method: EPA 8081 Preparation Method: EPA 3510 Aldrin 0.0014 U ug/L 0.0096 0.0014 1 03/30/19 09:04 04/09/19 06:16 309-00-2 alpha-BHC 0.0020 U ug/L 0.0096 0.0020 1 03/30/19 09:04 04/09/19 06:16 319-84-6 beta-BHC 0.0077 U ug/L 0.0096 0.0077 1 03/30/19 09:04 04/09/19 06:16 319-85-7 delta-BHC 0.0046 U ug/L 0.0096 0.0046 1 03/30/19 09:04 04/09/19 06:16 319-86-8 gamma-BHC (Lindane) 0.0021 U ug/L 0.0096 0.0021 1 03/30/19 09:04 04/09/19 06:16 58-89-9 Chlordane (Technical) 0.17 U ug/L 0.48 0.17 1 03/30/19 09:04 04/09/19 06:16 57-74-9 4,4'-DDD 0.0085 U ug/L 0.0096 0.0085 1 03/30/19 09:04 04/09/19 06:16 72-54-8 CU 4.4'-DDE 0.0048 U ug/L 0.0096 0.0048 1 03/30/19 09:04 04/09/19 06:16 72-55-9 4,4'-DDT 0.0048 U ug/L 0.0096 0.0048 1 03/30/19 09:04 04/09/19 06:16 50-29-3 CU Dieldrin 0.0019 U ug/L 0.0096 0.0019 1 03/30/19 09:04 04/09/19 06:16 60-57-1 Endosulfan I 0.0049 U ug/L 0.0096 0.0049 1 03/30/19 09:04 04/09/19 06:16 959-98-8 Endosulfan II 0.0038 U ug/L 0.0096 0.0038 1 03/30/19 09:04 04/09/19 06:16 33213-65-9 CU Endosulfan sulfate 0.0059 U ug/L 0.096 0.0059 1 03/30/19 09:04 04/09/19 06:16 1031-07-8 CU Endrin 0.0041 U ug/L 0.0096 0.0041 1 03/30/19 09:04 04/09/19 06:16 72-20-8 Endrin aldehyde 0.0035 U ug/L 0.096 0.0035 1 03/30/19 09:04 04/09/19 06:16 7421-93-4 CU Endrin ketone 0.0048 U ug/L 0.0096 0.0048 1 03/30/19 09:04 04/09/19 06:16 53494-70-5 CU Heptachlor 0.0059 U ug/L 0.0096 0.0059 1 03/30/19 09:04 04/09/19 06:16 76-44-8 'eptachlor epoxide 0.054 ug/L 0.0096 0.0050 1 03/30/19 09:04 04/09/19 06:16 1024-57-3 H7,V .ethoxychlor 0.0092 U ug/L 0.0096 0.0092 1 03/30/19 09:04 04/09/19 06:16 72-43-5 CU Toxaphene 0.24 U ug/L 0.48 0.24 1 03/30/19 09:04 04/09/19 06:16 8001-35-2 Surrogates Tetrachloro-m-xylene (S) 95 % 27-124 1 03/30/19 09:04 04/09/19 06:16 877-09-8 Decachlorobiphenyl (S) 81 % 10-132 1 03/30/19 09:04 04/09/19 06:16 2051-24-3 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Arsenic 7.1 U ug/L 10.0 7.1 1 04/02/19 08:02 04/02/19 16:50 7440-38-2 Barium 75.3 ug/L 10.0 0.84 1 04/02/19 08:02 04/02/19 16:50 7440-39-3 Iron 3830 ug/L 40.0 9.2 1 04/02/19 08:02 04/02/19 16:50 7439-89-6 Lead 4.6 U ug/L 10.0 4.6 1 04/02/19 08:02 04/02/19 16:50 7439-92-1 Date: 07/23/2019 10:44 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 19 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35456926 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 Sample: MW-9 Lab ID: 35456926007 Collected: 03/26/19 15:02 Received: 03/27/19 17:15 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8081 GCS Pesticides Analytical Method: EPA 8081 Preparation Method EPA 3510 Aldrin 0.0014 U ug/L 0.0097 0.0014 1 03/30/19 09:04 04/09/19 06:35 309-00-2 alpha-BHC 0.0020 U ug/L 0.0097 0.0020 1 03/30/19 09:04 04/09/19 06:35 319-84-6 beta-BHC 0.0077 U ug/L 0.0097 0.0077 1 03/30/19 09:04 04/09/19 06:35 319-85-7 delta-BHC 0.0046 U ug/L 0.0097 0.0046 1 03/30/19 09:04 04/09/19 06:35 319-86-8 gamma-BHC (Lindane) 0.0021 U ug/L 0.0097 0.0021 1 03/30/19 09:04 04/09/19 06:35 58-89-9 Chlordane (Technical) 0.17 U ug/L 0.48 0.17 1 03/30/19 09:04 04/09/19 06:35 57-74-9 4,4'-DDD 0.0086 U ug/L 0.0097 0.0086 1 03/30/19 09:04 04/09/19 06:35 72-54-8 CU 4,4'-DDE 0.0048 U ug/L 0.0097 0.0048 1 03/30/19 09:04 04/09/19 06:35 72-55-9 4.4'-DDT 0.0048 U ug/L 0.0097 0.0048 1 03/30/19 09:04 04/09/19 06:35 50-29-3 CU Dieldrin 0.0019 U ug/L 0.0097 0.0019 1 03/30/19 09:04 04/09/19 06:35 60-57-1 Endosulfan I 0.0049 U ug/L 0.0097 0.0049 1 03/30/19 09:04 04/09/19 06:35 959-98-8 Endosulfan 11 0.0039 U ug/L 0.0097 0.0039 1 03/30/19 09:04 04/09/19 06:35 33213-65-9 CU Endosulfan sulfate 0.0060 U ug/L 0.097 0.0060 1 03/30/19 09:04 04/09/19 06:35 1031-07-8 CU Endrin 0.0042 U ug/L 0.0097 0.0042 1 03/30/19 09:04 04/09/19 06:35 72-20-8 Endrin aldehyde 0.0035 U ug/L 0.097 0.0035 1 03/30/19 09:04 04/09/19 06:35 7421-93-4 CU Endrin ketone 0.0048 U ug/L 0.0097 0.0048 1 03/30/19 09:04 04/09/19 06:35 53494-70-5 CU Heptachlor 0.0060 U ug/L 0.0097 0.0060 1 03/30/19 09:04 04/09/19 06:35 76-44-8 Heptachlor epoxide 0.063 ug/L 0.0097 0.0050 1 03/30/19 09:04 04/09/19 06:35 1024-57-3 H7,V Methoxychlor 0.0093 U ug/L 0.0097 0.0093 1 03/30/19 09:04 04/09/19 06:35 72-43-5 CU Toxaphene 0.24 U ug/L 0.48 0.24 1 03/30/19 09:04 04/09/19 06:35 8001-35-2 Surrogates Tetrachloro-m-xylene (S) 151 % 27-124 1 03/30/19 09:04 04/09/19 06:35 877-09-8 H7, J(S0) Decachlorobiphenyl (S) 71 Ok 10-132 1 03/30/19 09:04 04/09/19 06:35 2051-24-3 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Arsenic 7.1 U ug/L 10.0 7.1 1 04/02/19 08:02 04/02/19 16:52 7440-38-2 Barium 95.1 ug/L 10.0 0.84 1 04/02/19 08:02 04/02/19 16:52 7440-39-3 Iron 4030 ug/L 40.0 9.2 1 04/02/19 08:02 04/02/19 16:52 7439-89-6 Lead 4.6 U ug/L 10.0 4.6 1 04/02/19 08:02 04/02/19 16:52 7439-92-1 Date: 07/23/2019 10:44 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 19 www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35456926 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 QC Batch: 527677 QC Batch Method: EPA 3010 Analysis Method: EPA 6010 Analysis Description: 6010 MET Associated Lab Samples: 35456926001, 35456926002, 35456926003, 35456926004, 35456926005, 35456926006, 35456926007 METHOD BLANK: 2855775 Matrix: Water Associated Lab Samples: Parameter 35456926001, 35456926002, 35456926003, 35456926004, 35456926005, 35456926006, 35456926007 Blank Reporting Units Result Limit MDL Analyzed Qualifiers Arsenic ug/L 7.1 U 10.0 7.1 04/02/19 16:15 Barium ug/L 0.84 U 10.0 0.84 04/02/19 16:15 Iron ug/L 9.2 U 40.0 9.2 04/02/19 16:15 Lead ug/L 4.6 U 10.0 4.6 04/02/19 16:15 LABORATORY CONTROL SAMPLE: 2855776 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic ug/L 250 241 96 80-120 Barium ug/L 250 239 95 80-120 Iron ug/L 2500 2480 99 80-120 Lead ug/L 250 249 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2855777 2855778 MS MSD 35456926001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L 7.1 U 250 250 248 254 98 100 75-125 2 20 Barium ug/L 46.5 250 250 287 290 96 97 75-125 1 20 Iron ug/L 333 2500 2500 2850 2870 101 102 75-125 1 20 Lead ug/L 4.6 U 250 250 255 259 102 104 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 07/23/2019 10:44 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 19 aceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35456926 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 QC Batch: 527144 Analysis Method: EPA 8081 QC Batch Method: EPA 3510 Analysis Description: 8081 GCS Pesticides Associated Lab Samples: 35456926001, 35456926002, 35456926003, 35456926004, 35456926005, 35456926006, 35456926007 METHOD BLANK: 2852411 Matrix: Water Associated Lab Samples: Parameter 35456926001, 35456926002, 35456926003, 35456926004, 35456926005, 35456926006, 35456926007 Blank Reporting Units Result Limit MDL Analyzed Qualifiers 4,4'-DDD ug/L 0.0089 U 0.010 0.0089 04/09/19 03:41 CU 4,4'-DDE ug/L 0.0050 U 0.010 0.0050 04/09/19 03:41 4,4'-DDT ug/L 0.0050 U 0.010 0.0050 04/09/19 03:41 CU Aldrin ug/L 0.0015 U 0.010 0.0015 04/09/19 03:41 alpha-BHC ug/L 0.0021 U 0.010 0.0021 04/09/19 03:41 beta-BHC ug/L 0.0080 U 0.010 0.0080 04/09/19 03:41 Chlordane (Technical) ug/L 0.18 U 0.50 0.18 04/09/19 03:41 delta-BHC ug/L 0.0048 U 0.010 0.0048 04/09/19 03:41 Dieldrin ug/L 0.0020 U 0.010 0.0020 04/09/19 03:41 Endosulfan I ug/L 0.0051 U 0.010 0.0051 04/09/19 03:41 Endosulfan II ug/L 0.0040 U 0.010 0.0040 04/09/19 03:41 CU Endosulfan sulfate ug/L 0.0062 U 0.10 0.0062 04/09/19 03:41 CU Endrin ug/L 0.0043 U 0.010 0.0043 04/09/19 03:41 Endrin aldehyde ug/L 0.0036 U 0.10 0.0036 04/09/19 03:41 CU Endrin ketone ug/L 0.0050 U 0.010 0.0050 04/09/19 03:41 gamma-BHC (Lindane) ug/L 0.0022 U 0.010 0.0022 04/09/19 03:41 Heptachlor ug/L 0.0062 U 0.010 0.0062 04/09/19 03:41 Heptachlor epoxide ug/L 0.053 0.010 0.0052 04/09/19 03:41 Methoxychlor ug/L 0.0096 U 0.010 0.0096 04/09/19 03:41 CU Toxaphene ug/L 0.25 U 0.50 0.25 04/09/19 03:41 Decachlorobiphenyl (S) % 84 10-132 04/09/19 03:41 Tetrachloro-m-xylene (S) % 64 27-124 04/09/19 03:41 LABORATORY CONTROL SAMPLE & LCSD: 2852412 2853474 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers 4,4'-DDD ug/L 0.5 0.49 0.50 98 99 67-133 1 40 CH 4,4'-DDE ug/L 0.5 0.48 0.49 96 98 59-125 1 40 4,4'-DDT ug/L 0.5 0.58 0.60 117 120 54-132 2 40 CH,CU Aldrin ug/L 0.5 0.45 0.45 90 90 25-116 1 40 alpha-BHC ug/L 0.5 0.47 0.47 93 95 53-126 1 40 beta-BHC ug/L 0.5 0.50 0.50 99 100 62-130 1 40 delta-BHC ug/L 0.5 0.35 0.35 69 70 35-122 1 40 Dieldrin ug/L 0.5 0.48 0.49 97 97 66-128 1 40 Endosulfan I ug/L 0.5 0.48 0.49 97 98 67-125 1 40 Endosulfan II ug/L 0.5 0.48 0.49 97 98 67-131 1 40 CH Endosulfan sulfate ug/L 0.5 0.54 0.56 108 111 62-127 3 40 CH,CU Endrin ug/L 0.5 0.49 0.50 98 100 66-130 1 40 Endrin aldehyde ug/L 0.5 0.50 0.51 100 102 61-124 2 40 CH,CU Endrin ketone ug/L 0.5 0.53 0.55 107 110 65-132 3 40 CH,CU Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 07/23/2019 10:44 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 19 www pacelabs. com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35456926 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 LABORATORY CONTROL SAMPLE & LCSD: 2852412 2853474 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers gamma-BHC (Lindane) ug/L 0.5 0.49 0.49 98 99 58-127 0 40 Heptachlor ug/L 0.5 0.48 0.49 96 97 35-123 1 40 Heptachlor epoxide ug/L 0.5 0.49 0.49 98 99 62-125 1 40 Methoxychlor ug/L 0.5 0.55 0.57 109 114 59-135 4 40 CH,CU Decachlorobiphenyl (S) % 84 88 10-132 Tetrachloro-m-xylene (S) % 75 75 27-124 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 07/23/2019 10:44 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 19 aceAnalytical www.pacelabs.com QUALIFIERS Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35456926 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 (954)582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. U Compound was analyzed for but not detected. CH The continuing calibration for this compound is outside of Pace Analytical acceptance limits. The results may be biased high. CU The continuing calibration for this analyte is above laboratory acceptance limits. Analyte was not detected above the reporting limit in any of the associated samples. H7 Re -extraction or re -analysis could not be performed within method holding time. J(S0) Estimated Value. Surrogate recovery outside laboratory control limits. V Indicates that the analyte was detected in both the sample and the associated method blank. Date: 07/23/2019 10:44AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 19 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach. FL 33064 (954)582-4300 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melreese Golf Course -Revised Report Pace Project No.: 35456926 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 35456926001 MW-1 EPA 3510 527144 EPA 8081 527849 35456926002 MW-2 EPA 3510 527144 EPA 8081 527849 35456926003 MW-3 EPA 3510 527144 EPA 8081 527849 35456926004 MW-4 EPA 3510 527144 EPA 8081 527849 35456926005 MW-5 EPA 3510 527144 EPA 8081 527849 35456926006 MW-38 EPA 3510 527144 EPA 8081 527849 35456926007 MW-9 EPA 3510 527144 EPA 8081 527849 35456926001 MW-1 EPA 3010 527677 EPA 6010 527793 35456926002 MW-2 EPA 3010 527677 EPA 6010 527793 35456926003 MW-3 EPA 3010 527677 EPA 6010 527793 35456926004 MW-4 EPA 3010 527677 EPA 6010 527793 35456926005 MW-5 EPA 3010 527677 EPA 6010 527793 35456926006 MW-38 EPA 3010 527677 EPA 6010 527793 35456926007 MW-9 EPA 3010 527677 EPA 6010 527793 Date: 07/23/2019 10:44 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 19 WO#:3545L 26 equest Document 1111 I 1111 IIIHUH 111 vant fields must be completed accurately. Section A Section B Required Client Information: Required Project Information: 35456926 Page - Of Company EE&G Environmental Services. LLC Report To Michael Van Ry . •••� � Address 5751 Miami Lakes Drive Copy To (• i , . Company Name Miami Lakes FL 33014 Address Regulatory Agency Email mvanry@eeandg com Purchase Order # Pace Quote Phone. (305)374-8300 IFax Project Name Melreese Golf Course Pace Project Manager chrislina.raschke@pacelabs.corn State / Location Reques:ed Due Date _ - Project #: 2018-3057 race Profile it FL Requested Analysis Filtered (Y! 1) 2 >- MATRIX cooE I,ATRIX CODE (see valid codes to left) SAMPLE TYPE (G=GRAB C=COMP) COLLECTED SAMPLE TEMP AT COLLECTION tt OF CONTAINERS• Preservatives Analyses Test a_ d Lai vi Q o O co co Q 0. 8260 VOC TRPH FL -PRO 8290 Dioxin & Furans OC Pesticides 8081 OP Pesticides 8141 8151 Herbicides 6010-Ba, Cd, Cr, Se, Ag 7470 Hg -- _ - z o` aJ 7,3 cc on.rg W..., DW W:r,e, Wr Wa.r,• Water WW ProductP SAMPLE ID aci soh° oi. START END HNO3 HCI U — One Character per box. Wope WP otho of Sample Ids must be unique r,:�e s2 DATE TIME DATE TIME n, 8 o. c D O 0 2 = O (0 Z Oc NL al Z m 2 L~ 0 1 I-• _ .. l-) ' 2 li 3 4 5 6 8 9 10 11 12 ADDITIONAL COMMENTS RELINQUISHED BY I AFFILIATION DATE TIME ACCEPTED BY I AFFILIAT/r ' DATE TIME SAMPLE CONDITIONS - 31.271, ,c5.) 7,„;. /,..) SAMPLER NAME AND SIGNATURE TEMP in C Received on Ice (Y/N) uslo y Sealed Cooler {Y/N) Samples Intact (YIN) PRINT Name of SAMPLER: SIGNATUREof SAMPLER: I DATE Signed: _ 0 CO N CO t7) d Billing: Tracking # P- -Pace Analytical Document Name Sample Condition Upon Receipt Fo m Document Revised May 30, 2018 Document No F-FL-C-007 rev 13 Issuing Autnonty Pace Florida Quality Office Project # Project Manager: Client: PM: CTR CLIENT: 36-EEG WP54569j' Due Date: 04/03/19 Date and Initials of person: Examining contents: Label: Deliver: pH: Thermometer Used -3 gV Date Time. 04 State of Ongin I 0 I For '.:P.: protects, all containers verified to 56 CC Cooler#1 Temp.'C %y,( (Visual) V. (Correction Factor) (/7% (Actual) Cooler #2 Temp.°C / (Visual) (Correction Factor) / (Actual) Cooler #3 Temp.°C (Visual) (Correction Factor) (Actual) Cooler#4 Temp.'C (Visual) (Correction Factor) (Actual) Cooler #5 Temp.'C (Visual) (Correction Factor) (Actual) Cooler #6 Temp.'C (Visual) (Correction Factor) (Actual) Courier: — Fed Ex Initials r�r Samples on ice, cooling process nas begun L Samples on ice cooling process nas begun L Samples on ice. cooling process nas begun L Samples on ice, cooling process has begun L Samples on ice, cooling process has begun L Samples on :ce, cooling process has begun UPS ❑ USPS — Client L Commercial Pace L Other Shipping Method: = First Overnight - Priority Overnight _ Standard Overnight = Ground = Other = Recipient = Sender = Third Party = Credit Card International Priority Unknown Custody Seal on Cooler/Box Present: LYes Seals intact: _ Yes .;.:4vU Ice: Packing Material: 'Bubble Wrap ❑ Bubble Bags K None ❑Other Samples shorted to lab (If Yes, complete) Shorted Date j-!V iy Shorted Time Nit ue Dry None Oty. / u ►'1 Comments: Chain of Custody Present .Yes = No ;N/A Chain of Custody Filled Out s - No IN/A Relinquished Signature & Sampler Name COC es _.. No -N/A Samples Arrived within Hold Time — es 1 No ;N/A Rush TAT requested on COC Yes •<IVo w =N/A Sufficient Volume �'C No GN/A Correct Containers Used -_Y No =N/A Containers Intact _Yeess Yes : No -N/A Sample Labels match COC (sample IDs & date(pme of collection) es No =N/A All containers needino acid/base preservation have been checked es All Containers needing preservation are found to oe in compliance with EPA recommendation --- Exceptions VOA. Conform. TOC. O&G, Carbarnates _ No EN/A No _ N/A Preservation Information Preservative Lot #/Trace # Date Time Initials Headspace in VOA Vials? ( >6mm) =Yes = NoA Trip Blank Present ;Yes = No -9iA Client Notification/ Resolution: Person Contacted Comments/ Resolution (use back for additional comments): Date/Time Project Manager Review. Date age-19 of 19 aceAnalytical® www.pacelabs.com April 05, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456922 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 27, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Some analyses have been subcontracted outside of the Pace Network. The subcontracted laboratory report has been attached. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry, EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 35 CERTIFICATIONS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456922 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 35 aceAnalytical wwwpacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456922 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35456922001 MW-9 Water 03/26/19 15:02 03/27/19 17:15 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 35 aceAnalytical wwwpacelabs_com SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456922 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35456922001 MW-9 FL -PRO BP2 3 PASI-O EPA 8270 by SIM MMG 20 PASI-O EPA 8260 SKI 70 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 35 aceAnalytical wv'w pace/abs. con SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456922 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35456922001 MW-9 EPA 8260 Acetone 14.2 I ug/L EPA 8260 Methyl-tert-butyl ether 0.58 I ug/L REPORT OF LABORATORY ANALYSIS 20.0 04/02/19 06:27 2.0 04/02/19 06:27 J This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 35 aceAnalytical e www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456922 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-9 Lab ID: 35456922001 Collected: 03/26/19 15:02 Received: 03/27/19 17:15 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual FL -PRO Water, Low Volume Analytical Method: FL -PRO Preparation Method: EPA 3510 Petroleum Range Organics Surrogates o-Terphenyl (S) N-Pentatriacontane (S) 0.88 U mg/L 1.1 0.88 1 03/29/19 11:37 03/30/19 00:23 88 93 66-139 1 03/29/19 11:37 03/30/19 00:23 84-15-1 42-159 1 03/29/19 11:37 03/30/19 00:23 630-07-09 8270 MSSV PAHLV by SIM Analytical Method: EPA 8270 by SIM Preparation Method: EPA 3510 Acenaphthene 0.040 U ug/L 0.50 0.040 1 03/29/19 08:15 03/29/19 17:50 83-32-9 Acenaphthylene 0.030 U ug/L 0.50 0.030 1 03/29/19 08:15 03/29/19 17:50 208-96-8 Anthracene 0.043 U ug/L 0.50 0.043 1 03/29/19 08:15 03/29/19 17:50 120-12-7 Benzo(a)anthracene 0.055 U ug/L 0.10 0.055 1 03/29/19 08:15 03/29/19 17:50 56-55-3 Benzo(a)pyrene 0.12 U ug/L 0.20 0.12 1 03/29/19 08:15 03/29/19 17:50 50-32-8 Benzo(b)fluoranthene 0.027 U ug/L 0.10 0.027 1 03/29/19 08:15 03/29/19 17:50 205-99-2 Benzo(g,h,i)perylene 0.15 U ug/L 0.50 0.15 1 03/29/19 08:15 03/29/19 17:50 191-24-2 Benzo(k)fluoranthene 0.16 U ug/L 0.50 0.16 1 03/29/19 08:15 03/29/19 17:50 207-08-9 Chrysene 0.026 U ug/L 0.50 0.026 1 03/29/19 08:15 03/29/19 17:50 218-01-9 Dibenz(a,h)anthracene 0.13 U ug/L 0.15 0.13 1 03/29/19 08:15 03/29/19 17:50 53-70-3 Fluoranthene 0.018 U ug/L 0.50 0.018 1 03/29/19 08:15 03/29/19 17:50 206-44-0 Fluorene 0.088 U ug/L 0.50 0.088 1 03/29/19 08:15 03/29/19 17:50 86-73-7 Indeno(1,2,3-cd)pyrene 0.12 U ug/L 0.15 0.12 1 03/29/19 08:15 03/29/19 17:50 193-39-5 1-Methylnaphthalene 0.19 U ug/L 2.0 0.19 1 03/29/19 08:15 03/29/19 17:50 90-12-0 2-Methylnaphthalene 0.68 U ug/L 2.0 0.68 1 03/29/19 08:15 03/29/19 17:50 91-57-6 Naphthalene 0.29 U ug/L 2.0 0.29 1 03/29/19 08:15 03/29/19 17:50 91-20-3 Phenanthrene 0.16 U ug/L 0.50 0.16 1 03/29/19 08:15 03/29/19 17:50 85-01-8 Pyrene 0.032 U ug/L 0.50 0.032 1 03/29/19 08:15 03/29/19 17:50 129-00-0 Surrogates 2-Fluorobiphenyl (S) 58 % 33-82 1 03/29/19 08:15 03/29/19 17:50 321-60-8 p-Terphenyl-d14 (S) 81 % 49-104 1 03/29/19 08:15 03/29/19 17:50 1718-51-0 8260 MSV Analytical Method: EPA 8260 1,1,1,2-Tetrachloroethane 0.32 U ug/L 1.0 0.32 1 04/02/19 06:27 630-20-6 1.1,1-Trichloroethane 0.30 U ug/L 1.0 0.30 1 04/02/19 06:27 71-55-6 1,1,2.2-Tetrachloroethane 0.20 U ug/L 0.50 0.20 1 04/02/19 06:27 79-34-5 1,1.2-Trichloroethane 0.30 U ug/L 1.0 0.30 1 04/02/19 06:27 79-00-5 1,1-Dichloroethane 0.34 U ug/L 1.0 0.34 1 04/02/19 06:27 75-34-3 1,1-Dichloroethene 0.27 U ug/L 1.0 0.27 1 04/02/19 06:27 75-35-4 1,1-Dichloropropene 0.31 U ug/L 1.0 0.31 1 04/02/19 06:27 563-58-6 1,2,3-Trichlorobenzene 0.34 U ug/L 1.0 0.34 1 04/02/19 06:27 87-61-6 1,2,3-Trichloropropane 1.1 U ug/L 2.0 1.1 1 04/02/19 06:27 96-18-4 1,2,3-Trimethylbenzene 0.17 U ug/L 1.0 0.17 1 04/02/19 06:27 526-73-8 1,2,4-Trichlorobenzene 0.32 U ug/L 1.0 0.32 1 04/02/19 06:27 120-82-1 1,2,4-Trimethylbenzene 0.24 U ug/L 1.0 0.24 1 04/02/19 06:27 95-63-6 1,2-Dichlorobenzene 0.29 U ug/L 1.0 0.29 1 04/02/19 06:27 95-50-1 J 1.2-Dichloroethane 0.27 U ug/L 1.0 0.27 1 04/02/19 06:27 107-06-2 1,2-Dichloropropane 0.23 U ug/L 1.0 0.23 1 04/02/19 06:27 78-87-5 1,3,5-Trimethylbenzene 0.24 U ug/L 1.0 0.24 1 04/02/19 06:27 108-67-8 1,3-Dichlorobenzene 0.33 U ug/L 1.0 0.33 1 04/02/19 06:27 541-73-1 Date: 04/05/2019 06:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 35 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456922 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-9 Lab ID: 35456922001 Collected: 03/26/19 15:02 Received: 03/27/19 17:15 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Analytical Method: EPA 8260 1,3-Dichloropropane 0.26 U ug/L 1.0 0.26 1 04/02/19 06:27 142-28-9 1.4-Dichlorobenzene 0.28 U ug/L 1.0 0.28 1 04/02/19 06:27 106-46-7 2.2-Dichloropropane 0.59 U ug/L 1.0 0.59 1 04/02/19 06:27 594-20-7 2-Butanone (MEK) 7.5 U ug/L 10.0 7.5 1 04/02/19 06:27 78-93-3 J 2-Chloroethylvinyl ether 1.4 U ug/L 40.0 1.4 1 04/02/19 06:27 110-75-8 J,c2 2-Chlorotoluene 0.28 U ug/L 1.0 0.28 1 04/02/19 06:27 95-49-8 2-Hexanone 0.85 U ug/L 10.0 0.85 1 04/02/19 06:27 591-78-6 4-Chlorotoluene 0.22 U ug/L 1.0 0.22 1 04/02/19 06:27 106-43-4 4-Methyl-2-pentanone (MIBK) 0.32 U ug/L 10.0 0.32 1 04/02/19 06:27 108-10-1 Acetone 14.2 I ug/L 20.0 5.3 1 04/02/19 06:27 67-64-1 Acetonitrile 24.5 U ug/L 40.0 24.5 1 04/02/19 06:27 75-05-8 Benzene 0.30 U ug/L 1.0 0.30 1 04/02/19 06:27 71-43-2 Bromobenzene 0.21 U ug/L 1.0 0.21 1 04/02/19 06:27 108-86-1 Bromochloromethane 0.37 U ug/L 1.0 0.37 1 04/02/19 06:27 74-97-5 Bromodichloromethane 0.19 U ug/L 0.60 0.19 1 04/02/19 06:27 75-27-4 Bromoform 2.6 U ug/L 3.0 2.6 1 04/02/19 06:27 75-25-2 Bromomethane 4.0 U ug/L 5.0 4.0 1 04/02/19 06:27 74-83-9 J 'arbon disulfide 0.45 U ug/L 10.0 0.45 1 04/02/19 06:27 75-15-0 J arbon tetrachloride 1.1 U ug/L 3.0 1.1 1 04/02/19 06:27 56-23-5 Chlorobenzene 0.35 U ug/L 1.0 0.35 1 04/02/19 06:27 108-90-7 Chloroethane 3.7 U ug/L 10.0 3.7 1 04/02/19 06:27 75-00-3 Chloroform 0.32 U ug/L 1.0 0.32 1 04/02/19 06:27 67-66-3 Chloromethane 0.97 U ug/L 1.0 0.97 1 04/02/19 06:27 74-87-3 J Dibromochloromethane 0.45 U ug/L 2.0 0.45 1 04/02/19 06:27 124-48-1 Dibromomethane 0.68 U ug/L 2.0 0.68 1 04/02/19 06:27 74-95-3 Dichlorodifluoromethane 0.26 U ug/L 1.0 0.26 1 04/02/19 06:27 75-71-8 Ethylbenzene 0.30 U ug/L 1.0 0.30 1 04/02/19 06:27 100-41-4 lodomethane 9.3 U ug/L 10.0 9.3 1 04/02/19 06:27 74-88-4 J Isopropylbenzene (Cumene) 0.30 U ug/L 1.0 0.30 1 04/02/19 06:27 98-82-8 Methyl-tert-butyl ether 0.58 I ug/L 2.0 0.51 1 04/02/19 06:27 1634-04-4 J Methylene Chloride 2.0 U ug/L 5.0 2.0 1 04/02/19 06:27 75-09-2 Styrene 0.26 U ug/L 1.0 0.26 1 04/02/19 06:27 100-42-5 Tetrachloroethene 0.38 U ug/L 1.0 0.38 1 04/02/19 06:27 127-18-4 Toluene 0.33 U ug/L 1.0 0.33 1 04/02/19 06:27 108-88-3 J Trichloroethene 0.36 U ug/L 1.0 0.36 1 04/02/19 06:27 79-01-6 Trichlorofluoromethane 0.35 U ug/L 1.0 0.35 1 04/02/19 06:27 75-69-4 Vinyl acetate 0.19 U ug/L 10.0 0.19 1 04/02/19 06:27 108-05-4 Vinyl chloride 0.39 U ug/L 1.0 0.39 1 04/02/19 06:27 75-01-4 Xylene (Total) 2.1 U ug/L 5.0 2.1 1 04/02/19 06:27 1330-20-7 cis-1,2-Dichloroethene 0.27 U ug/L 1.0 0.27 1 04/02/19 06:27 156-59-2 cis-1,3-Dichloropropene 0.17 U ug/L 0.50 0.17 1 04/02/19 06:27 10061-01-5 m&p-Xylene 2.1 U ug/L 4.0 2.1 1 04/02/19 06:27 179601-23-1 n-Butylbenzene 0.20 U ug/L 1.0 0.20 1 04/02/19 06:27 104-51-8 n-Propylbenzene 0.37 U ug/L 1.0 0.37 1 04/02/19 06:27 103-65-1 o-Xylene 0.27 U ug/L 1.0 0.27 1 04/02/19 06:27 95-47-6 p-Isopropyltoluene 0.31 U ug/L 5.0 0.31 1 04/02/19 06:27 99-87-6 Date: 04/05/2019 06:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 35 72ceAnalytical www.pace/abs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456922 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-9 Lab ID: 35456922001 Collected: 03/26/19 15:02 Received: 03/27/19 17:15 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Analytical Method: EPA 8260 sec-Butylbenzene 0.17 U ug/L 1.0 0.17 1 04/02/19 06:27 135-98-8 tert-Butylbenzene 0.26 U ug/L 1.0 0.26 1 04/02/19 06:27 98-06-6 trans-1.2-Dichloroethene 0.23 U ug/L 1.0 0.23 1 04/02/19 06:27 156-60-5 trans-1.3-Dichloropropene 0.17 U ug/L 0.50 0.17 1 04/02/19 06:27 10061-02-6 J(L1) Surrogates 4-Bromofluorobenzene (S) 100 % 70-130 1 04/02/19 06:27 460-00-4 1.2-Dichloroethane-d4 (S) 105 % 70-130 1 04/02/19 06:27 17060-07-0 Toluene-d8 (S) 98 % 70-130 1 04/02/19 06:27 2037-26-5 Date: 04/05/2019 06:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. without the written consent of Pace Analytical Services, LLC. Page 8 of 35 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456922 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 527630 Analysis Method: EPA 8260 QC Batch Method: EPA 8260 Analysis Description: 8260 MSV Associated Lab Samples: 35456922001 METHOD BLANK: 2855528 Matrix: Water Associated Lab Samples: 35456922001 Parameter Blank Reporting Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L 0.32 U 1.0 0.32 04/01/19 21:52 1,1,1-Trichloroethane ug/L 0.30 U 1.0 0.30 04/01/19 21:52 1,1,2,2-Tetrachloroethane ug/L 0.20 U 0.50 0.20 04/01/19 21:52 1,1,2-Trichloroethane ug/L 0.30 U 1.0 0.30 04/01/19 21:52 1,1-Dichloroethane ug/L 0.34 U 1.0 0.34 04/01/19 21:52 1,1-Dichloroethene ug/L 0.27 U 1.0 0.27 04/01/19 21:52 1,1-Dichloropropene ug/L 0.31 U 1.0 0.31 04/01/19 21:52 1,2,3-Trichlorobenzene ug/L 0.34 U 1.0 0.34 04/01/1921:52 1,2,3-Trichloropropane ug/L 1.1 U 2.0 1.1 04/01/1921:52 1,2,3-Trimethylbenzene ug/L 0.17 U 1.0 0.17 04/01/1921:52 1,2,4-Trichlorobenzene ug/L 0.32 U 1.0 0.32 04/01/19 21:52 1,2,4-Trimethylbenzene ug/L 0.24 U 1.0 0.24 04/01/1921:52 1,2-Dichlorobenzene ug/L 0.29 U 1.0 0.29 04/01/19 21:52 J 1,2-Dichloroethane ug/L 0.27 U 1.0 0.27 04/01/19 21:52 2-Dichloropropane ug/L 0.23 U 1.0 0.23 04/01/19 21:52 1,3,5-Trimethylbenzene ug/L 0.24 U 1.0 0.24 04/01/19 21:52 1,3-Dichlorobenzene ug/L 0.33 U 1.0 0.33 04/01/19 21:52 1,3-Dichloropropane ug/L 0.26 U 1.0 0.26 04/01/1921:52 1,4-Dichlorobenzene ug/L 0.28 U 1.0 0.28 04/01/19 21:52 2,2-Dichloropropane ug/L 0.59 U 1.0 0.59 04/01/19 21:52 2-Butanone (MEK) ug/L 7.5 U 10.0 7.5 04/01/19 21:52 J 2-Chloroethylvinyl ether ug/L 1.4 U 40.0 1.4 04/01/19 21:52 J 2-Chlorotoluene ug/L 0.28 U 1.0 0.28 04/01/19 21:52 2-Hexanone ug/L 0.85 U 10.0 0.85 04/01/19 21:52 4-Chlorotoluene ug/L 0.22 U 1.0 0.22 04/01/19 21:52 4-Methyl-2-pentanone (MIBK) ug/L 0.32 U 10.0 0.32 04/01/19 21:52 Acetone ug/L 5.3 U 20.0 5.3 04/01/19 21:52 Acetonitrile ug/L 24.5 U 40.0 24.5 04/01/19 21:52 Benzene ug/L 0.30 U 1.0 0.30 04/01/19 21:52 Bromobenzene ug/L 0.21 U 1.0 0.21 04/01/19 21:52 Bromochloromethane ug/L 0.37 U 1.0 0.37 04/01/19 21:52 Bromodichloromethane ug/L 0.19 U 0.60 0.19 04/01/19 21:52 Bromoform ug/L 2.6 U 3.0 2.6 04/01/19 21:52 Bromomethane ug/L 4.0 U 5.0 4.0 04/01/19 21:52 J Carbon disulfide ug/L 0.45 U 10.0 0.45 04/01/19 21:52 J Carbon tetrachloride ug/L 1.1 U 3.0 1.1 04/01/19 21:52 Chlorobenzene ug/L 0.35 U 1.0 0.35 04/01/19 21:52 Chloroethane ug/L 3.7 U 10.0 3.7 04/01/19 21:52 Chloroform ug/L 0.32 U 1.0 0.32 04/01/19 21:52 Chloromethane ug/L 0.97 U 1.0 0.97 04/01/19 21:52 J cis-1,2-Dichloroethene ug/L 0.27 U 1.0 0.27 04/01/19 21:52 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/05/2019 06:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 35 aceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456922 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 METHOD BLANK: 2855528 Matrix: Water Associated Lab Samples: 35456922001 Parameter Blank Reporting Units Result Limit MDL Analyzed Qualifiers cis-1,3-Dichloropropene ug/L 0.17 U 0.50 0.17 04/01/1921:52 Dibromochloromethane ug/L 0.45 U 2.0 0.45 04/01/19 21:52 Dibromomethane ug/L 0.68 U 2.0 0.68 04/01/19 21:52 Dichlorodifluoromethane ug/L 0.26 U 1.0 0.26 04/01/19 21:52 Ethylbenzene ug/L 0.30 U 1.0 0.30 04/01/19 21:52 lodomethane ug/L 9.3 U 10.0 9.3 04/01/19 21:52 J lsopropylbenzene (Cumene) ug/L 0.30 U 1.0 0.30 04/01/19 21:52 m&p-Xylene ug/L 2.1 U 4.0 2.1 04/01/19 21:52 Methyl-tert-butyl ether ug/L 0.51 U 2.0 0.51 04/01/19 21:52 J Methylene Chloride ug/L 2.0 U 5.0 2.0 04/01/19 21:52 n-Butylbenzene ug/L 0.20 U 1.0 0.20 04/01/19 21:52 n-Propylbenzene ug/L 0.37 U 1.0 0.37 04/01/19 21:52 o-Xylene ug/L 0.27 U 1.0 0.27 04/01/19 21:52 p-lsopropyltoluene ug/L 0.31 U 5.0 0.31 04/01/19 21:52 sec-Butylbenzene ug/L 0.17 U 1.0 0.17 04/01/19 21:52 Styrene ug/L 0.26 U 1.0 0.26 04/01/19 21:52 tert-Butylbenzene ug/L 0.26 U 1.0 0.26 04/01/19 21:52 Tetrachloroethene ug/L 0.38 U 1.0 0.38 04/01/19 21:52 Toluene ug/L 0.33 U 1.0 0.33 04/01/19 21:52 J trans-1,2-Dichloroethene ug/L 0.23 U 1.0 0.23 04/01/1921:52 trans-1,3-Dichloropropene ug/L 0.17 U 0.50 0.17 04/01/19 21:52 Trichloroethene ug/L 0.36 U 1.0 0.36 04/01/19 21:52 Trichlorofluoromethane ug/L 0.35 U 1.0 0.35 04/01/19 21:52 Vinyl acetate ug/L 0.19 U 10.0 0.19 04/01/19 21:52 Vinyl chloride ug/L 0.39 U 1.0 0.39 04/01/19 21:52 Xylene (Total) ug/L 2.1 U 5.0 2.1 04/01/19 21:52 1,2-Dichloroethane-d4 (S) % 104 70-130 04/01/19 21:52 4-Bromofluorobenzene (S) % 100 70-130 04/01/19 21:52 Toluene-d8 (S) % 98 70-130 04/01/19 21:52 LABORATORY CONTROL SAMPLE: 2855529 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 20 18.3 91 70-130 1,1,1-Trichloroethane ug/L 20 16.9 84 70-130 1,1,2,2-Tetrachloroethane ug/L 20 18.2 91 68-125 1,1,2-Trichloroethane ug/L 20 16.5 83 70-130 1,1-Dichloroethane ug/L 20 17.4 87 70-130 1,1-Dichloroethene ug/L 20 17.2 86 66-133 1,1-Dichloropropene ug/L 20 17.0 85 70-130 1,2,3-Trichlorobenzene ug/L 20 18.9 95 64-126 1,2,3-Trichloropropane ug/L 20 18.2 91 62-127 1,2,3-Trimethylbenzene ug/L 20 17.2 86 70-130 1,2,4-Trichlorobenzene ug/L 20 17.4 87 63-124 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/05/2019 06:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 35 aceAnalytical vivnv.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456922 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE: 2855529 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,2,4-Trimethylbenzene ug/L 20 17.8 89 70-130 1,2-Dichlorobenzene ug/L 20 23.0 115 70-130 J 1,2-Dichloroethane ug/L 20 16.1 81 70-130 1,2-Dichloropropane ug/L 20 17.3 86 70-130 1,3,5-Trimethylbenzene ug/L 20 17.5 87 70-130 1,3-Dichlorobenzene ug/L 20 16.6 83 70-130 1,3-Dichloropropane ug/L 20 17.6 88 70-130 1,4-Dichlorobenzene ug/L 20 16.8 84 70-130 2,2-Dichloropropane ug/L 20 17.3 87 59-133 2-Butanone (MEK) ug/L 40 33.9 85 47-143 J 2-Chloroethylvinyl ether ug/L 20 14.6 I 73 41-140 J 2-Chlorotoluene ug/L 20 16.5 82 70-130 2-Hexanone ug/L 40 33.1 83 48-145 4-Chlorotoluene ug/L 20 17.0 85 70-130 4-Methyl-2-pentanone (MIBK) ug/L 40 46.7 117 57-132 Acetone ug/L 40 37.2 93 46-148 Acetonitrile ug/L 200 213 106 33-175 Benzene ug/L 20 17.0 85 70-130 Bromobenzene ug/L 20 17.8 89 70-130 'romochloromethane ug/L 20 16.0 80 70-130 ,romodichloromethane ug/L 20 16.2 81 70-130 Bromoform ug/L 20 16.2 81 49-126 Bromomethane ug/L 20 5.0 25 10-165 J Carbon disulfide ug/L 20 15.5 78 60-141 J Carbon tetrachloride ug/L 20 16.4 82 63-126 Chlorobenzene ug/L 20 16.5 82 70-130 Chloroethane ug/L 20 17.6 88 71-142 Chloroform ug/L 20 16.5 82 70-130 Chloromethane ug/L 20 16.0 80 40-140 J cis-1,2-Dichloroethene ug/L 20 17.1 85 70-130 cis-1,3-Dichloropropene ug/L 20 16.9 84 70-130 Dibromochloromethane ug/L 20 16.1 81 62-118 Dibromomethane ug/L 20 15.9 80 70-130 Dichlorodifluoromethane ug/L 20 17.9 89 47-150 Ethylbenzene ug/L 20 17.4 87 70-130 lodomethane ug/L 40 18.4 46 10-164 J lsopropylbenzene (Cumene) ug/L 20 16.4 82 70-130 m&p-Xylene ug/L 40 36.8 92 70-130 Methyl-tert-butyl ether ug/L 20 15.6 78 64-124 J Methylene Chloride ug/L 20 17.1 85 65-136 n-Butylbenzene ug/L 20 24.9 124 70-130 n-Propylbenzene ug/L 20 18.1 90 70-130 o-Xylene ug/L 20 17.5 88 70-130 p-Isopropyltoluene ug/L 20 17.1 85 70-130 sec-Butylbenzene ug/L 20 17.9 90 70-130 Styrene ug/L 20 15.7 78 70-130 tert-Butylbenzene ug/L 20 17.2 86 70-130 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/05/2019 06:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 35 aceAnalytical www pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456922 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE: 2855529 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers Tetrachloroethene ug/L 20 21.9 110 64-134 Toluene ug/L 20 25.3 126 70-130 J trans-1,2-Dichloroethene ug/L 20 16.3 82 68-127 trans-1,3-Dichloropropene ug/L 20 25.2 126 65-121 J(L1) Trichloroethene ug/L 20 15.6 78 70-130 Trichlorofluoromethane ug/L 20 18.0 90 65-135 Vinyl acetate ug/L 20 19.1 95 60-144 Vinyl chloride ug/L 20 15.7 78 68-131 Xylene (Total) ug/L 60 54.3 91 70-130 1,2-Dichloroethane-d4 (S) % 104 70-130 4-Bromofluorobenzene (S) % 104 70-130 Toluene-d8 (S) % 98 70-130 MATRIX SPIKE SAMPLE: 2855766 Parameter 35456929001 Spike MS MS % Rec Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 0.32 U 20 18.8 94 70-130 1,1,1-Trichloroethane ug/L 0.30 U 20 18.5 92 70-130 1,1,2,2-Tetrachloroethane ug/L 0.20 U 20 18.1 91 68-125 1,1,2-Trichloroethane ug/L 0.30 U 20 16.2 81 70-130 1,1-Dichloroethane ug/L 0.34 U 20 18.4 92 70-130 1,1-Dichloroethene ug/L 0.27 U 20 19.1 95 66-133 1,1-Dichloropropene ug/L 0.31 U 20 18.6 93 70-130 1,2,3-Trichlorobenzene ug/L 0.34 U 20 11.8 59 64-126 J(M1) 1,2,3-Trichloropropane ug/L 1.1 U 20 16.5 83 62-127 1,2,3-Trimethylbenzene ug/L 0.17 U 20 18.4 92 70-130 1,2,4-Trichlorobenzene ug/L 0.32 U 20 13.0 65 63-124 1,2,4-Trimethylbenzene ug/L 0.24 U 20 19.0 95 70-130 1,2-Dichlorobenzene ug/L 0.29 U 20 16.7 83 70-130 J 1,2-Dichloroethane ug/L 0.27 U 20 16.3 82 70-130 1,2-Dichloropropane ug/L 0.23 U 20 17.9 89 70-130 1,3,5-Trimethylbenzene ug/L 0.24 U 20 18.6 93 70-130 1,3-Dichlorobenzene ug/L 0.33 U 20 16.9 84 70-130 1,3-Dichloropropane ug/L 0.26 U 20 17.9 89 70-130 1,4-Dichlorobenzene ug/L 0.28 U 20 16.7 84 70-130 2,2-Dichloropropane ug/L 0.59 U 20 16.9 85 59-133 2-Butanone (MEK) ug/L 7.5 U 40 31.6 79 47-143 J 2-Chloroethylvinyl ether ug/L 1.4 U 20 1.4 U 0 41-140 J,J(M1) 2-Chlorotoluene ug/L 0.28 U 20 17.6 88 70-130 2-Hexanone ug/L 0.85 U 40 32.7 82 48-145 4-Chlorotoluene ug/L 0.22 U 20 17.9 89 70-130 4-Methyl-2-pentanone (MIBK) ug/L 0.32 U 40 31.9 80 57-132 Acetone ug/L 6.9 I 40 37.1 75 46-148 Acetonitrile ug/L 24.5 U 200 166 83 33-175 Benzene ug/L 0.30 U 20 17.8 89 70-130 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/05/2019 06:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 35 (eAna/YticaI wv; w. pacelabs.corn QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456922 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 MATRIX SPIKE SAMPLE: 2855766 Parameter 35456929001 Spike MS MS % Rec Units Result Conc. Result % Rec Limits Qualifiers Bromobenzene ug/L 0.21 U 20 18.9 94 70-130 Bromochloromethane ug/L 0.37 U 20 16.3 81 70-130 Bromodichloromethane ug/L 0.19 U 20 17.1 86 70-130 Bromoform ug/L 2.6 U 20 14.7 74 49-126 Bromomethane ug/L 4.0 U 20 4.0 U 16 10-165 J Carbon disulfide ug/L 0.45 U 20 17.0 84 60-141 J Carbon tetrachloride ug/L 1.1 U 20 17.8 89 63-126 Chlorobenzene ug/L 0.35 U 20 17.0 85 70-130 Chloroethane ug/L 3.7 U 20 21.2 106 71-142 Chloroform ug/L 0.32 U 20 17.6 88 70-130 Chloromethane ug/L 0.97 U 20 15.2 76 40-140 J cis-1,2-Dichloroethene ug/L 0.27 U 20 17.8 89 70-130 cis-1,3-Dichloropropene ug/L 0.17 U 20 16.2 81 70-130 Dibromochloromethane ug/L 0.45 U 20 15.8 79 62-118 Dibromomethane ug/L 0.68 U 20 16.4 82 70-130 Dichlorodifluoromethane ug/L 0.26 U 20 20.6 103 47-150 Ethylbenzene ug/L 0.30 U 20 18.1 91 70-130 lodomethane ug/L 9.3 U 40 13.1 32 10-164 J Isopropylbenzene (Cumene) ug/L 0.30 U 20 17.7 88 70-130 i&p-Xylene ug/L 2.1 U 40 38.5 95 70-130 iethyl-tert-butyl ether ug/L 2.4 20 17.6 76 64-124 Methylene Chloride ug/L 2.0 U 20 16.8 84 65-136 n-Butylbenzene ug/L 0.20 U 20 18.3 91 70-130 n-Propylbenzene ug/L 0.37 U 20 19.6 98 70-130 o-Xylene ug/L 0.27 U 20 18.5 92 70-130 p-Isopropyltoluene ug/L 0.31 U 20 18.1 90 70-130 sec-Butylbenzene ug/L 0.17 U 20 19.3 96 70-130 Styrene ug/L 0.26 U 20 15.7 79 70-130 tert-Butylbenzene ug/L 0.26 U 20 19.0 94 70-130 Tetrachloroethene ug/L 0.38 U 20 15.2 76 64-134 Toluene ug/L 0.41 I 20 18.3 90 70-130 J trans-1,2-Dichloroethene ug/L 0.23 U 20 17.2 86 68-127 trans-1,3-Dichloropropene ug/L 0.17 U 20 16.4 82 65-121 Trichloroethene ug/L 0.36 U 20 16.8 84 70-130 Trichlorofluoromethane ug/L 0.35 U 20 20.4 102 65-135 Vinyl acetate ug/L 0.19 U 20 17.0 85 60-144 Vinyl chloride ug/L 0.39 U 20 18.3 92 68-131 Xylene (Total) ug/L 2.1 U 60 57.1 95 70-130 1,2-Dichloroethane-d4 (S) % 104 70-130 4-Bromofluorobenzene (S) % 103 70-130 Toluene-d8 (S) % 98 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/05/2019 06:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 35 wv,wpacelabs.corn QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456922 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 SAMPLE DUPLICATE: 2855765 Parameter 35456922001 Dup Max Units Result Result RPD RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L 0.32 U 0.32 U 40 1,1,1-Trichloroethane ug/L 0.30 U 0.30 U 40 1,1,2,2-Tetrachloroethane ug/L 0.20 U 0.20 U 40 1,1,2-Trichloroethane ug/L 0.30 U 0.30 U 40 1,1-Dichloroethane ug/L 0.34 U 0.34 U 40 1,1-Dichloroethene ug/L 0.27 U 0.27 U 40 1,1-Dichloropropene ug/L 0.31 U 0.31 U 40 1,2,3-Trichlorobenzene ug/L 0.34 U 0.34 U 40 1,2,3-Trichloropropane ug/L 1.1 U 1.1 U 40 1,2,3-Trimethylbenzene ug/L 0.17 U 0.17 U 40 1,2,4-Trichlorobenzene ug/L 0.32 U 0.32 U 40 1,2,4-Trimethylbenzene ug/L 0.24 U 0.24 U 40 1,2-Dichlorobenzene ug/L 0.29 U 0.29 U 40 J 1,2-Dichloroethane ug/L 0.27 U 0.27 U 40 1,2-Dichloropropane ug/L 0.23 U 0.23 U 40 1,3,5-Trimethylbenzene ug/L 0.24 U 0.24 U 40 1,3-Dichlorobenzene ug/L 0.33 U 0.33 U 40 1,3-Dichloropropane ug/L 0.26 U 0.26 U 40 1,4-Dichlorobenzene ug/L 0.28 U 0.28 U 40 2,2-Dichloropropane ug/L 0.59 U 0.59 U 40 2-Butanone (MEK) ug/L 7.5 U 7.5 U 40 J 2-Chloroethylvinyl ether ug/L 1.4 U 1.4 U 40 J 2-Chlorotoluene ug/L 0.28 U 0.28 U 40 2-Hexanone ug/L 0.85 U 0.85 U 40 4-Chlorotoluene ug/L 0.22 U 0.22 U 40 4-Methyl-2-pentanone (MIBK) ug/L 0.32 U 0.32 U 40 Acetone ug/L 14.2 I 5.3 U 40 Acetonitrile ug/L 24.5 U 24.5 U 40 Benzene ug/L 0.30 U 0.30 U 40 Bromobenzene ug/L 0.21 U 0.21 U 40 Bromochloromethane ug/L 0.37 U 0.37 U 40 Bromodichloromethane ug/L 0.19 U 0.19 U 40 Bromoform ug/L 2.6 U 2.6 U 40 Bromomethane ug/L 4.0 U 4.0 U 40 J Carbon disulfide ug/L 0.45 U 0.45 U 40 J Carbon tetrachloride ug/L 1.1 U 1.1 U 40 Chlorobenzene ug/L 0.35 U 0.35 U 40 Chloroethane ug/L 3.7 U 3.7 U 40 Chloroform ug/L 0.32 U 0.32 U 40 Chloromethane ug/L 0.97 U 0.97 U 40 J cis-1,2-Dichloroethene ug/L 0.27 U 0.27 U 40 cis-1,3-Dichloropropene ug/L 0.17 U 0.17 U 40 Dibromochloromethane ug/L 0.45 U 0.45 U 40 Dibromomethane ug/L 0.68 U 0.68 U 40 Dichlorodifluoromethane ug/L 0.26 U 0.26 U 40 Ethylbenzene ug/L 0.30 U 0.30 U 40 lodomethane ug/L 9.3 U 9.3 U 40 J Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/05/2019 06:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 35 www..pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456922 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 SAMPLE DUPLICATE: 2855765 Parameter 35456922001 Dup Max Units Result Result RPD RPD Qualifiers Isopropylbenzene (Cumene) ug/L 0.30 U 0.30 U 40 m&p-Xylene ug/L 2.1 U 2.1 U 40 Methyl-tert-butyl ether ug/L 0.58 I 0.61 I 40 J Methylene Chloride ug/L 2.0 U 2.0 U 40 n-Butylbenzene ug/L 0.20 U 0.20 U 40 n-Propylbenzene ug/L 0.37 U 0.37 U 40 o-Xylene ug/L 0.27 U 0.27 U 40 p-Isopropyltoluene ug/L 0.31 U 0.31 U 40 sec-Butylbenzene ug/L 0.17 U 0.17 U 40 Styrene ug/L 0.26 U 0.26 U 40 tert-Butylbenzene ug/L 0.26 U 0.26 U 40 Tetrachloroethene ug/L 0.38 U 0.38 U 40 Toluene ug/L 0.33 U 0.33 U 40 J trans-1,2-Dichloroethene ug/L 0.23 U 0.23 U 40 trans-1,3-Dichloropropene ug/L 0.17 U 0.17 U 40 Trichloroethene ug/L 0.36 U 0.36 U 40 Trichlorofluoromethane ug/L 0.35 U 0.35 U 40 Vinyl acetate ug/L 0.19 U 0.19 U 40 Vinyl chloride ug/L 0.39 U 0.39 U 40 'ylene (Total) ug/L 2.1 U 2.1 U 40 ,2-Dichloroethane-d4 (S) % 105 104 1 40 4-Bromofluorobenzene (S) % 100 100 1 40 Toluene-d8 (S) % 98 99 1 40 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/05/2019 06:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 35 QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456922 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 526899 Analysis Method: EPA 8270 by SIM QC Batch Method: EPA 3510 Analysis Description: 8270 Water PAHLV by SIM MSSV Associated Lab Samples: 35456922001 METHOD BLANK: 2850416 Matrix: Water Associated Lab Samples: 35456922001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1-Methylnaphthalene ug/L 0.19 U 2.0 0.19 03/29/19 17:28 2-Methylnaphthalene ug/L 0.68 U 2.0 0.68 03/29/19 17:28 Acenaphthene ug/L 0.040 U 0.50 0.040 03/29/19 17:28 Acenaphthylene ug/L 0.030 U 0.50 0.030 03/29/19 17:28 Anthracene ug/L 0.043 U 0.50 0.043 03/29/19 17:28 Benzo(a)anthracene ug/L 0.055 U 0.10 0.055 03/29/19 17:28 Benzo(a)pyrene ug/L 0.12 U 0.20 0.12 03/29/19 17:28 Benzo(b)fluoranthene ug/L 0.027 U 0.10 0.027 03/29/19 17:28 Benzo(g,h,i)perylene ug/L 0.15 U 0.50 0.15 03/29/19 17:28 Benzo(k)fluoranthene ug/L 0.16 U 0.50 0.16 03/29/19 17:28 Chrysene ug/L 0.026 U 0.50 0.026 03/29/19 17:28 Dibenz(a,h)anthracene ug/L 0.13 U 0.15 0.13 03/29/19 17:28 Fluoranthene ug/L 0.018 U 0.50 0.018 03/29/19 17:28 Fluorene ug/L 0.088 U 0.50 0.088 03/29/19 17:28 Indeno(1,2,3-cd)pyrene ug/L 0.12 U 0.15 0.12 03/29/19 17:28 Naphthalene ug/L 0.29 U 2.0 0.29 03/29/19 17:28 Phenanthrene ug/L 0.16 U 0.50 0.16 03/29/19 17:28 Pyrene ug/L 0.032 U 0.50 0.032 03/29/19 17:28 2-Fluorobiphenyl (S) % 58 33-82 03/29/19 17:28 p-Terphenyl-d14 (S) % 75 49-104 03/29/19 17:28 LABORATORY CONTROL SAMPLE: 2850417 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1-Methylnaphthalene ug/L 5 2.6 52 40-96 2-Methylnaphthalene ug/L 5 2.6 52 40-94 Acenaphthene ug/L 5 2.6 51 42-96 Acenaphthylene ug/L 5 2.3 46 39-90 Anthracene ug/L 5 2.9 57 46-109 Benzo(a)anthracene ug/L 5 3.6 71 50-116 Benzo(a)pyrene ug/L 5 3.3 65 48-117 Benzo(b)fluoranthene ug/L 5 3.5 71 51-124 Benzo(g,h,i)perylene ug/L 5 3.5 70 47-121 Benzo(k)fluoranthene ug/L 5 3.6 71 50-125 Chrysene ug/L 5 3.7 73 53-122 Dibenz(a,h)anthracene ug/L 5 3.3 66 45-123 Fluoranthene ug/L 5 3.6 70 52-119 Fluorene ug/L 5 2.6 53 44-100 Indeno(1,2,3-cd)pyrene ug/L 5 3.3 67 46-121 Naphthalene ug/L 5 2.6 51 40-91 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/05/2019 06:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 35 ceAnalytical® wwwpacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456922 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE: 2850417 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phenanthrene ug/L 5 3.0 59 47-111 Pyrene ug/L 5 3.4 68 51-120 2-Fluorobiphenyl (S) % 56 33-82 p-Terphenyl-d14 (S) % 75 49-104 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2850992 2850993 MS MSD 35457042004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1-Methylnaphthalene ug/L 0.19 U 5 5 3.0 2.7 58 52 40-96 11 40 2-Methylnaphthalene ug/L 0.68 U 5 5 2.9 2.6 58 52 40-94 11 40 Acenaphthene ug/L 0.040 U 5 5 3.0 2.7 59 54 42-96 10 40 Acenaphthylene ug/L 0.030 U 5 5 2.8 2.6 55 51 39-90 7 40 Anthracene ug/L 0.043 U 5 5 3.4 3.3 68 65 46-109 4 40 Benzo(a)anthracene ug/L 0.055 U 5 5 3.7 3.6 74 71 50-116 3 40 Benzo(a)pyrene ug/L 0.12 U 5 5 3.5 3.4 69 67 48-117 3 40 Benzo(b)fluoranthene ug/L 0.027 U 5 5 3.4 3.3 68 67 51-124 2 40 Renzo(g,h,i)perylene ug/L 0.15 U 5 5 3.3 3.2 66 64 47-121 4 40 ?nzo(k)fluoranthene ug/L 0.16 U 5 5 3.5 3.3 69 66 50-125 4 40 .;hrysene ug/L 0.026 U 5 5 3.6 3.5 72 70 53-122 2 40 Dibenz(a,h)anthracene ug/L 0.13 U 5 5 3.1 3.0 63 61 45-123 3 40 Fluoranthene ug/L 0.018 U 5 5 3.7 3.5 73 70 52-119 4 40 Fluorene ug/L 0.088 U 5 5 3.1 2.9 62 57 44-100 8 40 Indeno(1,2,3-cd)pyrene ug/L 0.12 U 5 5 3.2 3.1 64 61 46-121 4 40 Naphthalene ug/L 0.29 U 5 5 2.9 2.7 53 48 40-91 9 40 Phenanthrene ug/L 0.16 U 5 5 3.2 3.1 64 62 47-111 4 40 Pyrene ug/L 0.032 U 5 5 3.6 3.4 71 68 51-120 5 40 2-Fluorobiphenyl (S) % 66 60 33-82 p-Terphenyl-d14 (S) % 76 73 49-104 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/05/2019 06:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 35 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456922 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 526900 Analysis Method: FL -PRO QC Batch Method: EPA 3510 Analysis Description: FL -PRO Water Low Volume Associated Lab Samples: 35456922001 METHOD BLANK: 2850418 Matrix: Water Associated Lab Samples: 35456922001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Petroleum Range Organics mg/L 0.80 U 1.0 0.80 03/29/19 23:37 N-Pentatriacontane (S) % 88 42-159 03/29/19 23:37 o-Terphenyl (S) % 85 66-139 03/29/19 23:37 LABORATORY CONTROL SAMPLE: 2850419 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Petroleum Range Organics mg/L N-Pentatriacontane (S) o-Terphenyl (S) 5 5.0 100 66-119 93 42-159 89 66-139 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2851010 2851011 MS MSD 35457129002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Petroleum Range Organics mg/L 0.76 U 5 4.7 3.9 4.7 66 86 65-123 18 20 N-Pentatriacontane (S) % 85 92 42-159 o-Terphenyl (S) % 77 89 66-139 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/05/2019 06:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 35 aceAnalytical wvnv.pacelabs.com QUALIFIERS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456922 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. U Compound was analyzed for but not detected. J The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. J The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have a low bias. J The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. J(L1) Estimated Value. Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. J(M1) Estimated Value. Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. c2 Acid preservation may not be appropriate for the analysis of 2-Chloroethylvinyl ether. Date: 04/05/2019 06:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 35 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456922 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID QC Batch Method Analytical QC Batch Analytical Method Batch 35456922001 MW-9 EPA 3510 526900 FL -PRO 35456922001 MW-9 EPA 3510 526899 EPA 8270 by SIM 35456922001 MW-9 EPA 8260 527630 Date: 04/05/2019 06:10 PM REPORT OF LABORATORY ANALYSIS 527131 527119 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 35 5(7 Pdx4r.f,1Ic?! Ili Ili inn WO#:35456922 est Document ds must be completed accurately. aecuon H Required Client Information: Section 8 - - — "-- Required Project Information: Invoice Imu,ua,w,,. Page : Of Company Report To .. _ •. ._ _, Attention Address Copy To. • - Company Name Address. Regulatory Agency Email i, Purchase Order #'. Pace Ouote Phone ,. _ , , _ I Fax ' Project Name'. Pace Project Manager State I Location Requested Due Date - , Project # - - Pace Profile # FL Requested Analysis Filtered (YIN) # 2 r— SAMPLE ID One Character per box. (A-Z, 0-9 I , -) Sample Ids must be unique WORD( cone Dmm,yt Walr:r DW Wale, W I Wan Wale, WW Pruduul P oo Wed W.Pv WP Mr AR omr•, of r,.,,,,„, 15 MATRIX CODE (see valid codes to left) SAMPLE TYPE (G=GRAB C=COMP) COLLECTED SAMPLE TEMP AT COLLECTION ,n Lu _ 0 0 O Preservatives 2 5"-- START ENO Unpreserved o 04 _ HNO3 U = x 2 Na2S203 0 a, 2 -tit -E 0 Analyses Test - - -' T !` - Residual Chlorine (Y/N) DATE TIME DATE TIME 1 2 3 4 5 6 7 8 9 10 11 12 ADDITIONAL COMMENTS RELINQUISHED BY AFFILTION DATE TIME ACCEPT 1 AFFILIATION DATE TIME SAMPLE CONDITIONS /1Y _.--y-z.--7, ,-/ sue_ /7.---' --,____ �'I ,~ 1' / .774s ITEMP mC Received on Ice (Y/N) SAMPLER NAME AND SIGNATURE o y `-' .-- � � � ' ' � ? PRINT Name of SAMPLER: ..�SIGNATUt2E of SAMPLER: DATE Signed: Page 21 of 35 fir:ailn.i/t Irrrrl Project # n Recei • t Form (SCUR) W©#:35456922 Project Manager: PM: CTR Client: • 1 1 r • I CLIENT: 36-EEG Due Date: 04/03/19 - I . JV Date . �1`4 1 I Time f%-�( _ c_. Cooler #1 Temp.'C "' • L (Visual) 00 (Correction Factor) (Actual) Se--- -- Cooler #2 Temp.'C (Visual) (Correction Factor) (Actual) — Ss-c 'eS r' _ ,_a_ ._ Cooler #3 Temp.'C (Visual) (Correction Factor) (Actual) _ Ss C Es c- :s _:_ _ ,:ass =_s ce..- Cooler #4 Temp.'C (Visual) (Correction Factor) (Actual) Sat-.: es :- c= __:: _ .._e_ _ a_ ..-_ Cooler #5 Temp.'C (Visual) (Correction Factor) (Actual) — Sa'-c es c- ze ..,a _-_::ess -xis . ,_ _ Cooler#6 Temp.`C (Visual) (Correction Factor) (Actual) Ss.-,c:es:- :a ___ ..:ess _s ce_. Date and Initials of person: Examining contents: La bel: Deliver: pH: 1150 Init.as r • Courier: — Fed Ex — UPS `- USPS — Client — Commercraiace Shipping Method: c!rst Ove'-,rghi nr,ot:;y Ov r•,r; t Standard Over, ght Grnu"d internat:o^a' oncr:ty Other Billing: Recipient Sender "h:rd Party Credit Card Otner Tracking # unknown Custody Seal on Cooler/Box Present: _Yes _.j+irl' Seals intact: — Yes Ice: Packing Material: —Buoble `.Trap ` Bubble Bags ._None —Other Samples shorted to lab (If Yes, complete) Shorted Date Comments: St?oned T!'re Al • r ue Dry None O:y, At rt- Chair of Custoriy P'ese^t Project # n Recei • t Form (SCUR) W©#:35456922 Project Manager: PM: CTR Client: • 1 1 r • I CLIENT: 36-EEG Due Date: 04/03/19 - I . JV Date . �1`4 1 I Time f%-�( _ c_. Cooler #1 Temp.'C "' • L (Visual) 00 (Correction Factor) (Actual) Se--- -- Cooler #2 Temp.'C (Visual) (Correction Factor) (Actual) — Ss-c 'eS r' _ ,_a_ ._ Cooler #3 Temp.'C (Visual) (Correction Factor) (Actual) _ Ss C Es c- :s _:_ _ ,:ass =_s ce..- Cooler #4 Temp.'C (Visual) (Correction Factor) (Actual) Sat-.: es :- c= __:: _ .._e_ _ a_ ..-_ Cooler #5 Temp.'C (Visual) (Correction Factor) (Actual) — Sa'-c es c- ze ..,a _-_::ess -xis . ,_ _ Cooler#6 Temp.`C (Visual) (Correction Factor) (Actual) Ss.-,c:es:- :a ___ ..:ess _s ce_. Date and Initials of person: Examining contents: La bel: Deliver: pH: 1150 Init.as r • Courier: — Fed Ex — UPS `- USPS — Client — Commercraiace Shipping Method: c!rst Ove'-,rghi nr,ot:;y Ov r•,r; t Standard Over, ght Grnu"d internat:o^a' oncr:ty Other Billing: Recipient Sender "h:rd Party Credit Card Otner Tracking # unknown Custody Seal on Cooler/Box Present: _Yes _.j+irl' Seals intact: — Yes Ice: Packing Material: —Buoble `.Trap ` Bubble Bags ._None —Other Samples shorted to lab (If Yes, complete) Shorted Date Comments: St?oned T!'re Al • r ue Dry None O:y, At rt- Chair of Custoriy P'ese^t ..Xs No N A Chain of Custody Fitted Out s No N .A Re:,nquished Signature & Sampler Name COC _Xs No N-.A Samples Arrived %vithrn Hold Time es . Now N A Rush TAT requested on COC Yes ....eto N/A Sufficient Volume ,,,,'C No NA Correct Containers Used Yes _ No N-A Containers Intact -" Yes No NA Sa-;: _ _ace _ -a::•• . C.. sa- . < .....:::e : .. _. .:_. Xes No NA a.-a's •-ee7 .1 ac ^ case::-ese:.: e : _:.ec .. - ��� .., .-.mac.:._ ;;• ,... _ _ _ Yes Yes // No M .A No rl<rA _:.... '...... - Headspace in VOA Vials? ( >6mmr Yes , io N A Trip Blank Present Yes to N A Client Notification/ Resolution: 'c. s CCntaC.ed Comments/ Resolution (use back for additional comments): Data T,Me Prol:;:;t t:anager Dare Page 22 of 35 A': aceAnalytical ° National Center for Testing & Innovation A\ALYT CAL RPDORT April 05, 2019 Pace Analytical - Pompano Beach, FL Sample Delivery Group: L1084538 Samples Received: 04/02/2019 Project Number: 35456922 Description: 2018-3057/Melreese Golf Course Site: 001 Report To: Christina Raschke 3610 Park Central Blvd N Pompano Beach, FL 33064 Entire Report Reviewed By: Nancy McLain Project Manager Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced. except in full. without written approval of the laboratory. Where applicable, sampling conducted by Pace National is performed per guidance provided in laboratory standard operating procedures: 060302, 060303, and 060304. Mount Juliet, TN 37122 615-758-5858 800-767-5859 TABLE OF CONTENTS C�.r..!i LAB 'i:. _loN\`:'I" Cp: Cover Page Tc: Table of Contents 2 Ss: Sample Summary 3 Cn: Case Narrative 4 Sr: Sample Results 5 MW-9 L1084538-01 5 Qc: Quality Control Summary 6 Chlorinated Acid Herbicides (GC) by Method 8151 6 OP Pesticides by Method 8141 7 GI: Glossary of Terms 10 Al: Accreditations & Locations 11 Sc: Sample Chain of Custody 12 Cn b QC GI Al ACCOUNT: Pace Analytical - Pompano Beach, FL Page 24 of 35 PROJECT: SDG: DATE/TIME: PAGE: 35456922 L1084538 04/05/1913:59 2 of 13 SAMPLE SUMMARY ONE LAB. NATIONWIDE. MW-9 L1084538-01 GW Collected by Collected date/time Received date/time 03/26/1915:02 04/02119 08:45 d Chlorinated Acid Herbicides (GC) by Method 8151 OP Pesticides by Method 8141 E; :=o Dilution Preparation Analysis Analyst Location date/time date/time WG1259127 1 04/02/1913:17 04/04/19 21:17 KLM Mt. Juliet, TN WG1259403 1 04/02/19 19:22 04/04/1916:13 HMH Mt. Juliet, TN SS 4 Cn 5 Sr 6 Qc GI AlV ACCOUNT: Pace Analytical - Pompano Beach, FL Page 25 of 35 PROJECT: SDG: DATE/TIME: PAGE: 35456922 L1084538 04/05/1913:59 3 of 13 CASE NARRATIVE ONE LAB. NATIONWIDE. A' All sample aliquots were received at the correct temperature, in the proper containers, with the appropriate preservatives, and within method specified holding times, unless qualified or notated within the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data. Nancy McLain Project Manager Ss 6 Qc GI ACCOUNT: Pace Analytical - Pompano Beach, FL Page 26 of 35 PROJECT: SDG: DATE/TIME: PAGE: 35456922 L1084538 04/05/1913:59 4 of 13 MW-9 Collected date/time: 03/26/19 15:02 SAMPLE RESULTS - 01 L1084538 ONE LAB. NATIONWIDE. SA Chlorinated Acid Herbicides (GC) by Method 8151 Result Qualifier MDL RDL Dilution Analysis Batch e ug/I ug/I ug/I date/time .44-0 0.744 U 0.744 2.00 1 04/04/2019 21:17 WG1259127 Dalapon 1.04 U 1.04 2.00 1 04/04/2019 21:17 WG1259127 2,4-DB 0.775 U 0.775 4.00 1 04/04/2019 21:17 WG1259127 Dicamba 0.813 U 0.813 2.00 1 04/04/2019 21:17 WG1259127 Dichloroprop 0.778 U 0.778 2.00 1 04/04/2019 21:17 WG1259127 Dinoseb 0.795 U 0.795 2.00 1 04/04/2019 21:17 WG1259127 MCPA 13.1 U 13.1 200 1 04/04/2019 21:17 WG1259127 MCPP 7.15 J U 7.15 200 1 04/04/2019 21:17 WG1259127 2,4,5-T 0.843 U 0.843 2.00 1 04/04/2019 21:17 WG1259127 2,4,5-TP (Silvex) 0.845 U 0.845 2.00 1 04/04/2019 21:17 WG1259127 (S) 2,4-Dichlorophenyl Acetic 182 J 14.0-158 04/04/2019 21.17 WG1259127 Acid - OP Pesticides by Method 8141 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date/time Azinphos-Methyl 0.348 U 0.348 1.00 1 04/04/2019 16:13 WG1259403 Bolstar (Sulprofos) 0.205 U 0.205 1.00 1 04/04/201916:13 WG1259403 Chlorpyrifos 0.245 U 0.245 1.00 1 04/04/201916:13 WG1259403 Coumaphos 0.277 U 0.277 1.00 1 04/04/201916:13 WG1259403 Demeton,-0 and -S 0.341 J U 0.341 2.00 1 04/04/201916:13 WG1259403 Diazinon 0.377 U 0.377 1.00 1 04/04/201916:13 WG1259403 Dichlorvos 0.212 U 0.212 2.00 1 04/04/201916:13 WG1259403 Dimethoate 0.105 U 0.105 1.00 1 04/04/201916:13 WG1259403 Disulfoton 0.277 U 0.277 1.00 1 04/04/201916:13 WG1259403 0.261 U 0.261 1.00 1 04/04/201916:13 WG1259403 ,rop 0.354 U 0.354 1.00 1 04/04/201916:13 WG1259403 Ethyl Parathion 0.292 U 0.292 1.00 1 04/04/201916:13 WG1259403 Fensulfothion 0.130 U 0.130 1.00 1 04/04/201916:13 WG1259403 Fenthion 0.266 U 0.266 1.00 1 04/04/201916:13 WG1259403 Malathion 0.173 U 0.173 1.00 1 04/04/201916:13 WG1259403 Merphos 0.267 U 0.267 2.00 1 04/04/201916:13 WG1259403 Methyl parathion 0.257 U 0.257 1.00 1 04/04/201916:13 WG1259403 Mevinphos 0.118 U 0.118 1.00 1 04/04/201916:13 WG1259403 Naled 0.289 U 0.289 1.00 1 04/04/201916:13 WG1259403 Phorate 0.282 U 0.282 1.00 1 04/04/201916:13 WG1259403 Ronne! 0.252 U 0.252 1.00 1 04/04/2019 16:13 WG1259403 Stirophos 0.226 U 0.226 1.00 1 04/04/201916:13 WG1259403 Sulfotep 0.202 U 0.202 1.00 1 04/04/201916:13 WG1259403 TEPP 9.74 U 9.74 20.0 1 04/04/2019 16:13 WG1259403 Tokuthion (Prothothiofos) 0.254 U 0.254 1.00 1 04/04/201916:13 WG1259403 Trichloronate 0.213 U 0.213 1.00 1 04/04/201916:13 WG1259403 (S) Triphenyl Phosphate 82.2 42.0-129 04/04/201916:13 WG1259403 Cp 2 Tc Ss 4 Cn GI Al ACCOUNT: Pace Analytical - Pompano Beach, FL Page 27 of 35 PROJECT: SDG: DATE/TIME: PAGE: 35456922 L1084538 04/05/1913:59 5 of 13 WG1259127 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. Chlorinated Acid Herbicides (GC) by Method 8151 L1084538-01 Method Blank (MB) (MB) R3398822-1 04/04/19 18:54 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I 2,4-0 0.744 U 0.744 2.00 Dalapon 1.04 U 1.04 2.00 2,4-DB 0.775 U 0.775 4.00 Dicamba 0.813 U 0.813 2.00 Dichloroprop 0.778 U 0.778 2.00 Dinoseb 0.795 U 0.795 2.00 MCPA 13.1 U 13.1 200 MCPP 7.15 U 7.15 200 2,4,5-1' 0.843 U 0.843 2.00 2,4,5-TP (Silvex) 0.845 U 0.845 2.00 (S) 2,4-Dichlorophenyl Acetic 82.0 14.0-158 Acid Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3398822-2 04/04/19 19:08 • (LCSD) R3398822-3 04/04/19 19:23 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I % % % % % 2,4-0 5.00 3.93 3.93 78.6 78.6 50.0-120 0.000 20 Dalapon 5.00 4.85 4.81 97.0 96.2 32.0-120 0.828 20 2,4-DB 5.00 4.49 4.43 89.8 88.6 53.0-140 1.35 20 Dicamba 5.00 3.89 3.93 77.8 78.6 51.0-120 1.02 20 Dichloroprop 5.00 4.61 4.77 92.2 95.4 55.0-127 3.41 20 Dinoseb 5.00 3.40 3.34 68.0 66.8 36.0-134 1.78 20 MCPA 50.0 29.8 31.1 59.6 62.2 10.0-160 4.27 40 MCPP 50.0 94.0 82.1 188 164 10.0-160 J J 13.5 23 2,4,5-T 5.00 4.35 4.28 87.0 85.6 54.0-120 1.62 20 2,4,5-TP (Silvex) 5.00 3.52 3.52 70.4 70.4 50.0-125 0.000 20 (S) 2,4-Dichlorophenyl Acetic 80.6 79.2 14.0-158 Acid ACCOUNT: Pace Analytical - Pompano Beach, FL Cp 3 SS 4 Cn Qc GI ^AI Jr le 28 of 35 PROJECT: SDG: DATE/TIME: AGE: 35456922 L1084538 04/05/1913:59 6 of 13 WG12F-103 QUALITY CON'- -'OL SUMMARY OP PesticiL y Method 8141 L1 01 ONE LAB. NA-- NWIDE.410 Method Blank (MB) (MB) R3398830-1 04/04/19 13:03 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I Azinphos-Methyl 0.348 U 0.348 1.00 Bolstar (Sulprofos) 0.205 U 0.205 1.00 Chlorpyrifos 0.245 U 0.245 1.00 Coumaphos 0.277 U 0.277 1.00 Demeton,-0 and -5 0.341 U 0.341 2.00 Diazinon 0.377 U 0.377 1.00 Dichlorvos 0.212 U 0.212 2.00 Dimethoate 0.105 U 0.105 1.00 Disulfoton 0.277 U 0.277 1.00 EPN 0.261 U 0.261 1.00 Ethoprop 0.354 U 0.354 1,00 Ethyl Parathion 0.292 U 0.292 1.00 Fensulfothion 0.130 U 0.130 1.00 Fenthion 0.266 U 0.266 1.00 Malathion 0.173 U 0.173 1.00 Merphos 0.267 U 0.267 2.00 Methyl parathion 0.257 U 0.257 1.00 Mevinphos 0.118 U 0.118 1.00 Naled 0.289 U 0.289 1.00 Phorate 0.282 U 0.282 1.00 Ronnel 0.252 U 0.252 1.00 Stirophos 0.226 U 0.226 1.00 Sulfotep 0.202 U 0.202 1.00 TEPP 9.74 U 9.74 20.0 Tokuthion (Prothothiofos) 0.254 U 0.254 1.00 Trichloronate 0.213 U 0.213 1.00 (S) Triphenyl Phosphate 83.6 42.0-129 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3398830-2 04/04/19 14:07 • (LCSD) R3398830-3 04/04/19 14:38 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I % % % % % Azinphos-Methyl 5.00 5.01 4.00 100 80.0 43.0-142 J 22.4 20 Bolster (Sulprofos) 5.00 4.74 3.76 94.8 75.2 47.0-128 J 23.1 20 Chlorpyrifos 5.00 4.80 3.78 96.0 75.6 50.0-126 J 23.8 20 Coumaphos 5.00 5.41 4.27 108 85.4 37.0-137 J 23.6 20 Demeton,-0 and -S 2.50 2.07 1.65 82.8 66.0 22.0-150 22.6 24 Diazinon 5.00 4.78 3.74 95.6 74.8 54.0-130 J 24.4 20 Cp 3Ss aCn IsSr] 6 Qc 7GI Al Page 29 of 35 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Pompano Beach, FL 35456922 L1084538 04/05/1913:59 7 of 13 WG1259403 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. 40 OP Pesticides by Method 8141 L1084538-01 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3398830-2 04/04/19 14:07 • (LCSD) R3398830-3 04/04/19 14:38 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I % % % % % Dichlorvos 5.00 4.76 3.65 95.2 73.0 43.0-135 J 26.4 24 Dimethoate 5.00 2.85 2.56 57.0 51.2 27.0-120 10.7 27 Disulfoton 5.00 4.34 3.38 86.8 67.6 44.0-136 J 24.9 21 EPN 5.00 5.64 4.39 113 87.8 31.0-143 J 24.9 21 Ethoprop 5.00 4.57 3.52 91.4 70.4 52.0-130 J 26.0 20 Ethyl Parathion 5.00 4.77 3.74 95.4 74.8 42.0-134 J 24.2 20 Fensulfothion 5.00 4.78 4.13 95.6 82.6 42.0-137 14.6 20 Fenthion 5.00 4.47 3.51 89.4 70.2 53.0-133 J 24.1 20 Malathion 5.00 4.50 3.53 90.0 70.6 47.0-121 J 24.2 20 Merphos 5.00 3.82 2.98 76.4 59.6 14.0-123 24.7 25 Methyl parathion 5.00 4.71 3.67 94.2 73.4 43.0-135 J 24.8 20 Mevinphos 5.00 4.02 3.28 80.4 65.6 49.0-123 20.3 23 Naled 5.00 4.59 3.49 91.8 69.8 25.0-126 J 27.2 26 Phorate 5.00 4.04 3.10 80.8 62.0 44,0-129 J 26.3 20 Ronnel 5.00 4.58 3.55 91.6 71.0 51.0-125 J 25.3 20 Stirophos 5.00 4.98 3.86 99.6 77.2 53.0-125 J 25.3 20 Sulfotep 5.00 4.71 3.64 94.2 72.8 40.0-140 J 25.6 22 TEPP 50.0 19.0 26.8 38.0 53.6 18.0-122 J 34.1 32 Tokuthion (Prothothiofos) 5.00 4.79 3.78 95.8 75.6 50.0-128 J 23.6 20 Trichloronate 5.00 4.41 3.60 88.2 72.0 47.0-130 20.2 21 (S) Tnphenyl Phosphate 106 79.4 42.0-129 L1084538-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1084538-01 04/04/19 16:13 • (MS) R3398830-4 04/04/19 16:45 • (MSD) R3398830-5 04/0 4/19 17:17 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I ug/I % % % % % Azinphos-Methyl 5.00 0.348 4.83 4.56 96.6 91.2 1 29.0-157 5.75 20 Bolstar (Sulprofos) 5.00 0.205 4.68 4.41 93.6 88.2 1 37.0-138 5.94 20 Chlorpyrifos 5.00 0.245 4.67 4.52 93.4 90.4 1 42.0-131 3.26 20 Coumaphos 5.00 0.277 5.31 4.93 106 98.6 1 31.0-150 7.42 20 Demeton,-0 and -S 2.50 0.341 4.40 4.25 176 170 1 30.0-152 J P J 3.47 20 Diazinon 5.00 0.377 4.61 4.55 92.2 91.0 1 47.0-134 1.31 20 Dichlorvos 5.00 0.212 4.58 4.66 91.6 93.2 1 39.0-140 1.73 22 Dimethoate 5.00 0.105 3.69 3.49 73.8 69.8 1 17.0-129 5.57 20 Disulfoton 5.00 0.277 4.32 4.53 86.4 90.6 1 42.0-131 4.75 21 EPN 5.00 0.261 5.39 5.09 108 102 1 17.0-155 5.73 20 Ethoprop 5.00 0.354 4.46 4.38 89.2 87.6 1 46.0-133 1.81 20 Ethyl Parathion 5.00 0.292 4.69 4.50 93.8 90.0 1 30.0-138 4.13 20 ACCOUNT: Pace Analytical - Pompano Beach, FL Cp 3 SS 4 Cn 7GI Al •ge30of35 PROJECT: SDG: DATE/TIME: AGE: 35456922 L1084538 04/05/1913:59 8 of 13 WG12r 103 QUALITY CON' -'OL SUMMARY OP Pesticic. y Method 8141 d-01 ONE LAB. N �NWIDE. L1084538-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1084538-01 04/04/19 16:13 • (MS) R3398330-4 04/04/19 16:45 • (MSD) R3398830-5 04/04/19 17:17 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I ug/I % % o% % % Fensulfothion 5.00 0.130 5.48 5.24 110 105 1 36.0-145 4.48 20 Fenthion 5.00 0.266 4.29 4.19 85.8 83.8 1 46.0-140 2.36 20 Malathion 5.00 0.173 4.19 4.16 83.8 83.2 1 39.0-126 0.719 20 Merphos 5.00 0.267 3.64 3.65 72.8 73.0 1 10.0-120 0.274 27 Methyl parathion 5.00 0.257 4.67 4.60 93.4 92.0 1 28.0-142 1.51 20 Mevinphos 5.00 0.118 4.43 4.33 88.6 86.6 1 38.0-134 2.28 20 Naled 5.00 0.289 4.64 4.65 92.8 93.0 1 14.0-130 0.215 20 Phorate 5.00 0.282 3.89 3.87 77.8 77.4 1 38.0-134 0.515 20 Ronnel 5.00 0.252 4.42 4.29 88.4 85.8 1 42.0-131 2.99 20 Stirophos 5.00 0.226 4.89 4.63 97.8 92.6 1 33.0-143 5.46 20 Sulfotep 5.00 0.202 4.56 4.55 91.2 91.0 1 34.0-143 0.220 20 TEPP 50.0 9.74 44.4 41.8 88.8 83.6 1 38.0-120 6.03 25 Tokuthion (Prothothiofos) 5.00 0.254 4.66 4.54 93.2 90.8 1 35.0-140 2.61 24 Trichloronate 5.00 0.213 4.39 4.30 87.8 86.0 1 41.0-133 2.07 20 (S) Triphenyl Phosphate 98.0 93.8 42.0-129 ACCOUNT: Pace Analytical - Pompano Beach, FL Cp Tc 3S5 4 Cn Sr Qc GI Al Page 31 of 35 PROJECT: SDG: DATE/TIME: PAGE: 35456922 L1084538 04/05/1913:59 9 of 13 GLOSSARY OF TERMS ONE LAB. NATIONWIDE. JO Guide to Reading and Understanding Your Laboratory Report The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and if you have additional questions please contact your project representative. Abbreviations and Definitions MDL RDL Rec. RPD SDG (S) Analyte Dilution Limits Original Sample Qualifier Result Uncertainty (Radiochemistry) Case Narrative (Cn) Quality Control Summary (Qc) Sample Chain of Custody (Sc) Sample Results (Sr) Sample Summary (Ss) Qualifier Method Detection Limit. Reported Detection Limit. Recovery. Relative Percent Difference. Sample Delivery Group. Surrogate (Surrogate Standard) - Analyses added to every blank, sample, Laboratory Control Sample/Duplicate and Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be detected in all environmental media. The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes reported. If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor. These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or duplicated within these ranges. The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control sample. The Original Sample may not be included within the reported SDG. This column provides a letter and/or number designation that corresponds to additional information concerning the result reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable. The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL" (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte. Confidence level of 2 sigma. A brief discussion about the included sample results, including a discussion of any non -conformances to protocol observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report. This section of the report includes the results of the laboratory quality control analyses required by procedure or analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material. This is the document created in the field when your samples were initially collected. This is used to verify the time and date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the samples from the time of collection until delivery to the laboratory for analysis. This section of your report will provide the results of all testing performed on your samples. These results are provided by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for each sample will provide the name and method number for the analysis reported. This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and times of preparation and/or analysis. Description J P U The value is outside laboratory established criteria. RPD between the primary and confirmatory analysis exceeded 40%. Indicates the compound was analyzed for but not detected above the method detection limit. SS 4 Cn s Sr 6 Qc GI a Al ACCOUNT: PROJECT: SDG: Pace Analytical - Pompano Beach, FL 35456922 L1084538 DATE/TIME: 04/05/1913:59 Page 32 of 35 PAGE: 10 of 13 ACCREDITATIONS & LOCATIONS ONE LAB. NATIONWIDE. Pace National is the only environmental laboratory accredited/certified to support your work nationwide from one location. One phone call, one point of contact, one laboratory. No other lab is as accessible or prepared to handle your needs throughout the country. our capacity and capability from our single location laboratory is comparable to the collective totals of the network laboratories in our industry. The most significant benefit to our one location design is the design of our laboratory campus. The model is conducive to accelerated productivity, decreasing turn -around time, and preventing cross contamination, thus protecting sample integrity. Our focus on premium quality and prompt service allows us to be YOUR LAB OF CHOICE. Not all certifications held by the laboratory are applicable to the results reported in the attached report. Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace National. State Accreditations Alabama 40660 Nebraska NE-OS-15-05 Alaska 17-026 Nevada TN-03-2002-34 Arizona A20612 New Hampshire 2975 Arkansas 88-0469 New Jersey—NELAP TN002 California 2932 New Mexico' n/a Colorado TN00003 New York 11742 Connecticut PH-0197 North Carolina Env375 Honda E87487 North Carolina' DW21704 Georgia NELAP North Carolina' 41 Georgia' 923 North Dakota R-140 Idaho TN00003 Ohio—VAP CL0069 Illinois 200008 Oklahoma 9915 Indiana C-TN-01 Oregon TN200002 Iowa 364 Pennsylvania 68-02979 Kansas E-10277 Rhode Island LA000356 Kentucky's 90010 South Carolina 84004 Kentucky 3 16 South Dakota n/a Louisiana A130792 Tennessee' ° 2006 Louisiana' LA180010 Texas T104704245-18-15 Maine TN0002 Texas 5 LAB0152 Maryland 324 Utah TN00003 Massachusetts M-TN003 Vermont VT2006 Michigan 9958 Virginia 460132 Minnesota 047-999-395 Washington C847 Mississippi TN00003 West Virginia 233 Missouri 340 Wisconsin 9980939910 Montana CERT0086 Wyoming A2LA Third Party Federal Accreditations A2LA — ISO 17025 1461.01 AIHA-LAP,LLC EMLAP 100789 A2LA — ISO 17025 5 1461.02 DOD 1461.01 Canada 1461.01 USDA P330-15-00234 EPA—Crypto TN00003 Drinking Water z Underground Storage Tanks ' Aquatic Toxicity " Chemical/Microbiological 5 Mold 6 Wastewater n/a Accreditation not applicable Our Locations Pace National has sixty-four client support centers that provide sample pickup and/or the delivery of sampling supplies. If you would like assistance from one of our support offices, please contact our main office. Pace National performs all testing at our central laboratory. WA CA OR AK MT VVY CO' TA rI NM >o ND SD KS 1t ME Cn s Sr Qc GI 8 Al Sc ACCOUNT: Pace Analytical - Pompano Beach, FL PROJECT: 35456922 SDG: L1084538 DATE/TIME: 04/05/19 13:59 Page 33 of 35 PAGE: 11 of 13 Chain of Custody Workorder: 35456922 Workorder Name: Christina Raschke Pace Analytical South Florida 3610 Park Central Blvd N Pompano Beach, FL 33064 Phone (954)582-4300 Email: christina.raschke@pacelabs.com State of Sample Origin: FL M W-9 2 Collect 3/26/2019 15:02 2018-3057/Melreese Golf Course 0.f1-,J 35456922001 Water P.O. f35io Eat Results Requested By: 4/3/2019 r Jo aceAnalytical wwwpacektbacom L106-153 LAB USE ONLY 3 4 111111111111111111111111U---- Transfers Released By Date/Time Received By Date/Time °`trii/t7 /' (;) 2 3 Cooler Temperature on Receipt / °C Custody Sear Y)or N egl0zllk Received on Ice (Y or Samples Intact or N Monday. April 01. 2019 6:40.33 PM FMT-ALL-C-002rev.00 24March2009 Page 1 of 1 �34of35 Pace Analytical National Center for Testing & Innovation Cooler Receipt Form (;licnt: VA csrisL spc#: 1.10 n Cooler Received/Opened On: 4/4) L-- / 19 Temperature: ' 0 Received By: Patrick Nshifirungli Signature: Receipt Check List NP Ye2 No COC Seal Present / Intact? COC Signed / Accurate? Bottles arrive intact? Correct bottles used? Sufficient volume sent? If Applicable VOA Zero headspace? Preservation Correct / Checked? Page 35 of 35 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 April 12, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456928 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 27, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry. EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 19 aceAnalytical www.pacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456928 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35456928001 MW-3 Water 03/26/19 12:14 03/27/19 17:15 35456928002 MW-4 Water 03/26/19 13:30 03/27/19 17:15 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 19 °2eAna�yticaI WO#:35456928 rtical Request Document Section A Section B 1111 I Ell III 1111 II I ill 'JT. All relevant fields must be completed accurately. Required Client Information: Required Project II 35456928 Company. EERG Environmental Services, LLC Report To- Page : Of Address. PMichae, . _IIII, Attention: 5751 Miami Lakes Drive Miami Lakes, FL Copy To: Company Name 33014 Email. - Address Regulatory Agency mvanryca eeandg com Phone Purchase Order #: Pace Quote: (305)374.8300 Fax Requested Project Name: Melreese Golf Course Pace.Project Manager christina.raschke acelabs,com, @P State / Location Due Date. , _ Pro eCt #: 2018-3057 ^ace Profile # FL Requested Analysis Filtered ;Y/N) MATRIX CODE MATRIX CODE (see valid codes to left) ISAMPLE TYPE (G=GRAB C=COtdP) COLLECTED SAMPLE TEMP AT COLLECTION p OF CONTAINERS Preservatives Z Drinkine Watm DW Water WT Waste Water WVV SAMPLE ID Product P somsoim sL Oil OL START END Unpreserved I NaOH Na2S203 1 Analyses Test I PAH SIM 8260 VOC TRPH FL -PRO 8290 Dioxin & Furans OC Pesticides 8081 OP Pesticides 8141 8151 Herbicides 6010-Ba, Cd, Cr, Se, Ag 7470 Hg Residual Chlorine (Y/N) I Le F One Character per box. WIP.. WP (A-Z, 0-9 / , -) nor AR Sample Ids must be unique myotha Ts DATE TIME O = x = — Z DATE TIME O 1 2 ®�-- : . IIII ... ............ 3 ..----......... I..II...I... 4 ..----......... ■■II■II■I■II 5 II�■�■�__II.IIIIIII I.■.I■■IIII■ 6UII■.II.I. ■III..■I.I■ ..----.. IIIII.I .......III.. 89 .,----.■ IIII... ■II■.I■I■■II 10 11 12 ADDITIONAL COMMENTS - RELINQUISHED BY / AFFILIATION DATE .. TIME .ACCEPTED BY / ILIA N DATE : • TIME SAMPLE CONDITIONS `<< 322 3- , 5 (-) r SAMPLER NAME AND SIGNATURE .. ' ITEMP in C Received on Ice (Y/N) usto y Sealed Cooler (Y/N) Samples Intact (Y/N) PRINT Name of SAMPLER: SIGNATURE of SAMPLER:. ' DATE Signed: 0 (L CO d Billing: Tracking # J -PuceAnaI} tiCa/ .... .. ., , ocunent Name Sample Concit!on Upon Receipt Form Document kevised May 30. 2018 Document No F-FL-C-007 rev 13 Issuing Authority Pace Florida Quality Office WO# : 35456928 Project 1 PM: CTR Project Manager CLIENT : 36-EEG Client: Thermometer Used Dat Stale of On in - Cooler #1 Temp.'C (Visual) V• 0 (Correction Factor) • (Actual) Cooler#2 Temp.°C - (Visual) (Correction Factor) (Actual) Cooler #3 Temp.'C (Visual) (Correction Factor) (Actual) Cooler#4 Temp.'C (Visual) (Correction Factor) (Actual) Cooler #5 Temp.'C (Visual) (Correction Factor) (Actual) Cooler #6 Temp.'C (Visual) (Correction Factor) (Actual) Courier: C Fed Ex UPS 11 USPS — Client L Commercial Pace Shipping Method: _ First Overnight _ Priority Overnight Other _ Recipient _ Sender Due Date: 04/08/19 Time Date and Initials of person: Examining contents: Label: Deliver: pH: pro ectyall containers verified to 56 "C Initials. hir L Samples on ice. cooling process nas begun L Samples on ice, coohng process has beoun E Samples on ice, coohng process has beoun L Samples on ice, cooling process has begun L Samples on ice, coohng process has begun L Samples on ice, coohng process has beoun L Other _ Standard Overnight E Ground _ International Priority = Third Party - Credit Card /_ unknov+n Custody Seal on Cooler/Box Present: _Yes Seals intact: Yes ;.moo Ice: Packing Material: EBubble Wrap ❑ Bubble Bags None Other Samples shorted to lab (If Yes, complete) Shorted Date IrUE Comments: Shorted Time / • t ue Dry None Qty AO' Chain of Custody Present .?Yes- _ No EN/A Chain of Custody Filled Oul s E No EN/A Relinquished Signature & Sampler Name COC es _ _ No '=N/A Samples Arnved within Hold Time — es E. No -N/A Rush TAT requested on COC =Yes .fNow CN/A Sufficient Volume 9.1. = No =N/A Correct Containers Used _Yeess 'I No CN/A Containers Intact _Yes = No =N/A Sample Labels match COC (sample IDs & date time of collection) Xs = No EN/A All containers needing acid/case preservation have been _ checked Yes - No ,ralA All Containers needing preservation are found to be in compliance_ with EPA recommendation =Yes _ No /A Exceptions VOA, ColiforT. TOC O&G Careamates Preservation Information Preservative Lot #/Trace # Date Time._ Initials Headspace in VOA Vials? (>6mm). EYes _ No 7/A Trip Blank Present Yes = No, 7N/A Client Notification/ Resolution: Person Contacted Comments/ Resolution (use back for additional comments): Date/Time. Project Manager Review Date 4 of 19 (/!I2' Analyt www.pacelabacom www.pacelabs.com Report Prepared for: Christina Raschke PASI Florida 3610 Park Central Blvd N Pompano Beach FL 33064 REPORT OF LABORATORY ANALYSIS FOR PCDD/PCDF Report Prepared Date: April 12, 2019 Report No 10468853_8290FCDFR Pace Analytical Services, LLC. 1700 Elm Street Minneapolis, MN 55414 Phone: 612.607.1700 Fax: 612.607.6444 Report Information: Pace Project #: 10468853 Sample Receipt Date: 03/29/2019 Client Project #: 35456928 Client Sub PO #: N/A State Cert #: E87605 Invoicing & Reporting Options: The report provided has been invoiced as a Level 2 PCDD/PCDF Report. If an upgrade of this report package is requested, an additional charge may be applied. Please review the attached invoice for accuracy and forward any questions to Nathan Boberg, your Pace Project Manager. This report has been reviewed by: April 12, 2019 Nathan Boberg, Project Manager 612-360-0728 (612) 607-6444 (fax) nathan.boberg@pacelabs.com Report of Laboratory Analysis Th isreportshouldn otbereproduced,exceptinfull. withoutthewrittenconsentofPaceAnalyticalServices,l nc. Theresultsrelateonlytothesamplesincludedinthisreport. Page 5 of 19 Page 1 of 15 a ceAnalytical, Pace Analytical Services, LLC. 1700 Elm Street Minneapolis, MN 55414 Phone: 612.607.1700 Fax: 612.607.6444 DISCUSSION This report presents the results from the analyses performed on two samples submitted by a representative of Pace Analytical Services, LLC. The samples were analyzed for the presence or absence of polychlorodibenzo-p-dioxins (PCDDs) and polychlorodibenzofurans (PCDFs) using a modified version of USEPA Method 8290. The reporting limits were based on signal-to-noise measurements. Estimated Maximum Possible Concentration (EMPC) values were treated as positives in the toxic equivalence calculations. Per request, estimated detection limit (EDL) values were provided and flagged "U" where the target analytes were not detected. The recoveries of the isotopically -labeled PCDD/PCDF internal standards in the sample extracts ranged from 53-85%. All of the labeled internal standard recoveries obtained for this project were within the 40-135% target range specified in Method 8290. Also, since the quantification of the native 2,3,7,8-substituted congeners was based on isotope dilution, the data were automatically corrected for recovery and accurate values were obtained. In some cases, interfering substances impacted the determinations of PCDD or PCDF congeners; the affected values were flagged "I" where incorrect isotope ratios were obtained or "P" where polychlorinated diphenyl ethers were present. Concentrations below the calibration range were flagged "J" and should be regarded as estimates. A laboratory method blank was prepared and analyzed with the sample batch as part of our routine quality control procedures. The results show that PCDDs and PCDFs were not detected. These results indicate that the sample preparation procedures did not significantly impact the results of the field sample determinations. Laboratory spike samples were also prepared with the sample batch using clean reference matrix that had been fortified with native standard materials. The results show that the spiked native compounds were recovered at 111-140% with relative percent differences of 0.8-6.7%. The recovery values obtained for 2,3,7,8-TCDD, 1,2,3,6,7,8-HxCDD and 1,2,3,7,8,9-HxCDD in the laboratory spike and/or laboratory spike duplicate were above the 70-130% target range for the method, flagged "R" on the results tables, and may indicate high biases for these congeners in these determinations. However, since TCDD and HxCDD isomers were not detected in the field samples, the reported results were not impacted by these deviations. Matrix spikes were not prepared with the sample batch. The response obtained for the labeled OCDD in calibration standard analysis U190405A_17 was outside the target range. As specified in the method, the average of the daily response factors for this compound was used in the calculations for the samples from this runshift. The affected values were flagged "Y" on the results tables. It should be noted that the accuracy of the native congener determinations was not impacted by this deviation. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Page 6 of 19 Page 2 of 15 Report No 10468853_8290FC_DFR Pace Analytical Services. LLC 1700 Elm Street - Suite 200 Minneapolis. MN 55414 Tel: 612-607-1700 Fax: 612-607-6444 Minnesota Laboratory Certifications Authority Certificate # Authority Certificate # A2LA 2926.01 Minnesota - Pet 1240 Alabama 40770 Mississippi MN00064 Alaska - DW MN00064 Missouri - DW 10100 Alaska - UST 17-009 Montana CERT0092 Arizona AZ0014 Nebraska NE-OS-18-06 Arkansas - DW MN00064 Nevada MN00064 Arkansas - WW 88-0680 New Hampshire 2081 CNMI Saipan MP0003 New Jersey (NE MN002 California 2929 New York 11647 Colorado MN00064 North Carolina 27700 Connecticut PH-0256 North Carolina - 27700 EPA Region 8+ via MN 027-053 North Carolina - 530 Florida (NELAP E87605 North Dakota R-036 Georgia 959 Ohio - DW 41244 Guam 17-001r Ohio - VAP CL101 Hawaii MN00064 Oklahoma 9507 Idaho MN00064 Oregon - Primar MN300001 Illinois 200011 Oregon - Secon MN200001 Indiana C-MN-01 Pennsylvania 68-00563 Iowa 368 Puerto Rico MN00064 Kansas E-10167 South Carolina 74003 Kentucky - DW 90062 South Dakota NA Kentucky - WW 90062 Tennessee TN02818 Louisiana - DE 03086 Texas T104704192 Louisiana - DW MN00064 Utah (NELAP) MN00064 Maine MN00064 Virginia 460163 Maryland 322 Washington C486 Massachusetts M-MN064 West Virginia - 382 Michigan 9909 West Virginia - 9952C Minnesota 027-053-137 Wisconsin 999407970 Minnesota - De via MN 027-053 Wyoming - UST 2926.01 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. without the written consent of Pace Analytical Services. Inc. Report No 10468853_8290FC_DFR Page 7 of 19 Page 3 of 15 Appendix A Sample Management Report No 10468853_8290FC_d:Mk'e Analytical Services, Inc. Page 8 of 19 Page 4 of 15 2Ida Od06z8 C9989170 oN podeei Chain of Custody Samples were sent directly to the Subcontracting Laboratory. Workorder: 35456928 Workorder Name: 2018-3057/Melreese Golf Course State Of Origin: FL Cert. Needed: Li ves Owner Received Date: ace Analytical w,cw.pace!&Assam No 3/27/2019 Results Requested By: 4/8/2019 Report To Subcontract To � Ftegtiesied Analysis ---� _ �- � Christina Raschke Pace Analytical Minnesota' y Pace Analytical South Florida 1700 Elm Street SE I Park Central Blvd N Suite 200 Pompano Beach, FL 33064 Minneapolis, MN 55414 ' Phone (954)582-4300 Phone (612)607-1700 � `'• (' 12 a CY— l``0 i. 1 1 1 IiI i i46 `8 1. 3' 111) o I ` :' V _ I 1 ,� ° ° .. { ' _ .. s LAB USE ONLY Preserved Containers Item Sample la Sample Type Collect Date/Time Lab ID Matrix 9 5 1 MW-3 PS 3/26/2019 12 14 35456928001 Water 1 X /2J1 2 MW-4 PS 3/26/2019 13:30 35456928002 Wafer 1 X GCS3 I 4 5 1 Comments Transfers Released By Da /Ti me�i Rec v d By Date/Time grit r 1 05/ 1l / J0 a) c �-r/� S f ffj/ 2 Cooler Temperature on Receipt a - °C Custody Seal or N 1 Received on Ice /'Y it N Samples Intact Qr N -o csa co ***In order to maintain client confidentiality, location/name of the sam g site, sampler's name and signature may not be provided on this COC document. This chain of custody is considered complete as is since this information is available in the owner laboratory. o Wednesday. March :27. 2019 6:53:08 PM FMT-ALL-C-002rev00 24March2009 Page 1 r f 7 y',"'�i .-PaceAnalyficai Document Name: Sample Condition Upon Receipt Form Document Revised: 06Feb2019 Page 1 of 1 Document No.: F-MN-L-213-rev.25 Issuing Authority: Pace Minnesota Quality Office Sample Condition Upon Receipt Courier: Tracking Number: Client Name: j Ji- Fe Ex DUPS Pi 'i 15.1 47913 Project#: ❑LISPS ['Client ['Commercial See Exception Custody Seal on Cooler/Box Present? Packing Material: ubble Wrap Thermometer: ❑ G87A9155100842 WO*:10468853 PM: NB3 Due Date: 04/12/19 CLIENT: PASI—FL ❑No Seals Intact? Yes ❑No Biological Tissue Frozen? Des ❑No 1/A Temp Blank? Des G87A9170600254 Type of ice: Wet ❑Blue ['None ❑D-y ❑Melted Bubble Bags ['None ❑Other: Note: Each West Virginia Sample must have temp taken (no temp blanks) Temp should be above freezing to 6°C Cooler Temp Read w/temp blank: Correction Factor: Cooler Temp Corrected w/temp blank : aC aC Average Corrected Temp See Exceptions (no temp blank only): oC USDA Regulated Soil: /A, water sample/Other: } Date/Initials of Person Examining Contents: Did samples originate in a quarantine zone within the United States: AL, AR, CA, FL, GA, Did samples originate from a foreign source (internationally, including ID, LA. MS, NC, NM, NY, OK, OR, SC, TN, TX or VA (check maps)? ['Yes ❑No Hawaii and Puerto Rico)? ❑Yes ❑No if Yes to either question, fill out a Regulated Soil Checklist (F-MN-Q-338) and include with SCUR/COC paperwork. COMMENTS: Chain of Custody Present and Filled Out? .° f+'rs ❑No 1. Chain of Custody Relinquished? „„g+lt " ❑No 2. Sampler Name and/or Signature on COC? ❑Yes ❑No gifig 3. Samples Arrived within Hold Time? .ales ❑No 4. Short Hold Tirne Analysis (<72 hr)? ❑Yes Io 5. ['Fecal Coliform ❑HPC ['Total Coliformlr coli ❑BOD/CBOD DHex Chrome ['Turbidity ['Nitrate ❑Nitrite ❑Orthophos ❑Other Rush Turn Around Time Requested? ❑Yes ,..21f5 6. Sufficient Volume? ,Jfes ❑No 7. Correct Containers Used?e -Pace Containers Used? per ❑No ❑No 8. Containers Intact? es ❑No 9. Field Filtered Volume Received for Dissolved Tests? ['Yes [No 251A 10. Is sediment visible in the dissolved container? ❑Yes M No Is sufficient information available to reconcile the samples to the COC? Matrix: ater ❑Solt 0011 ❑Other pT ❑No 11. If no, write ID/ Date/Time on Container Below: See Exception • ■ All containers needing acid/base preservation have been checked? All containers needing preservation are found to be in compliance with EPA recommendation? {HNO3, H2SO4, <2pH, NaOH >9 Sulfide, NaOH>12 Cyanide) Exceptions: VOA, Coliform, TOC/DOC Oil and Grease, DRO/8015 (water) and Dioxin/PFAS ❑Yes Ores Des ❑No ENO ❑No 12N7r f A 12. Sample # 0 NaOH 0 HNO3 ■H2SO4 IIIIIIZinc Acetate Positive for Res. E Yes See Exception Chlorine? III NO ❑ Headspace in VOA Vials (greater than 6mm)? ❑Yes ❑No J nli, 13. See Exception III Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes DYes ❑No ❑No A Jf/A 14. /j Pace Trip Blank Lot # (if purchased): Zs'� � CLIENT NOTIFICATION/RESOLUTION Person Contacted: Comments/Resolution: Date/Time: t Field Data Required? Des ❑No Project Manager Review: Xat Date: 4/1/19 Note: Whenever there is a discrepancy affecting No Ca olin mpliancelsamptes, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e out of hold, incorrect preservative, out of temp, incorrect containers). 1i Labeled by: Report No 104688538290FCDFR Page 10 of 19 Page 6 of 15 P ceA7Qiyllca Documem Name: SLUR Exception Form — Cooier Above 6°C Document Revised: O4Fen2O19 Page 1 Of 1 Document No.: P-Wihi-C-298-Rev.O1 Issuing Authority: Pace Minnesota Quality Office SCAM Exceptions. During sample triage, this worm is to be piecedpiaced in each co&er that arrives es above 6.0 degrees C&skus Vilorkorder #a Container Out of Temp Same fl y Type Containers Other Issues Issue Type: Sample ID Container # of Type Cc Mainers PM" Notified? [pees Ohio If yes, indicate who was contacted/date/time. If no, indicate reason why. M Etapie CuoEer'Preject' if you answered yes,fiill out information to the le No Temp Blank Read Temp Corrected Temp Average Temp z3 Tracking Nurnbe C`a;A?F ste.rEerci' L611''(`rt' PI°!,=-:sen,?e Sid•' rip;il;=s ype cf Pi eserv. a'r: 1 i Amouinti i ::ray Da e Time : Ac3'et ,ct - NH j in Compliance Receipt Adjusted AO;USieo �ii:LJ ACciee I After j after addition? j initials i i Yes L_;I\io "e< `Ro Ye5 i iNe Page 11 of 19 Report No 10468853_8290FC_DFR Page 7 of 15 AnalyticalTM Reporting Flags Pace Analytical Services. LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 A = Reporting Limit based on signal to noise B = Less than 10x higher than method blank level C = Result obtained from confirmation analysis D = Result obtained from analysis of diluted sample E = Exceeds calibration range I = Interferencepresent J = Estimated value L = Suppressive interference, analyte may be biased low Nn = Value obtained from additional analysis P = PCDEInterference R = Recovery outside target range S = Peak saturated U = Analyte not detected V = Result verified by confirmation analysis X = %D Exceeds limits Y = Calculated using average of daily RFs * = SeeDiscussion REPORT OF LABORATORYANALYSIS Tel: 612-607-1700 Fax:612-607-6444 This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, Inc. Report No 10468853_8290FC_DFR Page 8 of 15 Page 12 of 19 Appendix B Sample Analysis Summary Report No 10468853_8290FC_dtik e Analytical Services, Inc. Page 13 of 19 Page 9 of 15 Total HpCDD OCDF OCDD ace Analytical Client's Sample ID Client's Sample ID Lab Sample ID Filename Injected By Total Amount Extracted Moisture Dry Weight Extracted ICAL ID CCaI Filename(s) Method Blank ID Native Isomers 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF TM Metho d 8290 Sample Analysis Results Client - PASI Florida M W- M W-3 35456928001 Y190406B_16 JRH 960 mL NA NA Y190110 Y1904066_02 & Y190406B_18 BLANK-69554 Conc EMPC pg/L pg/L EDL pg/L Matrix Dilution Collected Received Extracted Analyzed Internal Standards Pace Analytical Services. LLC 1700 Elm Street - Suite 200 Minneapolis. MN 55414 Tel: 612-607-1700 Fax: 612- 607-6444 Water NA 03/26/2019 12:14 03/29/2019 09:45 04/02/2019 11:30 04/06/2019 22:56 ng's Percent Added Recovery 0.91 U 0.91 U 1.3 U 1.3 U 1.8 U 1.5 U 1.6 U 3.4 U 3.4 U 1.4 U 0.66 U 0.53 U 0.93 U 0.76 U 2.1 U 1.4 U 1.4 U 1.8 U 2.4 U 2.1 U 2.4 1,2,3,4,6,7,8-HpCDD 1.6 1.4 U 3.5 U 5.4 0.91 2, 3, 7, 8-TCDF-13C 0.91 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 1.3 2,3,4,7,8-PeCDF-13C 1.3 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 1.8 1,2,3,6,7,8-HxCDF-13C 1.5 2,3,4,6,7,8-HxCDF-13C 1.6 1,2,3,7, 8, 9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 3.4 1,2, 3,6,7,8-HxCDD-13C 3.4 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1.1 PJ 1,2,3,4,6,7,8-HpCDD-13C 1.4 OCDD-13C 0.66 0.53 0.93 0.76 2.1 1.4 1.4 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 4.00 2.00 2.00 0.20 1.8 Total 2,3,7,8-TCDD 2.4 Equivalence: 0.26 pg/L 2.1 (Lower -bound - Using ITE Factors) 1.4 IJ 1.4 3.5 5.2 J 82 80 79 76 85 69 62 71 78 74 58 64 70 74 60 NA NA 90 Conc = Concentration (Totals include 2.3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit J = Estimated value P = PCDE Interference I= Interference present ND = Not Detected NA = Not Applicable NC = Not Calculated REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, Inc. Report No 10468853_8290FC_DFR Page 10 of 15 Page 14 of 19 aceAnalytical Client's Sample ID Lab Sample ID Filename Injected By Total Amount Extracted % Moisture Dry Weight Extracted ICAL ID CCal Filename(s) Method Blank ID Native Isomers TM Method 8290 Sample Analysis Results Client - PASI Florida MW-4 35456928002 Y190406B_17 JRH 877 mL NA NA Y190110 Y190406B_02 & Y190406B_18 BLANK-69554 Conc pg/L EMPC EDL pg/L pg/L Matrix Dilution Collected Received Extracted Analyzed Internal Standards Pace Analytical Services. LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612- 607-6444 Water NA 03/26/2019 13:30 03/29/2019 09:45 04/02/2019 11:30 04/06/2019 23:43 ng's Percent Added Recovery 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD 1.4 U 1.4 U 1.3 U 1.3 U 1.7 U 1.7 1.7 3.2 U 3.2 U 0.70 U 0.98 U 0.95 U 1.4 U 1.00 U 1.2 U 1.9 U 1.9 U 1.7 U 1.2 U 1.4 U 1.3 U 1.4 U 2.9 3.0 U 8.2 0.70 0.98 0.95 1.4 1.00 1.2 1.9 1.9 1.7 1.4 2,3,7,8-TCDF-13C 1.4 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 1.3 2,3,4,7,8-PeCDF-13C 1.3 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 1.7 1,2,3,6,7, 8-HxCDF-13C 1.3 J 2,3,4,6,7,8-HxCDF-13C 1.5 J 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 3.2 1,2, 3,6,7, 8-HxCDD-13C 3.2 1,2,3,4,6,7, 8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 2.00 77 2.00 75 2.00 74 2.00 71 2.00 78 2.00 65 2.00 58 2.00 67 2.00 73 2.00 69 2.00 54 2.00 60 2.00 65 2.00 68 4.00 53 2.00 NA 2.00 NA 0.20 76 1.2 Total 2,3,7,8-TCDD 1.4 Equivalence: 0.84 pg/L 1.3 (Lower -bound - Using ITE Factors) 1.4 1.4 J 3.0 4.4 IJ Conc = Concentration (Totals include 2,3.7.8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit J = Estimated value I = Interference present ND = Not Detected NA = Not Applicable NC = Not Calculated REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. without the written consent of Pace Analytical Services, Inc. Report No 10468853_8290FC_DFR Page 15 of 19 Page 11 of 15 Analytical Lab Sample Name Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) TM Me thod 8290 Blank Analysis Results DFBLKKS BLANK-69554 U190405A_06 945 mL U190403 U190405A_01 & U190405A_17 Native Conc Isomers pg/L EMPC EDL pg/L pg/L Matrix Dilution Extracted Analyzed Injected By Internal Standards Pace Analytical Services. LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax.612-607-6444 Water NA 04/02/2019 11:30 04/05/2019 13:54 JRH ng's Percent Added Recovery 2,3,7,8-TCDF 1.1 U Total TCDF 1.1 U 2,3,7,8-TCDD 1.5 U Total TCDD 1.5 U 1,2,3,7,8-PeCDF 1.3 U 2,3,4,7,8-PeCDF 0.78 U Total PeCDF 1.0 U 1,2,3,7,8-PeCDD 1.2 U Total PeCDD 1.2 U 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 0.58 U 2,3,4,6,7,8-HxCDF 0.73 U 1,2,3,7,8,9-HxCDF 0.75 U Total HxCDF 0.71 U 1,2,3,4,7,8-HxCDD 0.66 U 1,2,3,6,7,8-HxCDD 1.0 U 1,2,3,7,8,9-HxCDD 1.1 U Total HxCDD 0.92 U 1,2,3,4,6,7,8-HpCDF 0.86 U 1,2,3,4,7,8,9-HpCDF 1.1 U Total HpCDF 1.00 U 1,2,3,4,6,7,8-HpCDD 1.2 U Total HpCDD 1.2 U OCDF 2.4 U OCDD 3.0 U 0.83 0.76 IJ 0.58 0.73 0.75 0.71 0.66 1.0 1.1 0.92 1.1 2,3,7,8-TCDF-13C 1.1 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 1.5 2,3,4,7,8-PeCDF-13C 1.5 1,2,3,7, 8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 1.3 1, 2 , 3, 6, 7, 8-HxC D F-13C 0.78 2,3,4,6,7,8-HxCDF-13C 1.0 1,2, 3, 7, 8, 9-HxC DF-13C 1,2,3,4,7,8-HxCDD-13C 1.2 1, 2 , 3, 6, 7, 8-HxCDD-13 C 1.2 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 4.00 2.00 2.00 0.20 0.86 Total 2,3,7,8-TCDD 1.1 Equivalence: 0.083 pg/L 1.00 (Lower -bound - Using ITE Factors) 1.2 1.2 2.4 3.0 80 82 80 79 92 81 81 83 79 78 75 62 63 65 69 Y NA NA 86 Conc=Concentration (Totals include2,3,7,8-substituted isomers). EMPC = Estimated Maximum Possible Concentration EDL = Estimated Detection Limit J = Estimated value I = Interference present Y= Calculated using average of daily RFs REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services. Inc. Report No 10468853_8290FC_DFR Page 12 of 15 Page 16 of 19 aceAnalytical Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) Method Blank ID Native Isomers 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD TM Method 8290 Laboratory Control Spike Results LCS-69555 U190405A_15 923 mL U190403 U190405A_01 & U190405A_17 BLANK-69554 Matrix Dilution Extracted Analyzed Injected By Qs Qm % Internal (ng) (ng) Rec. Standards 0.20 0.23 116 2,3,7,8-TCDF-130 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 0.20 0.26 130 2,3,4,7,8-PeCDF-13C 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 1.0 1.2 119 1,2, 3, 6, 7, 8-HxCDF-13C 1.0 1.2 121 2,3,4,6,7,8-HxCDF-13C 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 1.0 1.1 111 1,2,3,6,7,8-HxCDD-13C 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1.0 1.2 124 1,2, 3,4,6,7,8-HpCDD-13C 1.0 1.2 117 OCDD-13C 1.0 1.1 114 1.0 1.1 114 1.0 1.0 1.0 1.0 1.0 1.0 2.0 2.0 1.2 1.3 1.3 1.2 1.1 1.1 2.4 2.4 121 133 R 127 123 115 113 121 121 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis. MN 55414 Tel: 612-607-1700 Fax: 612-607-6444 Water NA 04/02/2019 11:30 04/05/2019 20:52 JRH ng's Percent Added Recovery 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 4.0 2.0 2.0 0.20 76 77 71 71 82 74 76 78 74 72 66 52 54 54 55 Y NA NA 79 Qs = Quantity Spiked Qm = Quantity Measured Rec. = Recovery (Expressed as Percent) R = Recovery outside of target range Y = RF averaging used in calculations Nn = Value obtained from additional analysis NA = Not Applicable * = See Discussion REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Report No 10468853_8290FC_DFR Page 17 of 19 Page 13 of 15 Analytical Lab Sample ID Filename Total Amount Extracted ICAL ID CCaI Filename(s) Method Blank ID Native Isomers 2,3,7,8-TCDF Total TCDF 2,3,7,8-TCDD Total TCDD 1,2,3,7,8-PeCDF 2,3,4,7,8-PeCDF Total PeCDF 1,2,3,7,8-PeCDD Total PeCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 1,2,3,4,6,7,8-HpCDD Total HpCDD OCDF OCDD TM Method Method 8290 Laboratory Control Spike Results LCSD-69556 U190405A_16 942 mL U190403 U190405A_01 & U190405A_17 BLANK-69554 Qs Qm (ng) (ng) 0.20 0.24 ok Rec. 119 0.20 0.28 139 R 1.0 1.2 121 1.0 1.3 127 1.0 1.1 112 1.0 1.2 125 1.0 1.2 120 1.0 1.2 118 1.0 1.2 117 1.0 1.2 124 1.0 1.4 140 R 1.0 1.3 131 R 1.0 1.2 124 1.0 1.2 117 1.0 1.2 118 2.0 2.6 128 2.0 2.5 125 Matrix Dilution Extracted Analyzed Injected By Internal Standards Pace Analytical Services. LLC 1700 Elm Street - Suite 200 Minneapolis, MN 55414 Tel: 612-607-1700 Fax: 612-607-6444 Water NA 04/02/2019 11:30 04/05/2019 21:38 JRH ng's Percent Added Recovery 2,3,7,8-TCDF-13C 2,3,7,8-TCDD-13C 1,2,3,7,8-PeCDF-13C 2,3,4,7,8-PeCDF-13C 1,2,3,7,8-PeCDD-13C 1,2,3,4,7,8-HxCDF-13C 1,2,3,6,7,8-HxCDF-13C 2,3,4,6,7,8-HxCDF-13C 1,2,3,7,8,9-HxCDF-13C 1,2,3,4,7,8-HxCDD-13C 1,2,3,6,7,8-HxCDD-13C 1,2,3,4,6,7,8-HpCDF-13C 1,2,3,4,7,8,9-HpCDF-13C 1,2,3,4,6,7,8-HpCDD-13C OCDD-13C 1,2,3,4-TCDD-13C 1,2,3,7,8,9-HxCDD-13C 2,3,7,8-TCDD-37CI4 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 4.0 2.0 2.0 0.20 75 76 72 70 82 74 75 76 74 70 64 53 56 55 58 Y NA NA 83 Qs = Quantity Spiked Qm = Quantity Measured Rec. = Recovery (Expressed as Percent) R= Recovery outside of target range Y = RF averaging used in calculations Nn = Value obtained from additional analysis NA = Not Applicable = See Discussion REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. without the written consent of Pace Analytical Services. Inc. Report No 10468853_8290FC_DFR Page 18 of 19 Page 14 of 15 Analytical TM Method 8290 Pace Analytical Services, LLC 1700 Elm Street - Suite 200 Minneapolis. MN 55414 Spike Recovery Relative Percent Difference (RPD) Results Client PASI Florida Spike 1 ID LCS-69555 Spike 2 ID LCSD-69556 Spike 1 Filename U190405A_15 Spike 2 Filename U190405A_16 Spike 1 Spike 2 Compound %REC %REC %RPD Tel: 612-607-1700 Fax: 612-607-6444 2,3,7,8-TCDF 116 119 2.6 2,3,7,8-TCDD 130 139 6.7 1,2,3,7,8-PeCDF 119 121 1.7 2,3,4,7,8-PeCDF 121 127 4.8 1,2,3,7,8-PeCDD 111 112 0.9 1,2,3,4,7,8-HxCDF 124 125 0.8 1,2,3,6,7,8-HxCDF 117 120 2.5 2,3,4,6,7,8-HxCDF 114 118 3.4 1,2,3,7,8,9-HxCDF 114 117 2.6 1,2,3,4,7,8-HxCDD 121 124 2.4 1,2,3,6,7,8-HxCDD 133 140 5.1 1,2,3,7,8,9-HxCDD 127 131 3.1 1,2,3,4,6,7,8-HpCDF 123 124 0.8 1,2,3,4,7,8,9-HpCDF 115 117 1.7 1,2,3,4,6,7,8-HpCDD 113 118 4.3 OCDF 121 128 5.6 OCDD 121 125 3.3 %REC = Percent Recovered RPD = The difference between the two values divided by the mean value REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, withoutthewritten consent of Pace Analytical Services. Inc. Report No 10468853_8290FC_DFR Page 19 of 19 Page 15 of 15 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 April 02, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456930 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 27, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry, EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 14 /eAnaIytica! wurui narolnhe mm CERTIFICATIONS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456930 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 14 aceAnalytical www pacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456930 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35456930001 MW-3 Water 03/26/19 12:14 03/27/19 17:15 35456930002 MW-4 Water 03/26/19 13:30 03/27/19 17:15 35456930003 MW-5 Water 03/26/1913:57 03/27/1917:15 35456930004 MW-9 Water 03/26/19 15:02 03/27/19 17:15 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 14 SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456930 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35456930001 MW-3 35456930002 MW-4 35456930003 MW-5 35456930004 MW-9 EPA 350.1 MAJ 1 PASI-O EPA 350.1 MAJ 1 PASI-O EPA 350.1 MAJ 1 PASI-O EPA 350.1 MAJ 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 14 aceAnalytical www.pace/abs.com SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456930 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed 35456930001 MW-3 EPA 350.1 Nitrogen, Ammonia 0.47 mg/L 0.050 03/29/19 13:58 35456930002 MW-4 EPA 350.1 Nitrogen, Ammonia 0.64 mg/L 0.050 03/29/19 14:00 35456930003 MW-5 EPA 350.1 Nitrogen, Ammonia 3.0 mg/L 0.050 03/29/19 14:02 35456930004 MW-9 EPA 350.1 Nitrogen. Ammonia 9.3 mg/L 0.050 03/29/19 14:04 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 14 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456930 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-3 Lab ID: 35456930001 Collected: 03/26/19 12:14 Received: 03/27/19 17:15 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 350.1 Ammonia Analytical Method: EPA 350.1 Nitrogen. Ammonia 0.47 mg/L 0.050 0.035 1 03/29/19 13:58 7664-41-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/02/2019 03:18 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 14 aceAnalytical www.pacelabs.com ro� ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456930 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-4 Lab ID: 35456930002 Collected: 03/26/19 13:30 Received: 03/27/19 17:15 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 350.1 Ammonia Analytical Method: EPA 350.1 Nitrogen. Ammonia Date: 04/02/2019 03:18 PM 0.64 mg/L 0.050 0.035 1 03/29/19 14:00 7664-41-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 14 ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456930 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-5 Lab ID: 35456930003 Collected: 03/26/19 13:57 Received: 03/27/19 17:15 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 350.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia Date: 04/02/2019 03:18 PM 3.0 mg/L 0.050 0.035 1 03/29/19 14:02 7664-41-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 14 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456930 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-9 Lab ID: 35456930004 Collected: 03/26/19 15:02 Received: 03/27/19 17:15 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 350.1 Ammonia Analytical Method: EPA 350.1 Nitrogen, Ammonia Date: 04/02/2019 03:18 PM 9.3 mg/L 0.050 0.035 1 03/29/19 14:04 7664-41-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 14 c3 www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456930 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: QC Batch Method: 527077 EPA 350.1 Analysis Method: Analysis Description: Associated Lab Samples: 35456930001, 35456930002, 35456930003, 35456930004 EPA 350.1 350.1 Ammonia METHOD BLANK: 2851688 Matrix: Water Associated Lab Samples: Parameter 35456930001, 35456930002, 35456930003, 35456930004 Blank Reporting Units Result Limit MDL Analyzed Qualifiers Nitrogen, Ammonia mg/L 0.035 U 0.050 0.035 03/29/19 13:18 LABORATORY CONTROL SAMPLE: 2851689 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 1 1.1 107 90-110 MATRIX SPIKE SAMPLE: 2851691 92422841003 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 3.9 1 5.0 106 90-110 SAMPLE DUPLICATE: 2851690 92422841003 Dup Parameter Units Result Result RPD Max RPD Qualifiers Nitrogen, Ammonia mg/L 3.9 3.9 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/02/2019 03:18 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 14 /42ceAnalytical www..pacelabs.com QUALIFIERS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456930 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS U Compound was analyzed for but not detected. Date: 04/02/2019 03:18 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 14 www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melreese Golf Course Pace Project No.: 35456930 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID QC Batch Method Analytical QC Batch Analytical Method Batch 35456930001 MW-3 EPA 350.1 527077 35456930002 MW-4 EPA 350.1 527077 35456930003 MW-5 EPA 350.1 527077 35456930004 MW-9 EPA 350.1 527077 Date: 04/02/2019 03:18 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 14 WO#:35456930 racennagroca, I11I1IIII1II Section A III III I III ..0 r 1 r,tmail, 11.t.,ar .W4LIVOL LJvA.uuICI ll GAL DOCUMENT. All relevant fields must be completed accurately. 35456930 Required Client Information: rmation: Paige: Of Company EEF.G Envuonmentel Services LLC Reoon To Michael Van Ry Anennuc Address 5751 Miami Lakes Dnve Copy To. Company Name Miarm Lakes. FL 33011 Address Rogulatory Agency Email mvanryc0 eeandy cem Purchase Order # Pace Quote. Phone 1305)374-9300 JFa x Project Name Melreese Golf Course Pcree Project Manager christna.raschke el acelahs corn, (.P State! Location Regr�esreo Due Dale _ .. _ .., Project #: 2318 3057 -.- �•r„rne t FL MATRIX CODE MATRIX CODE (see valid codes to left) I TYPE (G=GRAB C=COMP) COLLECTED SAMPLE TEMP AT COLLE.:TION d OF CONTAINERS Preservatives Z Y Plinking Water OW Wale WT WaGc Wale, WW Pmun R SAMPLE ID Sod/Solida START END Unpreserved HNO3______ NaOH Methanol Other Analyses Test 6010 Al, As, Fe, Pb PAH SIM 8260 VOC TRPH FL -PRO 1 8290 Dioxin & Furans OC Pesticides 8081 OP Pesticides 8141 8151 Herbicides 6010-Ba, Cd, Cr, Q a 03 7470 Hg — c._ Residual Chlorine (Y/N) grk illco I One Character per box. Wme Wa (A-Z 0_9 / -) nti AR Sample Ids must be unique il.S„r Ts DATE TIME DATE TIME O N U x 0 N co iu z 1 2 _ 3 4 5 0 7 8 9 10 11 12 ADDITIONAL COMMENTS RELINQUISHED BY/ DATE TIME ACCEPTED BY I AFFILIATION DATE TIME SAMPLE CONDITONS C'W2- FL7 ICI ( CY' ? VZ------ - cli_2 1 v _ r SAMPLER NAME AND SIGNATURE t TEMP in C Received on Ice (Y/N) Custody Sealed Cooler (Y/N) a E PRINT Name of SAMPLER: .SIGNATURE of SAMPLER: DATE Signed: Page 13 of 14 iif-��'• -/ ceAnd/ytiCS! Document Name Sample Condition Upon Receipt Form Document Re,:s=_o Clay 30, 20t 6 Document No F-FL-C-007 rev 13 Issuing Authority Pace Florida Quality Office Project # Project Manager: Client: WO# : 35456930 PM: CTR CLIENT: 36-EEG Due Date: 04/03/19 Thermometer Used -''3 gt) Date State of Ongin% / Cooler #1 Temp.'C LI- C� U (Visual) 0.0 (Actual) Cooler #2 Temp.°C (Visual) (Actual) Cooler #3 Temp.°C (Visual) _ (Actual) Cooler #4 Temp.'C (Visual) (Actual) Cooler #5 Temp.'C (Visual) (Actual) Cooler #6 Temp.'C (Visual) (Actual) Fc . ;'! pro;eyig all containers verified to (Correction Factor) C� (Correction Factor) (Correction Factor) (Correction Factor) (Correction Factor) (Correction Factor) Courier: L Fed Ex UPS ❑ USPS — Client L Commercial Pace Date and Initials of person: Examining contents: Label: Deliver: pH: Time PIO Initials. C C C L C Samples on ice. cooking process has begun Samples on ice, cooking process has begun Samples on ice. cooling process has begun Samples on ice, cooling process has begun Samples on ice, cooling process has begun Samples on ice, cooling process has begun E Other Shipping Method: - First Overnight - Priority Overnight Standard Overnight - Ground - International Priority Other Billing: - Recipient - Sender - Third Party - Credit Card /_ unknown Tracking # Custody Seal on Cooler/Box Present: Flees Seals intact: ` Yes .7ettro-- Packing Material: L!Bubble Wrap Li Bubble Bags None Samples shorted to lab (If Yes, complete) Shorted Date r Other Ice: Shorted Time: / u ilf lue Dry None Qty At i Comments: Chain of Custody Present Yes - No -N/A Chain of Custody Filled Outs - No -N/A Relinquished Signature & Sampler Name COC es - No -N/A Samples Arrived within Hold Time — es : = NoN/A Rush TAT requested on COC =Yes .No EN/A Sufficient Volume ,(- No IT N/A Correct Containers Used _Yes - No EN/A Containers Intact _Yes =' No EN!A Labels match COC (sample IDs & date/time of collection) Xs11 No N/A All containers needing acid/base preservation have been checked "Yes - No N/A All Containers needing preservation are found to be in compliance with EPA recommendation es - No -N/A Exceptions VOA. Coliform TOG, O&G. Carbamates Preservation Information Preservative Lot #,Trace # Date Time Initials Headspace in VOA Vials? ( >6mm). -Yes - No A Trip Blank Present: -Yes - No 1G/A Client Notification/ Resolution: Person Contacted Comments/ Resolution (use back for additional comments): Date/Time Project Manager Review Date. age 14 of 14 www.pace/abs.com April 11, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457298 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on March 28, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Kelsey Cortina, EE&G Environmental Solutions, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC, Page 1 of 15 www.pacelabs.com CERTIFICATIONS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457298 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alaska DEC- CS/UST/LUST Alabama Certification #: 41320 Arizona Certification# AZ0819 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 15 aceAnalytical www.pacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457298 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35457298001 MW-6 Water 03/27/1912:00 03/28/19 17:45 35457298002 MW-7 Water 03/27/19 10:59 03/28/19 17:45 35457298003 MW-8 Water 03/27/19 09:44 03/28/19 17:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 15 SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457298 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35457298001 MW-6 EPA 8081 TCB 22 PASI-O EPA 6010 JWP 4 PASI-O 35457298002 MW-7 EPA 8081 TCB 22 PASI-O EPA6010 JWP 4 PASI-O 35457298003 MW-8 EPA 8081 TCB 22 PASI-O EPA 6010 JWP 4 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 15 SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457298 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35457298001 MW-6 EPA6010 Barium 13.3 ug/L 10.0 04/03/19 16:31 EPA 6010 Iron 87.6 ug/L 40.0 04/03/19 16:31 35457298002 MW-7 EPA 6010 Barium 174 ug/L 10.0 04/03/19 16:34 EPA 6010 Iron 884 ug/L 40.0 04/03/19 16:34 EPA 6010 Lead 6.9 I ug/L 10.0 04/03/19 16:34 35457298003 MW-8 EPA 6010 Barium 88.3 ug/L 10.0 04/03/19 16:37 EPA6010 Iron 793 ug/L 40.0 04/03/19 16:37 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 15 (1eAnaIYticaI www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457298 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-6 Lab ID: 35457298001 Collected: 03/27/19 12:00 Received: 03/28/19 17:45 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8081 GCS Pesticides Analytical Method: EPA 8081 Preparation Method: EPA 3510 Aldrin 0.0014 U ug/L 0.0096 0.0014 1 04/03/19 17:20 04/09/19 14:07 309-00-2 1p alpha-BHC 0.0020 U ug/L 0.0096 0.0020 1 04/03/19 17:20 04/09/19 14:07 319-84-6 1p beta-BHC 0.0077 U ug/L 0.0096 0.0077 1 04/03/19 17:20 04/09/19 14:07 319-85-7 1p delta-BHC 0.0046 U ug/L 0.0096 0.0046 1 04/03/19 17:20 04/09/19 14:07 319-86-8 1p gamma-BHC (Lindane) 0.0021 U ug/L 0.0096 0.0021 1 04/03/19 17:20 04/09/19 14:07 58-89-9 1p Chlordane (Technical) 0.17 U ug/L 0.48 0.17 1 04/03/19 17:20 04/09/19 14:07 57-74-9 1p 4,4'-DDD 0.0085 U ug/L 0.0096 0.0085 1 04/03/19 17:20 04/09/19 14:07 72-54-8 1p,CU 4,4'-DDE 0.0048 U ug/L 0.0096 0.0048 1 04/03/19 17:20 04/09/19 14:07 72-55-9 1p 4,4'-DDT 0.0048 U ug/L 0.0096 0.0048 1 04/03/19 17:20 04/09/19 14:07 50-29-3 1p,CU Dieldrin 0.0019 U ug/L 0.0096 0.0019 1 04/03/19 17:20 04/09/19 14:07 60-57-1 1p Endosulfan I 0.0049 U ug/L 0.0096 0.0049 1 04/03/19 17:20 04/09/19 14:07 959-98-8 1p Endosulfan 11 0.0038 U ug/L 0.0096 0.0038 1 04/03/19 17:20 04/09/19 14:07 33213-65-9 1p,CU Endosulfan sulfate 0.0060 U ug/L 0.096 0.0060 1 04/03/19 17:20 04/09/19 14:07 1031-07-8 1p,CU Endrin 0.0041 U ug/L 0.0096 0.0041 1 04/03/19 17:20 04/09/19 14:07 72-20-8 1p Endrin aldehyde 0.0035 U ug/L 0.096 0.0035 1 04/03/19 17:20 04/09/19 14:07 7421-93-4 1p,CU Endrin ketone 0.0048 U ug/L 0.0096 0.0048 1 04/03/19 17:20 04/09/19 14:07 53494-70-5 1p,CU Heptachlor 0.0060 U ug/L 0.0096 0.0060 1 04/03/19 17:20 04/09/19 14:07 76-44-8 1p Heptachlor epoxide 0.0050 U ug/L 0.0096 0.0050 1 04/03/19 17:20 04/09/19 14:07 1024-57-3 1p Methoxychlor 0.0092 U ug/L 0.0096 0.0092 1 04/03/19 17:20 04/09/19 14:07 72-43-5 1p,CU Toxaphene 0.24 U ug/L 0.48 0.24 1 04/03/19 17:20 04/09/19 14:07 8001-35-2 1p Surrogates Tetrachloro-m-xylene (S) 78 % 27-124 1 04/03/19 17:20 04/09/19 14:07 877-09-8 Decachlorobiphenyl (S) 55 % 10-132 1 04/03/19 17:20 04/09/19 14:07 2051-24-3 6010 MET 1CP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Arsenic 7.1 U ug/L 10.0 7.1 1 04/03/19 07:51 04/03/19 16:31 7440-38-2 Barium 13.3 ug/L 10.0 0.84 1 04/03/19 07:51 04/03/19 16:31 7440-39-3 Iron 87.6 ug/L 40.0 9.2 1 04/03/19 07:51 04/03/19 16:31 7439-89-6 Lead 4.6 U ug/L 10.0 4.6 1 04/03/19 07:51 04/03/19 16:31 7439-92-1 Date: 04/11/2019 09:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 15 wwwpacelabs.corn ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457298 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-7 Lab ID: 35457298002 Collected: 03/27/19 10:59 Received: 03/28/19 17:45 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8081 GCS Pesticides Analytical Method: EPA 8081 Preparation Method: EPA 3510 Aldrin 0.0014 U ug/L 0.0096 0.0014 1 04/03/19 17:20 04/09/19 14:27 309-00-2 1p alpha-BHC 0.0020 U ug/L 0.0096 0.0020 1 04/03/19 17:20 04/09/19 14:27 319-84-6 1p beta-BHC 0.0077 U ug/L 0.0096 0.0077 1 04/03/19 17:20 04/09/19 14:27 319-85-7 1p delta-BHC 0.0046 U ug/L 0.0096 0.0046 1 04/03/19 17:20 04/09/19 14:27 319-86-8 1p gamma-BHC (Lindane) 0.0021 U ug/L 0.0096 0.0021 1 04/03/19 17:20 04/09/19 14:27 58-89-9 1p Chlordane (Technical) 0.17 U ug/L 0.48 0.17 1 04/03/19 17:20 04/09/19 14:27 57-74-9 1p 4,4'-DDD 0.0086 U ug/L 0.0096 0.0086 1 04/03/19 17:20 04/09/19 14:27 72-54-8 1p,CU 4,4'-DDE 0.0048 U ug/L 0.0096 0.0048 1 04/03/19 17:20 04/09/19 14:27 72-55-9 1p 4,4'-DDT 0.0048 U ug/L 0.0096 0.0048 1 04/03/19 17:20 04/09/19 14:27 50-29-3 1p,CU Dieldrin 0.0019 U ug/L 0.0096 0.0019 1 04/03/19 17:20 04/09/19 14:27 60-57-1 1p Endosulfan I 0.0049 U ug/L 0.0096 0.0049 1 04/03/19 17:20 04/09/19 14:27 959-98-8 1p Endosulfan II 0.0038 U ug/L 0.0096 0.0038 1 04/03/19 17:20 04/09/19 14:27 33213-65-9 1p,CU Endosulfan sulfate 0.0060 U ug/L 0.096 0.0060 1 04/03/19 17:20 04/09/19 14:27 1031-07-8 1p,CU Endrin 0.0041 U ug/L 0.0096 0.0041 1 04/03/19 17:20 04/09/19 14:27 72-20-8 1p Endrin aldehyde 0.0035 U ug/L 0.096 0.0035 1 04/03/19 17:20 04/09/19 14:27 7421-93-4 1p,CU Endrin ketone 0.0048 U ug/L 0.0096 0.0048 1 04/03/19 17:20 04/09/19 14:27 53494-70-5 1p,CU Heptachlor 0.0060 U ug/L 0.0096 0.0060 1 04/03/19 17:20 04/09/19 14:27 76-44-8 1p '9,ptachlor epoxide 0.0050 U ug/L 0.0096 0.0050 1 04/03/19 17:20 04/09/19 14:27 1024-57-3 1p ethoxychlor 0.0092 U ug/L 0.0096 0.0092 1 04/03/19 17:20 04/09/19 14:27 72-43-5 1p,CU Toxaphene 0.24 U ug/L 0.48 0.24 1 04/03/19 17:20 04/09/19 14:27 8001-35-2 1p Surrogates Tetrachloro-m-xylene (S) 69 % 27-124 1 04/03/19 17:20 04/09/19 14:27 877-09-8 Decachlorobiphenyl (S) 43 % 10-132 1 04/03/19 17:20 04/09/19 14:27 2051-24-3 6010 MET ICP Analytical Method: EPA 6010 Preparation Method EPA 3010 Arsenic 7.1 U ug/L 10.0 7.1 1 04/03/19 07:51 04/03/19 16:34 7440-38-2 Barium 174 ug/L 10.0 0.84 1 04/03/19 07:51 04/03/19 16:34 7440-39-3 Iron 884 ug/L 40.0 9.2 1 04/03/19 07:51 04/03/19 16:34 7439-89-6 Lead 6.9 I ug/L 10.0 4.6 1 04/03/19 07:51 04/03/19 16:34 7439-92-1 Date: 04/11/2019 09:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 15 aceAna/ ical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457298 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-8 Lab ID: 35457298003 Collected: 03/27/19 09:44 Received: 03/28/19 17:45 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 8081 GCS Pesticides Analytical Method: EPA 8081 Preparation Method: EPA 3510 Aldrin 0.0015 U ug/L 0.0097 0.0015 1 04/03/19 17:20 04/09/19 14:46 309-00-2 1p alpha-BHC 0.0020 U ug/L 0.0097 0.0020 1 04/03/19 17:20 04/09/19 14:46 319-84-6 1p beta-BHC 0.0077 U ug/L 0.0097 0.0077 1 04/03/19 17:20 04/09/19 14:46 319-85-7 1p delta-BHC 0.0046 U ug/L 0.0097 0.0046 1 04/03/19 17:20 04/09/19 14:46 319-86-8 1p gamma-BHC (Lindane) 0.0021 U ug/L 0.0097 0.0021 1 04/03/19 17:20 04/09/19 14:46 58-89-9 1p Chlordane (Technical) 0.17 U ug/L 0.48 0.17 1 04/03/19 17:20 04/09/19 14:46 57-74-9 1p 4,4'-DDD 0.0086 U ug/L 0.0097 0.0086 1 04/03/19 17:20 04/09/19 14:46 72-54-8 1p 4,4'-DDE 0.0048 U ug/L 0.0097 0.0048 1 04/03/19 17:20 04/09/19 14:46 72-55-9 1p 4,4'-DDT 0.0048 U ug/L 0.0097 0.0048 1 04/03/19 17:20 04/09/19 14:46 50-29-3 1p Dieldrin 0.0019 U ug/L 0.0097 0.0019 1 04/03/19 17:20 04/09/19 14:46 60-57-1 1p Endosulfan I 0.0049 U ug/L 0.0097 0.0049 1 04/03/19 17:20 04/09/19 14:46 959-98-8 1p Endosulfan II 0.0039 U ug/L 0.0097 0.0039 1 04/03/19 17:20 04/09/19 14:46 33213-65-9 1p Endosulfan sulfate 0.0060 U ug/L 0.097 0.0060 1 04/03/19 17:20 04/09/19 14:46 1031-07-8 1p Endrin 0.0042 U ug/L 0.0097 0.0042 1 04/03/19 17:20 04/09/19 14:46 72-20-8 1p Endrin aldehyde 0.0035 U ug/L 0.097 0.0035 1 04/03/19 17:20 04/09/19 14:46 7421-93-4 1p Endrin ketone 0.0048 U ug/L 0.0097 0.0048 1 04/03/19 17:20 04/09/19 14:46 53494-70-5 1p Heptachlor 0.0060 U ug/L 0.0097 0.0060 1 04/03/19 17:20 04/09/19 14:46 76-44-8 1p Heptachlor epoxide 0.0050 U ug/L 0.0097 0.0050 1 04/03/19 17:20 04/09/19 14:46 1024-57-3 1p Methoxychlor 0.0093 U ug/L 0.0097 0.0093 1 04/03/19 17:20 04/09/19 14:46 72-43-5 1p Toxaphene 0.24 U ug/L 0.48 0.24 1 04/03/19 17:20 04/09/19 14:46 8001-35-2 1p Surrogates Tetrachloro-m-xylene (S) 60 % 27-124 1 04/03/19 17:20 04/09/19 14:46 877-09-8 Decachlorobiphenyl (S) 42 % 10-132 1 04/03/19 17:20 04/09/19 14:46 2051-24-3 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Arsenic 7.1 U ug/L 10.0 7.1 1 04/03/19 07:51 04/03/19 16:37 7440-38-2 Barium 88.3 ug/L 10.0 0.84 1 04/03/19 07:51 04/03/19 16:37 7440-39-3 Iron 793 ug/L 40.0 9.2 1 04/03/19 07:51 04/03/19 16:37 7439-89-6 Lead 4.6 U ug/L 10.0 4.6 1 04/03/19 07:51 04/03/19 16:37 7439-92-1 Date: 04/11/2019 09:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 15 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457298 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 528000 Analysis Method: EPA 6010 QC Batch Method: EPA 3010 Analysis Description: 6010 MET Associated Lab Samples: 35457298001, 35457298002, 35457298003 METHOD BLANK: 2857698 Matrix: Water Associated Lab Samples: 35457298001, 35457298002, 35457298003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic ug/L 7.1 U 10.0 7.1 04/03/19 15:56 Barium ug/L 0.84 U 10.0 0.84 04/03/19 15:56 Iron ug/L 9.2 U 40.0 9.2 04/03/19 15:56 Lead ug/L 4.6 U 10.0 4.6 04/03/19 15:56 LABORATORY CONTROL SAMPLE: 2857699 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic ug/L 500 490 98 ,80-120 Barium ug/L 500 496 99 80-120 Iron ug/L 2000 2010 100 80-120 Lead ug/L 500 503 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2857700 2857701 MS MSD 35457297001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L 7.1 U 500 500 524 511 105 102 75-125 2 20 Barium ug/L 23.0 500 500 543 527 104 101 75-125 3 20 Iron ug/L 347 2000 2000 2320 2260 99 96 75-125 3 20 Lead ug/L 8.4 I 500 500 479 467 94 92 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/11/2019 09:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 15 aceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457298 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 528202 Analysis Method: EPA 8081 QC Batch Method: EPA 3510 Analysis Description: 8081 GCS Pesticides Associated Lab Samples: 35457298001, 35457298002, 35457298003 METHOD BLANK: 2858737 Matrix: Water Associated Lab Samples: 35457298001, 35457298002, 35457298003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 4,4'-DDD ug/L 0.0089 U 0.010 0.0089 04/09/19 11:33 CU 4,4'-DDE ug/L 0.0050 U 0.010 0.0050 04/09/19 11:33 4,4'-DDT ug/L 0.0050 U 0.010 0.0050 04/09/19 11:33 CU Aldrin ug/L 0.0015 U 0.010 0.0015 04/09/19 11:33 alpha-BHC ug/L 0.0021 U 0.010 0.0021 04/09/19 11:33 beta-BHC ug/L 0.0080 U 0.010 0.0080 04/09/19 11:33 Chlordane (Technical) ug/L 0.18 U 0.50 0.18 04/09/19 11:33 delta-BHC ug/L 0.0048 U 0.010 0.0048 04/09/19 11:33 Dieldrin ug/L 0.0020 U 0.010 0.0020 04/09/19 11:33 Endosulfan I ug/L 0.0051 U 0.010 0.0051 04/09/19 11:33 Endosulfan II ug/L 0.0040 U 0.010 0.0040 04/09/19 11:33 CU Endosulfan sulfate ug/L 0.0062 U 0.10 0.0062 04/09/19 11:33 CU Endrin ug/L 0.0043 U 0.010 0.0043 04/09/19 11:33 Endrin aldehyde ug/L 0.013 I 0.10 0.0036 04/09/19 11:33 CU Endrin ketone ug/L 0.0050 U 0.010 0.0050 04/09/19 11:33 CU gamma-BHC (Lindane) ug/L 0.0022 U 0.010 0.0022 04/09/19 11:33 Heptachlor ug/L 0.0062 U 0.010 0.0062 04/09/19 11:33 Heptachlor epoxide ug/L 0.0052 U 0.010 0.0052 04/09/19 11:33 Methoxychlor ug/L 0.0096 U 0.010 0.0096 04/09/19 11:33 CU Toxaphene ug/L 0.25 U 0.50 0.25 04/09/19 11:33 Decachlorobiphenyl (S) % 53 10-132 04/09/19 11:33 Tetrachloro-m-xylene (S) % 66 27-124 04/09/19 11:33 LABORATORY CONTROL SAMPLE & LCSD: 2858738 2858834 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers 4,4'-DDD ug/L 0.5 0.52 0.49 104 98 67-133 6 40 CH 4,4'-DDE ug/L 0.5 0.47 0.43 94 87 59-125 8 40 4,4'-DDT ug/L 0.5 0.57 0.52 113 104 54-132 8 40 CH Aldrin ug/L 0.5 0.31 0.30 63 60 25-116 5 40 alpha-BHC ug/L 0.5 0.50 0.46 100 92 53-126 9 40 beta-BHC ug/L 0.5 0.56 0.51 112 103 62-130 9 40 delta-BHC ug/L 0.5 0.25 0.23 50 47 35-122 6 40 Dieldrin ug/L 0.5 0.51 0.48 102 96 66-128 6 40 Endosulfan I ug/L 0.5 0.51 0.48 103 96 67-125 6 40 Endosulfan II ug/L 0.5 0.52 0.49 103 98 67-131 6 40 CH Endosulfan sulfate ug/L 0.5 0.54 0.51 108 102 62-127 6 40 CH Endrin ug/L 0.5 0.53 0.49 106 98 66-130 8 40 Endrin aldehyde ug/L 0.5 0.60 0.56 120 113 61-124 6 40 CH Endrin ketone ug/L 0.5 0.57 0.55 115 109 65-132 5 40 CH Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/11/2019 09:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 15 aceAnalAcal www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457298 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 LABORATORY CONTROL SAMPLE & LCSD: 2858738 2858834 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers gamma-BHC (Lindane) ug/L 0.5 0.53 0.48 106 96 58-127 10 40 Heptachlor ug/L 0.5 0.39 0.36 79 72 35-123 9 40 Heptachlor epoxide ug/L 0.5 0.51 0.47 102 95 62-125 7 40 Methoxychlor ug/L 0.5 0.56 0.52 111 105 59-135 6 40 CH Decachlorobiphenyl (S) % 48 56 10-132 Tetrachloro-m-xylene (S) % 77 70 27-124 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/11/2019 09:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 15 ceAnalytical® wwwpacelabs.com QUALIFIERS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457298 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: 528202 [M5] A matrix spike/matrix spike duplicate was not performed for this batch due to insufficient sample volume. ANALYTE QUALIFIERS The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. U Compound was analyzed for but not detected. 1 p A matrix spike/matrix spike duplicate was not performed for this batch due to insufficient sample volume. CH The continuing calibration for this compound is outside of Pace Analytical acceptance limits. The results may be biased high. CU The continuing calibration for this analyte is above laboratory acceptance limits. Analyte was not detected above the reporting limit in any of the associated samples. Date: 04/11/2019 09:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 15 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melreese Golf Course Pace Project No.: 35457298 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 35457298001 MW-6 EPA 3510 528202 EPA 8081 529083 35457298002 MW-7 EPA 3510 528202 EPA 8081 529083 35457298003 MW-8 EPA 3510 528202 EPA 8081 529083 35457298001 MW-6 EPA 3010 528000 EPA 6010 528101 35457298002 MW-7 EPA 3010 528000 EPA 6010 528101 35457298003 MW-8 EPA 3010 528000 EPA 6010 528101 Date: 04/11/2019 09:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 15 - PaceAnalytical www.pacelabs.com WOC35457298 IIIIIIIIIII IIIIIIIIIII Company Name: PO# Address: { �' ..', r L City: I"t , ' ��; !' State: C Zip: P Attn:c L . ( \!'\,tall �1 Fax# Sample Phone: Project Name Sampler y r . / J cie One Event: Daily Weekly Monthly Signature �y a'L ` , Quartely Semi -Annual Annual N/A Sample ID a) co E 1 2 3 4 5 6 7 9 10 Item 1 3 4 Collect Collect Matrix Date Time Code^ .177 Zi lai 32 it li lc 447 c0 O re at c To" 19 g TRC pH CORD Page of Pres Codes c� n r LAB ANALYSIS n # of Containers Size/Type 1 �— 16ozP to Container Type Codes AV Amber Vl:,i ES Encore S.•,u:lr, CV Clo:,( Vial PPV Purple:.,nv,.), vial P Plastic PL C Plastic manner Al_ Ambe, Liter PL J Plastic Jar CL Clear Cher Z Ziploc ban AP Amhe•r Plastic TB Tedlar bag AG Anther Cale:::. WP Whin oak SI Soil J.,, G Gallon Jug Other IC Tean.co,e PPV Pr, pmsmvmi vm1 Si.** 2os. 'Ic,z, But, I60z. 32os or 1L. other 40m1 500rn1 250m1 125 m1 Ezamplo: 4ozP = 4oz Plastic, 8ozSJ= Itoz Soil Jar 0) ca D.. Matrix Codes SD Solid Waste GW Cround Winer EFF Ellluenl AFW Analyh• Fs® H2O WIN Wa:ae Water DW Dnrlklnt) Winer SW Surl.,ce Wale ML Max 1agonl OL 011 SL Sludge) SO Soil Sediment AO Aqueous NA Non:ottom n. PE Petroleum, 0 Other Preservative Type Codes A. None E. HCL B. HNO3 F. McOH C. H2SO4 G. Na2S2O3 D. NaOH H. NaHSO4 I. Ice J. MCAA K. Zn Acetate O. Other II n T.A.T REQUEST IRu1, ret, Approved) `i'"'I RUSH Today ID 21) 3D .1D Reli . uished b Pompano Lab 954-582-4300 Y Short Hold N Affiliation ❑ n II u n n ❑ El u II l REMARKS Circle QA/QC Report Level 1 2 3 4 CLP AFCEE QAPP Other Date 3I2 Revision: F•ALL•C•007- Rev.00 q Time EDD (Fees May Apply) ADaPT SEDD ERPIMS TSV CSV Other Received by S '417-- ffiliation COC Condition OK hicomplel,: Date, 7 It 4t /)k Required Stale Certification FL GA SC NC NJ PA LA TX IL __ Time Coolers #'s - Temp °C 1 342'2_ 3_ 4_ 5 Non-Conlormanee Found, Samples INTAC 1 ulaa, arnvaP Received on Wel lee^ Pruper Prenervahves In,llc.ro•d^ Ruce,v,nl will,,,, holdnyl 1im,.^ Custaly seal, Intact, Voktlne:. ,edit w,lheul Io'.,d:.p.,c,•^ Proi>•,r Cnel.en,,,., lla,vl'• C.O.C. Serial # 125978 �/"y -F' eAna/ytiCa/ Document Name Sample Conoc d:on Upon Rece,' -or m Document Revised May 30 2018 Document No F-Ft .r-nnV -- Issuing Authority Pace Florida Quanty Office Proje p77 CTR Project Manac CLIENT: 35"EEG Cliet Thermometer Used State of Origin Cooler #1 Temp.' ° !/ (Visual) Q' . 0 (Correction Factor) ° 2 (Actual) Cooler#2 Temp.`C (Visual) (Correction Factor) (Actual) Cooler#3 Temp.°C (Visual) (Correction Factor) (Actual) Cooler #4 Temp.'C (Visual) (Correction Factor) (Actual) Cooler#5 Temp.`C (Visual) (Correction Factor) (Actual) Cooler #6 Temp.'C (Visual) (Correction Factor) (Actual) WO## : 354572�$ 04/04/19 Due Date: Courier: [ Fed Ex ] UPS ❑ USPS — Client (_ Commercial Pace Shipping Method: = First Overnight - Priority Overnight = Standard Overnight E Ground = Other Billing: = Recipient E. Sender = Third Party = Credit Card Tracking # / L Custody Seal on Cooler/Box Present: Yes I Mo Seals intact: 7 Yes o Packing Material: EBubble Wrap ❑ Bubble Bags LNone ❑Other Samples shorted to lab (If Yes, complete) Shorted Date' Comments: ,orm (SCUR) Date and Initials of person: Examining contents: Label: Deliver: pH: Time:/)9 ❑ For VA/ protects, all containers verified to 56 `C I s ials G Sampies on cooling process has begun L. Samples or ice, cooling process has begun C Samples on ice, cooling process has begun Samples on ice, cooling process has begun E Samples on ice cooling process has begun C Samples on ice, cooling process has beaun Other E. International Priority E. Unknown Ice: Shorted Time Blue Dry None Qty Chain of Custody Present —7,Sfes - No EN/A Chain of Custody Filled Out _Yes E. No _N/A Relinquished Signature & Sampler Name COC E No =N/A Samples Arrived within Hold Time !Yes - No EN/A Rush TAT requested on COC /No LN/A Sufficient Volume ��Yes i es _ No EN/A Correct Containers Used ZYes L No EN/A Containers Intact fires = No El N/A Sample Labels rnatch COC (sample IDs & date/time of collection) 24es E. No EN/A. All containers needing acid/base preservation nave been _ checked eS All Containers needing preservation are found to be in compliance with EPA recommendation - es Exceptions VOA Colrform, TOC, O&G. Carbamates _ No =N/A = No =N/A Preservation Iniormat on Preservative Lot #/Trace # Date Time Initials Headspace in VOA Vials? ( >6mm) E. % E No J N/A Trip Blank Present: =Yes = NoA Client Notification/ Resolution: Person Contacted Comments/ Resolution (use back for additional comments): Date/Time Protect Manager Review Date Page 15 of 15 aceAnalytical wwwpacelabs.com April 15, 2019 Craig Clevenger EE&G Environmental Services, LLC 5751 Miami Lakes Drive East Miami Lakes, FL 33014 RE: Project: 2018-3057/Melreese Golf Course Pace Project No.: 35460158 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach. FL 33064 954-582-4300 Dear Craig Clevenger: Enclosed are the analytical results for sample(s) received by the laboratory on April 09, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, h 2 J2 -. Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Michael Van Ry. EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. without the written consent of Pace Analytical Services, LLC. Page 1 of 13 79aceAnalytical® www.pacelabs.com CERTIFICATIONS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35460158 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alaska DEC- CS/UST/LUST Alabama Certification #: 41320 Arizona Certification# AZ0819 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 13 aceAnalytical c www.pacelabs.com SAMPLE SUMMARY Project: 2018-3057/Melreese Golf Course Pace Project No.: 35460158 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach. FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35460158001 MW-10 Water 04/09/1910:05 04/09/19 13:45 35460158002 MW-11 Water 04/09/19 11:04 04/09/19 13:45 35460158003 MW-12 Water 04/09/1911:56 04/09/1913:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. without the written consent of Pace Analytical Services, LLC. Page 3 of 13 aceAnalytical www.pacelabs.com SAMPLE ANALYTE COUNT Project: 2018-3057/Melreese Golf Course Pace Project No.: 35460158 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35460158001 MW-10 EPA6010 SC1 3 PASI-O 35460158002 MW-11 EPA 6010 SC1 3 PASI-O 35460158003 MW-12 EPA 6010 SC1 3 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 13 Analytical wwwpacelabs.car, SUMMARY OF DETECTION Project: 2018-3057/Melreese Golf Course Pace Project No.: 35460158 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35460158001 MW-10 EPA 6010 Arsenic 9.5 I ug/L 10.0 04/12/19 16:56 EPA 6010 Iron 1060 ug/L 40.0 04/12/19 16:56 35460158002 MW-11 EPA 6010 Iron 842 ug/L 40.0 04/12/19 17:08 35460158003 MW-12 EPA 6010 Iron 427 ug/L 40.0 04/12/19 17:12 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 13 ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35460158 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-10 Lab ID: 35460158001 Collected: 04/09/19 10:05 Received: 04/09/19 13:45 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Arsenic 9.5 I ug/L 10.0 7.1 1 04/11/19 03:53 04/12/19 16:56 7440-38-2 Iron 1060 ug/L 40.0 9.2 1 04/11/19 03:53 04/12/19 16:56 7439-89-6 Lead 4.6 U ug/L 10.0 4.6 1 04/11/19 03:53 04/12/19 16:56 7439-92-1 Date: 04/15/2019 11:38 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 13 www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35460158 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-11 Lab ID: 35460158002 Collected: 04/09/19 11:04 Received: 04/09/19 13:45 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Arsenic 7.1 U ug/L 10.0 7.1 1 04/11/19 03:53 04/12/19 17:08 7440-38-2 Iron 842 ug/L 40.0 9.2 1 04/11/19 03:53 04/12/19 17:08 7439-89-6 Lead 4.6 U ug/L 10.0 4.6 1 04/11/19 03:53 04/12/19 17:08 7439-92-1 Date: 04/15/2019 11:38 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 13 aceAnalytical www.pace/abs.com ANALYTICAL RESULTS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35460158 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-12 Lab ID: 35460158003 Collected: 04/09/19 11:56 Received: 04/09/19 13:45 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Arsenic 7.1 U ug/L 10.0 7.1 1 04/11/19 03:53 04/12/19 17:12 7440-38-2 Iron 427 ug/L 40.0 9.2 1 04/11/19 03:53 04/12/19 17:12 7439-89-6 Lead 4.6 U ug/L 10.0 4.6 1 04/11/19 03:53 04/12/19 17:12 7439-92-1 Date: 04/15/2019 11:38 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 13 wvnv.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/Melreese Golf Course Pace Project No.: 35460158 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 530129 Analysis Method: EPA 6010 QC Batch Method: EPA 3010 Analysis Description: 6010 MET Associated Lab Samples: 35460158001, 35460158002, 35460158003 METHOD BLANK: 2870377 Matrix: Water Associated Lab Samples: 35460158001, 35460158002, 35460158003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic ug/L 7.1 U 10.0 7.1 04/12/1916:21 Iron ug/L 9.2 U 40.0 9.2 04/12/19 16:21 Lead ug/L 4.6 U 10.0 4.6 04/12/19 16:21 LABORATORY CONTROL SAMPLE: 2870378 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic ug/L 250 248 99 80-120 Iron ug/L 2500 2520 101 80-120 Lead ug/L 250 259 103 80-120 'ATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2870379 2870380 MS MSD 35459733002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L 7.1 U 250 250 248 247 98 98 75-125 0 20 Iron ug/L 3770 2500 2500 6060 6130 92 95 75-125 1 20 Lead ug/L 4.6 U 250 250 255 250 101 100 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/15/2019 11:38 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 13 its%eAnalytical www.pacelabs.com QUALIFIERS Project: 2018-3057/Melreese Golf Course Pace Project No.: 35460158 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL- Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. Compound was analyzed for but not detected. Date: 04/15/2019 11:38 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 13 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/Melreese Golf Course Pace Project No.: 35460158 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 35460158001 MW-10 EPA 3010 530129 EPA 6010 530145 35460158002 MW-11 EPA 3010 530129 EPA 6010 530145 35460158003 MW-12 EPA 3010 530129 EPA 6010 530145 Date: 04/15/2019 11:38 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC- Page 11 of 13 P1"Card:4,o! WO#:35460158 -"'cal Request Document .11 relevant fields must be completed accurately. Section A Section B Required Client Information: Required Project In 1111 111 0158 a,..., I'I _ 1 I Page - Of Company EE&G Environmental Services. LLC Report To Michael Address: 5751 Miami Lakes Dr. Copy To - Miami Lakes. FL 33014 Address Regulatory Agency Email. illvanry@eeando.corii Purchase Order 4 Pace Quote. Phone 305-374-8300 IFax Project Name: A*- i �i.;,,,- G. Pace Project Manager. State 1 Location Requested Due Date. �-;.,, ,,,,r'„t-c-i Project 11 I.ci ' `{ - 7 , , Pace Profile 4 FL Requested Analysis Fil ered (Y/N) Xtt tu ~ MATRIX coot. Minkel!) Wale! Dw Water WT Waste Water Ww P,odvct P SAMPLE ID Sod/Sold OJ sL OL One Character per box. WT.!wP (A-Z, 0-9 / , •) A,r AR Sample Ids must be unique Met or q ru.. Ts MATRIX CODE (see valid codes to IeR) SAMPLE TYPE (G=GRAB C=COMP) COLLECTED SAMPLE TEMP AT COLLECTION X OF CONTAINERS Preservatives 2 5: START END Unpreserved ' S HCI NaOH Na2S2O3 Methanol Olher Analyses Test L` — .- x = Residual Chlorine (Y/N) DATE TIME DATE TIME 1 • �� �! iJ wr j! ;z`, i 7 X. it =jrcll r ve 2 /den\N - )i 1 jiC`-t ` ,\ c; O,55, /5, I<, [1) 3 W 1. 15(, _ 2 A i--7,-,:,c ,,,i 7.4.,,,i•,.. i 4 5 6 7 9 10 11 12 ADDITIONAL COMMENTS RELINQUISHED BY I AFFILIATION DATE TIME ACCEPTED BY I AFFILIATio DATE TIME SAMPLE CONDITIONS . _ G ;i I h .. — �,� ,/ / / SAMPLER NAME AND SIGNATURE / ITEMP in C 0 v Z usto y Sealed Cooler YIN a E Z PRINT Name of SAMPLER: If I �SU%5=_S�� t {rtn;.oct'z SIGNATURE of SAMPLER: / v 1 DATE Signed: csi CD) CO elk f.icrtitrr. /.17ical WO# : 35460158 fs UR) PM: CTR Project #CLIENT: 36-EEG Project Manager: Client: Thermometer Usec Due Date: 04/15/19 Date y;'0 '4 Time /a Pace ce Date and Initials of person: Examining contents: Label: Deliver: pH: Stale of Ongm _ -c• .e._ ::::-:a e. _ ._ e.... .. Cooler #1 Temp.'C �.-,.,. 'j 3 (Visual) ' U (Correction Factor) /1 i .3 (Actual) Cooler #2 Temp.'C (Visual) (Correction Factor) (Actual) Cooler #3 Temp.'C (Visual) (Correction Factor) (Actual) Cooler#4 Temp.`C (Visual) (Correction Factor) (Actual) Cooler #5 Temp.'C (Visual) (Correction Factor) (Actual) Cooler #6 Temp.`C (Visual) (Correction Factor) (Actual) Courier: — Fed Ex — UPS USPS — Client — Commercial I Pace Initial L Sa._ es :., to _.... _ o:.ess .•2s cep Say -..es cr _e .,_ ocess ! Saes or .ce cco •'es S --c es c .._ coo ,ocess • es tea4^ Sa_ .es o -g Other Shipping Method: First Overnight Priority Overnight Standard Overnight Ground Internatio'.al Priority Other Billing: Recipient Sender Third Party Credit Card Unknown Tracking # Custody Seal on Cooler/Box Present: _Yes /No Seals intact: _ Yes /No Ice: We Blue Dry None Packing Material: —Bubble Wrap Bubble Bags None _ Other Samples shorted to lab (If Yes, complete) Shorted Date Comments: Shorted Time Oty Chain of Custody Present 'Yes No N A Chain of Custody Filled Out I Yes No NSA Relinquished Signature & Sampler Name COC es :: No .N.A Samples Arrived within Hold Time ,,:Yes . _-N.'A Rush TAT requested on COC Yes /No / No NSA Sufficient Volume _;Yes No . N A Correct Containers Used -`Yes _- No _ NSA Containers Intact -. Yes No N'A S_•-ce_ace sr-a::-CC.,'sam.._• srsc_te: cc _.... •Yes No N.A A CC , -:a. _ eac acc Lase o'eser;a:v _.e. tee „ e;7<eo _Yes - -. _.. :a c.. e.e... ."ese. a:c c c o.. ..:,...e _. .. a-:::,-.... :__- e.::._ _a:3- .....'es cx�.2_.., s .7.,., •.. -..: =,&7; J....,..^a:es No N A No N A P'eseva... -•asa'va: •:e .. a:•_ Lot s-r a:e# _ate -„-e Headspace in VOA Vials"' i >6mmi Yes No -'N,A Trip Blank Present Yes No N-H. Client Notification/ Resolution: Person Contacted Comments/ Resolution (use back for additional comments): Date Time Project Manager Review Date Page 13 of 13 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach. FL 33064 954-582-4300 April 17, 2019 Thuysi Ho EE&G Environmental Services, LLC 5751 Miami Lakes Dr. Hialeah, FL 33014 RE: Project: 2018-3057/1802 NW 37 Ave Miami -Revised Report Pace Project No.: 35460143 Dear Thuysi Ho: Enclosed are the analytical results for sample(s) received by the laboratory on April 09, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. This is a revised report. Dissolved Arsenic and Iron have been added. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Craig Clevenger, EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 12 vonv.pacelabs.co,m CERTIFICATIONS Project: 2018-3057/1802 NW 37 Ave Miami -Revised Report Pace Project No.: 35460143 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alaska DEC- CS/UST/LUST Alabama Certification #: 41320 Arizona Certification# AZ0819 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 12 aceAnalytical® www.pacelabs.com SAMPLE SUMMARY Project: 2018-3057/1802 NW 37 Ave Miami -Revised Report Pace Project No.. 35460143 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35460143001 MW-2 Water 04/08/19 10:40 04/09/19 15:00 REPORT OF LABORATORY ANALYSIS This report shall riot be reproduced. except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 12 _ aceAnalytical www.pacelabs.com SAMPLE ANALYTE COUNT Project: 2018-3057/1802 NW 37 Ave Miami -Revised Report Pace Project No.: 35460143 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35460143001 MW-2 EPA 6010 SC1 2 PASI-O EPA6010 JWP 2 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 12 aceAnalytical , wvilv.pacelabs.co.T SUMMARY OF DETECTION Project: 2018-3057/1802 NW 37 Ave Miami -Revised Report Pace Project No.: 35460143 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35460143001 MW-2 EPA 6010 Arsenic 20.9 ug/L 10.0 04/12/19 16:52 EPA 6010 Iron 1600 ug/L 40.0 04/12/19 16:52 EPA 6010 Arsenic, Dissolved 20.1 ug/L 10.0 04/16/19 17:55 EPA 6010 Iron, Dissolved 1370 ug/L 40.0 04/16/19 17:55 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 12 aceAnalytical® www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/1802 NW 37 Ave Miami -Revised Report Pace Project No.: 35460143 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-2 Lab ID: 35460143001 Collected: 04/08/19 10:40 Received: 04/09/19 15:00 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3010 Arsenic 20.9 ug/L Iron 1600 ug/L 10.0 7.1 1 04/11/19 03:53 04/12/19 16:52 7440-38-2 40.0 9.2 1 04/11/19 03:53 04/12/19 16:52 7439-89-6 6010 MET ICP, Dissolved Analytical Method: EPA 6010 Preparation Method: EPA 3010 Arsenic, Dissolved Iron, Dissolved Date: 04/17/2019 10:48 AM 20.1 ug/L 1370 ug/L 10.0 7.1 1 04/15/19 10:59 04/16/19 17:55 7440-38-2 40.0 9.2 1 04/15/19 10:59 04/16/19 17:55 7439-89-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 12 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/1802 NW 37 Ave Miami -Revised Report Pace Project No.: 35460143 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 530129 Analysis Method: EPA 6010 QC Batch Method: EPA 3010 Analysis Description: 6010 MET Associated Lab Samples: 35460143001 METHOD BLANK: 2870377 Matrix: Water Associated Lab Samples: 35460143001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic ug/L 7.1 U 10.0 Iron ug/L 9.2 U 40.0 7.1 04/12/19 16:21 9.2 04/12/1916:21 LABORATORY CONTROL SAMPLE: 2870378 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic ug/L 250 248 99 80-120 Iron ug/L 2500 2520 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2870379 2870380 MS MSD 35459733002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L 7.1 U 250 250 248 247 98 98 75-125 0 20 Iron ug/L 3770 2500 2500 6060 6130 92 95 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/17/2019 10:48AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 12 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/1802 NW 37 Ave Miami -Revised Report Pace Project No.: 35460143 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 531021 Analysis Method: EPA 6010 QC Batch Method: EPA 3010 Analysis Description: 6010 MET Filtered Diss. Associated Lab Samples: 35460143001 METHOD BLANK: 2876069 Matrix: Water Associated Lab Samples: 35460143001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic, Dissolved Iron, Dissolved ug/L 7.1 U 10.0 ug/L 9.2 U 40.0 7.1 04/16/19 17:49 9.2 04/16/19 17:49 LABORATORY CONTROL SAMPLE: 2876070 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic, Dissolved Iron, Dissolved ug/L 250 235 94 80-120 ug/L 2500 2600 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2876071 2876072 MS MSD 35460143001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic, Dissolved Iron, Dissolved ug/L 20.1 250 250 254 254 93 94 75-125 0 20 ug/L 1370 2500 2500 4000 4030 105 106 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. Date: 04/17/2019 10:48 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 12 ace Analytical vrrnv.pacelabs.com QUALIFIERS Project. 2018-3057/1802 NW 37 Ave Miami -Revised Report Pace Project No.: 35460143 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS U Compound was analyzed for but not detected. Date: 04/17/2019 10:48 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 12 /12eAnalytical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/1802 NW 37 Ave Miami -Revised Report Pace Project No.: 35460143 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID QC Batch Method Analytical QC Batch Analytical Method Batch 35460143001 MW-2 35460143001 MW-2 Date: 04/17/2019 10:48AM EPA 3010 530129 EPA 6010 530145 EPA 3010 531021 EPA 6010 531095 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 12 WO#:35460143 raceluaryucn 1111 I III II II II I1I II III vant fields must be completed accurately Section A Section B 35460143 Required Client Information: Required Project Information: Page : ! Of 1 Company EE&G Environmental Services, LLC Report To Thuysi Ho Attention Address 5751 Miami Lakes Dr. Copy To Company Name Hialeah. FL 33014 Address Regulatory Agency Email tho@eeandg. com Purchase Order :Y Pace Quote Phone (305)374-8300 Fax Project Narne. 1802 NW 37 Ave Miami Pace Pmiact Manager 9 cnnstinaraschke(d?pacelabs.corn. Stater Location Requested Due Date. Project #: 2018-3057 Pace Pictde # FL Requested Analysis Filtered MATRIX cone f.1ATRIX CODE (see :and codes to left) SAMPLE TYPE (G=GRAB C=COMP) COLLECTED SAMPLE TEMP AT COLLECTION If OF CONTAINERS Preservatives Z i- Dnnhmp WOdi DW W:,,r, WT W.,.li Wur�WW Product Soil/Soled sL SAMPLE ID S on 01 START END Unpreserved HNO3 Methanol Analyses Test (Z - Q o tD t. y�y 4 V+ Residual Chlorine (YIN) ~ One Character per box. Wien WPifi (A-Z, 0-9/ , -) A, AR Sample Ids must be unique Ti5tu� er Ts DATE TIME DATE TIME a. x x z" O N z O 1 w z Vic 21l5ll9 ie _— ? a ttrcti.ve 2 55. A) El -Fe 3 1'Cu Se { TH,mf 4 5 6 - 7 8 9 10 11 12 ADDmONAL COMMENTS RELINQUISHED BY/AFFILIATION DATE TIME ACCEPTED BY/AFFILIATION �/ t DATE t TIME SAMPLE CONDITIONS P7A/L-- y / wI ( 2-0 f SAMPLER NAME AND SIGNATURE TEMP in C Received on Ice (Y/N) Custody Sealed Cooler (Y/N) 0 a u _Z PRINT Name of SAMPLER: 7 / R. ✓;5t� l -ex , 14 p 7 SIGNATURE of SAMPLER: / �1/I 4,1 I DATE Signed: l 1 oren, _.,se.. May 3=• 201 Cooler #1 Temp.'C Cooler #2 Temp.'C Cooler #3 Temp.'C Cooler #4 Temp.'C Cooler tr5 Temp.'C Cooler #6 Temp.'C rce.4; ?.3/}.lieu: Issuwng Autnonry Pace Flonaa Qualdy Office MMIIIIMMMIRW# Project PM: CTR Project ManageI LIENT: 36-EEG Client. _rn 3rne e Sea 7- f Q Scale of :;r:g•n y.3 Due Date: 04/13/19 Date Date and Initials of person: Examining contents: Label: Deliver: pH: Time ./ 7/ Z. (Visual) C. 0 (Correction Factor) II. 3 (Actual) (Visual) (Correction Factor) (Actual) (Visual) (Correction Factor) (Actual) (Visual) (Correction Factor) (Actual) (Visual) (Correction Factor) (Actual) (Visual) (Correction Factor) (Actual) UPS Courier: — Fed Ex U S Shipping Method: : curs',Ove-n-g^t Other Billing: - Recap.ent 7 Seneer Tracking P — Ghent — C r _ a a; P c,e an:on:y Overn.Ohr L n L_ Sa''p'es e, _ooi.'g process "as --_ S_r_oes o^ ,ce cooling process nas ceg Sa-lo.es Cr ,Ce C,00lmc process ^as cey^u- Samples on ce. coo:mg process nas oe_.,- Sa'nptes or .ce. coohng process nas Samples on .,c„ coohng orccess nas ^e: , Other i nterna!;ona! Pnon.y UnknOwn Custody Seal on Cooler/Box Present: _'YeS Packing Material:—Buoble `. •"ra;:n Bjoble Sacs --._None Samples shorted to lab (If Yes: complete) Shorted Date Seals intact: _ Yes /NO Ice vVet 3'ce Dry None L Other Snorted Time -_;ca;r C -..s:o"Y "2e ent G — NO _'N .. -- t_- na." _.5:00', _ "Ieo Out ie's _J"$s _ NO _ N.A Kehnqwsneo Stgnaiure & Sar',p,er Na-ne ..l. J �..Ves _ No —N..1 Sa'^cles .,.r..vea :Vltrnr Hc.ic -rrf,e /es —/NC _N,r, R,;st- _ .- •eeuested or; cc:: Yes 7No 'N.:, _ . .:.k.me 7Yes _ No -N. .^. ..orrec! C:r:ainers Usea veC — NO — ' C crota• e s ^tac! /Yes _ No -N _. : ices I_`i= —N _7-13- eett rC a_....._S=Vase.'.a. _.._.. ,3.. /'NI --ese-.a:.3n.r t=.._a:- I Ghent Notit cationi Resolution ^ntac: Comments. Resolution (use back for additional comments): a:= Page 12 of 12 aceAnalytical www.pacelabs.com April 17, 2019 Thuysi Ho EE&G Environmental Services, LLC 5751 Miami Lakes Dr. Hialeah, FL 33014 RE: Project: 2018-3057/1802 NW 37 Ave Miami -Revised Report Pace Project No.: 35460147 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Dear Thuysi Ho: Enclosed are the analytical results for sample(s) received by the laboratory on April 09, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. This is a revised report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Christina Raschke christina.raschke@pacelabs.com (954)582-4300 Project Manager Enclosures cc: Craig Clevenger, EE&G Environmental Services, LLC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 13 aceAnalytical www.pacelabs.com CERTIFICATIONS Project: 2018-3057/1802 NW 37 Ave Miami -Revised Report Pace Project No.: 35460147 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Ormond Beach Certification Ds 8 East Tower Circle, Ormond Beach, FL 32174 Alaska DEC- CS/UST/LUST Alabama Certification #: 41320 Arizona Certification# AZ0819 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Ceti 0074 Nebraska Certification: NE-OS-28-14 New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 13 aceAnalytical wwwpacelabs.com SAMPLE SUMMARY Project 2018-3057/1802 NW 37 Ave Miami -Revised Report Pace Project No.: 35460147 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Matrix Date Collected Date Received 35460147001 MIN-5 Water 04/08/19 14:20 04/09/1915:00 35460147002 MW-9 Water 04/08/19 13:10 04/09/19 15:00 35460147003 MW-38 Water 04/08/19 12:00 04/09/19 15:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 13 aceAnalytical www.pacelabs.com SAMPLE ANALYTE COUNT Project: 2018-3057/1802 NW 37 Ave Miami -Revised Report Pace Project No.: 35460147 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab ID Sample ID Method Analytes Analysts Reported Laboratory 35460147001 MW-5 EPA6010 SC1 1 PASI-O 35460147002 MW-9 EPA6010 SC1 1 PASI-O 35460147003 MW-38 EPA6010 SC1 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 13 aceAnalytical o wwwpacelabs.com SUMMARY OF DETECTION Project: 2018-3057/1802 NW 37 Ave Miami -Revised Report Pace Project No.: 35460147 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 35460147001 MW-5 EPA6010 Iron 2560 ug/L 40.0 04/10/19 12:23 35460147002 MW-9 EPA 6010 Iron 1750 ug/L 40.0 04/10/19 12:26 35460147003 MW-38 EPA 6010 Iron 2000 ug/L 40.0 04/10/19 12:34 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 13 7eAna/yticaI www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/1802 NW 37 Ave Miami -Revised Report Pace Project No.: 35460147 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-5 Lab ID: 35460147001 Collected: 04/08/19 14:20 Received: 04/09/19 15:00 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3010 Iron Date: 04/17/2019 06:36 PM 2560 ug/L 40.0 9.2 1 04/10/19 04:47 04/10/19 12:23 7439-89-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 13 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/1802 NW 37 Ave Miami -Revised Report Pace Project No.: 35460147 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-9 Lab ID: 35460147002 Collected: 04/08/19 13:10 Received: 04/09/19 15:00 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3010 Iron 1750 ug/L 40.0 9.2 1 04/10/19 04:47 04/10/19 12:26 7439-89-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/17/2019 06:36 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 13 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: 2018-3057/1802 NW 37 Ave Miami -Revised Report Pace Project No.: 35460147 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Sample: MW-38 Lab ID: 35460147003 Collected: 04/08/19 12:00 Received: 04/09/19 15:00 Matrix: Water Parameters Results Units PQL MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA6010 Preparation Method: EPA3010 Iron Date: 04/17/2019 06:36 PM 2000 ug/L 40.0 9.2 1 04/10/19 04:47 04/10/19 12:34 7439-89-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 13 aceAnalytical® www.pacelabs.com QUALITY CONTROL DATA Project: 2018-3057/1802 NW 37 Ave Miami -Revised Report Pace Project No.: 35460147 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 QC Batch: 529756 Analysis Method: EPA 6010 QC Batch Method: EPA 3010 Analysis Description: 6010 MET Associated Lab Samples: 35460147001, 35460147002, 35460147003 METHOD BLANK: 2868353 Matrix: Water Associated Lab Samples: 35460147001, 35460147002, 35460147003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Iron ug/L 9.2 U 40.0 9.2 04/10/19 11:14 LABORATORY CONTROL SAMPLE: 2868354 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Iron ug/L 2500 2620 105 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2868355 2868356 MS MSD 35459117001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Dn ug/L 1.1 mg/L 2500 2500 3710 3720 104 104 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 04/17/2019 06:36 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 13 /2aceAnalytical® www.pacelabs.com QUALIFIERS Project: 2018-3057/1802 NW 37 Ave Miami -Revised Report Pace Project No.: 35460147 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS U Compound was analyzed for but not detected. Date: 04/17/2019 06:36 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 13 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: 2018-3057/1802 NW 37 Ave Miami -Revised Report Pace Project No.: 35460147 Pace Analytical Services, LLC 3610 Park Central Blvd N Pompano Beach, FL 33064 954-582-4300 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 35460147001 MW-5 EPA 3010 529756 EPA 6010 529761 35460147002 MW-9 EPA 3010 529756 EPA 6010 529761 35460147003 MW-38 EPA 3010 529756 EPA 6010 529761 Date: 04/17/2019 06:36 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 13 " Mallirral WO#:35-40147 [�(IIIIIIIIIIIIIIIIIII Document must be completed accurately. Section A Section B J5460147III Required Client Information: Required Project Information: Page : 1 Of Company EEAG Environmental Services, LLC Report To Thuysi Ho Attention Address. 5751 Miami Lakes Dr Copy to Compzny Name --1 Hialeah, FL 33014 Address Regulatory Agency Email tho@eeandg com Purchase Order #. Pace Ocole Phone (305)374-8300 JFax Pro(ect Name 1802 NW 37 Ave Miami Pace Pr,iect Manager chnstina raschke@pacdlabs cam. State 1 Location Requested Due Dale Project #: 2018-3057 Pare Profile # FL Recl..ee:ted Aa rIysia -i1 C u,i iY: I) Mnirxix coot MATRIX CODE (see valid codes to left) SAMPLE TYPE (G=GRAB C=COMP) COLLECTED SAMPLE TEMP AT COLLECTION # OF CONTAINERS Preservatives Z >- Dunking W. DW Water WI Wale Wnlet WIN SAMPLE ID So Solid S. Oil OE. START END LUnpreserved HNO3 [Na2S203 l Methanol Other Analyses Test u up `� Q Zi- > o U(A-Z, m oO m cc #ot W 1— One Character per box. Wipe WP Air AR 0.9 I , -) Sample Ids must be unique Ti:.,un 15 DATE TIME DATE TIME to _ = 1 0 z 1 71rl w- 5 w s 1/ J)9 1420 2. 2 X A * A(C,1% r v -e 2 / \ 1/,/ - i3i0 2 2 )\ A 0,55• lVJn 4 5 g 7 8 9 10 11 12 ADDITIONAL COMMENTS RELINQUISHED BY I AFFILIATION DATE TIME ACCEPTED BY/AFFILIATION I DATE{ TIME SAMPLE CONDITIONS SAMPLER NAME AND SIGNATURE TEMP in C Received on Ice (Y/N) usto y Sealed Cooler (Y/N) 2SIGNATURE ig ? v3 c pp PRINT Name of SAMPLER: Jy��.,�� iZirVla>.n,� of SAMPLER: Akt... "J„�� rY'fl DATE Signed: 4 / i la _l/ Page 12 of 13 Cooler X1 Temp.'C I Project # Project Manager: Client: Tnerrorreter'Used Stale C;rigin .3 W0#:35460147 PM: CTR Due Date: 04/10/1 CLIENT: 36-EEG Cooler X2 Temp 'C Cooler X3 Temp.'C Cooler g4 Temp.'C Cooler g5 Temp 'C Cooler #6 Temp.'C (Visual) (Visual) (Visual) (Visual) (Visual) (Visual) Courier: — Fed Ex UPS Shipping Method: - Girt C-'ern gr'. C:her Billing: — Reco en! Tracking # Custody Seal on Cooler/Box Present: Packing Material• ao2Cis ss g A tr.cr,ry .ace = cr ca Cuahly Office CUR) DFte '/A T %�IZ Date and Initials of person: Examining contents: Label:_ Deliver: pH: - .. projects _ :a _ _ .e.. r' e.. «. (Correction Factor) h1t3(Actual) L. �aTp'c ese=c.-'''gprocess 'asneg (Correction Factor) (Actual) Sar-Dies o^ .ce cee:^g crccess as oeown (Correction Factor) (Actual) Sar-c'=_s.- CO. coViryg crccess-.ascec:,r (Correction Factor) (Actual) I Sarip:es on .ce, coo,rg process ,as oeg..n (Correction Factor) (Actual) i' S=r'rp'es on coo+^g process -as cea,;r (Correction Factor) (Actual) ` Sarie'es on ce coo!,-g process -as oe_,.,, USPS — Chen: Commercia: i— Dace — Q�rer Pnor,;.; Overn,gh,' S'anca•d Qv''' — :Gro.:;r7 - rle rnaPGnal Pro 'v Sender Third Par'y Crea ! Cal _Yes o Seals intact: ves /Nc ::rrac Sucbie Baps _^lone —Other Samples shorted to lab (If Yes. complete) Snorter Date • Ice: t le: Shjr`el me 5!ue Dr: h =r.e air of .,us!ody ese..t Xy.s _ No N. C-a:r of Custody c,nec Opt - 74' s - No _ N.A Reiindu sued Signature & Samper Na-,e ::3:: :Yes _ No 7N'A Sar^r-les Arrived within HoIc Ttr'ie -- Tes ._ tic - N. A. ;, RUSh Trequested on CO:, -Yes /- NG _N;F, ". : e-:'.:iu ,e ..?'es IT No _N'A v _ r tee'. _ .. . _. ... `s J c 3 .. Jes .. No =N;G. -S.r...: _ .. _., 7 re5 _ No —N SE---- _�.=- __... CC _a^cle _s S pate. e . J _\ate —.. - :::: .a __-e__ _ ac. 7 ::: 35e_esc.c.7 a._zee- -_ /Vac _ ._ %.: -ese._:z" - -.- fi e.......a-e .: ..a,c >5r'r, es - No _N A d a-t = _sent _ - .: =3!: Client Notification% Resolution -�r C ntacle:1 Comments; Resolution (use back for additional comments): Page 13 of 13